WO2015058505A1 - 一种植入传感器的蓄电池 - Google Patents

一种植入传感器的蓄电池 Download PDF

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Publication number
WO2015058505A1
WO2015058505A1 PCT/CN2014/076143 CN2014076143W WO2015058505A1 WO 2015058505 A1 WO2015058505 A1 WO 2015058505A1 CN 2014076143 W CN2014076143 W CN 2014076143W WO 2015058505 A1 WO2015058505 A1 WO 2015058505A1
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sensor
electrode
battery
working electrode
electrolyte
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PCT/CN2014/076143
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English (en)
French (fr)
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王强
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华为技术有限公司
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Publication of WO2015058505A1 publication Critical patent/WO2015058505A1/zh

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    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M10/00—Secondary cells; Manufacture thereof
    • H01M10/42—Methods or arrangements for servicing or maintenance of secondary cells or secondary half-cells
    • H01M10/48—Accumulators combined with arrangements for measuring, testing or indicating the condition of cells, e.g. the level or density of the electrolyte
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M50/00—Constructional details or processes of manufacture of the non-active parts of electrochemical cells other than fuel cells, e.g. hybrid cells
    • H01M50/50—Current conducting connections for cells or batteries
    • H01M50/569—Constructional details of current conducting connections for detecting conditions inside cells or batteries, e.g. details of voltage sensing terminals
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02E—REDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
    • Y02E60/00—Enabling technologies; Technologies with a potential or indirect contribution to GHG emissions mitigation
    • Y02E60/10—Energy storage using batteries

Definitions

  • the present invention relates to the field of batteries, and more particularly to a battery in which a sensor is implanted.
  • battery maintenance is the key to ensuring the safe operation of base stations and data centers.
  • current professional technicians and technical means are far from meeting the maintenance of batteries in base stations and data centers. How to improve the level of battery maintenance, how to improve the quality of battery operation, how to reduce the battery operating costs, is undoubtedly necessary and urgent.
  • the invention provides a battery implanted with a sensor, which can detect the running condition of the battery in time and improve the maintenance level and running quality of the battery.
  • the battery for implanting the sensor according to the present invention includes a sealing cover and a sensor, the top of the battery is provided with a receiving hole, the sensor is fixedly received in the receiving hole, and the sealing cover seals the receiving hole Said battery constitutes a closed cavity; said sensor is an electrochemical sensor, said sensor comprising a housing, a working electrode, a contrast electrode, an electrolyte, an ion exchange membrane and a filter; said shell The air inlet and the air outlet are opened, the filter is disposed at the air inlet and the air outlet, and the working electrode, the comparison electrode, the electrolyte, and the ion exchange membrane are all accommodated in The working electrode and the contrast electrode are arranged side by side in parallel, and the working electrode is electrically connected to a first end of an external constant voltage source via a resistor, and the comparison electrode is electrically connected to the external constant voltage a second end of the source; the working electrode, the contrast electrode, the electrolyte, the external constant voltage source and the resistor form a series current loop
  • the battery is used in any one of a lead-acid battery and a lithium iron phosphate battery.
  • the working electrode is made of any one of mercury, gold, silver, platinum, graphite, carbon cloth, carbon felt, conductive polymer, and polymer composite.
  • the electrolyte is any one of an organic electrolyte, an organogel electrolyte, a solid electrolyte, and a solid polymer electrolyte.
  • the comparison electrode is any one of lithium metal, sodium, and platinum.
  • the sensor further includes a reference electrode, the reference electrode is disposed between the working electrode and the comparison electrode, and the reference electrode, the working electrode, and the contrast The electrodes are arranged in parallel, and the voltage values of the reference electrode and the working electrode are constant.
  • the reference electrode is a calomel electrode or a silver-silver chloride electrode.
  • the filter material of the filter is activated carbon.
  • the ion exchange membrane is a low porosity polytetrafluoroethylene membrane.
  • the battery placed by the present invention places the sensor in the battery, detects internal gas concentration or ion concentration, and collects data in time to predict the operation of a single battery or a plurality of batteries. Line status.
  • the battery management system is controlled and optimized by implanting the sensor, so that the battery can be maintained in time, greatly extending the service life of the battery.
  • it has also changed the passive “headache” mode into a proactive management mode.
  • the maintenance level and the running quality of the battery are improved, and the operating cost of the battery is also reduced.
  • the sensor is miniaturized and has a cost advantage.
  • FIG. 1 is a schematic structural view of a battery in which a sensor is implanted according to an embodiment of the present invention
  • FIG. 2 is a schematic structural diagram of a sensor according to an embodiment of the present invention.
  • Figure 3 is a performance table based on the sensor shown in Figure 2.
  • the battery of the sensor 100 can detect the ion and gas concentration inside the battery.
  • the battery can be any one of a conventional lead-acid battery and a lithium iron phosphate battery.
  • the battery includes a sealing cover (not shown) and a sensor 100.
  • the top of the battery is provided with a receiving hole 110.
  • the sensor 100 is fixedly received in the receiving hole 110.
  • the sealing cover seals the receiving hole 110, and the battery constitutes a closed cavity.
  • the sensor 100 is electrically Chemical sensor.
  • the storage battery of the sensor 100 provided by the embodiment of the invention enables the traditional battery to "open the mouth” and achieve the "smart" state of self-test and self-diagnosis.
  • the sensor 100 can also be implanted in a data center backup battery, a hybrid power cycle battery, and a power grid peaking FM battery.
  • the senor 100 includes a housing (not shown), a working electrode 10, a contrast electrode 20, an electrolyte 30, an ion exchange membrane 40, and a filter 70.
  • the housing defines an air inlet 50 and an air outlet 60, and the filter 70 is disposed at the air inlet 50 and the air outlet 60.
  • the filter 70 only allows gas detectable by the sensor 100 to enter the sensor 100, while absorbing the gas that the sensor 100 cannot detect.
  • the filter medium of the filter 70 is activated carbon.
  • the sensor 100 may detect polluting gases include gases, such as CO, S0 2, C0 2 and NO x. And flammable gases such as H 2 , CH 4 .
  • the metal ions detectable by the sensor 100 include copper (Cu), lead (Pb), Zn (Zn), cadmium (Cd), manganese (Mn), strontium (Sb), strontium (Tl), iron (Fe), Nickel (Ni), arsenic (As), mercury (Hg), selenium (Se), cobalt (Co), molybdenum (Mo), gold (Au), 4 ⁇ (Ag), chromium (Cr), hexavalent chromium, Tin (Sn), 4 bar (Pd) and uranium (U).
  • the working electrode 10, the contrast electrode 20, the electrolyte 30, and the ion exchange membrane 40 are all housed in the casing.
  • the working electrode 10 and the comparison electrode 20 are arranged side by side in parallel, and the working electrode 10 is electrically connected to a first end of an external constant voltage source E via a resistor R, and the comparison electrode 20 is electrically connected to the external constant The second end of the voltage source E.
  • the working electrode 10, the comparison electrode 20, the electrolyte 30, the external constant voltage source E, and the resistor R constitute a series current loop.
  • the voltage of the external constant voltage source E is adjusted, and the corresponding gas or ion is subjected to a redox reaction under the corresponding voltage condition, so that various gas concentrations or ion concentrations can be quantitatively detected.
  • the material of the working electrode 10 is any one of mercury, gold, silver, platinum, graphite, carbon cloth, carbon felt, conductive polymer, and polymer composite material.
  • the working electrode 10 is required to undergo a semi-electrolysis reaction for a long period of time.
  • the electrolyte 30 is an organic or water-washing electrolyte 30 which is required to promote an electrolytic reaction and efficiently transport the ion charge to the electrode.
  • the electrolyte 30 is any one of an organic electrolyte, an organogel electrolyte, a solid electrolyte, and a solid polymer electrolyte.
  • the electrolyte 30 of the sensor 100 is made of the same material as the electrolyte in the battery.
  • the contrast electrode 20 is any one of lithium metal, sodium, and platinum.
  • the material of the working electrode 10 and the contrast electrode 20 may be platinum. In other embodiments, the working electrodes 10 and the contrast electrode 20 may be made of different materials.
  • the sensor 100 further includes a reference electrode 80, and the reference electrode 80 is disposed on the working electrode 10 and the contrast electrode 20 between.
  • the reference electrode 80, the working electrode 10 and the contrast electrode 20 are arranged in parallel, and the voltage values of the reference electrode 80 and the working electrode 10 are constant.
  • the reference electrode 80 typically requires protection and avoids reaction with gases or ions to be detected. To maintain the reference electrode 80 at the same electrochemical potential.
  • the reference electrode 80 does not allow current to pass therethrough to avoid changing the electrochemical potential of the reference electrode 80.
  • the reference electrode 80 is a calomel electrode or a silver-silver chloride electrode.
  • the ion exchange membrane 40 covers one side of the working electrode 10.
  • the ion exchange membrane 40 serves as a barrier for protecting the working electrode 10.
  • the ion exchange membrane 40 is a polytetrafluoroethylene film having a low porosity.
  • the battery of the implant sensor 100 provided by the embodiment of the present invention has strong resolution and a long life expectancy.
  • gas or ions to be measured diffuse through the ion exchange membrane
  • Electrochemical oxidation or reduction reaction is performed on the working electrode 10.
  • the nature of the reaction depends on the thermodynamic potential of the working electrode 10 and the electrochemical redox properties of the analytical ions.
  • the working electrode 10, the comparison electrode 20, the electrolyte 30, the external constant voltage source E and the resistor R constitute a series current loop.
  • the magnitude of the current is proportional to the gas concentration or ion concentration and is measured by the voltage value of the resistor R.
  • the battery provided by the present invention places the sensor 100 in the battery, detects internal gas concentration or ion concentration, and collects data in time to predict the operating condition of a single battery or a plurality of batteries.
  • the battery management system is controlled and optimized by implanting the sensor 100 as compared to existing conventional batteries, so that the battery can be maintained in time, greatly extending the life of the battery.
  • it has changed the passive “headache” mode into a proactive management model.
  • the maintenance level and the running quality of the battery are improved, and the operating cost of the battery is also reduced.
  • the sensor 100 is miniaturized and has a cost advantage.

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  • Chemical & Material Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Electrochemistry (AREA)
  • General Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Manufacturing & Machinery (AREA)
  • Measuring Oxygen Concentration In Cells (AREA)
  • Secondary Cells (AREA)

Abstract

公开了一种植入传感器的蓄电池，包括密封盖和传感器，蓄电池的顶部设收容孔，传感器固定收容于收容孔内，密封盖密封收容孔，所述蓄电池构成一封闭腔体；传感器为电化学传感器，传感器包括壳体、工作电极、对比电极、电解质、离子交换膜和过滤器；壳体开设进气口和出气口，过滤器设于进气口和出气口处，且工作电极、对比电极、电解质、离子交换膜均收容于壳体内；工作电极、对比电极平行并列设置，且工作电极经一电阻电连接至外界恒电压源的第一端，对比电极电连接至外界恒电压源的第二端；工作电极、对比电极、电解质、外界恒电压源和电阻构成串联电流回路。该蓄电池大幅延长了使用寿命。提高了维护水平、运行质量，还降低了运行成本。

Description

一种植入传感器的蓄电池 本申请要求于 2013 年 10 月 24 日提交中国专利局的申请号为 201310505466.2, 其发明名称为 "一种植入传感器的蓄电池" 的中国专利申请的 优先权， 其全部内容通过引用结合在本申请中。
技术领域
本发明涉及一种蓄电池领域， 尤其涉及一种植入传感器的蓄电池。
背景技术
目前蓄电池的维护是保障基站和数据中心安全运行的重点。 当前基站和数 据中心内蓄电池维护存在诸多问题。 如蓄电池组前期未及时发现已劣化的蓄电 池， 致使蓄电池组劣化积累、 加剧， 最终导致蓄电池过早报废。 另外， 目前的 专业技术人员以及技术手段， 已经远远不能满足基站和数据中心内蓄电池的维 护工作。 如何提高蓄电池维护的水平， 如何提高蓄电池运行的质量， 如何减少 蓄电池运行成本， 无疑是当前必要和急迫的。
发明内容
本发明提供一种植入传感器的蓄电池， 可及时检测所述蓄电池的运行状况， 提高蓄电池的维护水平和运行质量。
本发明提供的所述植入传感器的蓄电池， 包括密封盖和传感器， 所述蓄电 池的顶部设收容孔， 所述传感器固定收容于所述收容孔内， 所述密封盖密封所 述收容孔， 所述蓄电池构成一封闭腔体； 所述传感器为电化学传感器， 所述传 感器包括壳体、 工作电极、 对比电极、 电解质、 离子交换膜和过滤器； 所述壳 体开设进气口和出气口， 所述过滤器设于所述进气口和所述出气口处， 且所述 工作电极、 所述对比电极、 所述电解质、 所述离子交换膜均收容于所述壳体内； 所述工作电极、 所述对比电极平行并列设置， 且所述工作电极经一电阻电连接 至外界恒电压源的第一端， 所述对比电极电连接至所述外界恒电压源的第二端； 所述工作电极、 所述对比电极、 所述电解质、 所述外界恒电压源和所述电阻构 成串联电流回路； 所述离子交换膜覆盖于所述工作电极的一侧面。
在第一种可能的实现方式中， 所述蓄电池釆用铅酸蓄电池、 磷酸铁锂蓄电 池中的任意一种。
在第二种可能的实现方式中， 所述工作电极的材质为汞、 金、 银、 铂、 石 墨、 碳布、 碳毡、 导电聚合物、 高分子复合材料中的任一种。
在第三种可能的实现方式中， 所述电解质为有机电解质、 有机凝胶电解质、 固体电解质、 固体聚合物电解质中的任一种。
在第四种可能的实现方式中， 所述对比电极为金属锂、 钠、 铂中的任一种。 在第五种可能的实现方式中， 所述传感器还包括参考电极， 所述参考电极 设于所述工作电极和所述对比电极之间， 且所述参考电极、 所述工作电极和所 述对比电极平行设置， 所述参考电极与所述工作电极的电压值恒定。
结合第五种可能的实现方式， 在第六种可能的实现方式中， 所述参考电极 为甘汞电极或银-氯化银电极。
在第七种可能的实现方式中， 所述过滤器的滤材为活性炭。
在第八种可能的实现方式中， 所述离子交换膜为低孔隙率的聚四氟乙烯薄 膜。
综上， 本发明提供的所述蓄电池， 将所述传感器置于所述蓄电池内， 检测 内部气体浓度或离子浓度， 及时釆集数据以预测单个蓄电池或多个蓄电池的运 行状况。 相比于现有传统蓄电池， 通过植入所述传感器来控制和优化电池管理 系统， 因而可及时维护所述蓄电池， 大幅延长了所述蓄电池的使用寿命。 另外， 还改变了以往被动的 "头痛医头" 模式为积极主动管理模式。 因而， 提高了所 述蓄电池的维护水平、 运行质量， 还降低了所述蓄电池的运行成本。 且所述传 感器微型化， 具有成本优势。
附图说明
为了更清楚地说明本发明的技术方案， 下面将对实施方式中所需要使用的 附图作简单地介绍， 显而易见地， 下面描述中的附图仅仅是本发明的一些实施 方式， 对于本领域普通技术人员来讲， 在不付出创造性劳动的前提下， 还可以 根据这些附图获得其他的附图。
图 1是本发明实施例提供的植入传感器的蓄电池的结构示意图；
图 2是本发明实施例提供的传感器的结构示意图；
图 3是基于图 2所示的传感器的性能表。
具体实施方式
下面将结合本发明实施例中的附图， 对本发明实施例中的技术方案进行清 楚、 完整地描述， 显然， 所描述的实施例仅仅是本发明一部分实施例， 而不是 全部的实施例。 基于本发明中的实施例， 本领域普通技术人员在没有作出创造 性劳动前提下所获得的所有其他实施例， 都属于本发明保护的范围。
本发明实施例提供的植入传感器 100 的蓄电池， 可检测蓄电池内部离子和 气体浓度。 所述蓄电池可釆用传统的铅酸蓄电池、 磷酸铁锂蓄电池中的任意一 种。 参见图 1， 所述蓄电池包括一密封盖（图中未画出）和传感器 100， 所述蓄 电池的顶部设收容孔 110， 所述传感器 100固定收容于所述收容孔 110内。 所述 密封盖密封所述收容孔 110， 所述蓄电池构成一封闭腔体。 所述传感器 100为电 化学传感器。
本发明实施例提供的植入传感器 100 的蓄电池， 让传统蓄电池能 "开口说 话"， 达到自检、 自诊断的 "智慧" 状态。 所述传感器 100也可植入数据中心备 电电池、 混合供电循环电池和电网调峰调频电池中。
参见图 2， 所述传感器 100包括壳体（图中未标示）、 工作电极 10、 对比电 极 20、 电解质 30、 离子交换膜 40和过滤器 70。
所述壳体开设进气口 50和出气口 60，所述过滤器 70设于所述进气口 50和 所述出气口 60处。 所述蓄电池经长期使用后， 内部易产生较多气体。 所述过滤 器 70仅允许所述传感器 100可检测的气体进入所述传感器 100， 而吸收去除所 述传感器 100无法检测的气体。本实施方式中，所述过滤器 70的滤材为活性炭。 所述传感器 100可检测的气体包括污染气体， 如 CO、 S02、 C02和 NOx 。 和可 燃绕性气体，如 H2、 CH4。所述传感器 100可检测的金属离子包括铜 (Cu)、铅 (Pb)、 辞 (Zn)、 镉 (Cd)、 锰 (Mn)、 锑 (Sb)、 铊 (Tl)、 铁 (Fe)、 镍 (Ni)、 砷 (As)、 汞 (Hg)、 硒 (Se)、 钴 (Co)、 钼 (Mo)、 金 (Au)、 4艮 (Ag)、 铬 (Cr)、 六价铬、 锡 (Sn)、 4巴 (Pd)和 铀 (U)。
所述工作电极 10、 所述对比电极 20、 所述电解质 30、 所述离子交换膜 40 均收容于所述壳体内。
所述工作电极 10、 所述对比电极 20平行并列设置， 且所述工作电极 10经 一电阻 R电连接至外界恒电压源 E的第一端，所述对比电极 20电连接至所述外 界恒电压源 E的第二端。 所述工作电极 10、 所述对比电极 20、 所述电解质 30、 所述外界恒电压源 E和所述电阻 R构成串联电流回路。 调节所述外界恒电压源 E的电压，在相应的电压条件下与相应的气体或离子进行氧化还原反应，从而能 定量检测各种气体浓度或离子浓度。 所述工作电极 10 的材质为汞、 金、 银、 铂、 石墨、 碳布、 碳毡、 导电聚 合物、 高分子复合材料中的任一种。 所述工作电极 10需在较长时间内进行半 电解反应。
所述电解质 30为有机或水洗电解质 30， 需能促进电解反应，有效将离子电 荷传送至电极。 具体的， 所述电解质 30为有机电解质、 有机凝胶电解质、 固体 电解质、 固体聚合物电解质中的任一种。 优选的， 所述传感器 100 的所述电解 质 30与所述蓄电池内的电解液材质相同。
所述对比电极 20为金属锂、 钠、 铂中的任一种。 本实施方式中， 所述工作 电极 10和所述对比电极 20的材质可均为铂。 在其他实施方式中， 所述工作电 极 10和所述对比电极 20的材质可不相同。
另外， 为了给所述电解质 30中的所述工作电极 10提供稳定的电化学电位， 所述传感器 100还包括参考电极 80， 所述参考电极 80设于所述工作电极 10和 所述对比电极 20之间。 且所述参考电极 80、 所述工作电极 10和所述对比电极 20平行设置， 所述参考电极 80与所述工作电极 10的电压值恒定。 所述参考电 极 80通常需要保护而且避免与待检测的气体或离子发生反应。 以保持所述参考 电极 80处于同一电化学电位。 此外， 所述参考电极 80不允许有电流通过， 以 避免改变所述参考电极 80的电化学电位。 所述参考电极 80为甘汞电极或银-氯 化银电极。
所述离子交换膜 40覆盖于所述工作电极 10的一侧面。 所述离子交换膜 40 作为屏障用于保护所述工作电极 10。 本实施方式中， 所述离子交换膜 40为低孔 隙率的聚四氟乙烯薄膜。
参见图 3， 本发明实施例提供的所述植入传感器 100的蓄电池， 具有较强的 分辨率， 和较长的期望寿命。 本发明提供的所述蓄电池中， 待测的气体或离子扩散透过所述离子交换膜
40， 在所述工作电极 10上进行电化学氧化或还原反应。 其反应的性质根据所述 工作电极 10的热力学电位和分析离子的电化学氧化还原性质而定。 所述工作电 极 10、 所述对比电极 20、 所述电解质 30、 所述外界恒电压源 E和所述电阻 R 构成串联电流回路。 所述电流大小与所述气体浓度或离子浓度成正比， 并通过 所述电阻 R的电压值予以测量。
本发明提供的所述蓄电池， 将所述传感器 100置于所述蓄电池内， 检测内 部气体浓度或离子浓度， 及时釆集数据以预测单个蓄电池或多个蓄电池的运行 状况。 相比于现有传统蓄电池， 通过植入所述传感器 100来控制和优化电池管 理系统， 因而可及时维护所述蓄电池， 大幅延长了所述蓄电池的使用寿命。 另 外， 还改变了以往被动的 "头痛医头" 模式为积极主动管理模式。 因而， 提高 了所述蓄电池的维护水平、 运行质量， 还降低了所述蓄电池的运行成本。 且所 述传感器 100微型化， 具有成本优势。
最后应说明的是： 以上实施例仅用以说明本发明的技术方案， 而非对其限 制； 尽管参照前述实施例对本发明进行了详细的说明， 本领域的普通技术人员 应当理解： 其依然可以对前述各实施例所记载的技术方案进行修改， 或者对其 中部分技术特征进行等同替换； 而这些修改或者替换， 并不使相应技术方案的 本质脱离本发明各实施例技术方案的精神和范围。

Claims

权 利 要 求
1. 一种植入传感器的蓄电池， 其特征在于， 所述蓄电池包括密封盖和传感 器， 所述蓄电池的顶部设收容孔， 所述传感器固定收容于所述收容孔内， 所述 密封盖密封所述收容孔， 所述蓄电池构成一封闭腔体； 所述传感器为电化学传 感器， 所述传感器包括壳体、 工作电极、 对比电极、 电解质、 离子交换膜和过 滤器； 所述壳体开设进气口和出气口， 所述过滤器设于所述进气口和所述出气 口处， 且所述工作电极、 所述对比电极、 所述电解质、 所述离子交换膜均收容 于所述壳体内； 所述工作电极、 所述对比电极平行并列设置， 且所述工作电极 经一电阻电连接至外界恒电压源的第一端， 所述对比电极电连接至所述外界恒 电压源的第二端； 所述工作电极、 所述对比电极、 所述电解质、 所述外界恒电 压源和所述电阻构成串联电流回路； 所述离子交换膜覆盖于所述工作电极的一 侧面。
2. 如权利要求 1所述的植入传感器的蓄电池， 其特征在于， 所述蓄电池釆 用铅酸蓄电池、 磷酸铁锂蓄电池中的任意一种。
3. 如权利要求 1所述的植入传感器的蓄电池， 其特征在于， 所述工作电极 的材质为汞、 金、 银、 铂、 石墨、 碳布、 碳毡、 导电聚合物、 高分子复合材料 中的任一种。
4. 如权利要求 1所述的植入传感器的蓄电池， 其特征在于， 所述电解质为 有机电解质、 有机凝胶电解质、 固体电解质、 固体聚合物电解质中的任一种。
5. 如权利要求 1所述的植入传感器的蓄电池， 其特征在于， 所述对比电极 为金属锂、 钠、 铂中的任一种。
6. 如权利要求 1所述的植入传感器的蓄电池， 其特征在于， 所述传感器还 包括参考电极， 所述参考电极设于所述工作电极和所述对比电极之间， 且所述 参考电极、 所述工作电极和所述对比电极平行设置， 所述参考电极与所述工作 电极的电压值恒定。
7. 如权利要求 6所述的植入传感器的蓄电池， 其特征在于， 所述参考电极 为甘汞电极或银-氯化银电极。
8. 如权利要求 1所述的植入传感器的蓄电池， 其特征在于， 所述过滤器的 滤材为活性炭。
9. 如权利要求 1所述的植入传感器的蓄电池， 其特征在于， 所述离子交换 膜为低孔隙率的聚四氟乙烯薄膜。
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