WO2015047170A1 - Edible fat composition - Google Patents

Edible fat composition Download PDF

Info

Publication number
WO2015047170A1
WO2015047170A1 PCT/SE2014/051097 SE2014051097W WO2015047170A1 WO 2015047170 A1 WO2015047170 A1 WO 2015047170A1 SE 2014051097 W SE2014051097 W SE 2014051097W WO 2015047170 A1 WO2015047170 A1 WO 2015047170A1
Authority
WO
WIPO (PCT)
Prior art keywords
fat
fat composition
oil
edible fat
edible
Prior art date
Application number
PCT/SE2014/051097
Other languages
French (fr)
Inventor
Fidelmar Bucio GARCÍA
Laura Alejandra Calderón ROCHA
Original Assignee
Aarhuskarlshamn Ab
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Aarhuskarlshamn Ab filed Critical Aarhuskarlshamn Ab
Priority to MX2016003619A priority Critical patent/MX2016003619A/en
Publication of WO2015047170A1 publication Critical patent/WO2015047170A1/en

Links

Classifications

    • CCHEMISTRY; METALLURGY
    • C11ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11CFATTY ACIDS FROM FATS, OILS OR WAXES; CANDLES; FATS, OILS OR FATTY ACIDS BY CHEMICAL MODIFICATION OF FATS, OILS, OR FATTY ACIDS OBTAINED THEREFROM
    • C11C3/00Fats, oils, or fatty acids by chemical modification of fats, oils, or fatty acids obtained therefrom
    • C11C3/04Fats, oils, or fatty acids by chemical modification of fats, oils, or fatty acids obtained therefrom by esterification of fats or fatty oils
    • C11C3/10Ester interchange
    • AHUMAN NECESSITIES
    • A23FOODS OR FOODSTUFFS; TREATMENT THEREOF, NOT COVERED BY OTHER CLASSES
    • A23CDAIRY PRODUCTS, e.g. MILK, BUTTER OR CHEESE; MILK OR CHEESE SUBSTITUTES; MAKING THEREOF
    • A23C13/00Cream; Cream preparations; Making thereof
    • A23C13/12Cream preparations
    • AHUMAN NECESSITIES
    • A23FOODS OR FOODSTUFFS; TREATMENT THEREOF, NOT COVERED BY OTHER CLASSES
    • A23CDAIRY PRODUCTS, e.g. MILK, BUTTER OR CHEESE; MILK OR CHEESE SUBSTITUTES; MAKING THEREOF
    • A23C15/00Butter; Butter preparations; Making thereof
    • A23C15/12Butter preparations
    • A23C15/126Butter containing a minority of vegetable oils; Enrichment of butter with fatty acids
    • AHUMAN NECESSITIES
    • A23FOODS OR FOODSTUFFS; TREATMENT THEREOF, NOT COVERED BY OTHER CLASSES
    • A23CDAIRY PRODUCTS, e.g. MILK, BUTTER OR CHEESE; MILK OR CHEESE SUBSTITUTES; MAKING THEREOF
    • A23C19/00Cheese; Cheese preparations; Making thereof
    • A23C19/02Making cheese curd
    • A23C19/055Addition of non-milk fats or non-milk proteins, polyol fatty acid polyesters or mineral oils
    • AHUMAN NECESSITIES
    • A23FOODS OR FOODSTUFFS; TREATMENT THEREOF, NOT COVERED BY OTHER CLASSES
    • A23CDAIRY PRODUCTS, e.g. MILK, BUTTER OR CHEESE; MILK OR CHEESE SUBSTITUTES; MAKING THEREOF
    • A23C9/00Milk preparations; Milk powder or milk powder preparations
    • A23C9/12Fermented milk preparations; Treatment using microorganisms or enzymes
    • A23C9/13Fermented milk preparations; Treatment using microorganisms or enzymes using additives
    • A23C9/1315Non-milk proteins or fats; Seeds, pulses, cereals or soja; Fatty acids, phospholipids, mono- or diglycerides or derivatives therefrom; Egg products
    • AHUMAN NECESSITIES
    • A23FOODS OR FOODSTUFFS; TREATMENT THEREOF, NOT COVERED BY OTHER CLASSES
    • A23CDAIRY PRODUCTS, e.g. MILK, BUTTER OR CHEESE; MILK OR CHEESE SUBSTITUTES; MAKING THEREOF
    • A23C9/00Milk preparations; Milk powder or milk powder preparations
    • A23C9/152Milk preparations; Milk powder or milk powder preparations containing additives
    • A23C9/1528Fatty acids; Mono- or diglycerides; Petroleum jelly; Paraffine; Phospholipids; Derivatives thereof
    • AHUMAN NECESSITIES
    • A23FOODS OR FOODSTUFFS; TREATMENT THEREOF, NOT COVERED BY OTHER CLASSES
    • A23GCOCOA; COCOA PRODUCTS, e.g. CHOCOLATE; SUBSTITUTES FOR COCOA OR COCOA PRODUCTS; CONFECTIONERY; CHEWING GUM; ICE-CREAM; PREPARATION THEREOF
    • A23G1/00Cocoa; Cocoa products, e.g. chocolate; Substitutes therefor
    • A23G1/30Cocoa products, e.g. chocolate; Substitutes therefor
    • A23G1/32Cocoa products, e.g. chocolate; Substitutes therefor characterised by the composition containing organic or inorganic compounds
    • A23G1/36Cocoa products, e.g. chocolate; Substitutes therefor characterised by the composition containing organic or inorganic compounds characterised by the fats used
    • AHUMAN NECESSITIES
    • A23FOODS OR FOODSTUFFS; TREATMENT THEREOF, NOT COVERED BY OTHER CLASSES
    • A23GCOCOA; COCOA PRODUCTS, e.g. CHOCOLATE; SUBSTITUTES FOR COCOA OR COCOA PRODUCTS; CONFECTIONERY; CHEWING GUM; ICE-CREAM; PREPARATION THEREOF
    • A23G9/00Frozen sweets, e.g. ice confectionery, ice-cream; Mixtures therefor
    • A23G9/32Frozen sweets, e.g. ice confectionery, ice-cream; Mixtures therefor characterised by the composition containing organic or inorganic compounds
    • A23G9/327Frozen sweets, e.g. ice confectionery, ice-cream; Mixtures therefor characterised by the composition containing organic or inorganic compounds characterised by the fatty product used, e.g. fat, fatty acid, fatty alcohol, their esters, lecithin, glycerides
    • CCHEMISTRY; METALLURGY
    • C11ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11CFATTY ACIDS FROM FATS, OILS OR WAXES; CANDLES; FATS, OILS OR FATTY ACIDS BY CHEMICAL MODIFICATION OF FATS, OILS, OR FATTY ACIDS OBTAINED THEREFROM
    • C11C3/00Fats, oils, or fatty acids by chemical modification of fats, oils, or fatty acids obtained therefrom
    • C11C3/02Fats, oils, or fatty acids by chemical modification of fats, oils, or fatty acids obtained therefrom by esterification of fatty acids with glycerol

Definitions

  • the present invention relates to the field of butter fat equivalents. More particularly, the invention relates to a fat composition made of vegetable oils and animal fat suitable to extend milk fat products.
  • Milk fat is, apart from being the fat part of its natural source milk, also part of processed dairy products such as cheese, yoghurt, cream and butter blends.
  • milk fat also called butter fat
  • the supply of milk fat, also called butter fat is limited, particularly in some geographical areas due to the limited supply of fresh milk. Due to its complex nature, it is difficult to replace milk fat and fats designed to extend
  • the fatty acids of milk/butter fat are composed of saturated and unsaturated fatty acids.
  • the saturated fatty acids are mainly palmitic acid, myristic acid, stearic acid, lower (at most 12 carbon atoms) saturated fatty acids as well as traces of pentadecanoic acid and heptadecanoic acid.
  • the unsaturated fatty acids are mainly oleic acid, palmitoleic acid, linoleic acid and linolenic acid.
  • WO2009/005351 describes a vegetable fat blend for replacing milk fat and processed food products containing such vegetable fat blend. With the aim to replace the milk fat with a healthier fat profile, WO2009/005351 provides a vegetable fat composition with fats having a different chemical profile and composition than milk fat.
  • WO1989/008988 describes a dairy substitute formulation comprising 6-10 parts by weight of an oil in a carbohydrate or protein matrix, maltodextrin, emulsifiers as well as antioxidants to provide a fat-modified dairy milk.
  • Products produced comprising the dairy substitute include custards, cream substitutes, ice cream and ice confections, soft serve creams, coffee whiteners, yoghurt, cakes and pastries, biscuits and table spreads (butter replacer).
  • the present invention relates to an edible fat composition
  • an edible fat composition comprising a blend of vegetable oils and animal fat with a combined fatty acid composition of about 3-15% of C14:0 and about 2-6% of C16: l and a total of short chain triglycerides (SCT) C4:0 and C6:0 of ⁇ 7%.
  • SCT short chain triglycerides
  • the amount of and ratio between SCT may be used to adjust for example the solid fat content (SFC) in such a way as to closely resemble the SFC, as well as fatty acid profile and a very similar chemical and physical profile as of milk fat.
  • the short chain triglycerides (SCT) comprise about 1-4% C4:0 and about 0.1-3% C6:0.
  • the total amount of SCT and the relative amounts of C4:0 and C6:0 is for example important to adjust the SFC, as well as fatty acid profile to achieve a very similar chemical and physical profile of the edible fat product compared to a fat product based on butter fat.
  • said edible fat composition is a fat composition wherein the short chain triglycerides (SCT) C4:0 is about 1.8-4%) and C6:0 is about 0.5-3%.
  • SCT short chain triglycerides
  • the molar ratio between C4:0 and C6:0 SCT in the edible fat composition is between 0.5 and 5.
  • said SCT comprises about 60-75%> C4:0 and about 25-35%> C6:0 short chain fatty acids.
  • said edible fat composition further comprises at least one of 0.5-3% of C8:0, 0.5-3% of C10:0, 2-5% of C12:0, 3- 15% of C14:0, 24-41% of C16:0, 2-6% of C16: l, 6-15% of C18:0, 18-35% of C18: l and 0.5-4% C18:2.
  • said animal fat is selected from tallow, lard and a mixture thereof.
  • said animal fat is tallow, such as beef tallow.
  • the vegetable oils in said edible fat composition is at least one selected from the group consisting of palm oil, palm kernel oil, coconut oil, soybean oil, partially and fully hydrogenated soybean oil, high oleic sunflower oil, hydrogenated canola oil, hydrogenated palm kernel oil and fractions thereof.
  • fractions are fractions of palm oil such as for example palm mid fractions (PMF) and other fractions mentioned herein.
  • said vegetable oil, animal fat and SCT are interesterified after blending. This has the benefit of providing a SFC with a suitable functionality for a specific application.
  • a further aspect of the present invention relates to a process for preparing an edible fat composition, said process comprises the steps of
  • step b interesterification of the blend of step b.
  • Further embodiments of the process are wherein the SCT comprises 60-75% of C4:0 and 25-35% of C6:0 short chain fatty acids.
  • process further comprises at least one of e) bleaching and f) deodorizing the interesterified blend of step 8c) above and optionally a step d) deodorization of the blend of step 8b.
  • animal fat is selected from any of tallow, such as beef tallow, lard and a mixture thereof.
  • said vegetable oil is at least one selected from the group consisting of palm oil, palm kernel oil, coconut oil, , soybean oil, partially and fully hydrogenated soybean oil, high oleic sunflower oil, hydrogenated canola oil and fractions thereof.
  • fractions thereof are palm mid fractions (PMF).
  • Still even further embodiments of the process are the process in any of its embodiments for preparing an edible fat composition according to any of its embodiments herein.
  • composition according to any of its embodiments or the edible fat composition prepared by the process according to any of its embodiments is replacing all or a part of the butter fat of a dairy product or a confectionary product with milk fat.
  • said dairy product is a milk, margarine, butter blend, liquid, whipping and sour cream, hard cheese, processed cheese or fresh cheese, yoghurt or an ice cream product and the confectionary product with milk fat is a chocolate or a compound.
  • a dairy product or a milk fat containing confectionary products comprising the edible fat composition according to any of its embodiments or the edible fat composition prepared by the process according to any of its embodiments.
  • Said dairy or confectionary product may in further embodiments be selected from the group consisting of a milk, a margarine, a butter blend, a liquid cream, a whipping cream, a sour cream, a hard cheese, a processed cheese, a fresh cheese, a yoghurt and an ice cream or a confectionary product, such as a chocolate or compound, e.g. a milk chocolate or compound with milk fat.
  • Fig la-d shows a comparison of fatty acid composition between butter fat (hashed) and an edible fat composition of the invention (black).
  • Fig la shows one embodiment of the invention (Embodiment 1 or Embl) according to Example 1 with FAME (fatty acid methyl ester) profile compared to butter fat.
  • Embodiment 1 is in black line as compared to butter fat in hashed line.
  • Table 1 shows the same information in numbers.
  • Fig lb shows an extended fat embodiment with 30 wt.% of Embodiment 1 + 70wt.% of butter fat in black line compared to butter fat in hashed line.
  • Table 2 shows the same information in numbers.
  • Fig lc shows a second extended fat embodiment with 40 wt.% of Embodiment 1 + 60wt.% of butter fat in black line compared to butter fat in hashed line.
  • Table 3 shows the same information in numbers.
  • Fig Id shows a third extended fat embodiment with 50 wt.% of Embodiment 1 + 50wt.% of butter fat in black line compared to butter fat in hashed line.
  • Fig 2 shows an example of the production process.
  • the esterification is between butyric fatty acid and caproic fatty acid and glycerin to produce a SCT-fat.
  • SCT-fat is then imported together with the vegetable oils and edible tallow and blended.
  • Optionally (*) the blend is deodorized.
  • the blend is then interesterified, followed by bleaching and deodorization.
  • the last step, packaging is of course dependent on the further application process for each and every dairy or milk containing confectionary product.
  • milk fat and “butter fat” is used with the same meaning and interchangeably.
  • Milk/butter fat represents the fatty portion of milk.
  • fatty acid encompasses fatty acid residues in triglycerides.
  • SCT short-chain triglycerides.
  • Short chain triglycerides contain short-chain fatty acids (SCFA) with aliphatic tails of fewer than six carbons.
  • SCFA short-chain fatty acids
  • edible is something that is suitable for use as food or as part of a food product, such as a dairy or confectionary product.
  • An edible fat is thus suitable for use as fat in food or food product and an edible composition is a composition suitable for use in food or a food product, such as a dairy or confectionary product.
  • % or “percentage” all relates to weight percentage i.e. wt.% or wt.-% if nothing else is indicated.
  • the singular forms "a”, “and” and “the” include plural referents unless the context clearly dictates otherwise.
  • At least one is intended to mean one or more, i.e. 1, 2, 3, 4, 5, 6, 7, 8, 9, 10, etc.
  • vegetable oil and “vegetable fat” is used interchangeably, unless otherwise specified.
  • a fat composition designed to be a milk/butter fat equivalent whilst maintaining a similar fatty acid profile as compared to butter fat.
  • Said composition is a butter fat equivalent, made by a blend of animal fat and vegetable oils and it has surprisingly been found that such a blend has similar fatty acid profile and a very similar chemical and physical profile as milk fat, which means that apart from its similar fatty acid profile, also melting point, cholesterol levels, phytosterol levels etc. is similar as for butter fat.
  • Said fat composition is an edible fat composition and is used to replace all or parts of butter fat in dairy or confectionary products.
  • the butter fat by replacing all or parts of the butter fat, it is extending the original butter fat to different degrees in a dairy product or confectionary product comprising milk fat, such as a compound or chocolate, thereby keeping all benefits with butter fat relating to fatty acid profile as well as a very similar chemical and physical profile as butter fat.
  • the fat composition according to the invention will also thereby reduce the production costs of the dairy or confectionary product by extending traditional butter fat still while maintaining the physiochemical profile compared to milk fat.
  • the use of the edible fat composition as described herein by extending all or parts of the butter fat in dairy or confectionary products will also help the dairy and the confectionary industry to overcome the shortage of butterfat, particularly relating to seasonal variations. It should also be noted that milk fat compositions vary over the year.
  • fatty acid composition may also occur.
  • content in milk fat of butyric acid may vary between about 0.3% and 2.3%
  • caproic acid may vary between about 0.8% and 1.7%
  • content of laurylic acid between about 2.0% and 4.3%
  • content of myristic acid between about 7.3%) and 12.4% by weight
  • Palmitoleic acid content in milk fat may vary between 0.3% and 3.5% by weight.
  • the content of saturated fats may be between about 57% and 71%, the content of mono-unsaturated fats may vary between about 23% and 38%, while the content of poly-unsaturated may vary between about 0.5% and 7.4% by weight.
  • the edible fat compositions according to embodiments of the present invention may also vary within certain limits without impairing the quality of the dairy products or confectionary products to which the edible fat compositions are added.
  • the present invention relates to an edible fat composition
  • an edible fat composition comprising a blend of vegetable oils and animal fat with a fatty acid composition of about 3-15% of C 14:0 and about 2-6% of C16: l and a total of short chain triglycerides (SCT) C4:0 and C6:0 of ⁇ 7%.
  • SCT are triglycerides comprising fatty acids with aliphatic tails of fewer than six carbons esterified with glycerol.
  • the SCT comprises 60-75%) of C4:0 (butyric) and 25-35%> of C6:0 (caproic) short chain fatty acids esterified with glycerol.
  • said edible fat composition further comprises at least one of 0.5-3% of C8:0, 0.5-3% of C10:0, 2-5% of C12:0, 3-15% of C14:0, 24-41% of C16:0, 2-6% of C16: l, 6- 15% of C18:0, 18-35% of C18: l and 0.5-4% C18:2.
  • said edible fat composition comprises 0.5- 3% of C8:0, 0.5-3% of C10:0, 2-5% of C12:0, 3-15% of C14:0, 24-41% of C16:0, 2-6% of C16: l, 6-15% of C18:0, 18-35% of C18: l and 0.5-4% C18:2.
  • the source of the vegetable fats for providing fatty acids may vary, as long as the vegetable fat provides suitable amounts of each fatty acid as specified herein.
  • suitable sources for fatty acids of the vegetable oils in said edible fat composition is at least one selected from the group consisting of palm oil, palm kernel oil, coconut oil, soybean oil, partially or fully
  • fractions thereof are for example fractions of palm oil with IV (iodine value) of 20-50, palm kernel oil fractions with IV of 6-30, such as 12-26, coconut oil fractions of IV of 5-15, such as 6-12.
  • said edible fat composition comprises palm oil, palm kernel oil, animal fat, for example edible tallow, and SCT.
  • palm oil is about 13-19wt.%, such as 13, 14, 15, 16, 17, 18, or even 19wt.% of palm oil or its fractions, about 7-13wt.%, such as 7, 8, 9, 10, 11, 12 or even 13wt.% of palm kernel oil or its fractions, about 64- 70wt.% of edible tallow such as e.g. beef tallow, and about 7-8wt.% of SCT- fat, such as 7 or 8wt.%.
  • Said SCT-fat is made of short chain fatty acids C4:0 and C6:0 esterified with glycerol to a short chain triglyceride fat (SCT-fat), and wherein the SCT comprises 60-75% of C4:0 and 25-35% of C6:0 short chain fatty acids in wt.% and carbomdouble bound.
  • all the fats are interesterified after blending.
  • the edible fat composition may in particular embodiments comprise about 67% edible tallow and about 7% SCT in wt.%.
  • Said edible fat composition may then further comprise about 16% palm oil or its fractions thereof, and about 10% palm kernel oil (PCO) or its fractions thereof in wt.%, and all fats are interesterified after blending.
  • Short chain triglycerides may be made by esterification of any natural source of said fatty acid with glycerol.
  • C4:0 and C6:0 may be from any commercially available source of natural butyric and/or caproic acid (Acidchem International Sdn. Bhd., Axxence, DE, or Elan Chemical Company, Inc. NJ, US) or industrially prepared e.g. butyric acid by fermentation of sugar and starch.
  • the edible fat composition further comprises animal fat. Any animal fat may be used as long as it is edible. Further, said animal fat may be hydrogenated of not. Thus, further embodiments are wherein said animal fat is selected from tallow, lard and a mixture thereof. Tallow and lard may be from any animal, as long as it is edible. In further embodiments, said animal fat is tallow, such as beef tallow.
  • the edible fat composition comprises different types of additives.
  • additives are antioxidants, e.g. butylated hydroxytoluene (BTH, also known as butylhydroxytoluene), flavours, e.g. butter oil, etc. depending on the specific application.
  • BTH butylated hydroxytoluene
  • the antioxidants may also be natural antioxidants, such as ascorbyl palmitate and tocopherols. It is, however, important to point out that the fat part only of the edible fat composition described herein even without any added flavors provides a surprisingly good flavor by itself in the final dairy and confectionary product.
  • Figure 1 shows a comparison of fatty acids between butter fat (black) and an embodiment of an edible fat composition of the invention (dashed).
  • a process for preparing said edible fat composition and all its embodiments comprises the steps of a) esterification of short chain fatty acids C4:0 and C6:0 with glycerol to short chain triglycerides (SCT), wherein the SCT comprises 60-75% by weight of C4:0 and 25-35%> by weight of C6:0 short chain fatty acids with 4 and 6 carbon atoms respectively and 0 carbon-carbon double bonds, b) blending vegetable oil(s) including said esterified SCT in a) and animal fat, and, and c) interesterification of the blend.
  • SCT short chain triglycerides
  • SCT comprises 60-75%) of C4:0 and 25-35%> of C6:0 short chain fatty acids in with 4 and 6 carbon atoms respectively and 0 carbon-carbon double bonds.
  • process further comprises at least one of e) bleaching and f) deodorizing the interesterified blend of step 8c) above and optionally a step d) deodorization of the blend of step 8b.
  • each of the ingredients forming the blend of step b) above may be each one previously refined, bleached and deodorized. Further, particularly if the acid value is high, the blend must be deodorized to avoid MeONa, i.e. sodium methoxide or CH 3 ONa, contamination in the interesterification process.
  • MeONa i.e. sodium methoxide or CH 3 ONa
  • the interesterification process in step c) may be a chemical interesterification or an enzymatic interesterification. Both chemical interesterification and enzymatic interesterification is described well in the art. Both chemical and enzymatic interesterification may be done at standard procedures. One example of the process is shown in figure 2.
  • animal fat is selected from any of tallow, such as beef tallow, lard and a mixture thereof.
  • said vegetable oil is at least one selected from the group consisting of palm oil, palm kernel oil, coconut oil, soybean oil, partially or fully hydrogenated soybean oil, high oleic sunflower oil, hydrogenated canola oil and fractions thereof. Fractions thereof may be any fraction of the vegetable oil, particularly fractions mentioned herein.
  • Still even further embodiments of the process are the process in any of its embodiments for preparing an edible fat composition according to any of its embodiments herein.
  • compositions according to any of its embodiments or the edible fat composition prepared by the process according to any of its embodiments is replacing all or a part of the butter fat of a dairy or confectionary product.
  • said dairy product is a milk, margarine, butter blend, liquid, whipping and sour cream, hard cheese, processed cheese or fresh cheese, yoghurt or an ice cream product or a confectionary product, such as a chocolate or compound, e.g. a milk chocolate or compound with milk fat.
  • dairy product or confectionary product comprising the edible fat composition according to any of its embodiments or the edible fat composition prepared by the process according to any of its embodiments.
  • Said dairy or confectionary product may in further embodiments be selected from the group consisting of a milk, a margarine, a butter blend, a liquid cream, a whipping cream, a sour cream, a hard cheese, a processed cheese, a fresh cheese, a yoghurt and an ice cream or a confectionary product, such as a chocolate or compound, e.g. a milk chocolate or compound with milk fat.
  • the source of lauric C 12:0 in the edible fat composition may, apart from PKO also be coconut oil or any other source with high lauric content, if such source is more suitable in SFC for a particular application.
  • hydrogenation of the vegetable fat part such as e.g. PKO (palm kernel oil), soybean oil and canola oil, is suitable to get a desired SFC.
  • palm kernel oil has an iodine value of 14 to 21 and may be hydrogenated to give products with IV down to 2.
  • the palm oil can be fractionated into an olein (IV 21-26) and a stearin (IV 6-8) and each of these fractions may then further be hydrogenated.
  • the fractionated parts of palm oil differ particularly in their levels of palmitic acid and oleic acid.
  • Said vegetable fat may also be interesterified, such as for example
  • said vegetable fat is interesterified with the SCT and the animal fat.
  • said edible composition and all its embodiments or the composition prepared by the process and all its embodiments is replacing all or a part of the butter fat of a dairy or confectionary product, while still maintaining a similar fatty acid profile to milk/butter fat.
  • it is intended to mean from about 5 wt.% to about 90 or even 100% of the butter fat of a dairy or confectionary product, such as 5, 10, 15, 20, 25, 30, 35, 40, 45, 50, 55, 60, 65, 70, 75, 80, 85, 90, 95, 99 or even 100 wt.% of the butter fat of the dairy product.
  • Further embodiments are wherein 0.1 to 100% of the butter fat is exchanged to the fat composition of the invention.
  • Even further embodiments are whereon 0.1 to 50% is exchanged to the fat composition of the invention.
  • Still even further embodiments are wherein up to and including about 30%, such as wherein 0.1 to 30% is exchanged to the fat composition of the invention.
  • the dairy or confectionary product may be any dairy product such as a milk, a margarine, a butter blend, a liquid, a whipping and a sour cream, a hard cheese, a processed cheese or fresh cheese, a yoghurt or an ice cream product or a confectionary product, such as a chocolate or compound, e.g. a milk chocolate or compound with milk fat.
  • dairy product such as a milk, a margarine, a butter blend, a liquid, a whipping and a sour cream, a hard cheese, a processed cheese or fresh cheese, a yoghurt or an ice cream product or a confectionary product, such as a chocolate or compound, e.g. a milk chocolate or compound with milk fat.
  • confectionary product comprising the edible fat composition or any of its embodiments or the edible fat composition or any of its embodiments prepared by the process or any of its embodiments described herein.
  • One embodiment is a milk comprising the edible fat composition or any of its embodiments or the edible fat composition or any of its embodiments prepared by the process or any of its embodiments described herein.
  • a further embodiment is a margarine comprising the edible fat composition or any of its embodiments or the edible fat composition or any of its embodiments prepared by the process or any of its embodiments described herein.
  • Still a further embodiment is a butter blend comprising the edible fat composition or any of its embodiments or the edible fat composition or any of its embodiments prepared by the process or any of its embodiments described herein.
  • Still a further embodiment is a cream, such as a liquid cream, a sour cream or a whipping cream, comprising the edible fat composition or any of its embodiments or the edible fat composition or any of its embodiments prepared by the process or any of its embodiments described herein.
  • a cream such as a liquid cream, a sour cream or a whipping cream, comprising the edible fat composition or any of its embodiments or the edible fat composition or any of its embodiments prepared by the process or any of its embodiments described herein.
  • Still a further embodiment is a hard cheese comprising the edible fat composition or any of its embodiments or the edible fat composition or any of its embodiments prepared by the process or any of its embodiments described herein.
  • Still a further embodiment is a processed or fresh cheese comprising the edible fat composition or any of its embodiments or the edible fat composition or any of its embodiments prepared by the process or any of its embodiments described herein.
  • Still a further embodiment is a yoghurt comprising the edible fat composition or any of its embodiments or the edible fat composition or any of its embodiments prepared by the process or any of its embodiments described herein.
  • An ice cream product comprising the edible fat composition or any of its embodiments or the edible fat composition or any of its embodiments prepared by the process or any of its embodiments described herein.
  • Example 1 Production of an edible fat composition for extending butter fat.
  • This Example describes the production of edible fat compositions according to embodiments of the invention for extending butter fat.
  • compositions are butter fat equivalent made of a blend of vegetable and animal fat according to the invention.
  • SCT-FAT varies in its C4 and C6 content according to a general formula.
  • One example of a general formula is given below:
  • Antioxidant 150 ppm BHT
  • the wt.% of SCT-FAT is changed, i.e. increased or decreased.
  • the wt.% of Palm oil and/or Palm Kernel Oil is decreased or increased accordingly to compensate to have a total of 100 wt.%.
  • one particular edible fat composition is Embl which has C6:0 of 1.31 wt.% and C4:0 of 2.15 wt.%, i.e. having a total of 3.46 wt.% instead of the 7% in the general formula.
  • the 3.54 wt.% left up to 7% is compensated by Palm Oil as well as Palm Kernel Oil in about equal amounts or similar depending on the application of the edible fat composition, determined case by case.
  • Esterification process is made by blending the C4:0, C6:0 and glycerol in a reactor, then start at 80°C and atmospheric pressure, increasing 10°C each 4 - 5 hours, and at the same time introducing an increasing vacuum.
  • Fig la shows FAME (fatty acid methyl ester) profile compared to butter fat for Embl, where C4 is 2.15 wt.% and C6 is 1.31 wt.%.
  • Fig lb shows FAME (fatty acid methyl ester) profile of an extended fat product embodiment with 30 wt.% of Embl + 70wt.% of butter fat in black line compared to butter fat only in hashed line.
  • Fig lc shows FAME (fatty acid methyl ester) profile of a second extended fat product embodiment with 40 wt.%) of Embl + 60wt.%> of butter fat in black line compared to butter fat in hashed line.
  • Fig Id shows FAME (fatty acid methyl ester) profile of a third extended fat embodiment with 50 wt.% of Embl + 50wt.% of butter fat in black line compared to butter fat in hashed line.
  • Table 5 below shows SFC (solid fat content, IUPAC 2.150B) of Embodiment 1 (Embl), as well as the above mentioned extended products.
  • compositions may be used in different dairy applications to extend the butter fat as exemplified below: Milk
  • Example 2 Examples of dairy products extended with an edible fat composition
  • This example provides recipes for dairy products extended with Embl of Example 1.
  • Ingredients are mixed and used as liquid milk after pasteurization and homogenization.
  • a cheese is made according to standard procedures for cheese making including pasteurization, homogenization and coagulation/condensation. In brief, it includes
  • a fresh cheese was prepared with a fat composition of 30% Embl and 70% of milk fat and a total fat content of 25% according the above standard procedure and compared to a fresh cheese having the same total fat content but with a fat composition consisting of milk fat only.
  • a yoghurt is made according to standard procedures for yoghurt making including pasteurization, homogenization and fermentation.
  • a cream is made according to standard procedures for cream making including pasteurization and homogenization.
  • Example 3 Confectionary application A milk chocolate with a total fat content of about 32%.
  • composition of milk chocolate comprising Emb 1
  • milk chocolate was hand tempered on marble and used for 20 gram chocolate bars. Evaluation of the above milk chocolate when compared to the corresponding chocolate without Embl and having 5.2 % milk fat revealed no significant difference between the two chocolates. Accordingly, milk fat in chocolate may be replaced by the fat composition of the present invention without impairing the sensory properties of the chocolate.
  • the products comprising Emb 1 fat were compared to products containing only milk fat.
  • the products comprising Emb 1 fat compared generally well with the products containing only milk fat.

Landscapes

  • Chemical & Material Sciences (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Food Science & Technology (AREA)
  • Polymers & Plastics (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • General Chemical & Material Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Inorganic Chemistry (AREA)
  • Wood Science & Technology (AREA)
  • Organic Chemistry (AREA)
  • Biophysics (AREA)
  • Microbiology (AREA)
  • Edible Oils And Fats (AREA)
  • Dairy Products (AREA)

Abstract

The present invention relates to an edible fat composition comprising a blend of vegetable oils and animal fat with a combined fatty acid composition of about 3-15% of C14:0 and about 2-6% of C16:1 and a total of short chain triglycerides (SCT) C4:0 and C6:0 of ≤ 7%.Further, the invention relates to process of its preparation as well as uses thereof in dairy and confectionary products.

Description

EDIBLE FAT COMPOSITION
TECHNICAL FIELD The present invention relates to the field of butter fat equivalents. More particularly, the invention relates to a fat composition made of vegetable oils and animal fat suitable to extend milk fat products.
BACKGROUND
Milk fat is, apart from being the fat part of its natural source milk, also part of processed dairy products such as cheese, yoghurt, cream and butter blends.
The supply of milk fat, also called butter fat, is limited, particularly in some geographical areas due to the limited supply of fresh milk. Due to its complex nature, it is difficult to replace milk fat and fats designed to extend
milk/butterfat whilst maintaining a similar fatty acids profile to butterfat are not available.
The limited supply of fresh milk also causes the price of milk and its milk fat to be high. Thus, products with milk fat included, such as dairy products, will have an increased production cost as well thereby increasing the price for the end consumer. Thus, there is also a drive to reduce costs of dairy products including butter fat.
There have been some attempts to make milk/butter fat blends to replace milk fat by vegetable oils, however, mainly with focus on making the product healthier. Said vegetable oils have different chemical and physical profiles than milk fat. The fatty acids of milk/butter fat are composed of saturated and unsaturated fatty acids. The saturated fatty acids are mainly palmitic acid, myristic acid, stearic acid, lower (at most 12 carbon atoms) saturated fatty acids as well as traces of pentadecanoic acid and heptadecanoic acid. The unsaturated fatty acids are mainly oleic acid, palmitoleic acid, linoleic acid and linolenic acid.
WO2009/005351 describes a vegetable fat blend for replacing milk fat and processed food products containing such vegetable fat blend. With the aim to replace the milk fat with a healthier fat profile, WO2009/005351 provides a vegetable fat composition with fats having a different chemical profile and composition than milk fat.
US4,130,572 describes the fractionation of beef tallow into five different fractions. As pointed out in the abstract, each fraction has its own chemical profile by means of distinctive fatty acid and glyceride composition as well as its own physical profile by means of its own distinctive thermal characteristics. The applicants suggest use of the different fractions in the formulation of salad oils, margarine and liquid as well as plastic shortenings.
WO1989/008988 describes a dairy substitute formulation comprising 6-10 parts by weight of an oil in a carbohydrate or protein matrix, maltodextrin, emulsifiers as well as antioxidants to provide a fat-modified dairy milk.
Products produced comprising the dairy substitute include custards, cream substitutes, ice cream and ice confections, soft serve creams, coffee whiteners, yoghurt, cakes and pastries, biscuits and table spreads (butter replacer).
There is thus a need for a fat which may replace milk fat whilst maintaining a similar fatty acid profile chemically and physically as milk fat and that as well reduces the production costs of dairy products. The present invention addresses such needs and interests. SUMMARY
In one aspect, the present invention relates to an edible fat composition comprising a blend of vegetable oils and animal fat with a combined fatty acid composition of about 3-15% of C14:0 and about 2-6% of C16: l and a total of short chain triglycerides (SCT) C4:0 and C6:0 of < 7%. It has surprisingly been found that an edible fat composition resembling milk fat can be made from vegetable oils combined with animal fats. Hereby, an alternative to milk fat is obtained having many of the nutritional benefits as well as very similar chemical and physical profile of milk fat at reduced costs.
The amount of and ratio between SCT may be used to adjust for example the solid fat content (SFC) in such a way as to closely resemble the SFC, as well as fatty acid profile and a very similar chemical and physical profile as of milk fat. According to embodiments of the invention the short chain triglycerides (SCT) comprise about 1-4% C4:0 and about 0.1-3% C6:0.
The total amount of SCT and the relative amounts of C4:0 and C6:0 is for example important to adjust the SFC, as well as fatty acid profile to achieve a very similar chemical and physical profile of the edible fat product compared to a fat product based on butter fat.
Further embodiments are wherein said edible fat composition is a fat composition wherein the short chain triglycerides (SCT) C4:0 is about 1.8-4%) and C6:0 is about 0.5-3%. According to advantageous embodiments of the invention, the molar ratio between C4:0 and C6:0 SCT in the edible fat composition is between 0.5 and 5.
Still further embodiments are wherein said SCT comprises about 60-75%> C4:0 and about 25-35%> C6:0 short chain fatty acids. Still further embodiments are wherein said edible fat composition further comprises at least one of 0.5-3% of C8:0, 0.5-3% of C10:0, 2-5% of C12:0, 3- 15% of C14:0, 24-41% of C16:0, 2-6% of C16: l, 6-15% of C18:0, 18-35% of C18: l and 0.5-4% C18:2.
Still even further embodiments are wherein said animal fat is selected from tallow, lard and a mixture thereof. In further embodiments, said animal fat is tallow, such as beef tallow.
In further embodiments, the vegetable oils in said edible fat composition is at least one selected from the group consisting of palm oil, palm kernel oil, coconut oil, soybean oil, partially and fully hydrogenated soybean oil, high oleic sunflower oil, hydrogenated canola oil, hydrogenated palm kernel oil and fractions thereof. Examples of fractions are fractions of palm oil such as for example palm mid fractions (PMF) and other fractions mentioned herein.
In still further embodiments, said vegetable oil, animal fat and SCT are interesterified after blending. This has the benefit of providing a SFC with a suitable functionality for a specific application.
A further aspect of the present invention relates to a process for preparing an edible fat composition, said process comprises the steps of
a. esterification of short chain fatty acids C4:0 and C6:0 with glycerol to short chain triglycerides (SCT),
b. blending the vegetable oil(s) including said SCT of step a with animal fat, and
c. interesterification of the blend of step b. Further embodiments of the process are wherein the SCT comprises 60-75% of C4:0 and 25-35% of C6:0 short chain fatty acids.
Even further embodiments are wherein the process further comprises at least one of e) bleaching and f) deodorizing the interesterified blend of step 8c) above and optionally a step d) deodorization of the blend of step 8b.
Still even further embodiments of the process are wherein said animal fat is selected from any of tallow, such as beef tallow, lard and a mixture thereof.
Still even further embodiments of the process are wherein said vegetable oil is at least one selected from the group consisting of palm oil, palm kernel oil, coconut oil, , soybean oil, partially and fully hydrogenated soybean oil, high oleic sunflower oil, hydrogenated canola oil and fractions thereof. Examples of fractions thereof are palm mid fractions (PMF).
Still even further embodiments of the process are the process in any of its embodiments for preparing an edible fat composition according to any of its embodiments herein.
Further aspects are uses of the edible fat composition according to any of its embodiments or the edible fat composition prepared by the process according to any of its embodiments in a dairy product or a confectionary product, such as a chocolate or compound, e.g. a milk chocolate or compound with milk fat.
Further embodiments if the use is wherein the composition according to any of its embodiments or the edible fat composition prepared by the process according to any of its embodiments is replacing all or a part of the butter fat of a dairy product or a confectionary product with milk fat. Said use may in further embodiments be wherein said dairy product is a milk, margarine, butter blend, liquid, whipping and sour cream, hard cheese, processed cheese or fresh cheese, yoghurt or an ice cream product and the confectionary product with milk fat is a chocolate or a compound.
Further aspects are a dairy product or a milk fat containing confectionary products comprising the edible fat composition according to any of its embodiments or the edible fat composition prepared by the process according to any of its embodiments. Said dairy or confectionary product may in further embodiments be selected from the group consisting of a milk, a margarine, a butter blend, a liquid cream, a whipping cream, a sour cream, a hard cheese, a processed cheese, a fresh cheese, a yoghurt and an ice cream or a confectionary product, such as a chocolate or compound, e.g. a milk chocolate or compound with milk fat. SHORT DESCRIPTION OF DRAWINGS
Fig la-d shows a comparison of fatty acid composition between butter fat (hashed) and an edible fat composition of the invention (black).
Fig la shows one embodiment of the invention (Embodiment 1 or Embl) according to Example 1 with FAME (fatty acid methyl ester) profile compared to butter fat. Embodiment 1 is in black line as compared to butter fat in hashed line. Table 1 shows the same information in numbers.
Fig lb shows an extended fat embodiment with 30 wt.% of Embodiment 1 + 70wt.% of butter fat in black line compared to butter fat in hashed line. Table 2 shows the same information in numbers. Fig lc shows a second extended fat embodiment with 40 wt.% of Embodiment 1 + 60wt.% of butter fat in black line compared to butter fat in hashed line. Table 3 shows the same information in numbers. Fig Id shows a third extended fat embodiment with 50 wt.% of Embodiment 1 + 50wt.% of butter fat in black line compared to butter fat in hashed line.
Fig 2 shows an example of the production process. The esterification is between butyric fatty acid and caproic fatty acid and glycerin to produce a SCT-fat. The SCT-fat is then imported together with the vegetable oils and edible tallow and blended. Optionally (*) the blend is deodorized. The blend is then interesterified, followed by bleaching and deodorization. The last step, packaging, is of course dependent on the further application process for each and every dairy or milk containing confectionary product. DETAILED DESCRIPTION
Definitions
As used herein the term "milk fat" and "butter fat" is used with the same meaning and interchangeably. Milk/butter fat represents the fatty portion of milk. As used herein, the term "fatty acid" encompasses fatty acid residues in triglycerides.
As used herein "SCT" is intended to mean short-chain triglycerides. Short chain triglycerides contain short-chain fatty acids (SCFA) with aliphatic tails of fewer than six carbons. As used herein "edible" is something that is suitable for use as food or as part of a food product, such as a dairy or confectionary product. An edible fat is thus suitable for use as fat in food or food product and an edible composition is a composition suitable for use in food or a food product, such as a dairy or confectionary product. As used herein, "%" or "percentage" all relates to weight percentage i.e. wt.% or wt.-% if nothing else is indicated. As used herein, the singular forms "a", "and" and "the" include plural referents unless the context clearly dictates otherwise.
As used herein, "at least one" is intended to mean one or more, i.e. 1, 2, 3, 4, 5, 6, 7, 8, 9, 10, etc. As used herein, "vegetable oil" and "vegetable fat" is used interchangeably, unless otherwise specified.
As revealed above, it is provided a fat composition designed to be a milk/butter fat equivalent whilst maintaining a similar fatty acid profile as compared to butter fat. Said composition is a butter fat equivalent, made by a blend of animal fat and vegetable oils and it has surprisingly been found that such a blend has similar fatty acid profile and a very similar chemical and physical profile as milk fat, which means that apart from its similar fatty acid profile, also melting point, cholesterol levels, phytosterol levels etc. is similar as for butter fat. Said fat composition is an edible fat composition and is used to replace all or parts of butter fat in dairy or confectionary products. Thus, by replacing all or parts of the butter fat, it is extending the original butter fat to different degrees in a dairy product or confectionary product comprising milk fat, such as a compound or chocolate, thereby keeping all benefits with butter fat relating to fatty acid profile as well as a very similar chemical and physical profile as butter fat. Further, the fat composition according to the invention will also thereby reduce the production costs of the dairy or confectionary product by extending traditional butter fat still while maintaining the physiochemical profile compared to milk fat. Thus, the use of the edible fat composition as described herein by extending all or parts of the butter fat in dairy or confectionary products will also help the dairy and the confectionary industry to overcome the shortage of butterfat, particularly relating to seasonal variations. It should also be noted that milk fat compositions vary over the year. Regional variations in fatty acid composition may also occur. For example, the content in milk fat of butyric acid may vary between about 0.3% and 2.3%, caproic acid may vary between about 0.8% and 1.7% , the content of laurylic acid between about 2.0% and 4.3% and the content of myristic acid between about 7.3%) and 12.4% by weight. Palmitoleic acid content in milk fat may vary between 0.3% and 3.5% by weight.
In milk, the content of saturated fats may be between about 57% and 71%, the content of mono-unsaturated fats may vary between about 23% and 38%, while the content of poly-unsaturated may vary between about 0.5% and 7.4% by weight.
Accordingly, the edible fat compositions according to embodiments of the present invention may also vary within certain limits without impairing the quality of the dairy products or confectionary products to which the edible fat compositions are added.
In some embodiments of the invention, it may be possible, at least partly, to compensate for the natural variations in milk. In this way, more uniform dairy products and/or confectionary products may be obtained over the year by replacing a part of or all of the milk fat in the product with the edible fat compositions according to these embodiments.
Thus, in one aspect, the present invention relates to an edible fat composition comprising a blend of vegetable oils and animal fat with a fatty acid composition of about 3-15% of C 14:0 and about 2-6% of C16: l and a total of short chain triglycerides (SCT) C4:0 and C6:0 of < 7%. SCT are triglycerides comprising fatty acids with aliphatic tails of fewer than six carbons esterified with glycerol. In the edible fat composition, the SCT comprises 60-75%) of C4:0 (butyric) and 25-35%> of C6:0 (caproic) short chain fatty acids esterified with glycerol. Still further embodiments are wherein said edible fat composition further comprises at least one of 0.5-3% of C8:0, 0.5-3% of C10:0, 2-5% of C12:0, 3-15% of C14:0, 24-41% of C16:0, 2-6% of C16: l, 6- 15% of C18:0, 18-35% of C18: l and 0.5-4% C18:2. Further embodiments are wherein said edible fat composition comprises 0.5- 3% of C8:0, 0.5-3% of C10:0, 2-5% of C12:0, 3-15% of C14:0, 24-41% of C16:0, 2-6% of C16: l, 6-15% of C18:0, 18-35% of C18: l and 0.5-4% C18:2. The source of the vegetable fats for providing fatty acids may vary, as long as the vegetable fat provides suitable amounts of each fatty acid as specified herein. Examples of suitable sources for fatty acids of the vegetable oils in said edible fat composition is at least one selected from the group consisting of palm oil, palm kernel oil, coconut oil, soybean oil, partially or fully
hydrogenated soybean oil, high oleic sunflower oil, hydrogenated canola oil, hydrogenated palm kernel oil and where applicable also fractions thereof. Fractions thereof are for example fractions of palm oil with IV (iodine value) of 20-50, palm kernel oil fractions with IV of 6-30, such as 12-26, coconut oil fractions of IV of 5-15, such as 6-12.
In particular embodiments, said edible fat composition comprises palm oil, palm kernel oil, animal fat, for example edible tallow, and SCT. For example one embodiment is wherein palm oil is about 13-19wt.%, such as 13, 14, 15, 16, 17, 18, or even 19wt.% of palm oil or its fractions, about 7-13wt.%, such as 7, 8, 9, 10, 11, 12 or even 13wt.% of palm kernel oil or its fractions, about 64- 70wt.% of edible tallow such as e.g. beef tallow, and about 7-8wt.% of SCT- fat, such as 7 or 8wt.%. Said SCT-fat is made of short chain fatty acids C4:0 and C6:0 esterified with glycerol to a short chain triglyceride fat (SCT-fat), and wherein the SCT comprises 60-75% of C4:0 and 25-35% of C6:0 short chain fatty acids in wt.% and carbomdouble bound. In a further embodiment, all the fats are interesterified after blending. For example, the edible fat composition may in particular embodiments comprise about 67% edible tallow and about 7% SCT in wt.%. Said edible fat composition may then further comprise about 16% palm oil or its fractions thereof, and about 10% palm kernel oil (PCO) or its fractions thereof in wt.%, and all fats are interesterified after blending.
Short chain triglycerides (SCT) C4:0 and C6:0 may be made by esterification of any natural source of said fatty acid with glycerol. C4:0 and C6:0 may be from any commercially available source of natural butyric and/or caproic acid (Acidchem International Sdn. Bhd., Axxence, DE, or Elan Chemical Company, Inc. NJ, US) or industrially prepared e.g. butyric acid by fermentation of sugar and starch.
The edible fat composition further comprises animal fat. Any animal fat may be used as long as it is edible. Further, said animal fat may be hydrogenated of not. Thus, further embodiments are wherein said animal fat is selected from tallow, lard and a mixture thereof. Tallow and lard may be from any animal, as long as it is edible. In further embodiments, said animal fat is tallow, such as beef tallow.
In further embodiments, the edible fat composition comprises different types of additives. Examples of such additives are antioxidants, e.g. butylated hydroxytoluene (BTH, also known as butylhydroxytoluene), flavours, e.g. butter oil, etc. depending on the specific application. The antioxidants may also be natural antioxidants, such as ascorbyl palmitate and tocopherols. It is, however, important to point out that the fat part only of the edible fat composition described herein even without any added flavors provides a surprisingly good flavor by itself in the final dairy and confectionary product. Figure 1 shows a comparison of fatty acids between butter fat (black) and an embodiment of an edible fat composition of the invention (dashed).
In a further aspect, a process for preparing said edible fat composition and all its embodiments is described. Said process comprises the steps of a) esterification of short chain fatty acids C4:0 and C6:0 with glycerol to short chain triglycerides (SCT), wherein the SCT comprises 60-75% by weight of C4:0 and 25-35%> by weight of C6:0 short chain fatty acids with 4 and 6 carbon atoms respectively and 0 carbon-carbon double bonds, b) blending vegetable oil(s) including said esterified SCT in a) and animal fat, and, and c) interesterification of the blend.
Further embodiments of the process are wherein the SCT comprises 60-75%) of C4:0 and 25-35%> of C6:0 short chain fatty acids in with 4 and 6 carbon atoms respectively and 0 carbon-carbon double bonds.
Even further embodiments are wherein the process further comprises at least one of e) bleaching and f) deodorizing the interesterified blend of step 8c) above and optionally a step d) deodorization of the blend of step 8b.
Each of the ingredients forming the blend of step b) above may be each one previously refined, bleached and deodorized. Further, particularly if the acid value is high, the blend must be deodorized to avoid MeONa, i.e. sodium methoxide or CH3ONa, contamination in the interesterification process.
The interesterification process in step c) may be a chemical interesterification or an enzymatic interesterification. Both chemical interesterification and enzymatic interesterification is described well in the art. Both chemical and enzymatic interesterification may be done at standard procedures. One example of the process is shown in figure 2.
Still even further embodiments of the process are wherein said animal fat is selected from any of tallow, such as beef tallow, lard and a mixture thereof.
Still even further embodiments of the process are wherein said vegetable oil is at least one selected from the group consisting of palm oil, palm kernel oil, coconut oil, soybean oil, partially or fully hydrogenated soybean oil, high oleic sunflower oil, hydrogenated canola oil and fractions thereof. Fractions thereof may be any fraction of the vegetable oil, particularly fractions mentioned herein.
Still even further embodiments of the process are the process in any of its embodiments for preparing an edible fat composition according to any of its embodiments herein.
Further aspects provided herein are uses of the edible fat composition and all its embodiments or the composition prepared by the process and all its embodiments in a dairy product or a confectionary product. Further embodiments if the use is wherein the composition according to any of its embodiments or the edible fat composition prepared by the process according to any of its embodiments is replacing all or a part of the butter fat of a dairy or confectionary product. Said use may in further embodiments be wherein said dairy product is a milk, margarine, butter blend, liquid, whipping and sour cream, hard cheese, processed cheese or fresh cheese, yoghurt or an ice cream product or a confectionary product, such as a chocolate or compound, e.g. a milk chocolate or compound with milk fat. Further aspects are a dairy product or confectionary product comprising the edible fat composition according to any of its embodiments or the edible fat composition prepared by the process according to any of its embodiments. Said dairy or confectionary product may in further embodiments be selected from the group consisting of a milk, a margarine, a butter blend, a liquid cream, a whipping cream, a sour cream, a hard cheese, a processed cheese, a fresh cheese, a yoghurt and an ice cream or a confectionary product, such as a chocolate or compound, e.g. a milk chocolate or compound with milk fat.
The skilled man would know how to choose the vegetable oils and fractions thereof to achieve a suitable solid fact content (SFC) for each dairy product or confectionary product application. Further examples are also given herein. Methods to measure solid fat content are well known in the art and is usually measured by pulse MR (Rutledge et al., 1988, Rev. Franc. Corps Gras, 35, 157-162) such as using l UPAC 2.150 B.
For example, the source of lauric C 12:0 in the edible fat composition, may, apart from PKO also be coconut oil or any other source with high lauric content, if such source is more suitable in SFC for a particular application. In certain applications hydrogenation of the vegetable fat part, such as e.g. PKO (palm kernel oil), soybean oil and canola oil, is suitable to get a desired SFC. For example, palm kernel oil has an iodine value of 14 to 21 and may be hydrogenated to give products with IV down to 2. Alternatively, the palm oil can be fractionated into an olein (IV 21-26) and a stearin (IV 6-8) and each of these fractions may then further be hydrogenated. The fractionated parts of palm oil differ particularly in their levels of palmitic acid and oleic acid.
Accordingly, further embodiments are wherein the vegetable fat is
hydrogenated. Said vegetable fat may also be interesterified, such as for example
interesterified with the SCT and/or the animal fat. Thus, further embodiments are wherein said vegetable fat is interesterified, such as for example
interesterified with the SCT and/or the animal fat. IN still a further
embodiment, said vegetable fat is interesterified with the SCT and the animal fat.
In further embodiments, said edible composition and all its embodiments or the composition prepared by the process and all its embodiments is replacing all or a part of the butter fat of a dairy or confectionary product, while still maintaining a similar fatty acid profile to milk/butter fat. By all or parts thereof, it is intended to mean from about 5 wt.% to about 90 or even 100% of the butter fat of a dairy or confectionary product, such as 5, 10, 15, 20, 25, 30, 35, 40, 45, 50, 55, 60, 65, 70, 75, 80, 85, 90, 95, 99 or even 100 wt.% of the butter fat of the dairy product. Further embodiments are wherein 0.1 to 100% of the butter fat is exchanged to the fat composition of the invention. Even further embodiments are whereon 0.1 to 50% is exchanged to the fat composition of the invention. Still even further embodiments are wherein up to and including about 30%, such as wherein 0.1 to 30% is exchanged to the fat composition of the invention.
The dairy or confectionary product may be any dairy product such as a milk, a margarine, a butter blend, a liquid, a whipping and a sour cream, a hard cheese, a processed cheese or fresh cheese, a yoghurt or an ice cream product or a confectionary product, such as a chocolate or compound, e.g. a milk chocolate or compound with milk fat.
Thus, further aspects of the present invention is a dairy product or a
confectionary product comprising the edible fat composition or any of its embodiments or the edible fat composition or any of its embodiments prepared by the process or any of its embodiments described herein. One embodiment is a milk comprising the edible fat composition or any of its embodiments or the edible fat composition or any of its embodiments prepared by the process or any of its embodiments described herein.
A further embodiment is a margarine comprising the edible fat composition or any of its embodiments or the edible fat composition or any of its embodiments prepared by the process or any of its embodiments described herein.
Still a further embodiment is a butter blend comprising the edible fat composition or any of its embodiments or the edible fat composition or any of its embodiments prepared by the process or any of its embodiments described herein.
Still a further embodiment is a cream, such as a liquid cream, a sour cream or a whipping cream, comprising the edible fat composition or any of its embodiments or the edible fat composition or any of its embodiments prepared by the process or any of its embodiments described herein.
Still a further embodiment is a hard cheese comprising the edible fat composition or any of its embodiments or the edible fat composition or any of its embodiments prepared by the process or any of its embodiments described herein.
Still a further embodiment is a processed or fresh cheese comprising the edible fat composition or any of its embodiments or the edible fat composition or any of its embodiments prepared by the process or any of its embodiments described herein.
Still a further embodiment is a yoghurt comprising the edible fat composition or any of its embodiments or the edible fat composition or any of its embodiments prepared by the process or any of its embodiments described herein.
An ice cream product comprising the edible fat composition or any of its embodiments or the edible fat composition or any of its embodiments prepared by the process or any of its embodiments described herein.
Non-limiting examples which embody certain aspects of the invention will now be described. EXAMPLES
Example 1: Production of an edible fat composition for extending butter fat.
This Example describes the production of edible fat compositions according to embodiments of the invention for extending butter fat.
The compositions are butter fat equivalent made of a blend of vegetable and animal fat according to the invention. In this example, the SCT-FAT varies in its C4 and C6 content according to a general formula. One example of a general formula is given below:
General formula:
16wt.% Palm Oil
10wt.% Palm Kernel Oil
67wt.% Beef Tallow
7 wt.% SCT-FAT (C4:0 60-75wt.% C6:0 25-35wt. %)
Antioxidant: 150 ppm BHT
In different embodiments, as given below, the wt.% of SCT-FAT is changed, i.e. increased or decreased. In all such cases, the wt.% of Palm oil and/or Palm Kernel Oil is decreased or increased accordingly to compensate to have a total of 100 wt.%.
For example, one particular edible fat composition is Embl which has C6:0 of 1.31 wt.% and C4:0 of 2.15 wt.%, i.e. having a total of 3.46 wt.% instead of the 7% in the general formula. The 3.54 wt.% left up to 7% is compensated by Palm Oil as well as Palm Kernel Oil in about equal amounts or similar depending on the application of the edible fat composition, determined case by case.
Process:
1. Esterification process of short chain fatty acids (each with defined C4 and C6 %) and glycerol to obtain SCT-FAT (Short Chain Triglyceride FAT).
Esterification process is made by blending the C4:0, C6:0 and glycerol in a reactor, then start at 80°C and atmospheric pressure, increasing 10°C each 4 - 5 hours, and at the same time introducing an increasing vacuum.
2. Blending all the ingredients, each one previously refined, bleached and deodorized (standard procedure).
3. Dry chemical interesterification for 30 minutes under vacuum at 120°C with 0.3%) MeONa added after the 30 minutes of drying. The reaction is then allowed to proceed for 30 minutes at 80°C. After 30 minutes 0.7% citric acid is added and the reaction allowed to proceed for additional 30 minutes. Trisyl (0.15%) is then added to the reaction and allowed to proceed under the same conditions (80°C) for additional 30 minutes.. 4. Bleaching using 0.8% bleaching earth for 40 minutes at 90°C. After that, the product is filtered.
5. Deodorization at 220 - 235 °C for 1.5h or till the FFA is 0.1%.
6. Packing in boxes a'25 kg.
A summary of the process is found in Figure 2. RESULTS:
The result is compositions with similar physical and chemical properties as of butter fat. Results shown in figure la-d and in Table 1-4 below are comparisons of fatty acid composition between butter fat (hashed) and an Embodiment 1 (Embl) (black) as an example of an edible fat composition of the invention. Fig la shows FAME (fatty acid methyl ester) profile compared to butter fat for Embl, where C4 is 2.15 wt.% and C6 is 1.31 wt.%. Fig lb shows FAME (fatty acid methyl ester) profile of an extended fat product embodiment with 30 wt.% of Embl + 70wt.% of butter fat in black line compared to butter fat only in hashed line. Fig lc shows FAME (fatty acid methyl ester) profile of a second extended fat product embodiment with 40 wt.%) of Embl + 60wt.%> of butter fat in black line compared to butter fat in hashed line. Fig Id shows FAME (fatty acid methyl ester) profile of a third extended fat embodiment with 50 wt.% of Embl + 50wt.% of butter fat in black line compared to butter fat in hashed line.
TABLE 1 - Emb 1 compared to Butter fat
Embl vs Butter Fat
Fatty Acids Embl Butter Fat C4:0 2,15 2,32
C6:0 1,31 1,61
C8:0 0,45 1,03
C10:0 0,43 2,27
C11:0 0 0,16
C12:0 5,34 3,04
C14:0 3,88 8,99 cu-.i 0,34 0,55
C15:0 0,35 0,90
C16:0 26,47 26,60
C16:l 1,93 2,34
C17:0 0,97 0,73
C17:l 0,54 0,52
C18:0 13,69 12,49
C18:l t 4,46 3,56
C18:l c 32,74 26,56
C18:2t 0,40 1,21
C18:2 c 3,91 1,79
C20:0 0,20 0
C18:3 N3 0,17 1,06
C20:l 0,17 0,99 TABLE 2 - Embl 30%/Butter fat 70% vs Butter fat
Embl vs Butter Fat
BLEND: Embl
Fatty Acids 30% /Butter Fat Butter Fat
70%
C4:0 2,15 2,32
C6:0 1,49 1,61
C8:0 0,84 1,03
C10:0 1,73 2,27
C11:0 0,11 0,16
C12:0 3,72 3,04
C14:0 7,59 8,99 cu-.i 0,52 0,55
C15:0 0,75 0,90
C16:0 26,97 26,60
C16:l 2,25 2,34
C17:0 0,84 0,73
C17:l 0,45 0,52
C18:0 13,09 12,49
C18:l t 3,88 3,56
C18:l c 28,66 26,56
C18:2t 1,02 1,21
C18:2 c 2,14 1,79
C20:0 0,13 0 C18:3 N3 0,72 1,06
C20:l 0,84 0,99
TABLE 3 - Embl 40%/Butter fat 60% vs Butter fat
Embl vs Butter Fat
BLEND: Embl
Fatty Acids 40% / Butter Fat Butter Fat
60%
C4:0 2,09 2,32
C6:0 1,46 1,61
C8:0 0,78 1,03
C10:0 1,53 2,27
C11:0 0,10 0,16
C12:0 4,04 3,04
C14:0 7,00 8,99 cu-.i 0,53 0,55
C15:0 0,69 0,90
C16:0 26,59 26,60
C16:l 2,14 2,34
C17:0 0,84 0,73
C17:l 0,47 0,52
C18:0 13,20 12,49
C18:l t 4,30 3,56 C18: l c 29,06 26,56
C18:2 t 0,96 1,21
C18:2 c 2,47 1,79
C20:0 0, 17 0
C18:3 N3 0,64 1,06
C20: l 0,85 0,99
TABLE 4 - Embl 50%/Butter fat 50% vs Butter fat
Embl vs Butter Fat
BLEND: Embl
Fatty Acids 50% / Butter Fat Butter Fat
50%
C4:0 2,00 2,32
C6:0 1,41 1,61
C8:0 0,70 1,03
C10:0 1,31 2,27
C11 :0 0,08 0, 16
C12:0 4,22 3,04
C14:0 6,30 8,99 cu-. i 0,49 0,55
C15:0 0,61 0,90
C16:0 24,22 26,60
C16: l 2,04 2,34 C17:0 0,85 0,73
C17: l 0,48 0,52
C18:0 13,26 12,49
C18: l t 4, 17 3,56
C18: l c 30, 14 26,56
C18:2 t 0,67832 1,21501
C18:2 c 2,65 1,79
C20:0 0, 18 0
C18:3 N3 0,52 1,06
C20: l 0,59 0,99
Table 5 below shows SFC (solid fat content, IUPAC 2.150B) of Embodiment 1 (Embl), as well as the above mentioned extended products.
TABLE 5 - Embl alone and replacing butter fat in 30, 40, 50 and 100% compared to pure butter fat
0% Embl 30% 40% 50% 100%
100% Embl Embl Embl Embl butter fat 70% 60% 50% 0% butter butter fat butter fat butter fat fat
SFC
10 °C 42,8 40,9 41 41,2 43,4
20 °C 14, 1 15,2 16,4 16,7 20,2
30 °C 3,25 4,4 4,9 5,2 7,7
40 °C 0 0,5 1 1,5 3,7
50 °C 0 0 0 0 0 It is noted that the Solid Fat Content of Embl is remarkably close to that of pure butter fat clearly indicating the interchangeability of Embl with butter fat at different concentrations or even the possibility of a total replacement of butter fat with Emb 1.
Said compositions may be used in different dairy applications to extend the butter fat as exemplified below: Milk
Margarine, butter blends
Liquid, whipping and sour cream
Hard, processed and fresh cheese
Yoghurt
Ice cream
Example 2: Examples of dairy products extended with an edible fat composition
This example provides recipes for dairy products extended with Embl of Example 1.
The process conditions for selected processes used for making all products in this example are the same:
- Pasteurization at 75 °C for 15 seconds,
Homogenization at 65 °C at 1600 psi
- Coagulation temperature for cheese is 35-40° C
- Fermentation temperature in yoghurt is 40 °C Table 1 - Liquid milk
Figure imgf000028_0001
Ingredients are mixed and used as liquid milk after pasteurization and homogenization.
Cheese
Figure imgf000028_0002
A cheese is made according to standard procedures for cheese making including pasteurization, homogenization and coagulation/condensation. In brief, it includes
• Milk decreaming
• Blend of milk and butter fat replacer
• Homogenization
• Pasteurization • Coagulation
• Pressing
A fresh cheese was prepared with a fat composition of 30% Embl and 70% of milk fat and a total fat content of 25% according the above standard procedure and compared to a fresh cheese having the same total fat content but with a fat composition consisting of milk fat only.
The result of the comparison is given under the evaluation of products here below.
Yoghurt
Figure imgf000029_0001
A yoghurt is made according to standard procedures for yoghurt making including pasteurization, homogenization and fermentation.
In brief it includes:
• Milk decreaming
• Blend of milk and butter fat replacer
• Homogenization
• Pasteurization
• Fermentation
• Maduration Cream
Ingredient %
Milk cream (30% butter fat) 50
Skim powder milk 5
Water 14.95
Embl 30
Emulsifier 0.05
Citric acid 0.3
A cream is made according to standard procedures for cream making including pasteurization and homogenization.
• Milk decreaming
• Blend of milk cream and butter fat replacer (adding skimmed milk powder)
• Homogenization
• Pasteurization
Example 3: Confectionary application A milk chocolate with a total fat content of about 32%.
Composition of milk chocolate comprising Emb 1
Cocoa butter 20.7%
Cocoa mass 10.7%
Sugar 45.9%
Skim milk powder 17.0%
Milk fat 3.6%
Emb 1 1.6% Lecithin 0.5%
The milk chocolate was hand tempered on marble and used for 20 gram chocolate bars. Evaluation of the above milk chocolate when compared to the corresponding chocolate without Embl and having 5.2 % milk fat revealed no significant difference between the two chocolates. Accordingly, milk fat in chocolate may be replaced by the fat composition of the present invention without impairing the sensory properties of the chocolate.
Example 4: Evaluation of products
The products comprising Emb 1 fat were compared to products containing only milk fat.
This was done by letting a panel of 36 persons evaluate the products with respect to flavor, consistence and creaminess (where appropriate) using hedonic 9-point trials.
The products were also tested with respect to preference.
The products comprising Emb 1 fat compared generally well with the products containing only milk fat.
In some cases there was no significant difference between the compared products, in other cases the products comprising Embl where preferred slightly.
Typical results are shown below for fresh cheese.
Comparison of fresh cheese (see Example 2 above) with 30% of the fat phase being Embl and fresh cheese with only milk fat. Evaluation of Consistency of fresh cheese, panel of 36 persons
Figure imgf000032_0001
58%) of the panel preferred the fresh cheese comprising Embl, while 42% favored the fresh cheese comprising only milk fat. Conclusion
All product examples given above in examples 2 and 3 had an excellent taste as well as a similar chemical and physical profile as products made from milk fat only.
Accordingly, it is possible to partly or fully replace milk fat in dairy- and confectionary products with the fat compositions described herein and retain and sometimes improve customer appeal and preference of the dairy- and confectionary products.

Claims

1. An edible fat composition comprising a blend of vegetable oils and animal fat, said edible fat composition comprising a fatty acid composition of about 3-15% of C14:0 and about 2-6% of C16: l and a total of short chain triglycerides (SCT) C4:0 and C6:0 of < 7%.
2. The edible fat composition according to claim 1, wherein the short chain triglycerides (SCT) comprise about 1-4% C4:0 and about 0.1-3% C6:0.
3. The edible fat composition according to claim 1, wherein the short chain triglycerides (SCT) C4:0 is about 1.8-4% and C6:0 is about 0.5- 3%.
4. The edible fat composition according to any of claims 1-3, wherein said SCT comprises about 60-75% C4:0 and about 25-35% C6:0 short chain fatty acids.
The edible fat composition according to any of claims 1-4, further comprising at least one of 0.5-3% of C8:0, 0.5-3% of C10:0, 2-5% of C12:0, 3-15% of C14:0, 24-41% of C16:0, 2-6% of C16: l, 6-15% of C18:0, 18-35% of C18: l and 0.
5-4% C18:2.
6. The edible fat composition according to any of claims 1-5, wherein said animal fat is selected from tallow, lard and a mixture thereof.
7. The edible fat composition according to any of claims 1-6, wherein said animal fat is tallow, such as beef tallow.
8. The edible fat composition according to claim 1, wherein said vegetable oil is at least one selected from the group consisting of palm oil, palm kernel oil, hydrogenated palm kernel oil, coconut oil, soybean oil, fully or partially hydrogenated soybean oil, high oleic sunflower oil, hydrogenated canola oil and fractions thereof.
The edible fat composition according to any of claims 1-8, wherein said vegetable oil, SCT and animal fat are interesterified.
A process for preparing an edible fat composition, said process comprising the steps of
a. esterification of short chain fatty acids C4:0 and C6:0 with
glycerol to short chain triglycerides (SCT),
b. blending the vegetable oil including said SCT of step a with animal fat, and
c. interesterification of the blend of step 8b.
11. The process according to claim 10, wherein the SCT comprises 60-75% of C4:0 and 25-35% of C6:0 short chain fatty acids.
12. The process according to any of claims 10-11, further comprising at least one of e) bleaching and f) deodorizing the interesterified blend of step 8c) above and optionally a step d) deodorization of the blend of step 8b.
13. The process according to any of claims 10-12, wherein said animal fat is selected from tallow, such as beef tallow, lard and a mixture thereof.
14. The process according to any of claims 10-13, wherein said vegetable oil is at least one selected from the group consisting of palm oil, palm kernel oil, cocoa nut oil, soya bean oil, hydrogenated canola oil and fractions thereof.
15. The process according to any of claims 10-14 for preparing an edible fat composition according to any of claims 1-9.
16. Use of the edible fat composition according to any of claims 1-9 or the edible fat composition prepared by the process according to any of claims 10-15 in a dairy product or confectionary product.
17. The use according to claim 16, wherein the composition according to any of claims 1-9 or the edible fat composition prepared by the process according to any of claims 10-15 is replacing all or a part of the butter fat of a dairy or confectionary product.
18. The use according to claim 17, wherein said dairy product is a milk, margarine, butter blend, liquid, whipping and sour cream, hard cheese, processed cheese or fresh cheese, yoghurt or an ice cream product and said confectionary product is a chocolate or compound.
19. A dairy product or a confectoinary product comprising the edible fat composition according to any of claims 1-10 or the edible fat composition prepared by the process according to any of claims 10-15.
20. The dairy product or confectionary product according to claim 18, selected from the group consisting of a milk, a margarine, a butter blend, a liquid cream, a whipping cream, a sour cream, a hard cheese, a processed cheese, a fresh cheese, a yoghurt and an ice cream or a confectionary product such as a chocolate or compound.
PCT/SE2014/051097 2013-09-26 2014-09-24 Edible fat composition WO2015047170A1 (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
MX2016003619A MX2016003619A (en) 2013-09-26 2014-09-24 Edible fat composition.

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
SE1351116 2013-09-26
SE1351116-7 2013-09-26

Publications (1)

Publication Number Publication Date
WO2015047170A1 true WO2015047170A1 (en) 2015-04-02

Family

ID=52744103

Family Applications (1)

Application Number Title Priority Date Filing Date
PCT/SE2014/051097 WO2015047170A1 (en) 2013-09-26 2014-09-24 Edible fat composition

Country Status (2)

Country Link
MX (1) MX2016003619A (en)
WO (1) WO2015047170A1 (en)

Cited By (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP6172423B1 (en) * 2016-02-22 2017-08-02 不二製油株式会社 Transesterified oil and plastic fat composition using the same as hard stock
CN108208202A (en) * 2016-12-15 2018-06-29 嘉里特种油脂(上海)有限公司 A kind of low saturation fat or oil composition and preparation method thereof
CN108236016A (en) * 2016-12-26 2018-07-03 丰益(上海)生物技术研发中心有限公司 A kind of fat or oil composition and preparation method thereof, purposes
CN111838327A (en) * 2020-07-23 2020-10-30 海普诺凯营养品有限公司 Grease for milk powder base powder and preparation method thereof
EP4065675A4 (en) * 2019-11-29 2023-06-21 Aak Ab Non-hydrogenated fat composition

Citations (9)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CA573130A (en) * 1959-03-31 Swift And Company Synthetic butterfat and substitutes for butterfat
BE776847A (en) * 1971-12-17 1972-04-17 Palmafina N V Sa COMPOSITIONS OF FAT FOR BREASTFEEDING FEEDS
GB1383148A (en) * 1972-04-17 1975-02-05 Fuji Oil Co Ltd Soy cheese
GB1383149A (en) * 1972-04-20 1975-02-05 Fuji Oil Co Ltd Soy cheese and process for making same
US3873729A (en) * 1970-11-17 1975-03-25 Fuji Oil Co Ltd Preparation of a cheese-like fermented food
US4049839A (en) * 1973-03-05 1977-09-20 The United States Of America As Represented By The Secretary Of Agriculture Physiochemically designed fat compositions from tallow
EP0037017A2 (en) * 1980-03-27 1981-10-07 Henkel Kommanditgesellschaft auf Aktien Fat with milkfat-like properties and process for its preparation
EP0192284A1 (en) * 1985-01-24 1986-08-27 Unilever N.V. Fat blends containing milk fat or a milk fat fraction and a non-milk fat, and spreads containing said fat blends
JPS61209544A (en) * 1985-03-14 1986-09-17 Ueda Seiyu Kk Oil and fat resembling fat of human milk

Patent Citations (9)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CA573130A (en) * 1959-03-31 Swift And Company Synthetic butterfat and substitutes for butterfat
US3873729A (en) * 1970-11-17 1975-03-25 Fuji Oil Co Ltd Preparation of a cheese-like fermented food
BE776847A (en) * 1971-12-17 1972-04-17 Palmafina N V Sa COMPOSITIONS OF FAT FOR BREASTFEEDING FEEDS
GB1383148A (en) * 1972-04-17 1975-02-05 Fuji Oil Co Ltd Soy cheese
GB1383149A (en) * 1972-04-20 1975-02-05 Fuji Oil Co Ltd Soy cheese and process for making same
US4049839A (en) * 1973-03-05 1977-09-20 The United States Of America As Represented By The Secretary Of Agriculture Physiochemically designed fat compositions from tallow
EP0037017A2 (en) * 1980-03-27 1981-10-07 Henkel Kommanditgesellschaft auf Aktien Fat with milkfat-like properties and process for its preparation
EP0192284A1 (en) * 1985-01-24 1986-08-27 Unilever N.V. Fat blends containing milk fat or a milk fat fraction and a non-milk fat, and spreads containing said fat blends
JPS61209544A (en) * 1985-03-14 1986-09-17 Ueda Seiyu Kk Oil and fat resembling fat of human milk

Cited By (11)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP6172423B1 (en) * 2016-02-22 2017-08-02 不二製油株式会社 Transesterified oil and plastic fat composition using the same as hard stock
WO2017145927A1 (en) * 2016-02-22 2017-08-31 不二製油グループ本社株式会社 Transesterified oil and plastic oil/fat composition using same as hardstock
CN108699489A (en) * 2016-02-22 2018-10-23 不二制油集团控股株式会社 Ester-exchanged oil and the plastic fat composition for being set to hard stock
US11178885B2 (en) 2016-02-22 2021-11-23 Fuji Oil Holdings Inc. Transesterified oil and plastic oil/fat composition using same as hardstock
CN108699489B (en) * 2016-02-22 2022-03-01 不二制油集团控股株式会社 Transesterified oil and plastic fat composition made of the transesterified oil as hardstock
CN108208202A (en) * 2016-12-15 2018-06-29 嘉里特种油脂(上海)有限公司 A kind of low saturation fat or oil composition and preparation method thereof
CN108236016A (en) * 2016-12-26 2018-07-03 丰益(上海)生物技术研发中心有限公司 A kind of fat or oil composition and preparation method thereof, purposes
CN108236016B (en) * 2016-12-26 2021-09-24 丰益(上海)生物技术研发中心有限公司 Grease composition and preparation method and application thereof
EP4065675A4 (en) * 2019-11-29 2023-06-21 Aak Ab Non-hydrogenated fat composition
CN111838327A (en) * 2020-07-23 2020-10-30 海普诺凯营养品有限公司 Grease for milk powder base powder and preparation method thereof
CN111838327B (en) * 2020-07-23 2022-09-06 海普诺凯营养品有限公司 Grease for milk powder base powder and preparation method thereof

Also Published As

Publication number Publication date
MX2016003619A (en) 2016-10-26

Similar Documents

Publication Publication Date Title
JP5634264B2 (en) Oil and fat composition and plastic oil and fat composition
KR101525272B1 (en) Fat composition for chocolate coatings
US9743681B2 (en) Oil and fat composition that can be used as non-tempering type hard butter
JP6366495B2 (en) Oil and fat composition and oily food using the oil and fat composition
JP4653772B2 (en) Oil composition for soft chocolate
US20230404102A1 (en) Edible microbial oil
WO2015047170A1 (en) Edible fat composition
WO2011111527A1 (en) Oleaginous composition and oil-in-water type emulsifier containing oleaginous composition
DK2566341T3 (en) fat Blend
JP6225278B2 (en) Plastic oil composition
CN111935988A (en) Soft chocolate
JP6678651B2 (en) Edible fat composition
CN117642073A (en) Fat composition and water-in-oil emulsion
JP2015202099A (en) composite confectionery fat composition
JP7203555B2 (en) fat composition
JP5640609B2 (en) Oil composition for whipped cream
US9167829B2 (en) Oil/fat composition
JP2017205061A (en) Oil and fat composition for composite confectionery
JP6679207B2 (en) Plastic fat composition
US20210307348A1 (en) Fat spread product, process for preparing the same, and its use as table spread or in bakery
JP6198503B2 (en) Oil and fat for foamable oil-in-water emulsion and foamable oil-in-water emulsion comprising the oil and fat
EP2749175A1 (en) Hard butter
BRPI0903778A2 (en) Vegetable fat food composition, process of preparing a vegetable fat food composition and use of a vegetable fat food composition in the preparation of stuffing
WO2023043357A1 (en) Milk fat replacer for chocolate or chocolate-like products
WO2023097143A1 (en) Soft solid fat compositions and methods of making and use thereof

Legal Events

Date Code Title Description
121 Ep: the epo has been informed by wipo that ep was designated in this application

Ref document number: 14846810

Country of ref document: EP

Kind code of ref document: A1

DPE1 Request for preliminary examination filed after expiration of 19th month from priority date (pct application filed from 20040101)
WWE Wipo information: entry into national phase

Ref document number: MX/A/2016/003619

Country of ref document: MX

NENP Non-entry into the national phase

Ref country code: DE

122 Ep: pct application non-entry in european phase

Ref document number: 14846810

Country of ref document: EP

Kind code of ref document: A1