WO2015046543A1 - Method for manufacturing glass substrate for magnetic disk and method for manufacturing magnetic disk - Google Patents
Method for manufacturing glass substrate for magnetic disk and method for manufacturing magnetic disk Download PDFInfo
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- WO2015046543A1 WO2015046543A1 PCT/JP2014/075966 JP2014075966W WO2015046543A1 WO 2015046543 A1 WO2015046543 A1 WO 2015046543A1 JP 2014075966 W JP2014075966 W JP 2014075966W WO 2015046543 A1 WO2015046543 A1 WO 2015046543A1
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- abrasive grains
- glass substrate
- grinding
- magnetic disk
- dispersed
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- G—PHYSICS
- G11—INFORMATION STORAGE
- G11B—INFORMATION STORAGE BASED ON RELATIVE MOVEMENT BETWEEN RECORD CARRIER AND TRANSDUCER
- G11B5/00—Recording by magnetisation or demagnetisation of a record carrier; Reproducing by magnetic means; Record carriers therefor
- G11B5/84—Processes or apparatus specially adapted for manufacturing record carriers
- G11B5/8404—Processes or apparatus specially adapted for manufacturing record carriers manufacturing base layers
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B24—GRINDING; POLISHING
- B24B—MACHINES, DEVICES, OR PROCESSES FOR GRINDING OR POLISHING; DRESSING OR CONDITIONING OF ABRADING SURFACES; FEEDING OF GRINDING, POLISHING, OR LAPPING AGENTS
- B24B37/00—Lapping machines or devices; Accessories
- B24B37/11—Lapping tools
- B24B37/20—Lapping pads for working plane surfaces
- B24B37/24—Lapping pads for working plane surfaces characterised by the composition or properties of the pad materials
- B24B37/245—Pads with fixed abrasives
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B24—GRINDING; POLISHING
- B24B—MACHINES, DEVICES, OR PROCESSES FOR GRINDING OR POLISHING; DRESSING OR CONDITIONING OF ABRADING SURFACES; FEEDING OF GRINDING, POLISHING, OR LAPPING AGENTS
- B24B7/00—Machines or devices designed for grinding plane surfaces on work, including polishing plane glass surfaces; Accessories therefor
- B24B7/20—Machines or devices designed for grinding plane surfaces on work, including polishing plane glass surfaces; Accessories therefor characterised by a special design with respect to properties of the material of non-metallic articles to be ground
- B24B7/22—Machines or devices designed for grinding plane surfaces on work, including polishing plane glass surfaces; Accessories therefor characterised by a special design with respect to properties of the material of non-metallic articles to be ground for grinding inorganic material, e.g. stone, ceramics, porcelain
- B24B7/228—Machines or devices designed for grinding plane surfaces on work, including polishing plane glass surfaces; Accessories therefor characterised by a special design with respect to properties of the material of non-metallic articles to be ground for grinding inorganic material, e.g. stone, ceramics, porcelain for grinding thin, brittle parts, e.g. semiconductors, wafers
Definitions
- the present invention relates to a grinding tool applied to manufacture of a magnetic disk glass substrate mounted on a magnetic disk device such as a hard disk drive (HDD), a method of manufacturing a glass substrate for magnetic disk using the grinding tool, and a magnetic disk It relates to a manufacturing method.
- a magnetic disk device such as a hard disk drive (HDD)
- HDD hard disk drive
- a magnetic disk as one of information recording media mounted on a magnetic disk device such as a hard disk drive (HDD).
- a magnetic disk is configured by forming a thin film such as a magnetic layer on a substrate, and an aluminum substrate has been conventionally used as the substrate.
- the ratio of the glass substrate capable of narrowing the distance between the magnetic head and the magnetic disk as compared with the aluminum substrate is gradually increasing.
- the surface of the glass substrate is polished with high accuracy so as to increase the recording density so that the flying height of the magnetic head can be reduced as much as possible.
- HDDs high recording capacity and lower prices. In order to achieve this, it is necessary to further improve the quality and cost of glass substrates for magnetic disks. It is coming.
- high smoothness on the surface of the magnetic disk is indispensable for reducing the flying height (flying height) necessary for increasing the recording density.
- a substrate surface with a high smoothness is required in the end. Therefore, it is necessary to polish the glass substrate surface with high accuracy.
- further polishing is performed to reduce the surface roughness and microwaviness, thereby reducing the main surface. Has achieved extremely high smoothness.
- a diamond pad is a combination of diamond particles or agglomerates (concentrated abrasive grains) in which several diamond particles are hardened with a fixing material such as glass, using a binding material such as a resin (for example, an acrylic resin). It is fixed.
- a resin layer containing diamond may be formed on the sheet, and then a groove may be formed in the resin layer to form a protrusion.
- the diamond pad referred to here is not necessarily a general name, but is referred to as a “diamond pad” for convenience of explanation in this specification.
- abrasive grains with a distorted shape are present between the surface plate and the glass and are non-uniform, so if the load on the abrasive grains is not constant and the load is concentrated, the surface of the surface plate Because of the low elasticity of cast iron, deep cracks enter the glass, the work-affected layer is deep, and the processing surface roughness of the glass also increases, so a large amount of removal was required in the subsequent mirror polishing process. It was difficult to reduce processing costs.
- Patent Document 2 discloses a tool for grinding using fixed abrasive particles in which a polishing complex (aggregate) in which diamond abrasive particles are bonded with a binder is dispersed in an organic resin at a constant ratio.
- the surface roughness of the processed surface can be reduced, the load on the subsequent mirror polishing process is reduced, and the processing cost of the glass substrate is reduced.
- the present invention has been made to solve such a conventional problem, and its purpose is to achieve both processing speed and processing quality (particularly flatness of the substrate) in grinding processing using fixed abrasive grains.
- the present invention has the following configuration.
- (Configuration 1) A method of manufacturing a glass substrate for a magnetic disk including a grinding process for grinding a main surface of a glass substrate, wherein the grinding process includes grinding abrasive grains, a binder for bonding the abrasive grains, and a binder.
- a glass substrate main surface using a grinding tool which is hard and includes dispersed particles softer than the abrasive grains, and is bonded in a state where the abrasive grains and the dispersed particles are dispersed in the binder.
- (Configuration 2) The method for manufacturing a glass substrate for a magnetic disk according to Configuration 1, wherein the binding material is a resin material.
- (Configuration 3) 3. The method for manufacturing a glass substrate for a magnetic disk according to Configuration 1 or 2, wherein the grinding abrasive grains are concentrated abrasive grains in which a plurality of abrasive grains are bonded with a fixing material.
- (Configuration 4) 4. The method for manufacturing a glass substrate for a magnetic disk according to any one of configurations 1 to 3, wherein the grinding abrasive grains include diamond abrasive grains. (Configuration 5) 5. The method for manufacturing a glass substrate for a magnetic disk according to any one of configurations 1 to 4, wherein the dispersed particles are made of alumina or zirconia.
- (Configuration 8) A method of manufacturing a glass substrate for a magnetic disk according to any one of configurations 1 to 7, wherein a ratio of the dispersed grains to the abrasive grains in the binder is in a range of 0.1 to 5 times.
- (Configuration 9) A magnetic disk manufacturing method comprising forming at least a magnetic recording layer on a magnetic disk glass substrate manufactured by the method for manufacturing a magnetic disk glass substrate according to any one of Structures 1 to 8.
- a grinding tool for grinding a glass substrate surface for an electronic device comprising: grinding abrasive grains; a binder for binding the abrasive grains; and a dispersed grain that is harder than the binder and softer than the abrasive grains.
- a grinding tool wherein the grinding abrasive grains and the dispersed grains are bonded in a state of being dispersed in the binder.
- the above-described configuration can solve the conventional problems, and in the grinding process using the fixed abrasive grains, the processing speed and the processing quality (particularly the flatness of the substrate) are balanced, and the processing quality is stable at a stable processing speed.
- a grinding tool applied to a grinding treatment of a glass substrate that can be stably obtained for a long period of time.
- a highly reliable magnetic disk can be obtained using the glass substrate obtained thereby.
- a glass substrate for a magnetic disk is usually manufactured through shape processing, main surface grinding, end surface polishing, main surface polishing, chemical strengthening, and the like.
- a glass substrate is obtained by cutting into a predetermined size from a sheet-like glass produced by a float method or a downdraw method.
- a sheet-like plate glass produced by pressing from molten glass may be used.
- the present invention is suitable when a glass substrate having a mirror-like main surface is used at the start of grinding.
- the glass substrate is subjected to a grinding process for improving dimensional accuracy and shape accuracy.
- a main surface of the glass substrate is generally ground using a double-side grinding apparatus and using hard abrasive grains such as diamond.
- a predetermined plate thickness and flatness are processed, and a predetermined surface roughness is obtained.
- the present invention relates to the improvement of this grinding process.
- the grinding process in the present invention is a grinding process using, for example, grinding abrasive grains (fixed abrasive grains) containing diamond particles, and in a double-side grinding apparatus, for example, between upper and lower surface plates on which diamond pads are attached as grinding tools.
- a lubricating liquid coolant
- the grinding tool (fixed abrasive grindstone) used for the grinding process is, for example, a diamond pad, and its configuration is schematically shown in FIG.
- a diamond pad 1 shown in FIG. 1 uses a binding material such as a resin (for example, an acrylic resin), which is a collection of abrasive grains 3 in which several diamond particles 5 (see FIG. 2) are hardened with a fixing material such as glass.
- the pellet 4 fixed in this manner is affixed to the sheet 2.
- the configuration shown in FIG. 1 is merely an example, and the present invention is not limited to this.
- a diamond pad that has a resin layer containing diamond particles formed on a sheet and then has grooves formed in the resin layer to form protrusions may be used.
- abrasive grain when it is referred to as fixed abrasive grains or simply abrasive grains, unless otherwise specified, it means a grinding abrasive grain such as the above diamond grain, and the average grain of the abrasive grains. When it says a diameter, it shall mean the average particle diameter of the said abrasive grain.
- the present inventor is difficult to achieve both the processing speed and the processing quality (particularly the flatness of the substrate) with the above-described conventional technology, and the stable processing speed and the good processing quality are stable for a long period of time. I found out that I could not get it. Therefore, as a result of searching for a solution that can increase the processing speed and perform stable grinding, the present inventor used a combination of abrasive grains and dispersed grains softer than the abrasive grains. The present inventors have found that the above-described problems can be solved by applying a grinding tool in which these abrasive grains and dispersed grains are dispersed in a binder.
- the force applied to each of the abrasive grains from the surface plate is dispersed by the presence of the dispersed particles.
- the force applied from the surface plate can be dispersed, and the wear of the tool can be suppressed.
- the distance between the dispersed abrasive grains tends to be non-uniform, but in the present invention, as described above, the dispersed grains are dispersed in addition to the abrasive grains, As a result, the abrasive grains are dispersed at a uniform distance, and uneven wear hardly occurs.
- the grinding tool applied to the grinding process in the present invention is a grinding tool for grinding the glass substrate surface, and is harder than the grinding abrasive grains, the binder for bonding the abrasive grains, and the binder.
- dispersed abrasive particles softer than the abrasive grains are provided, and the abrasive grains and the dispersed grains are bonded in a state of being dispersed in the binder.
- the present invention is characterized in that in the grinding process for grinding a glass substrate, the glass substrate main surface is ground using the grinding tool.
- the abrasive grains may be abrasive grains themselves, but are preferably concentrated abrasive grains in which a plurality of abrasive grains are bonded with a fixing material. Since the single abrasive grains have a small surface area, the gripping resin strength is low and they easily fall off.
- the abrasive grains are preferably diamond grains. In this case, it is preferable that the average particle diameter of the diamond abrasive grains is in the range of about 1.5 to 10 ⁇ m. When the average particle diameter of the diamond abrasive grains is less than the above range, the cut into the mirror-like glass substrate becomes shallow and the biting into the glass substrate is difficult to proceed.
- the average particle diameter of the diamond abrasive grains exceeds the above range, the roughness of the finish becomes rough, so that there is a possibility that the machining allowance load in the subsequent process becomes large. Further, in the case of diamond abrasive grains, it is preferable that the accumulated abrasive grains have a cumulative average particle diameter of about 30 to 50 ⁇ m. Moreover, as a fixing material which fixes abrasive grains, a glass material is suitable, for example.
- the average particle diameter is a point where the cumulative curve is 50% when the cumulative curve is obtained with the total volume of the powder group in the particle size distribution measured by the laser diffraction method as 100%. (Referred to as “cumulative average particle diameter (50% diameter)”).
- the cumulative average particle diameter (50% diameter) is a value that can be measured using a particle diameter / particle size distribution measuring device.
- binder for bonding the abrasive grains examples include metals, glass, resin materials, etc., but resin materials are particularly preferable from the viewpoint of having an appropriate cushioning property and not causing excessive damage to the glass. It is.
- resin material examples include acrylate, epoxy, polycarbonate, and polyester.
- the dispersed particles dispersed together with the abrasive grains in the binder are grains that are harder than the binder and softer than the abrasive grains.
- the force applied to each of the abrasive grains from the surface plate can be dispersed by the presence of the dispersed particles.
- the hardness of the dispersed grains depends on the material of the binder and the abrasive grains, the hardness is generally Mohs and the abrasive grains are about 6.5 to 9.5, so long as the hardness is softer than that.
- the glass used for the grains has a lower Mohs hardness than the abrasive grains.
- the material of the dispersed particles is not particularly limited as long as it satisfies the above-mentioned requirements with respect to hardness, but is preferably made of glass, alumina, or zirconia in terms of Mohs hardness. Moreover, the mixture of the grain from which a material differs may be sufficient. Since these materials are moderately softer than diamond, they wear out before the diamond abrasive grains. Therefore, diamond processing is not hindered.
- the range of the average particle diameter of the alumina or zirconia particles is preferably the same as the average particle diameter of the diamond abrasive grains.
- the dispersed particles may be the particles themselves, but may also be aggregates in which a plurality of dispersed particles are bonded with a glass fixing material such as vitrified bonding.
- the plurality of dispersed grains may be the same or different from each other.
- the glass in this case is softer than the glass substrate to be ground.
- the size of the dispersed particles is preferably the same as that of the aggregate in the case of the particles themselves. By doing so, it becomes easy to disperse both uniformly. Further, it is preferable that the ratio of the size of the abrasive grains (the size in the case of concentrated abrasive grains) and the size of the dispersed grains is substantially equal, and in particular, both are the same size.
- the ratio of the size of the abrasive grains to the dispersed grains is the ratio of the average grain diameter of the dispersed grains to the average grain diameter of the abrasive grains ((average grain diameter of dispersed grains) / (average grain diameter of abrasive grains)). In the range of 0.8 to 1.2. By doing so, it becomes easy to disperse both uniformly.
- both binder is the same material. By doing so, it becomes easy to disperse both uniformly.
- the dispersed grains may be grains composed only of glass that is preferably softer than the glass to be ground.
- the size of the dispersed particles and the ratio of the size to the abrasive grains are the same as in the case of the dispersed particles such as alumina.
- the grinding tool of the present invention is bonded in the state where the abrasive grains and the dispersed grains are dispersed in the binder, and specifically, for example, diamond abrasive grains and non-diamond such as alumina.
- diamond abrasive grains and non-diamond such as alumina.
- an embodiment in which diamond grinding abrasive grains and dispersed grains made of glass are used in combination is particularly suitable. According to this embodiment, the dispersion effect that prevents the generation of the swell component is the highest.
- the ratio of the abrasive grains to the dispersed grains in the binder is not particularly limited, but the following dispersion ratio is preferable from the viewpoint of sufficiently achieving the effects of the present invention.
- the range of the dispersed grains is 0.1 to 3 times that of the abrasive grains 1.
- the range of 0.1 to 5 times the dispersed grains with respect to the abrasive grains 1 is preferable.
- the total amount of the dispersion grains is 0.1 to 5 times that of the grinding grains 1.
- the density of the fixed abrasive grains dispersed in a binder such as a resin (counted as one in the case of aggregated abrasive grains or aggregates) on the grinding surface is 10 to 40 (pieces / mm 2 ). It is preferable that it is the range of these.
- the content of the fixed abrasive grains in the grinding tool is preferably 5 to 80% by volume.
- the abrasive grains of a material softer than the diamond abrasive grains and the aggregates thereof are dispersed together with the diamond aggregate abrasive grains, whereby the distance between the abrasive grains of the diamond aggregate abrasive grains can be uniformly extended.
- excessive pressure concentration on the diamond collecting abrasive grains can be prevented. Thereby, processing can be stabilized even at a high processing speed, and good flatness can be maintained.
- the load during processing is preferably 15 to 200 g / cm 2 in terms of surface pressure.
- a higher load load may be applied to the glass surface than during normal grinding. Is preferred.
- the higher the load the deeper the cutting depth of the abrasive grains, the rougher the glass surface can be made (roughened).
- the grinding should be performed under conditions where the cutting depth of the abrasive grains is reduced by reducing the load. Is desirable.
- FIG. 2 is a schematic diagram for explaining a state at the time of grinding, and shows a state in which the diamond abrasive grains 3 are biting into the glass substrate 10 and are ground (expected view).
- the surface roughness of the glass substrate after completion of the grinding treatment is preferably finished in the range of 0.02 to 3.0 ⁇ m in Ra.
- the processing load of a subsequent process can be reduced by keeping the roughness of the finish low.
- the glass constituting the glass substrate is preferably an amorphous aluminosilicate glass.
- a glass substrate can be finished to a smooth mirror surface by mirror polishing the surface, and the strength after processing is good.
- an aluminosilicate glass for example, a glass containing SiO2 as a main component and containing 20 wt% or less of Al2O3 is preferable. Further, it is more preferable to use glass containing SiO2 as a main component and containing Al2O3 or less by 15% by weight or less.
- SiO2 is 62% by weight to 75% by weight
- Al2O3 is 5% by weight to 15% by weight
- Li2 ⁇ O is 4% by weight to 10% by weight
- Na2O is 4% by weight to 12% by weight
- ZrO2 is contained in an amount of 5.5% to 15% by weight as a main component
- the weight ratio of Na2O / ZrO2 is 0.5 to 2.0
- the weight ratio of Al2O3 / ZrO2 is 0.4 to 2.5.
- Amorphous aluminosilicate glass that does not contain the following phosphorous oxide can be used.
- the heat-resistant glass used for the next generation heat-assisted magnetic recording magnetic disk is, for example, 50 to 75% of SiO2, 0 to 5% of Al2O3, and 0 to 2% of BaO in terms of mol%. , Li2O 0-3%, ZnO 0-5%, Na2O and K2O 3-15% in total, MgO, CaO, SrO and BaO 14-35% in total, ZrO2, TiO2, La2O3, Y2O3, Yb2O3 , Ta2O5, Nb2O5 and HfO2 in total 2 to 9%, the molar ratio [(MgO + CaO) / (MgO + CaO + SrO + BaO)] is in the range of 0.85 to 1, and the molar ratio [Al2O3 / (MgO + CaO)] is 0.
- Glass having a range of ⁇ 0.30 can be preferably used. Further, SiO2 is 56 to 75 mol%, Al2O3 is 1 to 9 mol%, a total of 6 to 15 mol% of alkali metal oxides selected from the group consisting of Li2O, Na2O and K2O, and a group consisting of MgO, CaO and SrO 10 to 30 mol% in total of alkaline earth metal oxides selected from the group consisting of oxides selected from the group consisting of ZrO2, TiO2, Y2O3, La2O3, Gd2O3, Nb2O5 and Ta2O5 in total exceeding 0% and not more than 10 mol% Including glass.
- the content of Al2O3 in the glass composition is preferably 15% by weight or less. Furthermore, it is more preferable that the content of Al2O3 is 5 mol% or less.
- mirror polishing is performed to obtain a highly accurate plane.
- the amount of removal in the subsequent mirror polishing process can be reduced, the processing load can be reduced, and the processing cost can be reduced.
- a polishing pad of a polisher such as polyurethane while supplying a slurry (polishing liquid) containing a metal oxide abrasive such as cerium oxide or colloidal silica.
- a slurry polishing liquid
- a metal oxide abrasive such as cerium oxide or colloidal silica.
- a glass substrate having high smoothness is obtained, for example, by polishing with a cerium oxide-based abrasive (first polishing process) and then with final polishing (mirror polishing) (second polishing process) using colloidal silica abrasive grains. It is possible.
- the surface of the glass substrate after mirror polishing is preferably a mirror surface having an arithmetic average surface roughness Ra of 0.2 nm or less, more preferably 0.1 nm or less.
- the arithmetic average roughness Ra is a roughness calculated in accordance with Japanese Industrial Standard (JIS) B0601.
- the surface roughness (the arithmetic average roughness Ra) is preferably practically the surface roughness obtained when measured with an atomic force microscope (AFM).
- chemical strengthening treatment can be performed.
- a method of the chemical strengthening treatment for example, a low-temperature ion exchange method in which ion exchange is performed in a temperature range not exceeding the glass transition temperature is preferable.
- the chemical strengthening treatment is a process in which a molten chemical strengthening salt is brought into contact with a glass substrate, whereby an alkali metal element having a relatively large atomic radius in the chemical strengthening salt and a relatively small atomic radius in the glass substrate.
- This is a treatment in which an alkali metal element is ion-exchanged, an alkali metal element having a large ion radius is permeated into the surface layer of the glass substrate, and compressive stress is generated on the surface of the glass substrate.
- the chemically strengthened glass substrate is excellent in impact resistance, it is particularly preferable for mounting on a HDD for mobile use, for example.
- the chemical strengthening salt alkali metal nitrates such as potassium nitrate and sodium nitrate can be preferably used.
- the present invention also provides a method for manufacturing a magnetic disk using the above glass substrate for a magnetic disk.
- the magnetic disk is produced by forming at least a magnetic recording layer (magnetic layer) on the magnetic disk glass substrate according to the present invention.
- a magnetic recording layer magnetic layer
- a hexagonal CoCrPt-based or CoPt-based ferromagnetic alloy having a large anisotropic magnetic field can be used.
- a method of forming the magnetic layer it is preferable to use a method of forming a magnetic layer on a glass substrate by a sputtering method, for example, a DC magnetron sputtering method.
- a protective layer and a lubricating layer may be formed on the magnetic recording layer.
- the protective layer an amorphous carbon-based protective layer is suitable.
- a lubricating layer a lubricant having a functional group at the end of the main chain of the perfluoropolyether compound can be used.
- Example 1 (1) Substrate preparation, (2) Shape processing, (3) End surface polishing, (4) Main surface grinding, (5) Main surface polishing (first polishing), (6) Chemical strengthening, (7) Main A glass substrate for a magnetic disk of this example was manufactured through surface polishing (second polishing).
- Substrate preparation A large glass plate made of aluminosilicate glass having a thickness of 1 mm produced by the float method was prepared, and cut into a 70 mm ⁇ 70 mm square piece using a diamond cutter. Subsequently, it processed into the disk shape of outer diameter 65mm and internal diameter 20mm using the diamond cutter.
- This aluminosilicate glass contains SiO2: 62-75 wt%, ZrO2: 5.5-15 wt%, Al2O3: 5-15 wt%, Li2O: 4-10 wt%, Na2O: 4-12 wt% Glass that can be chemically strengthened was used.
- the surface of the obtained substrate was a mirror surface with a surface roughness Ra of 5 nm or less.
- This main surface grinding was performed by using a double-sided grinding machine and setting a glass substrate held by a carrier between the upper and lower surface plates to which diamond pads were attached.
- a diamond pad a plurality of diamond abrasive grains consolidated with glass, an aggregate in which a plurality of alumina particles are fixed with glass, and a plurality of the aggregate abrasive grains and aggregates are combined.
- the average particle size of the diamond abrasive grains is 4.0 ⁇ m
- the average particle size of the diamond collecting abrasive grains is 40 ⁇ m
- the average particle size of the alumina particles is 4.0 ⁇ m
- the average particle size of the alumina aggregate is 40 ⁇ m.
- a diamond pad dispersed in a resin was used so that the maximum particle size was 45 ⁇ m and the ratio of diamond aggregated abrasive grains to alumina aggregate was 1: 0.5.
- the glass in which the abrasive grains were hardened had a lower hardness than the glass to be processed.
- the density of the fixed abrasive grains on the total ground surface was 20 (pieces / mm 2 ). Moreover, it carried out using the lubricating liquid. Moreover, the rotation speed of the surface plate and the load on the glass substrate were adjusted as appropriate.
- the first polishing was performed using a hard polisher (hard foamed urethane) as the polisher.
- the polishing liquid was pure water in which cerium oxide was dispersed as an abrasive, and the load and polishing time were appropriately set.
- the glass substrate after the first polishing step was sequentially immersed in cleaning baths of neutral detergent, pure water, IPA (isopropyl alcohol), and IPA (steam drying), ultrasonically cleaned, and dried.
- Chemical strengthening was performed on the glass substrate after the cleaning.
- a chemical strengthening solution in which potassium nitrate and sodium nitrate were mixed was prepared, the chemical strengthening solution was heated to 380 ° C., and the cleaned and dried glass substrate was immersed for about 4 hours to perform chemical strengthening treatment.
- Example 2 In the main surface grinding process of the first embodiment, a collecting abrasive grain obtained by hardening a plurality of diamond abrasive grains with glass, a plurality of dispersed grains made of glass, and a resin that binds the plurality of the concentrated abrasive grains and the dispersed grains.
- the average particle size of the diamond abrasive grains is about 4.0 ⁇ m
- the average particle size of the diamond concentrating abrasive grains is 40 ⁇ m
- the average particle size of the glass dispersed particles is 4.0 ⁇ m
- the maximum particle size of the glass aggregate is 45 ⁇ m
- the magnetic disk was ground in the same manner as in Example 1 except that a diamond pad dispersed in the resin was used so that the ratio of diamond aggregated abrasive grains to glass aggregate was 1: 0.5.
- a glass substrate was prepared.
- Example 3 In the main surface grinding process of Example 1, aggregated abrasive grains obtained by solidifying a plurality of diamond abrasive grains with glass, aggregates in which a plurality of alumina particles are fixed with glass, a plurality of dispersed grain aggregates made of glass, A plurality of aggregated abrasive grains, a resin that binds the alumina particle aggregates and the glass dispersed grain aggregates, and the average particle diameter of the diamond abrasive grains is about 4.0 ⁇ m, and the average particle diameter of the alumina particles is about 1 to 4.0 ⁇ m, the average particle size of the glass particles is about 1 to 4.0 ⁇ m, the maximum particle size of the alumina aggregate and the glass aggregate is 45 ⁇ m, and the ratio of these diamond agglomerated abrasive grains to the alumina aggregate and the glass aggregate is 1: Grinding was performed in the same manner as in Example 1 except that a diamond pad dispersed in the resin so as to be 0.5: 0.5 was used,
- Example 1 In the main surface grinding process of Example 1, a conventional diamond pad is used in which concentrated abrasive grains obtained by hardening a plurality of diamond abrasive grains with glass (the average grain diameter of the diamond abrasive grains is about 4.0 ⁇ m) are dispersed in the resin. Except for this, grinding was performed in the same manner as in Example 1 to produce a magnetic disk glass substrate. (Comparative Example 2) Grinding was carried out in the same manner as in Comparative Example 1 except that a diamond pad with a fixed grinding grain density of 30 (pieces / mm 2 ) was used for the total fixed abrasive grains (in this example, only diamond abrasive grains). A glass substrate for a magnetic disk was produced.
- the main surface grinding was performed continuously for 100 batches, 100 batches in total.
- the flatness of the glass substrate after grinding is measured using a flat nesting tester, and a predetermined standard (3 ⁇ m or less) is determined as a non-defective product.
- the rate (flatness defect rate) was calculated, and the results are shown in Table 1.
- Table 1 also shows the processing speed during grinding (processing speed ratio with respect to Comparative Example 1).
- Example 2 in which diamond concentration abrasive grains and glass dispersion grains were used in combination, the flatness failure rate was zero%. Further, it can be seen from the comparison between Comparative Examples 1 and 2 that when the grinding surface density of the fixed abrasive grains is decreased in the conventional diamond pad, the flatness defect rate is deteriorated although the processing speed is improved. This shows that stable processing cannot be achieved simply by lowering the fixed abrasive density.
- Example 2 Manufacture of magnetic disk
- An adhesion layer made of a Ti-based alloy thin film, a soft magnetic layer made of a CoTaZr alloy thin film, an underlayer made of a Ru thin film, a perpendicular magnetic recording layer made of a CoCrPt alloy, a protective layer, and a lubricating layer are sequentially formed on the glass substrate.
- a protective layer a hydrogenated carbon layer was formed.
- the lubricating layer was formed by dipping a liquid lubricant of alcohol-modified perfluoropolyether.
- the obtained magnetic disk was installed in an HDD equipped with a DFH head, and a load / unload durability test was conducted for one month while operating the DFH function in a high temperature and high humidity environment of 80 ° C. and 80% RH. There were no particular obstacles and good results were obtained.
Abstract
Description
また、ガラス基板表面は磁気ヘッドの浮上高さを極力下げることができるように、高精度に研磨して高記録密度化を実現している。近年、HDDの更なる大記録容量化、低価格化の要求は増すばかりであり、これを実現するためには、磁気ディスク用ガラス基板においても更なる高品質化、低コスト化が必要になってきている。 There is a magnetic disk as one of information recording media mounted on a magnetic disk device such as a hard disk drive (HDD). A magnetic disk is configured by forming a thin film such as a magnetic layer on a substrate, and an aluminum substrate has been conventionally used as the substrate. However, recently, in response to the pursuit of higher recording density, the ratio of the glass substrate capable of narrowing the distance between the magnetic head and the magnetic disk as compared with the aluminum substrate is gradually increasing.
Further, the surface of the glass substrate is polished with high accuracy so as to increase the recording density so that the flying height of the magnetic head can be reduced as much as possible. In recent years, there has been an increasing demand for HDDs with higher recording capacity and lower prices. In order to achieve this, it is necessary to further improve the quality and cost of glass substrates for magnetic disks. It is coming.
特許文献2には、ダイヤモンド砥粒をバインダーで結合した研磨複合体(凝集体)を有機樹脂内部に一定比率で分散させた固定砥粒による研削加工用の工具が開示されている。 In conventional loose abrasive grains, abrasive grains with a distorted shape are present between the surface plate and the glass and are non-uniform, so if the load on the abrasive grains is not constant and the load is concentrated, the surface of the surface plate Because of the low elasticity of cast iron, deep cracks enter the glass, the work-affected layer is deep, and the processing surface roughness of the glass also increases, so a large amount of removal was required in the subsequent mirror polishing process. It was difficult to reduce processing costs. In contrast, in grinding with a fixed abrasive using a diamond pad, the abrasive grains are uniformly present on the surface of the sheet, so that the load is not concentrated, and in addition, the abrasive is fixed to the sheet using resin. Therefore, even if a load is applied to the abrasive grains, the high elastic action of the resin fixing the abrasive grains makes the cracks (deformed layer) on the processed surface shallow, and the processed surface roughness can be reduced. The load on the machine (such as machining allowance) is reduced, and processing costs can be reduced.
Patent Document 2 discloses a tool for grinding using fixed abrasive particles in which a polishing complex (aggregate) in which diamond abrasive particles are bonded with a binder is dispersed in an organic resin at a constant ratio.
要するに、従来技術では、加工速度と加工品質(特に基板の平坦度)の両立が困難であり、安定した加工速度で良好な加工品質が長期間安定して得られない。 When grinding a glass substrate using a grinding tool with a fixed abrasive as disclosed in Patent Document 2 above, select an agglomerate density that matches the workpiece and adjust the processing pressure. It is always necessary to control the pressure applied to the tip portion (blade edge) of the diamond abrasive grains. It is advantageous to select a grinding tool having a low agglomerate density, particularly when processing is desired to be performed quickly. In this case, since the interval between the aggregates is large, the processing speed increases, but the wear of the tool also increases. Further, when the aggregate density is low, the distance between the dispersed aggregates tends to be non-uniform, and uneven wear tends to occur. When mass production of a glass substrate using such a conventional grinding tool is performed, the processing speed is fast in the initial stage, but grinding abrasive grains fall off, uneven wear, clogging, etc. are repeated, and the tool surface undulates. Components are formed, and at a relatively early stage (several batches have elapsed since the start of processing), the processing speed decreases and the quality after processing decreases. In particular, the quality deterioration of flatness becomes remarkable. Although it is possible to recover the machining speed reduced by the correction work for removing the waviness component generated on the tool surface, it is necessary to frequently perform such a correction work, so that the production load is large.
In short, in the prior art, it is difficult to achieve both the processing speed and the processing quality (particularly the flatness of the substrate), and good processing quality cannot be stably obtained for a long time at a stable processing speed.
すなわち、上記課題を解決するため、本発明は以下の構成を有する。
(構成1)
ガラス基板の主表面を研削する研削処理を含む磁気ディスク用ガラス基板の製造方法であって、前記研削処理では、研削砥粒と、該研削砥粒を結合する結合材と、該結合材よりも硬く、且つ前記研削砥粒よりも柔らかい分散粒とを備え、前記結合材中に前記研削砥粒と前記分散粒とが分散された状態で結合されている研削工具を用いて、ガラス基板主表面の研削を行うことを特徴とする磁気ディスク用ガラス基板の製造方法。 As a result of searching for a solution that can increase the processing speed and perform stable grinding, the present inventor has completed the present invention.
That is, in order to solve the above problems, the present invention has the following configuration.
(Configuration 1)
A method of manufacturing a glass substrate for a magnetic disk including a grinding process for grinding a main surface of a glass substrate, wherein the grinding process includes grinding abrasive grains, a binder for bonding the abrasive grains, and a binder. A glass substrate main surface using a grinding tool which is hard and includes dispersed particles softer than the abrasive grains, and is bonded in a state where the abrasive grains and the dispersed particles are dispersed in the binder. A method for producing a glass substrate for a magnetic disk, characterized in that:
前記結合材は、樹脂材料であることを特徴とする構成1に記載の磁気ディスク用ガラス基板の製造方法。
(構成3)
前記研削砥粒は、複数の研削砥粒が固定材で結合された集結砥粒であることを特徴とする構成1又は2に記載の磁気ディスク用ガラス基板の製造方法。 (Configuration 2)
2. The method for manufacturing a glass substrate for a magnetic disk according to
(Configuration 3)
3. The method for manufacturing a glass substrate for a magnetic disk according to
前記研削砥粒は、ダイヤモンド砥粒を含むことを特徴とする構成1乃至3のいずれかに記載の磁気ディスク用ガラス基板の製造方法。
(構成5)
前記分散粒は、アルミナ又はジルコニアからなることを特徴とする構成1乃至4のいずれかに記載の磁気ディスク用ガラス基板の製造方法。 (Configuration 4)
4. The method for manufacturing a glass substrate for a magnetic disk according to any one of
(Configuration 5)
5. The method for manufacturing a glass substrate for a magnetic disk according to any one of
前記分散粒は、研削するガラスよりも柔らかいガラスからなることを特徴とする構成1乃至4のいずれかに記載の磁気ディスク用ガラス基板の製造方法。
(構成7)
前記分散粒は、複数の分散粒が、研削するガラスよりも柔らかいガラスで結合された凝集体であることを特徴とする構成1乃至4のいずれかに記載の磁気ディスク用ガラス基板の製造方法。 (Configuration 6)
5. The method for manufacturing a glass substrate for a magnetic disk according to any one of
(Configuration 7)
5. The method of manufacturing a glass substrate for a magnetic disk according to any one of
前記結合材中の前記研削砥粒に対する前記分散粒の比率が、0.1~5倍の範囲であることを特徴とする構成1乃至7のいずれかに記載の磁気ディスク用ガラス基板の製造方法。
(構成9)
構成1乃至8のいずれかに記載の磁気ディスク用ガラス基板の製造方法により製造された磁気ディスク用ガラス基板上に、少なくとも磁気記録層を形成することを特徴とする磁気ディスクの製造方法。 (Configuration 8)
8. A method of manufacturing a glass substrate for a magnetic disk according to any one of
(Configuration 9)
A magnetic disk manufacturing method comprising forming at least a magnetic recording layer on a magnetic disk glass substrate manufactured by the method for manufacturing a magnetic disk glass substrate according to any one of
電子デバイス用のガラス基板表面を研削する研削工具であって、研削砥粒と、該研削砥粒を結合する結合材と、該結合材よりも硬く、且つ前記研削砥粒よりも柔らかい分散粒とを備え、前記結合材中に前記研削砥粒と前記分散粒とが分散された状態で結合されていることを特徴とする研削工具。 (Configuration 10)
A grinding tool for grinding a glass substrate surface for an electronic device, comprising: grinding abrasive grains; a binder for binding the abrasive grains; and a dispersed grain that is harder than the binder and softer than the abrasive grains. A grinding tool, wherein the grinding abrasive grains and the dispersed grains are bonded in a state of being dispersed in the binder.
磁気ディスク用ガラス基板は、通常、形状加工、主表面研削、端面研磨、主表面研磨、化学強化、等を経て製造される。
本発明の磁気ディスク用ガラス基板の製造方法においては、フロート法やダウンドロー法で製造されたシート状ガラスから所定の大きさに切り出してガラス基板を得る。また、これ以外に、溶融ガラスからプレスで作製したシート状板ガラスを用いてもよい。本発明は、研削加工開始時に主表面が鏡面状のガラス基板を使用する場合に好適である。 Hereinafter, embodiments of the present invention will be described in detail.
A glass substrate for a magnetic disk is usually manufactured through shape processing, main surface grinding, end surface polishing, main surface polishing, chemical strengthening, and the like.
In the method for producing a glass substrate for a magnetic disk according to the present invention, a glass substrate is obtained by cutting into a predetermined size from a sheet-like glass produced by a float method or a downdraw method. In addition to this, a sheet-like plate glass produced by pressing from molten glass may be used. The present invention is suitable when a glass substrate having a mirror-like main surface is used at the start of grinding.
この研削加工は、通常両面研削装置を用い、ダイヤモンド等の硬質砥粒を用いてガラス基板主表面の研削を行う。こうしてガラス基板主表面を研削加工することにより、所定の板厚、平坦度に加工するとともに、所定の表面粗さを得る。 Next, the glass substrate is subjected to a grinding process for improving dimensional accuracy and shape accuracy.
In this grinding process, a main surface of the glass substrate is generally ground using a double-side grinding apparatus and using hard abrasive grains such as diamond. By grinding the main surface of the glass substrate in this way, a predetermined plate thickness and flatness are processed, and a predetermined surface roughness is obtained.
そこで、本発明者は、加工速度を高めて、なお且つ安定した研削加工を行うことが可能な解決手段を模索した結果、研削砥粒と、該研削砥粒よりも柔らかい分散粒とを併用し、結合材中にこれらの研削砥粒と分散粒とが分散された状態で結合されている研削工具を適用することによって、上記課題を解決できることを見出したものである。 As described above, the present inventor is difficult to achieve both the processing speed and the processing quality (particularly the flatness of the substrate) with the above-described conventional technology, and the stable processing speed and the good processing quality are stable for a long period of time. I found out that I could not get it.
Therefore, as a result of searching for a solution that can increase the processing speed and perform stable grinding, the present inventor used a combination of abrasive grains and dispersed grains softer than the abrasive grains. The present inventors have found that the above-described problems can be solved by applying a grinding tool in which these abrasive grains and dispersed grains are dispersed in a binder.
また、本発明は、ガラス基板を研削する研削処理において、上記研削工具を用いて、ガラス基板主表面の研削を行うことを特徴とするものである。 That is, the grinding tool applied to the grinding process in the present invention is a grinding tool for grinding the glass substrate surface, and is harder than the grinding abrasive grains, the binder for bonding the abrasive grains, and the binder. In addition, dispersed abrasive particles softer than the abrasive grains are provided, and the abrasive grains and the dispersed grains are bonded in a state of being dispersed in the binder.
Further, the present invention is characterized in that in the grinding process for grinding a glass substrate, the glass substrate main surface is ground using the grinding tool.
本発明においては、上記研削砥粒がダイヤモンド砥粒であることが好ましい。この場合、ダイヤモンド砥粒の平均粒子径が1.5~10μm程度の範囲であることが好適である。
ダイヤモンド砥粒の平均粒子径が上記の範囲を下回ると鏡面状ガラス基板に対する切り込みが浅くなりガラス基板への食い込みが進行し難くなる。一方、ダイヤモンド砥粒の平均粒子径が上記の範囲を上回ると仕上りの粗さが粗くなるため後工程の取り代負荷が大きくなるおそれがある。
また、ダイヤモンド砥粒の集結砥粒である場合、この集結砥粒の粒径は、累積平均粒子径が30~50μm程度であることが好ましい。
また、砥粒同士を固定する固定材としては例えばガラス材が好適である。 The abrasive grains may be abrasive grains themselves, but are preferably concentrated abrasive grains in which a plurality of abrasive grains are bonded with a fixing material. Since the single abrasive grains have a small surface area, the gripping resin strength is low and they easily fall off.
In the present invention, the abrasive grains are preferably diamond grains. In this case, it is preferable that the average particle diameter of the diamond abrasive grains is in the range of about 1.5 to 10 μm.
When the average particle diameter of the diamond abrasive grains is less than the above range, the cut into the mirror-like glass substrate becomes shallow and the biting into the glass substrate is difficult to proceed. On the other hand, when the average particle diameter of the diamond abrasive grains exceeds the above range, the roughness of the finish becomes rough, so that there is a possibility that the machining allowance load in the subsequent process becomes large.
Further, in the case of diamond abrasive grains, it is preferable that the accumulated abrasive grains have a cumulative average particle diameter of about 30 to 50 μm.
Moreover, as a fixing material which fixes abrasive grains, a glass material is suitable, for example.
上記分散粒の大きさは、粒そのものの場合は、凝集体の場合と同等であることが好ましい。こうすることで、両者を均一に分散させやすくなる。
また、上記研削砥粒の大きさ(集結砥粒の場合はその大きさ)と分散粒との大きさの比は、ほぼ同等であることが好適であり、特に両者が同じ大きさであることが望ましい。研削砥粒と分散粒との大きさの比は、研削砥粒の平均粒径に対する分散粒の平均粒径の比((分散粒の平均粒径)/(研削砥粒の平均粒径))で0.8~1.2の範囲内とすることが好ましい。こうすることで、両者を均一に分散させやすくなる。
また、研削砥粒の固定材と分散粒の固定剤とが用いられる場合、両者の結合材は同じ材料であることが好ましい。こうすることで、両者を均一に分散させやすくなる。 The dispersed particles may be the particles themselves, but may also be aggregates in which a plurality of dispersed particles are bonded with a glass fixing material such as vitrified bonding. In this case, the plurality of dispersed grains may be the same or different from each other. Moreover, it is preferable that the glass in this case is softer than the glass substrate to be ground.
The size of the dispersed particles is preferably the same as that of the aggregate in the case of the particles themselves. By doing so, it becomes easy to disperse both uniformly.
Further, it is preferable that the ratio of the size of the abrasive grains (the size in the case of concentrated abrasive grains) and the size of the dispersed grains is substantially equal, and in particular, both are the same size. Is desirable. The ratio of the size of the abrasive grains to the dispersed grains is the ratio of the average grain diameter of the dispersed grains to the average grain diameter of the abrasive grains ((average grain diameter of dispersed grains) / (average grain diameter of abrasive grains)). In the range of 0.8 to 1.2. By doing so, it becomes easy to disperse both uniformly.
Moreover, when the fixing material of a grinding grain and the fixing agent of a dispersion grain are used, it is preferable that both binder is the same material. By doing so, it becomes easy to disperse both uniformly.
このガラスのみからなる分散粒の場合、分散粒の大きさや、研削砥粒との大きさの比などに関しては、上記アルミナ等の分散粒の場合と同様である。 The dispersed grains may be grains composed only of glass that is preferably softer than the glass to be ground.
In the case of the dispersed particles made of only glass, the size of the dispersed particles and the ratio of the size to the abrasive grains are the same as in the case of the dispersed particles such as alumina.
本発明においては、特にダイヤモンド研削砥粒と、ガラスからなる分散粒との併用の実施態様が好適である。この実施態様によれば、うねり成分発生を防止する分散効果が最も高くなる。 The grinding tool of the present invention is bonded in the state where the abrasive grains and the dispersed grains are dispersed in the binder, and specifically, for example, diamond abrasive grains and non-diamond such as alumina. Use in combination with dispersed grains, combined use of diamond abrasive grains and dispersed grains made of glass, or combined use of diamond abrasive grains, non-diamond dispersed grains such as alumina, and dispersed grains made of glass, etc. As mentioned.
In the present invention, an embodiment in which diamond grinding abrasive grains and dispersed grains made of glass are used in combination is particularly suitable. According to this embodiment, the dispersion effect that prevents the generation of the swell component is the highest.
ダイヤモンド研削砥粒と、アルミナ等の非ダイヤモンド分散粒との併用の場合は、研削砥粒1に対し分散粒0.1~3倍の範囲であることが好適である。
また、ダイヤモンド研削砥粒と、ガラスからなる分散粒との併用の場合は、研削砥粒1に対し分散粒0.1~5倍の範囲であることが好適である。
また、ダイヤモンド研削砥粒と、アルミナ等の非ダイヤモンド分散粒と、ガラスからなる分散粒との併用の場合は、研削砥粒1に対し分散粒の全量が0.1~5倍の範囲であることが好適である。
また、樹脂等の結合材中に分散される固定砥粒の合計(集結砥粒や凝集体の場合はそれを1個と数える)の研削面における密度は、10~40(個/mm2)の範囲であることが好ましい。また、研削工具中における固定砥粒の含有量は、5~80体積%であることが好ましい。固定砥粒の含有量が上記範囲を逸脱(超過及び不足のいずれも)すると、いずれも加工時間の増大を招いてコスト高となる場合がある。
本発明では、ダイヤモンド砥粒よりやわらかい材料の砥粒及びその凝集体を、ダイヤモンド集結砥粒と一緒に分散させることにより、ダイヤモンド集結砥粒の砥粒間距離を均一に伸ばすことができる。また、ダイヤモンド集結砥粒への過度の圧力集中を防止することができる。これにより、高い加工速度においても加工を安定化することができ、良好な平坦度を維持することができる。 In the present invention, the ratio of the abrasive grains to the dispersed grains in the binder is not particularly limited, but the following dispersion ratio is preferable from the viewpoint of sufficiently achieving the effects of the present invention.
When the diamond abrasive grains are used in combination with non-diamond dispersed grains such as alumina, the range of the dispersed grains is 0.1 to 3 times that of the
Further, when the diamond abrasive grains are used in combination with the dispersed grains made of glass, the range of 0.1 to 5 times the dispersed grains with respect to the
In the case of using a combination of diamond grinding grains, non-diamond dispersion grains such as alumina, and dispersion grains made of glass, the total amount of the dispersion grains is 0.1 to 5 times that of the grinding
Further, the density of the fixed abrasive grains dispersed in a binder such as a resin (counted as one in the case of aggregated abrasive grains or aggregates) on the grinding surface is 10 to 40 (pieces / mm 2 ). It is preferable that it is the range of these. Further, the content of the fixed abrasive grains in the grinding tool is preferably 5 to 80% by volume. If the content of the fixed abrasive deviates from the above range (both excess and deficiency), both may increase the processing time and increase the cost.
In the present invention, the abrasive grains of a material softer than the diamond abrasive grains and the aggregates thereof are dispersed together with the diamond aggregate abrasive grains, whereby the distance between the abrasive grains of the diamond aggregate abrasive grains can be uniformly extended. In addition, excessive pressure concentration on the diamond collecting abrasive grains can be prevented. Thereby, processing can be stabilized even at a high processing speed, and good flatness can be maintained.
なお、鏡面状のガラス基板表面を例えばダイヤモンドパッドで研削加工する場合、まず、ダイヤモンド砥粒をガラス基板表面に食い込ませるためガラス表面に対して通常の研削加工時よりも高い荷重負荷をかけることが好適である。高い負荷はそれだけ砥粒の切り込み深さが深くなるため、ガラス表面の粗さを粗くさせる(粗面化する)ことができる。
このような加工初期段階でガラス表面が粗面化された後には、研削加工に対して高い負荷は必要なく、むしろ負荷を下げて砥粒の切り込み深さを浅くした条件で研削加工を行うことが望ましい。図2は、研削加工時の状態を説明するための模式図であり、ダイヤモンド砥粒3がガラス基板10に食い込んで研削している状態を示している(予想図)。 In the grinding treatment in the present invention, the load during processing is preferably 15 to 200 g / cm 2 in terms of surface pressure.
When grinding a mirror-like glass substrate surface with, for example, a diamond pad, first, in order to cause the diamond abrasive grains to bite into the glass substrate surface, a higher load load may be applied to the glass surface than during normal grinding. Is preferred. The higher the load, the deeper the cutting depth of the abrasive grains, the rougher the glass surface can be made (roughened).
After the glass surface has been roughened in such an initial stage of processing, there is no need for a high load on the grinding process. Rather, the grinding should be performed under conditions where the cutting depth of the abrasive grains is reduced by reducing the load. Is desirable. FIG. 2 is a schematic diagram for explaining a state at the time of grinding, and shows a state in which the diamond
また、SiO2を56~75モル%、Al2O3を1~9モル%、Li2O、Na2OおよびK2Oからなる群から選ばれるアルカリ金属酸化物を合計で6~15モル%、MgO、CaOおよびSrOからなる群から選ばれるアルカリ土類金属酸化物を合計で10~30モル%、ZrO2、TiO2、Y2O3、La2O3、Gd2O3、Nb2O5およびTa2O5からなる群から選ばれる酸化物を合計で0%超かつ10モル%以下、含むガラスであってもよい。
本発明において、ガラス組成におけるAl2O3の含有量が15重量%以下であると好ましい。さらには、Al2O3の含有量が5モル%以下であるとなお好ましい。 The heat-resistant glass used for the next generation heat-assisted magnetic recording magnetic disk is, for example, 50 to 75% of SiO2, 0 to 5% of Al2O3, and 0 to 2% of BaO in terms of mol%. , Li2O 0-3%, ZnO 0-5%, Na2O and K2O 3-15% in total, MgO, CaO, SrO and BaO 14-35% in total, ZrO2, TiO2, La2O3, Y2O3, Yb2O3 , Ta2O5, Nb2O5 and HfO2 in total 2 to 9%, the molar ratio [(MgO + CaO) / (MgO + CaO + SrO + BaO)] is in the range of 0.85 to 1, and the molar ratio [Al2O3 / (MgO + CaO)] is 0. Glass having a range of ˜0.30 can be preferably used.
Further, SiO2 is 56 to 75 mol%, Al2O3 is 1 to 9 mol%, a total of 6 to 15 mol% of alkali metal oxides selected from the group consisting of Li2O, Na2O and K2O, and a group consisting of MgO, CaO and
In the present invention, the content of Al2O3 in the glass composition is preferably 15% by weight or less. Furthermore, it is more preferable that the content of Al2O3 is 5 mol% or less.
また、本発明において表面粗さ(上記算術平均粗さRa)は、原子間力顕微鏡(AFM)で測定したときに得られる表面形状の表面粗さとすることが実用上好ましい。 In the present invention, the surface of the glass substrate after mirror polishing is preferably a mirror surface having an arithmetic average surface roughness Ra of 0.2 nm or less, more preferably 0.1 nm or less. In the present invention, the arithmetic average roughness Ra is a roughness calculated in accordance with Japanese Industrial Standard (JIS) B0601.
In the present invention, the surface roughness (the arithmetic average roughness Ra) is preferably practically the surface roughness obtained when measured with an atomic force microscope (AFM).
本発明において磁気ディスクは、本発明による磁気ディスク用ガラス基板の上に少なくとも磁気記録層(磁性層)を形成して製造される。磁性層の材料としては、異方性磁界の大きな六方晶系であるCoCrPt系やCoPt系強磁性合金を用いることができる。磁性層の形成方法としてはスパッタリング法、例えばDCマグネトロンスパッタリング法によりガラス基板の上に磁性層を成膜する方法を用いることが好適である。 The present invention also provides a method for manufacturing a magnetic disk using the above glass substrate for a magnetic disk.
In the present invention, the magnetic disk is produced by forming at least a magnetic recording layer (magnetic layer) on the magnetic disk glass substrate according to the present invention. As a material for the magnetic layer, a hexagonal CoCrPt-based or CoPt-based ferromagnetic alloy having a large anisotropic magnetic field can be used. As a method of forming the magnetic layer, it is preferable to use a method of forming a magnetic layer on a glass substrate by a sputtering method, for example, a DC magnetron sputtering method.
本発明によって得られる磁気ディスク用ガラス基板を利用することにより、信頼性の高い磁気ディスクを得ることができる。 Further, a protective layer and a lubricating layer may be formed on the magnetic recording layer. As the protective layer, an amorphous carbon-based protective layer is suitable. Further, as the lubricating layer, a lubricant having a functional group at the end of the main chain of the perfluoropolyether compound can be used.
By using the glass substrate for magnetic disk obtained by the present invention, a highly reliable magnetic disk can be obtained.
(実施例1)
以下の(1)基板準備、(2)形状加工、(3)端面研磨、(4)主表面研削加工、(5)主表面研磨(第1研磨)、(6)化学強化、(7)主表面研磨(第2研磨)、を経て本実施例の磁気ディスク用ガラス基板を製造した。 Hereinafter, embodiments of the present invention will be specifically described with reference to examples. In addition, this invention is not limited to a following example.
Example 1
(1) Substrate preparation, (2) Shape processing, (3) End surface polishing, (4) Main surface grinding, (5) Main surface polishing (first polishing), (6) Chemical strengthening, (7) Main A glass substrate for a magnetic disk of this example was manufactured through surface polishing (second polishing).
フロート法により製造された厚さ1mmのアルミノシリケートガラスからなる大板ガラスを準備し、70mm×70mmの正方形の小片にダイヤモンドカッターを用いて裁断した。次いで、ダイヤモンドカッターを用いて、外径65mm、内径20mmの円盤形状に加工した。このアルミノシリケートガラスとしては、SiO2:62~75重量%、ZrO2:5.5~15重量%、Al2O3:5~15重量%、Li2O:4~10重量%、Na2O:4~12重量%を含有する化学強化可能なガラスを使用した。
得られた基板の表面は、表面粗さRaが5nm以下の鏡面であった。 (1) Substrate preparation A large glass plate made of aluminosilicate glass having a thickness of 1 mm produced by the float method was prepared, and cut into a 70 mm × 70 mm square piece using a diamond cutter. Subsequently, it processed into the disk shape of outer diameter 65mm and internal diameter 20mm using the diamond cutter. This aluminosilicate glass contains SiO2: 62-75 wt%, ZrO2: 5.5-15 wt%, Al2O3: 5-15 wt%, Li2O: 4-10 wt%, Na2O: 4-12 wt% Glass that can be chemically strengthened was used.
The surface of the obtained substrate was a mirror surface with a surface roughness Ra of 5 nm or less.
次に、ダイヤモンド砥石を用いてガラス基板の中央部分に孔を空けると共に、外周端面および内周端面に所定の面取り加工を施した。 (2) Shape processing Next, a diamond grindstone was used to make a hole in the central portion of the glass substrate, and a predetermined chamfering was applied to the outer peripheral end surface and the inner peripheral end surface.
次いで、ブラシ研磨により、ガラス基板を回転させながらガラス基板の端面(内周、外周)を研磨した。 (3) End surface polishing Next, the end surface (inner periphery, outer periphery) of the glass substrate was polished by brush polishing while rotating the glass substrate.
この主表面研削加工は両面研削装置を用い、ダイヤモンドパッドが貼り付けられた上下定盤の間にキャリアにより保持したガラス基板をセットして行なった。本実施例では、ダイヤモンドパッドとして、複数のダイヤモンド砥粒をガラスで固めた集結砥粒と、複数のアルミナ粒子をガラスで固定した凝集体と、複数の当該集結砥粒及び凝集体を結合している樹脂とを備え、ダイヤモンド砥粒の平均粒径が4.0μm、ダイヤモンドの集結砥粒の平均粒径が40μm、アルミナ粒子の平均粒径が4.0μm、アルミナ凝集体の平均粒径は40μm、最大粒径は45μm、ダイヤモンド集結砥粒とアルミナ凝集体との比率が1:0.5となるように樹脂中に分散させたダイヤモンドパッドを使用した。上記砥粒等を固めたガラスは、加工するガラスよりも硬度の小さいものを使用した。また、上記固定砥粒の合計の研削面における密度は、20(個/mm2)とした。また、潤滑液を使用しながら行った。また、定盤の回転数、ガラス基板への荷重は、適宜調整して行った。 (4) Main surface grinding This main surface grinding was performed by using a double-sided grinding machine and setting a glass substrate held by a carrier between the upper and lower surface plates to which diamond pads were attached. In this example, as a diamond pad, a plurality of diamond abrasive grains consolidated with glass, an aggregate in which a plurality of alumina particles are fixed with glass, and a plurality of the aggregate abrasive grains and aggregates are combined. The average particle size of the diamond abrasive grains is 4.0 μm, the average particle size of the diamond collecting abrasive grains is 40 μm, the average particle size of the alumina particles is 4.0 μm, and the average particle size of the alumina aggregate is 40 μm. A diamond pad dispersed in a resin was used so that the maximum particle size was 45 μm and the ratio of diamond aggregated abrasive grains to alumina aggregate was 1: 0.5. The glass in which the abrasive grains were hardened had a lower hardness than the glass to be processed. The density of the fixed abrasive grains on the total ground surface was 20 (pieces / mm 2 ). Moreover, it carried out using the lubricating liquid. Moreover, the rotation speed of the surface plate and the load on the glass substrate were adjusted as appropriate.
次に、上述した研削加工で残留した傷や歪みを除去するための第1研磨を両面研磨装置を用いて行なった。両面研磨装置においては、研磨パッドが貼り付けられた上下研磨定盤の間にキャリアにより保持したガラス基板を密着させ、このキャリアを太陽歯車(サンギア)と内歯歯車(インターナルギア)とに噛合させ、上記ガラス基板を上下定盤によって挟圧する。その後、研磨パッドとガラス基板の研磨面との間に研磨液を供給して回転させることによって、ガラス基板が定盤上で自転しながら公転して両面を同時に研磨加工するものである。具体的には、ポリシャとして硬質ポリシャ(硬質発泡ウレタン)を用い、第1研磨を実施した。研磨液としては酸化セリウムを研磨剤として分散した純水とし、荷重、研磨時間は適宜設定した。上記第1研磨工程を終えたガラス基板を、中性洗剤、純水、IPA(イソプロピルアルコール)、IPA(蒸気乾燥)の各洗浄槽に順次浸漬して、超音波洗浄し、乾燥した。 (5) Main surface polishing (first polishing)
Next, the 1st grinding | polishing for removing the flaw and distortion which remain | survived by the grinding process mentioned above was performed using the double-side polish apparatus. In a double-side polishing machine, a glass substrate held by a carrier is closely attached between an upper and lower polishing surface plate to which a polishing pad is attached, and this carrier is engaged with a sun gear (sun gear) and an internal gear (internal gear). The glass substrate is sandwiched between upper and lower surface plates. Thereafter, a polishing liquid is supplied and rotated between the polishing pad and the polishing surface of the glass substrate, whereby the glass substrate revolves while rotating on the surface plate to simultaneously polish both surfaces. Specifically, the first polishing was performed using a hard polisher (hard foamed urethane) as the polisher. The polishing liquid was pure water in which cerium oxide was dispersed as an abrasive, and the load and polishing time were appropriately set. The glass substrate after the first polishing step was sequentially immersed in cleaning baths of neutral detergent, pure water, IPA (isopropyl alcohol), and IPA (steam drying), ultrasonically cleaned, and dried.
次に、上記洗浄を終えたガラス基板に化学強化を施した。化学強化は硝酸カリウムと硝酸ナトリウムの混合した化学強化液を用意し、この化学強化溶液を380℃に加熱し、上記洗浄・乾燥済みのガラス基板を約4時間浸漬して化学強化処理を行なった。 (6) Chemical strengthening Next, chemical strengthening was performed on the glass substrate after the cleaning. For chemical strengthening, a chemical strengthening solution in which potassium nitrate and sodium nitrate were mixed was prepared, the chemical strengthening solution was heated to 380 ° C., and the cleaned and dried glass substrate was immersed for about 4 hours to perform chemical strengthening treatment.
次いで上記の第1研磨で使用したものと同じ両面研磨装置を用い、ポリシャを軟質ポリシャ(スウェード)の研磨パッド(発泡ポリウレタン製)に替えて第2研磨を実施した。この第2研磨は、上述した第1研磨で得られた平坦な表面を維持しつつ、例えばガラス基板主表面の表面粗さをRaで0.2nm程度以下の平滑な鏡面に仕上げるための鏡面研磨加工である。研磨液としてはコロイダルシリカを分散した純水とし、荷重、研磨時間は適宜設定した。上記第2研磨工程を終えたガラス基板を、中性洗剤、純水、IPA、IPA(蒸気乾燥)の各洗浄槽に順次浸漬して、超音波洗浄し、乾燥した。 (7) Main surface polishing (second polishing)
Next, using the same double-side polishing apparatus as that used in the first polishing, the polishing was changed to a polishing pad (made of polyurethane foam) of a soft polisher (suede), and the second polishing was performed. This second polishing is, for example, mirror polishing for finishing the surface roughness of the glass substrate main surface to a smooth mirror surface with a Ra of about 0.2 nm or less while maintaining the flat surface obtained by the first polishing described above. It is processing. The polishing liquid was pure water in which colloidal silica was dispersed, and the load and polishing time were appropriately set. The glass substrate after the second polishing step was sequentially immersed in each cleaning bath of neutral detergent, pure water, IPA, and IPA (steam drying), ultrasonically cleaned, and dried.
実施例1の主表面研削加工において、複数のダイヤモンド砥粒をガラスで固めた集結砥粒と、ガラスで出来た複数の分散粒と、複数の当該集結砥粒及び分散粒を結合している樹脂とを備え、ダイヤモンド砥粒の平均粒径が約4.0μm、ダイヤモンド集結砥粒の平均粒径が40μm、ガラス分散粒の平均粒径が4.0μm、ガラス凝集体の最大粒径は45μm、ダイヤモンド集結砥粒とガラス凝集体との比率が1:0.5となるように樹脂中に分散させたダイヤモンドパッドを使用したこと以外は、実施例1と同様にして研削加工を行い、磁気ディスク用ガラス基板を作製した。 (Example 2)
In the main surface grinding process of the first embodiment, a collecting abrasive grain obtained by hardening a plurality of diamond abrasive grains with glass, a plurality of dispersed grains made of glass, and a resin that binds the plurality of the concentrated abrasive grains and the dispersed grains. The average particle size of the diamond abrasive grains is about 4.0 μm, the average particle size of the diamond concentrating abrasive grains is 40 μm, the average particle size of the glass dispersed particles is 4.0 μm, and the maximum particle size of the glass aggregate is 45 μm, The magnetic disk was ground in the same manner as in Example 1 except that a diamond pad dispersed in the resin was used so that the ratio of diamond aggregated abrasive grains to glass aggregate was 1: 0.5. A glass substrate was prepared.
実施例1の主表面研削加工において、複数のダイヤモンド砥粒をガラスで固めた集結砥粒と、複数のアルミナ粒子をガラスで固定した凝集体と、ガラスで出来た複数の分散粒凝集体と、複数の当該集結砥粒、アルミナ粒子凝集体及びガラス分散粒凝集体を結合している樹脂とを備え、ダイヤモンド砥粒の平均粒径が約4.0μm、アルミナ粒子の平均粒径が約1~4.0μm、ガラス粒子の平均粒径が約1~4.0μm、アルミナ凝集体とガラス凝集体の最大粒径は45μm、これらダイヤモンド集結砥粒とアルミナ凝集体とガラス凝集体の比率が1:0.5:0.5となるように樹脂中に分散させたダイヤモンドパッドを使用したこと以外は、実施例1と同様にして研削加工を行い、磁気ディスク用ガラス基板を作製した。 Example 3
In the main surface grinding process of Example 1, aggregated abrasive grains obtained by solidifying a plurality of diamond abrasive grains with glass, aggregates in which a plurality of alumina particles are fixed with glass, a plurality of dispersed grain aggregates made of glass, A plurality of aggregated abrasive grains, a resin that binds the alumina particle aggregates and the glass dispersed grain aggregates, and the average particle diameter of the diamond abrasive grains is about 4.0 μm, and the average particle diameter of the alumina particles is about 1 to 4.0 μm, the average particle size of the glass particles is about 1 to 4.0 μm, the maximum particle size of the alumina aggregate and the glass aggregate is 45 μm, and the ratio of these diamond agglomerated abrasive grains to the alumina aggregate and the glass aggregate is 1: Grinding was performed in the same manner as in Example 1 except that a diamond pad dispersed in the resin so as to be 0.5: 0.5 was used, and a glass substrate for a magnetic disk was produced.
実施例1の主表面研削加工において、複数のダイヤモンド砥粒をガラスで固めた集結砥粒(ダイヤモンド砥粒の平均粒径が約4.0μm)を樹脂中に分散させた従来のダイヤモンドパッドを使用したこと以外は、実施例1と同様にして研削加工を行い、磁気ディスク用ガラス基板を作製した。
(比較例2)
固定砥粒の合計(この例ではダイヤモンド集結砥粒のみ)の研削面における密度を30(個/mm2)としたダイヤモンドパッドを使用したこと以外は、比較例1と同様にして研削加工を行い、磁気ディスク用ガラス基板を作製した。 (Comparative Example 1)
In the main surface grinding process of Example 1, a conventional diamond pad is used in which concentrated abrasive grains obtained by hardening a plurality of diamond abrasive grains with glass (the average grain diameter of the diamond abrasive grains is about 4.0 μm) are dispersed in the resin. Except for this, grinding was performed in the same manner as in Example 1 to produce a magnetic disk glass substrate.
(Comparative Example 2)
Grinding was carried out in the same manner as in Comparative Example 1 except that a diamond pad with a fixed grinding grain density of 30 (pieces / mm 2 ) was used for the total fixed abrasive grains (in this example, only diamond abrasive grains). A glass substrate for a magnetic disk was produced.
上記実施例および比較例において、研削加工後のガラス基板について、フラットネステスターを用いて、平坦度の測定を行い、所定の基準(3μm以下)を良品とし、この基準を満たさないガラス基板の発生率(平坦度不良率)を算出し、結果を表1に示した。また、研削加工時の加工速度(比較例1に対する加工速度比)についても併せて表1に示した。 In each of the above Examples and Comparative Examples, the main surface grinding was performed continuously for 100 batches, 100 batches in total.
In the above examples and comparative examples, the flatness of the glass substrate after grinding is measured using a flat nesting tester, and a predetermined standard (3 μm or less) is determined as a non-defective product. The rate (flatness defect rate) was calculated, and the results are shown in Table 1. Table 1 also shows the processing speed during grinding (processing speed ratio with respect to Comparative Example 1).
1.従来のダイヤモンド集結砥粒だけを含む研削工具(ダイヤモンドパッド)を用いた比較例1では、100バッチの連続加工を行うと、加工速度と加工品質が低下し、安定した研削加工が行えない。
これに対して、アルミナ粒子凝集体もしくはガラス分散粒、或いはアルミナ粒子凝集体とガラス分散粒の両者をダイヤモンド集結砥粒とともに分散させた研削工具を用いた実施例1~3では、加工速度と加工品質(特に基板の平坦度)の両立を図り、安定した加工速度で良好な加工品質が長期間安定して得られる。特に、ダイヤモンド集結砥粒とガラス分散粒を併用した実施例2では、平坦度不良率がゼロ%であった。
また、比較例1、2の比較より、従来のダイヤモンドパッドにおいて固定砥粒の研削面密度を低下させると、加工速度は向上するものの平坦度不良率が悪化してしまうことがわかる。これは、単純に固定砥粒密度を下げるだけでは安定した加工ができないことを示している。 From the results in Table 1, the following can be understood.
1. In Comparative Example 1 using a conventional grinding tool (diamond pad) containing only diamond concentrating abrasive grains, when 100 batches are continuously processed, the processing speed and processing quality are lowered, and stable grinding cannot be performed.
On the other hand, in Examples 1 to 3 using the grinding tool in which the alumina particle aggregate or the glass dispersed particle, or both the alumina particle aggregate and the glass dispersed particle are dispersed together with the diamond concentrating abrasive grains, the processing speed and the processing are performed. Good quality (particularly the flatness of the substrate) can be achieved, and good processing quality can be stably obtained over a long period of time at a stable processing speed. In particular, in Example 2 in which diamond concentration abrasive grains and glass dispersion grains were used in combination, the flatness failure rate was zero%.
Further, it can be seen from the comparison between Comparative Examples 1 and 2 that when the grinding surface density of the fixed abrasive grains is decreased in the conventional diamond pad, the flatness defect rate is deteriorated although the processing speed is improved. This shows that stable processing cannot be achieved simply by lowering the fixed abrasive density.
上記実施例1で得られた磁気ディスク用ガラス基板に以下の成膜工程を施して、垂直磁気記録用磁気ディスクを得た。
すなわち、上記ガラス基板上に、Ti系合金薄膜からなる付着層、CoTaZr合金薄膜からなる軟磁性層、Ru薄膜からなる下地層、CoCrPt合金からなる垂直磁気記録層、保護層、潤滑層を順次成膜した。保護層は、水素化カーボン層を成膜した。また、潤滑層は、アルコール変性パーフルオロポリエーテルの液体潤滑剤をディップ法により形成した。
得られた磁気ディスクについて、DFHヘッドを備えたHDDに組み込み、80℃かつ80%RHの高温高湿環境下においてDFH機能を作動させつつ1ヶ月間のロードアンロード耐久性試験を行ったところ、特に障害も無く、良好な結果が得られた。 (Manufacture of magnetic disk)
The following film formation process was performed on the magnetic disk glass substrate obtained in Example 1 to obtain a magnetic disk for perpendicular magnetic recording.
That is, an adhesion layer made of a Ti-based alloy thin film, a soft magnetic layer made of a CoTaZr alloy thin film, an underlayer made of a Ru thin film, a perpendicular magnetic recording layer made of a CoCrPt alloy, a protective layer, and a lubricating layer are sequentially formed on the glass substrate. Filmed. As the protective layer, a hydrogenated carbon layer was formed. The lubricating layer was formed by dipping a liquid lubricant of alcohol-modified perfluoropolyether.
The obtained magnetic disk was installed in an HDD equipped with a DFH head, and a load / unload durability test was conducted for one month while operating the DFH function in a high temperature and high humidity environment of 80 ° C. and 80% RH. There were no particular obstacles and good results were obtained.
2 シート
3 集結砥粒
4 ペレット
5 ダイヤモンド粒子
10 ガラス基板
1 Diamond Pad 2
Claims (10)
- ガラス基板の主表面を研削する研削処理を含む磁気ディスク用ガラス基板の製造方法であって、
前記研削処理では、研削砥粒と、該研削砥粒を結合する結合材と、該結合材よりも硬く、且つ前記研削砥粒よりも柔らかい分散粒とを備え、前記結合材中に前記研削砥粒と前記分散粒とが分散された状態で結合されている研削工具を用いて、ガラス基板主表面の研削を行うことを特徴とする磁気ディスク用ガラス基板の製造方法。 A method of manufacturing a glass substrate for a magnetic disk including a grinding process for grinding a main surface of a glass substrate,
The grinding process includes grinding abrasive grains, a binder that bonds the abrasive grains, and dispersed grains that are harder than the binder and softer than the abrasive grains. A method for producing a glass substrate for a magnetic disk, comprising grinding a main surface of a glass substrate using a grinding tool in which grains and the dispersed grains are bonded in a dispersed state. - 前記結合材は、樹脂材料であることを特徴とする請求項1に記載の磁気ディスク用ガラス基板の製造方法。 2. The method for manufacturing a glass substrate for a magnetic disk according to claim 1, wherein the binder is a resin material.
- 前記研削砥粒は、複数の研削砥粒が固定材で結合された集結砥粒であることを特徴とする請求項1又は2に記載の磁気ディスク用ガラス基板の製造方法。 3. The method for producing a glass substrate for a magnetic disk according to claim 1, wherein the abrasive grains are concentrated abrasive grains in which a plurality of abrasive grains are bonded with a fixing material.
- 前記研削砥粒は、ダイヤモンド砥粒を含むことを特徴とする請求項1乃至3のいずれかに記載の磁気ディスク用ガラス基板の製造方法。 4. The method for producing a glass substrate for a magnetic disk according to claim 1, wherein the grinding abrasive grains include diamond abrasive grains.
- 前記分散粒は、アルミナ又はジルコニアからなることを特徴とする請求項1乃至4のいずれかに記載の磁気ディスク用ガラス基板の製造方法。 5. The method for producing a glass substrate for a magnetic disk according to claim 1, wherein the dispersed particles are made of alumina or zirconia.
- 前記分散粒は、研削するガラスよりも柔らかいガラスからなることを特徴とする請求項1乃至4のいずれかに記載の磁気ディスク用ガラス基板の製造方法。 5. The method for manufacturing a glass substrate for a magnetic disk according to claim 1, wherein the dispersed particles are made of glass softer than glass to be ground.
- 前記分散粒は、複数の分散粒が、研削するガラスよりも柔らかいガラスで結合された凝集体であることを特徴とする請求項1乃至4のいずれかに記載の磁気ディスク用ガラス基板の製造方法。 5. The method of manufacturing a glass substrate for a magnetic disk according to claim 1, wherein the dispersed particles are aggregates in which a plurality of dispersed particles are bonded with glass softer than glass to be ground. .
- 前記結合材中の前記研削砥粒に対する前記分散粒の比率が、0.1~5倍の範囲であることを特徴とする請求項1乃至7のいずれかに記載の磁気ディスク用ガラス基板の製造方法。 The production of a glass substrate for a magnetic disk according to any one of claims 1 to 7, wherein a ratio of the dispersed grains to the abrasive grains in the binder is in a range of 0.1 to 5 times. Method.
- 請求項1乃至8のいずれかに記載の磁気ディスク用ガラス基板の製造方法により製造された磁気ディスク用ガラス基板上に、少なくとも磁気記録層を形成することを特徴とする磁気ディスクの製造方法。 A method for producing a magnetic disk, comprising forming at least a magnetic recording layer on the glass substrate for a magnetic disk produced by the method for producing a glass substrate for a magnetic disk according to any one of claims 1 to 8.
- 電子デバイス用のガラス基板表面を研削する研削工具であって、
研削砥粒と、該研削砥粒を結合する結合材と、該結合材よりも硬く、且つ前記研削砥粒よりも柔らかい分散粒とを備え、前記結合材中に前記研削砥粒と前記分散粒とが分散された状態で結合されていることを特徴とする研削工具。
A grinding tool for grinding a glass substrate surface for an electronic device,
Grinding abrasive grains, a binder for bonding the abrasive grains, and dispersed grains that are harder than the binder and softer than the abrasive grains, and the abrasive grains and the dispersed grains in the binder And a grinding tool characterized by being combined in a dispersed state.
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JP2015539444A JP6313314B2 (en) | 2013-09-28 | 2014-09-29 | Manufacturing method of glass substrate for magnetic disk, manufacturing method of glass substrate, manufacturing method of magnetic disk, and grinding tool |
CN201480053014.8A CN105579198B (en) | 2013-09-28 | 2014-09-29 | The manufacture method of glass substrate for disc and the manufacture method of disk and grinding tool |
SG11201602379QA SG11201602379QA (en) | 2013-09-28 | 2014-09-29 | Method for manufacturing magnetic-disk glass substrate, methodfor manufacturing magnetic disk, and grinding tool |
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CN (2) | CN108447507B (en) |
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Cited By (3)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
WO2016181751A1 (en) * | 2015-05-13 | 2016-11-17 | バンドー化学株式会社 | Polishing pad and method for manufacturing polishing pad |
WO2017119342A1 (en) * | 2016-01-06 | 2017-07-13 | バンドー化学株式会社 | Polishing material |
JP2020099954A (en) * | 2018-12-20 | 2020-07-02 | 本田技研工業株式会社 | Vitrified grindstone and method for manufacture thereof |
Families Citing this family (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
SG10202006113YA (en) * | 2013-09-28 | 2020-07-29 | Hoya Corp | Grinding tool, method for manufacturing glass substrate, method for manufacturing magnetic-disk glass substrate, and method for manufacturing magnetic disk |
US10783921B2 (en) | 2017-09-29 | 2020-09-22 | Hoya Corporation | Glass spacer and hard disk drive apparatus |
Citations (3)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JP2002542057A (en) * | 1999-04-23 | 2002-12-10 | スリーエム イノベイティブ プロパティズ カンパニー | Abrasive articles suitable for polishing glass and glass-ceramic workpieces |
JP2005202997A (en) * | 2004-01-13 | 2005-07-28 | Hoya Corp | Manufacturing method of glass substrate for magnetic disk, and manufacturing method of magnetic disk |
JP2009072832A (en) * | 2007-09-18 | 2009-04-09 | Bando Chem Ind Ltd | Polishing sheet and method for production thereof |
Family Cites Families (15)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
EP0403592A1 (en) * | 1988-06-30 | 1990-12-27 | MITCHELL, Richard, J | Abrasive product with reduced particle concentration |
JPH0761615B2 (en) * | 1992-09-28 | 1995-07-05 | 東芝タンガロイ株式会社 | Coated high hardness powder and method for producing the same |
JP4099291B2 (en) * | 1999-06-23 | 2008-06-11 | Hoya株式会社 | Manufacturing method of glass substrate for magnetic disk |
JP2001138244A (en) * | 1999-08-17 | 2001-05-22 | Mitsubishi Materials Corp | Resin bond type grinding wheel |
EP1276593B1 (en) * | 2000-04-28 | 2005-08-17 | 3M Innovative Properties Company | Abrasive article and methods for grinding glass |
TW200734120A (en) * | 2005-12-06 | 2007-09-16 | Disco Corp | Polishing grindstone and method for producing same |
JP2012064295A (en) * | 2009-11-10 | 2012-03-29 | Showa Denko Kk | Method for manufacturing glass substrate for magnetic recording medium |
CN102656632B (en) * | 2009-12-29 | 2016-08-31 | Hoya株式会社 | The manufacture method of glass substrate for disc and glass substrate for disc |
JP5585269B2 (en) * | 2010-07-22 | 2014-09-10 | 旭硝子株式会社 | Method for manufacturing glass substrate for magnetic recording medium |
JP2012169024A (en) * | 2011-02-16 | 2012-09-06 | Showa Denko Kk | Method for manufacturing glass substrate for magnetic recording medium |
JP5906823B2 (en) * | 2011-03-15 | 2016-04-20 | 旭硝子株式会社 | Method for manufacturing glass substrate for magnetic recording medium |
JP2013012280A (en) * | 2011-06-30 | 2013-01-17 | Konica Minolta Advanced Layers Inc | Method for manufacturing glass substrate for hdd |
JP5814719B2 (en) * | 2011-09-28 | 2015-11-17 | Hoya株式会社 | Substrate manufacturing method, mask blank manufacturing method, transfer mask manufacturing method, and correction carrier |
CN103182659A (en) * | 2011-12-30 | 2013-07-03 | 财团法人金属工业研究发展中心 | Grinding tool and manufacturing method thereof |
SG10202006113YA (en) * | 2013-09-28 | 2020-07-29 | Hoya Corp | Grinding tool, method for manufacturing glass substrate, method for manufacturing magnetic-disk glass substrate, and method for manufacturing magnetic disk |
-
2014
- 2014-09-29 SG SG10202006113YA patent/SG10202006113YA/en unknown
- 2014-09-29 CN CN201810239795.XA patent/CN108447507B/en active Active
- 2014-09-29 CN CN201480053014.8A patent/CN105579198B/en active Active
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- 2014-09-29 SG SG11201602379QA patent/SG11201602379QA/en unknown
-
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- 2018-01-16 JP JP2018004802A patent/JP6490842B2/en active Active
Patent Citations (3)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JP2002542057A (en) * | 1999-04-23 | 2002-12-10 | スリーエム イノベイティブ プロパティズ カンパニー | Abrasive articles suitable for polishing glass and glass-ceramic workpieces |
JP2005202997A (en) * | 2004-01-13 | 2005-07-28 | Hoya Corp | Manufacturing method of glass substrate for magnetic disk, and manufacturing method of magnetic disk |
JP2009072832A (en) * | 2007-09-18 | 2009-04-09 | Bando Chem Ind Ltd | Polishing sheet and method for production thereof |
Cited By (6)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
WO2016181751A1 (en) * | 2015-05-13 | 2016-11-17 | バンドー化学株式会社 | Polishing pad and method for manufacturing polishing pad |
JP6046865B1 (en) * | 2015-05-13 | 2016-12-21 | バンドー化学株式会社 | Polishing pad and polishing pad manufacturing method |
WO2017119342A1 (en) * | 2016-01-06 | 2017-07-13 | バンドー化学株式会社 | Polishing material |
JPWO2017119342A1 (en) * | 2016-01-06 | 2018-01-11 | バンドー化学株式会社 | Abrasive |
JP2020099954A (en) * | 2018-12-20 | 2020-07-02 | 本田技研工業株式会社 | Vitrified grindstone and method for manufacture thereof |
JP7023829B2 (en) | 2018-12-20 | 2022-02-22 | 本田技研工業株式会社 | Vitrified grindstone and its manufacturing method |
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MY176672A (en) | 2020-08-19 |
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