WO2014200328A1 - A method for forming silicon grass - Google Patents

A method for forming silicon grass Download PDF

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Publication number
WO2014200328A1
WO2014200328A1 PCT/MY2014/000095 MY2014000095W WO2014200328A1 WO 2014200328 A1 WO2014200328 A1 WO 2014200328A1 MY 2014000095 W MY2014000095 W MY 2014000095W WO 2014200328 A1 WO2014200328 A1 WO 2014200328A1
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WO
WIPO (PCT)
Prior art keywords
silicon
forming
present
grass
etching
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Ceased
Application number
PCT/MY2014/000095
Other languages
French (fr)
Inventor
Buyong Muhamad Ramdzan
Mohd Zain Azlina
Arifin FADZILAH
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Mimos Bhd
Original Assignee
Mimos Bhd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Mimos Bhd filed Critical Mimos Bhd
Publication of WO2014200328A1 publication Critical patent/WO2014200328A1/en
Anticipated expiration legal-status Critical
Ceased legal-status Critical Current

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Classifications

    • BPERFORMING OPERATIONS; TRANSPORTING
    • B81MICROSTRUCTURAL TECHNOLOGY
    • B81CPROCESSES OR APPARATUS SPECIALLY ADAPTED FOR THE MANUFACTURE OR TREATMENT OF MICROSTRUCTURAL DEVICES OR SYSTEMS
    • B81C1/00Manufacture or treatment of devices or systems in or on a substrate
    • B81C1/00015Manufacture or treatment of devices or systems in or on a substrate for manufacturing microsystems
    • B81C1/00023Manufacture or treatment of devices or systems in or on a substrate for manufacturing microsystems without movable or flexible elements
    • B81C1/00031Regular or irregular arrays of nanoscale structures, e.g. etch mask layer
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B81MICROSTRUCTURAL TECHNOLOGY
    • B81BMICROSTRUCTURAL DEVICES OR SYSTEMS, e.g. MICROMECHANICAL DEVICES
    • B81B2203/00Basic microelectromechanical structures
    • B81B2203/01Suspended structures, i.e. structures allowing a movement
    • B81B2203/0127Diaphragms, i.e. structures separating two media that can control the passage from one medium to another; Membranes, i.e. diaphragms with filtering function
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B81MICROSTRUCTURAL TECHNOLOGY
    • B81BMICROSTRUCTURAL DEVICES OR SYSTEMS, e.g. MICROMECHANICAL DEVICES
    • B81B2203/00Basic microelectromechanical structures
    • B81B2203/03Static structures
    • B81B2203/0361Tips, pillars
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B81MICROSTRUCTURAL TECHNOLOGY
    • B81CPROCESSES OR APPARATUS SPECIALLY ADAPTED FOR THE MANUFACTURE OR TREATMENT OF MICROSTRUCTURAL DEVICES OR SYSTEMS
    • B81C2201/00Manufacture or treatment of microstructural devices or systems
    • B81C2201/01Manufacture or treatment of microstructural devices or systems in or on a substrate
    • B81C2201/0101Shaping material; Structuring the bulk substrate or layers on the substrate; Film patterning
    • B81C2201/0128Processes for removing material
    • B81C2201/013Etching
    • B81C2201/0132Dry etching, i.e. plasma etching, barrel etching, reactive ion etching [RIE], sputter etching or ion milling

Definitions

  • the present invention relates to a method for forming a silicon grass structure which its application is in sensor technology
  • sensing membrane One of the most important feature in a sensor is a sensing membrane.
  • the ensing membran is fabricated in a form of fiat surface.
  • the flat surface structure of a sensing membrane is limiting the reactivity of tons that would cause no enough surface potential for the sensor device to property function. This would affect, the performance of the sensor.
  • a method for forming a silicon sensing membrane such as inUS 20!0/lK ⁇ 92888.
  • process for etching a silicon-containing substrate to form structures is provided, in the process, a metal is deposited and patterned onto a silicon-containing substrate (commonly one with a resistivity above 1-10 ohm-em) in such a way that the metal is present and touches silicon where etching is desired and is blocked from touching silicon or not present elsewhere.
  • the metallized substrate is submerged into an etchant aqueous solution comprising about 4 to about 49 weight percent HP and an oxidizing agent such as about 0,5 to about 30 weight percent H.sub,20.sub.2, thus producing a metallized substrate with one or more trenches.
  • a second silicon etch is optionally employed t remove nanowires inside the one or more trenches.
  • the present invention pro- videsmethod for forming Si grass structure comprising;formtng a silicon well ( 100); etching the silicon well to form silicon grass structure (200); characterised in that the step of forming silicon well ⁇ 100) is conducted using a standard deep reactive ion etching Bosch process using photoresist as the masking material.
  • the above provision is advantageous as the present invention provides more surface area of the sensing material, thus increasing the performance of the sensor.
  • the method tor forming the silicon, grass structure is invented using inductivel coupled plasma (ICP) deep reactive ion etching (DRIE) process chamber, it was found that the diameter and height of silicon grass re controllable by varying the wafer chuck silicon temperature process parameter.
  • Bosch process is one type of silicon etching technology for high-aspect

Landscapes

  • Engineering & Computer Science (AREA)
  • Chemical & Material Sciences (AREA)
  • Manufacturing & Machinery (AREA)
  • Nanotechnology (AREA)
  • Analytical Chemistry (AREA)
  • Microelectronics & Electronic Packaging (AREA)
  • Pressure Sensors (AREA)

Abstract

The present invention relates to a method for forming Si grass structure comprising: forming a silicon well (100); and etching the silicon well to form silicon grass structure (200); characterized in that the step of forming silicon well (100) is conducted using a standard deep reactive ion etching Bosch process using photoresist as the masking material. The present invention provides more surface area of the sensing membrane thus increasing the performance of a sensor.

Description

Description
Title of Invention: A METHOD FOE FORMING SILICON GRASS
[ 1 ] FIELD OF INVENTION
f 2] The present invention relates to a method for forming a silicon grass structure which its application is in sensor technology,
1.31 BACKGROUND OF THE INVENTION
(41 One of the most important feature in a sensor is a sensing membrane. Currently, the ensing membran is fabricated in a form of fiat surface. The flat surface structure of a sensing membrane is limiting the reactivity of tons that would cause no enough surface potential for the sensor device to property function. This would affect, the performance of the sensor. While many had invented a method for forming a silicon sensing membrane such as inUS 20!0/lK}92888. which construes : process for etching a silicon-containing substrate to form structures is provided, in the process, a metal is deposited and patterned onto a silicon-containing substrate (commonly one with a resistivity above 1-10 ohm-em) in such a way that the metal is present and touches silicon where etching is desired and is blocked from touching silicon or not present elsewhere. The metallized substrate is submerged into an etchant aqueous solution comprising about 4 to about 49 weight percent HP and an oxidizing agent such as about 0,5 to about 30 weight percent H.sub,20.sub.2, thus producing a metallized substrate with one or more trenches. A second silicon etch is optionally employed t remove nanowires inside the one or more trenches.
[5 J However, the prior art still could not solve the above problem which isrelaied to low sttrface-area- o-volnme ratio of the sensing material structure,
[6] Therefore it is a need for an invention thai can overcome the above mentioned
problem.
[7] SUMMARY OF THE INVENTION
[8] According to an aspect of the present invention, the present invention pro- videsmethod for forming Si grass structure comprising;formtng a silicon well ( 100); etching the silicon well to form silicon grass structure (200); characterised in that the step of forming silicon well { 100) is conducted using a standard deep reactive ion etching Bosch process using photoresist as the masking material. The above provision is advantageous as the present invention provides more surface area of the sensing material, thus increasing the performance of the sensor. The method tor forming the silicon, grass structure is invented using inductivel coupled plasma (ICP) deep reactive ion etching (DRIE) process chamber, it was found that the diameter and height of silicon grass re controllable by varying the wafer chuck silicon temperature process parameter. Bosch process is one type of silicon etching technology for high-aspect
Figure imgf000004_0001
Figure imgf000005_0002
Figure imgf000005_0001
Figure imgf000006_0001
Figure imgf000007_0001
Figure imgf000008_0001

Claims

Figure imgf000009_0001
flow rate of 8 to 10 seem; wherein the silicon s at 0°C below pressure of 4 to 5 Pa for a predetermined time.
(Claim 8] A method for forming S grass structure as claimed in Claim 5. wherein the third sequential etching and passi ation (205) further comprising: exposing the silicon to SPft plasma for one seconds at flow rate of 200 to 250secni;
exposing the silicon to a mixture of CJP* and 0:> plasma for three seconds, with the€4F¾ at. a flow rate of 120 to 150 seem and the 0; at a flow rate of 8 to 10 seem; whereto the silicon at -4 to -5 'C below pressure of 4 to 5 Fa for a predetermined time.
PCT/MY2014/000095 2013-06-13 2014-05-02 A method for forming silicon grass Ceased WO2014200328A1 (en)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
MYPI2013002176 2013-06-13
MYPI2013002176 2013-06-13

Publications (1)

Publication Number Publication Date
WO2014200328A1 true WO2014200328A1 (en) 2014-12-18

Family

ID=51300799

Family Applications (1)

Application Number Title Priority Date Filing Date
PCT/MY2014/000095 Ceased WO2014200328A1 (en) 2013-06-13 2014-05-02 A method for forming silicon grass

Country Status (1)

Country Link
WO (1) WO2014200328A1 (en)

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN105384145A (en) * 2015-11-19 2016-03-09 中国科学院微电子研究所 An embedded nano-forest structure and its preparation method

Non-Patent Citations (2)

* Cited by examiner, † Cited by third party
Title
CRAIGIE C J D ET AL: "Polymer thickness effects on Bosch etch profiles", JOURNAL OF VACUUM SCIENCE AND TECHNOLOGY: PART B, AVS / AIP, MELVILLE, NEW YORK, NY, US, vol. 20, no. 6, 1 November 2002 (2002-11-01), pages 2229 - 2232, XP012009536, ISSN: 1071-1023, DOI: 10.1116/1.1515910 *
JUNG KYUBONG ET AL: "Parameter study for silicon grass formation in Bosch process", JOURNAL OF VACUUM SCIENCE AND TECHNOLOGY: PART B, AVS / AIP, MELVILLE, NEW YORK, NY, US, vol. 28, no. 1, 15 January 2010 (2010-01-15), pages 143 - 148, XP012143916, ISSN: 1071-1023, DOI: 10.1116/1.3280131 *

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN105384145A (en) * 2015-11-19 2016-03-09 中国科学院微电子研究所 An embedded nano-forest structure and its preparation method

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