WO2014141698A1

WO2014141698A1 - Liquid treatment method and liquid treatment device used therein

Info

Publication number: WO2014141698A1
Application number: PCT/JP2014/001381
Authority: WO
Inventors: 晶義枝川; 山本　寛; 秀基永岡; 英典船越; 拓也小棚木; 隆司榊原
Original assignee: パナソニック株式会社
Priority date: 2013-03-12
Filing date: 2014-03-11
Publication date: 2014-09-18
Also published as: JP2014172021A; US9522829B2; KR101764520B1; JP6150105B2; KR20150119192A; CN105189367A; US20160039689A1

Abstract

Provided are a novel treatment method and treatment device for a liquid, capable of using concentrate recovered using centrifugal separation as ballast water. The present invention relates to a liquid treatment method having a storage step including physical treatment using centrifugal force for supplied liquid supplied to a storage means in a casing, the liquid treatment method comprising inactivating aquatic organisms in the concentrate obtained by the physical treatment using centrifugal force, and supplying the concentrate having undergone inactivation treatment to the storage means.

Description

Liquid processing method and liquid processing apparatus used therefor

The present disclosure relates to a liquid processing method and a liquid processing apparatus used therefor.

In ships such as tankers and large cargo ships, when navigating in a state where oil or cargo is not loaded or in a small amount, the ballast water is usually placed in the ballast tank to ensure the stability and balance of the ship. Contained and sailed. This ballast water is usually pumped and injected into seawater at the port where it is unloaded and discharged at the port where it was loaded. In this way, ballast water uses the seawater of the port where it was unloaded, so the ballast water contains aquatic microorganisms that inhabit the area around the port where it was unloaded. Is done. For this reason, when ballast water is injected into a ship, for example, a foreign substance contained in the taken-in liquid is separated and removed using a centrifugal separation method (for example, Patent Document 1).

JP 2007-90144 A

濃縮 Concentrated liquid containing foreign substances separated by the centrifugal separation method is collected and usually discharged appropriately out of the ship. However, the collected concentrated liquid contains not only foreign substances but also moisture. That is, the moisture contained in the concentrate is discharged outside the ship without being used as ballast water even though it has been taken into the ship. On the other hand, if the concentrated liquid can be used as ballast water without being discharged to the outside, it is expected that the storage efficiency of the ballast water can be improved. Therefore, a new liquid processing method and apparatus capable of using the concentrated liquid recovered by the centrifugal separation method as ballast water are provided.

In one or a plurality of aspects, the present disclosure is a liquid processing method including a storage process including performing a physical process using a centrifugal force on a supply liquid supplied to a storage unit in a housing, and the centrifugation A liquid comprising: deactivating aquatic organisms in a concentrated liquid obtained by physical treatment using force, and supplying the concentrated liquid subjected to the deactivating process to the storage means. It relates to the processing method.

Further, in one or a plurality of aspects, the present disclosure provides physical means for performing physical treatment using centrifugal force on a supply liquid supplied to a storage means in a housing, and a concentrated liquid obtained by the physical treatment. It is related with the processing apparatus of the liquid provided with the collection | recovery means which collects, and the supply means which supplies the substance which inactivates aquatic organisms to the said collection | recovery means.

According to the present disclosure, since the concentrated liquid normally discharged out of the ship during ballasting can be used as ballast water, for example, the storage efficiency of ballast water can be improved.

FIG. 1 is a schematic configuration diagram used for explaining the ballast water treatment method in the first embodiment. FIG. 2 is a schematic configuration diagram used for explaining the ballast water treatment method according to the second embodiment. FIG. 3 is a schematic configuration diagram used for explaining the ballast water treatment method according to the third embodiment. FIG. 4 is a schematic configuration diagram used for explaining the ballast water treatment method in the fourth embodiment. FIG. 5 is a schematic configuration diagram used for explaining the ballast water treatment method in the fifth embodiment.

The present disclosure may relate to one or more of the following embodiments.
[1] A liquid processing method including a storage step including performing a physical process using centrifugal force on a supply liquid supplied to a storage unit in a housing,
Performing inactivation treatment of aquatic organisms in the concentrate obtained by physical treatment using the centrifugal force, and supplying the concentrate subjected to the inactivation treatment to the storage means. A liquid processing method.
[2] The treatment method according to [1], wherein the inactivation treatment includes mixing a substance that inactivates aquatic organisms with the concentrate.
[3] The processing method according to [2], wherein the supply liquid is seawater, and the inactivating substance is fresh water.
[4] The processing method according to [2], wherein the inactivating substance is a chlorine-containing substance.
[5] The processing method according to [4], comprising electrolyzing the supply liquid and / or the concentrated liquid to produce the chlorine-containing substance.
[6] Physical means for performing physical treatment using centrifugal force on the supply liquid supplied to the storage means in the housing;
A recovery means for recovering the concentrate obtained by the physical treatment;
A liquid processing apparatus comprising: supply means for supplying a substance that inactivates aquatic organisms to the recovery means.

The “casing” in the present disclosure includes, in particular, one or a plurality of embodiments that are not particularly limited, such as a ship, and preferably a general ship including a ballast tank. General ships equipped with a ballast tank include, but are not limited to, a container ship, a low-low ship, a tanker, a bulk carrier, a chemical ship, and an automobile carrier in one or more embodiments. The “storage means in the housing” in the present disclosure is not particularly limited as long as it is disposed in the housing and can store at least liquid. In one or a plurality of embodiments, a ballast tank, a bilge tank, and the like can be given. It is done.

The “supply liquid supplied to the storage means” in the present disclosure is a liquid that is taken from outside the housing and supplied to the storage means in one or a plurality of embodiments that are not particularly limited, and is stored in the ballast tank as ballast water. Liquid to be used. Examples of the liquid taken from the outside of the casing include seawater, brackish water, and fresh water in one or more embodiments that are not particularly limited. The “reserving step” in the present disclosure refers to a step of storing a liquid in the storing means in the housing in one or a plurality of embodiments.

In one or a plurality of embodiments, the “aquatic organism” in the present disclosure includes microorganisms that inhabit the sea, rivers, lakes, and the like, and in addition, yeast, mold, plant or zooplankton, plankton eggs, Includes relatively small-sized aquatic organisms such as spores, bacteria, fungi, viruses, algae, shellfish larvae such as snails and bivalves, and crustacean larvae such as crabs. Further, it may include microorganisms that can live in estuaries, rivers, canals and the like connected to the sea, and the aquatic organisms described above.

In the present disclosure, “physical treatment using centrifugal force” is not particularly limited, and in one or more embodiments, at least a part of aquatic organisms in the supply liquid is separated or collected from the supply liquid using centrifugal force. And recovering a concentrate containing separated or collected aquatic organisms. In one or a plurality of embodiments, the physical treatment using centrifugal force is to stir the feed solution using centrifugal force and to separate the feed solution into a supernatant and a concentrated solution using centrifugal force. Etc. The stirring of the supply liquid using centrifugal force can be performed using a line mixer in one or a plurality of embodiments. In one or a plurality of embodiments, separation of the supply liquid using centrifugal force can be performed using a hydrocyclone. In one or a plurality of embodiments, the “supernatant” in the present disclosure refers to a separation liquid having a low solid content concentration among separation liquids obtained by separating a supply liquid using centrifugal force. . In one or a plurality of embodiments, the “concentrated liquid” in the present disclosure is a separated liquid having a solid content concentration higher than that of a supernatant liquid among the separated liquids obtained by separating a supply liquid using centrifugal force. Say. In one or a plurality of embodiments, the solid content includes an aquatic organism having a shell and a shell height of 50 μm or more, and / or a shell having an aspect ratio (shell length / shell height) of 0.1 to 10. Examples include aquatic organisms and scales.

In one or a plurality of embodiments, as the “inactivation treatment of aquatic organisms” in the present disclosure, at least a part of aquatic organisms in a concentrated liquid obtained by physical treatment using centrifugal force is destroyed, killed, It refers to killing, killing, or sterilizing, preferably destroying, killing, killing, or sterilizing using a substance that inactivates at least a part of aquatic organisms in the concentrate. In one or a plurality of non-limiting embodiments, the aquatic organism inactivation treatment includes mixing a substance that inactivates aquatic organisms with the concentrate, or a substance that inactivates the aquatic organisms by electrolyzing the concentrate. Can be generated, and the concentrated solution can be irradiated with ultraviolet rays. In the present disclosure, “a substance that inactivates aquatic organisms” (hereinafter, also referred to as “inactivation substance”) includes, in one or more embodiments, fresh water, hydrogen peroxide, ozone, a chlorine-containing substance, and activity. Examples include oxygen species. When the supply liquid supplied to the storage means is seawater, it is preferable that the inactivating substance is fresh water from the viewpoint that corrosion of piping and the like accompanying the inactivation treatment can be reduced. As fresh water, for example, the salt concentration is less than 0.05%, and demineralized water can be included. Examples of fresh water include drinking water, fresh water, and industrial water in one or more embodiments. Examples of the chlorine-containing substance include hypochlorous acid, chlorous acid, chloric acid, substances containing these ions and salts, and the like in one or a plurality of embodiments.

Hereinafter, the present disclosure will be described in detail with reference to preferred embodiments. However, the present disclosure is not limited to the embodiment described below.

(Embodiment 1)
FIG. 1 is a schematic diagram for explaining a liquid processing method according to Embodiment 1 of the present disclosure. The liquid treatment method according to Embodiment 1 of the present disclosure is a method of performing inactivation treatment of marine organisms in a concentrated solution using drinking water, in which the supply liquid is seawater, the inactivating substance is drinking water. It is one embodiment.

As shown in FIG. 1, the processing apparatus used in the liquid processing method of Embodiment 1 includes an electrolysis apparatus 2, a centrifugal separator 3, and a concentrated liquid storage tank 4 that stores a concentrated liquid recovered from the centrifugal apparatus 3. Is provided. The electrolyzer 2 has one end connected to the ballast pump P <b> 1 and the other end connected to the ballast tank 5 via the centrifugal separator 3. The concentrate storage tank 4 has one end connected to the centrifugal separator 3 and the other end connected to the ballast tank 5 via a pump. In addition, a drinking water tank 6 in which drinking water that is an inactivating substance is stored is connected to the concentrate storage tank 4 via an infusion pump.

The electrolysis apparatus 2 includes an electrolytic cell connected to the power supply apparatus 7 in one or a plurality of embodiments that are not particularly limited. In one or a plurality of embodiments that are not particularly limited, the electrolytic cell is provided with a plurality of electrodes (for example, an anode and a cathode), the electrodes are electrically connected to a power supply device, and are supplied with a DC voltage to be electrically connected. It is configured to be decomposed. The shape of the electrode is not particularly limited, and may be any of a rectangular shape, a circular shape, a rod shape, and the like, and the electrode surface may be a flat plate shape or a net shape. The electrode material is not particularly limited, but titanium and stainless steel are preferable. In one or more embodiments that are not particularly limited, the anode is preferably coated with a platinum-based metal composite alloy. The interelectrode voltage in the electrolyzer 2 is not particularly limited, and in one or more embodiments, the interelectrode voltage per 1 m ^{2 of} electrode area is 5 to 500V. The electrolysis is preferably performed on the total amount of ballast water (liquid supplied to the ballast tank 5). It is possible to electrolyze a part of ballast water and inject the generated chlorine-containing substance into the remaining ballast water. Therefore, it is necessary to generate a higher concentration of chlorine compounds, and the electrolyzer 2 needs to be circulated and cooled. In addition, an injection device for injecting the remaining ballast water is required separately.

In the liquid processing apparatus shown in FIG. 1, the liquid taken from the outside of the casing is treated with the supernatant liquid and the concentrated liquid by physical processing using centrifugal force by the centrifugal separator 3 after processing by the electrolysis apparatus 2. The supernatant is supplied to the ballast tank 5 and the concentrate is supplied to the concentrate storage tank 4. The concentrated liquid stored in the concentrated liquid storage tank 4 is inactivated by the mixing of drinking water from the drinking water tank 6, and the concentrated liquid subjected to inactivation treatment is the ballast trunk 5. To be supplied. According to the liquid treatment method of Embodiment 1, since drinking water is used as an inactivating substance, marine organisms contained in the concentrated liquid can be killed and inactivated by changes in osmotic pressure or the like. Moreover, since hypochlorous acid is contained in drinking water, in addition to the change in osmotic pressure, an inactivation treatment effect by hypochlorous acid can be expected.

A hypochlorite concentration meter 8 is arranged on the pipe connecting the electrolyzer 2 and the centrifugal separator 3 so that the hypochlorous acid concentration of the liquid in the pipe can be measured. The hypochlorous acid concentration meter 8 is connected to the control unit 9, and based on the hypochlorous acid concentration measured by the hypochlorous acid concentration meter 8, the power supply device 7 connected to the electrolyzer 2 is controlled by the control unit 9. Has been. The drinking water injection pump P2 is controlled by the control unit 9.

The concentrated liquid storage tank 4 may be provided with an air diffusion tube capable of bubbling nitrogen gas or the like from the viewpoint of improving the inactivation treatment efficiency of marine organisms. The concentrated liquid storage tank 4 may be provided with stirring means such as a propeller at the bottom of the tank from the viewpoint of improving the inactivation treatment efficiency of marine organisms.

An embodiment of a liquid (ballast water) processing method using the liquid processing apparatus shown in FIG. 1 will be described.

First, seawater taken from the outside of the enclosure via the sea chest 1 by the ballast pump P1 is introduced into the electrolysis apparatus 2, and the electrolysis of the seawater is performed in the electrolysis apparatus 2. By performing electrolysis, hypochlorous acid is generated in the seawater, and aquatic organisms contained in the seawater are inactivated by hypochlorous acid. The electrolysis may be performed while measuring the concentration of hypochlorous acid in the treated liquid discharged from the electrolysis apparatus 2 by the hypochlorous acid concentration meter 8, or the next in the ballast water in the ballast tank 5. It may be performed while monitoring the concentration of chlorous acid. For example, it is preferable to carry out so that the concentration of hypochlorous acid in the treated liquid discharged from the electrolysis apparatus 2 is 0.1 mg / L or more. From the viewpoint of reduction, it is preferable to carry out so as to be 20 mg / L or less. In one or a plurality of embodiments, mixing of the chlorine-containing substance into the liquid to be treated may include controlling the concentration of the chlorine-containing substance to 0.1 to 20 mg / L. For example, the electrolysis apparatus 2 may be controlled so that the concentration of hypochlorous acid in the ballast water in the ballast tank 5 is 0.1 to 20 mg / L.

Next, the seawater electrolyzed by the electrolyzer 2 is introduced into the centrifuge 3. The centrifugal separator 3 performs agitation / separation using centrifugal force to separate the supernatant and the concentrate, and the supernatant is supplied to the ballast tank 5 and the concentrate is supplied to the concentrate storage tank 4. . By performing physical treatment using centrifugal force, for example, aquatic organisms that are difficult to inactivate by electrolysis using the electrolysis apparatus 2 can be efficiently separated or collected.

In one or a plurality of embodiments that are not particularly limited, the centrifugal separator 3 may be a liquid cyclone. Hereinafter, a case where a liquid cyclone is used will be described as an example. In one or a plurality of embodiments, the maximum processing liquid amount of the hydrocyclone is not particularly limited, but is preferably 1 to 10,000 m ³ / hour, and more preferably from the viewpoint of installation space in the ship. When the processing amount is 10 to 1000 m ³ / hour or more, it is preferable to install a plurality of liquid cyclones in parallel. The casing size of the hydrocyclone is not particularly limited in one or a plurality of embodiments, but the diameter is 0.001 to 0.00 per 1 m ³ / hour of processing liquid from the viewpoint of installation space in the ship. It is preferable that the height is 1 m and the height is 0.003 to 0.3 m. In one or a plurality of embodiments, the difference between the inlet pressure and the outlet pressure of the hydrocyclone (hereinafter referred to as pressure loss) is preferably 0.01 to 1 MPa, and the required head of the pump that sends the feed liquid to the hydrocyclone From this point, it is more preferably 0.01 to 0.1 MPa. In one or a plurality of embodiments, the inlet flow velocity of the hydrocyclone is preferably 0.1 to 100 m from the viewpoint of obtaining sufficient separation performance by centrifugal force and suppressing the necessary pump head due to an increase in pressure loss. / Sec, more preferably 1 to 10 m / sec, still more preferably 1 m / sec or more and less than 10 m / sec. From the viewpoints of suppressing the increase in the amount of the supply liquid for obtaining the necessary amount of the supernatant and suppressing the increase in the pump capacity associated therewith, the amount of the concentrated liquid is preferably 10% or less of the amount of the supply liquid.

In parallel with or independently of the supply of the supernatant from the centrifugal separator 3 to the ballast tank 5, the inactive treatment of marine organisms contained in the concentrate is performed in the concentrate storage tank 4, and the processed concentrate Is supplied to the ballast tank 5. Concentrated liquids include, for example, marine organisms having shells such as shellfish, preferably marine organisms having shells and shell heights of 50 μm or more, and marine organisms having shells with an aspect ratio of 0.1 to 10. Biology etc. may be included. The salinity of seawater is usually 3.1 to 3.8%. For this reason, from the point of efficiently inactivating marine organisms, it is preferable to mix the concentrated solution and drinking water so that the salt concentration of the liquid after mixing is 1.5% or less. Preferably it is 1.0% or less. In addition, in the mixing of the concentrate and the drinking water, the ratio of the concentrate and the drinking water can be appropriately set according to the salt concentration of the concentrate, but as one or more embodiments, the concentration of the concentrate and the drinking water The ratio is preferably 1: 1.06 to 1.53, more preferably 1: 2.1 to 2.8. In addition, it was confirmed that marine organisms contained in the concentrate could be inactivated by setting the ratio of the concentrate to drinking water to be approximately 1: 1.75 (data not shown). In order to improve the efficiency of inactivation treatment of marine organisms, the mixing of concentrate with drinking water changes the salinity of the concentrate abruptly and drastically increases the osmotic pressure of marine organisms contained in the concentrate. It is preferable to carry out such a change.

In the present embodiment, the case where drinking water is used as the inert substance has been described as an example. However, the present embodiment is not limited thereto, and the inert substance is fresh water other than drinking water (for example, industrial water). Etc.). In the present embodiment, the case where the inactivation treatment of marine organisms is performed by adding drinking water to the concentrate storage tank 4 has been described as an example, but the present embodiment is not limited thereto, You may carry out by mixing a concentrate, drinking water, and an in-line mixer etc.

(Embodiment 2)
FIG. 2 is a schematic diagram for explaining a liquid processing method according to the second embodiment of the present disclosure. The liquid treatment method in Embodiment 2 of the present disclosure is an embodiment of a method for performing inactivation treatment of aquatic organisms in a concentrated liquid using hypochlorous acid.

As shown in FIG. 2, the processing apparatus used in the liquid processing method of Embodiment 2 includes a centrifugal separator 3, a concentrated liquid storage tank 4 that stores a concentrated liquid recovered from the centrifugal apparatus 3, and a hypochlorous acid tank. 10. The centrifugal separator 3 has one end connected to the ballast pump P <b> 1 and the other end connected to the ballast tank 5. The concentrate storage tank 4 has one end connected to the centrifugal separator 3 and the other end connected to the ballast tank 5 via a pump. Further, a hypochlorous acid tank 16 in which hypochlorous acid as an inactivating substance is stored is connected to the concentrate storage tank 4 via an injection pump P3. In the processing apparatus of the second embodiment, the same centrifugal separator 3 as that of the first embodiment can be used.

In the liquid processing apparatus shown in FIG. 2, the liquid taken from the outside of the housing is separated into a supernatant and a concentrated liquid by physical processing using centrifugal force by the centrifugal separator 3, and the supernatant is ballasted. The concentrated liquid is supplied to the concentrated liquid storage tank 4 in the tank 5. The concentrated liquid stored in the concentrated liquid storage tank 4 is inactivated by mixing the hypochlorous acid from the hypochlorous acid tank 16 to inactivate aquatic organisms in the concentrated liquid. Is supplied to the ballast trunk 5.

The pipe connecting the concentrate storage tank 4 and the ballast tank 5 is provided with a hypochlorous acid concentration meter 18 so that the concentration of hypochlorous acid in the liquid in the pipe can be measured. The hypochlorous acid concentration meter 18 is connected to the control unit 19, and the hypochlorous acid injection pump P 3 is controlled by the control unit 19 based on the hypochlorous acid concentration measured by the hypochlorous acid concentration meter 18. . The concentrated liquid storage tank 4 may be provided with an air diffusion tube capable of bubbling nitrogen gas or the like from the viewpoint of improving the inactivation processing efficiency of marine organisms.

An embodiment of a liquid (ballast water) treatment method using the liquid treatment apparatus shown in FIG. 2 will be described.

First, the liquid taken from the outside of the housing by the ballast pump P1 is introduced into the centrifugal separator 3 and subjected to agitation / separation using centrifugal force, and separated into a supernatant and a concentrated liquid. The liquid is supplied to the ballast tank 5 and the concentrated liquid is supplied to the concentrated liquid storage tank 4. The processing by the centrifugal separator 3 can be performed in the same manner as in the first embodiment.

In parallel with or independently of the supply of the supernatant from the centrifugal separator 3 to the ballast tank 5, the inactive treatment of marine organisms contained in the concentrate is performed in the concentrate storage tank 4, and the processed concentrate Is supplied to the ballast tank 5. In one or a plurality of embodiments, the mixing of hypochlorous acid with the concentrate is preferably performed so that the concentration of hypochlorous acid in the mixed liquid is 20 mg / L or more, and the inactivation treatment efficiency, Further, from the viewpoint of reducing the influence on the coating of the tank or the like, it is preferable to carry out at 20 to 20000 mg / L. The mixing time of the concentrate and hypochlorous acid is 1 minute to 10 hours, preferably 5 minutes to 5 hours, from the viewpoint of the inactivation treatment efficiency and the size of the concentrate storage tank.

In addition, in FIG. 2, although demonstrated taking the example of the form which supplies the liquid withdrawn from the exterior of the housing | casing to the centrifuge 3 from the ballast pump P1, this embodiment is not limited to this, For example, An electrolysis device may be disposed between the ballast pump P1 and the centrifugal separator 3. Further, instead of the hypochlorous acid tank 16, hypochlorous acid may be generated by an electrolyzer and supplied to the concentrate storage tank 4.

(Embodiment 3)
FIG. 3 is a schematic diagram for explaining a liquid processing method according to Embodiment 3 of the present disclosure. The liquid treatment method according to Embodiment 3 of the present disclosure is an embodiment of a method for performing inactivation treatment of aquatic organisms in a concentrated liquid using hypochlorous acid.

As shown in FIG. 3, in the processing apparatus used in the liquid processing method of Embodiment 3, the pipe connecting the electrolyzer 2 and the centrifugal separator 3 branches, and hypochlorous acid generated by the electrolyzer 2 is removed. The configuration is the same as that of the processing apparatus of the first embodiment except that the concentrate storage tank 4 can be supplied and the concentrate storage tank 4 is not connected to the drinking water tank.

An embodiment of a liquid (ballast water) treatment method using the liquid treatment apparatus shown in FIG. 3 will be described.

First, the liquid taken from the outside of the housing by the ballast pump P1 is introduced into the electrolyzer 2 and seawater is electrolyzed in the electrolyzer 2. The treatment by the electrolyzer 2 can be performed in the same manner as in the first embodiment. Next, the seawater electrolyzed by the electrolyzer 2 is introduced into the centrifuge 3. The processing by the centrifugal separator 3 can be performed in the same manner as in the first embodiment.

In parallel with or independently of the supply of the supernatant from the centrifugal separator 3 to the ballast tank 5, the inactive treatment of marine organisms contained in the concentrate is performed in the concentrate storage tank 4, and the processed concentrate Is supplied to the ballast tank 5. Control from the pipe connecting the electrolyzer 2 and the centrifuge 3 to the concentrate storage tank 4 can be performed using an electric valve, a three-way valve, or the like in one or a plurality of embodiments. In one or a plurality of embodiments, the concentration of hypochlorous acid supplied to the concentrate storage tank 4 is 21 mg / L or more from the viewpoint of reducing the inactivation treatment efficiency and the influence on the coating of the tank and the like. 21 to 21000 mg / L. Moreover, it is preferable to carry out so that the concentration of hypochlorous acid in the concentrated liquid storage tank 4 (concentration after mixing the concentrated liquid and hypochlorous acid) is 20 mg / L or more, and the inactivation treatment efficiency, and From the viewpoint of reducing the influence on the coating of a tank or the like, it is preferable to carry out so as to be 20 to 20000 mg / L. The mixing time of the concentrate and hypochlorous acid is 1 minute to 10 hours, preferably 5 minutes to 5 hours, from the viewpoint of the inactivation treatment efficiency and the size of the concentrate storage tank.

(Embodiment 4)
FIG. 4 is a schematic diagram for explaining a liquid processing method according to Embodiment 4 of the present disclosure. The liquid treatment method in Embodiment 4 of the present disclosure is an embodiment of a method for performing inactivation treatment of aquatic organisms in a concentrated liquid using hypochlorous acid.

As shown in FIG. 4, in the processing apparatus used in the liquid processing method of Embodiment 4, the concentrated liquid is supplied to the electrolysis apparatus 32 instead of the concentrated liquid storage tank 16, and the concentrated liquid is electrolyzed in the electrolysis apparatus 32. It is the same form as the processing apparatus of Embodiment 2 except being inactivated and being inactivated. According to this embodiment, since the concentrated solution is directly electrolyzed to generate hypochlorous acid, the sterilizing ability of aquatic organisms can be further improved, and the inactivation efficiency of the aquatic organisms contained in the concentrated solution can be further increased. Can be improved.

An embodiment of a liquid (ballast water) processing method using the liquid processing apparatus shown in FIG. 4 will be described.

First, the liquid taken from the outside of the housing by the ballast pump P1 is introduced into the centrifugal separator 3 and subjected to agitation / separation using centrifugal force, and separated into a supernatant and a concentrated liquid. The liquid is supplied to the ballast tank 5 and the concentrated liquid is supplied to the electrolyzer 32. The processing by the centrifugal separator 3 can be performed in the same manner as in the first embodiment.

In the electrolyzer 32, the concentrated solution is electrolyzed to generate hypochlorous acid in the concentrated solution to inactivate aquatic organisms. The electrolysis device 32 is connected to a power supply device 37, and the power supply device 37 is controlled by the control unit 39 based on the hypochlorous acid concentration measured by the hypochlorous acid concentration meter 38. In one or a plurality of embodiments, the electrolysis treatment is preferably performed so that the hypochlorous acid concentration is 20 mg / L or more, and the deactivation treatment efficiency and the influence on coating of a tank or the like are reduced. Therefore, it is preferably carried out so as to be 20 to 20000 mg / L. The mixing time of the concentrated solution and hypochlorous acid is 1 minute to 10 hours, preferably 5 minutes to 5 hours, from the viewpoint of inactivation treatment efficiency.

(Embodiment 5)
FIG. 5 is a schematic diagram for explaining a liquid processing method according to the fifth embodiment of the present disclosure. The liquid treatment method according to the fifth embodiment of the present disclosure is one of methods in which the supply water is seawater, the inactivating substance is drinking water, and the aquatic organisms in the concentrated liquid are inactivated using the drinking water. It is an embodiment.

As shown in FIG. 5, the processing apparatus used in the liquid processing method of Embodiment 5 does not include the concentrate storage tank 4, and the configuration is such that the concentrate recovered from the centrifuge 3 is supplied to the ballast tank 5. In addition, the pipe connecting the centrifugal separator 3 and the ballast trunk 5 that connects the centrifugal separator 3 and the ballast tank 5 has a drinking water tank 6 in which drinking water as an inactive substance is stored. Is the same configuration as the processing apparatus of the first embodiment, except that is connected via a pump.

According to the liquid processing method of the fifth embodiment, the drinking water tank 6 is connected to the pipe connected to the centrifugal separator 3, and the drinking water can be directly injected into the pipe. For this reason, since drinking water is injected into the vortex of the concentrated liquid discharged from the centrifugal separator 3, the drinking water is efficiently stirred into the concentrated liquid by the stirring effect of the swirling flow generated in the centrifugal separator 3, Inactivation treatment efficiency can be improved.

Claims

A liquid processing method having a storing step including performing a physical process using centrifugal force on a supply liquid supplied to a storing means in a housing,
Performing inactivation treatment of aquatic organisms in the concentrate obtained by physical treatment using the centrifugal force, and supplying the concentrate subjected to the inactivation treatment to the storage means. A liquid processing method.
The treatment method according to claim 1, wherein the inactivation treatment includes mixing a substance that inactivates aquatic organisms with the concentrate.
The processing method according to claim 2, wherein the supply liquid is seawater, and the inactivating substance is fresh water.
The treatment method according to claim 2, wherein the inactivating substance is a chlorine-containing substance.
The processing method according to claim 4, comprising electrolyzing the supply liquid and / or the concentrated liquid to produce the chlorine-containing substance.
Physical means for performing physical treatment using centrifugal force on the supply liquid supplied to the storage means in the housing;
A recovery means for recovering the concentrate obtained by the physical treatment;
A liquid processing apparatus comprising: supply means for supplying a substance that inactivates aquatic organisms to the recovery means.