WO2014124549A1 - Recyclable multichannel ceramic floor tile - Google Patents

Recyclable multichannel ceramic floor tile Download PDF

Info

Publication number
WO2014124549A1
WO2014124549A1 PCT/CN2013/000584 CN2013000584W WO2014124549A1 WO 2014124549 A1 WO2014124549 A1 WO 2014124549A1 CN 2013000584 W CN2013000584 W CN 2013000584W WO 2014124549 A1 WO2014124549 A1 WO 2014124549A1
Authority
WO
WIPO (PCT)
Prior art keywords
clay
ore
waste
mud particles
channel
Prior art date
Application number
PCT/CN2013/000584
Other languages
French (fr)
Chinese (zh)
Inventor
彭幸华
吴进艺
张谋森
Original Assignee
福建省乐普陶板制造有限公司
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by 福建省乐普陶板制造有限公司 filed Critical 福建省乐普陶板制造有限公司
Publication of WO2014124549A1 publication Critical patent/WO2014124549A1/en

Links

Classifications

    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B33/00Clay-wares
    • C04B33/02Preparing or treating the raw materials individually or as batches
    • C04B33/04Clay; Kaolin
    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B33/00Clay-wares
    • C04B33/02Preparing or treating the raw materials individually or as batches
    • C04B33/13Compounding ingredients
    • C04B33/132Waste materials; Refuse; Residues
    • C04B33/1324Recycled material, e.g. tile dust, stone waste, spent refractory material
    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B2235/00Aspects relating to ceramic starting mixtures or sintered ceramic products
    • C04B2235/02Composition of constituents of the starting material or of secondary phases of the final product
    • C04B2235/30Constituents and secondary phases not being of a fibrous nature
    • C04B2235/34Non-metal oxides, non-metal mixed oxides, or salts thereof that form the non-metal oxides upon heating, e.g. carbonates, nitrates, (oxy)hydroxides, chlorides
    • C04B2235/3427Silicates other than clay, e.g. water glass
    • C04B2235/3436Alkaline earth metal silicates, e.g. barium silicate
    • C04B2235/3445Magnesium silicates, e.g. forsterite
    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B2235/00Aspects relating to ceramic starting mixtures or sintered ceramic products
    • C04B2235/02Composition of constituents of the starting material or of secondary phases of the final product
    • C04B2235/30Constituents and secondary phases not being of a fibrous nature
    • C04B2235/34Non-metal oxides, non-metal mixed oxides, or salts thereof that form the non-metal oxides upon heating, e.g. carbonates, nitrates, (oxy)hydroxides, chlorides
    • C04B2235/3427Silicates other than clay, e.g. water glass
    • C04B2235/3436Alkaline earth metal silicates, e.g. barium silicate
    • C04B2235/3454Calcium silicates, e.g. wollastonite
    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B2235/00Aspects relating to ceramic starting mixtures or sintered ceramic products
    • C04B2235/02Composition of constituents of the starting material or of secondary phases of the final product
    • C04B2235/30Constituents and secondary phases not being of a fibrous nature
    • C04B2235/34Non-metal oxides, non-metal mixed oxides, or salts thereof that form the non-metal oxides upon heating, e.g. carbonates, nitrates, (oxy)hydroxides, chlorides
    • C04B2235/3427Silicates other than clay, e.g. water glass
    • C04B2235/3463Alumino-silicates other than clay, e.g. mullite
    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B2235/00Aspects relating to ceramic starting mixtures or sintered ceramic products
    • C04B2235/02Composition of constituents of the starting material or of secondary phases of the final product
    • C04B2235/30Constituents and secondary phases not being of a fibrous nature
    • C04B2235/34Non-metal oxides, non-metal mixed oxides, or salts thereof that form the non-metal oxides upon heating, e.g. carbonates, nitrates, (oxy)hydroxides, chlorides
    • C04B2235/3427Silicates other than clay, e.g. water glass
    • C04B2235/3463Alumino-silicates other than clay, e.g. mullite
    • C04B2235/3472Alkali metal alumino-silicates other than clay, e.g. spodumene, alkali feldspars such as albite or orthoclase, micas such as muscovite, zeolites such as natrolite
    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B2235/00Aspects relating to ceramic starting mixtures or sintered ceramic products
    • C04B2235/02Composition of constituents of the starting material or of secondary phases of the final product
    • C04B2235/30Constituents and secondary phases not being of a fibrous nature
    • C04B2235/34Non-metal oxides, non-metal mixed oxides, or salts thereof that form the non-metal oxides upon heating, e.g. carbonates, nitrates, (oxy)hydroxides, chlorides
    • C04B2235/3427Silicates other than clay, e.g. water glass
    • C04B2235/3463Alumino-silicates other than clay, e.g. mullite
    • C04B2235/3481Alkaline earth metal alumino-silicates other than clay, e.g. cordierite, beryl, micas such as margarite, plagioclase feldspars such as anorthite, zeolites such as chabazite
    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B2235/00Aspects relating to ceramic starting mixtures or sintered ceramic products
    • C04B2235/02Composition of constituents of the starting material or of secondary phases of the final product
    • C04B2235/30Constituents and secondary phases not being of a fibrous nature
    • C04B2235/34Non-metal oxides, non-metal mixed oxides, or salts thereof that form the non-metal oxides upon heating, e.g. carbonates, nitrates, (oxy)hydroxides, chlorides
    • C04B2235/349Clays, e.g. bentonites, smectites such as montmorillonite, vermiculites or kaolines, e.g. illite, talc or sepiolite
    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B2235/00Aspects relating to ceramic starting mixtures or sintered ceramic products
    • C04B2235/60Aspects relating to the preparation, properties or mechanical treatment of green bodies or pre-forms
    • C04B2235/602Making the green bodies or pre-forms by moulding
    • C04B2235/6021Extrusion moulding
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02PCLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
    • Y02P40/00Technologies relating to the processing of minerals
    • Y02P40/60Production of ceramic materials or ceramic elements, e.g. substitution of clay or shale by alternative raw materials, e.g. ashes

Definitions

  • Multi-channel ceramic floor turning technology capable of recycling
  • the invention relates to the field of building materials and preparation technology thereof, in particular to a multi-channel ceramic floor which can be recycled.
  • Ceramic floor tiles are high-energy, high-emission, high-energy-consuming industries, including other existing building materials such as wood flooring and stone.
  • the resources are limited, and their mining is extremely damaging to the environment, thus improving the use of ceramic tiles.
  • the existing ceramic floor tiles have a single function and a thin thickness. They are only suitable for wet laying. They are moisture-proof, sound-proof and have poor anti-slip function. Most of them use glaze, printing and inkjet processes. The colors are easy to age and not wear-resistant, and the service life is also short.
  • the ground after construction is affected by the natural force of thermal expansion and contraction, and it is easy to damage the buried pipeline under the ground. If the common hot and cold water pipes leak, it is easy to damage the floor decoration materials, such as ground cracking and drumming. Moreover, the distance between the ground after construction and the floor heating pipe below it is more than 50mm.
  • the object of the present invention is to overcome the above deficiencies and to provide a recyclable, multi-channel, thermal energy Description
  • the technical solution of the present invention is: a recyclable multi-pass, ceramic floor tile which is processed from ridge earth rock, clay, ore, waste or waste brick material, said ridge
  • the soil is mainly composed of pyrophyllite, illite and sericite.
  • the ore is mainly a mixture of potassium feldspar, albite, talc and wollastonite.
  • the weight ratio of the raw materials is: Earth rock:
  • a recyclable multi-channel ceramic floor transfer production method comprising the following steps:
  • step (1) Preparation of mixed powder, the uniformly mixed raw materials in step (1) are subjected to Raymond grinding, and processed into powders of 20 mesh to 60 mesh, wherein the content of less than 60 mesh is more than 5%, and the green body is formed without cracking;
  • step (3) Preparation of the mud, adding the powder of step (2) to the stirring granulation equipment, stirring with water and extruding into mud particles, wherein the water content of the mud particles is 14 to 18%, and the particle size of the mud particles is 10 ⁇ 25mm;
  • step (3) Place the mud of step (3) in the old warehouse, and the moisture content of the mud is uniform after 24 hours of boring;
  • the mud of the step ( ) is vacuum extruded into a multi-channel brick, wherein the vacuum is 0.09 MPa, and the extrusion pressure is greater than 20 Bar;
  • the kiln is assembled, and the multi-channel bricks after molding are dried for 8-10 hours, wherein the drying temperature is not more than 150 'C, and the multi-channel bricks after drying are less than 1.5% and transported into the kiln for sintering;
  • the invention has the advantages that: the ridge rock containing the weakly viscous minerals, such as pyrophyllite, ore, sericite, etc., is used to reduce the water content, ensure the aluminum content, and improve the toughness and strength of the finished product. Sticky The soil plays a role in improving the plasticity and yield of the green body.
  • the flux and flux minerals such as potassium and sodium feldspar can reduce the sintering temperature and the water absorption rate of the finished product, and the calorific value in the waste residue can reach the waste.
  • Mineral, the ore is mainly a mixture of potassium feldspar, albite, talc and wollastonite.
  • the weight ratio of the raw materials is: ridge soil rock: 20 ⁇ 25%, clay: 30 ⁇ 45% ore : 15 ⁇ 20%, waste or waste brick: 5 ⁇ 10%.
  • the ridge soil rock reduces the water content, guarantees the aluminum content, and improves the toughness and strength of the finished product.
  • the clay plays a role in improving the plasticity and yield of the body, and the flux and flux minerals such as potassium and sodium feldspar. It can reduce the sintering temperature and the water absorption rate of the finished product, and the calorific value in the waste residue can achieve the effect of energy saving.
  • the invention discloses a production method of a multi-channel ceramic floor which can be recycled, comprising the following steps: 1) processing raw materials, drying the clay after 5 days in summer or 13 days in winter, and then placing it in the indoor silo for 10 days, obtaining Clay with a water content of 8%, according to the ridge soil: 20 ⁇ 25%, clay: 30 ⁇ 45% ore: 15 ⁇ 20%, waste or waste brick: 5-10% by weight, fully stirred and mixed 2) Mixing powder preparation, mixing the homogeneous raw materials in step (1) with Raymond mill, processing into 20-60 mesh particles, wherein the content below 60 mesh is more than 5%, to ensure that the green mold is not cracked; 3) Preparation of the mud, adding the powder of step (2) to the stirring granulation equipment, stirring with water and extruding into mud, wherein the moisture content of the mud is 14-18%, and the particle size of the mud is 10 ⁇ 25 ⁇
  • step (3) Place the mud of step (3) in the old warehouse, and the moisture content of the mud is uniform after 24 hours of boring;
  • step (4) The mud of step (4) is vacuum extruded into a multi-channel brick, wherein the degree of vacuum is 0.09 MPa,
  • Extrusion pressure is greater than 20Bar

Landscapes

  • Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Ceramic Engineering (AREA)
  • Dispersion Chemistry (AREA)
  • Materials Engineering (AREA)
  • Structural Engineering (AREA)
  • Organic Chemistry (AREA)
  • Environmental & Geological Engineering (AREA)
  • Compositions Of Oxide Ceramics (AREA)
  • Processing Of Solid Wastes (AREA)

Abstract

A recyclable multichannel ceramic floor tile is manufactured by processing raw materials of ridge soil rocks, clay, ore, residues, or waste bricks, wherein the ridge soil rocks are minerals obtained by mixing and grinding pyrophyllite, illite, and sericite; the ore is a mixture of potassium feldspar, soda feldspar, magnesium silicate, and wollastonite; and the weight percentages of the raw materials are: ridge soil rocks of 20% to 25%, clay of 30% to 45%, ore of 15% to 20%, and residues or waste bricks of 5% to 10%.

Description

一种能循环使用的多通道陶瓷地板转 技术领域  Multi-channel ceramic floor turning technology capable of recycling
本发明涉及建筑材料及其制备技术领域, 尤其是涉及的是一种能够循环使 用.的多通道陶瓷地板  The invention relates to the field of building materials and preparation technology thereof, in particular to a multi-channel ceramic floor which can be recycled.
背景技术 Background technique
陶瓷地砖是高能耗、 高排放、说高耗资源的产业, 包括现有的其他建材如木 地板和石材等, 资源有限, 其开采对环境破坏极大, 因此提高陶瓷地砖的使用  Ceramic floor tiles are high-energy, high-emission, high-energy-consuming industries, including other existing building materials such as wood flooring and stone. The resources are limited, and their mining is extremely damaging to the environment, thus improving the use of ceramic tiles.
 Book
寿命或循环使用是生态保护的必由之路。 现有的陶瓷地砖功能单一, 厚度薄, 只适合于湿法铺设, 防潮、 隔音、 防滑功能差, 且大多使用釉面、 印花、 喷墨 工艺, 花色易老化不耐磨, 使用寿命也比较短, 施工后的地面因热胀冷缩的自 然力作用, 极易破坏地面下的暗埋管线, 如常见到的冷热水管渗漏, 极易破坏 地面装饰材料, 如地面开裂、 起鼓。 而且施工后的地面与其下面的地暖管距离 超过 50mm, 此种施工方法会导致传热慢, 热效率低, 增加能耗和碳排放。 北方 地区冬季易发生严重空气污染与供暖热效率低有很大关系. 尤其在中国人口密 集的中南部地区, 冬季异常湿冷, 由于历史原因中南部地区未规划集中供暖, 每到冬季家家户户采用各种方式取暖, 不安全且能耗高。 较好的方法是在地板 下安装发热电缆, 安全、 舒适、 能耗低, 但发热电缆必须是活动安装, 而日前 的地面施工时无法满足其要求的。 采用常见的作业方式施工后的地面, 各种管 线深埋在水泥中, 任何一条管线老化或漏水或者需要增加一条新的管线都必须 大面积破坏现有的地面和其他无需维修的管线, 由此会带来巨大的经济损失和 资源浪费。 发明内容 Life or recycling is the only way to ecological protection. The existing ceramic floor tiles have a single function and a thin thickness. They are only suitable for wet laying. They are moisture-proof, sound-proof and have poor anti-slip function. Most of them use glaze, printing and inkjet processes. The colors are easy to age and not wear-resistant, and the service life is also short. The ground after construction is affected by the natural force of thermal expansion and contraction, and it is easy to damage the buried pipeline under the ground. If the common hot and cold water pipes leak, it is easy to damage the floor decoration materials, such as ground cracking and drumming. Moreover, the distance between the ground after construction and the floor heating pipe below it is more than 50mm. This construction method will result in slow heat transfer, low thermal efficiency, and increased energy consumption and carbon emissions. The severe air pollution in the northern part of the country is closely related to the low heat efficiency of heating. Especially in the densely populated central and southern parts of China, the winter is extremely wet and cold. Due to historical reasons, central heating is not planned in the central and southern regions. Every winter, every household adopts various methods. Heating, unsafe and energy efficient. A better method is to install a heating cable under the floor, which is safe, comfortable, and low in energy consumption. However, the heating cable must be installed in an active manner, but the ground construction cannot meet its requirements. The ground after construction is carried out by common operation methods. Various pipelines are buried deep in the cement. Any pipeline that is aging or leaking or needs to add a new pipeline must destroy the existing ground and other maintenance-free pipelines. It will bring huge economic losses and waste of resources. Summary of the invention
本发明的目的在于克服上述不足, 提供一种可循环使用、 多通道、 热能利 说 明 书 The object of the present invention is to overcome the above deficiencies and to provide a recyclable, multi-channel, thermal energy Description
用效率高的陶瓷地板砖。 Use high efficiency ceramic floor tiles.
为实现上述目的, 本发明的技术解决方案是: 一种能循环使用的多通,道陶 瓷地板砖, 它由脊性土岩、 粘土、 矿石、 废渣或废砖原料加工而成, 所述脊性 土岩主要为叶腊石、 伊利石和絹云母混合研磨后的矿物, 所述矿石主要为钾长 石、 钠长石、 滑石和硅灰石的混合物, 所述原料的重量百分配比为: 脊性土岩: In order to achieve the above object, the technical solution of the present invention is: a recyclable multi-pass, ceramic floor tile which is processed from ridge earth rock, clay, ore, waste or waste brick material, said ridge The soil is mainly composed of pyrophyllite, illite and sericite. The ore is mainly a mixture of potassium feldspar, albite, talc and wollastonite. The weight ratio of the raw materials is: Earth rock:
20 - 25 %, 粘土: 30~45%矿石: 15~20%, 废渣或废砖: 5~10%„ 20 - 25 %, clay: 30~45% ore: 15~20%, waste or waste brick: 5~10% „
一种能循环使用的多通道陶瓷地板转的生产方法, 包括以下步骤:  A recyclable multi-channel ceramic floor transfer production method comprising the following steps:
1)原料加工, 将粘土经过夏季 5天或冬季 13天时间晒干后, 再放置在室内 料仓陈腐 10天后, 得到含水量为 8%的粘土, 按脊性土岩: 20 ~ 25%, 粘土:, 30- 45%矿石: 15~20%, 废渣或废砖: 5 ~ 10%的重量比例, 进行充分搅拌、 混匀;  1) Raw material processing, after the clay is dried for 5 days in summer or 13 days in winter, and then placed in the indoor silo for 10 days, the clay with water content of 8% is obtained, according to the ridge soil rock: 20 ~ 25%, Clay: 30-45% ore: 15~20%, waste or waste brick: 5 ~ 10% by weight, stir well and mix well;
2)混合粉制备, 将步骤(1)中混合均匀的原料进行雷蒙磨, 加工为 20目 ~ 60目的粉粒, 其中低于 60目的含量大于 5%, 保障生坯成型不开裂;  2) Preparation of mixed powder, the uniformly mixed raw materials in step (1) are subjected to Raymond grinding, and processed into powders of 20 mesh to 60 mesh, wherein the content of less than 60 mesh is more than 5%, and the green body is formed without cracking;
3 ) 泥粒制备, 将步骤( 2 ) 的粉粒加入搅拌造粒设备, 进行加水搅拌并挤 出成泥粒, 其中泥粒的含水量为 14~ 18%, 泥粒的粒度为 10 ~ 25mm; 3) Preparation of the mud, adding the powder of step (2) to the stirring granulation equipment, stirring with water and extruding into mud particles, wherein the water content of the mud particles is 14 to 18%, and the particle size of the mud particles is 10 ~ 25mm;
4)将步骤(3)的泥粒放置在陈腐仓, 经 24小时以上的闷料, 保证泥粒的 水分均匀;  4) Place the mud of step (3) in the old warehouse, and the moisture content of the mud is uniform after 24 hours of boring;
5 )将步骤( )的泥粒经真空挤压成型为多通道砖坯,其中真空度为 0.09Mpa, 挤出压力大于 20Bar;  5) The mud of the step ( ) is vacuum extruded into a multi-channel brick, wherein the vacuum is 0.09 MPa, and the extrusion pressure is greater than 20 Bar;
6)装窑,成型后的多通道砖坯,经 8 ~ 10小时干燥, 其中干燥温度不大于 150 'C, 干燥后的多通道砖坯水分小于 1.5%时输送入窑烧结;  6) The kiln is assembled, and the multi-channel bricks after molding are dried for 8-10 hours, wherein the drying temperature is not more than 150 'C, and the multi-channel bricks after drying are less than 1.5% and transported into the kiln for sintering;
7)烧成, 保证烧成温度大于 1100 , 经过 4 5小时烧制成品。  7) Bake, ensure that the firing temperature is greater than 1100, and burn the finished product after 4 hours.
本发明的优点是: 采用包括叶腊石, 伊石、 絹云母等磨细后具有弱粘性矿 物的脊性土岩, 起到了降低含水量, 保障铝含量, 提高成品的韧性和强度。 粘 土在配方中起到了提高坯体的可塑性和成品率, 钾、 钠长石等熔剂和助熔剂矿 物, 可以起到降低烧结温度和成品吸水率的作用, 而且废渣中有热值, 达到利 废节能的效果, 在制砖过程中结合模具挤压成型为多通道空腔地板砖, 厚度超 过 35隱, 弯曲强度超过 60Mpa, 达到欧盟干法铺贴的标准, 既可以干铺也可以用 地板胶简单处理湿铺, 多通道可实现地面各种管线和将来需要增加的各种管线 自由布设安装, 施工效率高, 且更说换简单无需破坏现有结构, 完全可以循环使 用, 是一种耗材少、 节能隔音的环保型产品。 The invention has the advantages that: the ridge rock containing the weakly viscous minerals, such as pyrophyllite, ore, sericite, etc., is used to reduce the water content, ensure the aluminum content, and improve the toughness and strength of the finished product. Sticky The soil plays a role in improving the plasticity and yield of the green body. The flux and flux minerals such as potassium and sodium feldspar can reduce the sintering temperature and the water absorption rate of the finished product, and the calorific value in the waste residue can reach the waste. The effect of energy saving, in the process of brick making, combined with die extrusion into multi-channel cavity floor tiles, the thickness exceeds 35 hidden, the bending strength exceeds 60Mpa, meets the standard of EU dry-laid paving, can be dry or floor glue Simple processing of wet paving, multi-channel can realize various pipelines on the ground and various pipelines that need to be added in the future. The construction efficiency is high, and it is simple to change without destroying the existing structure. It can be recycled completely. It is a kind of low-cost consumables. Energy-saving and environmentally friendly products.
具体实施方式 书 下面以实施例具体地描述本发明, 本发明的范围不受实施例的限制。 一种能循环使用的多通道陶瓷地板砖, 它由脊性土岩、 粘土、 矿石、 废渣 或废砖原料加工而成, 所述脊性土岩主要为叶腊石、 伊利石和絹云母混合研磨 后的矿物, 所述矿石主要为钾长石、 钠长石、 滑石和硅灰石的混合物, 所述原 料的重量百分配比为: 脊性土岩: 20~25%, 粘土: 30~45%矿石: 15~20%, 废渣或废砖: 5~10%。 其中脊性土岩, 起到了降低含水量, 保障铝含量, 提高 成品的韧性和强度, 粘土在配方中起到了提高坯体的可塑性和成品率, 钾、 钠 长石等熔剂和助熔剂矿物, 可以起到降低烧结温度和成品吸水率的作用, 而且 废渣中有热值, 达到利废节能的效果。 一种能循环使用的多通道陶瓷地板 ^的生产方法, 包括以下步骤: 1)原料加工, 将粘土经过夏季 5天或冬季 13天时间晒干后, 再放置在室内 料仓陈腐 10天后, 得到含水量为 8%的粘土, 按脊性土岩: 20~25%, 粘土: 30~ 45%矿石: 15~20%, 废渣或废砖: 5-10%的重量比例, 进行充分搅拌、 混匀; 2 )混合粉制备, 将步骤( 1 )中混合均匀的原料进行雷蒙磨, 加工为 20目 ~ 60目的粉粒, 其中低于 60目的含量大于 5%, 保障生坯成型不开裂; 3 ) 泥粒制备, 将步骤( 2 ) 的粉粒加入搅拌造粒设备, 进行加水搅拌并挤 出成泥粒, 其中泥粒的含水量为 14 ~ 18%, 泥粒的粒度为 10~25瞧; BEST MODE FOR CARRYING OUT THE INVENTION The present invention is specifically described by the following examples, and the scope of the present invention is not limited by the examples. A multi-channel ceramic floor tile which can be recycled, which is processed from ridge earth rock, clay, ore, waste slag or waste brick material, and the ridge earth rock is mainly mixed with pyrophyllite, illite and sericite. Mineral, the ore is mainly a mixture of potassium feldspar, albite, talc and wollastonite. The weight ratio of the raw materials is: ridge soil rock: 20~25%, clay: 30~45% ore : 15~20%, waste or waste brick: 5~10%. Among them, the ridge soil rock reduces the water content, guarantees the aluminum content, and improves the toughness and strength of the finished product. The clay plays a role in improving the plasticity and yield of the body, and the flux and flux minerals such as potassium and sodium feldspar. It can reduce the sintering temperature and the water absorption rate of the finished product, and the calorific value in the waste residue can achieve the effect of energy saving. The invention discloses a production method of a multi-channel ceramic floor which can be recycled, comprising the following steps: 1) processing raw materials, drying the clay after 5 days in summer or 13 days in winter, and then placing it in the indoor silo for 10 days, obtaining Clay with a water content of 8%, according to the ridge soil: 20~25%, clay: 30~45% ore: 15~20%, waste or waste brick: 5-10% by weight, fully stirred and mixed 2) Mixing powder preparation, mixing the homogeneous raw materials in step (1) with Raymond mill, processing into 20-60 mesh particles, wherein the content below 60 mesh is more than 5%, to ensure that the green mold is not cracked; 3) Preparation of the mud, adding the powder of step (2) to the stirring granulation equipment, stirring with water and extruding into mud, wherein the moisture content of the mud is 14-18%, and the particle size of the mud is 10~25瞧
4)将步骤(3)的泥粒放置在陈腐仓, 经 24小时以上的闷料, 保证泥粒的 水分均匀; 4) Place the mud of step (3) in the old warehouse, and the moisture content of the mud is uniform after 24 hours of boring;
5 )将步骤( 4 )的泥粒经真空挤压成型为多通道砖坯,其中真空度为 0.09Mpa, 5) The mud of step (4) is vacuum extruded into a multi-channel brick, wherein the degree of vacuum is 0.09 MPa,
 Say
挤出压力大于 20Bar; Extrusion pressure is greater than 20Bar;
6)装窑,成型后的多通道砖坯,经 8- 10小时干燥,其中干燥温度不大于 150 6) The kiln is assembled, and the multi-channel bricks after molding are dried for 8-10 hours, wherein the drying temperature is not more than 150
 Book
°C, 干燥后的多通道砖坯水分小于 1.5%时输送入窑烧结; °C, when the moisture of the multi-channel brick after drying is less than 1.5%, it is sent into the kiln for sintering;
7)烧成, 保证烧成温度大于 1100 , 经过 4-5小时烧制成品。 最后, 将烧制好的成品经过切割、 严格评检、 包装入成品库。 7) Firing, ensure that the firing temperature is greater than 1100, and burn the finished product after 4-5 hours. Finally, the fired finished product is cut, rigorously inspected and packaged into the finished product warehouse.

Claims

权 利 要 求 书 claims
1、 一种能循环使用的多通道陶瓷地板砖, 它由脊性土岩、 粘土、 矿石、 废 渣或废砖原料加工而成, 其特征在于: 所述脊性土岩主要为叶腊石、 伊利石和 绢云母混合研磨后的矿物, 所述矿石主要为钾长石、 钠长石、 滑石和硅灰石的 混'合物, 所述原料的重量百分配比为: 脊性土岩: 20~25%, 粘土: 30~45% 矿石: 15~20%, 废渣或废砖: 5~10%。 1. A recyclable multi-channel ceramic floor tile, which is processed from ridged soil rock, clay, ore, waste residue or waste brick raw materials, and is characterized in that: the ridged soil rock is mainly pyrophyllite, illite and Sericite is a mixed and ground mineral. The ore is mainly a mixture of potassium feldspar, albite, talc and wollastonite. The weight percentage of the raw materials is: Ridge soil rock: 20~25 %, clay: 30~45%, ore: 15~20%, waste residue or waste brick: 5~10%.
2、 根据权利要求 1所述的一种能循环使用的多通道陶瓷地板砖的生产方法, 包括以下步骤: 2. A method for producing recyclable multi-channel ceramic floor tiles according to claim 1, comprising the following steps:
1)原料加工, 将粘土经过夏季 5天或冬季 13天时间晒干后, 再放置在室内 料仓陈腐 10天后, 得到含水量为 8%的粘土, 按脊性土岩: 20~25%, 粘土: 30 ~ 45%矿石: 15~20%, 废渣或废砖: 5~10%的重量比例, 进行充分搅拌、 混匀; 1) Raw material processing: After drying the clay for 5 days in summer or 13 days in winter, and then placing it in an indoor silo to age for 10 days, clay with a moisture content of 8% is obtained. According to ridged soil rock: 20~25%, Clay: 30~45% ore: 15~20%, waste residue or waste bricks: 5~10% by weight, stir and mix thoroughly;
2 )混合粉制备, 将步驟( 1 )中混合均匀的原料进行雷蒙磨, 加工为 20目 ~ 60目的粉粒, 其中低于 60目的含量大于 5%, 保障生坯成型不开裂; 2) Preparation of mixed powder, the uniformly mixed raw materials in step (1) are subjected to Raymond mill, and processed into powder particles of 20 mesh to 60 mesh, in which the content of less than 60 mesh is greater than 5%, ensuring that the green body will not crack during molding;
3 )泥粒制备, 将步骤( 2 ) 的粉粒加入搅拌造粒设备, 进行加水搅拌并挤 出成泥粒, 其中泥粒的含水量为 14- 18%, 泥粒的粒度为 10- 25mm; 3) Preparation of mud particles, add the powder in step (2) to the mixing and granulating equipment, add water, stir and extrude into mud particles, where the moisture content of the mud particles is 14-18%, and the particle size of the mud particles is 10-25 mm. ;
4)将步骤(3) 的泥粒放置在陈腐仓, 经 24小时以上的闷料, 保证泥粒的 水分均匀; 4) Place the mud particles from step (3) in a stale storage bin, and stuff them for more than 24 hours to ensure uniform moisture content of the mud particles;
5 )将步骤( 4 )的泥粒经真空挤压成型为多通道砖坯,其中真空度为 0.09Mpa, 挤出压力大于 20Bar; 5) The mud particles in step (4) are vacuum extruded into multi-channel bricks, where the vacuum degree is 0.09Mpa and the extrusion pressure is greater than 20Bar;
6)装窑,成型后的多通道砖坯,经 8~10小时千燥,其中干燥温度不大于 150 。C, 干燥后的多通道砖坯水分小于 1.5%时输送入窑烧结; 6) Install the kiln and dry the formed multi-channel bricks for 8 to 10 hours, with the drying temperature not exceeding 150°C. C. When the moisture content of the dried multi-channel bricks is less than 1.5%, they are transported to the kiln for sintering;
7)烧成, 保证烧成温度大于 1100 , 经过 4-5小时烧制成品。 7) Firing, ensure that the firing temperature is greater than 1100, and the finished product will be fired after 4-5 hours.
PCT/CN2013/000584 2013-02-18 2013-05-16 Recyclable multichannel ceramic floor tile WO2014124549A1 (en)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
CN201310052129.2 2013-02-18
CN201310052129.2A CN103992096B (en) 2013-02-18 2013-02-18 Recyclable multichannel ceramic floor tile

Publications (1)

Publication Number Publication Date
WO2014124549A1 true WO2014124549A1 (en) 2014-08-21

Family

ID=51306471

Family Applications (1)

Application Number Title Priority Date Filing Date
PCT/CN2013/000584 WO2014124549A1 (en) 2013-02-18 2013-05-16 Recyclable multichannel ceramic floor tile

Country Status (2)

Country Link
CN (1) CN103992096B (en)
WO (1) WO2014124549A1 (en)

Families Citing this family (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN104973852A (en) * 2015-06-12 2015-10-14 常州大学 Antifreezing eco-friendly brick produced from waste brick powder and preparation method thereof
CN105418077B (en) * 2015-11-12 2017-09-29 哈尔滨工业大学 A kind of processing method of nano ceramics interior three-dimensional micro-channel
CN105712697B (en) * 2016-01-22 2018-07-13 福建科福材料有限公司 A kind of Ceramic Slurry for Sanitary Ceramics and its preparation process
CN106747304A (en) * 2016-12-02 2017-05-31 绥阳县华夏陶瓷有限责任公司 A kind of manufacture craft of environment protection tile
CN110041047A (en) * 2019-03-02 2019-07-23 福建埃瑞森材料科技有限公司 A kind of dedicated wall hanging ceramic plate of tunnel underground and its production method
CN117656606A (en) * 2024-01-30 2024-03-08 福建省晋江市泗农建材有限公司 High-resistance anti-reflection non-radiation ceramic heat-insulation composite board and production process thereof

Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN1297860A (en) * 1999-12-01 2001-06-06 新疆建筑材料研究所 Glazed tile made with acid lithium slag and its making process
CN101386528A (en) * 2008-10-27 2009-03-18 佛山欧神诺陶瓷股份有限公司 Method for producing ceramic tile by metallurgical steel slag
CN101718131A (en) * 2009-12-01 2010-06-02 西安交通大学 Ceramic plate for curtain wall decoration and preparation method thereof
CN102765931A (en) * 2012-08-03 2012-11-07 北京科技大学 Method for preparing ceramic material utilizing magnetic separation tail sludge from steel slag wet process

Family Cites Families (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN102518249B (en) * 2011-12-08 2014-07-16 江苏省建筑科学研究院有限公司 Sludge and silt sintered brick with clay brick surface layer and preparation method thereof

Patent Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN1297860A (en) * 1999-12-01 2001-06-06 新疆建筑材料研究所 Glazed tile made with acid lithium slag and its making process
CN101386528A (en) * 2008-10-27 2009-03-18 佛山欧神诺陶瓷股份有限公司 Method for producing ceramic tile by metallurgical steel slag
CN101718131A (en) * 2009-12-01 2010-06-02 西安交通大学 Ceramic plate for curtain wall decoration and preparation method thereof
CN102765931A (en) * 2012-08-03 2012-11-07 北京科技大学 Method for preparing ceramic material utilizing magnetic separation tail sludge from steel slag wet process

Also Published As

Publication number Publication date
CN103992096A (en) 2014-08-20
CN103992096B (en) 2015-07-01

Similar Documents

Publication Publication Date Title
WO2014124549A1 (en) Recyclable multichannel ceramic floor tile
CN104291788B (en) A kind of high strength hollow brick and preparation method thereof
EP2985270B1 (en) Preparation method of low-temperature fast-fired lightweight ceramic heat insulation plate.
CN101672083B (en) Method for producing self-insulation baked brick by using pure coal gangue
CN101016207B (en) Manufacture method for high heat preservation sintering hollow composite brick
CN102992803B (en) Air-added brick with slag as matrix and method for processing same
CN101857400A (en) Lightweight insulating brick and production process thereof
CN104310949B (en) A kind of Boccaro shale hollow brick
CN105967753B (en) A method of freeze thawing resistance ground water-permeable brick is produced using golden antimony tailing
CN102924059A (en) Shale porous brick and method for manufacturing same
CN104355576A (en) Waterproof self-insulation brick and preparation method thereof
CN104276809A (en) Abrasion-proof hollow brick containing purple sand shale
CN106380217A (en) Making method for lightweight environment-friendly ceramic plate
KR101062321B1 (en) Non-sintering construction material and method of manufacturing thereof
CN104310944A (en) Coal gangue sintered hollow brick
CN107140896A (en) Concrete and preparation method thereof
CN102924043A (en) Shale yellow sand hollow brick and preparation method thereof
CN103043956A (en) Method for preparing energy-saving wall material by utilizing waste foam glass
CN107235708A (en) Energy-saving brick for gardens and preparation method thereof
CN107721384A (en) Yellow environment-friendly pavior brick with pervious function
CN101649665A (en) Sintered porous brick and preparation method thereof
CN101649664A (en) Sintered porous brick and preparation method thereof
CN104291789A (en) Perforated brick with strong water absorption property, and preparation method thereof
CN101386523B (en) Artificial porcelain granule and preparation method thereof
CN101497523A (en) Method for producing light heat-insulating brick by biomass energy and light heat-insulating brick thereof

Legal Events

Date Code Title Description
121 Ep: the epo has been informed by wipo that ep was designated in this application

Ref document number: 13875020

Country of ref document: EP

Kind code of ref document: A1

NENP Non-entry into the national phase

Ref country code: DE

122 Ep: pct application non-entry in european phase

Ref document number: 13875020

Country of ref document: EP

Kind code of ref document: A1