CN103992096B - Recyclable multichannel ceramic floor tile - Google Patents
Recyclable multichannel ceramic floor tile Download PDFInfo
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- CN103992096B CN103992096B CN201310052129.2A CN201310052129A CN103992096B CN 103992096 B CN103992096 B CN 103992096B CN 201310052129 A CN201310052129 A CN 201310052129A CN 103992096 B CN103992096 B CN 103992096B
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- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B33/00—Clay-wares
- C04B33/02—Preparing or treating the raw materials individually or as batches
- C04B33/04—Clay; Kaolin
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- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B33/00—Clay-wares
- C04B33/02—Preparing or treating the raw materials individually or as batches
- C04B33/13—Compounding ingredients
- C04B33/132—Waste materials; Refuse; Residues
- C04B33/1324—Recycled material, e.g. tile dust, stone waste, spent refractory material
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- C04B2235/00—Aspects relating to ceramic starting mixtures or sintered ceramic products
- C04B2235/02—Composition of constituents of the starting material or of secondary phases of the final product
- C04B2235/30—Constituents and secondary phases not being of a fibrous nature
- C04B2235/34—Non-metal oxides, non-metal mixed oxides, or salts thereof that form the non-metal oxides upon heating, e.g. carbonates, nitrates, (oxy)hydroxides, chlorides
- C04B2235/3427—Silicates other than clay, e.g. water glass
- C04B2235/3436—Alkaline earth metal silicates, e.g. barium silicate
- C04B2235/3445—Magnesium silicates, e.g. forsterite
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- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
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- C04B2235/00—Aspects relating to ceramic starting mixtures or sintered ceramic products
- C04B2235/02—Composition of constituents of the starting material or of secondary phases of the final product
- C04B2235/30—Constituents and secondary phases not being of a fibrous nature
- C04B2235/34—Non-metal oxides, non-metal mixed oxides, or salts thereof that form the non-metal oxides upon heating, e.g. carbonates, nitrates, (oxy)hydroxides, chlorides
- C04B2235/3427—Silicates other than clay, e.g. water glass
- C04B2235/3436—Alkaline earth metal silicates, e.g. barium silicate
- C04B2235/3454—Calcium silicates, e.g. wollastonite
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- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B2235/00—Aspects relating to ceramic starting mixtures or sintered ceramic products
- C04B2235/02—Composition of constituents of the starting material or of secondary phases of the final product
- C04B2235/30—Constituents and secondary phases not being of a fibrous nature
- C04B2235/34—Non-metal oxides, non-metal mixed oxides, or salts thereof that form the non-metal oxides upon heating, e.g. carbonates, nitrates, (oxy)hydroxides, chlorides
- C04B2235/3427—Silicates other than clay, e.g. water glass
- C04B2235/3463—Alumino-silicates other than clay, e.g. mullite
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- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B2235/00—Aspects relating to ceramic starting mixtures or sintered ceramic products
- C04B2235/02—Composition of constituents of the starting material or of secondary phases of the final product
- C04B2235/30—Constituents and secondary phases not being of a fibrous nature
- C04B2235/34—Non-metal oxides, non-metal mixed oxides, or salts thereof that form the non-metal oxides upon heating, e.g. carbonates, nitrates, (oxy)hydroxides, chlorides
- C04B2235/3427—Silicates other than clay, e.g. water glass
- C04B2235/3463—Alumino-silicates other than clay, e.g. mullite
- C04B2235/3472—Alkali metal alumino-silicates other than clay, e.g. spodumene, alkali feldspars such as albite or orthoclase, micas such as muscovite, zeolites such as natrolite
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- C—CHEMISTRY; METALLURGY
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- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B2235/00—Aspects relating to ceramic starting mixtures or sintered ceramic products
- C04B2235/02—Composition of constituents of the starting material or of secondary phases of the final product
- C04B2235/30—Constituents and secondary phases not being of a fibrous nature
- C04B2235/34—Non-metal oxides, non-metal mixed oxides, or salts thereof that form the non-metal oxides upon heating, e.g. carbonates, nitrates, (oxy)hydroxides, chlorides
- C04B2235/3427—Silicates other than clay, e.g. water glass
- C04B2235/3463—Alumino-silicates other than clay, e.g. mullite
- C04B2235/3481—Alkaline earth metal alumino-silicates other than clay, e.g. cordierite, beryl, micas such as margarite, plagioclase feldspars such as anorthite, zeolites such as chabazite
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- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B2235/00—Aspects relating to ceramic starting mixtures or sintered ceramic products
- C04B2235/02—Composition of constituents of the starting material or of secondary phases of the final product
- C04B2235/30—Constituents and secondary phases not being of a fibrous nature
- C04B2235/34—Non-metal oxides, non-metal mixed oxides, or salts thereof that form the non-metal oxides upon heating, e.g. carbonates, nitrates, (oxy)hydroxides, chlorides
- C04B2235/349—Clays, e.g. bentonites, smectites such as montmorillonite, vermiculites or kaolines, e.g. illite, talc or sepiolite
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- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
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- C04B2235/00—Aspects relating to ceramic starting mixtures or sintered ceramic products
- C04B2235/60—Aspects relating to the preparation, properties or mechanical treatment of green bodies or pre-forms
- C04B2235/602—Making the green bodies or pre-forms by moulding
- C04B2235/6021—Extrusion moulding
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- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
- Y02P40/00—Technologies relating to the processing of minerals
- Y02P40/60—Production of ceramic materials or ceramic elements, e.g. substitution of clay or shale by alternative raw materials, e.g. ashes
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- Engineering & Computer Science (AREA)
- Ceramic Engineering (AREA)
- Dispersion Chemistry (AREA)
- Materials Engineering (AREA)
- Structural Engineering (AREA)
- Organic Chemistry (AREA)
- Environmental & Geological Engineering (AREA)
- Compositions Of Oxide Ceramics (AREA)
- Processing Of Solid Wastes (AREA)
Abstract
The invention relates to the field of building materials, and concretely relates to a recyclable multichannel ceramic floor tile. The recyclable multichannel ceramic floor tile is prepared by processing lean earth rock, clay, ore, and waste slag or waste bricks. The lean earth rock is mainly a mineral obtained by mixing pyrophillite, illite and sericite and grinding. Ore is mainly a mixture of potash feldspar, albite, talcum and wollastonite. The weight proportions of the raw materials comprise 20-25% of lean earth rock, 30-45% of clay, 15-20% of ore and 5-10% of waste slag or waste bricks. According to the ceramic floor tile, lean earth rock is employed for reducing water content and improving the toughness and the strength of a finished product; ore gives play to reduction of sintering temperature and water absorption rate; and waste slag has calorific value, so that the effects of utilizing waste and saving energy are realized. In the tile making process, a mold is employed for compression molding of the multichannel floor tile with cavities. The multichannel floor tiles are spread in a dry way or are spread in a wet way by processing with a floor glue, so that free laying and installation of pipelines are realized, and the construction efficiency is high. The multichannel floor tile is recyclable, and has extremely good energy-saving environment-protection effect.
Description
Technical field
The present invention relates to material of construction and preparing technical field thereof, what especially relate to is a kind of hyperchannel ceramic floor brick that can recycle.
Background technology
Floor tile is the industry in high energy consumption, maximum discharge, high cost source; comprise other building materials existing as timber floor and stone material etc.; resource-constrained, its exploitation is very big to environmental disruption, therefore improves the work-ing life of floor tile or to recycle be the only way of ecological protection.Existing floor tile function singleness, thickness is thin, is suitable only for wet method and lays, and protection against the tide, sound insulation, antiskid function are poor, and mostly use glaze paint, stamp, ink-jetting process, pattern is easily aging not wear-resisting, and work-ing life is also shorter, the natural force effect of the ground after construction because expanding with heat and contract with cold, very easily destroy underground concealed piping, the hot water pipe seepage seen as usual, very easily destroys floor decorative material, as ground cracking, plays drum.And the ground after construction with floor heating pipe distance below it more than 50mm, this kind of constructional method can cause heat transfer slow, and thermo-efficiency is low, increase energy consumption and carbon emission.Easily to there is severe air winter and pollute with heating that thermo-efficiency is low much relations in northern area.Especially in the southern that Chinese population is intensive, winter anomaly is clammy, and because central heating is not planned in historical reasons southern, every household was adopted and warmed oneself in various manners every winter, dangerous and energy consumption is high.Good method installs heating cable under floor, safe, comfortable, energy consumption is low, but heating cable must be movable installation, and cannot meet during current ground construction that it requires.Adopt the ground after common mode of operation construction, various pipeline is buried in cement, any pipeline aging or leak or need increase by new pipeline all must the existing ground of extensive damage and other without the need to maintenance pipeline, huge financial loss and the wasting of resources can be brought thus.
Summary of the invention
The object of the invention is to overcome above-mentioned deficiency, provide a kind of and can be recycled, ceramic floor brick that hyperchannel, utilization efficiency of heat energy are high.
For achieving the above object, technical solution of the present invention is: a kind of hyperchannel ceramic floor brick that can recycle, it is formed by ridge Tu Yan, clay, ore, waste residue or useless brick Raw material processing, described ridge Tu Yan is mainly the mineral after agalmatolite, illite and sericite mixed grinding, described ore is mainly the mixture of potassium felspar sand, albite, talcum and wollastonite, the weight percent proportioning of described raw material is: ridge Tu Yan: 20 ~ 25%, clay: 30 ~ 45% ores: 15 ~ 20%, waste residue or useless brick: 5 ~ 10%.
A production method for the hyperchannel ceramic floor brick that can recycle, comprises the following steps:
1) Raw material processing, by clay after aestivate 5 days or time 13 day winter dry, be placed on indoor feed bin again after old 10 days, obtain the clay that water content is 8%, press ridge Tu Yan: 20 ~ 25%, clay: 30 ~ 45% ores: 15 ~ 20%, waste residue or useless brick: the part by weight of 5 ~ 10%, fully stir, mix;
2) powder mix preparation, carries out Raymond mill by the raw material mixed in step (1), is processed as 20 order ~ 60 object powders, is wherein greater than 5% lower than 60 object content, ensures that green compact are shaping and does not ftracture;
3) mud pellet preparation, the powder of step (2) is added stirring-granulating equipment, and carrying out adds water stirs and is extruded into mud pellet, and wherein the water content of mud pellet is 14 ~ 18%, and the granularity of mud pellet is 10 ~ 25mm;
4) mud pellet of step (3) is placed on ageing tower, the shelving more than 24 hours, ensures the uniform moisture of mud pellet;
5) be hyperchannel adobe by the mud pellet of step (4) through extrusion under vacuum, wherein vacuum tightness is 0.09MPa, and extrusion pressure is greater than 20Bar;
6) loading of kiln, the hyperchannel adobe after shaping, dry through 8 ~ 10 hours, wherein drying temperature is not more than 150 DEG C, is conveyed into klining knot when dried hyperchannel raw brick moisture content is less than 1.5%;
7) burn till, ensure that firing temperature is greater than 1100 DEG C, fired finished product through 4 ~ 5 hours.
Advantage of the present invention is: adopt and comprise agalmatolite, have the ridge Tu Yan of weak viscous mineral, serve reduction water content after Yi Shi, sericite etc. are levigate, ensures aluminium content, improves toughness and the intensity of finished product.Clay serves the plasticity-and yield rate that improve base substrate in formula, potassium, the flux such as albite and fusing assistant mineral, the effect reducing sintering temperature and finished product water-intake rate can be played, and have calorific value in waste residue, reach the effect of utilize waste and save energy, be hyperchannel cavity floor brick in conjunction with mould extrusion molding in brickmaking process, thickness is more than 35mm, flexural strength is more than 60MPa, reach the standard of European Union's dry method paving, both can do paving also can spread with floor glue simple process is wet, hyperchannel can realize the various pipeline in ground and need the various pipelines increased freely to lay installation in the future, operating efficiency is high, and change simple without the need to destroying existing structure, can recycle completely, that a kind of consumptive material is few, the environmentally friendly machine of energy-saving sound insulation.
Embodiment
Describe the present invention particularly with embodiment below, scope of the present invention is not by the restriction of embodiment.
A kind of hyperchannel ceramic floor brick that can recycle, it is formed by ridge Tu Yan, clay, ore, waste residue or useless brick Raw material processing, described ridge Tu Yan is mainly the mineral after agalmatolite, illite and sericite mixed grinding, described ore is mainly the mixture of potassium felspar sand, albite, talcum and wollastonite, the weight percent proportioning of described raw material is: ridge Tu Yan: 20 ~ 25%, clay: 30 ~ 45% ores: 15 ~ 20%, waste residue or useless brick: 5 ~ 10%.Its median ridge Tu Yan, serve reduction water content, ensure aluminium content, improve toughness and the intensity of finished product, clay serves the plasticity-and yield rate that improve base substrate in formula, and the flux such as potassium, albite and fusing assistant mineral can play the effect reducing sintering temperature and finished product water-intake rate, and have calorific value in waste residue, reach the effect of utilize waste and save energy.
A production method for the hyperchannel ceramic floor brick that can recycle, comprises the following steps:
1) Raw material processing, by clay after aestivate 5 days or time 13 day winter dry, be placed on indoor feed bin again after old 10 days, obtain the clay that water content is 8%, press ridge Tu Yan: 20 ~ 25%, clay: 30 ~ 45% ores: 15 ~ 20%, waste residue or useless brick: the part by weight of 5 ~ 10%, fully stir, mix;
2) powder mix preparation, carries out Raymond mill by the raw material mixed in step (1), is processed as 20 order ~ 60 object powders, is wherein greater than 5% lower than 60 object content, ensures that green compact are shaping and does not ftracture;
3) mud pellet preparation, the powder of step (2) is added stirring-granulating equipment, and carrying out adds water stirs and is extruded into mud pellet, and wherein the water content of mud pellet is 14 ~ 18%, and the granularity of mud pellet is 10 ~ 25mm;
4) mud pellet of step (3) is placed on ageing tower, the shelving more than 24 hours, ensures the uniform moisture of mud pellet;
5) be hyperchannel adobe by the mud pellet of step (4) through extrusion under vacuum, wherein vacuum tightness is 0.09MPa, and extrusion pressure is greater than 20Bar;
6) loading of kiln, the hyperchannel adobe after shaping, dry through 8 ~ 10 hours, wherein drying temperature is not more than 150 DEG C, is conveyed into klining knot when dried hyperchannel raw brick moisture content is less than 1.5%;
7) burn till, ensure that firing temperature is greater than 1100 DEG C, fired finished product through 4 ~ 5 hours.
Finally, the finished product baked is passed through cutting, strictly comments inspection, is packaged into stockyard.
Claims (1)
1. a production method for the hyperchannel ceramic floor brick that can recycle, comprises the following steps:
1) Raw material processing, by clay after aestivate 5 days or time 13 day winter dry, be placed on indoor feed bin again after old 10 days, obtain the clay that water content is 8%, press ridge Tu Yan: 20 ~ 25%, clay: 30 ~ 45% ores: 15 ~ 20%, waste residue: the part by weight of 5 ~ 10%, above-mentioned each component sum is 100%, fully stirs, mixes; Described ridge Tu Yan is mainly the mineral after agalmatolite, illite and sericite mixed grinding, and described ore is mainly the mixture of potassium felspar sand, albite, talcum and wollastonite;
2) powder mix preparation, carries out Raymond mill by the raw material mixed in step (1), is processed as 20 order ~ 60 object powders, is wherein greater than 5% lower than 60 object content, ensures that green compact are shaping and does not ftracture;
3) mud pellet preparation, the powder of step (2) is added stirring-granulating equipment, and carrying out adds water stirs and is extruded into mud pellet, and wherein the water content of mud pellet is 14 ~ 18%, and the granularity of mud pellet is 10 ~ 25mm;
4) mud pellet of step (3) is placed on ageing tower, the shelving more than 24 hours, ensures the uniform moisture of mud pellet;
5) be hyperchannel adobe by the mud pellet of step (4) through extrusion under vacuum, wherein vacuum tightness is 0.09MPa, and extrusion pressure is greater than 20Bar;
6) loading of kiln, the hyperchannel adobe after shaping, dry through 8 ~ 10 hours, wherein drying temperature is not more than 150 DEG C, is conveyed into klining knot when dried hyperchannel raw brick moisture content is less than 1.5%;
7) burn till, ensure that firing temperature is greater than 1100 DEG C, fired finished product through 4 ~ 5 hours.
Priority Applications (2)
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CN201310052129.2A CN103992096B (en) | 2013-02-18 | 2013-02-18 | Recyclable multichannel ceramic floor tile |
PCT/CN2013/000584 WO2014124549A1 (en) | 2013-02-18 | 2013-05-16 | Recyclable multichannel ceramic floor tile |
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CN201310052129.2A CN103992096B (en) | 2013-02-18 | 2013-02-18 | Recyclable multichannel ceramic floor tile |
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CN103992096B true CN103992096B (en) | 2015-07-01 |
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CN104973852A (en) * | 2015-06-12 | 2015-10-14 | 常州大学 | Antifreezing eco-friendly brick produced from waste brick powder and preparation method thereof |
CN105418077B (en) * | 2015-11-12 | 2017-09-29 | 哈尔滨工业大学 | A kind of processing method of nano ceramics interior three-dimensional micro-channel |
CN105712697B (en) * | 2016-01-22 | 2018-07-13 | 福建科福材料有限公司 | A kind of Ceramic Slurry for Sanitary Ceramics and its preparation process |
CN106747304A (en) * | 2016-12-02 | 2017-05-31 | 绥阳县华夏陶瓷有限责任公司 | A kind of manufacture craft of environment protection tile |
CN110041047A (en) * | 2019-03-02 | 2019-07-23 | 福建埃瑞森材料科技有限公司 | A kind of dedicated wall hanging ceramic plate of tunnel underground and its production method |
CN117656606A (en) * | 2024-01-30 | 2024-03-08 | 福建省晋江市泗农建材有限公司 | High-resistance anti-reflection non-radiation ceramic heat-insulation composite board and production process thereof |
Citations (2)
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CN101386528A (en) * | 2008-10-27 | 2009-03-18 | 佛山欧神诺陶瓷股份有限公司 | Method for producing ceramic tile by metallurgical steel slag |
CN102518249A (en) * | 2011-12-08 | 2012-06-27 | 江苏省建筑科学研究院有限公司 | Sludge and silt sintered brick with clay brick surface layer and preparation method thereof |
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CN1090597C (en) * | 1999-12-01 | 2002-09-11 | 新疆建筑材料研究所 | Glazed tile made with acid lithium slag and its making process |
CN101718131B (en) * | 2009-12-01 | 2011-07-27 | 西安交通大学 | Ceramic plate for curtain wall decoration and preparation method thereof |
CN102765931B (en) * | 2012-08-03 | 2014-03-26 | 北京科技大学 | Method for preparing ceramic material utilizing magnetic separation tail sludge from steel slag wet process |
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- 2013-05-16 WO PCT/CN2013/000584 patent/WO2014124549A1/en active Application Filing
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---|---|---|---|---|
CN101386528A (en) * | 2008-10-27 | 2009-03-18 | 佛山欧神诺陶瓷股份有限公司 | Method for producing ceramic tile by metallurgical steel slag |
CN102518249A (en) * | 2011-12-08 | 2012-06-27 | 江苏省建筑科学研究院有限公司 | Sludge and silt sintered brick with clay brick surface layer and preparation method thereof |
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