WO2014109215A1 - Construction structure and method for producing same - Google Patents
Construction structure and method for producing same Download PDFInfo
- Publication number
- WO2014109215A1 WO2014109215A1 PCT/JP2013/084339 JP2013084339W WO2014109215A1 WO 2014109215 A1 WO2014109215 A1 WO 2014109215A1 JP 2013084339 W JP2013084339 W JP 2013084339W WO 2014109215 A1 WO2014109215 A1 WO 2014109215A1
- Authority
- WO
- WIPO (PCT)
- Prior art keywords
- panel
- long
- building structure
- width direction
- foam
- Prior art date
Links
- 238000010276 construction Methods 0.000 title claims abstract 3
- 238000004519 manufacturing process Methods 0.000 title claims description 11
- 239000006260 foam Substances 0.000 claims abstract description 29
- 239000000463 material Substances 0.000 claims description 66
- 229920005862 polyol Polymers 0.000 description 60
- 150000003077 polyols Chemical class 0.000 description 44
- LYCAIKOWRPUZTN-UHFFFAOYSA-N Ethylene glycol Chemical compound OCCO LYCAIKOWRPUZTN-UHFFFAOYSA-N 0.000 description 31
- 239000000203 mixture Substances 0.000 description 30
- -1 polyol compound Chemical class 0.000 description 26
- 239000004721 Polyphenylene oxide Substances 0.000 description 22
- 229920000570 polyether Polymers 0.000 description 22
- PEDCQBHIVMGVHV-UHFFFAOYSA-N Glycerine Chemical compound OCC(O)CO PEDCQBHIVMGVHV-UHFFFAOYSA-N 0.000 description 19
- 229920001228 polyisocyanate Polymers 0.000 description 16
- 239000005056 polyisocyanate Substances 0.000 description 16
- MTHSVFCYNBDYFN-UHFFFAOYSA-N diethylene glycol Chemical compound OCCOCCO MTHSVFCYNBDYFN-UHFFFAOYSA-N 0.000 description 13
- WGCNASOHLSPBMP-UHFFFAOYSA-N hydroxyacetaldehyde Natural products OCC=O WGCNASOHLSPBMP-UHFFFAOYSA-N 0.000 description 13
- 229920005830 Polyurethane Foam Polymers 0.000 description 12
- 239000011496 polyurethane foam Substances 0.000 description 12
- 238000005187 foaming Methods 0.000 description 11
- 238000002156 mixing Methods 0.000 description 11
- 239000003999 initiator Substances 0.000 description 10
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 10
- GOOHAUXETOMSMM-UHFFFAOYSA-N Propylene oxide Chemical compound CC1CO1 GOOHAUXETOMSMM-UHFFFAOYSA-N 0.000 description 9
- IAYPIBMASNFSPL-UHFFFAOYSA-N Ethylene oxide Chemical compound C1CO1 IAYPIBMASNFSPL-UHFFFAOYSA-N 0.000 description 8
- 235000011187 glycerol Nutrition 0.000 description 8
- 238000000034 method Methods 0.000 description 8
- UPMLOUAZCHDJJD-UHFFFAOYSA-N 4,4'-Diphenylmethane Diisocyanate Chemical compound C1=CC(N=C=O)=CC=C1CC1=CC=C(N=C=O)C=C1 UPMLOUAZCHDJJD-UHFFFAOYSA-N 0.000 description 7
- 239000003054 catalyst Substances 0.000 description 7
- 125000002887 hydroxy group Chemical group [H]O* 0.000 description 7
- DNIAPMSPPWPWGF-UHFFFAOYSA-N Propylene glycol Chemical compound CC(O)CO DNIAPMSPPWPWGF-UHFFFAOYSA-N 0.000 description 6
- 238000012644 addition polymerization Methods 0.000 description 6
- 238000007906 compression Methods 0.000 description 6
- 230000006835 compression Effects 0.000 description 6
- 238000002347 injection Methods 0.000 description 6
- 239000007924 injection Substances 0.000 description 6
- 238000009413 insulation Methods 0.000 description 6
- 239000012948 isocyanate Substances 0.000 description 6
- 150000002513 isocyanates Chemical class 0.000 description 6
- 239000011550 stock solution Substances 0.000 description 6
- RNFJDJUURJAICM-UHFFFAOYSA-N 2,2,4,4,6,6-hexaphenoxy-1,3,5-triaza-2$l^{5},4$l^{5},6$l^{5}-triphosphacyclohexa-1,3,5-triene Chemical compound N=1P(OC=2C=CC=CC=2)(OC=2C=CC=CC=2)=NP(OC=2C=CC=CC=2)(OC=2C=CC=CC=2)=NP=1(OC=1C=CC=CC=1)OC1=CC=CC=C1 RNFJDJUURJAICM-UHFFFAOYSA-N 0.000 description 5
- 238000006243 chemical reaction Methods 0.000 description 5
- 150000001875 compounds Chemical class 0.000 description 5
- 239000003063 flame retardant Substances 0.000 description 5
- 229920000642 polymer Polymers 0.000 description 5
- 238000000926 separation method Methods 0.000 description 5
- 239000003381 stabilizer Substances 0.000 description 5
- PUPZLCDOIYMWBV-UHFFFAOYSA-N (+/-)-1,3-Butanediol Chemical compound CC(O)CCO PUPZLCDOIYMWBV-UHFFFAOYSA-N 0.000 description 4
- 125000002947 alkylene group Chemical group 0.000 description 4
- WERYXYBDKMZEQL-UHFFFAOYSA-N butane-1,4-diol Chemical compound OCCCCO WERYXYBDKMZEQL-UHFFFAOYSA-N 0.000 description 4
- 239000004088 foaming agent Substances 0.000 description 4
- 125000000524 functional group Chemical group 0.000 description 4
- 125000004435 hydrogen atom Chemical group [H]* 0.000 description 4
- IQPQWNKOIGAROB-UHFFFAOYSA-N isocyanate group Chemical group [N-]=C=O IQPQWNKOIGAROB-UHFFFAOYSA-N 0.000 description 4
- 239000002994 raw material Substances 0.000 description 4
- 239000004604 Blowing Agent Substances 0.000 description 3
- SJRJJKPEHAURKC-UHFFFAOYSA-N N-Methylmorpholine Chemical compound CN1CCOCC1 SJRJJKPEHAURKC-UHFFFAOYSA-N 0.000 description 3
- 125000001931 aliphatic group Chemical group 0.000 description 3
- SZXQTJUDPRGNJN-UHFFFAOYSA-N dipropylene glycol Chemical compound OCCCOCCCO SZXQTJUDPRGNJN-UHFFFAOYSA-N 0.000 description 3
- 230000000694 effects Effects 0.000 description 3
- 238000005227 gel permeation chromatography Methods 0.000 description 3
- 239000007788 liquid Substances 0.000 description 3
- 229920001296 polysiloxane Polymers 0.000 description 3
- 229920002635 polyurethane Polymers 0.000 description 3
- 239000004814 polyurethane Substances 0.000 description 3
- 238000007142 ring opening reaction Methods 0.000 description 3
- 239000012970 tertiary amine catalyst Substances 0.000 description 3
- OMDXZWUHIHTREC-UHFFFAOYSA-N 1-[2-(dimethylamino)ethoxy]ethanol Chemical compound CC(O)OCCN(C)C OMDXZWUHIHTREC-UHFFFAOYSA-N 0.000 description 2
- JOYRKODLDBILNP-UHFFFAOYSA-N Ethyl urethane Chemical compound CCOC(N)=O JOYRKODLDBILNP-UHFFFAOYSA-N 0.000 description 2
- NBIIXXVUZAFLBC-UHFFFAOYSA-N Phosphoric acid Chemical compound OP(O)(O)=O NBIIXXVUZAFLBC-UHFFFAOYSA-N 0.000 description 2
- PPBRXRYQALVLMV-UHFFFAOYSA-N Styrene Chemical compound C=CC1=CC=CC=C1 PPBRXRYQALVLMV-UHFFFAOYSA-N 0.000 description 2
- WYURNTSHIVDZCO-UHFFFAOYSA-N Tetrahydrofuran Chemical compound C1CCOC1 WYURNTSHIVDZCO-UHFFFAOYSA-N 0.000 description 2
- 150000001412 amines Chemical class 0.000 description 2
- 150000004982 aromatic amines Chemical class 0.000 description 2
- 238000011156 evaluation Methods 0.000 description 2
- XXMIOPMDWAUFGU-UHFFFAOYSA-N hexane-1,6-diol Chemical compound OCCCCCCO XXMIOPMDWAUFGU-UHFFFAOYSA-N 0.000 description 2
- 239000011810 insulating material Substances 0.000 description 2
- 239000011347 resin Substances 0.000 description 2
- 229920005989 resin Polymers 0.000 description 2
- 239000000126 substance Substances 0.000 description 2
- 150000005846 sugar alcohols Polymers 0.000 description 2
- 239000000057 synthetic resin Substances 0.000 description 2
- 229920003002 synthetic resin Polymers 0.000 description 2
- IMNIMPAHZVJRPE-UHFFFAOYSA-N triethylenediamine Chemical compound C1CN2CCN1CC2 IMNIMPAHZVJRPE-UHFFFAOYSA-N 0.000 description 2
- WTLBZVNBAKMVDP-UHFFFAOYSA-N tris(2-butoxyethyl) phosphate Chemical compound CCCCOCCOP(=O)(OCCOCCCC)OCCOCCCC WTLBZVNBAKMVDP-UHFFFAOYSA-N 0.000 description 2
- DNIAPMSPPWPWGF-GSVOUGTGSA-N (R)-(-)-Propylene glycol Chemical compound C[C@@H](O)CO DNIAPMSPPWPWGF-GSVOUGTGSA-N 0.000 description 1
- RBACIKXCRWGCBB-UHFFFAOYSA-N 1,2-Epoxybutane Chemical compound CCC1CO1 RBACIKXCRWGCBB-UHFFFAOYSA-N 0.000 description 1
- GEYOCULIXLDCMW-UHFFFAOYSA-N 1,2-phenylenediamine Chemical compound NC1=CC=CC=C1N GEYOCULIXLDCMW-UHFFFAOYSA-N 0.000 description 1
- CBCKQZAAMUWICA-UHFFFAOYSA-N 1,4-phenylenediamine Chemical compound NC1=CC=C(N)C=C1 CBCKQZAAMUWICA-UHFFFAOYSA-N 0.000 description 1
- DDHUNHGZUHZNKB-UHFFFAOYSA-N 2,2-dimethylpropane-1,3-diamine Chemical compound NCC(C)(C)CN DDHUNHGZUHZNKB-UHFFFAOYSA-N 0.000 description 1
- PQXKWPLDPFFDJP-UHFFFAOYSA-N 2,3-dimethyloxirane Chemical compound CC1OC1C PQXKWPLDPFFDJP-UHFFFAOYSA-N 0.000 description 1
- PISLZQACAJMAIO-UHFFFAOYSA-N 2,4-diethyl-6-methylbenzene-1,3-diamine Chemical compound CCC1=CC(C)=C(N)C(CC)=C1N PISLZQACAJMAIO-UHFFFAOYSA-N 0.000 description 1
- RLYCRLGLCUXUPO-UHFFFAOYSA-N 2,6-diaminotoluene Chemical compound CC1=C(N)C=CC=C1N RLYCRLGLCUXUPO-UHFFFAOYSA-N 0.000 description 1
- KKFDCBRMNNSAAW-UHFFFAOYSA-N 2-(morpholin-4-yl)ethanol Chemical compound OCCN1CCOCC1 KKFDCBRMNNSAAW-UHFFFAOYSA-N 0.000 description 1
- HZAXFHJVJLSVMW-UHFFFAOYSA-N 2-Aminoethan-1-ol Chemical compound NCCO HZAXFHJVJLSVMW-UHFFFAOYSA-N 0.000 description 1
- LCZVSXRMYJUNFX-UHFFFAOYSA-N 2-[2-(2-hydroxypropoxy)propoxy]propan-1-ol Chemical compound CC(O)COC(C)COC(C)CO LCZVSXRMYJUNFX-UHFFFAOYSA-N 0.000 description 1
- LSYBWANTZYUTGJ-UHFFFAOYSA-N 2-[2-(dimethylamino)ethyl-methylamino]ethanol Chemical compound CN(C)CCN(C)CCO LSYBWANTZYUTGJ-UHFFFAOYSA-N 0.000 description 1
- LIAWCKFOFPPVGF-UHFFFAOYSA-N 2-ethyladamantane Chemical compound C1C(C2)CC3CC1C(CC)C2C3 LIAWCKFOFPPVGF-UHFFFAOYSA-N 0.000 description 1
- WADSJYLPJPTMLN-UHFFFAOYSA-N 3-(cycloundecen-1-yl)-1,2-diazacycloundec-2-ene Chemical compound C1CCCCCCCCC=C1C1=NNCCCCCCCC1 WADSJYLPJPTMLN-UHFFFAOYSA-N 0.000 description 1
- YBRVSVVVWCFQMG-UHFFFAOYSA-N 4,4'-diaminodiphenylmethane Chemical compound C1=CC(N)=CC=C1CC1=CC=C(N)C=C1 YBRVSVVVWCFQMG-UHFFFAOYSA-N 0.000 description 1
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 1
- PIICEJLVQHRZGT-UHFFFAOYSA-N Ethylenediamine Chemical compound NCCN PIICEJLVQHRZGT-UHFFFAOYSA-N 0.000 description 1
- KWYHDKDOAIKMQN-UHFFFAOYSA-N N,N,N',N'-tetramethylethylenediamine Chemical compound CN(C)CCN(C)C KWYHDKDOAIKMQN-UHFFFAOYSA-N 0.000 description 1
- SVYKKECYCPFKGB-UHFFFAOYSA-N N,N-dimethylcyclohexylamine Chemical compound CN(C)C1CCCCC1 SVYKKECYCPFKGB-UHFFFAOYSA-N 0.000 description 1
- UEEJHVSXFDXPFK-UHFFFAOYSA-N N-dimethylaminoethanol Chemical compound CN(C)CCO UEEJHVSXFDXPFK-UHFFFAOYSA-N 0.000 description 1
- ABLZXFCXXLZCGV-UHFFFAOYSA-N Phosphorous acid Chemical class OP(O)=O ABLZXFCXXLZCGV-UHFFFAOYSA-N 0.000 description 1
- 239000004793 Polystyrene Substances 0.000 description 1
- 229920002323 Silicone foam Polymers 0.000 description 1
- AWMVMTVKBNGEAK-UHFFFAOYSA-N Styrene oxide Chemical compound C1OC1C1=CC=CC=C1 AWMVMTVKBNGEAK-UHFFFAOYSA-N 0.000 description 1
- WOURXYYHORRGQO-UHFFFAOYSA-N Tri(3-chloropropyl) phosphate Chemical compound ClCCCOP(=O)(OCCCCl)OCCCCl WOURXYYHORRGQO-UHFFFAOYSA-N 0.000 description 1
- XSTXAVWGXDQKEL-UHFFFAOYSA-N Trichloroethylene Chemical compound ClC=C(Cl)Cl XSTXAVWGXDQKEL-UHFFFAOYSA-N 0.000 description 1
- ZJCCRDAZUWHFQH-UHFFFAOYSA-N Trimethylolpropane Chemical compound CCC(CO)(CO)CO ZJCCRDAZUWHFQH-UHFFFAOYSA-N 0.000 description 1
- ORLQHILJRHBSAY-UHFFFAOYSA-N [1-(hydroxymethyl)cyclohexyl]methanol Chemical compound OCC1(CO)CCCCC1 ORLQHILJRHBSAY-UHFFFAOYSA-N 0.000 description 1
- 239000000654 additive Substances 0.000 description 1
- 150000001298 alcohols Chemical class 0.000 description 1
- 125000002723 alicyclic group Chemical group 0.000 description 1
- 125000005907 alkyl ester group Chemical group 0.000 description 1
- 125000005263 alkylenediamine group Chemical group 0.000 description 1
- WNROFYMDJYEPJX-UHFFFAOYSA-K aluminium hydroxide Chemical compound [OH-].[OH-].[OH-].[Al+3] WNROFYMDJYEPJX-UHFFFAOYSA-K 0.000 description 1
- 229910000147 aluminium phosphate Inorganic materials 0.000 description 1
- 239000003963 antioxidant agent Substances 0.000 description 1
- 230000003078 antioxidant effect Effects 0.000 description 1
- 125000003118 aryl group Chemical group 0.000 description 1
- 230000001588 bifunctional effect Effects 0.000 description 1
- 238000007664 blowing Methods 0.000 description 1
- 239000003086 colorant Substances 0.000 description 1
- 238000004891 communication Methods 0.000 description 1
- 238000013329 compounding Methods 0.000 description 1
- ZWAJLVLEBYIOTI-UHFFFAOYSA-N cyclohexene oxide Chemical compound C1CCCC2OC21 ZWAJLVLEBYIOTI-UHFFFAOYSA-N 0.000 description 1
- FWFSEYBSWVRWGL-UHFFFAOYSA-N cyclohexene oxide Natural products O=C1CCCC=C1 FWFSEYBSWVRWGL-UHFFFAOYSA-N 0.000 description 1
- 230000006866 deterioration Effects 0.000 description 1
- 150000004985 diamines Chemical class 0.000 description 1
- ZBCBWPMODOFKDW-UHFFFAOYSA-N diethanolamine Chemical compound OCCNCCO ZBCBWPMODOFKDW-UHFFFAOYSA-N 0.000 description 1
- 239000004205 dimethyl polysiloxane Substances 0.000 description 1
- IUNMPGNGSSIWFP-UHFFFAOYSA-N dimethylaminopropylamine Chemical compound CN(C)CCCN IUNMPGNGSSIWFP-UHFFFAOYSA-N 0.000 description 1
- 239000003480 eluent Substances 0.000 description 1
- 239000004872 foam stabilizing agent Substances 0.000 description 1
- 238000009472 formulation Methods 0.000 description 1
- 229920000578 graft copolymer Polymers 0.000 description 1
- 229910052736 halogen Inorganic materials 0.000 description 1
- 150000002367 halogens Chemical class 0.000 description 1
- 125000004836 hexamethylene group Chemical group [H]C([H])([*:2])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])[*:1] 0.000 description 1
- 229910052739 hydrogen Inorganic materials 0.000 description 1
- 239000001257 hydrogen Substances 0.000 description 1
- 238000000691 measurement method Methods 0.000 description 1
- 150000002736 metal compounds Chemical class 0.000 description 1
- 238000012986 modification Methods 0.000 description 1
- 230000004048 modification Effects 0.000 description 1
- TXXWBTOATXBWDR-UHFFFAOYSA-N n,n,n',n'-tetramethylhexane-1,6-diamine Chemical compound CN(C)CCCCCCN(C)C TXXWBTOATXBWDR-UHFFFAOYSA-N 0.000 description 1
- UFWIBTONFRDIAS-UHFFFAOYSA-N naphthalene-acid Natural products C1=CC=CC2=CC=CC=C21 UFWIBTONFRDIAS-UHFFFAOYSA-N 0.000 description 1
- SLCVBVWXLSEKPL-UHFFFAOYSA-N neopentyl glycol Chemical class OCC(C)(C)CO SLCVBVWXLSEKPL-UHFFFAOYSA-N 0.000 description 1
- 239000002736 nonionic surfactant Substances 0.000 description 1
- 125000005702 oxyalkylene group Chemical group 0.000 description 1
- 125000006353 oxyethylene group Chemical group 0.000 description 1
- WXZMFSXDPGVJKK-UHFFFAOYSA-N pentaerythritol Chemical compound OCC(CO)(CO)CO WXZMFSXDPGVJKK-UHFFFAOYSA-N 0.000 description 1
- UKODFQOELJFMII-UHFFFAOYSA-N pentamethyldiethylenetriamine Chemical compound CN(C)CCN(C)CCN(C)C UKODFQOELJFMII-UHFFFAOYSA-N 0.000 description 1
- 239000005011 phenolic resin Substances 0.000 description 1
- 150000003014 phosphoric acid esters Chemical class 0.000 description 1
- 230000000704 physical effect Effects 0.000 description 1
- 229920000435 poly(dimethylsiloxane) Polymers 0.000 description 1
- 229920002223 polystyrene Polymers 0.000 description 1
- 238000002360 preparation method Methods 0.000 description 1
- 238000003825 pressing Methods 0.000 description 1
- AOHJOMMDDJHIJH-UHFFFAOYSA-N propylenediamine Chemical compound CC(N)CN AOHJOMMDDJHIJH-UHFFFAOYSA-N 0.000 description 1
- KIDHWZJUCRJVML-UHFFFAOYSA-N putrescine Chemical compound NCCCCN KIDHWZJUCRJVML-UHFFFAOYSA-N 0.000 description 1
- 229920006300 shrink film Polymers 0.000 description 1
- 239000013514 silicone foam Substances 0.000 description 1
- 238000003756 stirring Methods 0.000 description 1
- 230000008961 swelling Effects 0.000 description 1
- YLQBMQCUIZJEEH-UHFFFAOYSA-N tetrahydrofuran Natural products C=1C=COC=1 YLQBMQCUIZJEEH-UHFFFAOYSA-N 0.000 description 1
- 229920002803 thermoplastic polyurethane Polymers 0.000 description 1
- STCOOQWBFONSKY-UHFFFAOYSA-N tributyl phosphate Chemical compound CCCCOP(=O)(OCCCC)OCCCC STCOOQWBFONSKY-UHFFFAOYSA-N 0.000 description 1
- DQWPFSLDHJDLRL-UHFFFAOYSA-N triethyl phosphate Chemical compound CCOP(=O)(OCC)OCC DQWPFSLDHJDLRL-UHFFFAOYSA-N 0.000 description 1
- WVLBCYQITXONBZ-UHFFFAOYSA-N trimethyl phosphate Chemical compound COP(=O)(OC)OC WVLBCYQITXONBZ-UHFFFAOYSA-N 0.000 description 1
- 150000004072 triols Chemical class 0.000 description 1
- 125000000391 vinyl group Chemical group [H]C([*])=C([H])[H] 0.000 description 1
- 229920002554 vinyl polymer Polymers 0.000 description 1
Images
Classifications
-
- E—FIXED CONSTRUCTIONS
- E04—BUILDING
- E04B—GENERAL BUILDING CONSTRUCTIONS; WALLS, e.g. PARTITIONS; ROOFS; FLOORS; CEILINGS; INSULATION OR OTHER PROTECTION OF BUILDINGS
- E04B2/00—Walls, e.g. partitions, for buildings; Wall construction with regard to insulation; Connections specially adapted to walls
- E04B2/56—Load-bearing walls of framework or pillarwork; Walls incorporating load-bearing elongated members
- E04B2/562—Load-bearing walls of framework or pillarwork; Walls incorporating load-bearing elongated members with fillings between the load-bearing elongated members
-
- E—FIXED CONSTRUCTIONS
- E04—BUILDING
- E04B—GENERAL BUILDING CONSTRUCTIONS; WALLS, e.g. PARTITIONS; ROOFS; FLOORS; CEILINGS; INSULATION OR OTHER PROTECTION OF BUILDINGS
- E04B1/00—Constructions in general; Structures which are not restricted either to walls, e.g. partitions, or floors or ceilings or roofs
- E04B1/62—Insulation or other protection; Elements or use of specified material therefor
- E04B1/74—Heat, sound or noise insulation, absorption, or reflection; Other building methods affording favourable thermal or acoustical conditions, e.g. accumulating of heat within walls
- E04B1/76—Heat, sound or noise insulation, absorption, or reflection; Other building methods affording favourable thermal or acoustical conditions, e.g. accumulating of heat within walls specifically with respect to heat only
- E04B1/7654—Heat, sound or noise insulation, absorption, or reflection; Other building methods affording favourable thermal or acoustical conditions, e.g. accumulating of heat within walls specifically with respect to heat only comprising an insulating layer, disposed between two longitudinal supporting elements, e.g. to insulate ceilings
-
- E—FIXED CONSTRUCTIONS
- E04—BUILDING
- E04C—STRUCTURAL ELEMENTS; BUILDING MATERIALS
- E04C2/00—Building elements of relatively thin form for the construction of parts of buildings, e.g. sheet materials, slabs, or panels
- E04C2/02—Building elements of relatively thin form for the construction of parts of buildings, e.g. sheet materials, slabs, or panels characterised by specified materials
- E04C2/10—Building elements of relatively thin form for the construction of parts of buildings, e.g. sheet materials, slabs, or panels characterised by specified materials of wood, fibres, chips, vegetable stems, or the like; of plastics; of foamed products
- E04C2/24—Building elements of relatively thin form for the construction of parts of buildings, e.g. sheet materials, slabs, or panels characterised by specified materials of wood, fibres, chips, vegetable stems, or the like; of plastics; of foamed products laminated and composed of materials covered by two or more of groups E04C2/12, E04C2/16, E04C2/20
-
- E—FIXED CONSTRUCTIONS
- E04—BUILDING
- E04C—STRUCTURAL ELEMENTS; BUILDING MATERIALS
- E04C2/00—Building elements of relatively thin form for the construction of parts of buildings, e.g. sheet materials, slabs, or panels
- E04C2/30—Building elements of relatively thin form for the construction of parts of buildings, e.g. sheet materials, slabs, or panels characterised by the shape or structure
- E04C2/38—Building elements of relatively thin form for the construction of parts of buildings, e.g. sheet materials, slabs, or panels characterised by the shape or structure with attached ribs, flanges, or the like, e.g. framed panels
- E04C2/386—Building elements of relatively thin form for the construction of parts of buildings, e.g. sheet materials, slabs, or panels characterised by the shape or structure with attached ribs, flanges, or the like, e.g. framed panels with a frame of unreconstituted or laminated wood
-
- E—FIXED CONSTRUCTIONS
- E04—BUILDING
- E04B—GENERAL BUILDING CONSTRUCTIONS; WALLS, e.g. PARTITIONS; ROOFS; FLOORS; CEILINGS; INSULATION OR OTHER PROTECTION OF BUILDINGS
- E04B1/00—Constructions in general; Structures which are not restricted either to walls, e.g. partitions, or floors or ceilings or roofs
- E04B1/62—Insulation or other protection; Elements or use of specified material therefor
- E04B1/74—Heat, sound or noise insulation, absorption, or reflection; Other building methods affording favourable thermal or acoustical conditions, e.g. accumulating of heat within walls
- E04B1/76—Heat, sound or noise insulation, absorption, or reflection; Other building methods affording favourable thermal or acoustical conditions, e.g. accumulating of heat within walls specifically with respect to heat only
- E04B1/78—Heat insulating elements
- E04B1/80—Heat insulating elements slab-shaped
-
- E—FIXED CONSTRUCTIONS
- E04—BUILDING
- E04B—GENERAL BUILDING CONSTRUCTIONS; WALLS, e.g. PARTITIONS; ROOFS; FLOORS; CEILINGS; INSULATION OR OTHER PROTECTION OF BUILDINGS
- E04B1/00—Constructions in general; Structures which are not restricted either to walls, e.g. partitions, or floors or ceilings or roofs
- E04B1/62—Insulation or other protection; Elements or use of specified material therefor
- E04B1/74—Heat, sound or noise insulation, absorption, or reflection; Other building methods affording favourable thermal or acoustical conditions, e.g. accumulating of heat within walls
- E04B2001/742—Use of special materials; Materials having special structures or shape
-
- E—FIXED CONSTRUCTIONS
- E04—BUILDING
- E04B—GENERAL BUILDING CONSTRUCTIONS; WALLS, e.g. PARTITIONS; ROOFS; FLOORS; CEILINGS; INSULATION OR OTHER PROTECTION OF BUILDINGS
- E04B1/00—Constructions in general; Structures which are not restricted either to walls, e.g. partitions, or floors or ceilings or roofs
- E04B1/62—Insulation or other protection; Elements or use of specified material therefor
- E04B1/74—Heat, sound or noise insulation, absorption, or reflection; Other building methods affording favourable thermal or acoustical conditions, e.g. accumulating of heat within walls
- E04B1/76—Heat, sound or noise insulation, absorption, or reflection; Other building methods affording favourable thermal or acoustical conditions, e.g. accumulating of heat within walls specifically with respect to heat only
- E04B2001/7695—Panels with adjustable width
Definitions
- the present invention relates to a building structure in which a panel is fitted between a plurality of long materials arranged in parallel, and a method for manufacturing the same.
- a building structure a plurality of long materials (for example, pillars and the like) arranged in the width direction and a hard panel fitted between the long materials so that the longitudinal directions thereof are parallel to each other are provided.
- a building structure is known (for example, Patent Document 1).
- the panel is a heat insulating material made of synthetic resin.
- the present invention provides a building structure that can easily fit a panel between long materials and prevent a gap from being generated between the panel and the long material, and a method for manufacturing the same.
- the issue is to provide.
- the building structure according to the present invention includes a plurality of long members arranged in parallel in a second direction orthogonal to the first direction, such that the longitudinal directions thereof are parallel to each other in the first direction, and the long A panel that is fitted between the scale members, and the panel has a plurality of cells that are elongated along a direction orthogonal to the second direction so as to have elasticity in the second direction. It is a foam.
- the plurality of long members are juxtaposed in the second direction orthogonal to the first direction so that the longitudinal directions of the long members are parallel to each other in the first direction.
- the panel is a foam having a plurality of cells formed elongated along a direction orthogonal to the second direction, the panel has elasticity in the second direction. Therefore, when the panel compressed in the second direction is released and restored between the long materials (or the panel is fitted between the long materials while being compressed in the second direction), the panel is It is fitted between the long materials while being in close contact with the long material and pressing the long material.
- the plurality of cells are arranged such that an elastic modulus in the second direction of the panel is smaller than an elastic modulus in the first direction of the panel. It may be configured to be elongated along the direction of 1.
- the elastic modulus in the second direction of the panel is reduced.
- the panel since the panel has elasticity in the second direction, the panel is easily compressed in the second direction.
- the elastic modulus in the first direction of the panel is increased. Accordingly, since the panel has rigidity in the first direction, the panel fitted between the long materials is stably held between the long materials.
- the manufacturing method of the building structure which concerns on this invention is the some elongate paralleled by the 2nd direction orthogonal to the said 1st direction so that a mutual longitudinal direction may become parallel in a 1st direction.
- the present invention has an excellent effect that a panel can be easily fitted between long materials, and a gap can be prevented from being generated between the panel and the long material.
- FIG. 1 shows the principal part front view of the building structure which concerns on one Embodiment of this invention.
- FIG. 2 is a sectional view taken along line II-II in FIG.
- FIG. 3 is an overall perspective view of the panel according to the embodiment.
- FIG. 4 is an enlarged cross-sectional view of a main part taken along line IV-IV in FIG.
- FIG. 5 shows the principal part perspective view explaining the manufacturing method of the panel which concerns on the same embodiment.
- FIG. 6 shows the principal part cross-sectional view explaining the manufacturing method of the building structure which concerns on the embodiment.
- FIG. 7 shows the principal part front view of the building structure which concerns on other embodiment of this invention.
- FIG. 8 shows the principal part cross-sectional view of the building structure which concerns on further another embodiment of this invention.
- FIG. 1 shows the principal part front view of the building structure which concerns on one Embodiment of this invention.
- FIG. 2 is a sectional view taken along line II-II in FIG.
- FIG. 3 is an overall perspective
- FIG. 9 shows the principal part cross-sectional view of the building structure which concerns on further another embodiment of this invention.
- FIG. 10 shows the principal part cross-sectional view of the building structure which concerns on further another embodiment of this invention.
- FIG. 11 shows an evaluation table of an embodiment according to the present invention.
- the building structure 1 which concerns on this embodiment is the multiple (it is two figures in FIG.1 and FIG.2) arranged in the width direction so that a mutual longitudinal direction may become parallel.
- the building structure 1 includes frame members 4 and 4 that are fixed to end portions of the long material 2, and a plate member 5 that is fixed to a side portion of the long material 2.
- the building structure 1 is a wall.
- the long material 2 includes support surfaces 21 and 21 that support the panel 3 on both sides in the width direction.
- the cross-sectional shape of the long material 2 is a rectangular shape.
- the plurality of long materials 2 are arranged so that the support surfaces 21 face each other.
- the long material 2 is a pillar, and is arranged so that the longitudinal direction is parallel to the height direction.
- the panel 3 is formed in a rectangular parallelepiped shape. In the state in which the panel 3 is fitted between the long members 2 and 2, the longitudinal direction of the panel 3 and the longitudinal direction of the long member 2 are parallel, and the width direction of the panel 3 and the width direction of the long member 2. And are parallel.
- the direction parallel to the longitudinal direction of the long material 2 is referred to as a first direction D1 of each of the building structure 1, the long material 2 and the panel 3, and is parallel to the direction in which the long materials 2 are juxtaposed.
- the direction is referred to as the second direction D2 of the building structure 1, the long material 2 and the panel 3, and the direction perpendicular to the first direction D1 and the second direction D2 is the building structure 1, long length.
- Each of the material 2 and the panel 3 is referred to as a third direction D3.
- the first direction D1 of the panel 3 is the longitudinal direction (vertical direction) of the panel 3
- the second direction D2 of the panel 3 is the width direction of the panel 3
- the third direction D3 is the thickness direction of the panel 3.
- the directions corresponding to the first to third directions D1, D2, and D3 are denoted by D1, D2, and D3, respectively.
- the panel 3 is formed of a synthetic resin (for example, urethane resin, styrene resin, phenol resin, etc.) and is a foam having elasticity.
- the panel 3 is a foam having a plurality of cells 31 that are formed in a long direction along a direction orthogonal to the width direction D2 so as to have elasticity in the width direction D2.
- the panel 3 has elasticity in the second direction D2.
- more than half of the cells 31 need only be formed long along a direction orthogonal to the second direction D2. That is, in the present invention, as long as the panel 3 has elasticity in the second direction D2, the cells 31 that are elongated along the direction parallel to the second direction D2 may be provided. .
- the panel 3 is formed so that the elastic modulus in the width direction D2 is smaller than the elastic modulus in the longitudinal direction D1.
- the panel 3 is formed so that the elastic modulus in the width direction D2 and the elastic modulus in the thickness direction D3 are substantially the same.
- the panel 3 has a plurality of cells 31 that are elongated along the longitudinal direction D1 in the direction orthogonal to the width direction D2, so that the elastic modulus in the width direction D2 is the same as that in the longitudinal direction D1. It is formed so as to be smaller than the elastic modulus. More specifically, the plurality of cells 31 are arranged with the longest dimension along the longitudinal direction D1, so that the elastic modulus in the width direction D2 and the thickness direction D3 of the panel 3 is the longitudinal direction D1. It is smaller than the elastic modulus.
- the elastic modulus is a ratio between stress and strain (deformation amount) within the elastic range when the panel 3 is deformed by applying an external force. In other words, the smaller the elastic modulus, the greater the amount of deformation with the same stress (pressure).
- the dimension W2 in the width direction D2 of the panel 3 that is not elastically deformed is larger than the separation distance W1 between the long materials 2 and 2, the panel 3 is compressed and deformed in the width direction D2 and It is fitted between the two.
- the dimension W2 in the width direction D2 of the panel 3 that is not elastically deformed is preferably 101% to 115%, more preferably 105% to 110% of the separation distance W1 of the long materials 2 and 2.
- the panel 3 is a polyurethane foam panel.
- the configuration of the panel 3 will be described in detail below.
- the panel 3 is obtained by mixing and reacting a polyol composition containing a polyol compound and water as a foaming agent, and a polyisocyanate component.
- the panel 3 has a longitudinal direction (longitudinal direction) D1, a width direction D2, and a thickness direction D3.
- a polyurethane foam panel with the ratio of 10% compression strength S D2 of a 10% compression strength S D1 and the width direction D2 of the foam density is 15 kg / m 3 or less and a vertical direction D1 (S D1 / S D2) is It is set to be 2 or more.
- the foam density (core density) of the panel 3 is preferably 15 kg / m 3 or less, more preferably 13 kg / m 3 or less, and further preferably 11 kg / m 3 or less.
- foam density is set within the above range, for example, by adjusting the amount of water as a blowing agent to 20 to 100 parts by weight (with respect to 100 parts by weight of the polyol compound).
- the foam density is a value measured according to JIS K7222.
- the foam density of the panel 3 is 15 kg / m 3 or less, it is very low, and the expansion ratio of the panel 3 is high. Therefore, the cell 31 is stretched in the vertical direction D1 and formed in an ellipsoidal shape.
- the major axis direction of the ellipsoidal cell 31 is parallel to the longitudinal direction D1 of the panel 3, the foam strength in the longitudinal direction D1 of the panel 3 is increased, while the foam strength in the width direction D2 and the thickness direction D3 of the panel 3 is increased.
- the width direction D2 and the thickness direction D3 of the panel 3 have elasticity (flexibility).
- the ratio between the 10% compressive strength S D2 of a 10% compression strength S D1 and the width direction D2 in the vertical direction D1 (S D1 / S D2) is 2 or more, are formed.
- the ratio to S D2 (S D1 / S D2 ) is preferably 3 or more, and more preferably 5 or more.
- the upper limit of the ratio (S D1 / S D2 ) is not particularly limited, but is about 7, for example.
- the X% compressive strength is a stress necessary for compressing and deforming the panel 3 by an amount of X%.
- 10% compression strength S D2 in the width direction D2 of the panel 3 it is preferably 3N / cm 2 or less, more preferably 1N / cm 2 or less, 0.5 N / cm 2 or less Is particularly preferred.
- the compressed panel 3 is quickly restored. Therefore, when the panel 3 is not damaged or destroyed even if it is compressed 20% in the width direction D2, and is opened after being compressed 20% in the width direction D2, the panel 3 has a dimension of 90 in the width direction D2 before compression. It is preferable to restore to% or more.
- the foaming direction of the cells 31 is substantially perpendicular to the width direction D2 and the thickness direction D3, respectively.
- substantially vertical means 90 ° ⁇ 15 °, particularly 90 ° ⁇ 10 °.
- the “cell foaming direction” means a major axis direction when the shape of each cell 31 is regarded as an ellipsoid, and in particular, a central portion of the panel 3 in the width direction D2 (the vertical direction D1 and the width direction D2). The direction when measured from the center at a portion of about 10% on both sides of the dimension in the longitudinal direction D1 and the dimension in the width direction D2 is assumed.
- the thermal conductivity ⁇ of the panel 3 is preferably 0.04 W / m ⁇ K or less. Thereby, even if it is the panel 3 reduced in density, sufficient heat insulation performance can be exhibited.
- the thermal conductivity is a value measured according to JIS A1412-2.
- the closed cell ratio of panel 3 is preferably 15% or less, and more preferably 0 to 10%. Thus, by increasing the communication rate, excellent dimensional stability can be ensured.
- the closed cell ratio is a value measured according to ASTM D2856.
- the panel 3 is obtained by mixing and reacting a polyol composition containing a polyol compound and water as a foaming agent and a polyisocyanate component.
- the polyol compound has an average functional group number of 2 to 4 and a weight average molecular weight of 3000 to 8000, a polyether polyol (A) which is a polymer of alkylene oxide, and a short glycol (B And).
- the polyether polyol (A) is a polyoxyalkylene polyol obtained by ring-opening addition polymerization of alkylene oxide to an initiator having 2 to 4 active hydrogen atoms.
- the initiator examples include aliphatic polyhydric alcohols (for example, ethylene glycol, propylene glycol, diethylene glycol, dipropylene glycol, 1,4-butanediol, 1,3-butanediol, 1,6-hexanediol, neopentyl Glycols such as glycol, cyclohexylene glycol and cyclohexanedimethanol, triols such as trimethylolpropane and glycerin, tetrafunctional alcohols such as pentaerythritol), aliphatic amines (eg ethylenediamine, propylenediamine, butylenediamine, hexamethylene) Alkylenediamines such as diamine and neopentyldiamine, alkanolamines such as monoethanolamine and diethanolamine), aromatic amines (eg, 2,4-toluenedia) Emissions, 2,6-toluene
- the polyether polyol (A) has an average number of functional groups of 2 to 4, more preferably 2.5 to 3.5. Further, the polyether polyol (A) preferably has a weight average molecular weight of 3000 to 5000.
- alkylene oxide examples include ethylene oxide, propylene oxide, 1,2-butylene oxide, 2,3-butylene oxide, styrene oxide, and cyclohexene oxide.
- ethylene oxide and propylene oxide in combination to cause ring-opening addition polymerization to the initiator.
- the ratio of ethylene oxide ((ethylene oxide) / (ethylene oxide + propylene oxide)) is preferably 5% to 30%.
- the hydroxyl value of the polyether polyol (A) is preferably 20 to 100 mgKOH / g, and more preferably 30 to 60 mgKOH / g.
- the hydroxyl value is less than 20 mgKOH / g, the viscosity ratio of the polyol composition to the polyisocyanate component becomes high, resulting in poor stirring during mixing.
- it exceeds 100 mgKOH / g it becomes difficult to impart moderate toughness to the obtained polyurethane foam.
- the hydroxyl value is a value measured according to JIS K1557-1: 2007.
- Short glycol (B) having a molecular weight of less than 250 includes, for example, ethylene glycol (molecular weight 62), propylene glycol (molecular weight 76), diethylene glycol (molecular weight 106), dipropylene glycol (molecular weight 134), 1,4-butanediol ( Examples include molecular weight 90), 1,3-butanediol (molecular weight 90), 1,6-hexanediol (molecular weight 118), glycerin (molecular weight 92), and tripropylene glycol (molecular weight 192).
- the molecular weight of the short glycol (B) is preferably 62 to 200 mgKOH / g, and more preferably 90 to 150 mgKOH / g.
- the polyol compound further contains a polyether polyol (C) which has an average functional group number of 2 to 4 and a weight average molecular weight of 3000 to 5000 and is a propylene oxide polymer. It is preferable.
- the polyether polyol (C) is a polyoxyalkylene polyol obtained by ring-opening addition polymerization of propylene oxide alone to an initiator having 2 to 4 active hydrogen atoms. Examples of the initiator include the aliphatic polyhydric alcohols, aliphatic amines, and aromatic amines described above, and are not particularly limited. As the initiator, glycerin is particularly preferable.
- the polyol composition used as a raw material contains 10 to 80 parts by weight of the polyether polyol (A) in 100 parts by weight of the polyol compound in order to produce a polyurethane foam panel 3 having a low density and excellent heat insulating performance. It is preferable to contain 10 to 60 parts by weight of the short glycol (B), more preferably 15 to 70 parts by weight of the polyether polyol (A), and more preferably 10 to 50 parts by weight of the short glycol (B).
- the polyether polyol (C) is contained, the polyether polyol (A) is contained in an amount of 10 to 30 parts by weight, the short glycol (B) is contained in an amount of 10 to 60 parts by weight, and the polyether polyol (C) is contained.
- polyether polyol A
- 10 to 50 parts by weight of short glycol B
- polyether polyol C
- water is blended as a foaming agent.
- the blowing agent is preferably water alone, and the blending amount thereof is preferably 20 to 100 parts by weight, more preferably 30 to 90 parts by weight, more preferably 40 to 40 parts by weight based on 100 parts by weight of the polyol compound. More preferably, it is 80 parts by weight.
- the density of the panel 3 can be reduced by blending a large amount of water.
- the flame retardant, catalyst and foam stabilizer are usually further added to the polyol composition.
- various additives such as a coloring agent and antioxidant, may further be mix
- the flame retardant examples include metal compounds such as organophosphates, halogen-containing compounds, and aluminum hydroxide. Particularly, organophosphates are preferable because they have an effect of reducing the viscosity of the polyol composition.
- organophosphates are preferable because they have an effect of reducing the viscosity of the polyol composition.
- organic phosphate esters include halogenated alkyl esters, alkyl phosphate esters, aryl phosphate esters, and phosphonate esters of phosphoric acid.
- the blending amount of the flame retardant is preferably 10 to 50 parts by weight, more preferably 15 to 40 parts by weight with respect to 100 parts by weight of the polyol compound.
- the flame retardant in addition to the polyether polyol (A) and the short glycol (B) in the polyol composition, is 20 parts by weight with respect to 100 parts by weight of the polyol compound. It is preferable to contain above.
- the catalyst is not particularly limited as long as it is a catalyst that accelerates the urethanization reaction, but it is preferable to use a reactive amine catalyst that can react with the isocyanate group of the polyisocyanate component.
- reactive amine catalysts include N, N-dimethylethanolamine, N, N-dimethylaminoethoxyethanol, N, N, N′-trimethylaminoethylethanolamine, N, N, N ′, N ′.
- a normal tertiary amine catalyst can also be used, and as such a tertiary amine catalyst, N, N, N ′, N′-tetramethylethylenediamine, N, N, N ′, N′— Examples thereof include tetramethylhexamethylenediamine, N, N, N ′, N ′, N ′′ -pentamethyldiethylenetriamine, diazabicycloundecene, N, N-dimethylcyclohexylamine, triethylenediamine, N-methylmorpholine and the like.
- the compounding amount of the catalyst is preferably 2 to 10 parts by weight, and more preferably 3 to 8 parts by weight with respect to 100 parts by weight of the polyol compound.
- foam stabilizer examples include, among known foam stabilizers for polyurethane foam, a graft copolymer of polyoxyalkylene glycol, which is a polymer of ethylene oxide or propylene oxide, and polydimethylsiloxane. Silicone foam stabilizers having an oxyethylene group content of 70 to 100 mol% in oxyalkylene are preferably used. Specifically, SH-193, SF-2937F, SF-2938F (manufactured by Toray Dow Corning Silicone), B-8465, B-8467, B-8481 (manufactured by Evonik Degussa Japan), L-6900 (manufactured by Momentive) and the like. The blending amount of the foam stabilizer is preferably 1 to 10 parts by weight with respect to 100 parts by weight of the polyol compound.
- polyisocyanate compounds such as aromatic, alicyclic and aliphatic polyisocyanates having two or more isocyanate groups are used as the polyisocyanate component which is mixed and reacted with the polyol composition to form the polyurethane foam panel 3.
- polyisocyanate component which is mixed and reacted with the polyol composition to form the polyurethane foam panel 3.
- MDI liquid diphenylmethane diisocyanate
- Liquid MDIs include Crude MDI (c-MDI) (44V-10, 44V-20, etc.
- polyisocyanate compounds known in the technical field of polyurethane can be used without limitation.
- Panel 3 preferably has an isocyanate index (NCO Index) of 30 or less, more preferably less than 30, when the polyol composition and the polyisocyanate component are mixed and reacted.
- NCO Index isocyanate index
- 20 is mentioned, for example.
- the isocyanate index is the percentage equivalent of the isocyanate group of the polyisocyanate component to all active hydrogen groups contained in the polyol composition (calculated using water as a blowing agent as a bifunctional active hydrogen compound). (Equivalent ratio of isocyanate groups to 100 equivalents of active hydrogen groups).
- the manufacturing method of the panel 3 is a manufacturing method of the polyurethane foam panel 3 obtained by making into a raw material the foaming stock solution composition containing the polyol composition containing the polyol compound and water which is a foaming agent, and a polyisocyanate component.
- a polyol compound has a polyol composition having an average functional group number of 2 to 4, a weight average molecular weight of 3000 to 8000, and a polyether polyol (A) which is a polymer of alkylene oxide, and a molecular weight.
- a polyol compound containing a short glycol (B) having a water content of less than 250, and containing 20 to 100 parts by weight of water with respect to 100 parts by weight of the polyol compound, the polyol composition and the polyisocyanate component Preferably, the isocyanate index when mixing and reacting with Arbitrariness.
- the plurality of cells 31 In order for the plurality of cells 31 to be formed along the longitudinal direction D1 of the panel 3 so that the panel 3 has elasticity in the width direction D2, as shown in FIG.
- an injection step of injecting the foaming stock solution composition with the surface extending along the width direction D2 and the thickness direction D3 as the bottom surface 71, and the foaming stock solution composition after the injection step It is preferable to provide a reaction step.
- the mixing head 8 has a bottom surface 71 as a surface extending along the width direction D2 and the thickness direction D3 with respect to the mold 7 having the vertical direction D1, the width direction D2, and the thickness direction D3. Then, a foaming stock solution composition containing a polyol composition and a polyisocyanate component is injected (injection step). After injection, the foamed stock solution composition reacts and forms a foam while foaming (swelling) in the longitudinal direction D1 (reaction process). In the reaction step, the mold 7 may be heated as a whole or locally as necessary.
- the configuration of the building structure 1 according to this embodiment is as described above. Next, a method for manufacturing the building structure 1 according to this embodiment will be described below with reference to FIG.
- the plurality of long materials 2 and 2 are juxtaposed in the width direction D2 so that the longitudinal direction D1 is parallel.
- the panel 3 is compressed in the width direction D2. Accordingly, the dimension W2 in the width direction D2 of the panel 3 which is larger than the separation distance W1 between the long materials 2 and 2 is smaller than the separation distance W1 between the long materials 2 and 2.
- the applied external force is released, so that the panel 3 is restored. Since the panel 3 tries to be further restored by the elastic force even after contacting the support surface 21 of the long material 2, the long material 2 is in close contact with the long material 2 and presses the long material 2. , Fits between the two.
- the plurality of long members 2 are orthogonal to the first direction D1 such that the longitudinal directions of the plurality of long members 2 are parallel to each other in the first direction D1.
- Two directions D2 are arranged in parallel.
- the panel 3 is a foam having a plurality of cells 31 that are elongated along a direction orthogonal to the second direction D2, the panel 3 has elasticity in the second direction D2.
- the building structure 1 allows the panel 3 to be easily fitted between the long members 2 and 2 and prevents a gap from being generated between the panel 3 and the long member 2. it can.
- the building structure 1 which concerns on this embodiment, since the several cell 31 is formed elongate along the direction orthogonal to the 2nd direction D2, the elasticity in the 2nd direction D2 of the panel 3 is provided. The rate is reduced. Thereby, since the panel 3 has elasticity in the second direction D2, the panel 3 is easily compressed in the second direction D2.
- the elastic modulus of the panel 3 in the first direction D1 is large. Become. Thereby, since the panel 3 has rigidity in the first direction D1, the panel 3 fitted between the long materials 2 and 2 is stably held between the long materials 2 and 2. As a result, the panel 3 can stand on its own.
- the heat insulation performance in the third direction D3 of the panel 3 is improved. It can also be made.
- this invention is not limited to the structure of above-described embodiment, and is not limited to the above-mentioned effect. It goes without saying that the present invention can be variously modified without departing from the gist of the present invention. For example, it is needless to say that configurations, methods, and the like according to various modifications described below may be arbitrarily selected and employed in the configurations, methods, and the like according to the above-described embodiments.
- one panel 3 is configured to be fitted between the long materials 2 and 2.
- the present invention is not limited to such a configuration.
- a plurality of panels 3 may be arranged in parallel in the first direction D ⁇ b> 1 and fitted between the long members 2 and 2.
- a plurality of panels 3 may be arranged in parallel in the second direction D2 and fitted between the long materials 2 and 2.
- the panel 3 when the first direction D ⁇ b> 1 is configured to be the height direction, the panel 3 includes a plurality of cells 31 that are elongated along the first direction D ⁇ b> 1.
- the elastic modulus in the width direction D2 is formed to be smaller than the elastic modulus in the longitudinal direction D1.
- adjacent panel end portions 32, 32 abut at positions deviated from between the long materials 2, 2, and the opposite panel end portions 33, 33 are long. It is located between the scale members 2 and 2 and is in contact with the long member 2 and the plate member 5. And the panel 3 receives external force so that the adjacent panel edge parts 32 and 32 are located between the elongate materials 2 and 2, and the panel 3 is compressed in the 2nd direction D2, while the elongate materials 2 and 2 are received. Fit between two.
- the panel 3 is configured such that the dimension in the first direction D1 is larger than the dimension in the second direction D2.
- the present invention is not limited to such a configuration.
- the panel 3 may be formed such that the dimension in the first direction D1 is smaller than the dimension in the second direction D2.
- the long material 2 is a pillar, and the building structure 1 is a wall.
- the present invention is not limited to such a configuration.
- the long material 2 may be a floor joist in which the first direction (longitudinal direction) D1 is a horizontal direction, and the building structure 1 may be a floor.
- the long material 2 may be a ceiling joist in which the first direction (longitudinal direction) D1 is the horizontal direction, and the building structure 1 may be a ceiling.
- 1 may be a rafter whose direction (longitudinal direction) D1 is inclined with respect to the vertical direction and the horizontal direction, and the building structure 1 may be a roof.
- the first to third directions D1, D2, and D3 are not limited to specific directions.
- the panel 3 is manufactured using the mold 7.
- the present invention is not limited to such a configuration.
- a configuration may be employed in which the foaming stock solution composition is spread on a conveyor, and the panel 3 is cut into a rectangular parallelepiped shape so that the vertical direction is the first direction D1.
- the panel 3 may be provided with a tapered portion 34 that is inclined with respect to the third direction D3 at the end in the second direction D2.
- the panel 3 is formed by the tapered portion 34 so that the dimension in the second direction D2 is gradually increased.
- the panel 3 is fitted between the long materials 2 and 2 while being compressed in the second direction D2 by being pressed in the third direction D3.
- the tapered portion 34 may be provided only at one end of the panel 3.
- a stop portion 6 that protrudes from the long material 2 in the second direction D2 and stops the panel 3 fitted between the long materials 2 and 2 is provided. It may be configured.
- the stop portion 6 includes a locking portion 61 that locks the panel 3 fitted between the long members 2 and 2 in the second direction D2, and an inclined portion 62 that is inclined with respect to the third direction D3. ing.
- the panel 3 is compressed in the second direction D2 by the inclined portion 62 of the stopper 6 when pressed in the third direction D3.
- the panel 3 is fitted between the long materials 2 and 2 by getting over the stopper 6. Since the panel 3 fitted between the long members 2 and 2 is locked to the stopper 6, it is prevented from coming out between the long members 2 and 2.
- the panel 3 may be configured such that the surface thereof is covered with a film (for example, a shrink film made of vinyl or the like). According to such a configuration, when the panel 3 is held by an operator or when a plurality of panels 3 are stacked, the panel 3 can be easily handled.
- a film for example, a shrink film made of vinyl or the like
- Polyol Compound Polyether Polyol (A) -1 Polyether polyol obtained by addition polymerization of ethylene oxide and propylene oxide using the trade name “Excenol-820” (manufactured by Asahi Glass Co., Ltd.) with glycerol as an initiator.
- Weight average molecular weight 4900, hydroxyl value (OHV) 34 mgKOH / g)
- Short glycol (B) -1: Diethylene glycol (DEG) (molecular weight 106, hydroxyl value (OHV) 1058 mg KOH / g, manufactured by Nacalai Tesque)
- Polyether polyol (C): trade name “T-3000S” (manufactured by Mitsui Chemicals), polyether polyol obtained by addition polymerization of only propylene oxide using glycerol as an initiator (weight average molecular weight 3000, hydroxyl value 56m
- the polyurethane foam panel 3 obtained by reacting the foaming stock composition is cut along a cut surface along the longitudinal direction D1 and the width direction D2, and the thickness direction D3 of the panel 3 and the foaming direction of the cells 31 are substantially perpendicular ( 90 °) panel 3 (length D1 dimension: 700 mm, width direction D2 dimension: 400 mm, thickness direction D3 dimension: 60 mm) was manufactured.
- the results are shown in FIG.
- GPC device manufactured by Shimadzu Corporation, LC-10A Column: Polymer Laboratories, (PLgel, 5 ⁇ m, 500 ⁇ ), (PLgel, 5 ⁇ m, 100 ⁇ ⁇ ), and (PLgel, 5 ⁇ m, 50 ⁇ ) are connected and used.
- Flow rate 1.0 ml / min Concentration: 1.0 g / l
- the foam density was determined according to JIS K 7222.
- the panels 3 of Examples 1 to 3 have low density, low brittleness, and excellent heat insulation performance in the thickness direction D3. Further, it can be seen that there is a difference in compressive strength between the vertical direction D1 and the horizontal direction D2 and elasticity in the width direction D2, so that the fitting workability is also excellent.
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Abstract
Description
ウレタンフォームパネル3の原料として、図11に示すような配合にてポリオール組成物を調製した。図11に示す各成分の詳細は、以下の通りである。 <Preparation of polyol composition>
As a raw material of the
ポリエーテルポリオール(A)-1:商品名「エクセノール-820」(旭硝子社製)、開始剤をグリセリンとして、エチレンオキサイド及びプロピレンオキサイドを付加重合して得られたポリエーテルポリオール(重量平均分子量4900、水酸基価(OHV)=34mgKOH/g)
ポリエーテルポリオール(A)-2:商品名「エクセノール-850」(旭硝子社製)、開始剤をグリセリンとして、エチレンオキサイド及びプロピレンオキサイドを付加重合して得られたポリエーテルポリオール(重量平均分子量7000、水酸基価(OHV)=25mgKOH/g)
ショートグリコール(B)-1:ジエチレングリコール(DEG)(分子量106、水酸基価(OHV)=1058mgKOH/g、ナカライテスク社製)
ポリエーテルポリオール(C):商品名「T-3000S」(三井化学社製)、開始剤をグリセリンとして、プロピレンオキサイドのみを付加重合して得られたポリエーテルポリオール(重量平均分子量3000、水酸基価=56mgKOH/g) (1) Polyol Compound Polyether Polyol (A) -1: Polyether polyol obtained by addition polymerization of ethylene oxide and propylene oxide using the trade name “Excenol-820” (manufactured by Asahi Glass Co., Ltd.) with glycerol as an initiator. Weight average molecular weight 4900, hydroxyl value (OHV) = 34 mgKOH / g)
Polyether polyol (A) -2: trade name “Exenol-850” (manufactured by Asahi Glass Co., Ltd.), polyether polyol obtained by addition polymerization of ethylene oxide and propylene oxide using glycerol as an initiator (weight average molecular weight 7000, Hydroxyl value (OHV) = 25 mgKOH / g)
Short glycol (B) -1: Diethylene glycol (DEG) (molecular weight 106, hydroxyl value (OHV) = 1058 mg KOH / g, manufactured by Nacalai Tesque)
Polyether polyol (C): trade name “T-3000S” (manufactured by Mitsui Chemicals), polyether polyol obtained by addition polymerization of only propylene oxide using glycerol as an initiator (weight average molecular weight 3000, hydroxyl value = 56mgKOH / g)
商品名「TMCPP」(大八化学社製)
(3)整泡剤
整泡剤-1:シリコーン系ノニオン界面活性剤、商品名「SF-2938F」(東レダウコーニングシリコーン社製)
(4)触媒
触媒-1:第3級アミン触媒、商品名「TOYOCAT-ET」(東ソー社製)
触媒-2:N,N-ジメチルアミノエトキシエタノール、商品名「カオーNo.26」
(花王社製) (2) Flame retardant Product name “TMCPP” (Daihachi Chemical Co., Ltd.)
(3) Foam stabilizer Foam stabilizer-1: silicone-based nonionic surfactant, trade name “SF-2938F” (manufactured by Toray Dow Corning Silicone)
(4) Catalyst Catalyst-1: Tertiary amine catalyst, trade name “TOYOCAT-ET” (manufactured by Tosoh Corporation)
Catalyst-2: N, N-dimethylaminoethoxyethanol, trade name “Kaoh No. 26”
(Made by Kao)
実施例1~3
図11に示す配合で調整したポリオール組成物とポリイソシアネート成分(c-MDI(住化バイエルウレタン社製「スミジュール44V-10」、NCO%:31%)を用い、イソシアネート指数(NCO Index)は図11に記載)に調整した発泡原液組成物を、図5に示すモールド7(縦方向D1の寸法:900mm、幅方向D2の寸法:500mm、厚み方向D3の寸法:500mm)の底面71にミキシングヘッド8から注入した。その後、発泡原液組成物を反応させて得られたポリウレタンフォームパネル3を縦方向D1及び幅方向D2に沿う切断面で裁断し、パネル3の厚み方向D3とセル31の発泡方向とが略垂直(90°)であるパネル3(縦方向D1の寸法:700mm、幅方向D2の寸法:400mm、厚み方向D3の寸法:60mm)を製造した。結果を図11に示す。 <Panel evaluation>
Examples 1 to 3
Using a polyol composition and a polyisocyanate component (c-MDI (“Sumidur 44V-10” manufactured by Sumika Bayer Urethane Co., Ltd., NCO%: 31%) adjusted with the formulation shown in FIG. 11, the isocyanate index (NCO Index) is The foaming stock composition prepared in FIG. 11) is mixed with the
重量平均分子量は、GPC(ゲル・パーミエーション・クロマトグラフィ)にて測定し、標準ポリスチレンにより換算した。
GPC装置:島津製作所製、LC-10A
カラム:Polymer Laboratories社製、(PLgel、5μm、500Å)、(PLgel、5μm、100Å)、及び(PLgel、5μm、50Å)の3つのカラムを連結して使用
流量:1.0ml/min
濃度:1.0g/l
注入量:40μl
カラム温度:40℃
溶離液:テトラヒドロフラン <Weight average molecular weight>
The weight average molecular weight was measured by GPC (gel permeation chromatography) and converted by standard polystyrene.
GPC device: manufactured by Shimadzu Corporation, LC-10A
Column: Polymer Laboratories, (PLgel, 5 μm, 500 Å), (PLgel, 5 μm, 100 及 び), and (PLgel, 5 μm, 50 Å) are connected and used. Flow rate: 1.0 ml / min
Concentration: 1.0 g / l
Injection volume: 40 μl
Column temperature: 40 ° C
Eluent: Tetrahydrofuran
フォーム密度については、JIS K 7222に準拠し求めた。 <Foam density>
The foam density was determined according to JIS K 7222.
JIS A9526(建築物断熱用吹付け硬質ウレタンフォーム)に基づき、JIS A1412-2(熱絶縁材の熱抵抗及び熱伝導率の測定方法-第2部:熱流計法)(HFM法)に準拠して、パネル3の厚み方向D3での熱伝導率を測定した。 <Thermal conductivity>
Based on JIS A9526 (Blowing rigid urethane foam for thermal insulation of buildings), it conforms to JIS A1412-2 (Measurement method of thermal resistance and thermal conductivity of thermal insulation materials-Part 2: Heat flow meter method) (HFM method). The thermal conductivity in the thickness direction D3 of the
上記方法にて製造したポリウレタンフォームパネル3(縦方向D1の寸法:700mm、幅方向D2の寸法:400mm、厚み方向D3の寸法:60mm)の中央部分(縦方向D1及び幅方向D2中心から、縦方向D1の寸法及び幅方向D2の寸法の両側10%程度の部分)から、50mm角の立方体をフォーム試料として切り出し、AUTOGRAPH AG-X plus(島津製作所社製)を使用して、圧縮速度5mm/minの条件で10%圧縮強度を測定した。 <10% compressive strength>
From the center part (vertical direction D1 and width direction D2 center) of the polyurethane foam panel 3 (size in the vertical direction D1: 700 mm, dimension in the width direction D2: 400 mm, dimension in the thickness direction D3: 60 mm) manufactured by the
幅方向D2の寸法が400mmであるパネル3で、幅方向D2に5%圧縮して、離間距離が380mmの長尺材2,2間に容易に嵌めることが可能であれば、所定幅に対して融通ありということでパネル3の嵌め込み作業性が良好(図11においては「○」)と判断した。 <Workability of inserting polyurethane foam panels into the specified shape>
If the
Claims (3)
- 互いの長手方向が第1の方向で平行となるように、前記第1の方向と直交する第2の方向で並列される複数の長尺材と、
前記長尺材間に嵌められるパネルとを備え、
前記パネルは、前記第2の方向で弾性を有するように、前記第2の方向と直交する方向に沿って長尺に形成される複数のセルを有する発泡体である建築構造体。 A plurality of long materials arranged in parallel in a second direction orthogonal to the first direction, such that their longitudinal directions are parallel to each other in the first direction;
A panel fitted between the long members,
The said structure is a building structure which is a foam which has a some cell formed in elongate along the direction orthogonal to the said 2nd direction so that it may have elasticity in the said 2nd direction. - 前記複数のセルは、前記パネルの前記第2の方向における弾性率が前記パネルの前記第1の方向における弾性率よりも小さくなるように、前記第1の方向に沿って長尺に形成される請求項1に記載の建築構造体。 The plurality of cells are formed long along the first direction so that an elastic modulus of the panel in the second direction is smaller than an elastic modulus of the panel in the first direction. The building structure according to claim 1.
- 互いの長手方向が第1の方向で平行となるように、前記第1の方向と直交する第2の方向で並列される複数の長尺材に対し、
前記第2の方向で弾性を有するように、前記第2の方向と直交する方向に沿って長尺に形成される複数のセルを有する発泡体であるパネルを、前記長尺材間に嵌める建築構造体の製造方法。 For a plurality of long materials arranged in parallel in a second direction orthogonal to the first direction so that their longitudinal directions are parallel to each other in the first direction,
A construction in which a panel, which is a foam having a plurality of cells formed in a long direction along a direction orthogonal to the second direction so as to have elasticity in the second direction, is fitted between the long materials. Manufacturing method of structure.
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US14/758,534 US20150345135A1 (en) | 2013-01-09 | 2013-12-20 | Construction structure and method for producing same |
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US10787816B1 (en) * | 2019-04-18 | 2020-09-29 | Spray Foam Distributors of NE Inc. | Spray foam insulation vent |
JP7464368B2 (en) | 2019-10-02 | 2024-04-09 | ニチハ株式会社 | Thermal insulation construction and thermal insulation construction method |
WO2022046766A1 (en) * | 2020-08-25 | 2022-03-03 | Ses Foam, Llc | Process for making low density spray polyurethane foam for insulation, sound abatement, and air sealing of building enclosures |
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JP2001301078A (en) * | 2000-04-20 | 2001-10-30 | Sekisui Chem Co Ltd | Polyolefinic resin composite foam, and vehicular member and shock absorbing member consisting of the same |
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- 2013-12-20 WO PCT/JP2013/084339 patent/WO2014109215A1/en active Application Filing
- 2013-12-20 CA CA2897479A patent/CA2897479C/en not_active Expired - Fee Related
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JP2001301078A (en) * | 2000-04-20 | 2001-10-30 | Sekisui Chem Co Ltd | Polyolefinic resin composite foam, and vehicular member and shock absorbing member consisting of the same |
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JP5615389B2 (en) | 2014-10-29 |
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CA2897479A1 (en) | 2014-07-17 |
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US20150345135A1 (en) | 2015-12-03 |
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