TW201441453A - Construction structure and method for producing same - Google Patents
Construction structure and method for producing same Download PDFInfo
- Publication number
- TW201441453A TW201441453A TW102148148A TW102148148A TW201441453A TW 201441453 A TW201441453 A TW 201441453A TW 102148148 A TW102148148 A TW 102148148A TW 102148148 A TW102148148 A TW 102148148A TW 201441453 A TW201441453 A TW 201441453A
- Authority
- TW
- Taiwan
- Prior art keywords
- panel
- foam
- weight
- building structure
- polyol
- Prior art date
Links
- 238000004519 manufacturing process Methods 0.000 title claims description 11
- 238000010276 construction Methods 0.000 title abstract 2
- 239000006260 foam Substances 0.000 claims abstract description 33
- 239000000463 material Substances 0.000 claims description 77
- 229920005862 polyol Polymers 0.000 description 60
- 150000003077 polyols Chemical class 0.000 description 42
- 239000000203 mixture Substances 0.000 description 29
- -1 polyol compound Chemical class 0.000 description 26
- 239000004721 Polyphenylene oxide Substances 0.000 description 21
- 229920000570 polyether Polymers 0.000 description 21
- PEDCQBHIVMGVHV-UHFFFAOYSA-N Glycerine Chemical compound OCC(O)CO PEDCQBHIVMGVHV-UHFFFAOYSA-N 0.000 description 16
- 229920001228 polyisocyanate Polymers 0.000 description 15
- 239000005056 polyisocyanate Substances 0.000 description 15
- MTHSVFCYNBDYFN-UHFFFAOYSA-N diethylene glycol Chemical compound OCCOCCO MTHSVFCYNBDYFN-UHFFFAOYSA-N 0.000 description 13
- 229920005830 Polyurethane Foam Polymers 0.000 description 11
- 238000005187 foaming Methods 0.000 description 11
- 238000002156 mixing Methods 0.000 description 11
- 239000011496 polyurethane foam Substances 0.000 description 11
- 150000002009 diols Chemical class 0.000 description 10
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 10
- GOOHAUXETOMSMM-UHFFFAOYSA-N Propylene oxide Chemical compound CC1CO1 GOOHAUXETOMSMM-UHFFFAOYSA-N 0.000 description 9
- UPMLOUAZCHDJJD-UHFFFAOYSA-N 4,4'-Diphenylmethane Diisocyanate Chemical compound C1=CC(N=C=O)=CC=C1CC1=CC=C(N=C=O)C=C1 UPMLOUAZCHDJJD-UHFFFAOYSA-N 0.000 description 8
- LYCAIKOWRPUZTN-UHFFFAOYSA-N Ethylene glycol Chemical compound OCCO LYCAIKOWRPUZTN-UHFFFAOYSA-N 0.000 description 8
- IAYPIBMASNFSPL-UHFFFAOYSA-N Ethylene oxide Chemical compound C1CO1 IAYPIBMASNFSPL-UHFFFAOYSA-N 0.000 description 8
- 235000011187 glycerol Nutrition 0.000 description 8
- 239000003054 catalyst Substances 0.000 description 7
- 125000002887 hydroxy group Chemical group [H]O* 0.000 description 7
- 239000003999 initiator Substances 0.000 description 7
- 229910019142 PO4 Inorganic materials 0.000 description 6
- DNIAPMSPPWPWGF-UHFFFAOYSA-N Propylene glycol Chemical compound CC(O)CO DNIAPMSPPWPWGF-UHFFFAOYSA-N 0.000 description 6
- 238000012644 addition polymerization Methods 0.000 description 6
- 238000006243 chemical reaction Methods 0.000 description 6
- 239000004088 foaming agent Substances 0.000 description 6
- 239000012948 isocyanate Substances 0.000 description 6
- 150000002513 isocyanates Chemical class 0.000 description 6
- 238000000034 method Methods 0.000 description 6
- 235000021317 phosphate Nutrition 0.000 description 6
- 239000002994 raw material Substances 0.000 description 6
- 239000003381 stabilizer Substances 0.000 description 6
- RNFJDJUURJAICM-UHFFFAOYSA-N 2,2,4,4,6,6-hexaphenoxy-1,3,5-triaza-2$l^{5},4$l^{5},6$l^{5}-triphosphacyclohexa-1,3,5-triene Chemical compound N=1P(OC=2C=CC=CC=2)(OC=2C=CC=CC=2)=NP(OC=2C=CC=CC=2)(OC=2C=CC=CC=2)=NP=1(OC=1C=CC=CC=1)OC1=CC=CC=C1 RNFJDJUURJAICM-UHFFFAOYSA-N 0.000 description 5
- 150000001875 compounds Chemical class 0.000 description 5
- 230000006835 compression Effects 0.000 description 5
- 238000007906 compression Methods 0.000 description 5
- 239000003063 flame retardant Substances 0.000 description 5
- 238000002347 injection Methods 0.000 description 5
- 239000007924 injection Substances 0.000 description 5
- 229920000642 polymer Polymers 0.000 description 5
- PUPZLCDOIYMWBV-UHFFFAOYSA-N (+/-)-1,3-Butanediol Chemical compound CC(O)CCO PUPZLCDOIYMWBV-UHFFFAOYSA-N 0.000 description 4
- 125000002947 alkylene group Chemical group 0.000 description 4
- 125000000524 functional group Chemical group 0.000 description 4
- 125000004435 hydrogen atom Chemical group [H]* 0.000 description 4
- IQPQWNKOIGAROB-UHFFFAOYSA-N isocyanate group Chemical group [N-]=C=O IQPQWNKOIGAROB-UHFFFAOYSA-N 0.000 description 4
- 239000010452 phosphate Substances 0.000 description 4
- 229920002635 polyurethane Polymers 0.000 description 4
- 239000004814 polyurethane Substances 0.000 description 4
- SJRJJKPEHAURKC-UHFFFAOYSA-N N-Methylmorpholine Chemical compound CN1CCOCC1 SJRJJKPEHAURKC-UHFFFAOYSA-N 0.000 description 3
- 150000001412 amines Chemical class 0.000 description 3
- WERYXYBDKMZEQL-UHFFFAOYSA-N butane-1,4-diol Chemical compound OCCCCO WERYXYBDKMZEQL-UHFFFAOYSA-N 0.000 description 3
- 239000003795 chemical substances by application Substances 0.000 description 3
- SZXQTJUDPRGNJN-UHFFFAOYSA-N dipropylene glycol Chemical compound OCCCOCCCO SZXQTJUDPRGNJN-UHFFFAOYSA-N 0.000 description 3
- 230000000694 effects Effects 0.000 description 3
- 238000005227 gel permeation chromatography Methods 0.000 description 3
- 239000011810 insulating material Substances 0.000 description 3
- 239000007788 liquid Substances 0.000 description 3
- 238000007142 ring opening reaction Methods 0.000 description 3
- 239000012970 tertiary amine catalyst Substances 0.000 description 3
- OMDXZWUHIHTREC-UHFFFAOYSA-N 1-[2-(dimethylamino)ethoxy]ethanol Chemical compound CC(O)OCCN(C)C OMDXZWUHIHTREC-UHFFFAOYSA-N 0.000 description 2
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 description 2
- PPBRXRYQALVLMV-UHFFFAOYSA-N Styrene Chemical compound C=CC1=CC=CC=C1 PPBRXRYQALVLMV-UHFFFAOYSA-N 0.000 description 2
- WYURNTSHIVDZCO-UHFFFAOYSA-N Tetrahydrofuran Chemical compound C1CCOC1 WYURNTSHIVDZCO-UHFFFAOYSA-N 0.000 description 2
- 150000004982 aromatic amines Chemical class 0.000 description 2
- 235000019437 butane-1,3-diol Nutrition 0.000 description 2
- ZBCBWPMODOFKDW-UHFFFAOYSA-N diethanolamine Chemical compound OCCNCCO ZBCBWPMODOFKDW-UHFFFAOYSA-N 0.000 description 2
- 238000011156 evaluation Methods 0.000 description 2
- NAQMVNRVTILPCV-UHFFFAOYSA-N hexane-1,6-diamine Chemical compound NCCCCCCN NAQMVNRVTILPCV-UHFFFAOYSA-N 0.000 description 2
- 238000009413 insulation Methods 0.000 description 2
- 238000012986 modification Methods 0.000 description 2
- 230000004048 modification Effects 0.000 description 2
- 150000003013 phosphoric acid derivatives Chemical class 0.000 description 2
- 229920001296 polysiloxane Polymers 0.000 description 2
- 239000011347 resin Substances 0.000 description 2
- 229920005989 resin Polymers 0.000 description 2
- 239000000057 synthetic resin Substances 0.000 description 2
- 229920003002 synthetic resin Polymers 0.000 description 2
- IMNIMPAHZVJRPE-UHFFFAOYSA-N triethylenediamine Chemical compound C1CN2CCN1CC2 IMNIMPAHZVJRPE-UHFFFAOYSA-N 0.000 description 2
- WTLBZVNBAKMVDP-UHFFFAOYSA-N tris(2-butoxyethyl) phosphate Chemical compound CCCCOCCOP(=O)(OCCOCCCC)OCCOCCCC WTLBZVNBAKMVDP-UHFFFAOYSA-N 0.000 description 2
- DNIAPMSPPWPWGF-GSVOUGTGSA-N (R)-(-)-Propylene glycol Chemical compound C[C@@H](O)CO DNIAPMSPPWPWGF-GSVOUGTGSA-N 0.000 description 1
- NIXYMFJMHHIQAC-UHFFFAOYSA-N 1,1-bis(dimethylamino)propan-2-ol Chemical compound CC(O)C(N(C)C)N(C)C NIXYMFJMHHIQAC-UHFFFAOYSA-N 0.000 description 1
- RBACIKXCRWGCBB-UHFFFAOYSA-N 1,2-Epoxybutane Chemical compound CCC1CO1 RBACIKXCRWGCBB-UHFFFAOYSA-N 0.000 description 1
- GEYOCULIXLDCMW-UHFFFAOYSA-N 1,2-phenylenediamine Chemical compound NC1=CC=CC=C1N GEYOCULIXLDCMW-UHFFFAOYSA-N 0.000 description 1
- 229940058015 1,3-butylene glycol Drugs 0.000 description 1
- CBCKQZAAMUWICA-UHFFFAOYSA-N 1,4-phenylenediamine Chemical compound NC1=CC=C(N)C=C1 CBCKQZAAMUWICA-UHFFFAOYSA-N 0.000 description 1
- OOFAEFCMEHZNGP-UHFFFAOYSA-N 1-n',1-n'-dimethylpropane-1,1-diamine Chemical compound CCC(N)N(C)C OOFAEFCMEHZNGP-UHFFFAOYSA-N 0.000 description 1
- XDIAMRVROCPPBK-UHFFFAOYSA-N 2,2-dimethylpropan-1-amine Chemical compound CC(C)(C)CN XDIAMRVROCPPBK-UHFFFAOYSA-N 0.000 description 1
- PQXKWPLDPFFDJP-UHFFFAOYSA-N 2,3-dimethyloxirane Chemical compound CC1OC1C PQXKWPLDPFFDJP-UHFFFAOYSA-N 0.000 description 1
- PISLZQACAJMAIO-UHFFFAOYSA-N 2,4-diethyl-6-methylbenzene-1,3-diamine Chemical compound CCC1=CC(C)=C(N)C(CC)=C1N PISLZQACAJMAIO-UHFFFAOYSA-N 0.000 description 1
- RLYCRLGLCUXUPO-UHFFFAOYSA-N 2,6-diaminotoluene Chemical compound CC1=C(N)C=CC=C1N RLYCRLGLCUXUPO-UHFFFAOYSA-N 0.000 description 1
- KKFDCBRMNNSAAW-UHFFFAOYSA-N 2-(morpholin-4-yl)ethanol Chemical compound OCCN1CCOCC1 KKFDCBRMNNSAAW-UHFFFAOYSA-N 0.000 description 1
- HZAXFHJVJLSVMW-UHFFFAOYSA-N 2-Aminoethan-1-ol Chemical compound NCCO HZAXFHJVJLSVMW-UHFFFAOYSA-N 0.000 description 1
- LCZVSXRMYJUNFX-UHFFFAOYSA-N 2-[2-(2-hydroxypropoxy)propoxy]propan-1-ol Chemical compound CC(O)COC(C)COC(C)CO LCZVSXRMYJUNFX-UHFFFAOYSA-N 0.000 description 1
- LSYBWANTZYUTGJ-UHFFFAOYSA-N 2-[2-(dimethylamino)ethyl-methylamino]ethanol Chemical compound CN(C)CCN(C)CCO LSYBWANTZYUTGJ-UHFFFAOYSA-N 0.000 description 1
- LIAWCKFOFPPVGF-UHFFFAOYSA-N 2-ethyladamantane Chemical compound C1C(C2)CC3CC1C(CC)C2C3 LIAWCKFOFPPVGF-UHFFFAOYSA-N 0.000 description 1
- WADSJYLPJPTMLN-UHFFFAOYSA-N 3-(cycloundecen-1-yl)-1,2-diazacycloundec-2-ene Chemical compound C1CCCCCCCCC=C1C1=NNCCCCCCCC1 WADSJYLPJPTMLN-UHFFFAOYSA-N 0.000 description 1
- YBRVSVVVWCFQMG-UHFFFAOYSA-N 4,4'-diaminodiphenylmethane Chemical compound C1=CC(N)=CC=C1CC1=CC=C(N)C=C1 YBRVSVVVWCFQMG-UHFFFAOYSA-N 0.000 description 1
- 239000004604 Blowing Agent Substances 0.000 description 1
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 1
- VGGSQFUCUMXWEO-UHFFFAOYSA-N Ethene Chemical compound C=C VGGSQFUCUMXWEO-UHFFFAOYSA-N 0.000 description 1
- JOYRKODLDBILNP-UHFFFAOYSA-N Ethyl urethane Chemical compound CCOC(N)=O JOYRKODLDBILNP-UHFFFAOYSA-N 0.000 description 1
- 239000005977 Ethylene Substances 0.000 description 1
- PIICEJLVQHRZGT-UHFFFAOYSA-N Ethylenediamine Chemical compound NCCN PIICEJLVQHRZGT-UHFFFAOYSA-N 0.000 description 1
- KWYHDKDOAIKMQN-UHFFFAOYSA-N N,N,N',N'-tetramethylethylenediamine Chemical compound CN(C)CCN(C)C KWYHDKDOAIKMQN-UHFFFAOYSA-N 0.000 description 1
- SVYKKECYCPFKGB-UHFFFAOYSA-N N,N-dimethylcyclohexylamine Chemical compound CN(C)C1CCCCC1 SVYKKECYCPFKGB-UHFFFAOYSA-N 0.000 description 1
- UEEJHVSXFDXPFK-UHFFFAOYSA-N N-dimethylaminoethanol Chemical compound CN(C)CCO UEEJHVSXFDXPFK-UHFFFAOYSA-N 0.000 description 1
- 239000004793 Polystyrene Substances 0.000 description 1
- AWMVMTVKBNGEAK-UHFFFAOYSA-N Styrene oxide Chemical compound C1OC1C1=CC=CC=C1 AWMVMTVKBNGEAK-UHFFFAOYSA-N 0.000 description 1
- WOURXYYHORRGQO-UHFFFAOYSA-N Tri(3-chloropropyl) phosphate Chemical compound ClCCCOP(=O)(OCCCCl)OCCCCl WOURXYYHORRGQO-UHFFFAOYSA-N 0.000 description 1
- XSTXAVWGXDQKEL-UHFFFAOYSA-N Trichloroethylene Chemical compound ClC=C(Cl)Cl XSTXAVWGXDQKEL-UHFFFAOYSA-N 0.000 description 1
- ZJCCRDAZUWHFQH-UHFFFAOYSA-N Trimethylolpropane Chemical compound CCC(CO)(CO)CO ZJCCRDAZUWHFQH-UHFFFAOYSA-N 0.000 description 1
- ORLQHILJRHBSAY-UHFFFAOYSA-N [1-(hydroxymethyl)cyclohexyl]methanol Chemical compound OCC1(CO)CCCCC1 ORLQHILJRHBSAY-UHFFFAOYSA-N 0.000 description 1
- 239000000654 additive Substances 0.000 description 1
- 150000001298 alcohols Chemical class 0.000 description 1
- 125000002723 alicyclic group Chemical group 0.000 description 1
- 125000001931 aliphatic group Chemical group 0.000 description 1
- WNROFYMDJYEPJX-UHFFFAOYSA-K aluminium hydroxide Chemical compound [OH-].[OH-].[OH-].[Al+3] WNROFYMDJYEPJX-UHFFFAOYSA-K 0.000 description 1
- 239000003963 antioxidant agent Substances 0.000 description 1
- 230000003078 antioxidant effect Effects 0.000 description 1
- 125000003118 aryl group Chemical group 0.000 description 1
- QVYARBLCAHCSFJ-UHFFFAOYSA-N butane-1,1-diamine Chemical compound CCCC(N)N QVYARBLCAHCSFJ-UHFFFAOYSA-N 0.000 description 1
- 239000003086 colorant Substances 0.000 description 1
- 229920001577 copolymer Polymers 0.000 description 1
- PDXRQENMIVHKPI-UHFFFAOYSA-N cyclohexane-1,1-diol Chemical compound OC1(O)CCCCC1 PDXRQENMIVHKPI-UHFFFAOYSA-N 0.000 description 1
- ZWAJLVLEBYIOTI-UHFFFAOYSA-N cyclohexene oxide Chemical compound C1CCCC2OC21 ZWAJLVLEBYIOTI-UHFFFAOYSA-N 0.000 description 1
- FWFSEYBSWVRWGL-UHFFFAOYSA-N cyclohexene oxide Natural products O=C1CCCC=C1 FWFSEYBSWVRWGL-UHFFFAOYSA-N 0.000 description 1
- 230000006866 deterioration Effects 0.000 description 1
- 238000010586 diagram Methods 0.000 description 1
- 239000004205 dimethyl polysiloxane Substances 0.000 description 1
- 238000004090 dissolution Methods 0.000 description 1
- 238000005886 esterification reaction Methods 0.000 description 1
- 150000002148 esters Chemical class 0.000 description 1
- 150000002334 glycols Chemical class 0.000 description 1
- 229910052736 halogen Inorganic materials 0.000 description 1
- 150000002367 halogens Chemical class 0.000 description 1
- ACCCMOQWYVYDOT-UHFFFAOYSA-N hexane-1,1-diol Chemical compound CCCCCC(O)O ACCCMOQWYVYDOT-UHFFFAOYSA-N 0.000 description 1
- XXMIOPMDWAUFGU-UHFFFAOYSA-N hexane-1,6-diol Chemical compound OCCCCCCO XXMIOPMDWAUFGU-UHFFFAOYSA-N 0.000 description 1
- 229910052739 hydrogen Inorganic materials 0.000 description 1
- 239000001257 hydrogen Substances 0.000 description 1
- WGCNASOHLSPBMP-UHFFFAOYSA-N hydroxyacetaldehyde Natural products OCC=O WGCNASOHLSPBMP-UHFFFAOYSA-N 0.000 description 1
- 238000005259 measurement Methods 0.000 description 1
- 150000002736 metal compounds Chemical class 0.000 description 1
- TXXWBTOATXBWDR-UHFFFAOYSA-N n,n,n',n'-tetramethylhexane-1,6-diamine Chemical compound CN(C)CCCCCCN(C)C TXXWBTOATXBWDR-UHFFFAOYSA-N 0.000 description 1
- NTNWKDHZTDQSST-UHFFFAOYSA-N naphthalene-1,2-diamine Chemical compound C1=CC=CC2=C(N)C(N)=CC=C21 NTNWKDHZTDQSST-UHFFFAOYSA-N 0.000 description 1
- SLCVBVWXLSEKPL-UHFFFAOYSA-N neopentyl glycol Chemical compound OCC(C)(C)CO SLCVBVWXLSEKPL-UHFFFAOYSA-N 0.000 description 1
- 239000002736 nonionic surfactant Substances 0.000 description 1
- 125000006353 oxyethylene group Chemical group 0.000 description 1
- WXZMFSXDPGVJKK-UHFFFAOYSA-N pentaerythritol Chemical compound OCC(CO)(CO)CO WXZMFSXDPGVJKK-UHFFFAOYSA-N 0.000 description 1
- UKODFQOELJFMII-UHFFFAOYSA-N pentamethyldiethylenetriamine Chemical compound CN(C)CCN(C)CCN(C)C UKODFQOELJFMII-UHFFFAOYSA-N 0.000 description 1
- 239000005011 phenolic resin Substances 0.000 description 1
- NBIIXXVUZAFLBC-UHFFFAOYSA-K phosphate Chemical compound [O-]P([O-])([O-])=O NBIIXXVUZAFLBC-UHFFFAOYSA-K 0.000 description 1
- UEZVMMHDMIWARA-UHFFFAOYSA-M phosphonate Chemical compound [O-]P(=O)=O UEZVMMHDMIWARA-UHFFFAOYSA-M 0.000 description 1
- 230000000704 physical effect Effects 0.000 description 1
- 229920000435 poly(dimethylsiloxane) Polymers 0.000 description 1
- 229920002223 polystyrene Polymers 0.000 description 1
- 238000002360 preparation method Methods 0.000 description 1
- 230000001737 promoting effect Effects 0.000 description 1
- AOHJOMMDDJHIJH-UHFFFAOYSA-N propylenediamine Chemical compound CC(N)CN AOHJOMMDDJHIJH-UHFFFAOYSA-N 0.000 description 1
- 238000000926 separation method Methods 0.000 description 1
- 229920006300 shrink film Polymers 0.000 description 1
- 239000007921 spray Substances 0.000 description 1
- 238000003756 stirring Methods 0.000 description 1
- 239000011550 stock solution Substances 0.000 description 1
- 239000000126 substance Substances 0.000 description 1
- YLQBMQCUIZJEEH-UHFFFAOYSA-N tetrahydrofuran Natural products C=1C=COC=1 YLQBMQCUIZJEEH-UHFFFAOYSA-N 0.000 description 1
- 229920002803 thermoplastic polyurethane Polymers 0.000 description 1
- STCOOQWBFONSKY-UHFFFAOYSA-N tributyl phosphate Chemical compound CCCCOP(=O)(OCCCC)OCCCC STCOOQWBFONSKY-UHFFFAOYSA-N 0.000 description 1
- DQWPFSLDHJDLRL-UHFFFAOYSA-N triethyl phosphate Chemical compound CCOP(=O)(OCC)OCC DQWPFSLDHJDLRL-UHFFFAOYSA-N 0.000 description 1
- WVLBCYQITXONBZ-UHFFFAOYSA-N trimethyl phosphate Chemical compound COP(=O)(OC)OC WVLBCYQITXONBZ-UHFFFAOYSA-N 0.000 description 1
- 150000004072 triols Chemical class 0.000 description 1
Classifications
-
- E—FIXED CONSTRUCTIONS
- E04—BUILDING
- E04B—GENERAL BUILDING CONSTRUCTIONS; WALLS, e.g. PARTITIONS; ROOFS; FLOORS; CEILINGS; INSULATION OR OTHER PROTECTION OF BUILDINGS
- E04B2/00—Walls, e.g. partitions, for buildings; Wall construction with regard to insulation; Connections specially adapted to walls
- E04B2/56—Load-bearing walls of framework or pillarwork; Walls incorporating load-bearing elongated members
- E04B2/562—Load-bearing walls of framework or pillarwork; Walls incorporating load-bearing elongated members with fillings between the load-bearing elongated members
-
- E—FIXED CONSTRUCTIONS
- E04—BUILDING
- E04B—GENERAL BUILDING CONSTRUCTIONS; WALLS, e.g. PARTITIONS; ROOFS; FLOORS; CEILINGS; INSULATION OR OTHER PROTECTION OF BUILDINGS
- E04B1/00—Constructions in general; Structures which are not restricted either to walls, e.g. partitions, or floors or ceilings or roofs
- E04B1/62—Insulation or other protection; Elements or use of specified material therefor
- E04B1/74—Heat, sound or noise insulation, absorption, or reflection; Other building methods affording favourable thermal or acoustical conditions, e.g. accumulating of heat within walls
- E04B1/76—Heat, sound or noise insulation, absorption, or reflection; Other building methods affording favourable thermal or acoustical conditions, e.g. accumulating of heat within walls specifically with respect to heat only
- E04B1/7654—Heat, sound or noise insulation, absorption, or reflection; Other building methods affording favourable thermal or acoustical conditions, e.g. accumulating of heat within walls specifically with respect to heat only comprising an insulating layer, disposed between two longitudinal supporting elements, e.g. to insulate ceilings
-
- E—FIXED CONSTRUCTIONS
- E04—BUILDING
- E04C—STRUCTURAL ELEMENTS; BUILDING MATERIALS
- E04C2/00—Building elements of relatively thin form for the construction of parts of buildings, e.g. sheet materials, slabs, or panels
- E04C2/02—Building elements of relatively thin form for the construction of parts of buildings, e.g. sheet materials, slabs, or panels characterised by specified materials
- E04C2/10—Building elements of relatively thin form for the construction of parts of buildings, e.g. sheet materials, slabs, or panels characterised by specified materials of wood, fibres, chips, vegetable stems, or the like; of plastics; of foamed products
- E04C2/24—Building elements of relatively thin form for the construction of parts of buildings, e.g. sheet materials, slabs, or panels characterised by specified materials of wood, fibres, chips, vegetable stems, or the like; of plastics; of foamed products laminated and composed of materials covered by two or more of groups E04C2/12, E04C2/16, E04C2/20
-
- E—FIXED CONSTRUCTIONS
- E04—BUILDING
- E04C—STRUCTURAL ELEMENTS; BUILDING MATERIALS
- E04C2/00—Building elements of relatively thin form for the construction of parts of buildings, e.g. sheet materials, slabs, or panels
- E04C2/30—Building elements of relatively thin form for the construction of parts of buildings, e.g. sheet materials, slabs, or panels characterised by the shape or structure
- E04C2/38—Building elements of relatively thin form for the construction of parts of buildings, e.g. sheet materials, slabs, or panels characterised by the shape or structure with attached ribs, flanges, or the like, e.g. framed panels
- E04C2/386—Building elements of relatively thin form for the construction of parts of buildings, e.g. sheet materials, slabs, or panels characterised by the shape or structure with attached ribs, flanges, or the like, e.g. framed panels with a frame of unreconstituted or laminated wood
-
- E—FIXED CONSTRUCTIONS
- E04—BUILDING
- E04B—GENERAL BUILDING CONSTRUCTIONS; WALLS, e.g. PARTITIONS; ROOFS; FLOORS; CEILINGS; INSULATION OR OTHER PROTECTION OF BUILDINGS
- E04B1/00—Constructions in general; Structures which are not restricted either to walls, e.g. partitions, or floors or ceilings or roofs
- E04B1/62—Insulation or other protection; Elements or use of specified material therefor
- E04B1/74—Heat, sound or noise insulation, absorption, or reflection; Other building methods affording favourable thermal or acoustical conditions, e.g. accumulating of heat within walls
- E04B1/76—Heat, sound or noise insulation, absorption, or reflection; Other building methods affording favourable thermal or acoustical conditions, e.g. accumulating of heat within walls specifically with respect to heat only
- E04B1/78—Heat insulating elements
- E04B1/80—Heat insulating elements slab-shaped
-
- E—FIXED CONSTRUCTIONS
- E04—BUILDING
- E04B—GENERAL BUILDING CONSTRUCTIONS; WALLS, e.g. PARTITIONS; ROOFS; FLOORS; CEILINGS; INSULATION OR OTHER PROTECTION OF BUILDINGS
- E04B1/00—Constructions in general; Structures which are not restricted either to walls, e.g. partitions, or floors or ceilings or roofs
- E04B1/62—Insulation or other protection; Elements or use of specified material therefor
- E04B1/74—Heat, sound or noise insulation, absorption, or reflection; Other building methods affording favourable thermal or acoustical conditions, e.g. accumulating of heat within walls
- E04B2001/742—Use of special materials; Materials having special structures or shape
-
- E—FIXED CONSTRUCTIONS
- E04—BUILDING
- E04B—GENERAL BUILDING CONSTRUCTIONS; WALLS, e.g. PARTITIONS; ROOFS; FLOORS; CEILINGS; INSULATION OR OTHER PROTECTION OF BUILDINGS
- E04B1/00—Constructions in general; Structures which are not restricted either to walls, e.g. partitions, or floors or ceilings or roofs
- E04B1/62—Insulation or other protection; Elements or use of specified material therefor
- E04B1/74—Heat, sound or noise insulation, absorption, or reflection; Other building methods affording favourable thermal or acoustical conditions, e.g. accumulating of heat within walls
- E04B1/76—Heat, sound or noise insulation, absorption, or reflection; Other building methods affording favourable thermal or acoustical conditions, e.g. accumulating of heat within walls specifically with respect to heat only
- E04B2001/7695—Panels with adjustable width
Landscapes
- Engineering & Computer Science (AREA)
- Architecture (AREA)
- Civil Engineering (AREA)
- Structural Engineering (AREA)
- Physics & Mathematics (AREA)
- Electromagnetism (AREA)
- Acoustics & Sound (AREA)
- Life Sciences & Earth Sciences (AREA)
- Wood Science & Technology (AREA)
- Building Environments (AREA)
- Panels For Use In Building Construction (AREA)
Abstract
Description
本發明係關於一種於並列之複數個長條材料間嵌入面板之建築構造體及其製造方法。 The present invention relates to an architectural structure in which panels are embedded between a plurality of long strips of materials and a method of manufacturing the same.
先前,作為建築構造體,已知有具備以彼此之長度方向平行之方式並列於寬度方向上之複數個長條材料(例如,柱等)、與嵌入於長條材料間之硬質面板之建築構造體(例如,專利文獻1)。例如,面板係由合成樹脂所構成之隔熱材料。 Conventionally, as a building structure, a plurality of elongated materials (for example, columns and the like) which are arranged in parallel in the longitudinal direction so as to be parallel to each other in the longitudinal direction, and a building structure of a rigid panel interposed between the elongated materials are known. Body (for example, Patent Document 1). For example, the panel is a heat insulating material composed of a synthetic resin.
對於該建築構造體,要求面板之尺寸之較高精度。具體而言,於面板之尺寸稍小之情形時,面板與長條材料之間產生間隙,反之,於面板之尺寸稍大之情形時,面板無法嵌入於長條材料間或強行嵌入之面板受到損傷。 For this building structure, a higher precision of the dimensions of the panel is required. Specifically, when the size of the panel is slightly smaller, a gap is formed between the panel and the long material. Conversely, when the panel is slightly larger, the panel cannot be embedded in the long material or the panel is forcibly embedded. damage.
專利文獻1:日本特開2003-278290號公報 Patent Document 1: Japanese Laid-Open Patent Publication No. 2003-278290
因此,鑒於該情況,本發明之課題在於提供一種容易將面板嵌入於長條材料間,並且可防止面板與長條材料之間產生間隙之建築構造 體及其製造方法。 Therefore, in view of the circumstances, an object of the present invention is to provide a building structure which can easily insert a panel between elongated materials and prevent a gap between the panel and the long material. Body and its manufacturing method.
本發明之建築構造體具備:複數個長條材料,以彼此之長度方向於第1方向上平行之方式並列於與上述第1方向正交之第2方向上;及面板,嵌入於上述長條材料間;且上述面板係具有沿著與上述第2方向正交之方向形成為長條之複數個單元的發泡體,以於上述第2方向上具有彈性。 The building structure according to the present invention includes: a plurality of elongated materials which are juxtaposed in a second direction orthogonal to the first direction so that their longitudinal directions are parallel in the first direction; and a panel embedded in the strip The panel has a foam having a plurality of cells formed in a long direction orthogonal to the second direction, and has elasticity in the second direction.
根據本發明之建築構造體,複數個長條材料係以彼此之長度方向於第1方向上平行之方式並列於與第1方向正交之第2方向上。面板係具有沿著與第2方向正交之方向形成為長條之複數個單元的發泡體,故而於第2方向上具有彈性。因此,藉由使於第2方向上被壓縮之面板在長條材料間解除其壓縮而進行復原(或,使面板一面於第2方向上被壓縮一面嵌入於長條材料間),可使面板於與長條材料密合且推壓長條材料之狀態下嵌入於長條材料間。 According to the building structure of the present invention, the plurality of elongated materials are arranged in parallel in the second direction orthogonal to the first direction so that the longitudinal directions thereof are parallel in the first direction. The panel has a foam having a plurality of cells formed in a long direction orthogonal to the second direction, and thus has elasticity in the second direction. Therefore, the panel can be restored by releasing the compression of the panel compressed in the second direction between the elongated materials (or inserting the panel surface between the elongated materials while being compressed in the second direction). It is embedded between the long strips in a state of being in close contact with the strip material and pushing the strip material.
又,本發明之建築構造體亦可為如下之構成:上述複數個單元以上述面板之上述第2方向之彈性模數小於上述面板之上述第1方向之彈性模數之方式,沿著上述第1方向形成為長條。 Further, the building structure of the present invention may be configured such that the plurality of units have the elastic modulus of the second direction of the panel smaller than the elastic modulus of the first direction of the panel, along the first The 1 direction is formed into a long strip.
根據該構成,複數個單元沿著與第2方向正交之方向形成為長條,故而面板之第2方向之彈性模數減小。藉此,面板於第2方向上具有彈性,故而面板於第2方向上容易被壓縮。進而,由於該複數個單元沿著與第2方向正交之方向中之第1方向形成為長條,故而面板之第1方向之彈性模數增大。藉此,面板於第1方向上具有剛性,故而嵌入於長條材料間之面板可穩定地保持於長條材料間。 According to this configuration, since a plurality of cells are formed in a long direction in a direction orthogonal to the second direction, the modulus of elasticity in the second direction of the panel is reduced. Thereby, since the panel has elasticity in the second direction, the panel is easily compressed in the second direction. Further, since the plurality of cells are formed in a long direction along the first direction orthogonal to the second direction, the elastic modulus of the first direction of the panel is increased. Thereby, since the panel has rigidity in the first direction, the panel interposed between the elongated materials can be stably held between the elongated materials.
又,本發明之建築構造體之製造方法係對於以彼此之長度方向於第1方向上平行之方式並列於與上述第1方向正交之第2方向上之複數個長條材料,將下述發泡體即面板嵌入於上述長條材料間,該發泡體以於上述第2方向上具有彈性之方式具有沿著與上述第2方向正交之方向形成為長條的複數個單元。 Moreover, the manufacturing method of the building structure of the present invention is a plurality of elongated materials which are arranged in parallel in the first direction orthogonal to the first direction so as to be parallel to each other in the first direction, and the following A panel in which a foam is inserted is interposed between the elongated materials, and the foam has a plurality of cells formed in a strip shape in a direction orthogonal to the second direction so as to have elasticity in the second direction.
如上所述,本發明具有如下之優異效果:使面板容易嵌入於長條材料間,並且可防止面板與長條材料之間產生間隙。 As described above, the present invention has an excellent effect of easily embedding a panel between elongated materials and preventing a gap between the panel and the elongated material.
1‧‧‧建築構造體 1‧‧‧Architectural structures
2‧‧‧長條材料 2‧‧‧Long strip material
3‧‧‧面板 3‧‧‧ panel
4‧‧‧框材 4‧‧‧ frame material
5‧‧‧板材 5‧‧‧ plates
6‧‧‧固定部 6‧‧‧ Fixed Department
7‧‧‧模具 7‧‧‧Mold
8‧‧‧混合頭 8‧‧‧ Mixing head
21‧‧‧支持面 21‧‧‧Support surface
31‧‧‧單元 31‧‧‧ unit
32‧‧‧面板端部 32‧‧‧End of the panel
33‧‧‧面板端部 33‧‧‧End of the panel
34‧‧‧錐形部 34‧‧‧Cone
61‧‧‧卡止部 61‧‧‧Cards
62‧‧‧傾斜部 62‧‧‧ inclined section
71‧‧‧底面 71‧‧‧ bottom
D1‧‧‧第1方向 D1‧‧‧1st direction
D2‧‧‧第2方向 D2‧‧‧2nd direction
D3‧‧‧第3方向 D3‧‧‧3rd direction
圖1係表示本發明之一實施形態之建築構造體之要部前視圖。 Fig. 1 is a front elevational view showing the main part of a building structure according to an embodiment of the present invention.
圖2係表示圖1之II-II線之剖面圖。 Figure 2 is a cross-sectional view taken along line II-II of Figure 1.
圖3係表示本實施形態之面板之整體立體圖。 Fig. 3 is a perspective view showing the entire panel of the embodiment.
圖4係表示圖3之IV-IV線之要部放大剖面圖。 Fig. 4 is an enlarged cross-sectional view showing an essential part taken along line IV-IV of Fig. 3.
圖5係表示說明本實施形態之面板之製造方法之要部立體圖。 Fig. 5 is a perspective view showing essential parts of a method of manufacturing a panel of the embodiment.
圖6係表示說明本實施形態之建築構造體之製造方法之要部橫剖面圖。 Fig. 6 is a cross-sectional view showing the principal part of the method of manufacturing the building structure of the embodiment.
圖7係表示本發明之另一實施形態之建築構造體之要部前視圖。 Fig. 7 is a front elevational view showing the main part of a building structure according to another embodiment of the present invention.
圖8係表示本發明之進而另一實施形態之建築構造體之要部橫剖面圖。 Fig. 8 is a cross-sectional view showing the principal part of a building structure according to still another embodiment of the present invention.
圖9係表示本發明之進而另一實施形態之建築構造體之要部橫剖面圖。 Fig. 9 is a cross-sectional view showing the principal part of a building structure according to still another embodiment of the present invention.
圖10係表示本發明之進而另一實施形態之建築構造體之要部橫剖面圖。 Fig. 10 is a cross-sectional view showing the principal part of a building structure according to still another embodiment of the present invention.
圖11係表示本發明之實施例之評價表。 Figure 11 is a diagram showing an evaluation form of an embodiment of the present invention.
以下參考圖1~圖6說明本發明之建築構造體之一實施形態。 An embodiment of the building structure of the present invention will be described below with reference to Figs. 1 to 6 .
如圖1及圖2所示,本實施形態之建築構造體1具備:以彼此之長度方向平行之方式並列於寬度方向上之複數個(於圖1及圖2中,圖示有2個)長條材料2;及嵌入於長條材料2、2間之面板3。建築構造體1具備:固定於長條材料2之端部之框材4、4;及固定於長條材料2之側部之板材5。於本實施形態中,建築構造體1為壁。 As shown in FIG. 1 and FIG. 2, the building structure 1 of the present embodiment includes a plurality of parallel rows in the longitudinal direction so as to be parallel to each other in the longitudinal direction (in FIG. 1 and FIG. 2, two are shown). The strip material 2; and the panel 3 embedded between the strips 2 and 2. The building structure 1 includes a frame member 4 and 4 fixed to an end portion of the elongated material 2, and a plate member 5 fixed to a side portion of the elongated material 2. In the present embodiment, the building structure 1 is a wall.
長條材料2於寬度方向之兩側具備支持面板3之支持面21、21。具體而言,長條材料2之剖面形狀為矩形狀。複數個長條材料2係以支持面21彼此相對之方式進行配置。於本實施形態中,長條材料2為柱,以長度方向與高度方向平行之方式進行配置。 The elongated material 2 is provided with support faces 21 and 21 of the support panel 3 on both sides in the width direction. Specifically, the cross-sectional shape of the elongated material 2 is a rectangular shape. The plurality of strips 2 are arranged such that the support faces 21 face each other. In the present embodiment, the elongated material 2 is a column and is disposed such that its longitudinal direction is parallel to the height direction.
面板3係形成為長方體狀。於面板3嵌入於長條材料2、2間之狀態下,面板3之長度方向與長條材料2之長度方向平行,面板3之寬度方向與長條材料2之寬度方向平行。 The panel 3 is formed in a rectangular parallelepiped shape. In a state in which the panel 3 is fitted between the elongated materials 2 and 2, the longitudinal direction of the panel 3 is parallel to the longitudinal direction of the elongated material 2, and the width direction of the panel 3 is parallel to the width direction of the elongated material 2.
於本發明中,與長條材料2之長度方向平行之方向係指建築構造體1、長條材料2及面板3之各自之第1方向D1,與並列長條材料2之方向平行之方向係指建築構造體1、長條材料2及面板3之各自之第2方向D2,與第1方向D1及第2方向D2正交之方向係指建築構造體1、長條材料2及面板3之各自之第3方向D3。 In the present invention, the direction parallel to the longitudinal direction of the long material 2 refers to the first direction D1 of each of the building structure 1, the elongated material 2, and the panel 3, and is parallel to the direction of the parallel strip material 2. The second direction D2 of each of the building structure 1, the long material 2, and the panel 3, and the direction orthogonal to the first direction D1 and the second direction D2 means the building structure 1, the elongated material 2, and the panel 3 The third direction of each is D3.
即,於本實施形態中,面板3之第1方向D1為面板3之長 度方向(縱向),面板3之第2方向D2為面板3之寬度方向,面板3之第3方向D3為面板3之厚度方向。以下,相當於第1方向~第3方向D1、D2、D3之方向分別標註D1、D2、D3之符號。 That is, in the present embodiment, the first direction D1 of the panel 3 is the length of the panel 3. In the direction of the dimension (longitudinal direction), the second direction D2 of the panel 3 is the width direction of the panel 3, and the third direction D3 of the panel 3 is the thickness direction of the panel 3. Hereinafter, the directions corresponding to the directions of the first direction to the third direction D1, D2, and D3 are denoted by D1, D2, and D3, respectively.
如圖3及圖4所示,面板3係由合成樹脂(例如,胺酯(urethane)系樹脂、苯乙烯系樹脂、酚系樹脂等)形成且具有彈性之發泡體。具體而言,面板3係具有沿著與寬度方向D2正交之方向形成為長條之複數個單元31的發泡體,以於寬度方向D2上具有彈性。 As shown in FIG. 3 and FIG. 4, the panel 3 is a foam which is formed of a synthetic resin (for example, an urethane resin, a styrene resin, a phenol resin, or the like) and has elasticity. Specifically, the panel 3 has a foam having a plurality of cells 31 formed in a long direction orthogonal to the width direction D2, and has elasticity in the width direction D2.
再者,於本發明中,無需所有之單元31沿著與第2方向D2正交之方向形成為長條,只要以面板3於第2方向D2上具有彈性之方式,使例如半數以上之單元31沿著與第2方向D2正交之方向形成為長條即可。即,於本發明中,只要面板3於第2方向D2上具有彈性,則亦可設置沿著與第2方向D2平行之方向形成為長條之單元31。 Furthermore, in the present invention, it is not necessary for all of the cells 31 to be formed in a strip in a direction orthogonal to the second direction D2, and for example, more than half of the cells are provided such that the panel 3 has elasticity in the second direction D2. 31 may be formed in a strip along a direction orthogonal to the second direction D2. That is, in the present invention, as long as the panel 3 has elasticity in the second direction D2, a unit 31 formed in a strip shape in a direction parallel to the second direction D2 may be provided.
面板3係以寬度方向D2之彈性模數小於長度方向D1之彈性模數之方式形成。並且,面板3係以寬度方向D2之彈性模數與厚度方向D3之彈性模數大致相同之方式形成。 The panel 3 is formed such that the elastic modulus in the width direction D2 is smaller than the elastic modulus in the longitudinal direction D1. Further, the panel 3 is formed such that the modulus of elasticity in the width direction D2 is substantially the same as the modulus of elasticity in the thickness direction D3.
具體而言,面板3係藉由使複數個單元31沿著與寬度方向D2正交之方向中之長度方向D1形成為長條,而以寬度方向D2之彈性模數小於長度方向D1之彈性模數之方式形成。更具體而言,藉由將複數個單元31以最長尺寸之方向沿著長度方向D1之方式進行配置,而使面板3之寬度方向D2及厚度方向D3之彈性模數小於長度方向D1之彈性模數。 Specifically, the panel 3 is formed by making the plurality of cells 31 elongated in the longitudinal direction D1 in the direction orthogonal to the width direction D2, and the elastic modulus in the width direction D2 is smaller than the elastic mode of the longitudinal direction D1. The way of the number is formed. More specifically, by arranging the plurality of cells 31 in the longitudinal direction D1 in the direction of the longest dimension, the elastic modulus of the width direction D2 and the thickness direction D3 of the panel 3 is smaller than the elastic mode of the length direction D1. number.
再者,彈性模數係對面板3施加外力使其變形之情形時之彈性範圍內的應力與應變(變形量)之比率。換而言之,彈性模數越小,以 相同之應力(壓力)進行變形之量越增大。 Further, the elastic modulus is a ratio of stress to strain (amount of deformation) in the elastic range when an external force is applied to the panel 3 to deform it. In other words, the smaller the modulus of elasticity, The same amount of stress (pressure) is deformed.
由於未發生彈性變形之面板3之寬度方向D2之尺寸W2大於長條材料2、2之相隔距離W1,故而將面板3於在寬度方向D2上被壓縮變形之狀態下嵌入於長條材料2、2間。未發生彈性變形之面板3之寬度方向D2之尺寸W2較佳為長條材料2、2之相隔距離W1之101%~115%,更佳為105%~110%。 Since the dimension W2 of the width direction D2 of the panel 3 which is not elastically deformed is larger than the distance W1 of the strip materials 2 and 2, the panel 3 is embedded in the strip material 2 in a state of being compressed and deformed in the width direction D2. 2 rooms. The dimension W2 of the width direction D2 of the panel 3 which is not elastically deformed is preferably 101% to 115%, more preferably 105% to 110%, of the distance W1 between the strips 2 and 2.
於本實施形態中,面板3為聚胺酯泡沫面板。於下文詳細地說明面板3之構成。 In the present embodiment, the panel 3 is a polyurethane foam panel. The constitution of the panel 3 will be described in detail below.
面板3係使多元醇組成物(含有多元醇化合物與作為發泡劑之水)與聚異氰酸酯成分進行混合、反應而獲得,且具有縱向(長度方向)D1、寬度方向D2及厚度方向D3之聚胺酯泡沫面板,並且設定為泡沫密度成為15kg/m3以下,且縱向D1之10%壓縮強度SD1與寬度方向D2之10%壓縮強度SD2之比(SD1/SD2)成為2以上。 The panel 3 is obtained by mixing and reacting a polyol composition (containing a polyol compound and water as a foaming agent) with a polyisocyanate component, and having a polyurethane in the longitudinal direction (longitudinal direction) D1, the width direction D2, and the thickness direction D3. foam panels, and is set to become foam density 15kg / m 3 or less, and 10% of the longitudinal compressive strength D1 D1 the width direction D2 S 10% of the compressive strength ratio S D2 (S D1 / S D2) becomes 2 or more.
面板3之泡沫密度(核心密度)較佳為15kg/m3以下,更佳為13kg/m3以下,進而較佳為11kg/m3以下。該泡沫密度係例如藉由將作為發泡劑之水之量調整為20~100重量份(相對於多元醇化合物100重量份)而設定為上述範圍內。此處,泡沫密度係依據JIS K7222進行測定之值。 The density of the foam panel (core density) is preferably 15kg / m 3 or less, more preferably 13kg / m 3 or less, and further preferably 11kg / m 3 or less. The foam density is set to be within the above range, for example, by adjusting the amount of water as a foaming agent to 20 to 100 parts by weight (100 parts by weight based on the polyol compound). Here, the foam density is a value measured in accordance with JIS K7222.
面板3之泡沫密度為15kg/m3以下,故而非常低,面板3之發泡倍率較高。因此,單元31係於縱向D1上被拉伸而形成為橢圓體狀。藉由使橢圓體狀之單元31之長徑方向與面板3之縱向D1平行,面板3之縱向D1之泡沫強度增高,另一方面,面板3之寬度方向D2及厚度方向D3 之泡沫強度降低,面板3之寬度方向D2及厚度方向D3具備彈性(柔軟性)。 The foam density of the panel 3 is 15 kg/m 3 or less, so it is very low, and the expansion ratio of the panel 3 is high. Therefore, the unit 31 is stretched in the longitudinal direction D1 to be formed into an ellipsoidal shape. By making the major axis direction of the ellipsoidal unit 31 parallel to the longitudinal direction D1 of the panel 3, the foam strength in the longitudinal direction D1 of the panel 3 is increased, and on the other hand, the foam strength in the width direction D2 and the thickness direction D3 of the panel 3 is lowered. The width direction D2 and the thickness direction D3 of the panel 3 are elastic (flexibility).
面板3係以縱向D1之10%壓縮強度SD1與寬度方向D2之10%壓縮強度SD2之比(SD1/SD2)成為2以上之方式形成。為了兼具將面板3嵌入於長條材料2、2間之作業性、與被嵌入之面板3之自支持性,較佳為縱向D1之10%壓縮強度SD1與寬度方向D2之10%壓縮強度SD2之比(SD1/SD2)為3以上,更佳為5以上。該比(SD1/SD2)之上限並無特別限定,例如為7左右。再者,X%壓縮強度為僅使面板3壓縮變形X%之量所必需之應力。 3 longitudinal panel lines D1 to 10% of the compressive strength and the width direction D2 D1 S 10% of the compressive strength ratio S D2 (S D1 / S D2) of 2 or more is formed becomes. In order to combine the workability of embedding the panel 3 between the elongated materials 2 and 2 and the self-supporting property of the panel 3 to be embedded, it is preferable to compress the 10% compressive strength S D1 and the width direction D2 of the longitudinal direction D1. The ratio of the strength S D2 (S D1 /S D2 ) is 3 or more, and more preferably 5 or more. The upper limit of the ratio (S D1 /S D2 ) is not particularly limited, and is, for example, about 7. Further, the X% compressive strength is a stress necessary for only compressing the panel 3 by an amount of X%.
為了提高將面板3嵌入於長條材料2、2間之作業性,必須使面板3於寬度方向D2上可容易壓縮。因此,面板3之寬度方向D2之10%壓縮強度SD2較佳為3N/cm2以下,更佳為1N/cm2以下,尤佳為0.5N/cm2以下。 In order to improve the workability of embedding the panel 3 between the elongated materials 2 and 2, it is necessary to easily compress the panel 3 in the width direction D2. Therefore, the 10% compressive strength S D2 of the width direction D2 of the panel 3 is preferably 3 N/cm 2 or less, more preferably 1 N/cm 2 or less, and particularly preferably 0.5 N/cm 2 or less.
又,為了提高將面板3嵌入於長條材料2、2間之作業性,亦必須使被壓縮之面板3迅速復原。因此,面板3較佳為即便於寬度方向D2上被壓縮20%亦不產生損傷及破壞,而且於在寬度方向D2上被壓縮20%後解除該壓縮之情形時,可復原至壓縮前之寬度方向D2之尺寸之90%以上。 Further, in order to improve the workability of embedding the panel 3 between the long materials 2 and 2, it is necessary to quickly restore the compressed panel 3. Therefore, it is preferable that the panel 3 is not damaged or broken even if it is compressed by 20% in the width direction D2, and can be restored to the width before compression when the compression is released after being compressed by 20% in the width direction D2. More than 90% of the size of the direction D2.
面板3較佳為單元31之發泡方向與寬度方向D2及厚度方向D3分別大致垂直。所謂「大致垂直」,具體而言,意指90°±15°,尤其意指90°±10°。所謂「單元之發泡方向」,意指將各個單元31之形狀視作橢圓體狀時之長徑方向,尤其係指於面板3之寬度方向D2之中央部分(自縱向D1及寬度方向D2中心至縱向D1之尺寸及寬度方向D2之尺寸之兩側10%左右之部分)進行測定時之方向。 Preferably, the panel 3 has a foaming direction of the unit 31 which is substantially perpendicular to the width direction D2 and the thickness direction D3. By "substantially perpendicular", specifically, it means 90 ° ± 15 °, especially 90 ° ± 10 °. The term "foaming direction of the unit" means the direction of the major axis when the shape of each unit 31 is regarded as an elliptical shape, and particularly refers to the central portion of the width direction D2 of the panel 3 (from the center of the longitudinal direction D1 and the width direction D2). The direction to the measurement is made to the portion of the dimension of the longitudinal direction D1 and the portion of the dimension D2 which is about 10% on both sides.
由於面板3可作為隔熱材料使用,故而面板3之熱導率λ 較佳為0.04W/m‧K以下。藉此,即便為經低密度化之面板3,亦可發揮充分之隔熱性能。再者,熱導率係依據JIS A1412-2進行測定之值。 Since the panel 3 can be used as a heat insulating material, the thermal conductivity of the panel 3 is λ. It is preferably 0.04 W/m‧K or less. Thereby, even if it is the panel 3 which is low density, it can exhibit sufficient heat insulation performance. Further, the thermal conductivity is a value measured in accordance with JIS A1412-2.
面板3之獨立氣泡率較佳為15%以下,更佳為0~10%。如此,藉由提高連通化率,可確保優異之尺寸穩定性。此處,獨立氣泡率係依據ASTM D2856進行測定之值。 The closed cell ratio of the panel 3 is preferably 15% or less, more preferably 0 to 10%. Thus, by increasing the connectivity ratio, excellent dimensional stability can be ensured. Here, the independent bubble ratio is a value measured in accordance with ASTM D2856.
如上所述,面板3係使多元醇組成物(含有多元醇化合物與作為發泡劑之水)、與聚異氰酸酯成分進行混合、反應而獲得。 As described above, the panel 3 is obtained by mixing and reacting a polyol composition (containing a polyol compound and water as a foaming agent) and a polyisocyanate component.
上述多元醇化合物較佳為含有平均官能基數為2~4且重量平均分子量為3000~8000且為環氧烷之聚合物的聚醚多元醇(A)、與分子量未達250之短鏈二醇(B)。 The above polyol compound is preferably a polyether polyol (A) having a polymer having an average number of functional groups of 2 to 4 and a weight average molecular weight of 3,000 to 8,000 and being an alkylene oxide, and a short-chain diol having a molecular weight of less than 250. (B).
聚醚多元醇(A)係於具有2~4個活性氫原子之起始劑中使環氧烷進行開環加成聚合所得之聚氧伸烷基多元醇。 The polyether polyol (A) is a polyoxyalkylene polyol obtained by subjecting an alkylene oxide to ring-opening addition polymerization in an initiator having 2 to 4 active hydrogen atoms.
作為起始劑,例如可列舉:脂肪族多元醇(例如,乙二醇、丙二醇、二乙二醇、二丙二醇、1,4-丁二醇、1,3-丁二醇、1,6-己二醇、新戊二醇、環己二醇、環己烷二甲醇等二醇類;三羥甲基丙烷、甘油等三醇類;新戊四醇等四官能醇類)、脂肪族胺(例如,乙二胺、丙二胺、丁二胺、己二胺、新戊二胺等伸烷基二胺;單乙醇胺、二乙醇胺等烷醇胺)、芳香族胺(例如,2,4-甲苯二胺、2,6-甲苯二胺、二乙基甲苯二胺、4,4'-二胺基二苯甲烷、對苯二胺、鄰苯二胺、萘二胺等)等。該等可分別單獨使用1種,又,亦可併用2種以上。作為起始劑,較佳為使用脂肪族醇,更佳為使用三醇類,尤佳為使用甘油。 As the initiator, for example, an aliphatic polyol (for example, ethylene glycol, propylene glycol, diethylene glycol, dipropylene glycol, 1,4-butanediol, 1,3-butylene glycol, 1,6-) may be mentioned. Glycols such as hexanediol, neopentyl glycol, cyclohexanediol, and cyclohexanedimethanol; triols such as trimethylolpropane and glycerin; tetrafunctional alcohols such as pentaerythritol; and aliphatic amines (e.g., alkyl diamine such as ethylenediamine, propylenediamine, butanediamine, hexamethylenediamine, neopentylamine, etc.; alkanolamine such as monoethanolamine or diethanolamine), aromatic amine (for example, 2, 4) - Toluene diamine, 2,6-toluenediamine, diethyltoluenediamine, 4,4'-diaminodiphenylmethane, p-phenylenediamine, o-phenylenediamine, naphthalenediamine, etc.). These may be used alone or in combination of two or more. As the initiator, it is preferred to use an aliphatic alcohol, more preferably a triol, and particularly preferably glycerin.
聚醚多元醇(A)之平均官能基數為2~4,更佳為2.5~3.5。 進而,聚醚多元醇(A)之重量平均分子量更佳為3000~5000。 The polyether polyol (A) has an average functional group number of 2 to 4, more preferably 2.5 to 3.5. Further, the weight average molecular weight of the polyether polyol (A) is more preferably from 3,000 to 5,000.
作為環氧烷(alkylene oxide),可列舉:環氧乙烷、環氧丙烷、1,2-環氧丁烷、2,3-環氧丁烷、環氧苯乙烷(styrene oxide)、環氧環己烷(cyclohexene oxide)等。其中,較佳為併用環氧乙烷及環氧丙烷,於上述起始劑中進行開環加成聚合。此時,較佳為將環氧乙烷之比率((環氧乙烷)/(環氧乙烷+環氧丙烷))設為5%~30%。 Examples of the alkylene oxide include ethylene oxide, propylene oxide, 1,2-butylene oxide, 2,3-butylene oxide, styrene oxide, and ring. Cyclohexene oxide or the like. Among them, it is preferred to use a combination of ethylene oxide and propylene oxide to carry out ring-opening addition polymerization in the above initiator. In this case, it is preferred to set the ratio of ethylene oxide ((ethylene oxide) / (ethylene oxide + propylene oxide)) to 5% to 30%.
聚醚多元醇(A)之羥值較佳為20~100mgKOH/g,更佳為30~60mgKOH/g。於該羥值未達20mgKOH/g之情形時,多元醇組成物相對於聚異氰酸酯成分之黏度比增高,產生混合時之攪拌不良。反之,於超過100mgKOH/g之情形時,變得難以對所獲得之聚胺酯泡沫賦予適度之韌性。羥值係依據JIS K1557-1:2007進行測定之值。 The hydroxyl value of the polyether polyol (A) is preferably from 20 to 100 mgKOH/g, more preferably from 30 to 60 mgKOH/g. When the hydroxyl value is less than 20 mgKOH/g, the viscosity ratio of the polyol composition to the polyisocyanate component is increased, resulting in poor stirring during mixing. On the other hand, in the case of exceeding 100 mgKOH/g, it becomes difficult to impart moderate toughness to the obtained polyurethane foam. The hydroxyl value is a value measured in accordance with JIS K1557-1:2007.
分子量未達250之短鏈二醇(B)例如可列舉:乙二醇(分子量62)、丙二醇(分子量76)、二乙二醇(分子量106)、二丙二醇(分子量134)、1,4-丁二醇(分子量90)、1,3-丁二醇(分子量90)、1,6-己二醇(分子量118)、甘油(分子量92)、三丙二醇(分子量192)等。該等之中,為更確實地提高泡沫之樹脂強度,較佳為二乙二醇、二丙二醇及甘油,尤佳為二乙二醇。短鏈二醇(B)之分子量較佳為62~200mgKOH/g,更佳為90~150mgKOH/g。 Examples of the short-chain diol (B) having a molecular weight of less than 250 include ethylene glycol (molecular weight 62), propylene glycol (molecular weight 76), diethylene glycol (molecular weight 106), dipropylene glycol (molecular weight 134), and 1,4- Butylene glycol (molecular weight 90), 1,3-butanediol (molecular weight 90), 1,6-hexanediol (molecular weight 118), glycerin (molecular weight 92), tripropylene glycol (molecular weight 192), and the like. Among these, in order to more reliably improve the resin strength of the foam, diethylene glycol, dipropylene glycol and glycerin are preferred, and diethylene glycol is particularly preferred. The molecular weight of the short-chain diol (B) is preferably from 62 to 200 mgKOH/g, more preferably from 90 to 150 mgKOH/g.
於用作原料之多元醇組成物中,作為多元醇化合物,較佳為進而含有平均官能基數為2~4且重量平均分子量為3000~5000之作為環氧丙烷之聚合物之聚醚多元醇(C)。聚醚多元醇(C)係於具有2~4個活性氫原子之起始劑中僅使環氧丙烷進行開環加成聚合所獲得之聚氧伸烷基多 元醇。作為起始劑,可列舉上述之脂肪族多元醇、脂肪族胺、芳香族胺等,並無特別限定。作為起始劑,尤佳為甘油。 In the polyol composition used as a raw material, as the polyol compound, a polyether polyol which is a polymer of propylene oxide having an average functional group number of 2 to 4 and a weight average molecular weight of 3,000 to 5,000 is preferably contained. C). The polyether polyol (C) is a polyoxyalkylene group obtained by subjecting only propylene oxide to ring-opening addition polymerization in an initiator having 2 to 4 active hydrogen atoms. Alcohol. The above-mentioned aliphatic polyol, aliphatic amine, aromatic amine, and the like are not particularly limited as the initiator. As the initiator, glycerin is particularly preferred.
於用作原料之多元醇組成物中,為了製造低密度化且隔熱性能優異之聚胺酯泡沫面板3,較佳為於多元醇化合物100重量份中,含有聚醚多元醇(A)10~80重量份,含有短鏈二醇(B)10~60重量份,更佳為含有聚醚多元醇(A)15~70重量份,含有短鏈二醇(B)10~50重量份。又,於含有聚醚多元醇(C)之情形時,較佳為含有聚醚多元醇(A)10~30重量份,含有短鏈二醇(B)10~60重量份,且含有聚醚多元醇(C)30~70重量份,進而更佳為含有聚醚多元醇(A)15~25重量份,含有短鏈二醇(B)10~50重量份,且含有聚醚多元醇(C)40~60重量份。 In the polyol composition used as a raw material, in order to produce a polyurethane foam panel 3 which is low in density and excellent in heat insulating property, it is preferable to contain a polyether polyol (A) 10 to 80 in 100 parts by weight of the polyol compound. The parts by weight include 10 to 60 parts by weight of the short-chain diol (B), more preferably 15 to 70 parts by weight of the polyether polyol (A), and 10 to 50 parts by weight of the short-chain diol (B). Further, in the case of containing the polyether polyol (C), it is preferably 10 to 30 parts by weight of the polyether polyol (A), 10 to 60 parts by weight of the short-chain diol (B), and contains a polyether. The polyol (C) is 30 to 70 parts by weight, more preferably 15 to 25 parts by weight of the polyether polyol (A), 10 to 50 parts by weight of the short-chain diol (B), and contains a polyether polyol ( C) 40 to 60 parts by weight.
於上述多元醇組成物中,摻合水作為發泡劑。發泡劑較佳為單獨為水,其摻合量相對於多元醇化合物100重量份,較佳為20~100重量份,更佳為30~90重量份,進而較佳為40~80重量份。藉由如此大量地摻合水,可謀求面板3之低密度化。 In the above polyol composition, water is blended as a foaming agent. The foaming agent is preferably water alone, and the blending amount thereof is preferably 20 to 100 parts by weight, more preferably 30 to 90 parts by weight, still more preferably 40 to 80 parts by weight, per 100 parts by weight of the polyol compound. . By blending water in such a large amount, the density of the panel 3 can be reduced.
於上述多元醇組成物中,通常可進而摻合難燃劑、觸媒及泡沫穩定劑。又,於上述多元醇組成物中,亦可進而摻合著色劑及抗氧化劑等各種添加劑。 In the above polyol composition, a flame retardant, a catalyst, and a foam stabilizer can be usually blended. Further, various additives such as a coloring agent and an antioxidant may be further blended in the above polyol composition.
作為難燃劑,可列舉:有機磷酸酯類、含鹵化合物、氫氧化鋁等金屬化合物,尤其是有機磷酸酯類具有多元醇組成物之黏度降低效果,故而較佳。作為有機磷酸酯,可列舉:磷酸之鹵化烷基酯、磷酸烷基酯、磷酸芳基酯、膦酸酯等。具體而言,可列舉:磷酸三(氯丙基)酯(TMCPP,大八化學製造)、磷酸三(丁氧基乙基)酯(TBEP)、磷酸三丁酯、磷酸三乙 酯、磷酸三甲酯、磷酸甲酚基二苯酯等。難燃劑之摻合量相對於多元醇化合物100重量份,較佳為10~50重量份,更佳為15~40重量份。尤其為了防止泡沫之脆性惡化,較佳為於多元醇組成物中,除上述聚醚多元醇(A)及上述短鏈二醇(B)以外,亦含有相對於多元醇化合物100重量份為20重量份以上之難燃劑。 Examples of the flame retardant include metal compounds such as organic phosphates, halogen-containing compounds, and aluminum hydroxide. In particular, organic phosphates have a viscosity-reducing effect of a polyol composition, which is preferable. Examples of the organic phosphate include a halogenated alkyl phosphate, an alkyl phosphate, an aryl phosphate, a phosphonate, and the like. Specific examples thereof include tris(chloropropyl) phosphate (TMCPP, manufactured by Daihachi Chemical Co., Ltd.), tris(butoxyethyl) phosphate (TBEP), tributyl phosphate, and triethyl phosphate. Ester, trimethyl phosphate, cresyl diphenyl phosphate, and the like. The blending amount of the flame retardant is preferably from 10 to 50 parts by weight, more preferably from 15 to 40 parts by weight, per 100 parts by weight of the polyol compound. In particular, in order to prevent the deterioration of the brittleness of the foam, it is preferred that the polyol composition contains 20 parts by weight of the polyol compound in addition to the above polyether polyol (A) and the short-chain diol (B). More than a part by weight of the flame retardant.
作為觸媒,只有為促進胺酯化反應之觸媒,則並無特別限定,較佳為使用可與聚異氰酸酯成分之異氰酸酯基進行反應之反應性之胺觸媒。作為此種反應性之胺觸媒,可列舉:N,N-二甲基乙醇胺、N,N-二甲基胺基乙氧基乙醇、N,N,N'-三甲基胺基乙基乙醇胺、N,N,N',N'-四甲基-2-羥基丙二胺、N-羥基乙基嗎福啉、N-甲基-N-羥基乙基哌、N,N-二甲基丙二胺等。 The catalyst is not particularly limited as long as it is a catalyst for promoting an amine esterification reaction, and an amine catalyst which is reactive with an isocyanate group of a polyisocyanate component is preferably used. As such a reactive amine catalyst, N,N-dimethylethanolamine, N,N-dimethylaminoethoxyethanol, N,N,N'-trimethylaminoethyl Ethanolamine, N,N,N',N'-tetramethyl-2-hydroxypropanediamine, N-hydroxyethylmorpholine, N-methyl-N-hydroxyethylpiper , N, N-dimethylpropanediamine, and the like.
再者,亦可使用通常之三級胺觸媒,作為此種三級胺觸媒,可列舉:N,N,N',N'-四甲基乙二胺、N,N,N',N'-四甲基己二胺、N,N,N',N',N"-五甲基二乙三胺、二氮雜雙環十一烯、N,N-二甲基環己胺、三乙二胺、N-甲基嗎福啉等。 Further, a usual tertiary amine catalyst can also be used. As such a tertiary amine catalyst, N, N, N', N'-tetramethylethylenediamine, N, N, N', N'-tetramethylhexamethylenediamine, N,N,N',N',N"-pentamethyldiethylenetriamine, diazabicycloundecene, N,N-dimethylcyclohexylamine, Triethylenediamine, N-methylmorpholine, and the like.
觸媒之摻合量相對於多元醇化合物100重量份,較佳為2~10重量份,更佳為3~8重量份。 The blending amount of the catalyst is preferably 2 to 10 parts by weight, more preferably 3 to 8 parts by weight, per 100 parts by weight of the polyol compound.
作為泡沫穩定劑,可自公知之聚胺酯泡沫用之泡沫穩定劑中,例如列舉作為環氧乙烷或環氧丙烷之聚合物之聚氧伸烷基二醇與聚二甲基矽氧烷之接枝共聚物,可較佳地使用聚氧伸烷基中之氧化乙烯基含有率為70~100莫耳%之聚矽氧泡沫穩定劑,具體而言,可列舉:SH-193、SF-2937F、SF-2938F(Dow Corning Toray Silicone公司製造)、B-8465、B -8467、B-8481(Evonik Degussa Japan公司製造)、L-6900(Momentive公司製造)等。泡沫穩定劑之摻合量相對於多元醇化合物100重量份,較佳為1~10重量份。 As a foam stabilizer, a foam stabilizer for a polyurethane foam can be known, for example, a graft of a polyoxyalkylene glycol as a polymer of ethylene oxide or propylene oxide and polydimethylsiloxane. As the copolymer, a polyoxyxylene foam stabilizer having an oxyethylene group content of 70 to 100 mol% in the polyoxyalkylene group can be preferably used, and specific examples thereof include SH-193 and SF-2937F. SF-2938F (manufactured by Dow Corning Toray Silicone), B-8465, B -8467, B-8481 (manufactured by Evonik Degussa Japan Co., Ltd.), L-6900 (manufactured by Momentive Co., Ltd.), and the like. The blending amount of the foam stabilizer is preferably from 1 to 10 parts by weight based on 100 parts by weight of the polyol compound.
作為與上述多元醇組成物進行混合、反應而形成聚胺酯泡沫面板3之聚異氰酸酯成分,可使用具有2個以上異氰酸酯基之芳香族系、脂環族系、脂肪族系等各種聚異氰酸酯化合物。就使用之容易性、反應速度、所獲得之聚胺酯泡沫之物理特性優異、及低成本等方面而言,較佳為使用液狀二苯基甲烷二異氰酸酯(MDI)。作為液狀MDI,可列舉:粗MDI(c-MDI)(44V-10、44V-20等(Sumika Bayer Urethane公司製造)、MILLIONATE MR-200(Nippon Polyurethane Industry))、含脲酮亞胺(uretonimine)之MDI(MILLIONATE MTL,Nippon Polyurethane Industry製造)等。除液狀MDI以外,亦可併用其他聚異氰酸酯化合物,作為併用之聚異氰酸酯化合物,可於聚胺酯之技術領域內並無限定地使用公知之聚異氰酸酯化合物。 As the polyisocyanate component which is mixed and reacted with the above polyol composition to form the polyurethane foam panel 3, various polyisocyanate compounds such as an aromatic, alicyclic or aliphatic group having two or more isocyanate groups can be used. Liquid diphenylmethane diisocyanate (MDI) is preferably used in terms of easiness of use, reaction rate, excellent physical properties of the obtained polyurethane foam, and low cost. Examples of the liquid MDI include crude MDI (c-MDI) (44V-10, 44V-20, etc. (manufactured by Sumika Bayer Urethane Co., Ltd.), MILLIONATE MR-200 (Nippon Polyurethane Industry), and uretonimine. MDI (MILLIONATE MTL, manufactured by Nippon Polyurethane Industry) and the like. In addition to the liquid MDI, other polyisocyanate compounds may be used in combination as the polyisocyanate compound to be used in combination, and a known polyisocyanate compound may be used without limitation in the technical field of the polyurethane.
面板3較佳為將使多元醇組成物與聚異氰酸酯成分進行混合、反應時之異氰酸酯指數(NCO Index)設為30以下,更佳為設為未達30。作為異氰酸酯指數之下限,例如可列舉20。藉由將異氰酸酯指數設為上述範圍內,可製成低密度、且具備優異之彈性及隔熱性能之聚胺酯泡沫面板3。此處,所謂異氰酸酯指數,意指以百分率表示聚異氰酸酯成分之異氰酸酯基相對於多元醇組成物中所含之所有活性氫基(將作為發泡劑之水作為二官能活性氫化合物進行計算)之當量比者(異氰酸酯基相對於活性氫基100當量之當量比)。 The panel 3 preferably has an isocyanate index (NCO Index) of 30 or less, more preferably 30 or less, when the polyol composition and the polyisocyanate component are mixed and reacted. The lower limit of the isocyanate index is, for example, 20 . By setting the isocyanate index within the above range, the polyurethane foam panel 3 having a low density and excellent elasticity and heat insulating properties can be obtained. Here, the isocyanate index means that the isocyanate group of the polyisocyanate component is expressed as a percentage relative to all the active hydrogen groups contained in the polyol composition (the water as a blowing agent is calculated as a difunctional active hydrogen compound) Equivalent ratio (equivalent ratio of isocyanate groups to 100 equivalents of active hydrogen groups).
面板3之製造方法係將含有多元醇組成物(含有多元醇化合物與作為發泡劑之水)、與聚異氰酸酯成分之發泡原液組成物作為原料而得之聚胺酯泡沫面板3之製造方法,較佳為該多元醇化合物例如多元醇組成物含有聚醚多元醇(A)、與分子量未達250之短鏈二醇(B)之多元醇化合物,且含有相對於多元醇化合物100重量份為20~100重量份之水,使多元醇組成物與聚異氰酸酯成分進行混合、反應時之異氰酸酯指數未達30,又,上述聚醚多元醇(A)其平均官能基數為2~4且重量平均分子量為3000~8000,且係環氧烷之聚合物。而且,為了以面板3於寬度方向D2上具有彈性之方式,使複數個單元31沿著面板3之縱向D1形成為長條,較佳為具備:注入步驟,如圖5所示,對於具有縱向D1、寬度方向D2及厚度方向D3之模具7,以沿寬度方向D2及厚度方向D3延伸之面作為底面71注入發泡原液組成物;以及反應步驟,於注入步驟後使上述發泡原液組成物進行反應。 The manufacturing method of the panel 3 is a manufacturing method of the polyurethane foam panel 3 which consists of a polyol composition (water containing a polyol compound and water as a foaming agent), and a foaming raw material composition of poly isocyanate component as a raw material. Preferably, the polyol compound, for example, a polyol composition contains a polyether polyol (A), a polyol compound having a short-chain diol (B) having a molecular weight of less than 250, and contains 20 parts by weight based on 100 parts by weight of the polyol compound. ~100 parts by weight of water, the polyol composition is mixed with the polyisocyanate component, the isocyanate index is less than 30, and the polyether polyol (A) has an average functional group number of 2 to 4 and a weight average molecular weight. It is 3000~8000 and is a polymer of alkylene oxide. Further, in order to form the plurality of units 31 in the longitudinal direction D1 of the panel 3 as a strip in such a manner that the panel 3 has elasticity in the width direction D2, it is preferable to have an injection step as shown in FIG. a mold 7 having a D1, a width direction D2, and a thickness direction D3, and a surface extending in the width direction D2 and the thickness direction D3 as a bottom surface 71 to inject a foaming stock composition; and a reaction step of causing the foaming stock composition after the injection step Carry out the reaction.
具體而言,於面板3之製造方法中,對於具有縱向D1、寬度方向D2及厚度方向D3之模具7,以沿寬度方向D2及厚度方向D3延伸之面作為底面71,自混合頭(mixing head)8注入含有多元醇組成物與聚異氰酸酯成分之發泡原液組成物(注入步驟)。注入後,發泡原液組成物一面進行反應,一面於縱向D1上進行發泡(一面膨脹),同時形成泡沫(反應步驟)。於上述反應步驟中,亦可視需要對模具7整體或局部地進行加溫。 Specifically, in the manufacturing method of the panel 3, for the mold 7 having the longitudinal direction D1, the width direction D2, and the thickness direction D3, the surface extending in the width direction D2 and the thickness direction D3 is used as the bottom surface 71, and the mixing head is used. 8) A foaming stock composition containing a polyol composition and a polyisocyanate component is injected (injection step). After the injection, the foaming stock composition is subjected to a reaction while being foamed (one side is expanded) in the longitudinal direction D1 to form a foam (reaction step). In the above reaction step, the mold 7 may be heated as a whole or in part as needed.
本實施形態之建築構造體1之構成係如上所述,其次,參考圖6於下文說明本實施形態之建築構造體1之製造方法。 The structure of the building structure 1 of the present embodiment is as described above. Next, a method of manufacturing the building structure 1 of the present embodiment will be described below with reference to Fig. 6 .
如圖6所示,複數個長條材料2、2係以長度方向D1平行 之方式並列於寬度方向D2上。藉由對面板3施加外力,而使面板3於寬度方向D2上被壓縮。藉此,大於長條材料2、2之相隔距離W1的面板3之寬度方向D2之尺寸W2變得小於長條材料2、2之相隔距離W1。 As shown in FIG. 6, a plurality of strips 2 and 2 are parallel in the longitudinal direction D1. The manner is juxtaposed in the width direction D2. The panel 3 is compressed in the width direction D2 by applying an external force to the panel 3. Thereby, the dimension W2 of the width direction D2 of the panel 3 which is larger than the distance W1 of the long strips 2, 2 becomes smaller than the distance W1 of the strip material 2, 2.
使於寬度方向D2上被壓縮之面板3位於長條材料2、2間後,解除所施加之外力,藉此使面板3復原。面板3抵接於長條材料2之支持面21後,亦因彈性力進而進行復原,故而於與長條材料2密合且推壓長條材料2之狀態下嵌入於長條材料2、2間。 After the panel 3 compressed in the width direction D2 is placed between the elongated materials 2 and 2, the applied external force is released, thereby restoring the panel 3. After the panel 3 abuts against the support surface 21 of the long material 2, the panel 3 is also restored by the elastic force, so that it is embedded in the strip material 2, 2 in a state in which it is adhered to the strip material 2 and the strip material 2 is pressed. between.
由以上可知,根據本實施形態之建築構造體1,複數個長條材料2係以彼此之長度方向於第1方向D1上平行之方式並列於與第1方向D1正交之第2方向D2上。面板3係具有沿著與第2方向D2正交之方向形成為長條之複數個單元31的發泡體,故而於第2方向D2上具有彈性。 As described above, according to the building structure 1 of the present embodiment, the plurality of elongated materials 2 are arranged side by side in the second direction D2 orthogonal to the first direction D1 so that the longitudinal directions thereof are parallel to each other in the first direction D1. . The panel 3 has a foam having a plurality of cells 31 formed in a long direction orthogonal to the second direction D2, and therefore has elasticity in the second direction D2.
因此,藉由使在第2方向D2上被壓縮之面板3於長條材料2、2間解除其壓縮而進行復原,可使面板3於與長條材料2密合且推壓長條材料2之狀態下嵌入於長條材料2、2間。如此,本實施形態之建築構造體1可使面板3容易嵌入於長條材料2、2間,並且可防止面板3與長條材料2之間產生間隙。 Therefore, the panel 3 compressed in the second direction D2 is released from compression between the elongated materials 2 and 2, and the panel 3 can be adhered to the elongated material 2 and the long material 2 can be pressed. It is embedded in the strip material 2 and 2 in the state. As described above, in the building structure 1 of the present embodiment, the panel 3 can be easily inserted between the elongated materials 2 and 2, and a gap can be prevented between the panel 3 and the elongated material 2.
又,根據本實施形態之建築構造體1,複數個單元31沿著與第2方向D2正交之方向形成為長條,故而面板3之第2方向D2之彈性模數減小。藉此,面板3於第2方向D2上具有彈性,故而面板3於第2方向D2上容易被壓縮。 Further, according to the building structure 1 of the present embodiment, since the plurality of units 31 are formed in a long direction in a direction orthogonal to the second direction D2, the modulus of elasticity of the panel 3 in the second direction D2 is reduced. Thereby, since the panel 3 has elasticity in the second direction D2, the panel 3 is easily compressed in the second direction D2.
進而,由於該複數個單元31沿著與第2方向D2正交之方向中之第1方向D1形成為長條,故而面板3之第1方向D1之彈性模數增 大。藉此,面板3於第1方向D1上具有剛性,故而嵌入於長條材料2、2間之面板3可穩定地保持於長條材料2、2間。結果面板3可自支持。 Further, since the plurality of cells 31 are formed in a long direction along the first direction D1 in the direction orthogonal to the second direction D2, the elastic modulus of the first direction D1 of the panel 3 is increased. Big. Thereby, since the panel 3 has rigidity in the first direction D1, the panel 3 interposed between the elongated materials 2 and 2 can be stably held between the elongated materials 2 and 2. The result panel 3 is self-supporting.
而且,由於該複數個單元31沿著與第2方向D2正交之方向中之第1方向D1形成為長條,故而亦可提高面板3之第3方向D3上之隔熱性能。 Further, since the plurality of cells 31 are formed in a long direction along the first direction D1 in the direction orthogonal to the second direction D2, the heat insulating performance in the third direction D3 of the panel 3 can be improved.
再者,本發明並非限定於上述實施形態之構成,又,並非限定於上述作用效果。本發明顯然可於不脫離本發明之主旨之範圍內進行各種變更。例如,顯然亦可任意選擇下述各種變更例之構成或方法等,採用於上述實施形態之構成或方法等中。 Furthermore, the present invention is not limited to the configuration of the above embodiment, and is not limited to the above-described effects. It is apparent that various modifications can be made without departing from the spirit and scope of the invention. For example, it is obvious that the configuration, method, and the like of the various modifications described below can be arbitrarily selected, and the configuration, method, and the like of the above-described embodiments can be employed.
上述實施形態之建築構造體1為如下之構成:使1個面板3嵌入於長條材料2、2間。然而,本發明並不限於該構成。例如,於本發明中,亦可為如圖7所示之構成:使面板3於第1方向D1上並列複數個而嵌入於長條材料2、2間,又,亦可為如圖8所示之構成:使面板3於第2方向D2上並列複數個而嵌入於長條材料2、2間。 The building structure 1 of the above embodiment has a configuration in which one panel 3 is fitted between the elongated materials 2 and 2. However, the present invention is not limited to this configuration. For example, in the present invention, as shown in FIG. 7, the panel 3 may be arranged in parallel in the first direction D1 and embedded in the strips 2 and 2, or may be as shown in FIG. The configuration is such that the panel 3 is placed in parallel in the second direction D2 and embedded between the elongated materials 2 and 2.
於圖7所示之建築構造體1係以第1方向D1成為高度方向之方式構成之情形時,面板3較佳為藉由使複數個單元31沿著第1方向D1形成為長條,而以寬度方向D2之彈性模數小於長度方向D1之彈性模數之方式形成。藉此,面板3於第1方向D1上具有剛性,故而嵌入於長條材料2、2間之面板3不僅可自支持,亦可自下方穩定地支持配置於上方之面板3。 In the case where the building structure 1 shown in FIG. 7 is configured such that the first direction D1 is in the height direction, the panel 3 is preferably formed in a long strip by the plurality of units 31 along the first direction D1. It is formed such that the elastic modulus of the width direction D2 is smaller than the elastic modulus of the longitudinal direction D1. Thereby, since the panel 3 has rigidity in the first direction D1, the panel 3 interposed between the elongated materials 2 and 2 can be self-supported, and the panel 3 disposed above can be stably supported from below.
於圖8所示之建築構造體1中,鄰接之面板端部32、32係於自長條材料2、2間偏離之位置抵接,該相反側之面板端部33、33分別位 於長條材料2、2間,抵接於長條材料2及板材5。然後,以鄰接之面板端部32、32位於長條材料2、2間之方式使面板3承受外力,藉此使面板3一面於第2方向D2上被壓縮一面嵌入於長條材料2、2間。 In the building structure 1 shown in Fig. 8, the adjacent panel end portions 32, 32 are abutted from a position offset from the strip materials 2, 2, and the opposite end panel end portions 33, 33 are respectively positioned. Between the strips 2 and 2, the strip 2 and the sheet 5 are abutted. Then, the panel 3 is subjected to an external force so that the adjacent panel end portions 32 and 32 are located between the elongated materials 2 and 2, whereby the panel 3 is compressed in the second direction D2 and embedded in the strip material 2, 2 between.
又,上述實施形態之建築構造體1為如下之構成:面板3以第1方向D1之尺寸大於第2方向D2之尺寸之方式形成。然而,本發明並不限於該構成。例如,於本發明中,亦可為如圖7所示之構成:面板3以第1方向D1之尺寸小於第2方向D2之尺寸之方式形成。 Further, the building structure 1 of the above-described embodiment has a configuration in which the panel 3 is formed such that the dimension in the first direction D1 is larger than the dimension in the second direction D2. However, the present invention is not limited to this configuration. For example, in the present invention, as shown in FIG. 7, the panel 3 may be formed such that the dimension of the first direction D1 is smaller than the dimension of the second direction D2.
又,於上述實施形態中,為如下之構成:長條材料2為柱,建築構造體1為壁。然而,本發明並不限於該構成。例如,於本發明中,亦可為如下之構成:長條材料2係第1方向(長度方向)D1為水平方向之地板托梁,建築構造體1係地板,又,亦可為如下之構成:長條材料2係第1方向(長度方向)D1為水平方向之天花板托梁,建築構造體1係天花板,進而,亦可為如下之構成:長條材料2係第1方向(長度方向)D1為鉛垂方向及相對於水平方向傾斜之方向之椽,建築構造體1係屋頂。總之,於本發明中,第1~第3方向D1、D2、D3並不限定於特定之方向。 Further, in the above embodiment, the configuration is such that the long material 2 is a column and the building structure 1 is a wall. However, the present invention is not limited to this configuration. For example, in the present invention, the long material 2 may be a floor joist in which the first direction (longitudinal direction) D1 is a horizontal direction, and the building structure 1 may be a floor, or may be as follows. The long material 2 is a first direction (longitudinal direction) D1 is a horizontal ceiling joist, and the building structure 1 is a ceiling. Further, the structure may be as follows: the long material 2 is a first direction (longitudinal direction) D1 is a vertical direction and a direction inclined with respect to the horizontal direction, and the building structure 1 is a roof. In short, in the present invention, the first to third directions D1, D2, and D3 are not limited to a specific direction.
又,於上述實施形態中,為如下之構成:面板3係使用模具7而製造。然而,本發明並不限於該構成。例如,於本發明中,亦可為如下之構成:於輸送器上噴灑發泡原液組成物,以鉛垂方向成為第1方向D1之方式將面板3裁斷為長方體狀。 Moreover, in the above embodiment, the panel 3 is manufactured using the mold 7. However, the present invention is not limited to this configuration. For example, in the present invention, the foaming stock solution may be sprayed onto the conveyor, and the panel 3 may be cut into a rectangular parallelepiped shape so that the vertical direction becomes the first direction D1.
又,於本發明中,亦可為如圖9所示之構成:面板3於第2方向D2之端部具備相對於第3方向D3傾斜之錐形部34。該面板3藉由錐形部34,而以第2方向D2之尺寸逐漸增大之方式形成。該面板3藉由在第 3方向D3上受到推壓,而一面於第2方向D2上被壓縮一面嵌入於長條材料2、2間。再者,錐形部34亦可僅設置於面板3之一個端部。 Further, in the present invention, as shown in FIG. 9, the panel 3 may have a tapered portion 34 that is inclined with respect to the third direction D3 at the end portion of the second direction D2. The panel 3 is formed by the tapered portion 34 so as to gradually increase in size in the second direction D2. The panel 3 by the first The three directions D3 are pressed, and one side is compressed in the second direction D2 and embedded between the elongated materials 2 and 2. Furthermore, the tapered portion 34 may be provided only at one end of the panel 3.
又,於本發明中,亦可為如圖10所示之構成:設置有自長條材料2向第2方向D2突出且固定嵌入於長條材料2、2間之面板3之固定部6。固定部6具備:將嵌入於長條材料2、2間之面板3於第2方向D2上卡止之卡止部61;以及相對於第3方向D3傾斜之傾斜部62。 Further, in the present invention, as shown in FIG. 10, a fixing portion 6 in which the long strip material 2 protrudes in the second direction D2 and is fixed to the panel 3 interposed between the elongated materials 2 and 2 may be provided. The fixing portion 6 includes a locking portion 61 that locks the panel 3 that is fitted between the elongated materials 2 and 2 in the second direction D2, and an inclined portion 62 that is inclined with respect to the third direction D3.
根據該構成,面板3係藉由在第3方向D3上受到推壓,而利用固定部6之傾斜部62於第2方向D2上被壓縮。面板3係藉由越過固定部6,而嵌入於長條材料2、2間。嵌入於長條材料2、2間之面板3由於卡止於固定部6,故而可防止自長條材料2、2間脫離。 According to this configuration, the panel 3 is pressed in the third direction D3, and is compressed by the inclined portion 62 of the fixing portion 6 in the second direction D2. The panel 3 is embedded between the elongated materials 2 and 2 by passing over the fixing portion 6. Since the panel 3 embedded between the long strips 2 and 2 is locked to the fixing portion 6, it is possible to prevent separation from the strip materials 2 and 2.
又,於本發明中,亦可為如下之構成:面板3之表面由膜(例如,由乙烯所構成之收縮膜等)所覆蓋。根據該構成,於作業人員手持面板3時或堆積有複數個面板3時,面板3之操作變得容易。 Further, in the present invention, the surface of the panel 3 may be covered with a film (for example, a shrink film made of ethylene or the like). According to this configuration, when the operator holds the panel 3 or when a plurality of panels 3 are stacked, the operation of the panel 3 is facilitated.
實施例 Example
以下,藉由實施例進而詳細地說明本發明,但本發明並非限定於該等實施例。 Hereinafter, the present invention will be described in detail by way of examples, but the invention is not limited thereto.
<多元醇組成物之製備> <Preparation of polyol composition>
作為胺酯泡沫面板3之原料,以如圖11所示之組成製備多元醇組成物。圖11所示各成分之詳細內容如下所示。 As a raw material of the urethane foam panel 3, a polyol composition was prepared in the composition shown in Fig. 11. The details of each component shown in Fig. 11 are as follows.
(1)多元醇化合物 (1) Polyol compound
聚醚多元醇(A)-1:商品名「Exenol-820」(Asahi Glass公司製造),以甘油作為起始劑,使環氧乙烷及環氧丙烷進行加成聚合而獲得之聚醚多 元醇(重量平均分子量4900,羥值(OHV)=34mgKOH/g) Polyether polyol (A)-1: trade name "Exenol-820" (manufactured by Asahi Glass Co., Ltd.), which is obtained by addition polymerization of ethylene oxide and propylene oxide using glycerin as a starting agent. Nonalcohol (weight average molecular weight 4900, hydroxyl value (OHV) = 34 mg KOH / g)
聚醚多元醇(A)-2:商品名「Exenol-850」(Asahi Glass公司製造),以甘油作為起始劑,使環氧乙烷及環氧丙烷進行加成聚合而獲得之聚醚多元醇(重量平均分子量7000,羥值(OHV)=25mgKOH/g) Polyether polyol (A)-2: trade name "Exenol-850" (manufactured by Asahi Glass Co., Ltd.), which is obtained by addition polymerization of ethylene oxide and propylene oxide using glycerin as a starting agent. Alcohol (weight average molecular weight 7000, hydroxyl value (OHV) = 25 mg KOH / g)
短鏈二醇(B)-1:二乙二醇(DEG)(分子量106,羥值(OHV)=1058mgKOH/g,Nacalai Tesque公司製造) Short-chain diol (B)-1: diethylene glycol (DEG) (molecular weight 106, hydroxyl value (OHV) = 1058 mgKOH/g, manufactured by Nacalai Tesque)
聚醚多元醇(C):商品名「T-3000S」(三井化學公司製造),以甘油作為起始劑,僅使環氧丙烷進行加成聚合而獲得之聚醚多元醇(重量平均分子量3000,羥值=56mgKOH/g) Polyether polyol (C): trade name "T-3000S" (manufactured by Mitsui Chemicals, Inc.), a polyether polyol obtained by addition polymerization of propylene oxide using glycerin as a starting agent (weight average molecular weight 3000) , hydroxyl value = 56mgKOH / g)
(2)難燃劑 (2) Flame retardant
商品名「TMCPP」(大八化學公司製造) Product name "TMCPP" (made by Daiba Chemical Co., Ltd.)
(3)泡沫穩定劑 (3) Foam stabilizer
泡沫穩定劑-1:聚矽氧系非離子界面活性劑,商品名「SF-2938F」(Dow Corning Toray Silicone公司製造) Foam Stabilizer-1: Polyoxynene nonionic surfactant, trade name "SF-2938F" (manufactured by Dow Corning Toray Silicone)
(4)觸媒 (4) Catalyst
觸媒-1:三級胺觸媒,商品名「TOYOCAT-ET」(Tosoh公司製造) Catalyst-1: Tertiary amine catalyst, trade name "TOYOCAT-ET" (manufactured by Tosoh Corporation)
觸媒-2:N,N-二甲基胺基乙氧基乙醇,商品名「Kao No.26」 Catalyst-2: N,N-dimethylaminoethoxyethanol, trade name "Kao No.26"
(花王公司製造) (made by Kao Corporation)
<面板評價> <Panel evaluation>
實施例1~3 Example 1~3
將製備為以圖11所示之組成製備之多元醇組成物與聚異氰酸酯成分(使用c-MDI(Sumika Bayer Urethane公司製造之「Sumidur 44V-10」, NCO%:31%),異氰酸酯指數(NCO Index)記載於圖11)之發泡原液組成物自混合頭8注入至圖5所示之模具7(縱向D1之尺寸:900mm,寬度方向D2之尺寸:500mm,厚度方向D3之尺寸:500mm)之底面71。其後,將使發泡原液組成物進行反應所獲得之聚胺酯泡沫面板3於沿著縱向D1及寬度方向D2之切斷面進行裁斷,製造面板3之厚度方向D3與單元31之發泡方向大致垂直(90°)之面板3(縱向D1之尺寸:700mm,寬度方向D2之尺寸:400mm,厚度方向D3之尺寸:60mm)。將結果示於圖11。 A polyol composition prepared by the composition shown in Fig. 11 and a polyisocyanate component (using c-MDI (Sumidur 44V-10) manufactured by Sumika Bayer Urethane Co., Ltd., were prepared. NCO%: 31%), isocyanate index (NCO Index) The foaming stock composition described in Fig. 11) is injected from the mixing head 8 to the mold 7 shown in Fig. 5 (the dimension of the longitudinal direction D1: 900 mm, the dimension of the width direction D2) : 500 mm, the dimension of the thickness direction D3: 500 mm). Thereafter, the polyurethane foam panel 3 obtained by reacting the foaming raw material composition is cut along the cut surface in the longitudinal direction D1 and the width direction D2, and the thickness direction D3 of the panel 3 is produced and the foaming direction of the unit 31 is substantially Vertical (90°) panel 3 (dimension of longitudinal D1: 700 mm, dimension of width direction D2: 400 mm, dimension of thickness direction D3: 60 mm). The results are shown in Fig. 11.
<重量平均分子量> <weight average molecular weight>
重量平均分子量係藉由GPC(Gel Permeation Chromatography,凝膠滲透層析法)進行測定,根據標準聚苯乙烯進行換算。 The weight average molecular weight is measured by GPC (Gel Permeation Chromatography) and converted according to standard polystyrene.
GPC裝置:島津製作所製造,LC-10A GPC device: manufactured by Shimadzu Corporation, LC-10A
管柱:將Polymer Laboratories公司製造之(PLgel,5μm,500Å)、(PLgel,5μm,100Å)、及(PLgel,5μm,50Å)之3根管柱連接而使用 Column: Connect three columns of (PLgel, 5μm, 500Å), (PLgel, 5μm, 100Å), and (PLgel, 5μm, 50Å) manufactured by Polymer Laboratories
流量:1.0ml/min Flow rate: 1.0ml/min
濃度:1.0g/l Concentration: 1.0g/l
注入量:40μl Injection volume: 40μl
管柱溫度:40℃ Column temperature: 40 ° C
溶離液:四氫呋喃 Dissolution: tetrahydrofuran
<泡沫密度> <foam density>
泡沫密度係依據JIS K 7222求出。 The foam density was determined in accordance with JIS K 7222.
<熱導率> <thermal conductivity>
基於JIS A9526(建築物隔熱用噴塗硬質胺酯泡沫),依據JIS A1412-2 (熱絕緣材料之熱阻及熱導率之測定方法-第2部分:熱流計法)(HFM法),測定面板3之厚度方向D3上之熱導率。 Based on JIS A9526 (spray hard amine ester foam for building insulation), in accordance with JIS A1412-2 (Method for Measuring Thermal Resistance and Thermal Conductivity of Thermal Insulating Material - Part 2: Heat Flow Meter Method) (HFM method), the thermal conductivity in the thickness direction D3 of the panel 3 was measured.
<10%壓縮強度> <10% compressive strength>
自根據上述方法所製造之聚胺酯泡沫面板3(縱向D1之尺寸:700mm,寬度方向D2之尺寸:400mm,厚度方向D3之尺寸:60mm)之中央部分(自縱向D1及寬度方向D2中心至縱向D1之尺寸及寬度方向D2之尺寸之兩側10%左右之部分),切出50mm見方之立方體作為泡沫試樣,使用AUTOGRAPH AG-X plus(島津製作所公司製造),於壓縮速度5mm/min之條件下測定10%壓縮強度。 The central portion of the polyurethane foam panel 3 (the dimension of the longitudinal direction D1: 700 mm, the dimension of the width direction D2: the size of the thickness direction D3: 60 mm) manufactured according to the above method (from the center of the longitudinal direction D1 and the width direction D2 to the longitudinal direction D1) The size of the dimension and the width of the D2 dimension are about 10% of the sides.) Cut a 50 mm square cube as a foam sample, using AUTOGRAPH AG-X plus (manufactured by Shimadzu Corporation) at a compression speed of 5 mm/min. The 10% compressive strength was measured.
<聚胺酯泡沫面板向既定形狀之嵌入作業性> <Embedding workability of polyurethane foam panel to a predetermined shape>
若寬度方向D2之尺寸為400mm之面板3於寬度方向D2上壓縮5%,而可容易嵌入於相隔距離為380mm之長條材料2、2間,則藉由對於既定寬度具有餘裕之情況,而判斷面板3之嵌入作業性為良好(於圖11中,為「○」)。 If the panel 3 having a size of 400 mm in the width direction D2 is compressed by 5% in the width direction D2 and can be easily embedded in the strips 2 and 2 separated by a distance of 380 mm, it is possible to have a margin for a predetermined width. It is judged that the embedding workability of the panel 3 is good ("○" in Fig. 11).
由圖11之結果可知,實施例1~3之面板3為低密度、脆性小、且於厚度方向D3上具備優異之隔熱性能。又,可知由於在縱向D1與橫方向D2之間壓縮強度存在差異,且寬度方向D2上具有彈性,故而嵌入作業性亦優異。 As is clear from the results of FIG. 11, the panels 3 of Examples 1 to 3 have low density and low brittleness, and have excellent heat insulating properties in the thickness direction D3. In addition, it is understood that there is a difference in compressive strength between the longitudinal direction D1 and the lateral direction D2 and elasticity in the width direction D2, so that the workability is excellent.
1‧‧‧建築構造體 1‧‧‧Architectural structures
2‧‧‧長條材料 2‧‧‧Long strip material
3‧‧‧面板 3‧‧‧ panel
4‧‧‧框材 4‧‧‧ frame material
D1‧‧‧第1方向 D1‧‧‧1st direction
D2‧‧‧第2方向 D2‧‧‧2nd direction
Claims (3)
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
JP2013001984A JP5615389B2 (en) | 2013-01-09 | 2013-01-09 | Building structure and manufacturing method thereof |
Publications (2)
Publication Number | Publication Date |
---|---|
TW201441453A true TW201441453A (en) | 2014-11-01 |
TWI510698B TWI510698B (en) | 2015-12-01 |
Family
ID=51166873
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
TW102148148A TWI510698B (en) | 2013-01-09 | 2013-12-25 | Building structure and manufacturing method thereof |
Country Status (6)
Country | Link |
---|---|
US (1) | US20150345135A1 (en) |
JP (1) | JP5615389B2 (en) |
KR (1) | KR20150086538A (en) |
CA (1) | CA2897479C (en) |
TW (1) | TWI510698B (en) |
WO (1) | WO2014109215A1 (en) |
Families Citing this family (4)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
SE538486C2 (en) | 2014-10-02 | 2016-08-02 | Paralox Ab | Wall element, wall section constructed of said wall element and method for building said wall section |
US10787816B1 (en) * | 2019-04-18 | 2020-09-29 | Spray Foam Distributors of NE Inc. | Spray foam insulation vent |
JP7464368B2 (en) * | 2019-10-02 | 2024-04-09 | ニチハ株式会社 | Thermal insulation construction and thermal insulation construction method |
CN116529280A (en) * | 2020-08-25 | 2023-08-01 | 豪瑞科技有限公司 | Method for preparing a low density spray polyurethane foam for thermal insulation, sound dampening and air tightness of a building envelope |
Family Cites Families (21)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US3111069A (en) * | 1962-08-13 | 1963-11-19 | Allied Chem | Paving joint construction |
US3231439A (en) * | 1962-11-27 | 1966-01-25 | Allied Chem | Dimensional stabilization of foam panels |
US3825465A (en) * | 1972-03-24 | 1974-07-23 | R Stock | Three dimensional reticulated structure |
US5250579A (en) * | 1992-09-28 | 1993-10-05 | The Dow Chemical Company | Cellular polymer containing perforated cell windows and a process for the preparation thereof |
DE19649829A1 (en) * | 1996-12-02 | 1998-06-04 | Bayer Ag | Flexible polyurethane foams and a process for their production |
JPH10169887A (en) * | 1996-12-06 | 1998-06-26 | Daicel Chem Ind Ltd | Heat insulation material |
US5846462A (en) * | 1997-05-16 | 1998-12-08 | Thompson; Edward J. | Method and apparatus for making high compression structural foam |
US6643389B1 (en) * | 2000-03-28 | 2003-11-04 | Stmicroelectronics, Inc. | Narrow array capacitive fingerprint imager |
JP2001301078A (en) * | 2000-04-20 | 2001-10-30 | Sekisui Chem Co Ltd | Polyolefinic resin composite foam, and vehicular member and shock absorbing member consisting of the same |
JP2004518836A (en) * | 2001-02-02 | 2004-06-24 | ダウ グローバル テクノロジーズ インコーポレイティド | Building panels with at least two panel elements of different average compressive strength |
US6841584B2 (en) * | 2002-03-18 | 2005-01-11 | University Of Southern California | Reinforced phenolic foam |
US9000061B2 (en) * | 2006-03-21 | 2015-04-07 | Honeywell International Inc. | Foams and articles made from foams containing 1-chloro-3,3,3-trifluoropropene (HFCO-1233zd) |
CA3009693C (en) * | 2008-10-20 | 2020-06-30 | Acell Industries Limited | Composite product with surface effect |
CA2784403A1 (en) * | 2009-12-18 | 2011-06-23 | Katsuhiko Shimizu | Process for producing rigid open-cell foam |
WO2011111608A1 (en) * | 2010-03-08 | 2011-09-15 | クラレクラフレックス株式会社 | Sound insulation floor structure and sound insulation floor components as well as method for reducing floor impact sounds |
JP5860709B2 (en) * | 2011-07-14 | 2016-02-16 | 東洋ゴム工業株式会社 | Polyol composition for rigid polyurethane foam and method for producing rigid polyurethane foam |
WO2013011773A1 (en) * | 2011-07-19 | 2013-01-24 | 東洋ゴム工業株式会社 | Polyurethane foam panel and method for producing same |
CA2842051A1 (en) * | 2011-07-19 | 2013-01-24 | Toyo Tire & Rubber Co., Ltd. | Polyurethane foam panel and production method for polyurethane foam panel |
WO2013093057A1 (en) * | 2011-12-22 | 2013-06-27 | Rockwool International A/S | Insulating element for the insulation of flat roofs |
JP5710653B2 (en) * | 2013-01-09 | 2015-04-30 | 東洋ゴム工業株式会社 | Polyurethane foam panels |
JP5710654B2 (en) * | 2013-01-09 | 2015-04-30 | 東洋ゴム工業株式会社 | Polyurethane foam panels |
-
2013
- 2013-01-09 JP JP2013001984A patent/JP5615389B2/en not_active Expired - Fee Related
- 2013-12-20 CA CA2897479A patent/CA2897479C/en not_active Expired - Fee Related
- 2013-12-20 US US14/758,534 patent/US20150345135A1/en not_active Abandoned
- 2013-12-20 KR KR1020157016397A patent/KR20150086538A/en not_active Application Discontinuation
- 2013-12-20 WO PCT/JP2013/084339 patent/WO2014109215A1/en active Application Filing
- 2013-12-25 TW TW102148148A patent/TWI510698B/en not_active IP Right Cessation
Also Published As
Publication number | Publication date |
---|---|
CA2897479C (en) | 2016-09-20 |
TWI510698B (en) | 2015-12-01 |
US20150345135A1 (en) | 2015-12-03 |
KR20150086538A (en) | 2015-07-28 |
WO2014109215A1 (en) | 2014-07-17 |
JP5615389B2 (en) | 2014-10-29 |
CA2897479A1 (en) | 2014-07-17 |
JP2014134002A (en) | 2014-07-24 |
Similar Documents
Publication | Publication Date | Title |
---|---|---|
JP5860709B2 (en) | Polyol composition for rigid polyurethane foam and method for producing rigid polyurethane foam | |
CN108290997B (en) | Method for producing rigid polyurethane foams | |
TWI510698B (en) | Building structure and manufacturing method thereof | |
TWI491633B (en) | Polyurethane foam board | |
JP2015004011A (en) | Method for producing rigid polyurethane foam | |
WO2013058341A1 (en) | Method for producing rigid foam synthetic resin | |
TWI468428B (en) | Polyurethane foam board and its manufacturing method | |
TWI503338B (en) | Polyurethane foam board | |
WO2013011773A1 (en) | Polyurethane foam panel and method for producing same | |
JP5314169B2 (en) | Polyurethane foam panel and manufacturing method thereof | |
JP5314167B2 (en) | Rigid polyurethane foam panel and manufacturing method thereof | |
JP2012144625A (en) | Polyol composition for open-cell polyurethane foam, and method of producing the open-cell polyurethane foam | |
JP2013185154A (en) | Polyurethane foam panel | |
JP5969252B2 (en) | Rigid polyurethane foam panel | |
JP5403898B2 (en) | Polyol composition for spray foamed rigid polyurethane foam and method for producing spray foamed rigid polyurethane foam |
Legal Events
Date | Code | Title | Description |
---|---|---|---|
MM4A | Annulment or lapse of patent due to non-payment of fees |