WO2014107930A1 - Environment-friendly, multifunctional, energy-saving, inorganic modified and flexible building decorative sheet and preparation method therefor - Google Patents

Environment-friendly, multifunctional, energy-saving, inorganic modified and flexible building decorative sheet and preparation method therefor Download PDF

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Publication number
WO2014107930A1
WO2014107930A1 PCT/CN2013/071697 CN2013071697W WO2014107930A1 WO 2014107930 A1 WO2014107930 A1 WO 2014107930A1 CN 2013071697 W CN2013071697 W CN 2013071697W WO 2014107930 A1 WO2014107930 A1 WO 2014107930A1
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Prior art keywords
parts
saving
decorative sheet
building energy
hours
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PCT/CN2013/071697
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French (fr)
Chinese (zh)
Inventor
李斯龙
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Li Silong
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Publication of WO2014107930A1 publication Critical patent/WO2014107930A1/en

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    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B28/00Compositions of mortars, concrete or artificial stone, containing inorganic binders or the reaction product of an inorganic and an organic binder, e.g. polycarboxylate cements
    • C04B28/02Compositions of mortars, concrete or artificial stone, containing inorganic binders or the reaction product of an inorganic and an organic binder, e.g. polycarboxylate cements containing hydraulic cements other than calcium sulfates
    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B2111/00Mortars, concrete or artificial stone or mixtures to prepare them, characterised by specific function, property or use
    • C04B2111/00017Aspects relating to the protection of the environment
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02WCLIMATE CHANGE MITIGATION TECHNOLOGIES RELATED TO WASTEWATER TREATMENT OR WASTE MANAGEMENT
    • Y02W30/00Technologies for solid waste management
    • Y02W30/50Reuse, recycling or recovery technologies
    • Y02W30/91Use of waste materials as fillers for mortars or concrete

Definitions

  • the invention relates to the field of building decoration materials, in particular to an environmentally-friendly multifunctional building energy-saving inorganic modified flexible decorative sheet and a preparation method thereof.
  • Organic decorative panels and glass curtain walls have waste of resources, serious energy consumption, and complicated processes.
  • Tiles and natural stone due to the limitations of the material of the tile itself, will cause serious pollution of the environment and energy consumption during the production and firing of the material; and the massive exploitation of natural stone will seriously damage the surface resources, which is extremely harmful to the environment. .
  • the ceramic tile itself is heavy, the construction process is complicated, the renovation is difficult, the accessories are easy to aging, and the defects appear when the natural disaster occurs, which will greatly affect the personal safety. Danger and injury.
  • the object of the present invention is to overcome the above-mentioned deficiencies of the prior art, to provide an energy-saving and resource-saving, and to replace the external decorative materials such as organic decorative boards, ceramic tiles, natural stone, etc., without the safety risks, lightweight, waterproof and durable, and flexible in texture. Finishing material and preparation method thereof.
  • An environmentally-friendly multifunctional building energy-saving inorganic modified flexible decorative sheet the formula of which is included by weight Lower component:
  • Titanium dioxide 0.5-2.0 parts
  • the following components are also included: 8-30 parts of clay slurry and 0.1-1 parts of color paste.
  • the polymer binder is an acrylic emulsion.
  • the hollow microspheres are 1-2 micrometer hollow spheres formed by borosilicate having a particle diameter of 10-90 micrometers.
  • the fineness of the quartz sand powder is 20-300 mesh.
  • the clay slurry is composed of the following parts by weight:
  • the clay slurry has a solid content of 20-40%.
  • the invention discloses a preparation method of an environmentally-friendly multifunctional building energy-saving inorganic modified flexible decorative sheet, comprising the following steps:
  • step 3 The modified slurry obtained in step 2 is separately poured or scraped and sprayed on a mold, and dried and cured at 40-110 ° C to mold, thereby obtaining energy-saving inorganic modification of the environmental protection multifunctional building.
  • Flexible decorative sheet
  • the invention discloses a preparation method of an environmentally-friendly multifunctional building energy-saving inorganic modified flexible decorative sheet, comprising the following steps:
  • step 2) Stir and disperse the clay slurry, color paste and defoamer for 0.5-1 hours, then add silicate, hollow microspheres, quartz sand powder, thickener and flame retardant to mix and mix for 1-2 hours. Then, after step 1) the immersed material is added to the mixture, and then added with a polymer binder and an antifoaming agent for stirring for 1-1.5 hours, and allowed to stand for 1-1.5 hours, and the pH is adjusted to 9-10 to obtain a modification.
  • step 3 The inorganic modified material slurry obtained in step 2 is poured or scraped and sprayed in a mold, and the nylon mesh is adhered on the back or the middle, and the mold is dried after curing at 40-110 ° C to obtain the environmental protection.
  • Functional building energy-saving inorganic modified flexible decorative sheet is obtained in step 2 poured or scraped and sprayed in a mold, and the nylon mesh is adhered on the back or the middle, and the mold is dried after curing at 40-110 ° C to obtain the environmental protection.
  • the clay slurry is composed of the following parts by weight: 5 parts of kaolin;
  • the clay slurry has a solid content of 20-40%.
  • the radiation is modified at the high temperature of the infrared light curve to make the product have good heat insulation, lighter quality and softer texture, especially It is safer and more reliable to use on high-rise buildings on the outer wall.
  • the natural raw tailings sand powder is added to the inorganic and some organic bonding materials at a higher infrared light temperature, and the fire performance is up to B1.
  • Natural raw materials, raw tailings and sandstone powder, and heat-insulating inorganic hollow microspheres make this product good in heat insulation, free of volatile and radioactive harmful compounds such as antimony and VCO. It will not be in the process of decoration, use, production and construction. The health of personnel is a hazard and is a green building energy-saving product.
  • the sheet can be copied into various patterns such as stone, ceramic tile and ancient brick.
  • the sheet material is light and it is an ideal decoration product for the exterior wall of high-rise building.
  • the flexible sheet can be directly bonded to the cement mortar base layer with an adhesive, and the construction cylinder can also be applied to the thermal insulation integrated system finish layer. (9) Great potential for space saving, only one-third thicker than wall tiles.
  • Advanced carbon fiber technology and processes have improved the tensile strength, impact and toughness of the product to an excellent level.
  • the dense and intelligent product film structure is anti-mildew, antibacterial, gas permeable, impervious to water, stable in volume, and extremely low in sizing. It has its own flexibility and is more stable in cracks and hollow drums.
  • this product is lighter in construction and greatly shortens the construction period.
  • Multi-functional building energy-saving inorganic modified flexible decorative sheet is the ideal material for building energy-saving exterior wall insulation and temperature-proof decorative system finishing materials.
  • Multi-functional building energy-saving inorganic modified flexible decorative sheet technology products can be recycled, and the physical properties of the sand are restored by physical and mechanical treatment for reuse or cultivation.
  • An environmentally-friendly multi-functional building energy-saving inorganic modified flexible decorative sheet comprises the following raw materials and their parts by weight: 10-18 parts of Portland cement, 20-50 parts of modified binder, insulating hollow microspheres 2-10 10 parts, inorganic powder 10-30 parts, high temperature resistant fiber 0.1-1 part, thickener 0.1-0.5 part, titanium white powder 0.5-2 part, foaming agent 0.1-0.5 part, flame retardant 0.2-1.5 parts.
  • the invention can directly form the finished product into a natural color type through the above formula, and can also be made into a color product, and the components to be added are 8-30 parts of the clay slurry and 0.1-1 part of the iron oxide color paste.
  • the silicate comprises cement.
  • the antifoaming agent includes Wacker 803# antifoaming agent.
  • the flame retardant includes a non-flame retardant.
  • the clay slurry is composed of kaolin, quartz powder, acicular fiber and water, and has a solid content of 20-40%.
  • the preparation method of the environmental protection multi-functional building energy-saving inorganic modified flexible decorative sheet of the invention comprises the following steps:
  • the modified slurry obtained in the step 2) is separately cast or sprayed on the mold, dried and cured at 40-110 ° C, and then subjected to surface treatment to obtain the energy-saving multifunctional environmental protection building.
  • Inorganic modified flexible decorative sheet; or the modified slurry is poured or sprayed in a mold, and the nylon or glass fiber mesh is attached on the back or the middle, and dried at 40-110 ° C to form a mold. After the surface treatment, the environmentally-friendly multifunctional building energy-saving inorganic modified flexible decorative sheet is obtained.
  • the silicate is cement
  • the defoaming agent is Wacker 803# defoaming agent
  • Nopko NXZ defoaming agent Nopko NXZ defoaming agent
  • Changfeng 3016# defoaming agent the flame retardant is ammonium polyphosphate. , aluminum hydroxide, etc.
  • the silicate is cement
  • the antifoaming agent is a polyether antifoaming agent
  • the flame retardant is ammonium polyphosphate.
  • the preparation method comprises the following steps:
  • step 2) Add 30 parts of clay slurry, 2 parts of iron oxide paste and 0.2 parts of antifoaming agent to the dispersion stirring vessel for 0.5 hour, then add 20 parts of silicate to the mixing vessel and heat insulation. 3 parts of beads, 20 parts of inorganic powder, 2 parts of titanium dioxide, and 0.2 parts of flame retardant are mixed and stirred for 2 hours. After mixing the materials soaked in step 1), 20 parts of polymer binder is added. 0.2 parts of antifoaming agent was stirred for 0.5 hours, and allowed to stand for 0.5 hour to prepare a polymer slurry;
  • the modified slurry obtained in step 2) is separately poured or scraped on a size-size sheet of silica gel and a plastic mold, and is also irradiated under infrared light temperature (temperature of 40 degrees for 5 hours, 50 degrees for 6 hours).
  • the organic decorative multi-functional building energy-saving inorganic powder modified flexible decorative sheet can be obtained by naturally drying and solidifying at a normal temperature, and the overall material thickness is 2.5-3 mm, and the dry weight is less than 7 kg/m2.
  • the silicate is cement
  • the antifoaming agent is Wacker 803
  • the flame retardant is ammonium polyphosphate
  • the clay slurry has a solid content of 20%.
  • the preparation method comprises the following steps:
  • the scraper was sprayed with a grinder and the paint roller was sprayed with a spray gun.
  • the first thickness was about 1.5 mm, and then the fiberglass mesh was finished.
  • spray a slurry after the infrared light temperature is dried and solidified (temperature is 40 degrees) for 5 hours. 60 degrees and 6 hours can also be dried naturally at normal temperature.
  • the overall material thickness is 2.5 ⁇ 3mm, and the dry weight of the material is less than 7kg/n.
  • the preparation method comprises the following steps:
  • step 2) Add 25 parts of clay slurry, 1 part of iron oxide paste and 0.1 part of antifoaming agent to the dispersion stirring vessel for 1 hour, and then add 18 parts of silicate in the dispersion stirring vessel. 7 parts of beads, 20 parts of inorganic powder, 2 parts of titanium dioxide, and 1.5 parts of flame retardant were mixed and stirred for 1 hour. Then, after mixing the materials after step 1), 30 parts of modified binder was added. 0.1 part of antifoaming agent was stirred for 1.5 hours, and allowed to stand for 1 hour to prepare a polymer slurry;
  • the silicate is cement
  • the antifoaming agent is Wacker 803
  • the flame retardant is ammonium polyphosphate
  • the clay slurry has a solid content of 40%.
  • the decorative sheet of the present invention is subjected to the following test
  • the radiation is modified at the high temperature of the infrared light curve to make the product have good heat insulation, lighter quality and softer texture, especially It is safer and more reliable to use on high-rise buildings on the outer wall.
  • the natural raw tailings sand powder is added to the inorganic and some organic bonding materials at a higher infrared light temperature, and the fire performance is up to B1.
  • Natural raw materials, raw tailings and sandstone powder, and heat-insulating inorganic hollow microspheres make this product good in heat insulation, free of volatile and radioactive harmful compounds such as antimony and VCO. It will not be in the process of decoration, use, production and construction. The health of personnel is a hazard and is a green building energy-saving product. (5) Excellent flexibility, used for internal and external wall finishes without cracking due to cracks in the substrate, and excellent water resistance.
  • the sheet can be copied into various patterns such as stone, ceramic tile and ancient brick.
  • the sheet material is light and it is an ideal decoration product for the exterior wall of high-rise building.
  • the flexible sheet can be directly bonded to the cement mortar base layer with an adhesive, and the construction cylinder can also be applied to the thermal insulation integrated system finish layer.
  • Advanced carbon fiber technology and processes have improved the tensile strength, impact and toughness of the product to an excellent level.
  • the dense and intelligent product film structure is anti-mildew, antibacterial, gas permeable, impervious to water, stable in volume, and extremely low in sizing. It has its own flexibility and is more stable in cracks and hollow drums.
  • this product is lighter in construction and greatly shortens the construction period.
  • Multi-functional building energy-saving inorganic modified flexible decorative sheet is the ideal material for building energy-saving exterior wall insulation and temperature-proof decorative system finishing materials.
  • Multi-functional building energy-saving inorganic modified flexible decorative sheet technology products can be recycled, and the physical properties of the sand are restored by physical and mechanical treatment for reuse or cultivation.
  • the above is only the embodiment of the present invention, and thus does not limit the scope of the patent of the present invention. Any equivalent structure or equivalent process transformation made by using the content of the specification of the present invention, or directly or indirectly applied to other related technical fields, The same is included in the scope of patent protection of the present invention.

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  • Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Ceramic Engineering (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Inorganic Chemistry (AREA)
  • Materials Engineering (AREA)
  • Structural Engineering (AREA)
  • Organic Chemistry (AREA)
  • Curing Cements, Concrete, And Artificial Stone (AREA)
  • Finishing Walls (AREA)

Abstract

Disclosed is an environment-friendly, multifunctional, energy-saving, inorganic modified, and flexible building decorative sheet, which comprises the following components in parts by weight: 10-18 parts of silicate cement, 20-50 parts of a polymer binder, 2-10 parts of hollow microbeads, 10-30 parts of a quartz sand powder, 0.1-1 part of a high-temperature-resistant fibre, 0.1-0.5 part of a thickening agent, 0.5-2.0 parts of titanium white, 0.1-0.5 part of a defoaming agent, and 0.2-1.5 parts of a flame retardant.

Description

环保多功能建筑节能无机改性柔性装饰片材及其制备方法 技术领域  Environmental protection multifunctional building energy-saving inorganic modified flexible decorative sheet and preparation method thereof
本发明涉及建筑装饰材料领域, 尤其涉及一种环保多功能建筑节能无机改 性柔性装饰片材及其制备方法。 背景技术  The invention relates to the field of building decoration materials, in particular to an environmentally-friendly multifunctional building energy-saving inorganic modified flexible decorative sheet and a preparation method thereof. Background technique
随着现代人们生活水平提高, 居住条件的改善, 在国家倡导建筑节能减排 政策下需要有一种资源再利用符合低碳环保、 多功能、 装饰性强的建筑装饰材 料来取代原有传统的有机装饰板、 玻璃幕墙、 涂料、 瓷砖和石材等建筑装饰材 料。  With the improvement of living standards of modern people and the improvement of living conditions, it is necessary to have a resource reuse in accordance with the national policy of building energy conservation and emission reduction, which is in line with low-carbon environmental protection, multi-functional and decorative architectural decoration materials to replace the traditional organic Decorative materials such as decorative panels, glass curtain walls, paints, tiles and stone.
有机装饰板和玻璃幕墙在自身材料上存在资源浪费、 能耗严重、 工艺繁杂、 应用于建筑外墙特别是高层建筑时存在造价高、 施工工艺繁杂、 污染严重、 固 定金属配件容易老化等缺陷、 在火灾和地震中存在许多安全隐患。  Organic decorative panels and glass curtain walls have waste of resources, serious energy consumption, and complicated processes. When applied to exterior walls of buildings, especially high-rise buildings, there are defects such as high cost, complicated construction process, serious pollution, and easy aging of fixed metal fittings. There are many safety hazards in fires and earthquakes.
瓷砖和天然石材, 因瓷砖本身材质的限制, 其在材料制作、 烧制过程中会 出现严重污染环境和消耗能源等现象; 而天然石材的大量开采则会严重破坏地 表资源, 对环境危害极大。 在建筑应用过程中特别是外墙上, 瓷砖除对设计要 求高外, 其石材自身重、 施工工艺繁杂、 翻新难、 配件易老化、 自然灾害发生 时出现脱落等缺陷会对人身安全构成极大危险和伤害。  Tiles and natural stone, due to the limitations of the material of the tile itself, will cause serious pollution of the environment and energy consumption during the production and firing of the material; and the massive exploitation of natural stone will seriously damage the surface resources, which is extremely harmful to the environment. . In the process of building application, especially on the outer wall, in addition to the high design requirements, the ceramic tile itself is heavy, the construction process is complicated, the renovation is difficult, the accessories are easy to aging, and the defects appear when the natural disaster occurs, which will greatly affect the personal safety. Danger and injury.
建筑涂料应用在建筑上是一种用途较为广泛的产品, 无论是质感还是材料 施工工艺都比较适用, 但也存在墙体开裂时, 涂层也开裂渗水等问题。 发明内容  The application of architectural coatings is a widely used product in construction. It is suitable for both texture and material construction processes, but there are also problems such as cracking and seepage of the wall when the wall is cracked. Summary of the invention
本发明的目的是为了克服上述现有技术的不足, 提供一种节能、 节省资源, 可代替有机装饰板、 瓷砖、 天然石材等外墙装饰材料, 无安全隐患的轻质、 防 水耐久、 质感柔性饰面材料及其制备方法。  The object of the present invention is to overcome the above-mentioned deficiencies of the prior art, to provide an energy-saving and resource-saving, and to replace the external decorative materials such as organic decorative boards, ceramic tiles, natural stone, etc., without the safety risks, lightweight, waterproof and durable, and flexible in texture. Finishing material and preparation method thereof.
为了实现上述发明目的, 本发明采用的技术方案为:  In order to achieve the above object, the technical solution adopted by the present invention is:
一种环保多功能建筑节能无机改性柔性装饰片材, 其配方按重量份包括以 下组分: An environmentally-friendly multifunctional building energy-saving inorganic modified flexible decorative sheet, the formula of which is included by weight Lower component:
硅酸盐水泥 10— 18份  Portland cement 10-18 parts
聚合物粘结剂 10—40份  Polymer binder 10-40 parts
空心微珠 2-10份  Hollow beads 2-10 parts
石英砂粉料 10—30份  Quartz sand powder 10-30 parts
耐高温纤维 0.1— 1份  High temperature resistant fiber 0.1-1 part
增稠剂 0.1— 0.5份  Thickener 0.1-0.5 parts
钛白粉 0.5—2.0份  Titanium dioxide 0.5-2.0 parts
消泡剂 0.1— 0.5份  Defoamer 0.1-0.5 parts
阻燃剂 0.2— 1.5份。  Flame retardant 0.2 - 1.5 parts.
其中, 还包括以下组分: 陶土浆料 8— 30份、 色浆 0.1-1份。  Among them, the following components are also included: 8-30 parts of clay slurry and 0.1-1 parts of color paste.
其中, 所述聚合物粘结剂为丙烯酸乳液。  Wherein, the polymer binder is an acrylic emulsion.
其中,所述空心微珠为粒径 10-90微米的硼硅酸盐形成的粒径 1-2微米空心 球形。  Wherein, the hollow microspheres are 1-2 micrometer hollow spheres formed by borosilicate having a particle diameter of 10-90 micrometers.
其中, 所述石英砂粉料的细度为 20-300目。  Wherein, the fineness of the quartz sand powder is 20-300 mesh.
其中, 所述陶土浆料由以下重量份的组分组成:  Wherein, the clay slurry is composed of the following parts by weight:
高岭土 5份;  5 parts of kaolin;
石英粉 15份;  15 parts of quartz powder;
硅灰粉 5份;  Silica fume 5 parts;
水 100-150分;  Water 100-150 points;
所述陶土浆料的固含量为 20-40%。  The clay slurry has a solid content of 20-40%.
为了实现上述发明目的, 本发明采用的另一技术方案为:  In order to achieve the above object, another technical solution adopted by the present invention is:
一种环保多功能建筑节能无机改性柔性装饰片材的制备方法, 包括以下步 骤:  The invention discloses a preparation method of an environmentally-friendly multifunctional building energy-saving inorganic modified flexible decorative sheet, comprising the following steps:
1 )常温下, 将耐高温纤维加入水中浸泡 2-4小时;  1) Soak the high temperature resistant fiber in water at room temperature for 2-4 hours;
2 )将陶土浆料、 色浆和消泡剂搅拌分散均匀 0.5-1 小时后, 加入硅酸盐、 空心微珠、 石英砂粉料、 增稠剂、 阻燃剂混合搅拌均匀 1-2小时, 再把步骤 1 ) 浸泡后的物料加入混合后, 再加入聚合物粘结剂、 消泡剂搅拌 1-1.5小时, 静置 熟化 1-1.5小时, 调准 PH值 9-10制得改性物浆料; 2) Stir and disperse the clay slurry, color paste and defoamer for 0.5-1 hours, then add silicate, hollow microspheres, quartz sand powder, thickener and flame retardant to mix and mix for 1-2 hours. Then, after the step 1) soaked materials are added to the mixture, the polymer binder and the antifoaming agent are added and stirred for 1-1.5 hours, and allowed to stand. After aging for 1-1.5 hours, adjust the pH value of 9-10 to prepare a modified slurry;
3 )将步骤 2 得到的改性物浆料分别浇注或者批刮、 喷涂在模具上, 在 40-110°C条件下干透固化后起模,制得所述环保多功能建筑节能无机改性柔性装 饰片材。  3) The modified slurry obtained in step 2 is separately poured or scraped and sprayed on a mold, and dried and cured at 40-110 ° C to mold, thereby obtaining energy-saving inorganic modification of the environmental protection multifunctional building. Flexible decorative sheet.
为了实现上述发明目的, 本发明采用的再一技术方案为:  In order to achieve the above object, another technical solution adopted by the present invention is:
一种环保多功能建筑节能无机改性柔性装饰片材的制备方法, 包括以下步 骤:  The invention discloses a preparation method of an environmentally-friendly multifunctional building energy-saving inorganic modified flexible decorative sheet, comprising the following steps:
1 )常温下, 将耐高温纤维加入水中浸泡 2-4小时;  1) Soak the high temperature resistant fiber in water at room temperature for 2-4 hours;
2 )将陶土浆料、 色浆和消泡剂搅拌分散均匀 0.5-1 小时后, 加入硅酸盐、 空心微珠、 石英砂粉料、 增稠剂、 阻燃剂混合搅拌均匀 1-2小时, 再把步骤 1 ) 浸泡后的物料加入混合后, 再加入聚合物粘结剂、 消泡剂搅拌 1-1.5小时, 静置 熟化 1-1.5小时, 调准 PH值 9-10制得改性物浆料;  2) Stir and disperse the clay slurry, color paste and defoamer for 0.5-1 hours, then add silicate, hollow microspheres, quartz sand powder, thickener and flame retardant to mix and mix for 1-2 hours. Then, after step 1) the immersed material is added to the mixture, and then added with a polymer binder and an antifoaming agent for stirring for 1-1.5 hours, and allowed to stand for 1-1.5 hours, and the pH is adjusted to 9-10 to obtain a modification. Material slurry
3 )将步骤 2得到无机改性物浆料浇注或者批刮、 喷涂在模具中, 背面或中 间贴合尼纶网, 在 40-110°C干透固化后起模, 制得所述环保多功能建筑节能无 机改性柔性装饰片材。  3) The inorganic modified material slurry obtained in step 2 is poured or scraped and sprayed in a mold, and the nylon mesh is adhered on the back or the middle, and the mold is dried after curing at 40-110 ° C to obtain the environmental protection. Functional building energy-saving inorganic modified flexible decorative sheet.
其中, 组分的重量份为:  Wherein, the parts by weight of the components are:
硅酸盐水泥 10— 18%  Portland cement 10-18%
聚合物粘结剂 20— 50%  Polymer binder 20-50%
空心微珠 2-10%  Hollow beads 2-10%
石英砂粉料 10—30%  Quartz sand powder 10-30%
耐高温纤维 0.1— 1%  High temperature resistant fiber 0.1-1%
增稠剂 0.1— 0.5%  Thickener 0.1-0.5%
钬白粉 0.5— 2.0%  钬 white powder 0.5— 2.0%
消泡剂 0.1— 0.5%  Defoamer 0.1—0.5%
阻燃剂 0.2— 1.5%  Flame retardant 0.2— 1.5%
陶土浆料 8— 30%  Clay slurry 8-30%
色浆 0.1-1%。  Color paste 0.1-1%.
其中, 所述陶土浆料由以下重量份的组分组成: 高岭土 5份; Wherein, the clay slurry is composed of the following parts by weight: 5 parts of kaolin;
石英粉 15份;  15 parts of quartz powder;
硅灰粉 5份;  Silica fume 5 parts;
水 100-150分;  Water 100-150 points;
所述陶土浆料的固含量为 20-40%。  The clay slurry has a solid content of 20-40%.
本发明的优点为:  The advantages of the invention are:
(1) 自重轻、 抗震、 安全性极高。  (1) Light weight, shock resistance and high safety.
由于本产品所采用天然原始的矿石尾矿砂石粉与现代高科技技术应用, 在 红外光曲线高温度下辐射改性而成使产品具有隔热性好、 自身质变得更轻、 质 地更加柔软, 尤其使用在外墙高层建筑上更加安全可靠。  Due to the natural original ore tailings and gravel powder used in this product and modern high-tech technology application, the radiation is modified at the high temperature of the infrared light curve to make the product have good heat insulation, lighter quality and softer texture, especially It is safer and more reliable to use on high-rise buildings on the outer wall.
(2) 阻燃无烟、 优异的防火性能。  (2) Flame retardant, excellent fire resistance.
天然原始的尾矿砂石粉添加入无机和部分有机粘结材料在较高红外光温度 体危害, 防火性能达 B1级。  The natural raw tailings sand powder is added to the inorganic and some organic bonding materials at a higher infrared light temperature, and the fire performance is up to B1.
(3)超强的化学稳定性, 使产品自洁、 耐酸、 耐久、 耐候性更加长久。 耐酸碱腐蚀、 耐高温、 耐紫外线老化, 适用于各种环境下高档外墙装饰及 产品的性能。  (3) Superior chemical stability, making the product self-cleaning, acid-resistant, durable, and weather-resistant. It is resistant to acid and alkali corrosion, high temperature resistance and UV aging. It is suitable for high-grade exterior wall decoration and product performance in various environments.
(4)节能低碳、 环保健康、 内外装饰同样适用。  (4) Energy-saving and low-carbon, environmentally friendly and healthy, both internal and external decoration are also applicable.
天然的原材料原始尾矿和砂石粉、 隔热无机空心微珠使本产品隔热性好、 不含曱 、 VCO等挥发性及放射性有害化合物, 在装饰、 使用、 生产、 施工过 程中不会对人员的健康造成危害, 是绿色建筑节能产品。  Natural raw materials, raw tailings and sandstone powder, and heat-insulating inorganic hollow microspheres make this product good in heat insulation, free of volatile and radioactive harmful compounds such as antimony and VCO. It will not be in the process of decoration, use, production and construction. The health of personnel is a hazard and is a green building energy-saving product.
(5)优异的柔性, 用于内外墙饰面不会因底材产生裂纹而开裂, 具有优异 的防水性。  (5) Excellent flexibility, used for internal and external wall finishes without cracking due to cracks in the substrate, and excellent water resistance.
(6)具有优异的抗盐析、抗泛碱性,使柔性装饰片材具有非常好的装饰性。 (6) It has excellent salting resistance and anti-alkaline properties, and makes the flexible decorative sheet have very good decorative properties.
(7) 片材可复制成石材、 瓷砖、 古砖等各种花纹, 片材材质轻, 是高层建 筑外墙理想装饰产品。 (7) The sheet can be copied into various patterns such as stone, ceramic tile and ancient brick. The sheet material is light and it is an ideal decoration product for the exterior wall of high-rise building.
(8)柔性片材可直接用粘结剂粘贴到水泥砂浆基层面上, 施工筒单也可应 用在保温一体化系统饰面层上。 ( 9 )极具潜力的节省空间、 厚度只有墙面砖的三分之一厚。 (8) The flexible sheet can be directly bonded to the cement mortar base layer with an adhesive, and the construction cylinder can also be applied to the thermal insulation integrated system finish layer. (9) Great potential for space saving, only one-third thicker than wall tiles.
原始的材料与现代先进的生产工艺铸造了当代优质超薄高性能的柔性装饰 材料产品。  The original materials and modern advanced production processes cast contemporary high-quality ultra-thin high-performance flexible decorative materials.
( 10 )优越的柔韧性、 超强的耐沖击性。  (10) Superior flexibility and superior impact resistance.
先进的碳纤维技术及工艺将产品抗拉伸强度、 沖击性和韧性提高到了极佳 状态。  Advanced carbon fiber technology and processes have improved the tensile strength, impact and toughness of the product to an excellent level.
( 11 )智能透气、 防霉抗菌、 防水、 抗裂性优异。  (11) Excellent in intelligent ventilation, anti-mildew, anti-water, and crack resistance.
致密智能的产品膜层结构型成防霉抗菌、 透气、 不透水、 体积稳定、 极低 的溶缩性具备了自身柔韧性在龟裂、 空鼓方面结构更加稳定。  The dense and intelligent product film structure is anti-mildew, antibacterial, gas permeable, impervious to water, stable in volume, and extremely low in sizing. It has its own flexibility and is more stable in cracks and hollow drums.
( 12 )具备极高的可粘结强度直接用于旧墙翻新节能改造。  (12) It has a very high bond strength and can be directly used for renovation and energy-saving renovation of old walls.
由于本产品具备轻质和优越的柔韧性、 抗裂、 防水性及天然的质感美观, 可直接用粘接剂粘贴在原有的墙面上, 从而使旧城改造过程无需大量墙体铲除 工序, 避免了大量资源浪费。  Because of its light weight and superior flexibility, crack resistance, water resistance and natural texture, it can be directly bonded to the original wall with adhesive, so that the old city transformation process does not require a lot of wall removal process. Avoid a lot of waste of resources.
( 13 )施工筒便、 色彩多样彰显天然效果。  (13) The construction of the tube and the variety of colors highlight the natural effects.
与外墙大理石、 花岗岩干挂施工相比, 本产品在施工方面更为轻便, 极大 的缩短了工期。 以天然原始材料为肌理, 历代工艺制品和现代艺术创作等做基 础, 集 300多种天然气和复配色调及与生倶来色泽天然优雅而丰富、 弥久历新、 30年不变型、 不变色符合现代城市建筑回归自然的特性。  Compared with the external wall marble and granite hanging construction, this product is lighter in construction and greatly shortens the construction period. Based on natural raw materials, historical crafts and modern art creations, it is based on more than 300 kinds of natural gas and complex color tones. It is rich in natural elegance and rich in color, long-lasting, 30-year-old, non-discoloring. It conforms to the characteristics of modern urban architecture returning to nature.
( 14 ) 多功能建筑节能无机改性柔性装饰片材是建筑节能外墙外保温和保 温装饰一体化系统饰面材料配套理想选材。  (14) Multi-functional building energy-saving inorganic modified flexible decorative sheet is the ideal material for building energy-saving exterior wall insulation and temperature-proof decorative system finishing materials.
集自重轻、 自洁性强、 防火、 防水、 抗裂、 耐酸、 耐候隔热及优越的柔韧 性于一体。 真实的天然质感是外墙外保温配套的绝佳首选产品。  It combines light weight, self-cleaning, fireproof, waterproof, crack resistant, acid resistant, weather resistant and superior flexibility. The true natural texture is the perfect choice for exterior insulation.
( 15 ) 回归自然。  (15) Return to nature.
多功能建筑节能无机改性柔性装饰片材技术产品可回收, 通过物理机械处 理还原砂土本质用于再利用或耕作。 具体实施方式  Multi-functional building energy-saving inorganic modified flexible decorative sheet technology products can be recycled, and the physical properties of the sand are restored by physical and mechanical treatment for reuse or cultivation. detailed description
为详细说明本发明的技术内容、 构造特征、 所实现目的及效果, 以下结合 实施方式详予说明。 In order to explain in detail the technical contents, structural features, achieved objects and effects of the present invention, the following combinations The embodiments are described in detail.
本发明是通过如下技术方案实施的:  The present invention is implemented by the following technical solutions:
一种环保多功能建筑节能无机改性柔性装饰片材包括以下原料及其重量 份: 硅酸盐水泥 10— 18份、 改性物粘结剂 20— 50份、 隔热空心微珠 2— 10份、 无机粉料 10—30份、 耐高温纤维 0.1— 1份、 增稠剂 0.1—0.5份、 钛白粉 0.5—2 份、 泡剂 0.1—0.5份、 阻燃剂 0.2—1.5份。  An environmentally-friendly multi-functional building energy-saving inorganic modified flexible decorative sheet comprises the following raw materials and their parts by weight: 10-18 parts of Portland cement, 20-50 parts of modified binder, insulating hollow microspheres 2-10 10 parts, inorganic powder 10-30 parts, high temperature resistant fiber 0.1-1 part, thickener 0.1-0.5 part, titanium white powder 0.5-2 part, foaming agent 0.1-0.5 part, flame retardant 0.2-1.5 parts.
本发明可以直接通过上述配方制成成品为天然色型, 同样也可以制成有颜 色的产品, 需要添加组分为陶土浆料 8—30份、 氧化铁色浆 0.1— 1份。  The invention can directly form the finished product into a natural color type through the above formula, and can also be made into a color product, and the components to be added are 8-30 parts of the clay slurry and 0.1-1 part of the iron oxide color paste.
所述的硅酸盐包括水泥。  The silicate comprises cement.
所述的消泡剂包括瓦克 803#消泡剂。  The antifoaming agent includes Wacker 803# antifoaming agent.
所述的阻燃剂包括非 阻燃剂。  The flame retardant includes a non-flame retardant.
所述的陶土浆料是由: 高岭土、 石英粉、 针状纤维石和水组成的浆料, 其 固含量为 20-40%。  The clay slurry is composed of kaolin, quartz powder, acicular fiber and water, and has a solid content of 20-40%.
本发明环保多功能建筑节能无机改性柔性装饰片材的制备方法包括如下步 骤:  The preparation method of the environmental protection multi-functional building energy-saving inorganic modified flexible decorative sheet of the invention comprises the following steps:
1 ) 常温下, 将耐高温纤维加入水中浸泡 2-4小时;  1) Soak the high temperature resistant fiber in water for 2-4 hours at room temperature;
2 )在分散搅拌容器中加入陶土浆浆料、 氧化铁色浆 (如复配色需添加 )和部 分消泡剂搅拌分散均匀 0.5— 1小时, 再在分散搅拌容器中加入硅酸盐、 隔热空 心微珠、 无机粉料、 阻燃剂混合搅拌均 1-2小时, 再把步骤 1 )浸泡后的物料与 共混合后, 再加入改性物粘结剂、 消泡剂搅拌 0.5— 1小时, 静置熟化 0.5— 1小 时, 制得改性物浆料;  2) Adding clay slurry, iron oxide color paste (such as complex color to be added) and partial defoamer to stir and disperse evenly in the dispersion mixing vessel for 0.5-1 hour, then adding silicate and heat insulation in the dispersion mixing vessel. The hollow microbeads, the inorganic powder and the flame retardant are mixed and stirred for 1-2 hours, and then the materials after the step 1) are mixed and mixed, and then the modified binder and the antifoaming agent are added and stirred for 0.5 to 1 hour. After standing for 0.5 to 1 hour, a modified slurry is obtained;
3 )将步骤 2 )得到的改性物浆料分别浇注或者批刮喷涂在模具上, 在 40— 110°C条件下干透固化后起模, 表面处理后制得所述环保多功能建筑节能无机改 性柔性装饰片材; 或将改性物浆料浇注或者批刮喷涂在模具中, 背面或中间贴 合尼纶网或玻纤网, 在 40—110°C干透固化后起模, 表面处理后制得所述环保多 功能建筑节能无机改性柔性装饰片材。  3) The modified slurry obtained in the step 2) is separately cast or sprayed on the mold, dried and cured at 40-110 ° C, and then subjected to surface treatment to obtain the energy-saving multifunctional environmental protection building. Inorganic modified flexible decorative sheet; or the modified slurry is poured or sprayed in a mold, and the nylon or glass fiber mesh is attached on the back or the middle, and dried at 40-110 ° C to form a mold. After the surface treatment, the environmentally-friendly multifunctional building energy-saving inorganic modified flexible decorative sheet is obtained.
实施例 1  Example 1
调配色 I型 包括如下步骤。 Matching color type I Including the following steps.
将耐高温纤维 0.3份和消泡剂 0.1份放入容器中清水浸泡 10小时, 在另一 高速分散搅拌容器中加入陶土浆料 35份(固含量 70% )、 氧化铁色浆 0.3份、 消 泡剂 0.1份、 高速搅拌分散(转速 1000/分钟) 为 0.5小时, 再加入硅酸盐水泥 13份、 陶瓷空心微珠 3份、 玻璃空心微珠 3份、 彩色石英砂 20份、 钛白粉 0.5 份、 阻燃剂 3份、 混合搅拌 0.5小时 (转速 150/分钟), 再把分散混合搅拌两个 容器中的物料合在一起再加入改性物粘结剂(固含量为 50% ) 35份、 消泡剂 0.1 份、 清水 3份低速搅拌 0.5小时(转速 100/分钟 )形成稠状浆料, 静置熟化 0.5 小时后浇注在已备好的各种纹理的塑模具上, 用泥工刀批刮、 涂料滚筒喷枪均 匀滚喷涂, 第一道厚度约 lmm铺上玻纤网, 一遍完后再滚喷涂批刮一道浆料, 在红外光温度辐射下干透固化后(温度为 40度) 5小时为温度 60度 6小时, 也 可用常温下自然干透固化方可起模, 总体材质厚度为 l ~ 3mm, 材质干重量为小 于 7kg/m20.3 parts of high temperature resistant fiber and 0.1 part of antifoaming agent were placed in a container for 10 hours in water, and 35 parts of clay slurry (solid content 70%) and 0.3 part of iron oxide color paste were added to another high speed dispersion stirring vessel. 0.1 part of foaming agent, high-speed stirring and dispersion (rotation speed 1000/min) for 0.5 hours, then adding 13 parts of Portland cement, 3 parts of ceramic hollow microspheres, 3 parts of glass hollow microspheres, 20 parts of colored quartz sand, and titanium white powder 0.5 3 parts, flame retardant 3 parts, mixing and stirring for 0.5 hours (rotation speed 150/min), then mixing and mixing the materials in the two containers together with the modified binder (solid content 50%) 35 parts 0.1 parts of defoaming agent, 3 parts of clear water for 0.5 hour at low speed (100/min) to form a thick slurry. After standing for 0.5 hours, it is poured on the prepared plastic molds and batched with a mason. Scrape, paint roller spray gun evenly sprayed, the first thickness of about 1mm spread on the glass fiber mesh, after one pass, then roll the spray to scrape a slurry, dry and solidified under infrared light temperature radiation (temperature is 40 degrees) 5 The hour is 60 degrees 6 hours, and the room temperature can also be used. Dry naturally before starting a curing mold, the overall thickness of the material of l ~ 3mm, the dry weight of the material is less than 7kg / m 2.
所述的硅酸盐为水泥, 所述的消泡剂为瓦克 803#消泡剂、诺普科 NXZ消泡 剂、 长风 3016#消泡剂, 所述的阻燃剂为聚磷酸铵、 氢氧化铝等。  The silicate is cement, the defoaming agent is Wacker 803# defoaming agent, Nopko NXZ defoaming agent, Changfeng 3016# defoaming agent, and the flame retardant is ammonium polyphosphate. , aluminum hydroxide, etc.
实施例 2  Example 2
天然色 I型  Natural color type I
包括如下步骤  Including the following steps
将 35份聚合物粘结剂 (固含量为 50% )倒入搅拌容器中, 开启搅拌机(转 速 200/分钟)加入 45份天然色彩石英砂、 0.1份消泡剂、 3份阻燃剂、 3份陶瓷 空心微珠、 3份玻璃空心微珠、 13份硅酸盐、 2份清水, 搅拌分散均匀形成稠状 浆料。静置熟化 0.5小时后浇注在已备好的各种凹凸纹理的模具上, 用泥工刀批 刮、 涂料滚筒喷枪均匀滚喷涂, 第一道厚度约 1.5mm, 再铺上玻纤网一遍完后 再滚喷涂一道浆料, 在红外光温度辐射干透固化后(温度为 40度) 5小时 60度 6小时也可用常温下自然烘干方可起模, 总体材质厚度 2.5 ~ 3mm, 材质干重量 为小于 7kg/m2Pour 35 parts of polymer binder (50% solids) into a stirred vessel, turn on the blender (speed 200/min), add 45 parts of natural color quartz sand, 0.1 part defoamer, 3 parts of flame retardant, 3 The ceramic hollow microbeads, 3 parts of glass hollow microbeads, 13 parts of silicate, 2 parts of clear water, stirred and dispersed uniformly to form a thick slurry. After standing for 0.5 hour, it was poured on the molds of various irregular textures, and was scraped with a grinder knife and sprayed with a paint roller. The first thickness was about 1.5 mm, and then the fiberglass mesh was placed again. Roll a spray of slurry, after the infrared light temperature is dried and solidified (temperature is 40 degrees). 5 hours, 60 degrees, 6 hours, can also be dried naturally at normal temperature, the overall material thickness is 2.5 ~ 3mm, dry weight of material It is less than 7 kg/m 2 .
所述的硅酸盐为水泥, 所述的消泡剂为聚醚类消泡剂, 所述的阻燃剂为聚 磷酸铵。 实施例 3 The silicate is cement, the antifoaming agent is a polyether antifoaming agent, and the flame retardant is ammonium polyphosphate. Example 3
调配色 II型  Matching color type II
制备方法包括如下步骤:  The preparation method comprises the following steps:
1 )将耐高温纤维 0.1份、 消泡剂 0.1份放入容器中加入热水 3份浸泡 5小 时;  1) Put 0.1 parts of high temperature resistant fiber and 0.1 part of antifoaming agent into a container and add 3 parts of hot water for 5 hours;
2 )在分散搅拌容器中加入陶土浆浆料 30份、 氧化铁色浆 2份和消泡剂 0.2 份搅拌分散均匀 0.5小时, 再匀分散搅拌容器中加入硅酸盐 20份、 隔热空心微 珠 3份、 无机粉料 20份、 钛白粉 2份、 阻燃剂 0.2份混合搅拌均匀 2小时, 再 把步骤 1 )浸泡后的物料与之混合后, 再加入聚合物粘结剂 20份、 消泡剂 0.2 份搅拌 0.5小时, 静置熟化 0.5小时, 制得聚合物浆料;  2) Add 30 parts of clay slurry, 2 parts of iron oxide paste and 0.2 parts of antifoaming agent to the dispersion stirring vessel for 0.5 hour, then add 20 parts of silicate to the mixing vessel and heat insulation. 3 parts of beads, 20 parts of inorganic powder, 2 parts of titanium dioxide, and 0.2 parts of flame retardant are mixed and stirred for 2 hours. After mixing the materials soaked in step 1), 20 parts of polymer binder is added. 0.2 parts of antifoaming agent was stirred for 0.5 hours, and allowed to stand for 0.5 hour to prepare a polymer slurry;
3 )将步骤 2 )得到的改性物浆料分别浇注或者批刮在大小规格片材硅胶及 塑胶模具上, 在红外光温度辐射下(温度为 40度 5小时, 50度为 6小时)也可 用常温下自然干透固化后起模, 制得所述环保多功能建筑节能无机粉改性柔性 装饰片材, 总体材质厚度 2.5— 3mm材质干重量为小于 7kg/m2。  3) The modified slurry obtained in step 2) is separately poured or scraped on a size-size sheet of silica gel and a plastic mold, and is also irradiated under infrared light temperature (temperature of 40 degrees for 5 hours, 50 degrees for 6 hours). The organic decorative multi-functional building energy-saving inorganic powder modified flexible decorative sheet can be obtained by naturally drying and solidifying at a normal temperature, and the overall material thickness is 2.5-3 mm, and the dry weight is less than 7 kg/m2.
所述的硅酸盐为水泥,所述的消泡剂为瓦克 803 ,所述的阻燃剂为聚磷酸铵, 陶土浆浆料的固含量为 20%。  The silicate is cement, the antifoaming agent is Wacker 803, the flame retardant is ammonium polyphosphate, and the clay slurry has a solid content of 20%.
实施例 4  Example 4
天然色型  Natural color
制备方法包括如下步骤:  The preparation method comprises the following steps:
1 )将耐高温纤维 0.1份、 消泡剂 0.1份放入容器中加入热水 3份浸泡 5小 时。  1) Put 0.1 parts of high temperature resistant fiber and 0.1 part of antifoaming agent into a container and add 3 parts of hot water for 5 hours.
2 )在分散搅拌容器中加入消泡剂 0.2份、增稠剂 0.2份搅拌分散均匀 0.5小 时, 再分散搅拌容器中加入硅酸盐 20份、 隔热空心玻璃微珠 5份、 无机粉料 40 份、 阻燃剂 0.2份混合搅拌均匀 2小时,再把步骤 1 )浸泡后的物料与之混合后, 再加入聚合物粘结剂 3份、 消泡剂 0.2份搅拌 0.5小时静置热化 0.5小时制得聚 合物浆料。静置熟化 0.5小时后浇注在已备好的各种凹凸纹理的模具上, 用泥工 刀批刮、 涂料滚筒喷枪均勾滚喷涂, 第一道厚度约 1.5mm, 再铺上玻纤网一遍 完后再滚喷涂一道浆料, 在红外光温度辐射干透固化后 (温度为 40度) 5小时 60度 6小时也可用常温下自然烘干方可起模, 总体材质厚度 2.5 ~ 3mm,材质干 重量为小于 7kg/n 。 2) Add 0.2 parts of antifoaming agent, 0.2 parts of thickener, and evenly disperse and disperse for 0.5 hour in the dispersing stirring vessel. Add 20 parts of silicate, 5 parts of insulating hollow glass microbeads, and inorganic powder 40 in the dispersing stirring vessel. 0.2 parts of the flame retardant and mixing and stirring for 2 hours, and then mixing the materials after the step 1), and then adding 3 parts of the polymer binder and 0.2 parts of the antifoaming agent for 0.5 hour to stand for heating. The polymer slurry was obtained in an hour. After standing for 0.5 hours, it was poured on the molds with various concave and convex textures prepared. The scraper was sprayed with a grinder and the paint roller was sprayed with a spray gun. The first thickness was about 1.5 mm, and then the fiberglass mesh was finished. After rolling, spray a slurry, after the infrared light temperature is dried and solidified (temperature is 40 degrees) for 5 hours. 60 degrees and 6 hours can also be dried naturally at normal temperature. The overall material thickness is 2.5 ~ 3mm, and the dry weight of the material is less than 7kg/n.
实施例 5  Example 5
调色配型  Color matching
制备方法包括如下步骤:  The preparation method comprises the following steps:
1 )将耐高温纤维 1份、 消泡剂 0.1份放入容器中加入热水浸泡 5小时; 1) 1 part of high temperature resistant fiber and 0.1 part of antifoaming agent are placed in a container and soaked in hot water for 5 hours;
2 )在分散搅拌容器中加入陶土浆浆料 25份、 氧化铁色浆 1份和 0.1份消泡 剂搅拌分散均匀 1小时, 再在分散搅拌容器中加入硅酸盐 18份、 隔热空心微珠 7份、 无机粉料 20份、 钛白粉 2份、 阻燃剂 1.5份混合搅拌均 1小时, 再把步 骤 1 )浸泡后的物料与之混合后, 再加入改性物粘结剂 30份、 消泡剂 0.1份搅 拌 1.5小时, 静置熟化 1小时, 制得聚合物浆料; 2) Add 25 parts of clay slurry, 1 part of iron oxide paste and 0.1 part of antifoaming agent to the dispersion stirring vessel for 1 hour, and then add 18 parts of silicate in the dispersion stirring vessel. 7 parts of beads, 20 parts of inorganic powder, 2 parts of titanium dioxide, and 1.5 parts of flame retardant were mixed and stirred for 1 hour. Then, after mixing the materials after step 1), 30 parts of modified binder was added. 0.1 part of antifoaming agent was stirred for 1.5 hours, and allowed to stand for 1 hour to prepare a polymer slurry;
3 )将聚合物浆料浇注或者批刮在模具中, 背面或中间贴合玻纤网, 在红外 光温度辐射下 (温度为 50度 5小时, 60度为 10小时)也可用常温下自然干透 固化后起模, 制得所述环保多功能建筑节能无机粉改性柔性装饰片材, 总体材 质厚度 3— 5mm材质干重量为小于 10kg。  3) Pouring or batching the polymer slurry into the mold, and bonding the glass fiber mesh on the back or the middle. Under infrared light temperature radiation (temperature is 50 degrees, 5 hours, 60 degrees is 10 hours), it can also be dried naturally at normal temperature. After curing through the curing, the environmentally-friendly multifunctional building energy-saving inorganic powder modified flexible decorative sheet is obtained, and the overall material thickness is 3-5 mm, and the dry weight is less than 10 kg.
所述的硅酸盐为水泥,所述的消泡剂为瓦克 803 ,所述的阻燃剂为聚磷酸铵, 陶土浆料的固含量为 40%。  The silicate is cement, the antifoaming agent is Wacker 803, the flame retardant is ammonium polyphosphate, and the clay slurry has a solid content of 40%.
将本发明的装饰片材进行以下测试 The decorative sheet of the present invention is subjected to the following test
欧诺楼饰贴性能测试指标 试验项目 技术指标  Onofrio decoration performance test indicators Test project Technical indicators
外观 至少 95%的材料主要区域无明显缺陷 (指破损、 起泡、 上下层分离) 单位面积, kg/m2 ≤8 Appearance of at least 95% of the material in the main area without obvious defects (referring to breakage, blistering, separation of upper and lower layers) unit area, kg / m 2 ≤ 8
吸水率 < 0.1%  Water absorption rate < 0.1%
抗冻性 100次循环后, 用肉眼观察表面无裂痕、 剥落、 粉化等损坏现象  Frost resistance After 100 cycles, the surface was observed with no cracks, flaking, chalking, etc.
柔辆性 4mm圆柱弯曲  Flexible car 4mm cylindrical bending
水蒸汽湿流密度 g / (m2h) (透气性) > 0.85 Water vapor wet flow density g / (m 2 h) (breathability) > 0.85
拉伸强度 > 4.0Mpa  Tensile strength > 4.0Mpa
抗盐析 > 144h无盐析等现象 阻燃性 B1级 A级 Salting resistance > 144h without salting and other phenomena Flame retardant B1 grade A
耐老化性 2000h, 外观无裂纹、 无损坏  Aging resistance 2000h, no cracks, no damage
尺寸稳定性 士 0.5 %  Dimensional stability ± 0.5%
沾污性 /级 ≤1级 Staining / grade ≤1
抗化学腐蚀性 800h , 无起泡、 剥落现象  Chemical resistance 800h, no blistering, peeling
耐酸性 (.2%, H2S03) 48h , 无异常 Acid resistance (.2%, H 2 S0 3 ) 48h, no abnormality
耐热性 85°C,5h, 涂层无起泡、 流淌  Heat resistance 85 ° C, 5h, no blistering, flowing
不透水性 0.3Mpa,40min.无渗漏  Impervious to water 0.3Mpa, 40min. No leakage
可溶性铅 ≤20  Soluble lead ≤20
有害物质限量 可溶性镉 ≤5  Limit of harmful substances Soluble cadmium ≤5
TVOC(mg/kg) ≤0.5  TVOC (mg/kg) ≤0.5
!ra ≤0.9 ! ra ≤0.9
放射性  Radioactivity
I , ≤ 1.2  I , ≤ 1.2
太阳反射比(浅白色) > 0.82  Solar reflectance (light white) > 0.82
隔热指标  Thermal insulation index
半球发射率 > 0.82  Hemispheric emissivity > 0.82
由此可知, 本发明的具有以下优点为:  It can be seen that the present invention has the following advantages:
( 1 ) 自重轻、 抗震、 安全性极高。  (1) Light weight, shock resistance and high safety.
由于本产品所采用天然原始的矿石尾矿砂石粉与现代高科技技术应用, 在 红外光曲线高温度下辐射改性而成使产品具有隔热性好、 自身质变得更轻、 质 地更加柔软, 尤其使用在外墙高层建筑上更加安全可靠。  Due to the natural original ore tailings and gravel powder used in this product and modern high-tech technology application, the radiation is modified at the high temperature of the infrared light curve to make the product have good heat insulation, lighter quality and softer texture, especially It is safer and more reliable to use on high-rise buildings on the outer wall.
( 2 ) 阻燃无烟、 优异的防火性能。  (2) Flame retardant, excellent fire resistance.
天然原始的尾矿砂石粉添加入无机和部分有机粘结材料在较高红外光温度 体危害, 防火性能达 B1级。  The natural raw tailings sand powder is added to the inorganic and some organic bonding materials at a higher infrared light temperature, and the fire performance is up to B1.
( 3 )超强的化学稳定性, 使产品自洁、 耐酸、 耐久、 耐候性更加长久。 耐酸碱腐蚀、 耐高温、 耐紫外线老化, 适用于各种环境下高档外墙装饰及 产品的性能。  (3) Superior chemical stability, making the product self-cleaning, acid-resistant, durable, and weather-resistant. It is resistant to acid and alkali corrosion, high temperature resistance and UV aging. It is suitable for high-grade exterior wall decoration and product performance in various environments.
( 4 )节能低碳、 环保健康、 内外装饰同样适用。  (4) Energy-saving and low-carbon, environmentally friendly and healthy, both internal and external decoration are also applicable.
天然的原材料原始尾矿和砂石粉、 隔热无机空心微珠使本产品隔热性好、 不含曱 、 VCO等挥发性及放射性有害化合物, 在装饰、 使用、 生产、 施工过 程中不会对人员的健康造成危害, 是绿色建筑节能产品。 ( 5 )优异的柔性, 用于内外墙饰面不会因底材产生裂纹而开裂, 具有优异 的防水性。 Natural raw materials, raw tailings and sandstone powder, and heat-insulating inorganic hollow microspheres make this product good in heat insulation, free of volatile and radioactive harmful compounds such as antimony and VCO. It will not be in the process of decoration, use, production and construction. The health of personnel is a hazard and is a green building energy-saving product. (5) Excellent flexibility, used for internal and external wall finishes without cracking due to cracks in the substrate, and excellent water resistance.
( 6 )具有优异的抗盐析、抗泛碱性,使柔性装饰片材具有非常好的装饰性。 (6) It has excellent resistance to salting out and anti-alkaline, making the flexible decorative sheet very decorative.
( 7 ) 片材可复制成石材、 瓷砖、 古砖等各种花纹, 片材材质轻, 是高层建 筑外墙理想装饰产品。 (7) The sheet can be copied into various patterns such as stone, ceramic tile and ancient brick. The sheet material is light and it is an ideal decoration product for the exterior wall of high-rise building.
( 8 )柔性片材可直接用粘结剂粘贴到水泥砂浆基层面上, 施工筒单也可应 用在保温一体化系统饰面层上。  (8) The flexible sheet can be directly bonded to the cement mortar base layer with an adhesive, and the construction cylinder can also be applied to the thermal insulation integrated system finish layer.
( 9 )极具潜力的节省空间、 厚度只有墙面砖的三分之一厚。  (9) Great potential for space saving, only one-third thicker than wall tiles.
原始的材料与现代先进的生产工艺铸造了当代优质超薄高性能的柔性装饰 材料产品。  The original materials and modern advanced production processes cast contemporary high-quality ultra-thin high-performance flexible decorative materials.
( 10 )优越的柔韧性、 超强的耐沖击性。  (10) Superior flexibility and superior impact resistance.
先进的碳纤维技术及工艺将产品抗拉伸强度、 沖击性和韧性提高到了极佳 状态。  Advanced carbon fiber technology and processes have improved the tensile strength, impact and toughness of the product to an excellent level.
( 11 )智能透气、 防霉抗菌、 防水、 抗裂性优异。  (11) Excellent in intelligent ventilation, anti-mildew, anti-water, and crack resistance.
致密智能的产品膜层结构型成防霉抗菌、 透气、 不透水、 体积稳定、 极低 的溶缩性具备了自身柔韧性在龟裂、 空鼓方面结构更加稳定。  The dense and intelligent product film structure is anti-mildew, antibacterial, gas permeable, impervious to water, stable in volume, and extremely low in sizing. It has its own flexibility and is more stable in cracks and hollow drums.
( 12 )具备极高的可粘结强度直接用于旧墙翻新节能改造。  (12) It has a very high bond strength and can be directly used for renovation and energy-saving renovation of old walls.
由于本产品具备轻质和优越的柔韧性、 抗裂、 防水性及天然的质感美观, 可直接用粘接剂粘贴在原有的墙面上, 从而使旧城改造过程无需大量墙体铲除 工序, 避免了大量资源浪费。  Because of its light weight and superior flexibility, crack resistance, water resistance and natural texture, it can be directly bonded to the original wall with adhesive, so that the old city transformation process does not require a lot of wall removal process. Avoid a lot of waste of resources.
( 13 )施工筒便、 色彩多样彰显天然效果。  (13) The construction of the tube and the variety of colors highlight the natural effects.
与外墙大理石、 花岗岩干挂施工相比, 本产品在施工方面更为轻便, 极大 的缩短了工期。 以天然原始材料为肌理, 历代工艺制品和现代艺术创作等做基 础, 集 300多种天然气和复配色调及与生倶来色泽天然优雅而丰富、 弥久历新、 30年不变型、 不变色符合现代城市建筑回归自然的特性。  Compared with the external wall marble and granite hanging construction, this product is lighter in construction and greatly shortens the construction period. Based on natural raw materials, historical crafts and modern art creations, it is based on more than 300 kinds of natural gas and complex color tones. It is rich in natural elegance and rich in color, long-lasting, 30-year-old, non-discoloring. It conforms to the characteristics of modern urban architecture returning to nature.
( 14 ) 多功能建筑节能无机改性柔性装饰片材是建筑节能外墙外保温和保 温装饰一体化系统饰面材料配套理想选材。  (14) Multi-functional building energy-saving inorganic modified flexible decorative sheet is the ideal material for building energy-saving exterior wall insulation and temperature-proof decorative system finishing materials.
集自重轻、 自洁性强、 防火、 防水、 抗裂、 耐酸、 耐候隔热及优越的柔韧 性于一体。 真实的天然质感是外墙外保温配套的绝佳首选产品。 Light weight, self-cleaning, fireproof, waterproof, crack resistant, acid resistant, weather resistant and superior flexibility Sexuality in one. The true natural texture is the perfect choice for exterior insulation.
( 15 ) 回归自然。  (15) Return to nature.
多功能建筑节能无机改性柔性装饰片材技术产品可回收, 通过物理机械处 理还原砂土本质用于再利用或耕作。 以上所述仅为本发明的实施例, 并非因此限制本发明的专利范围, 凡是利 用本发明说明书内容所作的等效结构或等效流程变换, 或直接或间接运用在其 他相关的技术领域, 均同理包括在本发明的专利保护范围内。  Multi-functional building energy-saving inorganic modified flexible decorative sheet technology products can be recycled, and the physical properties of the sand are restored by physical and mechanical treatment for reuse or cultivation. The above is only the embodiment of the present invention, and thus does not limit the scope of the patent of the present invention. Any equivalent structure or equivalent process transformation made by using the content of the specification of the present invention, or directly or indirectly applied to other related technical fields, The same is included in the scope of patent protection of the present invention.

Claims

权 利 要 求 书 claims
1、 一种环保多功能建筑节能无机改性柔性装饰片材, 其特征在于, 其配方 按重量份包括以下组分: 1. An environmentally friendly multi-functional building energy-saving inorganic modified flexible decorative sheet, characterized in that its formula includes the following components by weight:
硅酸盐水泥 10— 18份 Portland cement 10-18 parts
聚合物粘结剂 10—40份 Polymer binder 10-40 parts
空心微珠 2-10份 Hollow microbeads 2-10 parts
石英砂粉料 10—30份 Quartz sand powder 10-30 parts
耐高温纤维 0.1— 1份 High temperature resistant fiber 0.1-1 part
增稠剂 0.1— 0.5份 Thickener 0.1-0.5 parts
钛白粉 0.5—2.0份 Titanium dioxide 0.5-2.0 parts
消泡剂 0.1— 0.5份 Defoaming agent 0.1- 0.5 parts
阻燃剂 0.2— 1.5份。 Flame retardant 0.2-1.5 parts.
2、 根据权利要求 1所述的环保多功能建筑节能无机改性柔性装饰片材, 其 特征在于, 还包括以下组分: 陶土浆料 8— 30份、 色浆 0.1-1份。 2. The environmentally friendly multifunctional building energy-saving inorganically modified flexible decorative sheet according to claim 1, characterized in that it also includes the following components: 8-30 parts of clay slurry, 0.1-1 part of color paste.
3、 根据权利要求 1所述的环保多功能建筑节能无机改性柔性装饰片材, 其 特征在于, 所述聚合物粘结剂为丙烯酸乳液。 3. The environmentally friendly multifunctional building energy-saving inorganically modified flexible decorative sheet according to claim 1, characterized in that the polymer binder is an acrylic emulsion.
4、 根据权利要求 1所述的环保多功能建筑节能无机改性柔性装饰片材, 其 特征在于,所述空心微珠为粒径 10-90微米的硼硅酸盐形成的粒径 1-2微米空心 球形。 4. The environmentally friendly multifunctional building energy-saving inorganically modified flexible decorative sheet according to claim 1, characterized in that the hollow microbeads are formed of borosilicate with a particle size of 10-90 microns and a particle size of 1-2 Micron hollow sphere.
5、 根据权利要求 1所述的环保多功能建筑节能无机改性柔性装饰片材, 其 特征在于, 所述石英砂粉料的细度为 20-300目。 5. The environmentally friendly multifunctional building energy-saving inorganically modified flexible decorative sheet according to claim 1, characterized in that the fineness of the quartz sand powder is 20-300 mesh.
6、 根据权利要求 1所述的环保多功能建筑节能无机改性柔性装饰片材, 其 特征在于, 所述陶土浆料由以下重量份的组分组成: 6. The environmentally friendly multifunctional building energy-saving inorganic modified flexible decorative sheet according to claim 1, characterized in that the clay slurry consists of the following components by weight:
高岭土 5份; 5 parts kaolin;
石英粉 15份; Quartz powder 15 parts;
硅灰粉 5份; 5 parts of silica fume powder;
水 100-150分; Water 100-150 points;
所述陶土浆料的固含量为 20-40%。 The solid content of the clay slurry is 20-40%.
7、 一种环保多功能建筑节能无机改性柔性装饰片材的制备方法, 其特征在 于, 包括以下步骤: 7. A method for preparing an environmentally friendly multifunctional building energy-saving inorganically modified flexible decorative sheet, which is characterized by including the following steps:
1 )常温下, 将耐高温纤维加入水中浸泡 2-4小时; 1) At normal temperature, add high temperature resistant fiber to water and soak for 2-4 hours;
2 )将陶土浆料、 色浆和消泡剂搅拌分散均匀 0.5-1 小时后, 加入硅酸盐水 泥、 空心微珠、 石英砂粉料、 增稠剂、 阻燃剂混合搅拌均匀 1-2小时, 再把步骤 1 )浸泡后的物料加入混合后, 再加入聚合物粘结剂、 消泡剂搅拌 1-1.5 小时, 静置熟化 1-1.5小时, 调准 PH值 9-10制得改性物浆料; 2) Stir and disperse the clay slurry, color paste and defoaming agent evenly for 0.5-1 hour, then add Portland cement, hollow microbeads, quartz sand powder, thickener and flame retardant and mix and stir evenly for 1-2 hours, then add the soaked materials in step 1) and mix, then add polymer binder and defoaming agent, stir for 1-1.5 hours, leave to mature for 1-1.5 hours, and adjust the pH value to 9-10 to prepare the modified product. sex slurry;
3 )将步骤 2 得到的改性物浆料分别浇注或者批刮、 喷涂在模具上, 在 40-110°C条件下干透固化后起模,制得所述环保多功能建筑节能无机改性柔性装 饰片材。 3) Pour or scrape or spray the modified slurry obtained in step 2 on the mold respectively, dry and solidify at 40-110°C and then remove the mold to prepare the environmentally friendly multi-functional building energy-saving inorganic modification Flexible decorative sheet.
8、 一种环保多功能建筑节能无机改性柔性装饰片材的制备方法, 其特征在 于, 包括以下步骤: 8. A method for preparing an environmentally friendly, multi-functional building energy-saving inorganically modified flexible decorative sheet, which is characterized by including the following steps:
1 )常温下, 将耐高温纤维加入水中浸泡 2-4小时; 1) At normal temperature, add high temperature resistant fiber to water and soak for 2-4 hours;
2 )将陶土浆料、 色浆和消泡剂搅拌分散均匀 0.5-1 小时后, 加入硅酸盐水 泥、 空心微珠、 石英砂粉料、 增稠剂、 阻燃剂混合搅拌均匀 1-2小时, 再把步骤 1 )浸泡后的物料加入混合后, 再加入聚合物粘结剂、 消泡剂搅拌 1-1.5 小时, 静置熟化 1-1.5小时, 调准 PH值 9-10制得改性物浆料; 2) Stir and disperse the clay slurry, color paste and defoaming agent evenly for 0.5-1 hour, then add Portland cement, hollow microbeads, quartz sand powder, thickener and flame retardant and mix and stir evenly for 1-2 hours, then add the soaked materials in step 1) and mix, then add polymer binder and defoaming agent, stir for 1-1.5 hours, leave to mature for 1-1.5 hours, and adjust the pH value to 9-10 to prepare the modified product. sex slurry;
3 )将步骤 2得到无机改性物浆料浇注或者批刮、 喷涂在模具中, 背面或中 间贴合尼纶网, 在 40-110°C干透固化后起模, 制得所述环保多功能建筑节能无 机改性柔性装饰片材。 3) Pour, scrape or spray the inorganic modified material slurry obtained in step 2 into the mold, attach a nylon net to the back or in the middle, dry and solidify at 40-110°C and then take off the mold to prepare the environmentally friendly polyester. Functional building energy-saving inorganic modified flexible decorative sheet.
9、 根据权利要求 7或 8所述的环保多功能建筑节能无机改性柔性装饰片材 的制备方法, 其特征在于, 其中组分的重量份为: 9. The method for preparing the environmentally friendly multifunctional building energy-saving inorganic modified flexible decorative sheet according to claim 7 or 8, characterized in that the weight parts of the components are:
硅酸盐水泥 10— 18% Portland cement 10- 18%
聚合物粘结剂 20— 50% Polymer binder 20-50%
空心微珠 2-10% Hollow microbeads 2-10%
石英砂粉料 10—30% Quartz sand powder 10-30%
耐高温纤维 0.1— 1% High temperature resistant fiber 0.1- 1%
增稠剂 0.1— 0.5% 钬白粉 0.5— 2.0% Thickener 0.1- 0.5% Holmium white powder 0.5- 2.0%
消泡剂 0.1— 0.5% Defoaming agent 0.1- 0.5%
阻燃剂 0.2— 1.5% Flame retardant 0.2- 1.5%
陶土浆料 8— 30% Clay slurry 8-30%
色浆 0.1-1%。 Color paste 0.1-1%.
10、 根据权利要求 9所述的环保多功能建筑节能无机改性柔性装饰片材的 制备方法, 其特征在于, 所述陶土浆料由以下重量份的组分组成: 10. The preparation method of the environmentally friendly multifunctional building energy-saving inorganically modified flexible decorative sheet according to claim 9, characterized in that the clay slurry consists of the following components by weight:
高岭土 5份; 5 parts kaolin;
石英粉 15份; Quartz powder 15 parts;
硅灰粉 5份; 5 parts of silica fume powder;
水 100-150分; Water 100-150 points;
所述陶土浆料的固含量为 20-40%。 The solid content of the clay slurry is 20-40%.
PCT/CN2013/071697 2013-01-11 2013-02-20 Environment-friendly, multifunctional, energy-saving, inorganic modified and flexible building decorative sheet and preparation method therefor WO2014107930A1 (en)

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