WO2014101266A1 - Mélange d'engrais à libération prolongée adapté aux plantations de soja - Google Patents
Mélange d'engrais à libération prolongée adapté aux plantations de soja Download PDFInfo
- Publication number
- WO2014101266A1 WO2014101266A1 PCT/CN2013/001242 CN2013001242W WO2014101266A1 WO 2014101266 A1 WO2014101266 A1 WO 2014101266A1 CN 2013001242 W CN2013001242 W CN 2013001242W WO 2014101266 A1 WO2014101266 A1 WO 2014101266A1
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- WO
- WIPO (PCT)
- Prior art keywords
- fertilizer
- powder
- parts
- mixed
- phosphate
- Prior art date
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Classifications
-
- C—CHEMISTRY; METALLURGY
- C05—FERTILISERS; MANUFACTURE THEREOF
- C05B—PHOSPHATIC FERTILISERS
- C05B7/00—Fertilisers based essentially on alkali or ammonium orthophosphates
-
- C—CHEMISTRY; METALLURGY
- C05—FERTILISERS; MANUFACTURE THEREOF
- C05G—MIXTURES OF FERTILISERS COVERED INDIVIDUALLY BY DIFFERENT SUBCLASSES OF CLASS C05; MIXTURES OF ONE OR MORE FERTILISERS WITH MATERIALS NOT HAVING A SPECIFIC FERTILISING ACTIVITY, e.g. PESTICIDES, SOIL-CONDITIONERS, WETTING AGENTS; FERTILISERS CHARACTERISED BY THEIR FORM
- C05G5/00—Fertilisers characterised by their form
- C05G5/30—Layered or coated, e.g. dust-preventing coatings
Definitions
- the invention is a slow release compound fertilizer suitable for soybean planting application. It is a mixture of various fertilizers and non-specific fertilizer components containing substances that affect the nitrification of urea in the soil. Background technique
- Soybean is an important food crop and cash crop. Its yield and acreage are second only to rice, wheat and corn, ranking fourth in the world. It plays an important role in the people's death and the national economy. In recent years, the rapid development of livestock and poultry breeding industry, the corresponding feed industry demand for soybean meal is in short supply and shortage. Effective use of limited land resources and increased yield and quality of soybean crops are the direction of efforts.
- iron, zinc and molybdenum elements are essential micro-elements for soybean production.
- soybean rhizobium Due to the nitrogen fixation of soybean rhizobium, a prejudice has arisen, resulting in a biased application of phosphate and potash. In fact, the growth of soybeans is a crop that requires more nitrogen. After the pre-fertility and post-fertility root tumors decline, sufficient nitrogen supply is needed, which must be achieved by fertilization.
- Urea is a high-quality nitrogen fertilizer with high nitrogen content, fast fertilizer efficiency and large dosage.
- urea in the process of using urea, it is easy to be lost through volatilization, leaching, decomposition and runoff, resulting in low efficiency of fertilizer efficiency.
- the utilization rate in the current season is only about 30%, which not only causes waste of fertilizer, but also It pollutes the environment in which humans depend on the atmosphere, water and soil.
- sulfur and various polymer resins are used at home and abroad to coat urea. Or adding a uric acid inhibitor and a nitrification inhibitor; using a high molecular polymer material such as a cyclic chlorine resin or an acrylic resin or even a multi-layer coating or a mixture of several kinds of fertilizer particles to form a slow release controlled release fertilizer; the coating material is difficult Degradation in the soil, causing damage to the soil environment. Moreover, the process is complicated, the manufacturing cost is high, and the environment is polluted.
- Phosphorus is an important component of biological cytoplasm and an essential element for plant growth.
- the coating material is difficult to degrade, and long-term use will have a negative impact on the soil; even pollute the soil and affect the quality of agricultural products.
- the ratio of the main nutrient elements in the fertilizer does not match the demand for each stage of soybean growth, and the fertilizer efficiency is low.
- the object of the present invention is to avoid the above-mentioned deficiencies in the prior art, overcome the traditional prejudice, reduce the production cost, and excellent environmental protection, and provide a comprehensive nutrition, excellent sustained release performance, and can fully satisfy the soybean nutrient demand, the largest Limiting the effectiveness of the fertilizer, the slow-release compound fertilizer suitable for soybean planting can improve soybean yield and improve its quality.
- the object of the present invention can be achieved by the following measures:
- a slow-release compound fertilizer suitable for soybean planting application of the present invention characterized in that the mash is prepared as follows according to the mass fraction of raw materials:
- Zinc, iron, molybdenum additives 0. Bu 0.5
- the mixed phosphate fertilizer is prepared by compounding diammonium phosphate, calcium magnesium phosphate fertilizer and apatite powder, and the mass percentage is as follows:
- Calcium magnesium phosphate fertilizer % 1 0 ⁇ 25 3% apatite powder () ⁇ 4 () the apatite powder is ⁇ 2 0 5 content of the low grade rock phosphate in 10% ⁇ 20% of the fflj;
- the zinc, iron, and molybdenum additives are water-soluble salts of zinc, iron, and molybdenum:
- the granulation aid ⁇ 702 ⁇ 4-85% bentonite and 30%-15% bauxite powder are mixed;
- the preparation method comprises the following steps:
- urea 20 to 40 parts by weight of urea is heated and melted, and then 7 to 20 parts by weight of ammonium sulfate and 10 to 15 parts by weight of potassium sulfate are mixed uniformly to prepare a potassium fertilizer and a nitrogen fertilizer compound containing potassium, sulfur and ammonium, and used;
- the method of coating is as follows:
- the coating is accurately metered with stearic acid according to the formula, it is put into the stearic acid melting tank and heated to the molten state for use: b. .
- the mixed particles of the composite fertilizer prepared in the step 3 are accurately measured, and the molten stearic acid prepared in the step a is sprayed in the drum type mixing granulator to prepare the mixed particles to be as uniform as possible.
- Coating, hot air drying, room temperature air cooling, standby; process conditions are as follows:
- Hot air drying temperature is not higher than 80 'C
- the cooling air temperature is not higher than 50 ⁇ ;
- Modified zeolite powder powder material powder a. Preparation of powder for mixing powder
- the amount of the mixed powder prepared in the step a is controlled to be 10 ⁇ 15 kg of the mixed particles of the compound fertilizer prepared per 1000 kg of the compound 3 ;
- S and Ca are also in demand and are indispensable nutrients for plant production.
- Sulfur is an important component of protein.
- Calcium plays an irreplaceable role in plant seed germination and organ development.
- the S and Ca elements enter the compound fertilizer component and have positive effects in crop growth, pest control and soil improvement.
- the sulfur element in the raw material formulation of the present invention is added in the form of soluble sulfate, and the proportion is large, and the fourth largest nutrient element necessary for crop growth directly provides sulfur nutrients for soybean growth.
- the apatite component of the formula mixed phosphate fertilizer also provides calcium, which is compatible with other components in the raw material formula and is suitable for soybean growth. To improve the yield and quality of soybeans. Made a contribution.
- the object of the present invention can also be attained by the following measures - a sustained-release compound fertilizer suitable for soybean planting application of the present invention, characterized in that
- the mixed phosphate fertilizer is compounded by diammonium phosphate, calcium magnesium phosphate fertilizer and apatite powder, and the mass percentage thereof is as follows: phosphoric acid two hinges 35 ⁇ 45
- Apatite powder 35 ⁇ 40 It is a preferred technical solution.
- the mixed phosphate fertilizer is prepared by compounding diammonium phosphate, calcium magnesium phosphate fertilizer and apatite powder, and the mass percentage thereof is as follows:
- the method for applying the slow-release compound fertilizer suitable for soybean planting application of the present invention is characterized in that W, 45 50 Kg/mu is applied at one time.
- the coating material can be degraded under the soil microorganisms to avoid the pollution of the coating material to the soil environment. 4.
- the main nutrient and nutrient ratio in fertilizer is reasonable.
- the sulfur element in the raw material formula is added in the form of soluble sulfate, and the proportion is large.
- the fourth largest nutrient element necessary for crop growth provides sulfur nutrient directly for soybean. The efficiency of fertilizer efficiency is reduced, and the yield and quality of soybeans are improved.
- the sustained-release compound fertilizer suitable for soybean planting application of the present invention was prepared in accordance with the following procedure.
- urea 35 parts by weight of urea is heated and melted, and then 15 parts by weight of ammonium sulfate and 22 parts by weight of potassium sulfate are added and uniformly mixed to prepare a potassium fertilizer and a nitrogen fertilizer compound containing potassium, sulfur and ammonium, and used;
- apatite powder prepared in step a 35 parts by weight of diammonium phosphate, 25 parts by weight of calcium magnesium phosphate, and 40 parts by weight of apatite powder prepared in step a, are prepared for use;
- the coating method is as follows: 4.
- the stearic acid coating film is used in the amount of the mixed granules of the composite fertilizer prepared in the first step.
- the coating is accurately metered with stearic acid according to the formula, it is put into the stearic acid melting tank and heated to the molten state for use; b. .
- the mixed particles of the composite fertilizer prepared in the step 3 are accurately measured, and the molten stearic acid prepared by the step a is used.
- the outer surface of the mixed particles is sprayed to form a coating layer which is as uniform as possible on the outer surface of the mixed particles, and the hot air is dried, cooled at room temperature, and used; the process conditions are as follows:
- Hot air drying temperature is not higher than 80 ° C
- the cooling air temperature is not higher than 50 ° C :
- magnesium stearate 1. 2% ⁇ 2. 7 %, zeolite powder 97. 3% - 98. 8% of the raw material ratio, accurately weigh the raw materials, mix evenly, grind the powder, control the powder Fineness over 120 mesh sieve, spare;
- the amount of the mixed powder prepared in the step a is controlled to be 10 ⁇ 15 kg of the mixed particles of the compound fertilizer prepared per 1000 kg of the compound 3 ;
- the slow-release compound fertilizer suitable for soybean planting application of the present invention is prepared according to the raw material formula of Table 1.
- Example 2 Example 3
- Example 4 Example 5
- Example 6 Example ⁇ Urea 25 22 30 28 40 20 Ammonium sulphate 20 ⁇ 0 1 1 20 7 20 Potassium sulphate 25 35 19 20 25 20
- the sustained-release compound fertilizer suitable for soybean planting is prepared; the obtained product particles have a rounded appearance, and the product has no odor; the product quality reaches the following technical indexes:
Abstract
L'invention concerne un mélange d'engrais à libération prolongée adapté aux plantations de soja. L'invention concerne plus précisément un engrais ayant une activité digestive et formé de l'urée que l'on trouve dans le sol. La composition en parties de poids est la suivante : 20-40 parties d'urée, 7-20 parties de sulfate d'ammonium, 10-35 parties de sulfate de potassium, 25-30 parties de mélange d'engrais, 0,1-0,5 d'additif de zinc, de fer et de molybdène, 7-10 partie d'agent de granulation, le reste étant de l'eau. Le procédé de préparation comprend les étapes suivantes : a) préparation du mélange d'engrais à base de potassium et d'azote; b) préparation d'un mélange d'engrais phosphaté; c) préparation de chaque granulé pour le mélange d'engrais; d) revêtement avec un film d'acide stéarique; e) modification avec poudre de talc du matériau en poudre de zéolite; et f) criblage. Avantages : adapté à l'alimentation, haute performance à libération prolongée, peut pleinement satisfaire aux besoins nutritifs de soja, taux d'utilisation d'engrais élevé, meilleur rendement de soja et amélioration de la qualité de celui-ci, économie des ressources, sans danger pour l'environnement, adaptation aux plantations de soja.
Applications Claiming Priority (2)
Application Number | Priority Date | Filing Date | Title |
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CN201210574309.2 | 2012-12-26 | ||
CN201210574309.2A CN103058753B (zh) | 2012-12-26 | 2012-12-26 | 适合于大豆种植施用的缓释复合肥料 |
Publications (1)
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WO2014101266A1 true WO2014101266A1 (fr) | 2014-07-03 |
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PCT/CN2013/001242 WO2014101266A1 (fr) | 2012-12-26 | 2013-10-14 | Mélange d'engrais à libération prolongée adapté aux plantations de soja |
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CN (1) | CN103058753B (fr) |
WO (1) | WO2014101266A1 (fr) |
Cited By (1)
Publication number | Priority date | Publication date | Assignee | Title |
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CN110540463A (zh) * | 2019-09-19 | 2019-12-06 | 李清华 | 一种适用于大豆种植用的复合化肥及其制备方法 |
Families Citing this family (5)
Publication number | Priority date | Publication date | Assignee | Title |
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CN103058753B (zh) * | 2012-12-26 | 2015-04-22 | 施可丰化工股份有限公司 | 适合于大豆种植施用的缓释复合肥料 |
CN103601561A (zh) * | 2013-10-31 | 2014-02-26 | 界首市联发种植专业合作社 | 一种针对华北平原土壤的大豆有机复合肥 |
CN105272647A (zh) * | 2015-11-13 | 2016-01-27 | 张彦优 | 一种大豆专用缓释复合肥及其制备方法 |
CN105777271A (zh) * | 2016-03-31 | 2016-07-20 | 太仓市永发农场专业合作社 | 一种高营养农业用复合肥料及其制备方法 |
CN106588399A (zh) * | 2017-02-09 | 2017-04-26 | 合肥隆扬农业科技有限公司 | 一种适用于大豆种植用的复合化肥及其制备方法 |
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CN101177365B (zh) * | 2007-11-01 | 2010-08-11 | 山东农业大学 | 长效玉米专用控释肥及其制备方法 |
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2012
- 2012-12-26 CN CN201210574309.2A patent/CN103058753B/zh active Active
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- 2013-10-14 WO PCT/CN2013/001242 patent/WO2014101266A1/fr active Application Filing
Patent Citations (5)
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CN101121620A (zh) * | 2007-08-15 | 2008-02-13 | 陈温福 | 一种炭基缓释大豆专用肥料及其制备方法 |
CN101182265A (zh) * | 2007-12-05 | 2008-05-21 | 天津市中天化肥有限公司 | 三层涂膜大豆肥的生产方法 |
CN102093144A (zh) * | 2011-01-19 | 2011-06-15 | 施可丰化工股份有限公司 | 可生物降解包膜尿素 |
CN102432374A (zh) * | 2011-09-02 | 2012-05-02 | 史丹利化肥股份有限公司 | 熔体生物质复合硫酸钾型缓释肥料及其制备方法 |
CN103058753A (zh) * | 2012-12-26 | 2013-04-24 | 施可丰化工股份有限公司 | 适合于大豆种植施用的缓释复合肥料 |
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CN110540463A (zh) * | 2019-09-19 | 2019-12-06 | 李清华 | 一种适用于大豆种植用的复合化肥及其制备方法 |
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CN103058753A (zh) | 2013-04-24 |
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