WO2014026217A1 - Processing of lithium containing material - Google Patents
Processing of lithium containing material Download PDFInfo
- Publication number
- WO2014026217A1 WO2014026217A1 PCT/AU2013/000857 AU2013000857W WO2014026217A1 WO 2014026217 A1 WO2014026217 A1 WO 2014026217A1 AU 2013000857 W AU2013000857 W AU 2013000857W WO 2014026217 A1 WO2014026217 A1 WO 2014026217A1
- Authority
- WO
- WIPO (PCT)
- Prior art keywords
- solution
- lithium
- leach
- spodumene
- containing material
- Prior art date
Links
- 229910052744 lithium Inorganic materials 0.000 title claims abstract description 27
- WHXSMMKQMYFTQS-UHFFFAOYSA-N Lithium Chemical compound [Li] WHXSMMKQMYFTQS-UHFFFAOYSA-N 0.000 title claims abstract description 26
- 239000000463 material Substances 0.000 title claims abstract description 24
- WMFOQBRAJBCJND-UHFFFAOYSA-M Lithium hydroxide Chemical compound [Li+].[OH-] WMFOQBRAJBCJND-UHFFFAOYSA-M 0.000 claims abstract description 74
- 238000000034 method Methods 0.000 claims abstract description 69
- KWGKDLIKAYFUFQ-UHFFFAOYSA-M lithium chloride Chemical compound [Li+].[Cl-] KWGKDLIKAYFUFQ-UHFFFAOYSA-M 0.000 claims abstract description 34
- 239000012535 impurity Substances 0.000 claims abstract description 19
- 238000005868 electrolysis reaction Methods 0.000 claims abstract description 7
- 239000000243 solution Substances 0.000 claims description 59
- CNLWCVNCHLKFHK-UHFFFAOYSA-N aluminum;lithium;dioxido(oxo)silane Chemical compound [Li+].[Al+3].[O-][Si]([O-])=O.[O-][Si]([O-])=O CNLWCVNCHLKFHK-UHFFFAOYSA-N 0.000 claims description 25
- XGZVUEUWXADBQD-UHFFFAOYSA-L lithium carbonate Chemical compound [Li+].[Li+].[O-]C([O-])=O XGZVUEUWXADBQD-UHFFFAOYSA-L 0.000 claims description 22
- 229910052808 lithium carbonate Inorganic materials 0.000 claims description 22
- VEXZGXHMUGYJMC-UHFFFAOYSA-N Hydrochloric acid Chemical compound Cl VEXZGXHMUGYJMC-UHFFFAOYSA-N 0.000 claims description 21
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 14
- 229910052644 β-spodumene Inorganic materials 0.000 claims description 13
- 239000012141 concentrate Substances 0.000 claims description 12
- 239000013078 crystal Substances 0.000 claims description 12
- 238000001704 evaporation Methods 0.000 claims description 11
- 230000008020 evaporation Effects 0.000 claims description 11
- 229910052643 α-spodumene Inorganic materials 0.000 claims description 11
- CURLTUGMZLYLDI-UHFFFAOYSA-N Carbon dioxide Chemical compound O=C=O CURLTUGMZLYLDI-UHFFFAOYSA-N 0.000 claims description 10
- 229910052742 iron Inorganic materials 0.000 claims description 9
- 229910052782 aluminium Inorganic materials 0.000 claims description 8
- 238000002425 crystallisation Methods 0.000 claims description 8
- 239000011777 magnesium Substances 0.000 claims description 8
- 229910052749 magnesium Inorganic materials 0.000 claims description 8
- 239000011575 calcium Substances 0.000 claims description 7
- 238000005342 ion exchange Methods 0.000 claims description 7
- 150000001768 cations Chemical class 0.000 claims description 6
- GLXDVVHUTZTUQK-UHFFFAOYSA-M lithium hydroxide monohydrate Substances [Li+].O.[OH-] GLXDVVHUTZTUQK-UHFFFAOYSA-M 0.000 claims description 6
- 239000002244 precipitate Substances 0.000 claims description 6
- OYPRJOBELJOOCE-UHFFFAOYSA-N Calcium Chemical compound [Ca] OYPRJOBELJOOCE-UHFFFAOYSA-N 0.000 claims description 5
- FYYHWMGAXLPEAU-UHFFFAOYSA-N Magnesium Chemical compound [Mg] FYYHWMGAXLPEAU-UHFFFAOYSA-N 0.000 claims description 5
- 229910052791 calcium Inorganic materials 0.000 claims description 5
- 239000001569 carbon dioxide Substances 0.000 claims description 5
- 229910002092 carbon dioxide Inorganic materials 0.000 claims description 5
- PQVSTLUFSYVLTO-UHFFFAOYSA-N ethyl n-ethoxycarbonylcarbamate Chemical compound CCOC(=O)NC(=O)OCC PQVSTLUFSYVLTO-UHFFFAOYSA-N 0.000 claims description 5
- 238000001640 fractional crystallisation Methods 0.000 claims description 5
- 229940040692 lithium hydroxide monohydrate Drugs 0.000 claims description 5
- 229910052708 sodium Inorganic materials 0.000 claims description 5
- 239000012267 brine Substances 0.000 claims description 4
- HPALAKNZSZLMCH-UHFFFAOYSA-M sodium;chloride;hydrate Chemical compound O.[Na+].[Cl-] HPALAKNZSZLMCH-UHFFFAOYSA-M 0.000 claims description 4
- 238000009835 boiling Methods 0.000 claims description 3
- 150000001805 chlorine compounds Chemical class 0.000 claims description 3
- 229910052748 manganese Inorganic materials 0.000 claims description 3
- 238000001556 precipitation Methods 0.000 claims description 3
- 238000005660 chlorination reaction Methods 0.000 claims description 2
- 150000004679 hydroxides Chemical class 0.000 claims description 2
- 239000000047 product Substances 0.000 description 13
- XEEYBQQBJWHFJM-UHFFFAOYSA-N Iron Chemical compound [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 description 9
- CDBYLPFSWZWCQE-UHFFFAOYSA-L Sodium Carbonate Chemical compound [Na+].[Na+].[O-]C([O-])=O CDBYLPFSWZWCQE-UHFFFAOYSA-L 0.000 description 6
- 229910003002 lithium salt Inorganic materials 0.000 description 5
- 159000000002 lithium salts Chemical class 0.000 description 5
- 239000007789 gas Substances 0.000 description 4
- 238000004519 manufacturing process Methods 0.000 description 4
- 230000008719 thickening Effects 0.000 description 4
- KZBUYRJDOAKODT-UHFFFAOYSA-N Chlorine Chemical compound ClCl KZBUYRJDOAKODT-UHFFFAOYSA-N 0.000 description 3
- ZAMOUSCENKQFHK-UHFFFAOYSA-N Chlorine atom Chemical compound [Cl] ZAMOUSCENKQFHK-UHFFFAOYSA-N 0.000 description 3
- 239000002253 acid Substances 0.000 description 3
- 238000001354 calcination Methods 0.000 description 3
- 239000000460 chlorine Substances 0.000 description 3
- 229910052801 chlorine Inorganic materials 0.000 description 3
- 238000011084 recovery Methods 0.000 description 3
- 239000002002 slurry Substances 0.000 description 3
- 239000011734 sodium Substances 0.000 description 3
- 229910000029 sodium carbonate Inorganic materials 0.000 description 3
- 235000017550 sodium carbonate Nutrition 0.000 description 3
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 description 2
- PNEYBMLMFCGWSK-UHFFFAOYSA-N aluminium oxide Inorganic materials [O-2].[O-2].[O-2].[Al+3].[Al+3] PNEYBMLMFCGWSK-UHFFFAOYSA-N 0.000 description 2
- 238000001035 drying Methods 0.000 description 2
- 239000012065 filter cake Substances 0.000 description 2
- 238000001914 filtration Methods 0.000 description 2
- 239000001257 hydrogen Substances 0.000 description 2
- 229910052739 hydrogen Inorganic materials 0.000 description 2
- 238000002386 leaching Methods 0.000 description 2
- 239000011572 manganese Substances 0.000 description 2
- 229910003455 mixed metal oxide Inorganic materials 0.000 description 2
- 230000004048 modification Effects 0.000 description 2
- 238000012986 modification Methods 0.000 description 2
- 238000007669 thermal treatment Methods 0.000 description 2
- BPQQTUXANYXVAA-UHFFFAOYSA-N Orthosilicate Chemical compound [O-][Si]([O-])([O-])[O-] BPQQTUXANYXVAA-UHFFFAOYSA-N 0.000 description 1
- 239000004411 aluminium Substances 0.000 description 1
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 description 1
- 229910000323 aluminium silicate Inorganic materials 0.000 description 1
- 239000006227 byproduct Substances 0.000 description 1
- AXCZMVOFGPJBDE-UHFFFAOYSA-L calcium dihydroxide Chemical compound [OH-].[OH-].[Ca+2] AXCZMVOFGPJBDE-UHFFFAOYSA-L 0.000 description 1
- 239000000920 calcium hydroxide Substances 0.000 description 1
- 235000011116 calcium hydroxide Nutrition 0.000 description 1
- 229910001861 calcium hydroxide Inorganic materials 0.000 description 1
- 238000001816 cooling Methods 0.000 description 1
- 239000000498 cooling water Substances 0.000 description 1
- HNPSIPDUKPIQMN-UHFFFAOYSA-N dioxosilane;oxo(oxoalumanyloxy)alumane Chemical compound O=[Si]=O.O=[Al]O[Al]=O HNPSIPDUKPIQMN-UHFFFAOYSA-N 0.000 description 1
- 239000012717 electrostatic precipitator Substances 0.000 description 1
- 230000007613 environmental effect Effects 0.000 description 1
- 230000007717 exclusion Effects 0.000 description 1
- 238000010438 heat treatment Methods 0.000 description 1
- 229910000041 hydrogen chloride Inorganic materials 0.000 description 1
- IXCSERBJSXMMFS-UHFFFAOYSA-N hydrogen chloride Substances Cl.Cl IXCSERBJSXMMFS-UHFFFAOYSA-N 0.000 description 1
- 239000012633 leachable Substances 0.000 description 1
- 239000012263 liquid product Substances 0.000 description 1
- 150000002641 lithium Chemical class 0.000 description 1
- 238000003801 milling Methods 0.000 description 1
- 239000012452 mother liquor Substances 0.000 description 1
- 239000002245 particle Substances 0.000 description 1
- 239000010970 precious metal Substances 0.000 description 1
- 150000003839 salts Chemical class 0.000 description 1
- 229920006395 saturated elastomer Polymers 0.000 description 1
- 239000007787 solid Substances 0.000 description 1
- 229910052642 spodumene Inorganic materials 0.000 description 1
- 239000002562 thickening agent Substances 0.000 description 1
- 238000010977 unit operation Methods 0.000 description 1
- 238000005406 washing Methods 0.000 description 1
- 239000002699 waste material Substances 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C25—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES; APPARATUS THEREFOR
- C25B—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES FOR THE PRODUCTION OF COMPOUNDS OR NON-METALS; APPARATUS THEREFOR
- C25B1/00—Electrolytic production of inorganic compounds or non-metals
- C25B1/01—Products
- C25B1/14—Alkali metal compounds
- C25B1/16—Hydroxides
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01D—COMPOUNDS OF ALKALI METALS, i.e. LITHIUM, SODIUM, POTASSIUM, RUBIDIUM, CAESIUM, OR FRANCIUM
- C01D15/00—Lithium compounds
- C01D15/02—Oxides; Hydroxides
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01D—COMPOUNDS OF ALKALI METALS, i.e. LITHIUM, SODIUM, POTASSIUM, RUBIDIUM, CAESIUM, OR FRANCIUM
- C01D15/00—Lithium compounds
- C01D15/04—Halides
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01D—COMPOUNDS OF ALKALI METALS, i.e. LITHIUM, SODIUM, POTASSIUM, RUBIDIUM, CAESIUM, OR FRANCIUM
- C01D15/00—Lithium compounds
- C01D15/08—Carbonates; Bicarbonates
-
- C—CHEMISTRY; METALLURGY
- C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
- C22B—PRODUCTION AND REFINING OF METALS; PRETREATMENT OF RAW MATERIALS
- C22B1/00—Preliminary treatment of ores or scrap
- C22B1/14—Agglomerating; Briquetting; Binding; Granulating
- C22B1/16—Sintering; Agglomerating
-
- C—CHEMISTRY; METALLURGY
- C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
- C22B—PRODUCTION AND REFINING OF METALS; PRETREATMENT OF RAW MATERIALS
- C22B26/00—Obtaining alkali, alkaline earth metals or magnesium
- C22B26/10—Obtaining alkali metals
- C22B26/12—Obtaining lithium
-
- C—CHEMISTRY; METALLURGY
- C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
- C22B—PRODUCTION AND REFINING OF METALS; PRETREATMENT OF RAW MATERIALS
- C22B3/00—Extraction of metal compounds from ores or concentrates by wet processes
- C22B3/04—Extraction of metal compounds from ores or concentrates by wet processes by leaching
- C22B3/06—Extraction of metal compounds from ores or concentrates by wet processes by leaching in inorganic acid solutions, e.g. with acids generated in situ; in inorganic salt solutions other than ammonium salt solutions
- C22B3/10—Hydrochloric acid, other halogenated acids or salts thereof
-
- C—CHEMISTRY; METALLURGY
- C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
- C22B—PRODUCTION AND REFINING OF METALS; PRETREATMENT OF RAW MATERIALS
- C22B3/00—Extraction of metal compounds from ores or concentrates by wet processes
- C22B3/20—Treatment or purification of solutions, e.g. obtained by leaching
- C22B3/42—Treatment or purification of solutions, e.g. obtained by leaching by ion-exchange extraction
-
- C—CHEMISTRY; METALLURGY
- C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
- C22B—PRODUCTION AND REFINING OF METALS; PRETREATMENT OF RAW MATERIALS
- C22B3/00—Extraction of metal compounds from ores or concentrates by wet processes
- C22B3/20—Treatment or purification of solutions, e.g. obtained by leaching
- C22B3/44—Treatment or purification of solutions, e.g. obtained by leaching by chemical processes
-
- C—CHEMISTRY; METALLURGY
- C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
- C22B—PRODUCTION AND REFINING OF METALS; PRETREATMENT OF RAW MATERIALS
- C22B4/00—Electrothermal treatment of ores or metallurgical products for obtaining metals or alloys
- C22B4/02—Light metals
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
- Y02P10/00—Technologies related to metal processing
- Y02P10/20—Recycling
Definitions
- the present invention relates to the treatment of lithium containing material.
- the present invention relates to a process for the treatment of a lithium containing material and the production of lithium hydroxide and lithium carbonate.
- the process utilising the electrolysis of a lithium chloride solution obtained from either a spodumene ore or concentrate, or from brines.
- the process of the present invention is intended to provide a high purity or battery grade lithium hydroxide and lithium carbonate product.
- the process of the present invention may further provide a hydrochloric acid product. Still further, the process of the present invention, in one form, utilises precious metal containing mixed metal oxide (MMO) electrodes to heighten the efficiency of an electrochemical portion of the process.
- MMO mixed metal oxide
- Known processes for the production of lithium carbonate from lithium containing ores or concentrates typically utilise the thermal treatment of an alpha- spodumene ore or concentrate.
- This thermal treatment can be referred as decrepitation and transforms the alpha-spodumene to beta-spodumene which is in turn able to be solubilised by acid.
- the step in which the beta-spodumene is solubilised in acid takes place in a kiln and produces soluble lithium salt.
- the lithium salt is passed to one or more tanks in which the lithium salt is purified. Leached crude lithium salt is subsequently passed to a step in which the pH of the slurry is adjusted, whereby certain impurities, including iron and magnesium are intended to be precipitated.
- purified lithium salt is treated with soda ash to produce lithium carbonate.
- This lithium carbonate can be further treated with hydrated lime to produce lithium hydroxide.
- Processes for the production of lithium carbonate and lithium hydroxide from brines typically involves the use of evaporation ponds to increase the concentration of the salts contained therein before being passed to a series of steps aimed to reduce the impurities present.
- the process of the present invention has as one object thereof to overcome substantially one or more of the above mentioned problems associated with prior art processes, or to at least provide a useful alternative thereto.
- battery grade lithium carbonate refers to a product having a purity of about 99.5% or higher.
- battery grade lithium hydroxide refers to a product having a purity of about 99% or higher.
- step (iii) Passing the purified lithium chloride solution of step (ii) to an electrolysis step thereby producing a lithium hydroxide solution.
- the process solution of step (i) is prepared in the form of a pregnant leach solution.
- the pregnant leach solution is formed by passing a lithium containing material to a leach step in which the material is leached with hydrochloric acid.
- the impurity removal step (ii) further comprises a concentration step wherein the pregnant leach solution is concentrated to near saturation of lithium chloride.
- the lithium hydroxide solution produced in step (iii) may be thickened by evaporation of water to provide lithium hydroxide monohydrate crystals.
- the lithium hydroxide solution produced in step (iii) may be carbonated by passing compressed carbon dioxide through the solution, thereby producing a lithium carbonate precipitate.
- the lithium containing material is an alpha-spodumene ore or ore concentrate and the process further comprises a first step in which that alpha-spodumene ore or ore concentrate is calcined to produce beta-spodumene.
- the lithium containing material is a lithium containing brine.
- a first portion of the lithium hydroxide solution produced in step (iii) is thickened by evaporation/crystallisation to provide lithium hydroxide monohydrate crystals and a second portion thereof is carbonated by passing compressed carbon dioxide through the solution, thereby producing a lithium carbonate precipitate.
- the impurity removal steps of step (ii) include one or more of hyrdropyrolysis of Al and Fe chlorides, pH increase to precipitate hydroxides of Al, Fe, Mg and Mn, lithium carbonate precipitation for removal of Ca, and fractional crystalisation for the removal of Na and K.
- fractional crystallisation for the removal of Na and K is conducted immediately after the concentration step.
- the impurity removal steps preferably further comprises an ion exchange step.
- the ion exchange step removes substantially all calcium, magnesium and other multivalent cations remaining in the pregnant leach solution. Still preferably, such multivalent cations are removed to a level of less than about 10 ppm.
- water evaporated from the solution in evaporation/crystallisation is recompressed, combined with make-up steam and utilised in evaporation/crystallisation.
- the evaporation/crystallisation step preferably utilises a vacuum evaporative crystalliser.
- the beta-spodumene is cooled and milled prior to the leach step.
- the beta-spodumene is preferably milled to less than about 300 pm. Still preferably, the beta-spodumene is milled to a P 8 o of about 75 pm.
- the leach step is conducted at elevated temperature.
- the hydrochloric acid solution used in the leach step is preferably about 20% HCI w/w.
- the elevated temperature of the leach step is about the boiling point of the hydrochloric acid solution used in the leach step.
- the leach step is preferably conducted at atmospheric pressure.
- the leach step is conducted in a chlorination kiln at about 108°C over a residence time of about 6 to 10 hours.
- the residence time is about 8 hours.
- Figure 1 is a schematic flow-sheet depicting a process for the treatment of a lithium containing material in accordance with a first embodiment of the present invention in which the lithium containing material is an alpha- spodumene concentrate.
- FIG. 1 there is shown a process 10 for the treatment of a lithium containing material in accordance with a first embodiment of the present invention in which embodiment the lithium containing material is provided in the form of an alpha-spodumene concentrate.
- An alpha-spodumene concentrate 12 is passed to a calcining step in which the concentrate 12 is calcined in a calcining furnace 14 at a temperature of between about 1050°C to 1 100°C to convert the alpha-spodumene to leachable beta-spodumene.
- Off-gases from the calciner are directed through a cyclone (not shown) and an electrostatic precipitator (not shown) specified to comply with known environmental emissions limits.
- the resulting hot calcine is passed to a cooler 16 and indirectly cooled to about 80°C. It is then dry-milled to less than 300 pm, for example to a P 8 o of about 75 pm, in a mill, for example a closed circuit ball mill 18.
- the milled beta-spodumene is mixed with at least a 40 to 300% stoichiometric excess of 20% hydrochloric acid w/w 20 in a slurrying step.
- the slurrying step feeds a leach step, for example a leach circuit 22, comprising a first leach stage 24 and a second leach stage 26.
- the leach step is conducted at about 108°C, being the boiling point of the hydrochloric acid leach solution added in the slurrying step, for a period of about 6 to 12 hours, for example about 8 hours, in continuous leach tanks.
- a pulp density of about 40% is used in the leach circuit 22 to maximise the leach concentration and to ensure that the solubility limit of lithium chloride during leaching is not exceeded.
- Off-gases are cleaned in a wet scrubber (not shown).
- the leach step 22 produces a residue slurry and a process solution, for example a pregnant leach solution.
- the lithium and the aluminosilicate in the beta-spodumene leaches into solution with other impurities to give a sub-saturated concentration of lithium chloride in the pregnant leach liquor.
- the pregnant leach solution from the leach circuit 22 is passed to a thickening circuit 28, preferably comprising two stages 28a and 28b aligned with the stages 24 and 26 of the leach circuit 22.
- An overflow from the thickening circuit 28 is directed to a pyrohydrolysis step 30, operating at about 300oC, and in which chlorides of Al and Fe present in the pregnant leach solution are converted into their respective insoluble oxides 32. Any residual HCI is also recovered in an HCL removal step 34.
- impurity removal steps 36 further include a pH modification step 38 through the addition of LiOH 40 to raise the pH to about 9.
- the product of step 38 is passed to a belt filter 42 from which Al, Fe, Mn and Mg containing precipitates are recovered.
- the impurity removal steps 36 further include a calcium precipitation step 44 with the addition of either sodium carbonate (soda ash) or lithium carbonate 46, producing a calcium containing precipitate 48 from a further belt filter 50.
- a thickener underflow product 52 of the second thickening step 28b is passed to a drying step 54 before passing to waste 56 and subsequent disposal 58.
- the liquid product of the belt filter 50 being largely LiCI solution, is passed to a concentration step 60 and in turn to a fractional crystallisation step 62.
- the LiCI solution is concentrated to near saturation point, for example 35 to 40% LiCI w/w, and is cooled to a sub zero temperature.
- Na and K impurities 64 are largely removed, as NaCI and KCI crystals, respectively, by filtration.
- the lithium chloride solution is passed through an ion exchange step 66, comprising an Ion Exchange (IX) column 68 by which substantially all of any residual calcium, magnesium and other multivalent cations are removed to a level of less than about 10ppm, for example 1 ppm.
- IX Ion Exchange
- the further purified lithium chloride solution is then heated to 90°C and pumped to an electrolysis step 70 comprising a number of electrolysers, for example 6 to 20 electrolysers, in which lithium chloride and water are consumed to produce lithium hydroxide, chlorine and hydrogen.
- the weak or depleted lithium chloride solution contains dissolved chlorine gas.
- the dissolved chlorine is removed in two stages. In a first stage hydrochloric acid is added to the lithium chloride solution to reduce the pH to ⁇ 5 which forces some of the chlorine gas out of solution. The remaining dissolved chlorine gas is then removed by air stripping the solution (not shown).
- Chlorine and hydrogen produced as by-products are combined to produce HCI acid which is used in the slurrying step and leaching circuit 22.
- the lithium hydroxide solution obtained from the electrolysis step 70 is passed firstly to a holding tank 72, from which it can either be (i) evaporated and crystallised to produce lithium hydroxide monohydrate crystals, or (ii) sent to carbonation step to convert into lithium carbonate, as clearly shown in Figure 1 .
- the lithium hydroxide in solution is crystallised in, for example, a vacuum evaporative crystalliser 80 (Oslo type) operating at a temperature of about 80°C and pressure of about 45 kPa(a).
- the residence time is about 60 minutes so as to achieve a coarse crystal product.
- the resulting water vapour is recompressed, combined with make-up steam and used as the heating medium for the crystalliser 80.
- Lithium hydroxide crystals are washed by cold water (not shown) achieving a wash efficiency of 99%.
- the resulting wash solution is recycled back to the leach circuit 22 as noted above.
- Solids from the centrifuge are fed to an indirect- fired kiln or dryer 82, operating at about 120°C, which dries the crystals.
- the crystal product being battery grade LiOH.H 2 O, is pneumatically conveyed to product bins 84, and cooled to 50°C in a jacketed screw conveyer 86 as it is conveyed ultimately to bagging stations (not shown).
- lithium carbonate may be produced by carbonation of lithium hydroxide solution by passing compressed carbon dioxide gas 88 though the solution of lithium hydroxide in a carbonation vessel 90 in which lithium carbonate is precipitated.
- This slurry is fed to a washer/centrifuge 92 by way of a filter 94, after which wash water is recycled with any remaining lithium hydroxide solution or mother liquor to electrolysis 70.
- Wet lithium carbonate crystals are fed to a dryer 96 in which hot air is used to dry the crystals. Medium pressure air is used to heat the air.
- After drying the battery grade lithium carbonate may be micronized to a particle size requested by a customer prior to passing to storage bins 98 and subsequent bagging (not shown).
- Condensate throughout the process is used as make-up water for hot process water, cold process water and cooling water. As the process does not return condensate there is an overall positive water balance and about 1/10 th of the process water is discharged to a sewerage system (not shown).
- tantalite and alumina may also be recovered using the process of the present invention.
- the filter cake from the thickening step may be discharged to a tantalite recovery plant (not shown). Discharge from the tantalite recovery plant may be fed onto a belt filter to remove water, which is returned to the tantalite recovery plant.
- the filter does not use washing and has a filtration are of 19 m 2 .
- the filter cake from the belt filter is dried in a direct-fired kiln.
- the dry alumina silicate is cooled to 50°C in a jacketed screw conveyor and then pneumatically conveyed to a storage bin prior to dispatch.
- the lithium containing material may be provided in the form of a lithium containing brine.
- Brines do not require the calcining, cooling, milling and leach steps as described for the first embodiment of the present invention but it is envisaged that the remainder of the process will be substantially similar to that of the first embodiment described above.
- the process of the present invention provides a process by which a high purity or battery grade lithium hydroxide and lithium carbonate products may be obtained from an alpha-spodumene ore or concentrate, or from a lithium containing brine, whilst also allowing the production of a hydrogen chloride gas product.
- the leach circuit 22 may comprise only a single leach stage/operation without departing from the scope of the present invention.
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- Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Organic Chemistry (AREA)
- Metallurgy (AREA)
- Inorganic Chemistry (AREA)
- General Life Sciences & Earth Sciences (AREA)
- Geology (AREA)
- Manufacturing & Machinery (AREA)
- Mechanical Engineering (AREA)
- Environmental & Geological Engineering (AREA)
- Life Sciences & Earth Sciences (AREA)
- Geochemistry & Mineralogy (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Electrochemistry (AREA)
- General Chemical & Material Sciences (AREA)
- Manufacture And Refinement Of Metals (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
- Electrolytic Production Of Non-Metals, Compounds, Apparatuses Therefor (AREA)
Abstract
Description
Claims
Priority Applications (5)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
US14/344,632 US20150152523A1 (en) | 2012-08-13 | 2013-08-01 | Processing of lithium containing material |
CA2851786A CA2851786C (en) | 2012-08-13 | 2013-08-01 | Processing of lithium containing material |
CN201380003136.1A CN104271781A (en) | 2012-08-13 | 2013-08-01 | Processing of lithium containing material |
KR1020157006360A KR101857458B1 (en) | 2012-08-13 | 2013-08-01 | Processing of Lithium Containing Material |
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JP (1) | JP6275138B2 (en) |
KR (1) | KR101857458B1 (en) |
CN (2) | CN111519042A (en) |
AU (1) | AU2013201833B2 (en) |
CA (1) | CA2851786C (en) |
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AU2013201833A1 (en) | 2014-02-27 |
CN104271781A (en) | 2015-01-07 |
JP6275138B2 (en) | 2018-02-07 |
CN111519042A (en) | 2020-08-11 |
KR20150041661A (en) | 2015-04-16 |
AU2013201833B2 (en) | 2014-07-17 |
MY163075A (en) | 2017-08-15 |
CL2014001656A1 (en) | 2014-10-10 |
CA2851786C (en) | 2016-04-12 |
JP2015531826A (en) | 2015-11-05 |
US20150152523A1 (en) | 2015-06-04 |
CA2851786A1 (en) | 2014-02-20 |
KR101857458B1 (en) | 2018-05-14 |
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