WO2013190235A3 - Vitrocéramiques de chalcogénures à propriétés photoélectriques et leur procédé de fabrication - Google Patents

Vitrocéramiques de chalcogénures à propriétés photoélectriques et leur procédé de fabrication Download PDF

Info

Publication number
WO2013190235A3
WO2013190235A3 PCT/FR2013/051432 FR2013051432W WO2013190235A3 WO 2013190235 A3 WO2013190235 A3 WO 2013190235A3 FR 2013051432 W FR2013051432 W FR 2013051432W WO 2013190235 A3 WO2013190235 A3 WO 2013190235A3
Authority
WO
WIPO (PCT)
Prior art keywords
crystalline phase
chalcogenide glass
ceramics
manufacture
photoelectric properties
Prior art date
Application number
PCT/FR2013/051432
Other languages
English (en)
Other versions
WO2013190235A2 (fr
Inventor
Xianghua Zhang
Laurent Calvez
Hong Li MA
Xianping FAN
Yang Xu
Alain Lafond
Original Assignee
Centre National De La Recherche Scientifique
Universite De Nantes
Universite De Rennes 1
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Centre National De La Recherche Scientifique, Universite De Nantes, Universite De Rennes 1 filed Critical Centre National De La Recherche Scientifique
Priority to EP13744598.7A priority Critical patent/EP2864265A2/fr
Priority to US14/409,635 priority patent/US9492815B2/en
Priority to CN201380044154.4A priority patent/CN104755440B/zh
Publication of WO2013190235A2 publication Critical patent/WO2013190235A2/fr
Publication of WO2013190235A3 publication Critical patent/WO2013190235A3/fr

Links

Classifications

    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J27/00—Catalysts comprising the elements or compounds of halogens, sulfur, selenium, tellurium, phosphorus or nitrogen; Catalysts comprising carbon compounds
    • B01J27/06—Halogens; Compounds thereof
    • B01J27/08—Halides
    • B01J27/122—Halides of copper
    • C—CHEMISTRY; METALLURGY
    • C03—GLASS; MINERAL OR SLAG WOOL
    • C03C—CHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
    • C03C4/00—Compositions for glass with special properties
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J19/00—Chemical, physical or physico-chemical processes in general; Their relevant apparatus
    • B01J19/08—Processes employing the direct application of electric or wave energy, or particle radiation; Apparatus therefor
    • B01J19/12—Processes employing the direct application of electric or wave energy, or particle radiation; Apparatus therefor employing electromagnetic waves
    • B01J19/122—Incoherent waves
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J27/00—Catalysts comprising the elements or compounds of halogens, sulfur, selenium, tellurium, phosphorus or nitrogen; Catalysts comprising carbon compounds
    • B01J27/02—Sulfur, selenium or tellurium; Compounds thereof
    • B01J27/057—Selenium or tellurium; Compounds thereof
    • B01J27/0573—Selenium; Compounds thereof
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J35/00—Catalysts, in general, characterised by their form or physical properties
    • B01J35/30—Catalysts, in general, characterised by their form or physical properties characterised by their physical properties
    • B01J35/39—Photocatalytic properties
    • C—CHEMISTRY; METALLURGY
    • C03—GLASS; MINERAL OR SLAG WOOL
    • C03B—MANUFACTURE, SHAPING, OR SUPPLEMENTARY PROCESSES
    • C03B32/00—Thermal after-treatment of glass products not provided for in groups C03B19/00, C03B25/00 - C03B31/00 or C03B37/00, e.g. crystallisation, eliminating gas inclusions or other impurities; Hot-pressing vitrified, non-porous, shaped glass products
    • C03B32/02—Thermal crystallisation, e.g. for crystallising glass bodies into glass-ceramic articles
    • C—CHEMISTRY; METALLURGY
    • C03—GLASS; MINERAL OR SLAG WOOL
    • C03C—CHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
    • C03C10/00—Devitrified glass ceramics, i.e. glass ceramics having a crystalline phase dispersed in a glassy phase and constituting at least 50% by weight of the total composition
    • C—CHEMISTRY; METALLURGY
    • C03—GLASS; MINERAL OR SLAG WOOL
    • C03C—CHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
    • C03C10/00—Devitrified glass ceramics, i.e. glass ceramics having a crystalline phase dispersed in a glassy phase and constituting at least 50% by weight of the total composition
    • C03C10/16—Halogen containing crystalline phase
    • C—CHEMISTRY; METALLURGY
    • C03—GLASS; MINERAL OR SLAG WOOL
    • C03C—CHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
    • C03C15/00—Surface treatment of glass, not in the form of fibres or filaments, by etching
    • C—CHEMISTRY; METALLURGY
    • C03—GLASS; MINERAL OR SLAG WOOL
    • C03C—CHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
    • C03C19/00—Surface treatment of glass, not in the form of fibres or filaments, by mechanical means
    • C—CHEMISTRY; METALLURGY
    • C03—GLASS; MINERAL OR SLAG WOOL
    • C03C—CHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
    • C03C3/00—Glass compositions
    • C03C3/32—Non-oxide glass compositions, e.g. binary or ternary halides, sulfides or nitrides of germanium, selenium or tellurium
    • C03C3/321—Chalcogenide glasses, e.g. containing S, Se, Te
    • C03C3/323—Chalcogenide glasses, e.g. containing S, Se, Te containing halogen, e.g. chalcohalide glasses
    • C—CHEMISTRY; METALLURGY
    • C03—GLASS; MINERAL OR SLAG WOOL
    • C03C—CHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
    • C03C4/00—Compositions for glass with special properties
    • C03C4/14—Compositions for glass with special properties for electro-conductive glass
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01B—CABLES; CONDUCTORS; INSULATORS; SELECTION OF MATERIALS FOR THEIR CONDUCTIVE, INSULATING OR DIELECTRIC PROPERTIES
    • H01B1/00—Conductors or conductive bodies characterised by the conductive materials; Selection of materials as conductors
    • H01B1/06—Conductors or conductive bodies characterised by the conductive materials; Selection of materials as conductors mainly consisting of other non-metallic substances
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01L—SEMICONDUCTOR DEVICES NOT COVERED BY CLASS H10
    • H01L31/00—Semiconductor devices sensitive to infrared radiation, light, electromagnetic radiation of shorter wavelength or corpuscular radiation and specially adapted either for the conversion of the energy of such radiation into electrical energy or for the control of electrical energy by such radiation; Processes or apparatus specially adapted for the manufacture or treatment thereof or of parts thereof; Details thereof
    • H01L31/02—Details
    • H01L31/0224—Electrodes
    • H01L31/022466—Electrodes made of transparent conductive layers, e.g. TCO, ITO layers
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2219/00—Chemical, physical or physico-chemical processes in general; Their relevant apparatus
    • B01J2219/08—Processes employing the direct application of electric or wave energy, or particle radiation; Apparatus therefor
    • B01J2219/12—Processes employing electromagnetic waves
    • B01J2219/1203—Incoherent waves
    • C—CHEMISTRY; METALLURGY
    • C03—GLASS; MINERAL OR SLAG WOOL
    • C03C—CHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
    • C03C2204/00—Glasses, glazes or enamels with special properties

Landscapes

  • Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Organic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Materials Engineering (AREA)
  • General Chemical & Material Sciences (AREA)
  • Geochemistry & Mineralogy (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Ceramic Engineering (AREA)
  • Crystallography & Structural Chemistry (AREA)
  • Physics & Mathematics (AREA)
  • Dispersion Chemistry (AREA)
  • Electromagnetism (AREA)
  • Computer Hardware Design (AREA)
  • Microelectronics & Electronic Packaging (AREA)
  • Power Engineering (AREA)
  • Mechanical Engineering (AREA)
  • General Physics & Mathematics (AREA)
  • Condensed Matter Physics & Semiconductors (AREA)
  • Health & Medical Sciences (AREA)
  • General Health & Medical Sciences (AREA)
  • Toxicology (AREA)
  • Thermal Sciences (AREA)
  • Glass Compositions (AREA)

Abstract

Vitrocéramique de chalcogénure, ayant par exemple la composition suivante GeSe2-Sb2Se3–CuI, cette vitrocéramique comportant au moins une phase cristalline, caractérisée en ce que le taux de cristallisation et les dimensions d'au moins certains cristaux de la phase cristalline sont tels que ces cristaux sont sensiblement en contact les uns avec les autres de façon à ce que cette phase cristalline présente une conductivité électrique supérieure ou égale à 10-4s.cm-1 qui augmente sous éclairage du fait de la création d'un photo-courant au sein de la phase cristalline.
PCT/FR2013/051432 2012-06-20 2013-06-19 Vitrocéramiques de chalcogénures à propriétés photoélectriques et leur procédé de fabrication WO2013190235A2 (fr)

Priority Applications (3)

Application Number Priority Date Filing Date Title
EP13744598.7A EP2864265A2 (fr) 2012-06-20 2013-06-19 Vitrocéramiques de chalcogénures à propriétés photoélectriques et leur procédé de fabrication
US14/409,635 US9492815B2 (en) 2012-06-20 2013-06-19 Chalcogenide glass-ceramics with photoelectric properties and method for the manufacture thereof
CN201380044154.4A CN104755440B (zh) 2012-06-20 2013-06-19 具有光电性能的硫族化物玻璃-陶瓷及其制造方法

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
FR1255801 2012-06-20
FR1255801A FR2992310B1 (fr) 2012-06-20 2012-06-20 Vitroceramiques de chalcogenures a proprietes photoelectriques et leur procede de fabrication

Publications (2)

Publication Number Publication Date
WO2013190235A2 WO2013190235A2 (fr) 2013-12-27
WO2013190235A3 true WO2013190235A3 (fr) 2014-03-13

Family

ID=46889228

Family Applications (1)

Application Number Title Priority Date Filing Date
PCT/FR2013/051432 WO2013190235A2 (fr) 2012-06-20 2013-06-19 Vitrocéramiques de chalcogénures à propriétés photoélectriques et leur procédé de fabrication

Country Status (5)

Country Link
US (1) US9492815B2 (fr)
EP (1) EP2864265A2 (fr)
CN (1) CN104755440B (fr)
FR (1) FR2992310B1 (fr)
WO (1) WO2013190235A2 (fr)

Families Citing this family (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US10099957B2 (en) 2015-06-17 2018-10-16 Schott Corporation Infrared transmission chalcogenide glasses
CN108290773B (zh) * 2015-11-20 2020-10-16 Ａｇｃ株式会社 光学玻璃
CN109786485A (zh) * 2017-11-15 2019-05-21 张家港市六福新材料科技有限公司 半导体材料及其制备方法、太阳能电池
CN109999846B (zh) * 2019-04-02 2020-08-11 浙江大学 一种少层GeTe纳米片@TiO2纳米棒复合光阳极及制备方法
CN110981205A (zh) * 2019-12-25 2020-04-10 中建材蚌埠玻璃工业设计研究院有限公司 一种处理放射性铯污染土壤用微晶玻璃的制备方法

Citations (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
FR2857354A1 (fr) * 2003-07-07 2005-01-14 Centre Nat Rech Scient Composition vitreuses, de type vitroceramique, transparentes dans l'infrarouge
FR2967524A1 (fr) * 2010-11-16 2012-05-18 Peugeot Citroen Automobiles Sa Dispositif thermoélectrique et procédé d'utilisation du dispositif dans un véhicule

Family Cites Families (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
FR2831467B1 (fr) 2001-10-29 2003-12-19 Sicat Photocatalyseur et procede de purification d'effluents gazeux par photocatalyse d'oxydation
CN101215092B (zh) * 2008-01-10 2012-04-04 武汉理工大学 具有倍频功能的透红外硫系卤化物玻璃陶瓷及其制备方法

Patent Citations (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
FR2857354A1 (fr) * 2003-07-07 2005-01-14 Centre Nat Rech Scient Composition vitreuses, de type vitroceramique, transparentes dans l'infrarouge
FR2967524A1 (fr) * 2010-11-16 2012-05-18 Peugeot Citroen Automobiles Sa Dispositif thermoélectrique et procédé d'utilisation du dispositif dans un véhicule

Non-Patent Citations (3)

* Cited by examiner, † Cited by third party
Title
CALVEZ ET AL: "Glasses and glass-ceramics based on GeSe2-Sb2Se3 and halides for far infrared transmission", JOURNAL OF NON-CRYSTALLINE SOLIDS, NORTH-HOLLAND PHYSICS PUBLISHING. AMSTERDAM, NL, vol. 354, no. 12-13, 26 November 2007 (2007-11-26), pages 1123 - 1127, XP022438689, ISSN: 0022-3093, DOI: 10.1016/J.SSI.2007.11.039 *
GRUDINKIN S A ET AL: "Crystallization ability and optical and electrical properties of Ge(Se-Te)and Ge(Se-Te)chalcogenide glassy semiconductors", SEMICONDUCTORS, NAUKA/INTERPERIODICA, MO, vol. 45, no. 11, 11 November 2011 (2011-11-11), pages 1462 - 1466, XP019974954, ISSN: 1090-6479, DOI: 10.1134/S106378261111011X *
LAURENT CALVEZ: "Nouveaux verres et vitrocéramiques transparents dans l'infrarouge pour l'imagerie thermique", 23 February 2007 (2007-02-23), XP055091446, Retrieved from the Internet <URL:http://tel.archives-ouvertes.fr/docs/00/13/32/11/PDF/THESE.pdf> [retrieved on 20131204] *

Also Published As

Publication number Publication date
EP2864265A2 (fr) 2015-04-29
CN104755440B (zh) 2018-07-27
WO2013190235A2 (fr) 2013-12-27
FR2992310B1 (fr) 2014-07-25
US9492815B2 (en) 2016-11-15
FR2992310A1 (fr) 2013-12-27
CN104755440A (zh) 2015-07-01
US20150196898A1 (en) 2015-07-16

Similar Documents

Publication Publication Date Title
WO2013190235A3 (fr) Vitrocéramiques de chalcogénures à propriétés photoélectriques et leur procédé de fabrication
EP3387348A4 (fr) Matériau isolant doté d&#39;un constituant issu de ressources renouvelables
KR20180084762A (ko) 비정질 투명 도전성 필름, 그리고, 결정질 투명 도전성 필름 및 그 제조 방법
EP3140106A4 (fr) Filaments de poly(acide lactique) hautement cristallin pour la fabrication additive basée sur l&#39;extrusion de matière
EP3053956A4 (fr) Matériau de gaine de câble totalement exempt d&#39;halogènes pour dispositifs photovoltaïques en epcv réticulé par exposition à un rayonnement à 125 °c et procédé pour sa préparation
HK1185195A1 (zh) 基於使用鏈路利用作為到平局打破機制中的反饋的 的自動化業務工程
EP2998969A4 (fr) Composition pour former une électrode de cellule solaire et électrode fabriquée à partir de celle-ci
WO2015085275A3 (fr) Fabrication de réseaux structurés
EP3026674A4 (fr) Composition pour former une électrode de cellule solaire et électrode fabriquée à partir de la composition
EP3314659A4 (fr) Structures hétéroépitaxiales à matériau d&#39;interface de substrat stable à haute température
EP3755515A4 (fr) Composition polymère thermiquement conductrice
EP3214054A4 (fr) Procédé de production de verre de sulfure et d&#39;électrolyte solide cristallin, électrolyte solide cristallin, verre de sulfure et batterie à l&#39;état solide
EP3113627A4 (fr) Composition de succédané de sucre à faible teneur en calories et procédés de fabrication de celle-ci
EP3060533A4 (fr) Substrats en vitrocéramique pour la croissance de graphène
EP3025374A4 (fr) Pâte pour contact de dos enrichie en tellure et contenant du cuivre
WO2015191955A3 (fr) Pâte à base d&#39;aluminium et d&#39;étain et son utilisation dans la fabrication de conducteurs électriques soudables
EP3362002A4 (fr) Liaison à quatre barres à rapport stable pour la collecte d&#39;énergie de flexion du genou
EP3130021A4 (fr) Compositions d&#39;électrolyte cristallin solides-souples
EP3359885A4 (fr) Capteur solaire à conversion thermique
WO2013089843A3 (fr) Matériaux semi-conducteurs photovoltaïques
EP3111146A4 (fr) Récepteurs à cavité perfectionnés pour miroirs cylindro-paraboliques
EP3387349A4 (fr) Matériau isolant doté d&#39;un constituant issu de ressources renouvelables
PH12017501543A1 (en) Thermal switch based on polymer compound
PT3321973T (pt) Célula solar cristalina com uma camada transparente e condutora entre os contactos de lado dianteiro e procedimento para fabrico de uma tal célula solar
WO2012150287A3 (fr) Composition polymère pour dispositifs électriques

Legal Events

Date Code Title Description
121 Ep: the epo has been informed by wipo that ep was designated in this application

Ref document number: 13744598

Country of ref document: EP

Kind code of ref document: A2

WWE Wipo information: entry into national phase

Ref document number: 2013744598

Country of ref document: EP

WWE Wipo information: entry into national phase

Ref document number: 14409635

Country of ref document: US