WO2013179218A1 - Peinture résistante au feu pour application à une surface à l'extérieur ou à l'intérieur, articles manufacturés la comprenant, appareil pour sa fabrication et procédé pour sa fabrication - Google Patents

Peinture résistante au feu pour application à une surface à l'extérieur ou à l'intérieur, articles manufacturés la comprenant, appareil pour sa fabrication et procédé pour sa fabrication Download PDF

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Publication number
WO2013179218A1
WO2013179218A1 PCT/IB2013/054397 IB2013054397W WO2013179218A1 WO 2013179218 A1 WO2013179218 A1 WO 2013179218A1 IB 2013054397 W IB2013054397 W IB 2013054397W WO 2013179218 A1 WO2013179218 A1 WO 2013179218A1
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Prior art keywords
composition
agent
optionally
physical object
oxide
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PCT/IB2013/054397
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English (en)
Inventor
Joseph Labock
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L-M-J Nation Security Llc
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Application filed by L-M-J Nation Security Llc filed Critical L-M-J Nation Security Llc
Publication of WO2013179218A1 publication Critical patent/WO2013179218A1/fr
Priority to US14/534,338 priority Critical patent/US10000663B1/en

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    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D5/00—Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes

Definitions

  • the present invention relates generally to fire resistant paint, articles of manufacture, an apparatus for manufacture and a process for manufacture thereof, and more specifically to fire resistant paint featuring a combination of chemical and physical components.
  • US Patent No. 7638572 to Horley et al teaches a fire retardant coating that features a film forming polymer, an inorganic fire retardant material such as huntite, hydromagnesite, aluminum trihydroxide or magnesium hydroxide, and a metal stannate or metal hydroxyl stannate.
  • an inorganic fire retardant material such as huntite, hydromagnesite, aluminum trihydroxide or magnesium hydroxide
  • a metal stannate or metal hydroxyl stannate a simple coating which provides limited fire retardant ability.
  • the present invention relates, in at least some embodiments, to a heat resistant coating suitable for an indoor surface or for an outdoor surface.
  • outer it is meant that the surface is exposed to one or more of precipitation, sunlight, wind and severe weather.
  • severe weather includes, without limitation, storms, thunderstorms, lightning storms, hurricanes, tornadoes, floods, snow, ice storms and hail.
  • the surface is not exposed to one or more of precipitation, direct sunlight, wind or severe weather. Instead, the surface is at least partially contained within an enclosure and more preferably is at least protected by a roof.
  • fire resistant it is also meant heat resistant; the terms are used interchangeably herein.
  • a fire resistant composition comprising an intumescent base material, wherein said intumescent base material further comprises a blowing agent and a foaming agent, wherein said foaming agent is present in an amount of 20% to 60% and wherein said foaming agent comprises ammonium phosphate, and wherein said blowing agent comprises melamine; a flame spread reduction material, wherein said flame spread reduction material comprises sodium silicate (Na2 Si03); an oxygen reduction agent wherein said oxygen reduction agent comprises urea formaldehyde, a thermal transmission reduction agent comprising zirconium oxide and a plurality of refractory fibers wherein said fibers comprise physical fibers comprising titanium oxide ( ⁇ 02), the composition further comprising a charring agent, said charring agent comprising dipentaerythritol (DPE); a mechanical enhancer, said mechanical enhancer comprising a ceramic oxide; a stabilizer, said stabilizer comprising one or both of paraffin or erythritol
  • composition further comprises alumina trihydrate.
  • said charring agent further comprises one or more of chlorinated paraffin, pentaerythritol, polyurethane, resorcinol, inositol, polyalcohols, sorbitol, or dextrin, or a combination thereof.
  • said blowing agent further comprises one or more of urea, dicyandiamide, guanidine, or glycine, or a combination thereof.
  • said intumescent base material further comprises a binding agent.
  • said binding agent comprises calcium carbonate or butoxyethoxy ethanol.
  • said intumescent base material further comprises a solvent.
  • said solvent comprises water, oil, toluene, or propylene glycol.
  • said intumescent base material further comprises a pigment.
  • said pigment comprises one or more of titanium oxide, lamp black or oxalates, or a combination thereof.
  • said flame spread reduction material further comprises one or more of ammonium orthophosphate, an aluminum oxide, silicon dioxide, ferric oxide, sodium oxide, beryllium oxide (BeO), manganese oxide (MNO), tantalum oxide (Ta02), , calcium silicate (Ca2 Si04), antimony oxide or potassium metaphosphate.
  • ammonium orthophosphate an aluminum oxide, silicon dioxide, ferric oxide, sodium oxide, beryllium oxide (BeO), manganese oxide (MNO), tantalum oxide (Ta02), calcium silicate (Ca2 Si04), antimony oxide or potassium metaphosphate.
  • said aluminum oxide comprises aluminum oxide trihydrate (A12 03.3H20).
  • said fibers have a size of from 1 micron to 100 millimeter.
  • said fibers have a size of from 10 microns to 10 millimeter.
  • said fibers have a size of from 100 microns to 1 millimeter.
  • the intumescent base material is present in an amount of 20 to 60 percent of the total weight of the composition.
  • the flame spread reduction material is present in an amount of 2% to 12%.
  • oxygen reduction agent is present in an amount of 1% to 5%.
  • thermal transmission reduction agent is present in an amount of
  • the refractory fibers are present in an amount of 8% to 18%.
  • said stabilizer is present in an amount of 6% to 12%.
  • said mechanical enhancer comprises one or more of calcium carbonate (CaC03), calcium silicate, and sodium silicate.
  • said mechanical enhancer mechanical enhancer is present in an amount of 1% to 4%.
  • said elasticity agent is present in an amount of up to 20%.
  • the composition further comprises a water-resistance agent and an efflorescence reduction agent.
  • a water-resistance agent and said efflorescence reduction agent are the same agent and wherein said combined agent is selected from the group consisting of carboxymethyl cellulose, ethyl hydroxyethyl cellulose ammonium polyphosphate (NH4 H2 P04), melamine- formaldehyde coatings, acrylics, silicones, diethylene glycol, and monoethyletheracetate.
  • said combined agent is present in an amount of 4% to 8%.
  • composition further comprises a lead composition.
  • lead composition comprises a lead powder.
  • said lead powder is a mixture of lead and a lead oxide.
  • said lead composition further comprises a binder selected from the group consisting of a polymer, water glass, an emulsion of a plastic, an aqueous binder or polyvinylalcohol, such that the powder forms a solid composition.
  • a binder selected from the group consisting of a polymer, water glass, an emulsion of a plastic, an aqueous binder or polyvinylalcohol, such that the powder forms a solid composition.
  • said polymer comprises polytetrafluoroethylene (PTFE) or a poly saccharide.
  • composition further comprises an aerogel.
  • composition further comprises a nonwoven material, comprising a silica material, coated or impregnated with said aerogel.
  • a structure or physical object comprising a layer of said fire resistant base composition as described herein.
  • each composition is applied in a thickness in a range of from about 0.050 inch to about 0.50 inch.
  • the structure comprises an additional layer applied above the intumescent base.
  • said additional layer comprises silicone.
  • said additional layer comprises one component silicone.
  • said silicone is in the form of a rubber or resin.
  • said silicone comprises a siloxane polymer or a silica polymer.
  • said silicone comprises a derivatized silica polymer or a derivatized silicone.
  • said derivatized silica polymer or said derivatized silicone is derivatized with one or more hydrophobic groups.
  • hydrophobic groups comprise one or more of methyl groups and silyl groups.
  • said methyl groups are present such that the siloxane polymer comprises a polymethylsiloxane, a polydimethylsiloxane, or a polytrimethylsiloxane.
  • said silyl groups comprise trimethylsilyl and/or dimethylsilyl and/or monomethylsilyl groups.
  • the siloxane polymer comprises a polydimethylsiloxane and is present in a composition which further comprises amorphous silica and a crosslinker.
  • said base composition does not comprise a lead composition and wherein said lead composition is applied as a separate layer of material after said base composition.
  • said lead composition is in the form of lead loaded plastic.
  • said lead loaded plastic comprises lead powder incorporated into a plasticizer.
  • the present invention in various embodiments as described herein, is preferably applied to a physical structure so as to form a structure comprising a plurality of layers of composite material which integrate to provide predetermined load-behavior characteristics such as lower peak heat release rates, lower heat released per unit time, higher temperature gradient, low flame spread, high ignition delay, low peak heat release, low total heat release, high thermal stability, heat sink effect, a reduced amount of smoke and heat reflective property.
  • Fig. 1 shows an exemplary embodiment in which the apparatus operates on material that is not silicone-coated or that is already silicone-coated before the process of application of the coatings according to various embodiments of the present invention starts;
  • Fig. 2 shows an exemplary embodiment in which the apparatus performs silicone-coating of the material as an integral part of the coating process.
  • the present invention relates, in at least some embodiments, to a heat resistant coating suitable for an indoor surface or an outdoor surface.
  • a heat resistant composition which preferably further comprises one or more ingredients suitable for outdoor exposure.
  • ingredients may optionally comprise a water- resistance agent and an efflorescence reduction agent, which may optionally be the same agent.
  • the agent is optionally and preferably selected from the group consisting of carboxymethyl cellulose, ethyl hydroxyethyl cellulose, ammonium polyphosphate (NH4 H2 P04), melamine- formaldehyde coatings, and other low solubility coatings and acrylics, silicones, diethylene glycol, and monoethyletheracetate.
  • the water-resistance agent is optionally and preferably present in an amount of 4% to 8%.
  • ingredients include biocidal agents, particularly those against moss, algae, lichen, mold and fungi, and other ingredients.
  • biocidal agents may optionally comprise elementary silver, silver salts, chlorinated materials and so forth.
  • the composition may optionally be in the form of a coating.
  • the coating may optionally be in the form of a paint, in which case the composition preferably further comprises one or more pigments and/or dyes suitable for outdoor use.
  • pigments are titanium dioxide, iron oxide, magnesium oxide, zinc chromate, carbon black and barium sulphate.
  • Dyes include, for example, para red, thioindigo, antrachinon, phthalocyanine blue and azo dyes.
  • the pigment or dye may further optionally compromise a pigment extender, to improve coverage afforded by the paint.
  • the pigment extender may optionally include for example one or more of microcrystalline silica, nepheline syenite and/or metal fluoride; the metal fluoride may optionally include a silica coated metal fluoride.
  • the composition may optionally further comprise a latex base, such as a vinyl- acrylic, vinyl acetate-ethylene or vinyl-acetate emulsion for example; the latex base may also optionally comprise a polymer having interpolymerized units that comprise units derived from styrene, methyl styrene, vinyl, or combinations thereof and units derived from one or more acrylates, methacrylates, acrylonitrile, or combinations thereof.
  • a latex base such as a vinyl- acrylic, vinyl acetate-ethylene or vinyl-acetate emulsion
  • the latex base may also optionally comprise a polymer having interpolymerized units that comprise units derived from styrene, methyl styrene, vinyl, or combinations thereof and units derived from one or more acrylates, methacrylates, acrylonitrile, or combinations thereof.
  • the composition may optionally further comprise an enamel base, non-limiting examples of which include a chlorinated alkyd enamel base (for example from Sherwin Williams, USA) or a resin enamel base.
  • an enamel base non-limiting examples of which include a chlorinated alkyd enamel base (for example from Sherwin Williams, USA) or a resin enamel base.
  • composition may optionally further comprise a urethane base, for example in an aliphatic urethane base (for example from Sherwin Williams, USA), preferably used as an overcoating layer to a paint layer.
  • a urethane base for example in an aliphatic urethane base (for example from Sherwin Williams, USA), preferably used as an overcoating layer to a paint layer.
  • composition may also optionally be used to impregnate a material that is to be exposed to the outdoors, in addition to or in place of its use as a coating.
  • the outdoor surface may optionally comprise, without limitation, one or more of a wall or roof of a building or other enclosure (whether partial or complete); a road surface or other surface on which vehicles or pedestrians travel; or an outer surface of a vehicle, including without limitation wheeled vehicles, flying vehicles and marine vehicles.
  • a heat resistant composition according to various embodiments, which preferably further comprises one or more ingredients suitable for indoor exposure.
  • the composition features low or no amounts of volatile organic compounds (VOCs).
  • VOCs volatile organic compounds
  • the composition may optionally be in the form of a coating.
  • the coating may optionally be in the form of a paint, in which case the composition preferably further comprises one or more pigments and/or dyes suitable for indoor use.
  • pigments are titanium dioxide, iron oxide, magnesium oxide, zinc chromate, carbon black and barium sulphate.
  • Dyes include, for example, para red, thioindigo, antrachinon, phthalocyanine blue and azo dyes.
  • the pigment or dye may further optionally compromise a pigment extender, to improve coverage afforded by the paint.
  • the pigment extender may optionally include for example one or more of microcrystalline silica, nepheline syenite and/or metal fluoride; the metal fluoride may optionally include a silica coated metal fluoride.
  • the composition may optionally feature one or more ingredients for UV light curing and/or may optionally be in the form of a dry powder coating.
  • the composition may also optionally feature an aqueous base and/or a clay base that is suspended in water.
  • the composition may optionally further comprise a latex base, such as an acrylic, vinyl-acrylic, vinyl acetate-ethylene or vinyl-acetate emulsion for example; the latex base may also optionally comprise a polymer having interpolymerized units that comprise units derived from styrene, methyl styrene, vinyl, or combinations thereof and units derived from one or more acrylates, methacrylates, acrylonitrile, or combinations thereof.
  • the latex may also optionally feature one or more natural oils.
  • composition may also optionally be used to impregnate a material that is contained indoors, in addition to or in place of its use as a coating.
  • the indoor surface may optionally comprise, without limitation, one or more of an inner wall, within a building or other enclosure (whether partial or complete), including without limitation the underside of a roof; or an inner surface of a vehicle (ie - a surface contained within the vehicle), including without limitation wheeled vehicles, flying vehicles and marine vehicles.
  • a fire resistant composition comprising an intumescent base material; a flame spread reduction material comprising one or more of a zinc compound, a borate, a phosphate, a silicate or an oxide, and optionally and preferably further comprises alumina trihydrate; an oxygen reduction agent, a thermal transmission reduction agent and refractory fibers.
  • a base layer for being placed on a physical surface before the above fire resistant composition is applied comprising the intumescent base material of the fire resistant coating, and optionally one or more of mineral powder such as granite powder (sheet silicate mineral, iron pyrite), or a lead composition.
  • mineral powder such as granite powder (sheet silicate mineral, iron pyrite), or a lead composition.
  • an additional layer is present below the fire resistant composition, which is optionally and preferably applied above the fire resistant base composition but below the fire resistant composition.
  • the additional layer preferably comprises silicone and more preferably one component silicone.
  • the silicone is optionally in the form of a rubber or resin.
  • the silicone (polymerized siloxane) may optionally comprise any suitable siloxane polymer material.
  • a fire resistant composition as described herein optionally further comprising inorganic fibers.
  • the inorganic fibers may optionally comprise silica or PVA (polyvinyl alcohol), or a combination thereof.
  • the inorganic fibers may also optionally further comprise metals or other additives, for example for strengthening.
  • the inorganic fibers may optionally be provided in the form of a nonwoven fabric, which is optionally and preferably prepared through electrospinning.
  • a nonwoven fabric which is optionally and preferably prepared through electrospinning.
  • a fire resistant composition as described herein for either indoor or outdoor use, there is provided a fire resistant composition as described herein, optionally further comprising an aerogel.
  • An aerogel contains a gaseous phase, such as air, in place of a liquid phase.
  • An aerogel is derived from a wet gel in a process that replaces the entrained liquid phase with air. If the gel is formed from a water phase, the resulting semi-solid is called a hydrogel, and the water is exchanged with organic solvent prior to drying. If the gel is formed within an alcohol phase, the resulting semi-solid is called an alcogel, and can be dried directly.
  • Drying may optionally be performed according to a supercritical process, in which the temperature and pressure of the solvent phase inside of the gel structure are both increased beyond the critical point. This "supercritical" extraction condition lowers the surface tension between the liquid and the solid pore surfaces so that depressurization of the system at temperatures above the critical temperature leaves the pore structure filled with gas.
  • Aerogels as described herein optionally and preferably comprise silicas and silicate materials.
  • the silicate material comprises silicon alkoxides, such as silicon ethoxide derivatives, non-limiting examples of which include tetraethylorthosilicate (TEOS) and polydiethylsilicate (PDEOS).
  • suitable solvents include alcohols and supercritical carbon dioxide.
  • the surface of aerogels may optionally be modified with: silane coupling agents (alkyl, amine, sulfhydryl, carboxyl, formyl); enzymes, chelating agents and so forth.
  • silane coupling agents alkyl, amine, sulfhydryl, carboxyl, formyl
  • enzymes chelating agents and so forth.
  • the aerogel may optionally be provided in the form of a blanket or sheet, for example in combination with the previously described nonwoven fabric.
  • Non-limiting examples of aerogel products which are suitable for use with compositions of the present invention include Thermablok (Thermablok Inc, Tampa, FL, USA) and Pyrogel XT (ThermaXX Jackets, LLC, West Haven, CT, USA).
  • Other non-limiting, illustrative examples of aerogels and methods of preparing such may be found in US Patent Application No. 20080311398 to Bauer et al and in US Patent Application No. 20110056408 to Schaumburg et al, hereby incorporated by reference as if fully set forth herein.
  • the aerogel may also optionally be added to composition in a "wet” or partially solvated form.
  • the insulating properties of the aerogel may optionally be used in combination with the fire resistant compositions described herein to form insulating and fire resistant materials.
  • the aerogel is combined with carbon or carbon based materials for additional insulation against infrared heat.
  • a non-limiting example for such insulation would be to insulate windows, even for example for insulation filled glazings.
  • the fire resistant composition comprises both an aerogel and inorganic fibers, according to the various options described herein for each of these components.
  • plural or “a plurality” as used herein include, for example, “multiple” or “two or more”.
  • “a plurality of items” includes two or more items.
  • a fire-retardant coating material was prepared that included a fluid intumescent material (a non-limiting example of the intumescent base).
  • the fluid intumescent material included a foaming agent; a blowing agent gas source selected from the group consisting of melamine, urea, dicyandiamide, guanidine and glycine; a charring agent, a film-forming binder, a solvent and, in some cases, a pigment or filler.
  • Half a gallon of the intumescent material was mixed with 8 ounces of refractory fibers, which in this non-limiting example comprised 3 ounces of milled fiber and 5 ounces of short strand fibers.
  • the fibers comprised aluminum oxide (about 50% of the total fibers weight per weight), silicon dioxide (about 50%), ferric oxide (about 0.15%), titanium dioxide (about 0.15%), potassium oxide (about 0.15%), sodium oxide (about 0.2%) and zirconium oxide (about 0.2%). This combination was mixed with 16 ounces of granite powder and applied as a coating to one side of a wood sample of the size of 20x20 centimeters.
  • a layer of a one component, water-based, caulking grade, general purpose fire resistant sealant in the form of silicone resin was applied to the coated wood. After curing a layer of the fire resistant composition according to at least some embodiments of the present invention was applied.
  • the coating of the fire resistant composition was applied to a thickness of 0.250 inches in this non-limiting example; however, optionally the composition is applied in a thickness in a range of from about 0.050 inch to about 0.50 inch.
  • a propane torch having a temperature of 2600 F, was applied to the surface of the wood sample covered with the composition for one (1) hour.
  • the inner layer was shown to be unaffected; the outer layer swelled and bubbled, thereby forming a protective layer that protects the inner layer.
  • Example 2 coated fabric
  • Example 1 The same composition of Example 1 was applied to one side of a fabric article, featuring two pieces of heavy duty plain woven fabric attached together with fire related silicone sealant in which the coating was applied at the same thickness as for the wood in Example 1.
  • the fabric tested was a Pyroblanket (ADL Insulflex Inc), although optionally canvas, fiberglass (optionally coated), Kevlar, mineral impregnated or coated fabric, aluminum and other sheet metal fabrics may be used, additionally or alternatively.
  • the silicone sealant tested was Metacaulk 1000
  • Example 3 cardboard
  • Example 1 The same composition of Example 1 was applied to one side of a piece of cardboard at the same thickness as for the wood in Example 1.
  • a propane torch at a temperature of 1300 F, was applied to the coated cardboard for 12 minutes. Again, while the coating bubbled and swelled, the fabric maintained its integrity and was cool to the touch on the side away from the flame. The coated fabric was found to withstand a similar temperature range as for wood in Example 1.
  • Example 1 The same composition of Example 1 was applied to one side of a piece of drywall at the same thickness as for the wood in Example 1.
  • a propane torch at a temperature of 2600 F, was applied to the coated drywall for 90 minutes. Again, while the coating bubbled and swelled, the drywall maintained its integrity and was cool to the touch on the side away from the flame. The coated drywall was found to withstand a similar temperature range as for wood in Example 1.
  • Example 5 fabric case A fabric case was made from plain- woven heavy- duty pieces of fabric, again attached with Fire Rated Silicone Sealant to form a case in a shape of a box in the size of 20x10x20 centimeters. Inside the box was placed Styrofoam in the size of 3x3x3 cube, a cell phone battery and two AA energizer batteries. The box was sealed and exposed to open flame produced by igniting gasoline in an open bath made out of metal in the size of 60x60 centimeters. The temperature of the flame was measured to be 640C. After 15 minutes the objects were removed from the case. The materials that were placed inside the case were protected from the flames and the heat; no charring or heat or fire damage was observed, and the batteries were found to be fully functional.
  • Example 6 machine for applying coating(s)
  • Figures 1 and 2 show different embodiments of machines according to various embodiments of the present invention for applying the coating(s) described above.
  • Figure 1 shows an exemplary embodiment in which the apparatus operates on material that is not silicone-coated or that is already silicone-coated before the process of application of the coatings according to various embodiments of the present invention starts.
  • Figure 2 shows an exemplary embodiment in which the apparatus performs silicone-coating of the material as an integral part of the coating process.
  • a coating apparatus 100 features a loader 102 for receiving physical articles to be coated, which in turn provides the articles to a feeder 104. Primer is then applied at a priming table 106, which preferably features an electronic control unit 1 and a pressure tank 3 for holding the priming material.
  • the priming material is applied to the article by a spray unit 6, which comprises a motor drive (not shown) for moving spray unit 6 over the surface to be sprayed.
  • spray unit 6 features two spray heads 5, one of which optionally and preferably sprays material while the other of which preferably acts to cure the sprayed material.
  • Priming table 106 also features two heating tunnels 10 for more even heating of the sprayed material, although optionally only one heating tunnel 10 may be provided.
  • fire resistant base coating table 108 features similar components to priming table 106, for spraying the base coating on the article and for heating it.
  • the article passes to at least one fire resistant composition coating table 110 and optionally two such tables 110 as shown; more tables could optionally be implemented for multiple base coatings (not shown).
  • fire resistant composition coating table 110 features similar components to priming table 106, for spraying the base coating on the article and for heating it.
  • Figure 2 shows an apparatus 200 which is another embodiment of an apparatus for applying coatings according to various embodiments of the present invention. Components with the same number as Figure 1 have the same or similar function.
  • Silicone coating table 214 features at least one silicone pump 2 and preferably two silicone pumps 2 (shown as A and B) for pumping silicone onto the article.
  • the silicone is pumped from each silicone pump 2 to a spray gun 9 through a silicone gun applicator bridge 8.
  • a motor drive 4 ensures that the spray gun 9 is moved evenly over the article that is being sprayed.
  • the article then moves to a moisturizing spray table 216 for applying moisture for steaming with heating, after which the article is cured on a curing table 218.
  • the temperature for curing in this example was 60-70 C and also featured blown dry air; however, optionally curing may take place at a range of 40-90 C. Silicone coatings may for example take 16 minutes to cure; again optionally any of these coatings may be applied as a pre-formed layer.
  • the article is moved to one or more air- curing (air-drying) tables 220, which direct a flow of blown air onto the article.
  • air- curing (air-drying) tables 220 which direct a flow of blown air onto the article.
  • the remaining tables and processes occur as for Figure 1.
  • This Example relates to exemplary, illustrative formulations as described herein.
  • Formula 1 basic 1.foaming agent - mono-ammonium phosphate, (NH4)3P04 (in powder form or granules), 20%
  • Stabilizer and volatile organic (VOC) reduction components - erythritol and paraffin (optionally in equal amounts; also optionally only one of these two components may be present), 9%
  • Stabilizer and volatile organic (VOC) reduction components - erythritol and paraffin (optionally in equal amounts; also optionally only one of these two components may be present), 9%
  • Stabilizer and volatile organic (VOC) reduction components - erythritol and paraffin (optionally in equal amounts; also optionally only one of these two components may be present), 9%
  • Nonwoven fabric coated or impregnated with aerogel and then combined with the above composition, for example by being coated with the above composition.
  • the references cited herein teach many principles that are applicable to the present invention. Therefore the full contents of these publications are incorporated by reference herein where appropriate for teachings of additional or alternative details, features and/or technical background.

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  • Chemical & Material Sciences (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Wood Science & Technology (AREA)
  • Organic Chemistry (AREA)
  • Paints Or Removers (AREA)

Abstract

L'invention porte sur une composition résistante au feu et à la chaleur permettant de conférer une résistance au feu à une surface ou d'accroître la résistance au feu d'une surface à l'intérieur ou à l'extérieur. La composition est constituée d'une intégration de moyens à la fois chimiques et physiques. L'aspect physique est une composition de revêtement contenant des matériaux comprenant un moyen conférant de la résistance au feu et à la chaleur, un moyen permettant d'obtenir un plus faible dégagement de chaleur de pointe, un moyen permettant d'obtenir un plus faible dégagement de chaleur par unité de temps, un moyen permettant d'obtenir un gradient de température plus élevé, un moyen permettant d'obtenir un faible propagation de flamme, un moyen permettant d'obtenir un retard d'inflammation élevé, un moyen permettant d'obtenir un faible dégagement de chaleur de pointe, un moyen permettant d'obtenir un faible dégagement de chaleur totale, un moyen conférant une stabilité thermique élevée, un moyen de fourniture de revêtements élastiques et de réglage d'épaisseurs des revêtements et de la chaleur. Les aspects chimiques sont constitués d'additifs chimiques qui sont anti-feu.
PCT/IB2013/054397 2012-05-28 2013-05-28 Peinture résistante au feu pour application à une surface à l'extérieur ou à l'intérieur, articles manufacturés la comprenant, appareil pour sa fabrication et procédé pour sa fabrication WO2013179218A1 (fr)

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US201261652278P 2012-05-28 2012-05-28
US201261652281P 2012-05-28 2012-05-28
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CN103709868A (zh) * 2013-12-25 2014-04-09 广州泰祥实业新材料科技（新丰）有限公司 一种微球形SiO2气凝胶复合隔热保温外墙涂料及其制备方法
CN104230386A (zh) * 2014-09-23 2014-12-24 佛山市禾才科技服务有限公司 一种一次烧成微晶玻璃复合板的制备方法
CN104594897A (zh) * 2014-12-16 2015-05-06 苏州华安矿业科技有限公司 采煤机负压雾化二次降尘装置
CN109280433A (zh) * 2018-08-31 2019-01-29 浙江大高包装材料有限公司 一种颜料箔涂料
CN109485462A (zh) * 2018-12-26 2019-03-19 泸天化（集团）有限责任公司 一种利用梯度温度分离不同分子量脲醛肥料混合物的方法
US10260232B1 (en) 2017-12-02 2019-04-16 M-Fire Supression, Inc. Methods of designing and constructing Class-A fire-protected multi-story wood-framed buildings
US10290004B1 (en) 2017-12-02 2019-05-14 M-Fire Suppression, Inc. Supply chain management system for supplying clean fire inhibiting chemical (CFIC) totes to a network of wood-treating lumber and prefabrication panel factories and wood-framed building construction job sites
US10311444B1 (en) 2017-12-02 2019-06-04 M-Fire Suppression, Inc. Method of providing class-A fire-protection to wood-framed buildings using on-site spraying of clean fire inhibiting chemical liquid on exposed interior wood surfaces of the wood-framed buildings, and mobile computing systems for uploading fire-protection certifications and status information to a central database and remote access thereof by firefighters on job site locations during fire outbreaks on construction sites
US10332222B1 (en) 2017-12-02 2019-06-25 M-Fire Supression, Inc. Just-in-time factory methods, system and network for prefabricating class-A fire-protected wood-framed buildings and components used to construct the same
CN110105797A (zh) * 2019-06-14 2019-08-09 二工防爆科技股份有限公司 一种可抑制自燃的防爆配电箱
US10430757B2 (en) 2017-12-02 2019-10-01 N-Fire Suppression, Inc. Mass timber building factory system for producing prefabricated class-A fire-protected mass timber building components for use in constructing prefabricated class-A fire-protected mass timber buildings
US10642324B2 (en) 2016-04-06 2020-05-05 Hewlett-Packard Development Company, L.P. Cover for devices
CN111164167A (zh) * 2017-10-04 2020-05-15 日立化成株式会社 涂液、涂膜的制造方法及涂膜
US10653904B2 (en) 2017-12-02 2020-05-19 M-Fire Holdings, Llc Methods of suppressing wild fires raging across regions of land in the direction of prevailing winds by forming anti-fire (AF) chemical fire-breaking systems using environmentally clean anti-fire (AF) liquid spray applied using GPS-tracking techniques
US10814150B2 (en) 2017-12-02 2020-10-27 M-Fire Holdings Llc Methods of and system networks for wireless management of GPS-tracked spraying systems deployed to spray property and ground surfaces with environmentally-clean wildfire inhibitor to protect and defend against wildfires
CN112280424A (zh) * 2020-09-30 2021-01-29 青岛泽林建材有限公司 一种无机－有机杂化地坪涂料及其制备方法、应用
WO2021222685A1 (fr) * 2020-05-01 2021-11-04 Ppg Industries Ohio, Inc. Revêtements intumescents
US11395931B2 (en) 2017-12-02 2022-07-26 Mighty Fire Breaker Llc Method of and system network for managing the application of fire and smoke inhibiting compositions on ground surfaces before the incidence of wild-fires, and also thereafter, upon smoldering ambers and ashes to reduce smoke and suppress fire re-ignition
CN115678331A (zh) * 2022-09-28 2023-02-03 惠州市益可涂料有限公司 一种耐温防火涂料
US11826592B2 (en) 2018-01-09 2023-11-28 Mighty Fire Breaker Llc Process of forming strategic chemical-type wildfire breaks on ground surfaces to proactively prevent fire ignition and flame spread, and reduce the production of smoke in the presence of a wild fire
US11836807B2 (en) 2017-12-02 2023-12-05 Mighty Fire Breaker Llc System, network and methods for estimating and recording quantities of carbon securely stored in class-A fire-protected wood-framed and mass-timber buildings on construction job-sites, and class-A fire-protected wood-framed and mass timber components in factory environments
US11865390B2 (en) 2017-12-03 2024-01-09 Mighty Fire Breaker Llc Environmentally-clean water-based fire inhibiting biochemical compositions, and methods of and apparatus for applying the same to protect property against wildfire
US11865394B2 (en) 2017-12-03 2024-01-09 Mighty Fire Breaker Llc Environmentally-clean biodegradable water-based concentrates for producing fire inhibiting and fire extinguishing liquids for fighting class A and class B fires
US11911643B2 (en) 2021-02-04 2024-02-27 Mighty Fire Breaker Llc Environmentally-clean fire inhibiting and extinguishing compositions and products for sorbing flammable liquids while inhibiting ignition and extinguishing fire

Citations (7)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO1999043390A1 (fr) * 1995-12-29 1999-09-02 No Fire Technologies, Inc. Composition ignifuge intumescente de protection contre les hautes temperatures et de longue duree
US6613391B1 (en) * 2000-01-27 2003-09-02 Henry Gang Flame inhibiting and retarding chemical process and system for general use on multiple solid surfaces
US20080311398A1 (en) 2007-03-16 2008-12-18 Cabot Corporation Aerogel Particles and Methods Of Making Same
US7638572B2 (en) 2003-08-22 2009-12-29 Imperial Chemical Industries Limited Fire retardant coating composition
US20110056408A1 (en) 2007-11-12 2011-03-10 Cismi Aerogel compositions
US20110274927A1 (en) 2009-01-14 2011-11-10 Rie Watanabe Inorganic fiber structure and process for producing same
WO2012164478A1 (fr) * 2011-05-27 2012-12-06 L-M-J Nation Security Llc Composition de revêtement ignifuge de type intumescent

Patent Citations (7)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO1999043390A1 (fr) * 1995-12-29 1999-09-02 No Fire Technologies, Inc. Composition ignifuge intumescente de protection contre les hautes temperatures et de longue duree
US6613391B1 (en) * 2000-01-27 2003-09-02 Henry Gang Flame inhibiting and retarding chemical process and system for general use on multiple solid surfaces
US7638572B2 (en) 2003-08-22 2009-12-29 Imperial Chemical Industries Limited Fire retardant coating composition
US20080311398A1 (en) 2007-03-16 2008-12-18 Cabot Corporation Aerogel Particles and Methods Of Making Same
US20110056408A1 (en) 2007-11-12 2011-03-10 Cismi Aerogel compositions
US20110274927A1 (en) 2009-01-14 2011-11-10 Rie Watanabe Inorganic fiber structure and process for producing same
WO2012164478A1 (fr) * 2011-05-27 2012-12-06 L-M-J Nation Security Llc Composition de revêtement ignifuge de type intumescent

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* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN103709868A (zh) * 2013-12-25 2014-04-09 广州泰祥实业新材料科技（新丰）有限公司 一种微球形SiO2气凝胶复合隔热保温外墙涂料及其制备方法
CN104230386A (zh) * 2014-09-23 2014-12-24 佛山市禾才科技服务有限公司 一种一次烧成微晶玻璃复合板的制备方法
CN104594897A (zh) * 2014-12-16 2015-05-06 苏州华安矿业科技有限公司 采煤机负压雾化二次降尘装置
US10642324B2 (en) 2016-04-06 2020-05-05 Hewlett-Packard Development Company, L.P. Cover for devices
CN111164167A (zh) * 2017-10-04 2020-05-15 日立化成株式会社 涂液、涂膜的制造方法及涂膜
US10899038B2 (en) 2017-12-02 2021-01-26 M-Fire Holdings, Llc Class-A fire-protected wood products inhibiting ignition and spread of fire along class-A fire-protected wood surfaces and development of smoke from such fire
US11707639B2 (en) 2017-12-02 2023-07-25 Mighty Fire Breaker Llc Wireless communication network, GPS-tracked mobile spraying systems, and a command system configured for proactively spraying environmentally-safe anti-fire chemical liquid on combustible property surfaces to protect property against fire ignition and flame spread in the presence of wild fire
US10290004B1 (en) 2017-12-02 2019-05-14 M-Fire Suppression, Inc. Supply chain management system for supplying clean fire inhibiting chemical (CFIC) totes to a network of wood-treating lumber and prefabrication panel factories and wood-framed building construction job sites
US10311444B1 (en) 2017-12-02 2019-06-04 M-Fire Suppression, Inc. Method of providing class-A fire-protection to wood-framed buildings using on-site spraying of clean fire inhibiting chemical liquid on exposed interior wood surfaces of the wood-framed buildings, and mobile computing systems for uploading fire-protection certifications and status information to a central database and remote access thereof by firefighters on job site locations during fire outbreaks on construction sites
US10332222B1 (en) 2017-12-02 2019-06-25 M-Fire Supression, Inc. Just-in-time factory methods, system and network for prefabricating class-A fire-protected wood-framed buildings and components used to construct the same
US10260232B1 (en) 2017-12-02 2019-04-16 M-Fire Supression, Inc. Methods of designing and constructing Class-A fire-protected multi-story wood-framed buildings
US10430757B2 (en) 2017-12-02 2019-10-01 N-Fire Suppression, Inc. Mass timber building factory system for producing prefabricated class-A fire-protected mass timber building components for use in constructing prefabricated class-A fire-protected mass timber buildings
US11730987B2 (en) 2017-12-02 2023-08-22 Mighty Fire Breaker Llc GPS tracking and mapping wildfire defense system network for proactively defending homes and neighborhoods against threat of wild fire by spraying environmentally-safe anti-fire chemical liquid on property surfaces to inhibit fire ignition and flame spread in the presence of wild fire
US11697040B2 (en) 2017-12-02 2023-07-11 Mighty Fire Breaker Llc Wild fire defense system network using a command center, spraying systems and mobile computing systems configured to proactively defend homes and neighborhoods against threat of wild fire by spraying environmentally-safe anti-fire chemical liquid on property surfaces before presence of wild fire
US10653904B2 (en) 2017-12-02 2020-05-19 M-Fire Holdings, Llc Methods of suppressing wild fires raging across regions of land in the direction of prevailing winds by forming anti-fire (AF) chemical fire-breaking systems using environmentally clean anti-fire (AF) liquid spray applied using GPS-tracking techniques
US10814150B2 (en) 2017-12-02 2020-10-27 M-Fire Holdings Llc Methods of and system networks for wireless management of GPS-tracked spraying systems deployed to spray property and ground surfaces with environmentally-clean wildfire inhibitor to protect and defend against wildfires
US11654313B2 (en) 2017-12-02 2023-05-23 Mighty Fire Breaker Llc Wireless communication network, GPS-tracked ground-based spraying tanker vehicles and command center configured for proactively spraying environmentally-safe anti-fire chemical liquid on property surfaces to inhibit fire ignition and flame spread in the presence of wild fire
US11697041B2 (en) 2017-12-02 2023-07-11 Mighty Fire Breaker Llc Method of proactively defending combustible property against fire ignition and flame spread in the presence of wild fire
US10919178B2 (en) 2017-12-02 2021-02-16 M-Fire Holdings, Llc Class-A fire-protected oriented strand board (OSB) sheathing, and method of and automated factory for producing the same
US11697039B2 (en) 2017-12-02 2023-07-11 Mighty Fire Breaker Llc Wireless communication network, GPS-tracked back-pack spraying systems and command center configured for proactively spraying environmentally-safe anti-fire chemical liquid on property surfaces to inhibit fire ignition and flame spread in the presence of wild fire
US10267034B1 (en) 2017-12-02 2019-04-23 M-Fire Suppression, Inc. On-job-site method of and system for providing class-A fire-protection to wood-framed buildings during construction
US11836807B2 (en) 2017-12-02 2023-12-05 Mighty Fire Breaker Llc System, network and methods for estimating and recording quantities of carbon securely stored in class-A fire-protected wood-framed and mass-timber buildings on construction job-sites, and class-A fire-protected wood-framed and mass timber components in factory environments
US11395931B2 (en) 2017-12-02 2022-07-26 Mighty Fire Breaker Llc Method of and system network for managing the application of fire and smoke inhibiting compositions on ground surfaces before the incidence of wild-fires, and also thereafter, upon smoldering ambers and ashes to reduce smoke and suppress fire re-ignition
US11400324B2 (en) 2017-12-02 2022-08-02 Mighty Fire Breaker Llc Method of protecting life, property, homes and businesses from wild fire by proactively applying environmentally-clean anti-fire (AF) chemical liquid spray in advance of wild fire arrival and managed using a wireless network with GPS-tracking
US11654314B2 (en) 2017-12-02 2023-05-23 Mighty Fire Breaker Llc Method of managing the proactive spraying of environment ally-clean anti-fire chemical liquid on GPS-specified property surfaces so as to inhibit fire ignition and flame spread in the presence of wild fire
US11794044B2 (en) 2017-12-02 2023-10-24 Mighty Fire Breaker Llc Method of proactively forming and maintaining GPS-tracked and mapped environmentally-clean chemical firebreaks and fire protection zones that inhibit fire ignition and flame spread in the presence of wild fire
US11633636B2 (en) 2017-12-02 2023-04-25 Mighty Fire Breaker Llc Wireless neighborhood wildfire defense system network supporting proactive protection of life and property in a neighborhood through GPS-tracking and mapping of environmentally-clean anti-fire (AF) chemical liquid spray applied to the property before wild fires reach the neighborhood
US11638844B2 (en) 2017-12-02 2023-05-02 Mighty Fire Breaker Llc Method of proactively protecting property from wild fire by spraying environmentally-clean anti-fire chemical liquid on property surfaces prior to wild fire arrival using remote sensing and GPS-tracking and mapping enabled spraying
US11642555B2 (en) 2017-12-02 2023-05-09 Mighty Fire Breaker Llc Wireless wildfire defense system network for proactively defending homes and neighborhoods against wild fires by spraying environmentally-clean anti-fire chemical liquid on property and buildings and forming GPS-tracked and mapped chemical fire breaks about the property
US11865390B2 (en) 2017-12-03 2024-01-09 Mighty Fire Breaker Llc Environmentally-clean water-based fire inhibiting biochemical compositions, and methods of and apparatus for applying the same to protect property against wildfire
US11865394B2 (en) 2017-12-03 2024-01-09 Mighty Fire Breaker Llc Environmentally-clean biodegradable water-based concentrates for producing fire inhibiting and fire extinguishing liquids for fighting class A and class B fires
US11826592B2 (en) 2018-01-09 2023-11-28 Mighty Fire Breaker Llc Process of forming strategic chemical-type wildfire breaks on ground surfaces to proactively prevent fire ignition and flame spread, and reduce the production of smoke in the presence of a wild fire
CN109280433B (zh) * 2018-08-31 2021-04-02 浙江大高镭射科技股份有限公司 一种颜料箔涂料
CN109280433A (zh) * 2018-08-31 2019-01-29 浙江大高包装材料有限公司 一种颜料箔涂料
CN109485462A (zh) * 2018-12-26 2019-03-19 泸天化（集团）有限责任公司 一种利用梯度温度分离不同分子量脲醛肥料混合物的方法
CN110105797A (zh) * 2019-06-14 2019-08-09 二工防爆科技股份有限公司 一种可抑制自燃的防爆配电箱
CN115485340A (zh) * 2020-05-01 2022-12-16 Ppg工业俄亥俄公司 膨胀型涂料
WO2021222685A1 (fr) * 2020-05-01 2021-11-04 Ppg Industries Ohio, Inc. Revêtements intumescents
CN112280424B (zh) * 2020-09-30 2022-06-07 青岛泽林建材有限公司 一种无机－有机杂化地坪涂料及其制备方法、应用
CN112280424A (zh) * 2020-09-30 2021-01-29 青岛泽林建材有限公司 一种无机－有机杂化地坪涂料及其制备方法、应用
US11911643B2 (en) 2021-02-04 2024-02-27 Mighty Fire Breaker Llc Environmentally-clean fire inhibiting and extinguishing compositions and products for sorbing flammable liquids while inhibiting ignition and extinguishing fire
CN115678331B (zh) * 2022-09-28 2023-07-14 惠州市益可涂料有限公司 一种耐温防火涂料
CN115678331A (zh) * 2022-09-28 2023-02-03 惠州市益可涂料有限公司 一种耐温防火涂料

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