WO2013175758A1 - 鋼帯の連続焼鈍炉、連続焼鈍方法、連続溶融亜鉛めっき設備及び溶融亜鉛めっき鋼帯の製造方法 - Google Patents
鋼帯の連続焼鈍炉、連続焼鈍方法、連続溶融亜鉛めっき設備及び溶融亜鉛めっき鋼帯の製造方法 Download PDFInfo
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- WO2013175758A1 WO2013175758A1 PCT/JP2013/003199 JP2013003199W WO2013175758A1 WO 2013175758 A1 WO2013175758 A1 WO 2013175758A1 JP 2013003199 W JP2013003199 W JP 2013003199W WO 2013175758 A1 WO2013175758 A1 WO 2013175758A1
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- Prior art keywords
- furnace
- gas
- zone
- steel strip
- heating zone
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- 229910000831 Steel Inorganic materials 0.000 title claims abstract description 108
- 239000010959 steel Substances 0.000 title claims abstract description 108
- 238000000137 annealing Methods 0.000 title claims abstract description 72
- 238000000034 method Methods 0.000 title claims abstract description 31
- 238000004519 manufacturing process Methods 0.000 title claims description 9
- 229910001335 Galvanized steel Inorganic materials 0.000 title claims description 6
- 239000008397 galvanized steel Substances 0.000 title claims description 6
- 239000007789 gas Substances 0.000 claims abstract description 243
- 238000010438 heat treatment Methods 0.000 claims abstract description 148
- 238000002791 soaking Methods 0.000 claims abstract description 116
- 238000001816 cooling Methods 0.000 claims abstract description 66
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 claims abstract description 24
- 239000001301 oxygen Substances 0.000 claims abstract description 24
- 229910052760 oxygen Inorganic materials 0.000 claims abstract description 24
- 238000005192 partition Methods 0.000 claims abstract description 13
- 238000005246 galvanizing Methods 0.000 claims description 14
- 238000004891 communication Methods 0.000 claims description 3
- 230000032258 transport Effects 0.000 claims description 2
- 230000007547 defect Effects 0.000 abstract description 8
- 238000007791 dehumidification Methods 0.000 abstract description 4
- 238000006392 deoxygenation reaction Methods 0.000 abstract description 4
- 238000007747 plating Methods 0.000 description 22
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Chemical compound O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 13
- 210000004894 snout Anatomy 0.000 description 10
- 238000005275 alloying Methods 0.000 description 7
- 238000011144 upstream manufacturing Methods 0.000 description 7
- 238000001514 detection method Methods 0.000 description 6
- 238000009826 distribution Methods 0.000 description 6
- 238000007599 discharging Methods 0.000 description 5
- KDLHZDBZIXYQEI-UHFFFAOYSA-N Palladium Chemical compound [Pd] KDLHZDBZIXYQEI-UHFFFAOYSA-N 0.000 description 4
- 230000015572 biosynthetic process Effects 0.000 description 4
- 238000010586 diagram Methods 0.000 description 4
- 230000000694 effects Effects 0.000 description 4
- 238000005516 engineering process Methods 0.000 description 4
- 230000001590 oxidative effect Effects 0.000 description 4
- 238000012360 testing method Methods 0.000 description 4
- 239000003054 catalyst Substances 0.000 description 3
- 238000007796 conventional method Methods 0.000 description 3
- 230000007423 decrease Effects 0.000 description 3
- 239000000203 mixture Substances 0.000 description 3
- 238000007254 oxidation reaction Methods 0.000 description 3
- 230000009467 reduction Effects 0.000 description 3
- XEEYBQQBJWHFJM-UHFFFAOYSA-N Iron Chemical compound [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 description 2
- 229910004298 SiO 2 Inorganic materials 0.000 description 2
- 229910021536 Zeolite Inorganic materials 0.000 description 2
- 230000009471 action Effects 0.000 description 2
- 229910045601 alloy Inorganic materials 0.000 description 2
- 239000000956 alloy Substances 0.000 description 2
- 238000006243 chemical reaction Methods 0.000 description 2
- 239000012141 concentrate Substances 0.000 description 2
- HNPSIPDUKPIQMN-UHFFFAOYSA-N dioxosilane;oxo(oxoalumanyloxy)alumane Chemical compound O=[Si]=O.O=[Al]O[Al]=O HNPSIPDUKPIQMN-UHFFFAOYSA-N 0.000 description 2
- 230000005484 gravity Effects 0.000 description 2
- 239000012535 impurity Substances 0.000 description 2
- 239000000463 material Substances 0.000 description 2
- 238000005259 measurement Methods 0.000 description 2
- 229910052751 metal Inorganic materials 0.000 description 2
- 239000002184 metal Substances 0.000 description 2
- 230000003647 oxidation Effects 0.000 description 2
- 229910052763 palladium Inorganic materials 0.000 description 2
- 239000002436 steel type Substances 0.000 description 2
- 239000010457 zeolite Substances 0.000 description 2
- 229910019142 PO4 Inorganic materials 0.000 description 1
- 238000013459 approach Methods 0.000 description 1
- 230000004888 barrier function Effects 0.000 description 1
- 230000000903 blocking effect Effects 0.000 description 1
- 239000004566 building material Substances 0.000 description 1
- 230000008859 change Effects 0.000 description 1
- 239000010960 cold rolled steel Substances 0.000 description 1
- 230000008878 coupling Effects 0.000 description 1
- 238000010168 coupling process Methods 0.000 description 1
- 238000005859 coupling reaction Methods 0.000 description 1
- 230000003247 decreasing effect Effects 0.000 description 1
- 230000003635 deoxygenating effect Effects 0.000 description 1
- 238000009792 diffusion process Methods 0.000 description 1
- 238000005206 flow analysis Methods 0.000 description 1
- 239000011261 inert gas Substances 0.000 description 1
- 230000005764 inhibitory process Effects 0.000 description 1
- 238000009434 installation Methods 0.000 description 1
- 229910052742 iron Inorganic materials 0.000 description 1
- 239000010452 phosphate Substances 0.000 description 1
- NBIIXXVUZAFLBC-UHFFFAOYSA-K phosphate Chemical compound [O-]P([O-])([O-])=O NBIIXXVUZAFLBC-UHFFFAOYSA-K 0.000 description 1
- 230000008569 process Effects 0.000 description 1
- 230000009257 reactivity Effects 0.000 description 1
- 239000000126 substance Substances 0.000 description 1
- 239000013585 weight reducing agent Substances 0.000 description 1
Images
Classifications
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- C21D—MODIFYING THE PHYSICAL STRUCTURE OF FERROUS METALS; GENERAL DEVICES FOR HEAT TREATMENT OF FERROUS OR NON-FERROUS METALS OR ALLOYS; MAKING METAL MALLEABLE, e.g. BY DECARBURISATION OR TEMPERING
- C21D1/00—General methods or devices for heat treatment, e.g. annealing, hardening, quenching or tempering
- C21D1/74—Methods of treatment in inert gas, controlled atmosphere, vacuum or pulverulent material
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- C—CHEMISTRY; METALLURGY
- C21—METALLURGY OF IRON
- C21D—MODIFYING THE PHYSICAL STRUCTURE OF FERROUS METALS; GENERAL DEVICES FOR HEAT TREATMENT OF FERROUS OR NON-FERROUS METALS OR ALLOYS; MAKING METAL MALLEABLE, e.g. BY DECARBURISATION OR TEMPERING
- C21D1/00—General methods or devices for heat treatment, e.g. annealing, hardening, quenching or tempering
- C21D1/26—Methods of annealing
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- C—CHEMISTRY; METALLURGY
- C21—METALLURGY OF IRON
- C21D—MODIFYING THE PHYSICAL STRUCTURE OF FERROUS METALS; GENERAL DEVICES FOR HEAT TREATMENT OF FERROUS OR NON-FERROUS METALS OR ALLOYS; MAKING METAL MALLEABLE, e.g. BY DECARBURISATION OR TEMPERING
- C21D1/00—General methods or devices for heat treatment, e.g. annealing, hardening, quenching or tempering
- C21D1/74—Methods of treatment in inert gas, controlled atmosphere, vacuum or pulverulent material
- C21D1/76—Adjusting the composition of the atmosphere
-
- C—CHEMISTRY; METALLURGY
- C21—METALLURGY OF IRON
- C21D—MODIFYING THE PHYSICAL STRUCTURE OF FERROUS METALS; GENERAL DEVICES FOR HEAT TREATMENT OF FERROUS OR NON-FERROUS METALS OR ALLOYS; MAKING METAL MALLEABLE, e.g. BY DECARBURISATION OR TEMPERING
- C21D8/00—Modifying the physical properties by deformation combined with, or followed by, heat treatment
- C21D8/06—Modifying the physical properties by deformation combined with, or followed by, heat treatment during manufacturing of rods or wires
- C21D8/065—Modifying the physical properties by deformation combined with, or followed by, heat treatment during manufacturing of rods or wires of ferrous alloys
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- C—CHEMISTRY; METALLURGY
- C21—METALLURGY OF IRON
- C21D—MODIFYING THE PHYSICAL STRUCTURE OF FERROUS METALS; GENERAL DEVICES FOR HEAT TREATMENT OF FERROUS OR NON-FERROUS METALS OR ALLOYS; MAKING METAL MALLEABLE, e.g. BY DECARBURISATION OR TEMPERING
- C21D9/00—Heat treatment, e.g. annealing, hardening, quenching or tempering, adapted for particular articles; Furnaces therefor
- C21D9/52—Heat treatment, e.g. annealing, hardening, quenching or tempering, adapted for particular articles; Furnaces therefor for wires; for strips ; for rods of unlimited length
- C21D9/54—Furnaces for treating strips or wire
- C21D9/56—Continuous furnaces for strip or wire
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- C—CHEMISTRY; METALLURGY
- C21—METALLURGY OF IRON
- C21D—MODIFYING THE PHYSICAL STRUCTURE OF FERROUS METALS; GENERAL DEVICES FOR HEAT TREATMENT OF FERROUS OR NON-FERROUS METALS OR ALLOYS; MAKING METAL MALLEABLE, e.g. BY DECARBURISATION OR TEMPERING
- C21D9/00—Heat treatment, e.g. annealing, hardening, quenching or tempering, adapted for particular articles; Furnaces therefor
- C21D9/52—Heat treatment, e.g. annealing, hardening, quenching or tempering, adapted for particular articles; Furnaces therefor for wires; for strips ; for rods of unlimited length
- C21D9/54—Furnaces for treating strips or wire
- C21D9/56—Continuous furnaces for strip or wire
- C21D9/561—Continuous furnaces for strip or wire with a controlled atmosphere or vacuum
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- C—CHEMISTRY; METALLURGY
- C23—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
- C23C—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THE SURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL
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- C23C2/003—Apparatus
- C23C2/0035—Means for continuously moving substrate through, into or out of the bath
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- C—CHEMISTRY; METALLURGY
- C23—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
- C23C—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THE SURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL
- C23C2/00—Hot-dipping or immersion processes for applying the coating material in the molten state without affecting the shape; Apparatus therefor
- C23C2/003—Apparatus
- C23C2/0038—Apparatus characterised by the pre-treatment chambers located immediately upstream of the bath or occurring locally before the dipping process
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- C—CHEMISTRY; METALLURGY
- C23—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
- C23C—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THE SURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL
- C23C2/00—Hot-dipping or immersion processes for applying the coating material in the molten state without affecting the shape; Apparatus therefor
- C23C2/003—Apparatus
- C23C2/0038—Apparatus characterised by the pre-treatment chambers located immediately upstream of the bath or occurring locally before the dipping process
- C23C2/004—Snouts
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- C—CHEMISTRY; METALLURGY
- C23—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
- C23C—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THE SURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL
- C23C2/00—Hot-dipping or immersion processes for applying the coating material in the molten state without affecting the shape; Apparatus therefor
- C23C2/02—Pretreatment of the material to be coated, e.g. for coating on selected surface areas
- C23C2/022—Pretreatment of the material to be coated, e.g. for coating on selected surface areas by heating
- C23C2/0222—Pretreatment of the material to be coated, e.g. for coating on selected surface areas by heating in a reactive atmosphere, e.g. oxidising or reducing atmosphere
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- C—CHEMISTRY; METALLURGY
- C23—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
- C23C—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THE SURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL
- C23C2/00—Hot-dipping or immersion processes for applying the coating material in the molten state without affecting the shape; Apparatus therefor
- C23C2/02—Pretreatment of the material to be coated, e.g. for coating on selected surface areas
- C23C2/022—Pretreatment of the material to be coated, e.g. for coating on selected surface areas by heating
- C23C2/0224—Two or more thermal pretreatments
-
- C—CHEMISTRY; METALLURGY
- C23—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
- C23C—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THE SURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL
- C23C2/00—Hot-dipping or immersion processes for applying the coating material in the molten state without affecting the shape; Apparatus therefor
- C23C2/04—Hot-dipping or immersion processes for applying the coating material in the molten state without affecting the shape; Apparatus therefor characterised by the coating material
- C23C2/06—Zinc or cadmium or alloys based thereon
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- C—CHEMISTRY; METALLURGY
- C23—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
- C23C—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THE SURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL
- C23C2/00—Hot-dipping or immersion processes for applying the coating material in the molten state without affecting the shape; Apparatus therefor
- C23C2/26—After-treatment
- C23C2/28—Thermal after-treatment, e.g. treatment in oil bath
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- C—CHEMISTRY; METALLURGY
- C23—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
- C23C—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THE SURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL
- C23C2/00—Hot-dipping or immersion processes for applying the coating material in the molten state without affecting the shape; Apparatus therefor
- C23C2/34—Hot-dipping or immersion processes for applying the coating material in the molten state without affecting the shape; Apparatus therefor characterised by the shape of the material to be treated
- C23C2/36—Elongated material
- C23C2/40—Plates; Strips
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- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F27—FURNACES; KILNS; OVENS; RETORTS
- F27B—FURNACES, KILNS, OVENS, OR RETORTS IN GENERAL; OPEN SINTERING OR LIKE APPARATUS
- F27B9/00—Furnaces through which the charge is moved mechanically, e.g. of tunnel type; Similar furnaces in which the charge moves by gravity
- F27B9/04—Furnaces through which the charge is moved mechanically, e.g. of tunnel type; Similar furnaces in which the charge moves by gravity adapted for treating the charge in vacuum or special atmosphere
- F27B9/045—Furnaces with controlled atmosphere
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- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F27—FURNACES; KILNS; OVENS; RETORTS
- F27B—FURNACES, KILNS, OVENS, OR RETORTS IN GENERAL; OPEN SINTERING OR LIKE APPARATUS
- F27B9/00—Furnaces through which the charge is moved mechanically, e.g. of tunnel type; Similar furnaces in which the charge moves by gravity
- F27B9/28—Furnaces through which the charge is moved mechanically, e.g. of tunnel type; Similar furnaces in which the charge moves by gravity for treating continuous lengths of work
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- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F27—FURNACES; KILNS; OVENS; RETORTS
- F27D—DETAILS OR ACCESSORIES OF FURNACES, KILNS, OVENS, OR RETORTS, IN SO FAR AS THEY ARE OF KINDS OCCURRING IN MORE THAN ONE KIND OF FURNACE
- F27D7/00—Forming, maintaining, or circulating atmospheres in heating chambers
- F27D7/04—Circulating atmospheres by mechanical means
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B05—SPRAYING OR ATOMISING IN GENERAL; APPLYING FLUENT MATERIALS TO SURFACES, IN GENERAL
- B05D—PROCESSES FOR APPLYING FLUENT MATERIALS TO SURFACES, IN GENERAL
- B05D3/00—Pretreatment of surfaces to which liquids or other fluent materials are to be applied; After-treatment of applied coatings, e.g. intermediate treating of an applied coating preparatory to subsequent applications of liquids or other fluent materials
- B05D3/02—Pretreatment of surfaces to which liquids or other fluent materials are to be applied; After-treatment of applied coatings, e.g. intermediate treating of an applied coating preparatory to subsequent applications of liquids or other fluent materials by baking
- B05D3/0218—Pretreatment, e.g. heating the substrate
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B05—SPRAYING OR ATOMISING IN GENERAL; APPLYING FLUENT MATERIALS TO SURFACES, IN GENERAL
- B05D—PROCESSES FOR APPLYING FLUENT MATERIALS TO SURFACES, IN GENERAL
- B05D7/00—Processes, other than flocking, specially adapted for applying liquids or other fluent materials to particular surfaces or for applying particular liquids or other fluent materials
- B05D7/14—Processes, other than flocking, specially adapted for applying liquids or other fluent materials to particular surfaces or for applying particular liquids or other fluent materials to metal, e.g. car bodies
Definitions
- the present invention relates to a continuous annealing furnace for a steel strip, a continuous annealing method, a continuous hot dip galvanizing facility, and a method for manufacturing a hot dip galvanized steel strip.
- the high-strength cold-rolled steel strip contains oxidizable elements such as Si and Mn, these oxidizable elements are concentrated on the surface of the steel strip during annealing and oxides such as Si and Mn. As a result, there is a problem of poor appearance and chemical conversion treatment such as phosphate treatment.
- Patent Document 2 Techniques for efficiently obtaining an annealing atmosphere with a low dew point are disclosed in, for example, Patent Document 2 and Patent Document 3. These technologies are technologies for relatively small-scale one-pass vertical furnaces, and are not considered for application to multi-pass vertical furnaces such as CGL / CAL. For this reason, there is a very high risk that these techniques cannot efficiently reduce the dew point.
- the present invention sets the dew point of the furnace atmosphere to a steady operation prior to the steady operation in which the steel strip is continuously heat-treated or when the moisture concentration and / or oxygen concentration in the furnace atmosphere increases during the steady operation. It is an object of the present invention to provide a continuous annealing furnace for a steel strip that can be quickly reduced to a level suitable for the above. In addition, the present invention can stably obtain an atmosphere with a low dew point with few problems of pick-up defects and furnace wall damage, and easily oxidizable elements such as Si and Mn in steel on the steel strip surface during annealing.
- this invention makes it the subject to provide the continuous annealing method of the steel strip using the said continuous annealing furnace.
- this invention makes it a subject to provide the continuous hot-dip galvanization equipment provided with the said annealing furnace. Moreover, this invention makes it a subject to provide the manufacturing method of the hot dip galvanized steel strip which carries out the hot dip galvanization after continuously annealing a steel strip with the said annealing method.
- this invention is a technique applied to the annealing furnace in which the partition which physically isolate
- the inventors measured the dew point distribution in a large vertical furnace having multiple passes, and performed flow analysis based on the measurement. As a result, the inventors have found the following findings. 1) Compared with N 2 gas, which occupies most of the atmosphere, water vapor (H 2 O) has a lower specific gravity, so in a vertical annealing furnace with multiple passes, the upper part of the furnace tends to have a high dew point. 2) The gas inside the furnace is sucked from the upper part of the furnace and introduced into a refiner equipped with a deoxygenator and a dehumidifier to remove oxygen and moisture to lower the dew point.
- the means of the present invention for solving the above problems are as follows.
- a heating zone that transports the steel strip in the vertical direction, a soaking zone, and a cooling zone are arranged in this order, and a connecting portion between the soaking zone and the cooling zone is arranged in the upper part of the furnace, and the heating zone and the soaking zone are Communicating at the upper part of the furnace, providing a partition other than the communicating part at the upper part of the furnace to physically separate the heating zone and the soaking zone, supplying atmospheric gas into the furnace from outside the furnace, and supplying the furnace gas to the steel at the lower part of the heating zone While discharging from the belt introduction part, a part of the gas in the furnace is sucked and introduced into a refiner having a deoxygenator and a dehumidifier provided outside the furnace to remove oxygen and moisture in the gas and lower the dew point.
- the vertical annealing furnace is configured to return the dew point-reduced gas from the gas discharge port to the furnace, and the gas suction port from the furnace to the refiner is connected to the lower part of the soaking zone-cooling zone.
- the vertical distance from the steel strip introduction part at the bottom of the heating zone is 6 m or less and the furnace length direction distance.
- There heating zone excluding an area is less than 3m or / and, the soaking zone, a continuous annealing furnace of a steel strip, characterized in that provided over one position.
- FIG. 1 is a diagram showing a configuration example of a continuous hot-dip galvanizing line including a continuous annealing furnace for steel strip according to an embodiment of the present invention.
- FIG. 2 is a diagram illustrating an arrangement example of a gas suction port to the refiner, a gas discharge port from the refiner, and a dew point detection unit.
- FIG. 3 is a diagram illustrating a configuration example of a refiner.
- FIG. 4 is a diagram showing a trend of dew point reduction in an annealing furnace.
- the steel strip continuous hot dip galvanizing line is equipped with an annealing furnace upstream of the plating bath.
- an annealing furnace a heating zone, a soaking zone, and a cooling zone are arranged in this order from upstream to downstream of the furnace.
- the annealing furnace and the plating bath are connected via a snout, and the inside of the furnace from the heating zone to the snout is maintained in a reducing atmosphere gas or a non-oxidizing atmosphere.
- a radiant tube (RT) is used as a heating means, and the steel zone is indirectly heated.
- Sources of water include furnace wall, steel strip, inflow of outside air from the furnace entrance, inflow from cooling zone and snout, etc. If there is a leak point in RT or the furnace wall, that is also the water supply source. There is a case.
- the dew point it is necessary to lower the dew point to -40 ° C or lower, which is excellent in suppressing the oxidation of Si, Mn, etc.
- Both dew points need to be reduced.
- the lower dew point is advantageous from the viewpoint of plating properties, and it is preferable that the dew point can be lowered to ⁇ 45 ° C. or lower, more preferably -50 ° C. or lower.
- the present invention introduces a part of the atmospheric gas in the furnace into a refiner having a deoxygenating device and a dehumidifying device provided outside the furnace to remove oxygen and moisture in the gas.
- the dew point is lowered and the gas with the lowered dew point is returned to the furnace.
- the suction port for the in-furnace gas introduced into the refiner and the discharge port for the gas having a reduced dew point returned from the refiner are arranged as shown in 1) to 3) below.
- the gas suction port of the heating zone is arranged in a region excluding the region where the distance in the vertical direction is 6 m or less and the distance in the furnace length direction is 3 m or less from the steel strip introduction part below the heating zone.
- the present invention is based on such a viewpoint.
- Heating zone 3 and soaking zone 4 communicate with each other at the top of the furnace. Apart from the communication part at the upper part of the furnace, a partition wall 12 for blocking the atmosphere gas in the heating zone 3 and the soaking zone 4 is installed.
- the bulkhead 12 is installed at the middle position in the furnace length direction between the upper hearth roll at the heating zone 3 outlet and the upper hearth roll at the soaking zone 4 inlet, the upper end is close to the steel strip 1, and the lower end and the end in the width direction of the steel strip are It is arranged vertically so as to be in contact with the furnace wall.
- the cooling zone 5 is composed of a first cooling zone 5a and a second cooling zone 5b, and the first cooling zone 5a has one steel strip path.
- 17 is an atmospheric gas supply system for supplying atmospheric gas from outside the furnace
- 18 is a gas introduction pipe to the refiner
- 19 is a gas outlet pipe from the refiner 10.
- FIG. 2 shows an arrangement example of a gas suction port to the refiner 10, a gas discharge port from the refiner 10, and a dew point detection unit.
- Reference numerals 22a to 22e denote gas suction ports
- 23a to 23e denote gas discharge ports
- 24a to 24g denote dew point detection units.
- the furnace width (W) of the heating zone is 12m
- the soaking zone width is 4m
- the total heating zone and soaking zone width is 16m.
- the diameter of the gas suction port is ⁇ 200mm.
- a single gas suction port (22e) is disposed in the throat portion at the bottom of the connecting portion 13 between the soaking zone 3 and the cooling zone 4.
- the gas suction port is a set of two suction ports arranged at a distance of 1 m in the furnace length direction, and 1 m below the center of the upper hearth roll in the soaking zone (22b). 1/2 position (center in the height direction: 22c), 1m above the center of the lower tropical hearth roll (22d) and the center of the heating zone (1/2 position of the furnace height, center in the furnace length direction: In total, four sets of suction ports (22a to 22d) are arranged in 22a).
- the dew point detection part of the dew point meter that detects the dew point of the gas in the furnace is the connecting part (24g) between the soaking zone and the cooling zone, and between the two suction ports of each set arranged in the soaking zone and the heating zone (24b, 24d to 24f), the middle of the third and fourth outlets from the inlet side wall of the heating zone (middle of outlets 23c and 23d: 24a), the inlet side wall 1m above the center of the lower hearth roll of the heating zone It is arranged at a position (24c) of 6m.
- FIG. 3 shows a configuration example of the refiner 10.
- 30 is a heat exchanger
- 31 is a cooler
- 32 is a filter
- 33 is a blower
- 34 is a deoxygenator
- 35 and 36 are dehumidifiers
- 46 and 51 are switching valves
- 40 to 45, 47 to 50, 52 and 53 are valves.
- the deoxygenation device 34 is a deoxygenation device using a palladium catalyst.
- the dehumidifiers 35 and 36 are dehumidifiers using a synthetic zeolite catalyst. Two dehumidifiers 35 and 36 are arranged in parallel so that they can be operated continuously.
- the gas whose dew point has been lowered by removing oxygen and moisture with the refiner can be discharged into the furnace through the gas outlet pipes 19 and 19a to 19e and from the discharge ports 23a to 23e. Adjustment and stop of the discharge amount of the gas discharged from each discharge port into the furnace can be individually controlled by a valve (not shown) and a flow meter (not shown) provided in the middle of each gas outlet pipe 19a to 19e.
- the gas having a lowered dew point is passed through the heat exchanger 30, the gas is discharged from the gas outlets 23a to 23e and returned to the connecting portion 13 of the heating zone 3, soaking zone 4 and cooling zone 5.
- the temperature of the gas discharged into the furnace can be increased.
- the atmospheric dew point of the soaking zone and the connecting zone between the soaking zone and the cooling zone can be lowered to -40 ° C or lower, or further to -45 ° C or lower. Furthermore, it prevents atmospheric gas stagnation in the upper, middle, and lower parts of the furnace in the latter half of the heating zone. Or it can also fall below -50 degreeC.
- the location where the dew point is high is based on the average dew point of the heating zone, soaking zone, soaking zone-cooling zone, and higher dew point.
- the heating zone may not be concentrated because the temperature of the steel zone is low, and it may be necessary to prevent surface enrichment at the junction between the soaking zone and the soaking zone and cooling zone.
- a place with a higher dew point may be set as a place where the dew point is higher than the average value of the dew point at the junction between the soaking zone and the soaking zone and the cooling zone.
- this invention is applicable also to the continuous annealing line (CAL) which continuously anneals a steel strip.
- CAL continuous annealing line
- the refiner used synthetic zeolite for the dehumidifier and a palladium catalyst for the deoxygenator.
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- Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
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- Organic Chemistry (AREA)
- Materials Engineering (AREA)
- Metallurgy (AREA)
- Chemical Kinetics & Catalysis (AREA)
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- Thermal Sciences (AREA)
- Crystallography & Structural Chemistry (AREA)
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Abstract
Description
1)雰囲気の大部分を占めるN2ガスに比べて、水蒸気(H2O)は比重が軽いため、多パスを有する竪型焼鈍炉では、炉上部が高露点になりやすいこと。
2)炉内の上部から炉内ガスを吸引して脱酸素器と除湿器を備えるリファイナに導入して酸素及び水分を除去して露点を低下し、露点を低下したガスを炉内の特定部に戻すことで、炉上部が高露点になるのを防止して、炉内雰囲気の露点を定常操業に適した所定のレベルまで短時間で減少させることができること。
3)炉上部以外からも炉内ガスを吸引してリファイナに導入する場合には、加熱帯下部の鋼帯導入部付近の領域に導入部を設けないことが必要であること。
ここで、加熱帯のガスの吐出口の吐出幅W0は、加熱帯の最も入側に配置されたガス吐出口と、最も出側に配置されたガスの吐出口の炉長方向の間隔である。
ここで、ガスの吐出幅W1は、加熱帯の最も入側から吐出するガス吐出口と、最も出側から吐出するガス吐出口の炉長方向の間隔である。
A:露点-30.4℃(=体積水分比359ppm)、B:露点-31.2℃(=体積水分比330ppm)、
C:露点-30.8℃(=体積水分比)344ppm
Aでの吸引量=1000×359/(359+330+344)=348Nm3/hr
Bでの吸引量=1000×330/(359+330+344)=319Nm3/hr
Cでの吸引量=1000×344/(359+330+344)=333Nm3/hr
2 焼鈍炉
3 加熱帯
4 均熱帯
5 冷却帯
5a 第1冷却帯
5b 第2冷却帯
6 スナウト
7 めっき浴
8 ガスワイピングノズル
9 加熱装置
10 リファイナ
11a 上部ハースロール
11b 下部ハースロール
12 隔壁
13 連結部
14 スロート
15 ロール
16 シールロール
17 雰囲気ガス供給系統
18 ガス導入管
19 ガス導出管
22a~22e ガスの吸引口
23a~23e ガスの吐出口
24a~24g 露点検出部
30 熱交換器
31 クーラ
32 フィルタ
33 ブロワ
34 脱酸素装置
35、36 除湿装置
46、51 切替弁
40~45、47~50、52、53 弁
Claims (7)
- 鋼帯を上下方向に搬送する加熱帯、均熱帯及び冷却帯がこの順に配置され、前記均熱帯と前記冷却帯の連結部は炉上部に配置され、前記加熱帯と前記均熱帯は炉上部で連通し、炉上部の連通部以外は隔壁を設けて加熱帯と均熱帯を物理的に分離され、炉外より雰囲気ガスを炉内に供給し、炉内ガスを加熱帯下部の鋼帯導入部から排出するとともに、炉内ガスの一部を吸引して炉外に設けた脱酸素装置と除湿装置を有するリファイナに導入してガス中の酸素と水分を除去して露点を低下し、露点を低下したガスをガスの吐出口から炉内に戻すように構成された縦型焼鈍炉であって、炉内からリファイナへのガスの吸引口を、均熱帯-冷却帯の連結部下部に設け、かつ加熱帯下部の鋼帯導入部から鉛直方向距離が6m以下でかつ炉長方向距離が3m以下である領域を除く加熱帯、または/および、均熱帯に、1箇所以上設けることを特徴とする鋼帯の連続焼鈍炉。
- 前記加熱帯、均熱帯に配置したガスの吸引口近傍に炉内ガスの露点を測定する露点計の露点検出部を設置したことを特徴とする請求項1に記載の鋼帯の連続焼鈍炉。
- リファイナから炉内へのガスの吐出口を、均熱帯-冷却帯の連結部、および、加熱帯の上部に複数個設け、加熱帯上部のガスの吐出口の吐出幅W0は、加熱帯の炉幅Wに対して、W0/W>1/4を満足することを特徴とする請求項1または2に記載の鋼帯の連続焼鈍炉。
ここで、加熱帯のガスの吐出口の吐出幅W0は、加熱帯の最も入側に配置されたガス吐出口と、最も出側に配置されたガスの吐出口の炉長方向の間隔である。 - 請求項2または3に記載の鋼帯の連続焼鈍炉を用いて鋼帯を連続焼鈍する際に、加熱帯及び均熱帯のガスの吸引口近傍の炉内ガスの露点を測定し、露点が高い場所の炉内ガスを優先して吸引し、リファイナから戻るガスを加熱帯上部のガスの吐出口から優先して吐出することを特徴とする鋼帯の連続焼鈍方法。
- 加熱帯上部から吐出するガスの吐出幅W1は、加熱帯の炉幅Wに対して、W1/W>1/4を満足することを特徴とする請求項4に記載の鋼帯の連続焼鈍方法。
ここで、ガスの吐出幅W1は、加熱帯の最も入側から吐出するガスの吐出口と、最も出側から吐出するガスの吐出口の炉長方向の間隔である。 - 請求項1~3のいずれかに記載の焼鈍炉の下流に溶融亜鉛めっき設備を備えることを特徴とする鋼帯の連続溶融亜鉛めっき設備。
- 請求項4または5に記載の方法で鋼帯を連続焼鈍した後、溶融亜鉛めっきすることを特徴とする溶融亜鉛めっき鋼帯の製造方法。
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KR1020147032385A KR101614237B1 (ko) | 2012-05-24 | 2013-05-20 | 강대의 연속 어닐링로, 연속 어닐링 방법, 연속 용융 아연 도금 설비 및 용융 아연 도금 강대의 제조 방법 |
CN201380026386.7A CN104321447B (zh) | 2012-05-24 | 2013-05-20 | 钢带的连续退火炉、连续退火方法、连续热浸镀锌设备以及热浸镀锌钢带的制造方法 |
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WO2013150710A1 (ja) * | 2012-04-06 | 2013-10-10 | Jfeスチール株式会社 | 連続式溶融亜鉛めっき設備 |
FR3014447B1 (fr) * | 2013-12-05 | 2016-02-05 | Fives Stein | Procede et installation de traitement thermique en continu d'une bande d'acier |
JP6128068B2 (ja) * | 2014-07-07 | 2017-05-17 | Jfeスチール株式会社 | 合金化溶融亜鉛めっき鋼板の製造方法 |
JP6131919B2 (ja) * | 2014-07-07 | 2017-05-24 | Jfeスチール株式会社 | 合金化溶融亜鉛めっき鋼板の製造方法 |
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CN106834661B (zh) * | 2017-01-10 | 2019-03-05 | 首钢京唐钢铁联合有限责任公司 | 一种热镀锌双相钢选择性氧化控制方法 |
WO2018198493A1 (ja) * | 2017-04-27 | 2018-11-01 | Jfeスチール株式会社 | 合金化溶融亜鉛めっき鋼板の製造方法及び連続溶融亜鉛めっき装置 |
KR102109238B1 (ko) * | 2017-12-20 | 2020-05-11 | 주식회사 포스코 | 고강도강 표면 산화물 환원을 위한 연속 소둔 설비 |
BR112021011382B1 (pt) | 2018-12-21 | 2023-05-02 | Arcelormittal | Forno de recozimento de tiras de aço |
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