WO2013172789A1 - Système de déshumidification, méthode de déshumidification et système de refroidissement - Google Patents

Système de déshumidification, méthode de déshumidification et système de refroidissement Download PDF

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Publication number
WO2013172789A1
WO2013172789A1 PCT/SG2013/000198 SG2013000198W WO2013172789A1 WO 2013172789 A1 WO2013172789 A1 WO 2013172789A1 SG 2013000198 W SG2013000198 W SG 2013000198W WO 2013172789 A1 WO2013172789 A1 WO 2013172789A1
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WO
WIPO (PCT)
Prior art keywords
desiccant
dehumidifier
regenerator
conduit
heat exchanger
Prior art date
Application number
PCT/SG2013/000198
Other languages
English (en)
Inventor
Wenjian CAI
Lei Zhao
Xinli Wang
Original Assignee
Nanyang Technological University
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Publication date
Application filed by Nanyang Technological University filed Critical Nanyang Technological University
Priority to SG11201405212UA priority Critical patent/SG11201405212UA/en
Publication of WO2013172789A1 publication Critical patent/WO2013172789A1/fr

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Classifications

    • F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F24—HEATING; RANGES; VENTILATING
    • F24F—AIR-CONDITIONING; AIR-HUMIDIFICATION; VENTILATION; USE OF AIR CURRENTS FOR SCREENING
    • F24F3/00—Air-conditioning systems in which conditioned primary air is supplied from one or more central stations to distributing units in the rooms or spaces where it may receive secondary treatment; Apparatus specially designed for such systems
    • F24F3/12—Air-conditioning systems in which conditioned primary air is supplied from one or more central stations to distributing units in the rooms or spaces where it may receive secondary treatment; Apparatus specially designed for such systems characterised by the treatment of the air otherwise than by heating and cooling
    • F24F3/14—Air-conditioning systems in which conditioned primary air is supplied from one or more central stations to distributing units in the rooms or spaces where it may receive secondary treatment; Apparatus specially designed for such systems characterised by the treatment of the air otherwise than by heating and cooling by humidification; by dehumidification
    • F24F3/1411—Air-conditioning systems in which conditioned primary air is supplied from one or more central stations to distributing units in the rooms or spaces where it may receive secondary treatment; Apparatus specially designed for such systems characterised by the treatment of the air otherwise than by heating and cooling by humidification; by dehumidification by absorbing or adsorbing water, e.g. using an hygroscopic desiccant
    • F24F3/1417—Air-conditioning systems in which conditioned primary air is supplied from one or more central stations to distributing units in the rooms or spaces where it may receive secondary treatment; Apparatus specially designed for such systems characterised by the treatment of the air otherwise than by heating and cooling by humidification; by dehumidification by absorbing or adsorbing water, e.g. using an hygroscopic desiccant with liquid hygroscopic desiccants
    • F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F24—HEATING; RANGES; VENTILATING
    • F24F—AIR-CONDITIONING; AIR-HUMIDIFICATION; VENTILATION; USE OF AIR CURRENTS FOR SCREENING
    • F24F5/00—Air-conditioning systems or apparatus not covered by F24F1/00 or F24F3/00, e.g. using solar heat or combined with household units such as an oven or water heater
    • F24F5/0007—Air-conditioning systems or apparatus not covered by F24F1/00 or F24F3/00, e.g. using solar heat or combined with household units such as an oven or water heater cooling apparatus specially adapted for use in air-conditioning
    • F24F5/0014—Air-conditioning systems or apparatus not covered by F24F1/00 or F24F3/00, e.g. using solar heat or combined with household units such as an oven or water heater cooling apparatus specially adapted for use in air-conditioning using absorption or desorption
    • F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F24—HEATING; RANGES; VENTILATING
    • F24F—AIR-CONDITIONING; AIR-HUMIDIFICATION; VENTILATION; USE OF AIR CURRENTS FOR SCREENING
    • F24F3/00—Air-conditioning systems in which conditioned primary air is supplied from one or more central stations to distributing units in the rooms or spaces where it may receive secondary treatment; Apparatus specially designed for such systems
    • F24F3/12—Air-conditioning systems in which conditioned primary air is supplied from one or more central stations to distributing units in the rooms or spaces where it may receive secondary treatment; Apparatus specially designed for such systems characterised by the treatment of the air otherwise than by heating and cooling
    • F24F3/14—Air-conditioning systems in which conditioned primary air is supplied from one or more central stations to distributing units in the rooms or spaces where it may receive secondary treatment; Apparatus specially designed for such systems characterised by the treatment of the air otherwise than by heating and cooling by humidification; by dehumidification
    • F24F2003/144—Air-conditioning systems in which conditioned primary air is supplied from one or more central stations to distributing units in the rooms or spaces where it may receive secondary treatment; Apparatus specially designed for such systems characterised by the treatment of the air otherwise than by heating and cooling by humidification; by dehumidification by dehumidification only
    • F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F24—HEATING; RANGES; VENTILATING
    • F24F—AIR-CONDITIONING; AIR-HUMIDIFICATION; VENTILATION; USE OF AIR CURRENTS FOR SCREENING
    • F24F3/00—Air-conditioning systems in which conditioned primary air is supplied from one or more central stations to distributing units in the rooms or spaces where it may receive secondary treatment; Apparatus specially designed for such systems
    • F24F3/12—Air-conditioning systems in which conditioned primary air is supplied from one or more central stations to distributing units in the rooms or spaces where it may receive secondary treatment; Apparatus specially designed for such systems characterised by the treatment of the air otherwise than by heating and cooling
    • F24F3/14—Air-conditioning systems in which conditioned primary air is supplied from one or more central stations to distributing units in the rooms or spaces where it may receive secondary treatment; Apparatus specially designed for such systems characterised by the treatment of the air otherwise than by heating and cooling by humidification; by dehumidification
    • F24F2003/1458—Air-conditioning systems in which conditioned primary air is supplied from one or more central stations to distributing units in the rooms or spaces where it may receive secondary treatment; Apparatus specially designed for such systems characterised by the treatment of the air otherwise than by heating and cooling by humidification; by dehumidification using regenerators

Definitions

  • the present invention relates to a dehumidifying system, a method of dehumidifying and a cooling system using the dehumidifying system.
  • Sorption dehumidification can be classified into two categories, namely, adsorption dehumidification and absorption dehumidification.
  • Adsorption occurs when the physical or chemical, generally solid, remains unchanged in the dehumidification process; absorption conversely is when a change occurs, generally with liquid substances.
  • Both methods utilize the difference of the vapour pressure between process air and desiccants to realize the humidity control.
  • the desiccant material is cold and dry, its vapour pressure is lower than process air and moisture may be transferred from the process air to the desiccant for dehumidification.
  • the desiccant is warm and moist, the pressure gradient is inverted and water vapour migrates from the desiccant to the air flow for regeneration.
  • a liquid desiccant offers several advantages over a solid desiccant, namely the liquid desiccant has a higher capacity to hold moisture than that of the solid desiccant; the liquid desiccant requires lower regenerating temperature, mostly around 80°C while the solid desiccant is in the range of 100°C, this allows the exploitation of low-grade heat sources such as solar energy or waste heat; the pressure drop of process air through the liquid desiccant is lower than the solid desiccant; the liquid desiccant can be stored in the form of a concentrated desiccant for use during periods when no suitable regenerating heat source is available, and thus offer more flexible operational characteristics.
  • a first aspect of the present invention provides a dehumidifying system having a dehumidifier having a desiccant, the dehumidifier configured to dehumidify a process airflow, the dehumidifier having a dehumidifier inlet and a dehumidifier outlet connected to the dehumidifier inlet such that the desiccant is configured to flow out of the dehumidifier via the dehumidifier outlet and to enter the dehumidifier via the dehumidifier inlet, a regenerator configured to regenerate the desiccant, the regenerator having a regenerator inlet and a regenerator outlet connected to the regenerator inlet such that the desiccant is configured to flow out of the regenerator via the regenerator outlet and to enter the regenerator via the regenerator inlet, a cooler connected to the dehumidifier, the cooler designed to cool the desiccant, such that the desiccant is cooled by the cooler before entering the dehumidifier via the dehum
  • a second aspect of the invention provides an air cooling system comprising a dehumidifying system in the first aspect, an air conditioning system having a compressor for compressing a refrigerant, a condenser adapted to condense the refrigerant from the compressor from a vapour state into a liquid state, a vapour conduit connected to the compressor and the condenser for establishing fluid communication between the compressor and the condenser, an evaporator in fluid communication with the condenser, the evaporator for evaporating the refrigerant from the condenser from a liquid state to a vapour state, such that the heater of the dehumidifying system is in thermal communication with the vapour conduit, such that the heater is configured to receive heat from the vapour conduit, such that the desiccant through the heater receives heat from the refrigerant in the vapour conduit, such that the cooler of the dehumidifying system is in thermal communication with the evaporator, such that the cooler is configured to be cooled by the
  • the present invention provides a method of dehumidifying a process airflow having the steps of dehumidifying the process airflow by removing vapour from the process airflow by a desiccant in a dehumidifier, channelling the desiccant out of the dehumidifier, cooling the desiccant, channelling the cooled desiccant into the dehumidifier, transferring the desiccant from the dehumidifier to the regenerator, regenerating the desiccant by removing vapour from the desiccant by a regenerating airflow, channelling the desiccant out of the regenerator, heating the desiccant, channelling the heated desiccant into the regenerator, and supplying the regenerated desiccant from the regenerator to the dehumidifier.
  • FIG. 1 shows an exemplary embodiment of a dehumidifying system
  • FIG. 2 shows another exemplary embodiment of the dehumidifying system of Fig. 1;
  • FIG. 3 shows another exemplary embodiment of the dehumidifying system of Fig. 1;
  • FIG. 4 shows another exemplary embodiment of the dehumidifying system of Fig. 1;
  • Fig. 5 shows another exemplary embodiment of the dehumidifying system of Fig. 1;
  • Fig. 6 shows an exemplary embodiment of an air cooling system integrated with the dehumidifying system of Fig. 1;
  • FIG. 7 shows another exemplary embodiment of an air cooling system integrated with the dehumidifying system of Fig. 1;
  • FIG. 8 shows an exemplary embodiment of an air cooling system integrated with the dehumidifying system of Fig. 1;
  • FIG. 9 shows an exemplary method of dehumidifying a process airflow by the various embodiments in Figs. 1-6;
  • Fig. 10 shows a test result of a test for heat exhaustion from a compressor against cooling load
  • Fig. 11 shows a test result of a test for regeneration rate against concentration of desiccant
  • Fig. 12 shows a test result of a test for performance of dehumidifier against the concentration of desiccant.
  • Fig. 1 shows a dehumidifying system 10.
  • Dehumidifying system 10 may use a desiccant 20 to dehumidify an airflow.
  • Dehumidifying system 10 may be a liquid desiccant dehumidifying system (LDDS) which uses a liquid desiccant.
  • LDDS liquid desiccant dehumidifying system
  • Dehumidifying system 10 has a dehumidifier 100 which is configured to dehumidify a process airflow 180, which is an airflow through the dehumidifier 100, such that vapour in the process airflow 180 is removed from the process airflow by the desiccant 20.
  • Dehumidifier 100 has a dehumidifier inlet 102 and a dehumidifier outlet 104 connected to the dehumidifier inlet 102.
  • Desiccant 20 is configured to flow out of the dehumidifier 100 via the dehumidifier outlet 104 and to enter the dehumidifier 100 via the dehumidifier inlet 102.
  • Desiccant 20 in the dehumidifier 100 may flow directly from the outlet 104 into the inlet 102.
  • Dehumidifying system 10 further includes a regenerator 200 which is configured to regenerate the desiccant 20, such that vapour is removed from the desiccant 20 by a regenerating airflow 280.
  • Regenerator 200 has a regenerator inlet 202 and a regenerator outlet 204 connected to the regenerator inlet 202 such that desiccant 20 is configured to flow out of the regenerator 200 via the regenerator outlet 204 and to enter the regenerator 200 via the regenerator inlet 202. Desiccant 20 in the regenerator 200 may flow directly from the outlet 204 into the inlet 202.
  • Dehumidifying system 10 further includes a cooler 300 connected to the dehumidifier 100.
  • Cooler 300 is designed to cool the desiccant 20.
  • Desiccant 20 is cooled by the cooler 300 before entering the dehumidifier 100 via the dehumidifier inlet 102.
  • Cooler 300 may be in thermal contact with the dehumidifier 100 to cool the desiccant 20.
  • desiccant 20 in the dehumidifier 100 may flow directly from the outlet 104 into the inlet 102.
  • Dehumidifying system 10 further includes a heater 400 connected to the regenerator 200.
  • Heater 400 is designed to heat the desiccant 20. Desiccant 20 is heated by the heater 400 before entering the regenerator 200 via the regenerator inlet 202. Desiccant 20 in the regenerator 200 may flow directly from the outlet 204 into the inlet 202. Heater 400 may be in thermal contact with the regenerator 400 to heat the desiccant 20. In this example, desiccant 20 in the regenerator 200 may flow directly from the outlet 204 into the inlet 202.
  • Dehumidifying system 10 further includes a desiccant transfer conduit 110 connected to the dehumidifier 100 and the regenerator 200.
  • Desiccant transfer conduit 110 is adapted to establish fluid communication between the dehumidifier 100 and the regenerator 200.
  • Dehumidifying system 10 further includes a desiccant supply conduit 210 connected to the dehumidifier 100 and the regenerator 200.
  • Desiccant supply conduit 210 is adapted to establish fluid communication between the dehumidifier 100 and the regenerator 200.
  • Desiccant transfer conduit 110 and the desiccant supply conduit 210 forms a desiccant transfer loop 22 through the dehumidifier 100 and the regenerator 200, such that the desiccant loop 22 is configured to provide transfer of desiccant 20 from the dehumidifier 100 to the regenerator 200 via the desiccant transfer conduit 110 and supply of desiccant 20 from the regenerator 200 to the dehumidifier 100 via the desiccant supply conduit 210.
  • Desiccant transfer conduit 110 and desiccant supply conduit 210 may include pumps along the conduit to pump the desiccant 20 along the conduits.
  • Dehumidifier 100 and regenerator 200 may include vessels 106,206. Vessels 106,206 may be filled with desiccant 20. Vessel 106 of dehumidifier 100 may include packing column 112. Vessel 206 of regenerator 100 may include packing column 212.
  • the pre-cooled desiccant 20, e.g. liquid desiccant may be sprayed above the packing column 106.
  • Process airflow 180 e.g. ambient air, drawn into the dehumidifier 100 by a fan 108, directly contacts the falling desiccant 20.
  • surface vapour pressure of the process airflow 180 is higher than that of desiccant 20, e.g. liquid desiccant, both heat and mass transfer occur from the process airflow 180 to the desiccant 20.
  • the pre-heated desiccant 20, e.g. liquid desiccant, from the dehumidifier 100 may be sprayed above the packing column 206.
  • Regenerating airflow 280 e.g. ambient air
  • regenerating airflow drawn into the regenerator 200 by a fan 208
  • surface vapour pressure of the desiccant 20 is higher than that of regenerating airflow, e.g. ambient air, both heat and mass transfer occur from the desiccant 20 to regenerating airflow 280 and the process condenses the desiccant 20.
  • dehumidifier 100 may include a first transfer conduit 120.
  • First transfer conduit 120 may be connected to the dehumidifier 100 via the dehumidifier outlet 104 and cooler 300.
  • First transfer conduit 120 establishes fluid communication between dehumidifier 100 and cooler 300.
  • Dehumidifier may include a first supply conduit 122 connected to dehumidifier 100 via the dehumidifying inlet 102 and cooler 300.
  • First supply conduit 122 establishes fluid communication between the dehumidifier 100 and cooler 300.
  • First transfer conduit 120 and first supply conduit 122 may form a dehumidifying loop 124 through the deh umidifier 100 and cooler 300 (see Fig. 2) such that dehumidifying loop 124 provides flow of desiccant 20 from the dehumidifier 100 to cooler 300 via the first transfer conduit 120, through cooler 300 to cool the desiccant 20 and back into the dehumidifier 100 via the first supply conduit 122.
  • a second transfer conduit 220 may be connected to the regenerator 200 via the regenerator outlet 204 and heater 400. Second transfer conduit 220 establishes fluid communication between the regenerator 200 and heater 400. Second supply conduit 222 may be connected to the regenerator 200 via the regenerator inlet 202 and heater 400. Second supply conduit 222 establishes fluid communication between the regenerator 200 and heater 400.
  • Second transfer conduit 220 and second supply conduit 222 may form a regenerating loop 224 through the regenerator 200 and heater 400 (see Fig. 2) such that regenerating loop 224 provides flow of desiccant 20 from the regenerator 200 to heater 400 via the second transfer conduit 220, through heater 400 to heat up the desiccant 20 and back into the regenerator 200 via the second supply conduit 224.
  • dehumidifier 100 removes the moisture/vapour from the process airflow 180. As more moisture is absorbed by the desiccant 20, the concentration of the desiccant 20 drops. In other words, the desiccant 20 is diluted. Regenerator 200 condenses the diluted desiccant 20 from the dehumidifier 100 to an acceptable concentration.
  • the working principle of the dehumidifier system 10 is briefly described as follows:
  • the pre-cooled desiccant e.g. liquid desiccant
  • Process airflow 180 drawn into the dehumidifier 100 by a fan 108, directly contacts the falling desiccant 20.
  • process airflow 180 e.g. ambient air
  • both heat and mass transfer take place from process airflow 180 to the sprayed desiccant 20.
  • the surface vapour difference between the process airflow 180 and the desiccant 20 acts as the driving force for the mass transfer.
  • Fig. 3 shows another exemplary embodiment of dehumidifying system 10.
  • Dehumidifying system 10 may include a concentrated desiccant reservoir 510 for storing desiccant 20.
  • Desiccant 20 may be concentrated desiccant 20.
  • Concentrated desiccant reservoir 510 may be disposed along desiccant supply conduit 210 such that fluid communication is established between the concentrated desiccant reservoir 510 and the dehumidifier 100 and between the concentrated desiccant reservoir 510 and the regenerator 200 via the desiccant supply conduit 210.
  • Desiccant supply conduit 210 may be adapted to supply desiccant 20 from regenerator 200 to dehumidifier 100 via the concentrated desiccant reservoir 510.
  • Concentrated desiccant reservoir 510 may contain desiccant 20 having concentration of about 40% and below. Crystallization may occur when the concentration is more than 42%.
  • desiccant may be circulated continuously in each packing column 112,212 until certain concentrations are reached. Since the desiccant are cycled in the respective loops, i.e. dehumidifying loop and regenerating loop, for most of the time, no energy crossover between the loops occurs. As such, cooling and heating demands are required only to maintain the desiccants at the specified temperatures. Therefore, the energy consumption in the dehumidifying system 10 may be much lower than that in conventional systems.
  • dehumidifying system 10 may include a diluted desiccant reservoir 520 for storing desiccant 20.
  • Diluted desiccant reservoir 520 may be disposed along the desiccant transfer conduit 110 such that fluid communication is established between diluted desiccant reservoir 520 and dehumidifier 100 and between diluted desiccant reservoir 510 and regenerator 200 via the desiccant transfer conduit 110.
  • Desiccant transfer conduit 110 may be adapted to transfer desiccant 20 from the dehumidifier 100 to regenerator 200 via diluted desiccant reservoir 520.
  • Diluted desiccant reservoir 520 may contain desiccant 20 having concentration of about 25% and above. Dehumidification requirement may not be met if the concentration is less than 25%.
  • Concentrated desiccant reservoir 510 and diluted desiccant reservoir 520 may be storage tanks. Concentrated desiccant reservoir 510 and diluted desiccant reservoir 520 may provide independent operation of the two packing columns 112,212. By allowing independent operation of the two packing columns 112,212 in the dehumidifier 100 and regenerator 200 respectively, it is possible for distributed operation of the dehumidifier 100 and regenerator 200 to determined locations, i.e. centralized regeneration and decentralized dehumidification.
  • diluted desiccant reservoir 520 may be thermally connected to the concentrated desiccant reservoir 510 such that heat may be transferred between the diluted desiccant reservoir 520 and the concentrated desiccant reservoir 510.
  • Diluted desiccant reservoir 520 may be connected to the concentrated desiccant reservoir 510 via a finned plate 530.
  • dehumidifying system 10 may further include an airflow channel 600.
  • Airflow channel 600 may be connected to dehumidifier 100 and to regenerator 200.
  • Airflow channel 600 establishes fluid communication between dehumidifier 100 and regenerator 200 such that the airflow channel 600 is able to channel the process airflow 180 from the dehumidifier 100 into regenerator 200.
  • process airflow 180 becomes the regenerating airflow 280.
  • a zone 610 may be disposed along airflow channel 600 such that process airflow 180 flows into the zone 610 via airflow channel 600 before continuing along the airflow channel 600 into regenerator 200.
  • Process airflow 180 may be warmed up after going through zone 610.
  • Zone 610 may be a room, a container etc.
  • dehumidifying system 10 may include a first heat exchanger 710.
  • First heat exchanger 710 may be in thermal communication with the airflow channel 600 and the second transfer conduit 220 such that the first heat exchanger 710 provides transfer of heat between process airflow 180 along the airflow channel 600 and the desiccant 20 along the second transfer conduit 220.
  • dehumidifying system 10 may include a second heat exchanger 720.
  • Second heat exchanger 720 may be in thermal communication with cooler 300 and the airflow channel 600 such that second heat exchanger 720 provides transfer of heat from the process airflow 180 along the airflow channel 600 to the desiccant 20 through cooler 300.
  • Heat exchanger 720 may be in contact with the cooler 300 or connected to cooler 300 by a heat conductor 722.
  • dehumidifying system 10 may include a third heat exchanger 730.
  • Third heat exchanger 730 may be in thermal communication with cooler 300.
  • First transfer conduit 120 may be connected to third heat exchanger 730 and dehumidifier 100 to establish fluid communication between dehumidifier 100 and the third heat exchanger 730.
  • First supply conduit 120 may be connected to third heat exchanger 730 and dehumidifier 100 to establish fluid communication between dehumidifier 100 and third heat exchanger 730.
  • First transfer conduit 120 and first supply conduit 122 may form the dehumidifying loop 124 through dehumidifier 100 and third heat exchanger 730 such that dehumidifying loop 124 provides flow of desiccant 20 from dehumidifier 100 to third heat exchanger 730 via first transfer conduit 120, through third heat exchanger 730 to cool the desiccant 20 and back into dehumidifier 100 via first supply conduit 122.
  • Air cooling system 800 includes an air conditioning system 850, e.g. HVAC system, for conditioning, e.g. cooling, a process airflow.
  • Air cooling system 800 includes dehumidifying system 10 which may be integrated with the air conditioning system 850.
  • Air conditioning system 850 includes a compressor 852 for compressing a refrigerant, a condenser 854 adapted to condense the refrigerant from the compressor 852 from a vapour state into a liquid state.
  • a vapour conduit 856 is connected to compressor 852 and condenser 854 for establishing fluid communication between compressor 852 and condenser 854.
  • Air conditioning system 850 includes an evaporator 858 which is in fluid communication with condenser 854. Evaporator 858 evaporates the refrigerant from the condenser 854 from a liquid state to a vapour state thereby lowering the temperature of the refrigerant.
  • Air conditioning system 850 includes an expansion valve 860 for controlling the amount of refrigerant into the evaporator 858.
  • a fourth heat exchanger 740 may be in thermal communication with the vapour conduit 856 and fluid communication with second supply conduit 222. Desiccant 20 flowing along second supply conduit 222 may be heated by the refrigerant flowing along the vapour conduit 856 when the desiccant 20 flows through the fourth heat exchanger 740.
  • Heater 400 (not shown in Fig. 6) of dehumidifying system 10 may be in thermal communication with the vapour conduit 856 via fourth heat exchanger 740.
  • Fourth heat exchanger 740 may be heater 400 and connected to the second transfer conduit 220 and second supply conduit 222 (part of regenerating loop 224) such that heat is provided to desiccant 20 that flows along second transfer conduit 220, through the fourth heat exchanger 740 and along second supply conduit 222.
  • Heater 400 is therefore configured to receive heat from the vapour conduit 856 so that desiccant 20 flowing through the heater 400 receives heat from the refrigerant in the vapour conduit 856.
  • first heat exchanger 710 may be in thermal communication with fourth heat exchanger 740 such that desiccant 20 along the regenerating loop 224 flows through the first heat exchanger 710 and fourth heat exchanger 740 before entering regenerator 200.
  • desiccant 20 after leaving regenerator 200, may be heated up in steps.
  • the first and fourth heat exchangers 710,740 may be used to recover the waste heat from e.g. the air conditioning system 850 and dehumidifying system 10.
  • Humidity and temperature of regenerating airflow have great influences on the performance of regeneration.
  • higher temperature results in lower relative humidity for the same regenerating airflow that can increase the mass transfer coefficient.
  • An effect in heating up the regenerating airflow 280 is that the heat passed from the desiccant to the regenerating airflow 280 becomes much smaller, hence reducing the energy required to heat up the desiccant 20.
  • Dehumidifying system 10 makes use of the waste heat from compressor 852 to heat both the desiccant 20 and the regenerating airflow 280 so as to reduce the regenerating temperature to about 55°C.
  • third heat exchanger 730 may be in thermal communication with evaporator 858.
  • Cooler 300 of the dehumidifying system 10 may be third heat exchanger 730. Cooler 300 may be in thermal communication with evaporator 858.
  • Third heat exchanger 730 or cooler 300 may be configured to be cooled by evaporator 858 such that desiccant 20 through third heat exchanger 730 or cooler 300 may be cooled by the refrigerant through evaporator 858.
  • Cooler 300 in the dehumidifying system 10 may be the evaporator 858 whereby the second heat exchanger 720 may be in thermal communication with the evaporator 858.
  • a fifth heat exchanger 750 may be in thermal communication with the second heat exchanger 720. Chilled water from second heat exchanger 720 may be directed to the fifth heat exchanger 750, i.e. outlet of second heat exchanger 720 may be connected to the inlet of the fifth heat exchanger 750.
  • Fifth heat exchanger 750 may be connected to the evaporator 858 in air conditioning system 850, e.g. HVAC system. In this way, chilled water from the fifth heat exchanger 750 may be used to cool the desiccant 20 before entering the evaporator 858 in the air conditioning system 850.
  • Fifth heat exchanger 750 may be used to make use of the return chilled water in air conditioning system 850.
  • dehumidifying system 10 may include a heat pipe heat exchanger
  • Heat pipe heat exchanger 760 may include ducts 762,764. Outlet 204 and inlet 202 of regenerator 200 may be connected to the ducts 762,764 of the heat pipe heat exchanger
  • regenerator 760 respectively such that regenerating air flow 280 at the outlet 204 of regenerator 200 may flow through duct 762 of heat pipe heat exchanger 760 to heat up the heat pipe heat exchanger 760.
  • Regenerating air flow 280 of regenerator 200 may flow through the other duct 764 which may be in thermal connection with duct 762. In this way, regenerating air flow 280 may be heated by the flow at the outlet 204 before entering regenerator 200.
  • Heat pipe heat exchanger 760 may be used to recover the waste heat from regenerating air flow
  • Heat pipe heat exchanger 760 may be directly connected to the inlet 202 and outlet 204 of the regenerator 200.
  • Fig. 9 shows a method 1000 of dehumidifying a process airflow.
  • Method 1000 includes the following steps.
  • step 1010 the process airflow is dehumidified by removing vapour from the process airflow by a desiccant in a dehumidifier.
  • Sprayed desiccant interacts with the process airflow 180 and removes vapour from the process airflow 180.
  • step 1020 desiccant is channelled out of the dehumidifier.
  • desiccant 20 in vessel 106 at the bottom of dehumidifier 100 may be pumped by a pump 130 out of dehumidifier 100.
  • the humidity of process airflow 180 leaving the dehumidifier 100 may be controlled through adjusting the desiccant flow rate and the temperature in the dehumidifier 100.
  • step 1030 the desiccant is cooled.
  • Desiccant 20 flows along first transfer conduit 120 after being pumped out of dehumidifier 100 and cooled by third heat exchanger 730.
  • step 1040 the cooled desiccant is channelled into the dehumidifier.
  • desiccant 20 flows along first supply conduit 122 and being sprayed on the topside of the dehumidifier 100 after being cooled by third heat exchanger 730.
  • step 1050 the desiccant is transferred from the dehumidifier to the regenerator.
  • concentration of the desiccant 20 in dehumidifier 100 in vessel 106) drops to about 25% and below
  • about 80% of the desiccant 20 in dehumidifier 100 may be pumped by a pump 140 into the diluted desiccant reservoir 520 via desiccant transfer conduit 110.
  • the remaining about 20% of desiccant 20 diluted desiccant
  • Desiccant 20 may then be transferred from diluted desiccant reservoir 520 to regenerator 200.
  • diluted desiccant 20 in the diluted desiccant reservoir 520 may be transferred from the diluted desiccant reservoir 520 to regenerator 200.
  • a valve 522 adapted to control flow between diluted desiccant reservoir 520 and regenerator 200 and located along desiccant transfer conduit 110 may be opened to transfer about 80% of the diluted desiccant 20 from the diluted desiccant reservoir 520 to regenerator 200.
  • step 1060 the desiccant is regenerated by removing vapour from the desiccant by a regenerating airflow.
  • Desiccant 20 may be sprayed at about the topside of the regenerator 200 to interact with the regenerating airflow 280 to remove vapour from the desiccant 20.
  • step 1070 the desiccant is channelled out of the regenerator.
  • the cycle starts by pumping desiccant 20 out of regenerator 200 by a pump 150.
  • Pump 150 may be attached along second transfer conduit 220.
  • step 1080 the desiccant is heated.
  • Desiccant 20 pumped out of regenerator 200 flows along second transfer conduit 220 towards first heat exchanger 710 to heat the desiccant 20 when desiccant 20 flows through first heat exchanger 710. Thereafter, desiccant flow along second transfer conduit 220 towards fourth heat exchanger 740 and may be heated by fourth heat exchanger 740.
  • step 1090 the heated desiccant is channelled into the regenerator. After being heated, desiccant 20 is channelled back to regenerator 200 and sprayed onto the packing column 212 of regenerator 200.
  • step 1100 regenerated desiccant is supplied from the regenerator to the dehumidifier.
  • concentration of the desiccant 20 in regenerator 200 reaches to about 40% and above, about 80% of the desiccant 20 in the vessel 206 of regenerator may be pumped by a pump 160 into concentrated desiccant reservoir 510.
  • the remaining about 20% of desiccant 20 may be kept in the regenerator 200 to keep regenerator 200 working without disruption.
  • Desiccant 20 or concentrated desiccant may be supplied to the dehumidifier 100 from the concentrated desiccant reservoir 510.
  • a valve 512 adapted to control flow between concentrated desiccant reservoir 520 and dehumidifier 100 and located along desiccant supply conduit 210 may be opened to supply about 80% of concentrated desiccant from the concentrated desiccant reservoir 520 to the dehumidifier 100.
  • An effect of the dehumidifying system 10 being integrated with air cooling system 800 may be the application of low grade heat such as waste heat from compressor 852 which may not be used in conventional dehumidifying system for regeneration.
  • Dehumidifying system 10 may reduce the regeneration temperature to less than about 55°C and may substantially increase the system Coefficient of Performance (COP) to at least 3 by recovering the waste heat from compressor 852.
  • COP Coefficient of Performance
  • Regeneration of desiccant depends heavily on the operation of air conditioning system 850, e.g. HVAC system.
  • air conditioning system 850 may work at off-peak mode and less waste heat can be supplied to regenerator 200, thus resulting in much slower regeneration rates.
  • dehumidification load may still be large due to high relative humidity.
  • Concentrated desiccant reservoir 510 and diluted desiccant reservoir 520 may store the concentrated and diluted desiccants, respectively, such that the concentrated desiccant regenerated during peak operating hours can be used for dehumidification during the off-peak hours.
  • AHU air handling units
  • dehumidifier and regenerator may be installed together in order to facilitate the exchange of concentrated and diluted desiccants.
  • Dehumidifying system may have a reservoir for each tower and thus allowing the regenerator to be located near the chiller to use wasted heat for regeneration while the dehumidifier may be distributed with different AHUs to handle the latent load. In this way, the centralized regeneration at plant room and distributed dehumidification at AHU rooms is made possible.
  • the concentration span in each tower is about 10%.
  • automation technologies including modelling, automatic start/stop logic, performance monitoring, control and optimization, may have been developed.
  • the model may use self-turning controllers and optimize the system performance during the operation.
  • the optimization and dynamic control technologies may ensure that the dehumidifying system may be integrated under different working conditions and may always be running most efficiently, smoothly and safely.
  • the energy savings from the dehumidifying system with applications to the mass building HVAC market may be tremendous and may commercially viable.
  • Fig. 11 shows the testing results from the second test. It is shown that, with desiccant locally circulated, desiccant may be concentrated to about 40% even at 50°C regenerating temperature and humid outdoor air. However, the regeneration rate is lower than that of absorption. Additional, concentrated desiccant will be needed in dehumidifier. In addition, the regeneration rate increases when less humid building exhaust air is used to regenerate the desiccant. Also, the regeneration performance can be improved if both outdoor air and building exhaust air is heated, waste heat from compressor may be used as the energy source. If regeneration temperature is increased to 60°C, the regeneration rate is higher than the absorption rate even with untreated outdoor air. An additional advantage of using heated air is that the temperature drop in desiccant is smaller, thus reducing the energy used in heating up the desiccant.
  • a third test is performed to test the performance of dehumidifier using the LDDS testing bed while keeping the desiccant locally circulated in the dehumidifier.
  • the humidity of dehumidifier outlet air is normally controlled at around 8.8g/(kg dry air) (relative humidity around 45% at 25°C).
  • a fourth test is performed to test the performance of heat pipe heat exchanger and its effect on the regeneration rate using the LDDS testing bed combined with heat pipe heat exchanger.
  • the heat recovery efficiency is 50%.
  • the regeneration speed is increased by about 30% when the desiccant concentration is from 25% to 37%.
  • Fig. 12 shows the testing results for the third test.
  • Three factors will affect the outlet air humidity, namely, desiccant concentration, flow rate and temperature for a given supply air flow rate. If the range of desiccant concentration is fixed between about 28%-36.5%, the outlet air humidity can be controlled by adjusting the temperature in the range about 16- 32°C and flow rate in the range 17-29L/min, respectively.

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  • Engineering & Computer Science (AREA)
  • Chemical & Material Sciences (AREA)
  • Combustion & Propulsion (AREA)
  • Mechanical Engineering (AREA)
  • General Engineering & Computer Science (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Sustainable Development (AREA)
  • Central Air Conditioning (AREA)
  • Drying Of Gases (AREA)

Abstract

L'invention concerne un système de déshumidification avec un déshumidificateur contenant un dessiccant servant à déshumidifier un flux d'air de procédé et un régénérateur servant à régénérer le dessiccant. De plus, le déshumidificateur comprend un refroidisseur qui lui est raccordé, le refroidisseur étant conçu pour refroidir le dessiccant de façon que celui-ci soit refroidi par le refroidisseur avant d'entrer dans le déshumidificateur. De plus, le régénérateur comprend un système de chauffage qui lui est raccordé, le système de chauffage étant conçu pour chauffer le dessiccant de façon que celui-ci soit chauffé par le système de chauffage avant d'entrer dans le régénérateur. En outre, il y a une conduite de transfert de dessiccant raccordée au déshumidificateur et au régénérateur et une conduite d'alimentation en dessiccant raccordée au déshumidificateur et au régénérateur de façon que la conduite de transfert de dessiccant et la conduite d'alimentation en dessiccant forment une boucle de transfert de dessiccant traversant le déshumidificateur et le régénérateur telle que la boucle de dessiccant effectue le transfert de dessiccant du déshumidificateur au régénérateur par la conduite de transfert de dessiccant et l'alimentation en dessiccant du régénérateur au déshumidificateur par la conduite d'alimentation en dessiccant. En outre, il y a un réservoir de dessiccant concentré servant à stocker le dessiccant, le réservoir de dessiccant concentré étant situé le long de la conduite d'alimentation en dessiccant, et un réservoir de dessiccant dilué servant à stocker le dessiccant, le réservoir de dessiccant dilué étant situé le long de la conduite de transfert de dessiccant. L'invention concerne une méthode de déshumidification du flux d'air de procédé à l'aide du système de déshumidification et un système de refroidissement d'air incorporant le système de déshumidification.
PCT/SG2013/000198 2012-05-16 2013-05-16 Système de déshumidification, méthode de déshumidification et système de refroidissement WO2013172789A1 (fr)

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CN104296242A (zh) * 2014-09-03 2015-01-21 安徽华通铸业有限公司 柜式分体溶液调湿新风空调机
CN104833014A (zh) * 2015-05-03 2015-08-12 江苏格瑞力德空调制冷设备有限公司 自带全部冷热源且外输冷热媒的溶液式全空气空调机组
US9557093B2 (en) 2014-07-01 2017-01-31 Mekano Elektronik Teknik Sanayi Ve Ticaret Limited Sirketi Industrial dehumidifier system
EP3269980A1 (fr) * 2016-07-15 2018-01-17 Ingersoll-Rand Company Système de compresseur et soupape de régulation de lubrifiant
US9982901B2 (en) 2014-04-15 2018-05-29 Andrew Mongar Air conditioning method using a staged process using a liquid desiccant
EP3221648A4 (fr) * 2014-11-21 2018-06-27 7AC Technologies, Inc. Procédés et systèmes de conditionnement d'air à déshydratant liquide, du type divisé (split) et de petite dimension
WO2018182547A1 (fr) 2017-03-29 2018-10-04 Eneko Havalandirma Ve Isi Ekonomi̇si̇ Si̇stem Teknoloji̇leri̇ Maki̇ne San. Ve Ti̇c. A.Ş. Dispositifs et procédé de déshumidification
US10168056B2 (en) 2010-05-25 2019-01-01 7Ac Technologies, Inc. Desiccant air conditioning methods and systems using evaporative chiller
US10240602B2 (en) 2016-07-15 2019-03-26 Ingersoll-Rand Company Compressor system and method for conditioning inlet air
US10323867B2 (en) 2014-03-20 2019-06-18 7Ac Technologies, Inc. Rooftop liquid desiccant systems and methods
US10443868B2 (en) 2012-06-11 2019-10-15 7Ac Technologies, Inc. Methods and systems for turbulent, corrosion resistant heat exchangers
US10619867B2 (en) 2013-03-14 2020-04-14 7Ac Technologies, Inc. Methods and systems for mini-split liquid desiccant air conditioning
US10619868B2 (en) 2013-06-12 2020-04-14 7Ac Technologies, Inc. In-ceiling liquid desiccant air conditioning system
CN111189130A (zh) * 2020-02-07 2020-05-22 北京华创瑞风空调科技有限公司 溶液再生装置及具有其的空气除湿装置
US10760830B2 (en) 2013-03-01 2020-09-01 7Ac Technologies, Inc. Desiccant air conditioning methods and systems
US10921001B2 (en) 2017-11-01 2021-02-16 7Ac Technologies, Inc. Methods and apparatus for uniform distribution of liquid desiccant in membrane modules in liquid desiccant air-conditioning systems
US10941948B2 (en) 2017-11-01 2021-03-09 7Ac Technologies, Inc. Tank system for liquid desiccant air conditioning system
US11022330B2 (en) 2018-05-18 2021-06-01 Emerson Climate Technologies, Inc. Three-way heat exchangers for liquid desiccant air-conditioning systems and methods of manufacture
CN112880067A (zh) * 2021-01-22 2021-06-01 上海交通大学 吸附式制冷与除湿复合系统及其方法
CN113056143A (zh) * 2021-03-26 2021-06-29 赖南昌 一种具有低功耗除湿功能的电气控制柜及其使用方法
CN113757841A (zh) * 2021-08-19 2021-12-07 东南大学 一种低品位热梯级驱动热湿解耦处理空调系统
WO2022216155A1 (fr) * 2021-04-08 2022-10-13 Solutherm B.V. Système et procédé de déshumidification de l'air

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US11624517B2 (en) 2010-05-25 2023-04-11 Emerson Climate Technologies, Inc. Liquid desiccant air conditioning systems and methods
US10753624B2 (en) 2010-05-25 2020-08-25 7Ac Technologies, Inc. Desiccant air conditioning methods and systems using evaporative chiller
US10168056B2 (en) 2010-05-25 2019-01-01 7Ac Technologies, Inc. Desiccant air conditioning methods and systems using evaporative chiller
US10443868B2 (en) 2012-06-11 2019-10-15 7Ac Technologies, Inc. Methods and systems for turbulent, corrosion resistant heat exchangers
US11098909B2 (en) 2012-06-11 2021-08-24 Emerson Climate Technologies, Inc. Methods and systems for turbulent, corrosion resistant heat exchangers
US10760830B2 (en) 2013-03-01 2020-09-01 7Ac Technologies, Inc. Desiccant air conditioning methods and systems
US10619867B2 (en) 2013-03-14 2020-04-14 7Ac Technologies, Inc. Methods and systems for mini-split liquid desiccant air conditioning
US10619868B2 (en) 2013-06-12 2020-04-14 7Ac Technologies, Inc. In-ceiling liquid desiccant air conditioning system
US10619895B1 (en) 2014-03-20 2020-04-14 7Ac Technologies, Inc. Rooftop liquid desiccant systems and methods
US10323867B2 (en) 2014-03-20 2019-06-18 7Ac Technologies, Inc. Rooftop liquid desiccant systems and methods
US9982901B2 (en) 2014-04-15 2018-05-29 Andrew Mongar Air conditioning method using a staged process using a liquid desiccant
US10823436B2 (en) 2014-04-15 2020-11-03 Airgreen, Inc. Air conditioning method using a staged process using a liquid desiccant
US9557093B2 (en) 2014-07-01 2017-01-31 Mekano Elektronik Teknik Sanayi Ve Ticaret Limited Sirketi Industrial dehumidifier system
CN104296242A (zh) * 2014-09-03 2015-01-21 安徽华通铸业有限公司 柜式分体溶液调湿新风空调机
EP3221648A4 (fr) * 2014-11-21 2018-06-27 7AC Technologies, Inc. Procédés et systèmes de conditionnement d'air à déshydratant liquide, du type divisé (split) et de petite dimension
EP3667190A1 (fr) * 2014-11-21 2020-06-17 7AC Technologies, Inc. Procédés et systèmes pour une climatisation mini split à déshydratant liquide
US10731876B2 (en) 2014-11-21 2020-08-04 7Ac Technologies, Inc. Methods and systems for mini-split liquid desiccant air conditioning
CN104833014A (zh) * 2015-05-03 2015-08-12 江苏格瑞力德空调制冷设备有限公司 自带全部冷热源且外输冷热媒的溶液式全空气空调机组
US10724524B2 (en) 2016-07-15 2020-07-28 Ingersoll-Rand Industrial U.S., Inc Compressor system and lubricant control valve to regulate temperature of a lubricant
US10240602B2 (en) 2016-07-15 2019-03-26 Ingersoll-Rand Company Compressor system and method for conditioning inlet air
EP3269980A1 (fr) * 2016-07-15 2018-01-17 Ingersoll-Rand Company Système de compresseur et soupape de régulation de lubrifiant
WO2018182547A1 (fr) 2017-03-29 2018-10-04 Eneko Havalandirma Ve Isi Ekonomi̇si̇ Si̇stem Teknoloji̇leri̇ Maki̇ne San. Ve Ti̇c. A.Ş. Dispositifs et procédé de déshumidification
US10921001B2 (en) 2017-11-01 2021-02-16 7Ac Technologies, Inc. Methods and apparatus for uniform distribution of liquid desiccant in membrane modules in liquid desiccant air-conditioning systems
US10941948B2 (en) 2017-11-01 2021-03-09 7Ac Technologies, Inc. Tank system for liquid desiccant air conditioning system
EP3704415A4 (fr) * 2017-11-01 2021-11-03 7AC Technologies, Inc. Système de réservoir pour système de conditionnement d'air à déshydratant liquide
US11022330B2 (en) 2018-05-18 2021-06-01 Emerson Climate Technologies, Inc. Three-way heat exchangers for liquid desiccant air-conditioning systems and methods of manufacture
CN111189130A (zh) * 2020-02-07 2020-05-22 北京华创瑞风空调科技有限公司 溶液再生装置及具有其的空气除湿装置
CN112880067B (zh) * 2021-01-22 2022-04-26 上海交通大学 吸附式制冷与除湿复合系统及其方法
CN112880067A (zh) * 2021-01-22 2021-06-01 上海交通大学 吸附式制冷与除湿复合系统及其方法
CN113056143A (zh) * 2021-03-26 2021-06-29 赖南昌 一种具有低功耗除湿功能的电气控制柜及其使用方法
CN113056143B (zh) * 2021-03-26 2022-10-25 湖南嵘晟时代自动化科技有限公司 一种具有低功耗除湿功能的电气控制柜及其使用方法
WO2022216155A1 (fr) * 2021-04-08 2022-10-13 Solutherm B.V. Système et procédé de déshumidification de l'air
NL2027945B1 (en) * 2021-04-08 2022-10-20 Solutherm B V A system and method for dehumidifying air
CN113757841A (zh) * 2021-08-19 2021-12-07 东南大学 一种低品位热梯级驱动热湿解耦处理空调系统

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