WO2013170543A1 - 一种升温蓄热的纤维及其制备方法和纺织品 - Google Patents

一种升温蓄热的纤维及其制备方法和纺织品 Download PDF

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Publication number
WO2013170543A1
WO2013170543A1 PCT/CN2012/080093 CN2012080093W WO2013170543A1 WO 2013170543 A1 WO2013170543 A1 WO 2013170543A1 CN 2012080093 W CN2012080093 W CN 2012080093W WO 2013170543 A1 WO2013170543 A1 WO 2013170543A1
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Prior art keywords
fiber
textile
heat
preparation
weight
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PCT/CN2012/080093
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English (en)
French (fr)
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毛盈军
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Mao Yingjun
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Publication of WO2013170543A1 publication Critical patent/WO2013170543A1/zh

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    • DTEXTILES; PAPER
    • D01NATURAL OR MAN-MADE THREADS OR FIBRES; SPINNING
    • D01FCHEMICAL FEATURES IN THE MANUFACTURE OF ARTIFICIAL FILAMENTS, THREADS, FIBRES, BRISTLES OR RIBBONS; APPARATUS SPECIALLY ADAPTED FOR THE MANUFACTURE OF CARBON FILAMENTS
    • D01F1/00General methods for the manufacture of artificial filaments or the like
    • D01F1/02Addition of substances to the spinning solution or to the melt
    • D01F1/10Other agents for modifying properties
    • DTEXTILES; PAPER
    • D01NATURAL OR MAN-MADE THREADS OR FIBRES; SPINNING
    • D01FCHEMICAL FEATURES IN THE MANUFACTURE OF ARTIFICIAL FILAMENTS, THREADS, FIBRES, BRISTLES OR RIBBONS; APPARATUS SPECIALLY ADAPTED FOR THE MANUFACTURE OF CARBON FILAMENTS
    • D01F2/00Monocomponent artificial filaments or the like of cellulose or cellulose derivatives; Manufacture thereof
    • D01F2/06Monocomponent artificial filaments or the like of cellulose or cellulose derivatives; Manufacture thereof from viscose
    • D01F2/08Composition of the spinning solution or the bath

Definitions

  • the invention relates to a textile fiber and a preparation method thereof, in particular to a fiber for heating and storing heat, a preparation method thereof and a textile. Background technique
  • a kind of thermal insulation garment material produced in Japan is a composite fiber composed of electrothermal materials.
  • the principle is like an electric blanket.
  • the conductive fiber is used to heat the fiber to achieve heating effect.
  • the garment made of this fiber looks like a thin single coat. It is actually an electric heating suit.
  • the energy comes from a rechargeable battery that is carried around. In the cold winter, its constant heat is enough to withstand the cold.
  • Sun velvet is a new generation of representative materials made according to the principle of space cotton. It fully fluffs the traditional 100% wool fiber and fluffs it between the two soft mirrors to form a thin and controllable thermal convection barrier (gas enthalpy) with extremely low thermal conductivity and at the same time
  • the heat ray has a reflection effect, achieving double warming effect. Because the gas content in the gas is 90%, the sun velvet is light, soft and warm. Its fiber volume per unit volume is 2 / 3 less than cotton, 4 / 5 less than down, and the finished garment is beautiful and not bloated.
  • the clo value was 3.062.
  • the two-layer mirror has openable and closed micropores, like the pores of the skin. It can be opened for heat when it is hot. It can be turned off when it is cold, and the temperature is adjustable and breathable. It is the ideal material for autumn and winter.
  • Such a velvet material also has defects such as complicated manufacturing processes, high cost, and difficulty in industrialization.
  • An object of the present invention is to provide a heat-storing heat-storing fiber which is easy to manufacture, low in cost, and easy to industrially implement, a preparation method thereof and a textile.
  • the present invention provides a fiber for heating and heat storage, the fiber comprising a conventional textile fiber and a nano unit comprising 0.13% by weight of the total weight, the nano unit comprising micro particles of 300 to 8000 nm,
  • the microparticles include titanium, sulfur or a mixture thereof.
  • the conventional textile fibers comprise chemical fibers, and the chemical fibers comprise rayon and/or synthetic fibers.
  • the fine particles include 500 to 10,000 by weight of titanium and 50 to 100 by weight of sulfur.
  • the microparticles comprise 500 to 10,000 by weight of titanium and 50 to 100 by weight of sulfur.
  • the microparticles further comprise 50 3000 weight units of silicon and 10 to 500 weight units of iron.
  • Another object of the present invention is to provide a method for preparing a textile fiber which is rapidly heated and stored in the presence of light, and the preparation method comprises the following steps: A. A natural high molecular substance or an inorganic substance or a synthetic high molecular substance Or an inorganic substance is made into a spinning melt or a solution; B. adding the above-mentioned nano unit to the spinning melt or solution; C, scooping out by a spinning mechanism to form a fiber.
  • the advantages of the present invention are: Since the present invention adds a certain proportion of microparticle nano-units of 300 to 8000 nm in the conventional textile ⁇ dimension, the ⁇ dimension of the invention has an unexpected rapid temperature-increasing effect under the same illumination time and illumination intensity, and at the same time The invention has better heat storage performance than the conventional chemical fiber after the light is stopped, and the invention has lower manufacturing cost, simple manufacturing process and easy comparison with the existing heat generation. The advantages of industrial production and so on are better new heat-generating fiber materials in low temperature environments.
  • Figure 1 is a view showing a technical effect of the present invention
  • Fig. 2 is a temperature-time curve of the measurement method in Example 1. Detailed description of the invention
  • FIG. 1 there is shown a detection embodiment of the heat-generating effect of the heat-storing heat-storing fiber of the present invention.
  • Inspection unit Japan General Consortium Legal Person BOKEN Quality Evaluation Structure Kinki Office
  • Test items Temperature measurement, the test method is as follows:
  • the fiber of the present invention is a textile fiber comprising about 2.9% by weight of the total weight of the nano unit in the conventional textile fiber, the nanometer having a particle size of about 300 nm; the fine particle comprising 9000 weight unit of titanium and 90 weight Unit of sulfur (may also be added to only one of them), as well as other traces Elements, the nanocells of the present invention can be added in a fiber manufacturing process using any of the prior art.
  • Control group fiber Conventional textiles without nano-units.
  • weight unit described in the present invention preferably has a weight ratio of "micrograms/kg", and may be weighed according to other weight units according to actual needs.
  • thermocouple thermometer B is placed inside the central portion of the fabric S (15 cm X 15 cm) to be tested, and the following conditions are met.
  • the temperature change of the fabric S to be tested under illumination was measured every 20 minutes:
  • PRF-500WB reflector lamp produced by Panasonic Corporation A;
  • Measurement conditions Firstly, the reflector lamp A is irradiated for 10 minutes, the reflector lamp is turned off immediately, and it is measured for 10 minutes without being irradiated;
  • Measurement environment 20 ° C, 65 % H;
  • Determination method Firstly, the two fabrics to be tested are measured together, and then the positions of the two fabrics to be tested are exchanged and measured again. Finally, the average value of the two determinations is calculated to obtain the test result.
  • the temperature-time relationship curve of the above detection result is shown in FIG. 2, wherein the fabric to be tested corresponding to the curve with the upper position is included in the fabric to be tested, and the curve corresponding to the lower portion is to be tested.
  • the fabrics are ordinary textile fabrics which do not contain the invention.
  • the temperature-sensing heat storage of the present invention is more remarkable and expected than the conventional chemical fiber under the same light intensity and illumination time.
  • the rapid heating effect is not achieved, and at the same time, after the light is stopped, it has better heat storage performance than the conventional chemical fiber, as shown in Fig. 2.
  • Example 2
  • test sample is a textile fiber in which about 0.2% by weight of the nano unit is added to the conventional textile fiber, and the nano cell has a particle size of about 8000 nm; Including 500 weight units of titanium, and 3000 weight units of silicon and 12 weight units of iron, the nano-units of the present invention can be added in a fiber manufacturing process using any of the prior art.
  • This embodiment adopts a preparation method of textile fiber which is rapidly heated and stored in the light, and includes the following steps: A. A natural polymer material or an inorganic substance (such as viscose) or synthetic a high molecular substance or an inorganic substance (such as nylon or acrylic) to form a spinning melt or a solution; B. adding the above-mentioned nano unit in the spinning melt or solution; C, extruding through a spinning mechanism, Forming fibers.
  • the other process steps are the same as those of the prior art fiber preparation method, and are not described herein again.
  • Example 3 The temperature-time relationship curve of the detection result of this embodiment is omitted.
  • test sample is a textile fiber in which about 1.5% by weight of the nano unit is added to the conventional textile fiber, and the nano cell has a particle size of about 4000 nm; Including 55 parts by weight of sulfur, and 50 parts by weight of silicon and 500 parts by weight of iron, the nanounit of the present invention can be fabricated in any of the prior art fibers. Add in the process.
  • This embodiment adopts a preparation method of textile fiber which is rapidly heated and stored in the light, and includes a preparation step of the textile fiberized masterbatch, and the nano unit is added during the preparation of the plutonium masterbatch. And then produce the ⁇ .
  • the other process steps of the preparation method of the present embodiment are the same as those of the prior art, and will not be described herein.
  • the present invention employs 1 to 3% by weight of a nano-unit of 300 to 8000 nm to a conventional chemical enthalpy, so that the new chemical enthalpy has an unexpected temperature rise and The beneficial effects of heat storage.
  • a nano-unit of 300 to 8000 nm to a conventional chemical enthalpy
  • the new chemical enthalpy has an unexpected temperature rise and The beneficial effects of heat storage.
  • thermal effect can be added under the premise of the textile process, and the chemical vapor formed by the textiles will have better heat and storage.
  • another object of the present invention is to provide a textile which is rapidly heated and stored in the presence of light, such as a knitted or woven product, in which at least part of the above-mentioned fibers are included, and of course, the present invention can also be used in its entirety. Made of fiber that heats up and stores heat.
  • the heat-up and heat-storing fiber of the invention and the preparation method thereof can be effectively used for preparing high-quality new heat-storing heat-storage fiber fabric, and can be effectively applied in a low-temperature environment, thereby achieving an unexpected rapid temperature-increasing effect of light. And excellent heat storage performance. Further, the heat-storing and heat-storing fiber of the present invention has advantages such as lower manufacturing cost, simple manufacturing process, and ease of industrial production as compared with the conventional chemical vapor.

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  • Engineering & Computer Science (AREA)
  • Chemical & Material Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • General Chemical & Material Sciences (AREA)
  • Textile Engineering (AREA)
  • Manufacturing & Machinery (AREA)
  • Artificial Filaments (AREA)

Abstract

一种升温蓄热的纤维及其制备方法和使用该纤维制造的纺织品。升温蓄热的纤维包括:常规纺织纤维和占总量0.1-3%重量份的纳米单元,纳米单元包括300-8000纳米的微粒子,微粒子包括钛、硫或它们的混合物。

Description

一种升温蓄热的纤维及其制备方法和纺织品 技术领域
本发明涉及一种紡织纤维及其制备方法, 特別是涉及一种升温蓄热的 纤维及其制备方法和紡织品。 背景技术
传统纤维及纺织品的保温是以阻止身体所发出的热逃逸为主。 随着科 学的发展, 人们也研制出了部分具有发热功能的纤维, 例如:
1. 电热纤维
日本试制的一种保温服装材料, 是利用电热材料参与组成的复合纤维, 其原理如同电热毯, 利用导电纤维通电使纤维发热, 以达到取暖的效果。 用该纤维制成的服装, 外形似一件薄薄的单衣, 其实为一件电热衣, 能源 来自随身携带的可充电电池, 在寒冷的冬季里, 其源源不断的热量, 足以 抵御严寒。
此种电热纤维的缺陷在于, 制造成本高昂, 需要携带充电电池进行供 电, 日常生活中使用起来颇为不便。
2. 太阳绒
太阳绒是根据太空棉原理制成的新一代具有代表性的材料。 它是将传 统的 100 %羊毛纤维充分绒化、 蓬松后置于两层软镜面之间, 使其形成薄厚 可控的热对流阻挡层(气嚢), 其导热系数极低, 同时对人体的热射线有反射 作用, 实现了双重保暖的功效。 由于气嚢中气体含量占 90 %, 因而太阳绒 既轻便柔软又保暖。 其单位体积内纤维量比棉花少 2 / 3, 比羽绒少 4 / 5, 制成的服装美观而不臃肿。 经检测其克罗(clo)值为 3.062。 两层镜面上有可 开闭的微孔, 如同皮肤的毛孔, 热时可张开散热, 冷时又可关闭保温, 温 度可调且具有透气性, 是秋冬季的理想衣料。
此种太阳绒材料也存在有制造工艺复杂, 成本高昂, 难以产业化等缺 陷。
3. 化学保温、 调温纤维
有人利用化学方法制取保温、 调温纤维。 例如有一种附有一层不透水 的薄膜, 内装硫酸钠的纺织品, 当硫酸钠受热后会液化贮热, 其贮热能力 比水强 60倍, 从而使体感温度下降; 而遇冷时^ ^酸钠会固化, 同时将吸收 的热量散发出来。
此种材料在制成紡织品后, 容易在日常生活中由于各种刮蹭、 碰撞而 产生泄漏, 因此, 其实用性还有待于进一步提高。 发明内容
本发明的目的是提出一种制造方便、 成本低廉、 易于产业化实施的升温蓄 热纤维及其制备方法和纺织品。
为实现上述目的, 本发明提供了一种升温蓄热的纤维, 所述的纤维包括常 规纺织纤维和占总重量 0.1 3%重量份的纳米单元, 所述纳米单元包括 300 ~ 8000纳米的微粒子, 所述的微粒子包括钛、 硫或它们的混合物。
优选地, 所述常规紡织纤维包括化学纤维, 所述的化学纤维包括人造纤维 和 /或合成纤维。
更优选地, 包括占总重量 1.5 ~ 3%重量份的 300 - 4000纳米的微粒子。 进一步, 在所述的纳米单元中, 所述微粒子包括 500 ~ 10000重量单元的 钛和 50 ~ 100重量单元的硫。
优选地, 包括占总重量 0,1 - 1.5%重量份的 4000 ~ 8000纳米的微粒子。 更优选地, 在所述的纳米单元中, 所述微粒子包括 500 ~ 10000重量单元 的钛和 50 ~ 100重量单元的硫。
优选地, 在所述的纳米单元中, 所述的微粒子还包括 50 3000重量单元 的娃和 10 ~ 500重量单元的铁。
本发明的另一目的在于提供一种遇光快速升温并蓄热的纺织纤维的制备 方法, 所述制备方法包括如下步骤: A、 将天然的高分子物质或无机物、 或者 合成的高分子物质或无机物制成纺丝熔体或溶液; B、 在所述紡丝熔体或溶液 中添加上述的纳米单元; C、 经喷丝机构挢出, 形成纤维。
本发明的又一目的在于提供一种遇光快速升温并蓄热的纺织纤维的制备 方法, 所述制备方法包括紡织纤维化纤母粒的制备步骤, 在化纤母粒的制备过 程中, 添加上述的纳米单元。
本发明的再一目的在于提供一种遇光快速升温并蓄热的紡织品, 该纺织品 至少包括部分上述的纤维。
基于上述技术方案, 本发明的优点是: 由于本发明在常规紡织紆维中加入了一定比例 300 ~ 8000纳米的微粒子纳 米单元, 使得本发明的紆维在相同的光照时间和光照强度下, 具有预料不到的 遇光快速升温效果, 同时, 本发明的紆维在光照停止后, 比常规的化学纤维还 具有更好的蓄热性能, 并且本发明相对于现有的发热紆维而言, 具有制造成本 较低、 制造工艺简单、 易于工业化生产等等优点, 是在低温环境下较好的新型 发热纤维材料。
本发明的附加方面和优点将在下面的描述中部分给出, 部分将从下面 的描述中变得明显, 或通过本发明的实践了解到。 附图说明
本发明的上述和 /或附加的方面和优点从结合下面附图对实施例的描述 中将变得明显和容易理解, 其中:
图 1为本发明技术效果的检测装置; 以及
图 2为实施例 1中测量方法的温度-时间变化曲线。 发明详细描述
下面详细描述本发明的实施例, 所述实施例的示例在附图中示出, 其 中自始至终相同或类似的标号表示相同或类似的元件或具有相同或类似功 能的元件。 下面通过参考附图描述的实施例是示例性的, 仅用于解释本发 明, 而不能理解为对本发明的限制。 实施例中未注明具体技术或条件的, 按 照本领域内的文献所描述的技术或条件或者按照产品说明书进行。 所用试剂或 仪器未注明生产厂商者, 均为可以通过市购莰得的常规产品。
实施例 1:
参见图 1, 其示出了本发明的升温蓄热的纤维发热效果的检测实施例。 检测单位: 日本一般财团法人 BOKEN品质评价结构近畿事务所
品质试验 4艮告书编号: 11604789 - 1
检测项目: 温度测定, 试验方法如下:
1、 检测样品
①: 本发明纤维: 为在常规纺织纤维中加入了约占总重量 2.9%重量份纳 米单元的紡织纤维, 该纳米单元的微粒大小约 300纳米; 所述微粒子包括 9000 重量单元的钛和 90重量单元的硫(也可以只加入其中的一种) , 以及其他微量 元素,本发明的纳米单元可以采用现有技术中的任意一种在纤维制造的工艺中 进行添加。
②: 对照组纤维: 不含纳米单元的常规紡织紆维。
需要说明的是: 本发明所述的 "重量单元"优选为 "微克 /公斤" 的重量比 值, 也可以根据实际需要按照其他重量单元进行称量。
2、 检测方法:
如图 1所示,将两块层状的紆维待测面料 S放置在泡沫塑料台面 C上,在 待测面料 S ( 15cm X 15cm )中央部分的内侧设置热电偶温度计 B, 并按照下列 条件每隔 20分钟测定一次待测面料 S在光照下的温度变化:
使用光源: 松下公司生产的 PRF-500WB反射灯 A;
照射距离: L = 30cm;
测定条件: 先用反射灯 A照射 10分钟, 立刻关闭反射灯, 并在不照射的 状态下持续 10分钟来测定;
测定环境: 20°C、 65 % H;
测定方法: 先将两块待测面料一起测定, 然后交换两块待测面料的位置后 再次测定, 最后计算两次测定的平均值得出试验结果。
3、 上述样品的实验检测结果为:
温度 ( V ) 温度差
经过时间
① ② △T =①-②
0 20.7 20.7 0.0
1 35.8 30.9 4.9
2 41.9 35.0 6,9
3 46.8 38.4 8.4
4 50.1 40.8 9.3
5 52.3 42.6 9.7
6 53.9 43.8 10.1
7 54.6 44.6 10.0
8 55.5 45.3 10.2
9 56.2 45.8 10.4
10 56.8 46.3 10.5 11 40.8 36.1 4.7
12 34.5 31.7 2.8
13 31.2 29.2 2.0
14 29.0 27.5 1.5
15 27.6 26.3 1.3
16 26.4 25.4 1.0
17 25.5 24.6 0.9
18 24.8 24.0 0.8
19 24.2 23.6 0.6
20 23.7 23.3 0.4
上述检测结果的温度-时间关系曲线参见附图 2 所示, 其中, 上部位置较 高的曲线所对应的待测面料中包含本发明的紆维, 而下部位置较低的曲线所对 应的待测面料中为未包含本发明紆维的普通紡织面料。
通过该日本一般财团法人 BOKEN品质评价结构近畿事务所的上述检测结 构可以得出, 本发明升温蓄热的紆维在相同的光照强度和光照时间下, 比常规 的化学纤维具有更加显著的、预料不到的快速升温效果, 同时,在光照停止后, 比常规的化学纤维还具有更好的蓄热性能, 如图 2所示。 实施例 2:
本实施例与上述实施例的不同之处在于,检测样品是在常规紡织纤维中加 入了约占总重量 0.2%重量份纳米单元的纺织纤维, 该纳米单元的微粒大小约 8000纳米; 所述微粒子包括 500重量单元的钛, 以及 3000重量单元的硅和 12 重量单元的铁, 本发明的纳米单元可以釆用现有技术中的任意一种在纤维制造 的工艺中进行添加。
例如: 本实施例采用了一种遇光快速升温并蓄热的紡织纤维的制备方法, 其包括如下步骤: A、 将天然的高分子物质或无机物(如: 粘胶紆维)、 或者合 成的高分子物质或无机物 (如: 锦纶或腈纶)制成紡丝熔体或溶液; B、 在所 述紡丝熔体或溶液中添加上述的纳米单元; C、 经喷丝机构挤出, 形成纤维。 其他工艺步驟与现有技术的纤维制备方法相同, 在此不再赘述。
该样品的实验检测结果为: 温度 ( V ) 温度差
经过时间
③ ④ △T =③-④
0 20.7 20.7 0.0
1 35.7 30.9 4.8
2 41.6 35.0 6,6
3 46.6 38.4 8,2
4 50.0 40.8 9,2
5 52.1 42.6 9.5
6 53.8 43.8 10.0
7 54.7 44.6 10.1
8 55.5 45.3 10.2
9 56.1 45.8 10.3
10 56.7 46.3 10.4
11 40.9 36.1 4.8
12 34.4 31.7 2.7
13 31.3 29.2 2.1
14 29.2 27.5 1.7
15 27.5 26.3 1.2
16 26.4 25.4 1.0
17 25.5 24.6 0.9
18 24.7 24.0 0.7
19 24.1 23.6 0.5
20 23.7 23.3 0.4
本实施例检测结果的温度-时间关系曲线: 略。 实施例 3:
本实施例与上述实施例的不同之处在于,检测样品是在常规紡织纤维中加 入了约占总重量 1.5%重量份纳米单元的纺织纤维, 该纳米单元的微粒大小约 4000纳米; 所述微粒子包括 55重量单元的硫, 以及 50重量单元的硅和 500 重量单元的铁, 本发明的纳米单元可以釆用现有技术中的任意一种在纤维制造 的工艺中进行添加。
例如: 本实施例采用了一种遇光快速升温并蓄热的紡织纤维的制备方法, 其包括紡织纤维化紆母粒的制备步骤, 在化紆母粒的制备过程中, 添加上述的 纳米单元, 然后生产出紆维。 本实施例紆维制备方法的其他工艺步骤与现有技 术的纤维制备方法相同, 在此不再赘述。
该样品的实验检测结果为: 温度( °C ) 温度差
经过时间
⑤ ⑥ ΔΤ =⑤-⑥
0 20.7 20.7 0.0
1 35.9 30.9 5.0
2 42.0 35.0 7.0
3 46.9 38.4 8.5
4 50.2 40.8 9,4
5 52.4 42.6 9.8
6 54.0 43.8 10.2
7 54.8 44.6 10.2
8 55.6 45.3 10.3
9 56.2 45.8 10.4
10 56.9 46.3 10.6
11 40.9 36.1 4.8
12 34.6 31.7 2.9
13 31.4 29.2 2.2
14 29.2 27.5 1.7
15 27.8 26.3 1.5
16 26.7 25.4 1.3
17 25.6 24.6 1.0
18 24.9 24.0 0.9
19 24.4 23.6 0.8
20 23.8 23.3 0.5 本实施例检测结果的温度-时间关系曲线: 略。
由于现有的紡织工艺所限, 本发明采用向常规化学紆维中加入 1 ~ 3 %重 量份的 300 ~ 8000纳米的纳米单元, 以使新的化学紆维具有预料不到遇光快速 升温并蓄热的有益效果。 但本领域技术人员可以理解, 在紡织工艺允许的前提 下,可以加入更多重量份和 /或更小纳米颗粒的纳米单元,其所形成的化学紆维 亦将会有较好的发热、 蓄热效果。
此外, 本发明的另一目的是提供一种遇光快速升温并蓄热的紡织品, 例如 针织或梭织产品, 在该纺织品中, 至少包括部分上述的纤维, 当然, 也可以全 部使用本发明升温蓄热的纤维制成。
显而易见, 本领域的普通技术人 , 可以用本发明一种升温蓄热的纤维及 其制备方法和纺织品, 构成各种类型的紡织纤维、 紡织品及其制备方法。 工业实用性
本发明的升温蓄热的纤维及其制备方法, 能够有效地用于制备优质的新型 升温蓄热纤维织物, 进而能够有效地应用于低温环境下, 从而能够达到预料不 到的遇光快速升温效果和优良的蓄热性能。 并且, 本发明的升温蓄热的纤维, 与常规的化学紆维相比, 具有制造成本较低、 制造工艺简单、 易于工业化生产 等优点。 尽管本发明的具体实施方式已经得到详细的描述, 本领域技术人员将会理 解。 根据已经公开的所有教导, 可以对那些细节进行各种修改和替换, 这些改 变均在本发明的保护范围之内。本发明的全部范围由所附权利要求及其任何等 同物给出。
在本说明书的描述中, 参考术语 "一个实施例"、 "一些实施例"、 "示意性 实施例"、 "示例"、 "具体示例"、 或 "一些示例" 等的描述意指结合该实施例 或示例描述的具体特征、 结构、 材料或者特点包含于本发明的至少一个实施例 或示例中。 在本说明书中, 对上述术语的示意性表述不一定指的是相同的实施 例或示例。 而且, 描述的具体特征、 结构、 材料或者特点可以在任何的一个或 多个实施例或示例中以合适的方式结合。

Claims

权利要求书
1、 一种升温蓄热的紆维, 其特征在于: 所述的纤维包括常规紡织纤维和 占总重量 0,1 - 3%重量份的纳米单元, 所述纳米单元包括 300 ~ 8000纳米的微 粒子, 所述的微粒子包括钛、 硫或它们的混合物。
2、 根据权利要求 1所述的紆维, 其特征在于: 所述常规紡织紆维包括化 学紆维, 所述的化学纤维包括人造紆维和 /或合成纤维。
3、 根据权利要求 2所述的纤维, 其特征在于: 包括占总重量 1.5 3%重 量份的 300 4000纳米的微粒子。
4、 根据权利要求 3所述的纤维, 其特征在于: 在所述的纳米单元中, 所 述微粒子包括 500 ~ 10000重量单元的钛和 50 - 100重量单元的硫。
5、 根据权利要求 2所述的纤维, 其特征在于: 包括占总重量 0.1 1.5%重 量份的 4000 8000纳米的微粒子。
6、 根据权利要求 5所述的紆维, 其特征在于: 在所述的纳米单元中, 所 述微粒子包括 500 ~ 10000重量单元的钛和 50 - 100重量单元的硫。
7、 根据权利要求 4或 6所述的纤维, 其特征在于: 在所述的纳米单元中, 所述的微粒子还包括 50 - 3000重量单元的硅和 10 ~ 500重量单元的铁。
8、—种遇光快速升温并蓄热的紡织紆维的制备方法, 其特征在于: 所述制 备方法包括如下步骤:
A、 将天然的高分子物质或无机物、 或者合成的高分子物质或无机物制成 紡丝熔体或溶液;
B、在所述紡丝烺体或溶液中添加上述任意一项权利要求所述的纳米单元;
C、 经喷丝机构挤出, 形成纤维。
9、 一种遇光快速升温并蓄热的紡织纤维的制备方法, 其特征在于: 所述 制备方法包括纺织纤维化纤母粒的制备步骤, 在化纤母粒的制备过程中, 添加 权利要求 1 ~ 7中任意一项权利要求所述的纳米单元。
10、 一种遇光快速升温并蓄热的紡织品, 其特征在于: 读紡织品至少包括 部分上述任意一项权利要求所述的紆维。
PCT/CN2012/080093 2012-05-14 2012-08-14 一种升温蓄热的纤维及其制备方法和纺织品 WO2013170543A1 (zh)

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