JP7465588B2 - 両面恒温織物及びその製造方法 - Google Patents
両面恒温織物及びその製造方法 Download PDFInfo
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- JP7465588B2 JP7465588B2 JP2022581622A JP2022581622A JP7465588B2 JP 7465588 B2 JP7465588 B2 JP 7465588B2 JP 2022581622 A JP2022581622 A JP 2022581622A JP 2022581622 A JP2022581622 A JP 2022581622A JP 7465588 B2 JP7465588 B2 JP 7465588B2
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Description
前記第2繊維の製造と、
前記恒温織物の製造と、を含み、
前記第2繊維の製造は、
(1)アルキド樹脂を溶融または溶剤に溶解し、日焼け止めナノ粒子を加え、20-60分間攪拌する工程と、(2)工程(1)で得られた物質を粘稠状の半固体の形態にする工程と、(3)溶剤を完全に除去または降温して固体薄膜にし、前記日焼け止め反射コーティングを得る工程と、(4)前記ポリエステル繊維の周囲に前記日焼け止め反射コーティングを被覆する工程と、を含む方法1、または、
(1)前記方法1の工程(1)と一致する工程と、(2)前記工程(1)で得られた物質を粘稠状の半固体の形態にする工程と、(3)前記工程(2)で得られた前記粘稠状の半固体を前記ポリエステル繊維の周囲に塗布する工程と、を含む方法2により行われ、
前記両面恒温織物の製造は、請求項1~8のいずれか1項に記載の前記第1繊維と前記第2繊維とを二重織物に編成することにより行われる。
さらに、前記方法1または前記方法2における前記工程(2)について、粘稠状の半固体にする方法は、A.増粘剤を加えることと、B.溶解の場合、溶剤の一部を除去することと、C.溶融の場合は、温度を下げて粘稠状にすることとを含む。
本発明において、本明細書で使用する科学的および技術的名詞は、特に明記されていない限り、当業者が通常理解する意味を有する。また、本文で使用する試薬、材料と操作手順はすべて相応の分野で広く使用されている試薬、材料と通常の手順である。
本実施例は、温度調節可能な両面恒温織物を提供し、第1繊維と第2繊維を含み、両者が複合して二重繊維構造になっており、複合方式は従来技術での二重複合の方式を参照することができ、好ましくは裏経表緯の継ぎ合わせ方法を用いて内外層生地を複合させて両面織物を形成する。
(実施例2)
第2繊維の製造:方法1:(1)アルキド樹脂を溶融または溶剤に溶解し(溶解度が60~100%であればよく、すなわち不完全に溶解してもよい)その後、加熱条件下、日焼け止めナノ粒子を加え、20-60分間攪拌する、(2)(1)で得られた物質を粘稠状の半固体の形態にする、(3)溶剤を完全に除去または降温して固体薄膜にし、前記日焼け止め反射コーティングを得る、(4)次に、前記ポリエステル繊維の周囲に前記日焼け止め反射コーティングを被覆する、ここでのアルキド樹脂は乾性または半乾性の樹脂を選択できる。溶剤はアルキド樹脂を部分的に溶解できるものであればよい、例えばエステル、アルコール、ケトン系溶剤である。
方法2:(1)方法1の手順(1)と一致する、(2)(1)で得られた物質を粘稠状の半固体の形態にする、(3)手順(2)で得られた前記粘稠状の半固体を前記ポリエステル繊維の周囲に塗布する。
両面恒温織物の製造:そして、第1繊維と前記第2繊維を二重織物に編成する。編成方法は従来の二重生地に従えばよく、好ましくは裏経表緯の継ぎ合わせ方法を用いて内外層生地を複合させて両面織物を形成するような織り方を採用する。
実施例3
比較例1:実験例における日焼け止め反射コーティングを加えず、その他は実験例と一致した。
比較例2:実験例における日焼け止めナノ粒子を加えず、その他は実験例と一致した。
比較例3:実施例におけるアルキド樹脂を加えず、代わりにポリエステル繊維を圧延機に入れ、日焼け止めナノ粒子液に浸し、ディップ圧延ローラー群のディップ圧延を経て日焼け止めナノ粒子をポリエステル繊維の構造面にマイクロナノ押し当てし、乾燥後に日焼け止めナノ粒子にまみれたポリエステル繊維を形成した。その他は実験例と一致した。
比較例4:実験例における螺旋溝を表面にバンプが多く含まれる粗い構造に修正し、その他は実験例と一致した。
比較例5:実験例における変性麻繊維を麻繊維に修正し、その他は実験例と一致した。
1.10℃の条件下で湯たんぽで人体を模擬し、実施例1及び比較例1~5の恒温両面織物を湯たんぽに被せ、異なる両面恒温織物の保温性能を反映するように湯たんぽの温度の経時変化を測定する。
結果は次の表のとおりである。
Claims (11)
- 第1繊維と第2繊維とを含む両面恒温織物であって、
前記第1繊維は麻繊維であり、
前記第2繊維は、その表面にネジ状溝を有する螺旋繊維であり、
前記第1繊維と前記第2繊維とが複合して前記織物が形成され、該織物の一方の側が前記第1繊維であり、他方の側が前記第2繊維であり、着用時に第1繊維側と第2繊維側のいずれが内側又は外側を向いていてもよく、
前記第2繊維は、その表面をレーザー彫刻またはエッチングして作られたネジ状溝を有する螺旋繊維であり、
前記第2繊維は、ポリエステル繊維と、前記ポリエステル繊維の周囲に被覆された日焼け止め反射コーティングとを含み、前記ネジ状溝は、前記日焼け止め反射コーティングの外側に設けられており、
前記日焼け止め反射コーティングの成分は、アルキド樹脂と日焼け止めナノ粒子を含み、両者の重量比は1:(0~0.3)であり、
前記アルキド樹脂は、シリコーン変性アルキド樹脂であり、
前記第1繊維と前記第2繊維とを二重織物に編成することを特徴とする両面恒温織物。 - 前記第2繊維の繊度が2.0dtex~5.0dtexであることを特徴とする請求項1に記載の両面恒温織物。
- 前記麻繊維が変性麻繊維であることを特徴とする請求項1に記載の両面恒温織物。
- 前記シリコーン変性アルキド樹脂は、ポリアルキルシリコーン樹脂、ポリアリレートシリコーン樹脂またはポリアルキルアリールシリコーン樹脂とアルキド樹脂を共縮重合して得られるものであることを特徴とする請求項1に記載の両面恒温織物。
- 前記螺旋繊維の外面は、台形、矩形または三角形である歯型を呈することを特徴とする請求項4に記載の両面恒温織物。
- 前記歯型の歯型角は0~30°であり、歯先から歯底までの幅は0.1~3.0μmであり、ピッチは0.1~5.0μmであることを特徴とする請求項5に記載の両面恒温織物。
- 前記日焼け止めナノ粒子の粒径範囲が0.5~10μmであることを特徴とする請求項5に記載の両面恒温織物。
- 請求項1~7のいずれかに記載の両面恒温織物の製造方法において、前記製造方法は、
前記第2繊維の製造と、
両面恒温織物の製造と、を含み、
前記第2繊維の製造は、
(1)アルキド樹脂を溶融または溶剤に溶解し、日焼け止めナノ粒子を加え、20-60分間攪拌する工程と、(2) 工程(1)で得られた物質を粘稠状の半固体の形態にする工程と、(3)溶剤を完全に除去または降温して固体薄膜にし、前記日焼け止め反射コーティングを得る工程と、(4) 前記ポリエステル繊維の周囲に日焼け止め反射コーティングを被覆する工程と、を含む方法1、または、
前記方法1の工程(1)と同一の工程と、(2)前記工程(1)で得られた物質を粘稠状の半固体の形態にする工程と、(3)前記工程(2)で得られた前記粘稠状の半固体を前記ポリエステル繊維の周囲に塗布する工程と、を含む方法2により行われる、両面恒温織物の製造方法。 - 前記方法1について、工程(3)で得られた前記日焼け止め反射コーティングに、前記ネジ状溝を設けることを特徴とする請求項8に記載の製造方法。
- 前記方法1または前記方法2における工程(2)について、粘稠状の半固体にする工程は、A.増粘剤を加えることと、B.溶解の場合、溶剤の一部を除去することと、C.溶融の場合は、温度を下げて粘稠状にすることとを含むことを特徴とする請求項8に記載の製造方法。
- 前記方法1または前記方法2における工程(1)において、スチレンブタジエンゴム、クロロプレンゴム、ニトリルゴムのうちの少なくとも1種を含む結着剤を添加することを特徴とする請求項8に記載の製造方法。
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