WO2013162028A1 - Flavor inhalation tool and carbon heat source - Google Patents

Flavor inhalation tool and carbon heat source Download PDF

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Publication number
WO2013162028A1
WO2013162028A1 PCT/JP2013/062491 JP2013062491W WO2013162028A1 WO 2013162028 A1 WO2013162028 A1 WO 2013162028A1 JP 2013062491 W JP2013062491 W JP 2013062491W WO 2013162028 A1 WO2013162028 A1 WO 2013162028A1
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WO
WIPO (PCT)
Prior art keywords
heat source
carbon heat
flavor
holder
metal salt
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PCT/JP2013/062491
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French (fr)
Japanese (ja)
Inventor
洋介 畔上
朋広 小林
敦郎 山田
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日本たばこ産業株式会社
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Application filed by 日本たばこ産業株式会社 filed Critical 日本たばこ産業株式会社
Priority to JP2014512728A priority Critical patent/JP5816360B2/en
Publication of WO2013162028A1 publication Critical patent/WO2013162028A1/en

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    • AHUMAN NECESSITIES
    • A24TOBACCO; CIGARS; CIGARETTES; SIMULATED SMOKING DEVICES; SMOKERS' REQUISITES
    • A24DCIGARS; CIGARETTES; TOBACCO SMOKE FILTERS; MOUTHPIECES FOR CIGARS OR CIGARETTES; MANUFACTURE OF TOBACCO SMOKE FILTERS OR MOUTHPIECES
    • A24D1/00Cigars; Cigarettes
    • A24D1/22Cigarettes with integrated combustible heat sources, e.g. with carbonaceous heat sources

Definitions

  • the present invention relates to a flavor suction tool and a carbon heat source that have a carbon heat source and can suck and taste the flavor generated by the heat generated from the heat source.
  • Smoking articles such as cigarettes and cigars are typical flavor suction tools that generate smoke (aerosol) containing tobacco flavor components by burning tobacco leaves.
  • various flavor suction devices have been proposed in which a flavor generating source is heated by heat generated from a carbon heat source, and the flavor can be sucked without burning or pyrolysis of the flavor generating source.
  • Patent Document 1 a structure in which the carbon heat source is partially covered with a heat conductive element such as an aluminum alloy is known (for example, Patent Document 1). According to such a structure, the combustion of the carbon heat source can be prevented from proceeding to the contact portion with the holder containing the flavor generation source.
  • Patent Document 2 a structure in which the outer peripheral portion of the carbon heat source is surrounded by a non-flammable member is also known (for example, Patent Document 2).
  • the conventional flavor suction tool described above has the following problems. That is, since the carbon heat source is covered with a heat conductive element such as an aluminum alloy, a separate member other than the carbon heat source is required, which increases the manufacturing cost.
  • the first feature of the present invention is that a flavor generating source (flavor generating source 40), a cylindrical holder (holder 30) containing the flavor generating source, and one end portion in the axis (axis AX) direction of the holder (
  • a flavor suction tool (flavor suction tool 10) comprising a carbon heat source (carbon heat source 20) provided at the end 30e), the carbon heat source being held by the holder in the axial direction and at least partly Has a first part (first part 21) protruding from the holder and a second part (second part 22) including an end opposite to the flavor generating source, and at least one of the first parts
  • the gist is that the part contains a fire spread inhibitor that prevents the carbon heat source from spreading.
  • a second feature of the present invention is a carbon heat source provided at one end portion in the axial direction of a cylindrical holder containing a flavor generating source, and is held by the holder in the axial direction, and at least a part thereof is retained.
  • a first portion provided so as to protrude from the holder; and a second portion provided so as to include an end opposite to the flavor generating source, wherein at least a part of the first portion is the carbon.
  • the gist is to contain a fire spread inhibitor that prevents the heat source from spreading.
  • the third feature of the present invention is that a flavor generating source (flavor generating source 40), a cylindrical holder (holder 30) containing the flavor generating source, and one end portion in the axis (axis AX) direction of the holder (
  • a flavor suction tool (flavor suction tool 10) comprising a carbon heat source (carbon heat source 20) provided at the end 30e), the carbon heat source being held by the holder in the axial direction and at least partly Has a first part (first part 21) protruding from the holder and a second part (second part 22) including an end opposite to the flavor generating source, and the carbon heat source is at least one
  • the part contains sodium chloride, and the content of the sodium chloride in the first part with respect to the carbon heat source is required to be greater than the content of the sodium chloride with respect to the carbon heat source in the second part.
  • a fourth feature of the present invention is a carbon heat source provided at one end in the axial direction of a cylindrical holder containing a flavor generating source, and is held by the holder in the axial direction, and at least a part thereof is retained.
  • a first portion provided so as to protrude from the holder; and a second portion including an end opposite to the flavor generating source, the carbon heat source including sodium chloride at least in part,
  • the content rate of the sodium chloride with respect to the carbon heat source in one portion is larger than the content rate of the sodium chloride with respect to the carbon heat source in the second portion.
  • the fifth feature of the present invention is that a flavor generating source (flavor generating source 40), a holder (holder 30) containing the flavor generating source, and one end (end 30e) in the axis (axis AX) direction of the holder. ), And a carbon heat source (carbon heat source 20) having a protruding portion (protruding portion 23) at least a portion protruding from the holder.
  • the organic binder contains sodium carboxymethylcellulose, and the carboxymethylcellulose sodium ether is melted below the combustion temperature of the carbon heat source. The degree and summarized in that less than 0.3.
  • a sixth feature of the present invention is a carbon heat source provided at one end portion in the axial direction of a cylindrical holder containing a flavor generation source, provided at one end portion in the axial direction of the holder, at least a part of which is provided.
  • the protrusion has a protruding portion protruding from the holder, and includes a carbonaceous material, an organic binder, and a reinforcing agent.
  • the reinforcing agent is nonflammable at the combustion temperature of the carbon heat source, and the combustion temperature of the reinforcing agent or the carbon heat source.
  • At least one thermal decomposition product generated below melts at a temperature lower than the combustion temperature of the carbon heat source, the organic binder contains sodium carboxymethyl cellulose, and the degree of etherification of the sodium carboxymethyl cellulose is 0.3 or more. This is the gist.
  • FIG. 1 is a schematic perspective view of a flavor suction device according to the first embodiment.
  • FIG. 2 is a cross-sectional view along the axial direction of the flavor suction device according to the first embodiment.
  • FIG. 3 is a diagram illustrating a schematic configuration of a test sample of a carbon heat source according to an example of the first embodiment.
  • FIG. 4 is a diagram illustrating a schematic configuration of a smoker and a carbon heat source according to an example of the first embodiment.
  • FIG. 5 is a cross-sectional view along the axial direction of the carbon heat source according to the modified example of the first embodiment.
  • FIG. 6 is a schematic perspective view of a flavor suction device according to the second embodiment.
  • FIG. 1 is a schematic perspective view of a flavor suction device according to the first embodiment.
  • FIG. 2 is a cross-sectional view along the axial direction of the flavor suction device according to the first embodiment.
  • FIG. 3 is a diagram illustrating a schematic configuration of a test sample of
  • FIG. 7 is a cross-sectional view along the axial direction of the flavor suction device according to the second embodiment.
  • FIG. 8 is a cross-sectional view along the axial direction of the carbon heat source according to the modified example of the second embodiment.
  • FIG. 9 is a schematic perspective view of a flavor suction device according to the third embodiment.
  • FIG. 10 is sectional drawing along the axial direction of the flavor suction tool which concerns on 3rd Embodiment.
  • FIG. 1 is an overall schematic configuration diagram of a flavor suction tool 10 according to the first embodiment.
  • FIG. 2 is a cross-sectional view along the axial direction of the flavor suction tool 10.
  • the flavor suction device 10 has an elongated cylindrical shape, and includes a carbon heat source 20, a holder 30, and a flavor generation source 40.
  • the flavor suction tool 10 heats the flavor generating source 40 with heat generated from the carbon heat source 20 in order to suppress the generation of aerosol.
  • the carbon heat source 20 is provided at the end 30e (one end) in the axis AX direction of the holder 30.
  • the carbon heat source 20 is held by the end 30 e of the holder 30.
  • the carbon heat source 20 includes a first portion 21 and a second portion 22. Specifically, the first portion 21 is held by the end 30 e of the holder 30.
  • the first portion 21 is a portion that is held by the holder 30 and at least a portion of the first portion 21 protrudes from the holder 30 in the direction of the axis AX.
  • the second portion 22 is a portion including an end portion on the opposite side to the flavor generation source 40.
  • the second portion 22 is a portion that is adjacent to the first portion 21 and protrudes from the holder 30.
  • At least the first portion 21 includes a fire spread inhibitor that prevents the carbon heat source 20 from spreading. This prevents the holder 30 from spreading due to the heat generated by the carbon heat source 20. A more specific configuration of the carbon heat source 20 will be described later.
  • the holder 30 has a cylindrical shape containing the flavor generation source 40.
  • the holder 30 can be configured by a paper tube formed as a hollow cylindrical body by curving a rectangular cardboard into a cylindrical shape and aligning both side edges.
  • positions so that the carbon heat source 20 and the flavor generation source 40 may not adjoin by arrange
  • the flavor generating source 40 generates flavor by being heated by the carbon heat source 20.
  • tobacco leaf can be used.
  • tobacco raw materials such as general cigarettes used for cigarettes (cigarettes), granular tobacco used for snuff tobacco, roll tobacco, and molded tobacco are used.
  • Roll tobacco is obtained by forming sheet-like recycled tobacco into a roll shape, and has a flow path inside.
  • molded tobacco is obtained by molding granular tobacco.
  • a flavor component such as menthol may be supported on a porous or non-porous support.
  • the carbon heat source 20 is adjacent to the holder 30 in the direction of the axis AX, and is adjacent to the first portion 21 that is provided so as to protrude at least partially from the holder 30, and And a second portion 22 provided so as to protrude from the holder 30.
  • the first portion 21 and the second portion 22 are integrally formed.
  • the carbon heat source 20 is obtained by molding a mixture containing a plant-derived carbonaceous material, an incombustible additive, an organic or inorganic binder and water by a method such as extrusion.
  • the total length of the carbon heat source 20 is preferably in the range of 10 mm to 30 mm, and preferably in the range of 13 mm to 20 mm.
  • the outer diameter of the carbon heat source 20 is preferably in the range of 4 mm to 8 mm, and preferably in the range of 5 mm to 7 mm. Thereby, it can be used suitably as a heat source of the flavor suction tool 10.
  • the length of the carbon heat source 20 protruding from the holder 30 is preferably 8 mm to 15 mm.
  • the length of the first portion 21 can be, for example, in the range of 1 mm to 5 mm, preferably in the range of 1.5 to 3 mm, in the portion protruding from the holder 30.
  • the portion of the first portion 21 held by the holder 30 can be in the range of 3 mm to 10 mm, for example.
  • the length of the second portion 22 can be set in the range of 8 mm to 10 mm, for example. With such a configuration, when the flavor suction tool 10 is used, the user can suck the flavor a sufficient number of times.
  • the first portion 21 includes a fire spread inhibitor that prevents the carbon heat source 20 from spreading. That is, by including the fire spreader in the connection portion of the carbon heat source 20 with the holder 30, even if the user does not consciously extinguish the carbon heat source 20, the containing part containing the fire spreader is autonomous. Since the combustion is stopped, the spread of fire to the holder 30 or the like can be prevented.
  • the characteristics of the fire spread inhibitor contained in the first portion 21 of the carbon heat source 20 will be described. It is preferable that the fire spread inhibitor contained in the first portion 21 is nonflammable at the combustion temperature of the carbon heat source 20 and causes an endothermic reaction below the combustion temperature of the carbon heat source 20. Further, when thermal decomposition occurs as an endothermic reaction, it is preferable that at least one of the thermal decomposition products is nonflammable and non-volatile at the combustion temperature of the carbon heat source 20.
  • an inorganic substance that satisfies the following conditions can be used as the fire spread inhibitor.
  • the inorganic substance can be added to the carbon heat source by a method such as a solution, suspension, paste, or granular material.
  • a soluble or hardly soluble alkali metal salt that satisfies the above-mentioned conditions, or a soluble or hardly soluble alkaline earth metal salt can be preferably used.
  • a soluble inorganic salt or a hardly soluble inorganic salt can be used as a fire spread inhibitor.
  • Soluble inorganic salts include chlorides, carbonates or sulfates.
  • Examples of the hardly soluble inorganic salt include hydroxide, carbonate or sulfate.
  • chlorides such as sodium chloride, calcium chloride, magnesium chloride and potassium chloride, carbonates such as sodium carbonate and sodium bicarbonate, or sulfates such as sodium sulfate and magnesium sulfate and hydration thereof.
  • materials particularly preferred are materials.
  • hydroxides such as magnesium hydroxide and calcium hydroxide, carbonates such as calcium carbonate and magnesium carbonate, sulfates such as calcium sulfate and hydrates thereof are particularly preferable.
  • inorganic salts as shown in Table 1 can be used as a fire spread inhibitor.
  • a substance such as liquid glass can be used as a fire spread inhibitor.
  • Such liquid glass can be obtained as a liquid coating agent at room temperature by the method disclosed in Japanese Patent No. 2538527, for example, and after adding the coating agent to the first portion 21 of the carbon heat source 20 by a method such as coating, By drying at room temperature to about 200 ° C., a film containing at least one of silicon or metal oxide can be formed.
  • the first part 21 containing the fire spreader is added to a part of the carbon heat source 20 by a method such as dipping, spraying, spraying, wetting, or coating a solution, suspension, paste, or granular material of the fire spreader. Can be produced.
  • one end of a carbon heat source 20 produced to a size suitable for the flavor suction device 10 is impregnated to a predetermined depth in a liquid in which a fire spreader is dissolved or dispersed, held for a certain time, and then dried.
  • the first portion 21 can be provided over an arbitrary length.
  • the content of the fire spread inhibitor in the first portion 21 can be arbitrarily controlled by the solution concentration of the fire spread inhibitor and the impregnation time.
  • the carbon heat source 20 has an opening that communicates in the axis AX direction, such as a cylindrical shape, the impregnation position of the fire spread inhibitor is more accurately obtained by impregnating the solution with the fire spread inhibitor while venting the opening. Can be controlled.
  • the content of the suitable fire spread inhibitor and the length of the processed portion in the first portion 21 are as follows. A value that provides a sufficient fire spread prevention effect is selected. Further, when the fire spread inhibitor is soluble, a higher fire spread preventing effect can be obtained by penetrating into the carbon heat source 20.
  • the second portion 22 of the carbon heat source 20 may further include at least one of the inorganic substances listed in Table 1.
  • the content of the inorganic substance contained in the second portion 22 with respect to the carbon heat source 20 is preferably smaller than the content of the fire spreader contained in the first portion 21 with respect to the carbon heat source 20.
  • the carbon heat source 20 is not burned at the time of combustion due to an impact such as hitting an ashtray. Therefore, it is possible to prevent the carbon heat source 20 including the combustion part from dropping off (fire type dropping). Such an effect is particularly remarkable when an organic binder having a low thermal decomposition temperature is adopted as the binder of the carbon heat source 20.
  • the content of the soluble alkali metal salt or alkaline earth metal salt contained in the first portion 21 is preferably smaller than the content of the fire spreader contained in the second portion 22. Furthermore, a portion other than the first portion 21 of the carbon heat source 20 may contain a low-concentration soluble alkali metal salt.
  • Incombustibility at the combustion temperature of the carbon heat source 800 ° C. to 1200 ° C.
  • At least one thermal decomposition product generated below the combustion temperature of the inorganic substance or the carbon heat source melts below the combustion temperature of the carbon heat source.
  • the soluble alkali metal salts and alkaline earth metal salts listed in Table 1 can be suitably used.
  • a low-concentration soluble alkali metal salt can be added in the form of a solid or liquid when a carbonaceous material or a binder is mixed during molding such as extrusion.
  • the soluble alkali metal salt concentration of the second portion 22 excluding the first portion 21 is selected to be a value that provides a sufficient effect within a range that does not impair ignitability and other combustion characteristics. When selected, the concentration is preferably 5 wt% or less, and more preferably 0.5 wt% or less.
  • Carbonaceous material It is desirable to use a carbonaceous material from which volatile impurities have been removed by heat treatment or the like, but is not limited thereto.
  • the carbonaceous material can be included in the range of 10 wt% to 99 wt%, preferably 30 wt% to 70 wt%, and 40 wt% to 50 wt% to provide sufficient heat supply and combustion for preventing ash scattering, etc. Desirable from the viewpoint of characteristics.
  • Binder As the binder, organic binders such as sodium carboxymethyl cellulose (CMC) and ammonium alginate, minerals such as purified bentonite, or silica binders such as colloidal silica, water glass and calcium silicate are used. Binders known to those skilled in the art, such as inorganic binders, can be used.
  • the carbon heat source 20 includes the soluble alkali metal salt or the soluble alkaline earth metal salt listed in Table 1 and CMC is used as a binder
  • the degree of etherification of CMC is set to 0.3 or more.
  • the carbon heat source 20 can be given strength that can withstand manufacturing and use.
  • CMC having a low degree of etherification is used, the strength after molding and drying is poor, and the suitability for production and use may be significantly deteriorated.
  • CMC having a degree of etherification of less than 0.8 it becomes possible to easily mold at the time of molding such as extrusion.
  • CMC can be contained in an amount of 1 to 10 wt%, and more preferably 1 wt% to 8 wt% from the viewpoint of flavor.
  • Nonflammable additive for example, a carbonate or oxide composed of sodium, potassium, calcium, magnesium, silicon, etc. can be used, and it can be contained in 40 to 89 wt%. In particular, it is preferable to contain 40 wt% to 55 wt% of calcium carbonate in the carbon heat source 20.
  • a carbon heat source 20 having the composition shown in Table 2 was produced by the following method. -86 g of activated carbon and 117 g of calcium carbonate (CaCO 3 ) are mixed with 10.8 g of CMC having a degree of etherification of 0.6, and 250 g of water containing 2.2 g of sodium chloride is further mixed. Extrusion molding so as to form a cylindrical shape of 6 mm and an inner diameter of 4 mm. After the molding is dried, it is cut into a length of 13 mm to obtain the carbon heat source 20.
  • -86 g of activated carbon and 117 g of calcium carbonate (CaCO 3 ) are mixed with 10.8 g of CMC having a degree of etherification of 0.6, and 250 g of water containing 2.2 g of sodium chloride is further mixed. Extrusion molding so as to form a cylindrical shape of 6 mm and an inner diameter of 4 mm. After the molding is dried, it is cut into a length of 13 mm to obtain the carbon heat source 20
  • test Sample The carbon heat source produced by the above-described method was impregnated with an aqueous NaCl solution to produce test heat sources A to F shown in Table 3.
  • test heat sources A to F were impregnated with NaCl by the following method. ⁇ Insert a 13 mm heat source into a tube with an inner diameter of 5 mm, and immerse each sample in a NaCl aqueous solution having a concentration shown in Table 3 for 210 seconds while flowing air at 1000 ml / min. Dry at 6 ° C. for 6 hours to obtain a NaCl impregnation heat source
  • the weight ratio of NaCl and combustible material (sum of carbonaceous material and organic binder) is 0.35 or more, or the weight ratio of NaCl and carbonaceous material is 0.40 or more in the impregnation part of the fire spreader.
  • the content of the fire spread inhibitor in the carbon heat source 20 in the impregnated portion of the suspension or liquid glass of CaCO 3 or Mg (OH) 2 was calculated by the following equation.
  • ⁇ 1mm present fire spreader content addition amount of fire spread inhibitor / length of impregnated part in heat source
  • any of the fire spread inhibitors (CaCO 3 , Mg (OH) 2 , liquid glass) used in this test contains a predetermined amount in the carbon heat source 20, so that the content of the fire spread inhibitor is included. It was confirmed that combustion can be stopped autonomously at
  • The amount of addition required to stop combustion differs depending on the type of fire spread inhibitor used. For example, Mg (OH) 2 is considered to have a higher combustion stop effect than CaCO 3 . It is presumed that Mg (OH) 2 has a larger endothermic amount in pyrolysis. ⁇ The effect of preventing fire spread differs depending on the ratio of the amount added to the inside of the hole and the outer periphery.
  • test sample A test sample of a carbon heat source 20 (total length 15 mm, outer diameter 6 mm) having the composition shown in Table 8 was produced by extrusion molding.
  • excessive heat supply to the holder 30 can be prevented without providing another member other than the carbon heat source 20, and combustion or thermal decomposition of the holder 30 can be prevented. That is, since supply of excessive heat to the holder 30 is prevented, it is not necessary to give the holder 30 special heat resistance, and even a material such as a paper tube can be suitably used as the holder 30 and the manufacturing cost is increased. Can be suppressed.
  • the shapes of the first portion 21 and the second portion 22 of the carbon heat source 20 may be changed as follows.
  • 5A to 5C are cross-sectional views along the axial direction of the carbon heat source according to the modified example of the present invention.
  • the fire spread inhibitor (dot portion in the figure) may be disposed on the outer peripheral portion of the first portion 21. Further, as shown in FIG. 5B, the first portion 21 spreads as it approaches the flavor generating source 40 (not shown in FIG. 5B) in the cross section along the axial direction of the holder 30. You may comprise so that the area
  • the portion of the first portion 21 that does not contain the fire spread inhibitor is substantially triangular, but the portion does not necessarily have a triangular shape, and may be a pyramid shape, for example.
  • both the first portion 21 and the second portion 22 are provided with a fire spread inhibitor as they approach the flavor generating source 40 in the cross section along the axial direction of the holder 30. You may comprise so that the area
  • the fire spreader is included in the entire axis AX of the first portion 21 .
  • the fire spreader may be included only in the first portion 21 that is not held by the holder 30.
  • the flame spreader containing region is variously changed in the carbon heat source 20
  • the substance may be contained at different concentrations in the axial direction of the carbon heat source 20.
  • An example of the configuration described in (1-5.1) is that the second portion 22 contains a low concentration of soluble alkali metal salt or soluble alkaline earth metal salt.
  • the concentration gradient can be realized such that the concentration of the substance is thin on the ignition end side of the carbon heat source 20 and the holder 30 side is thick. Thereby, the amount of heat generated by the carbon heat source 20 can be controlled more precisely.
  • the preferable content (concentration) of the fire spread inhibitor varies depending on the shape and composition (calorific value) of the carbon heat source 20 as well as the type of the fire spread inhibitor, but it depends on the method shown in (1-4).
  • the fire spread inhibitor can be set to an arbitrary content.
  • the outer shape of the carbon heat source 20 is a cylindrical shape.
  • the present invention is not limited to the cylindrical shape, and various shapes such as a rectangular parallelepiped are naturally included in the present invention.
  • FIG. 6 is an overall schematic configuration diagram of the flavor suction tool 10 according to the second embodiment.
  • FIG. 7 is a cross-sectional view of the flavor suction tool 10 along the axial direction.
  • the flavor inhaler 10 has an elongated cylindrical shape as in the first embodiment, and includes a carbon heat source 20, a holder 30, and a flavor generation source 40.
  • the flavor suction tool 10 heats the flavor generating source 40 with heat generated from the carbon heat source 20 in order to suppress the generation of aerosol.
  • the carbon heat source 20 is adjacent to the holder 30 in the axis AX direction, and is adjacent to the first portion 21 and the first portion 21 provided so as to protrude at least partially from the holder 30. And a second portion 22 provided so as to protrude from the holder 30.
  • the first portion 21 and the second portion 22 are integrally formed.
  • the second portion 22 can also contain a low concentration of NaCl (an example of a fire spread inhibitor). That is, the content rate of NaCl in the second part 22 with respect to the carbon heat source 20 is smaller than the content rate of NaCl in the first part 21 with respect to the carbon heat source 20.
  • the carbon heat source 20 can be produced even if the holder 30 is spread by the heat generated by the carbon heat source 20 without impeding the ignitability of the carbon heat source 20 and the flavor suction tool 10 is hit against an ashtray with a certain level of force. Can prevent the burning part (fire type) from falling. Such an effect is particularly remarkable when an organic binder having a low thermal decomposition temperature is adopted as the binder of the carbon heat source 20.
  • the first portion 21 containing high-concentration NaCl is added to a part of the carbon heat source 20 by immersing, spraying, spraying, wetting, coating, or the like a solution, suspension, paste, or powder of NaCl. Can be produced.
  • the first portion 21 can be provided over any length.
  • the NaCl content in the first portion 21 can be arbitrarily controlled by the NaCl solution concentration and the impregnation time.
  • the carbon heat source 20 has an opening communicating in the direction of the axis AX like a cylindrical shape, the NaCl impregnation position can be controlled with higher accuracy by impregnating with the NaCl solution while venting the opening.
  • a suitable NaCl content in the first portion 21 and the length of the processed portion are values that can obtain a sufficient fire spread prevention effect in consideration of the relationship with the characteristics (shape, composition, etc.) of the carbon heat source 20 to be processed. Is selected. Further, by infiltrating NaCl into the carbon heat source 20, a higher fire spread prevention effect can be obtained.
  • the carbon heat source 20 can be provided with a fire type (carbon heat source 20) fall prevention function by low concentration sodium chloride (NaCl).
  • NaCl sodium chloride
  • Such low-concentration NaCl can be added in the form of a solid or liquid when, for example, a carbonaceous material or a binder is mixed during molding such as extrusion.
  • the NaCl concentration of the second portion 22 excluding the first portion 21 is selected to be a value that provides a sufficient effect within a range that does not impair the ignitability and other combustion characteristics, but may be, for example, 1 wt% or less. Preferably, it is 0.5 wt% or less.
  • Carbonaceous material It is desirable to use a carbonaceous material from which volatile impurities have been removed by heat treatment or the like, but is not limited thereto.
  • the carbonaceous material can be included in the range of 10 wt% to 99 wt%, preferably 30 wt% to 70 wt%, and 40 wt% to 50 wt% to provide sufficient heat supply and combustion for preventing ash scattering, etc. Desirable from the viewpoint of characteristics.
  • the carbonaceous material is not limited to this.
  • the carbonaceous material can be included in the range of 10 wt% to 99 wt%, preferably 30 wt% to 70 wt%, and 40 wt% to 50 wt% to provide sufficient heat supply and combustion for preventing ash scattering, etc. Desirable from the viewpoint of characteristics.
  • Binder As the binder, organic binders such as sodium carboxymethylcellulose (CMC) and ammonium alginate, minerals such as purified bentonite, or silica binders such as colloidal silica, water glass and calcium silicate are used. Binders known to those skilled in the art, such as inorganic binders, can be used.
  • CMC carboxymethylcellulose
  • ammonium alginate minerals such as purified bentonite
  • silica binders such as colloidal silica, water glass and calcium silicate are used. Binders known to those skilled in the art, such as inorganic binders, can be used.
  • the degree of etherification of CMC is set to 0.3 or more.
  • the carbon heat source 20 can be given strength that can withstand manufacturing and use.
  • CMC having a low degree of etherification is used, the strength after molding and drying is poor, and the suitability for production and use may be significantly deteriorated.
  • CMC having a degree of etherification of less than 0.8 it becomes possible to easily mold at the time of molding such as extrusion.
  • CMC can be contained in an amount of 1 to 10 wt%, and more preferably 1 wt% to 8 wt% from the viewpoint of flavor.
  • Nonflammable additives for example, carbonates or oxides composed of sodium, potassium, calcium, magnesium, silicon and the like can be used, and they can be contained in 40 to 89 wt%. In particular, it is preferable to contain 40 wt% to 55 wt% of calcium carbonate in the carbon heat source 20.
  • Carbon heat source 20 having the composition shown in Table 9 is produced by the following method. did. -86 g of activated carbon and 117 g of calcium carbonate (CaCO 3 ) are mixed with 10.8 g of CMC having a degree of etherification of 0.6, and 250 g of water containing 2.2 g of sodium chloride is further mixed. Extrusion molding so as to form a cylindrical shape of 6 mm and an inner diameter of 4 mm. After the molding is dried, it is cut into a length of 13 mm to obtain the carbon heat source 20.
  • Test Sample Test heat sources A to F shown in Table 10 were produced by impregnating the carbon heat source produced by the above-described method with an aqueous NaCl solution.
  • test heat sources A to F were impregnated with NaCl by the following method. Insert a 10 mm heat source into a tube with an inner diameter of 5 mm and immerse each sample in a NaCl aqueous solution having the concentration shown in Table 11 for 210 seconds while flowing air at 1000 ml / min. Dry at 6 ° C. for 6 hours to obtain a NaCl impregnation heat source
  • the weight ratio of NaCl to combustible material is 0.35 or more, or NaCl to carbonaceous material.
  • the carbon heat source 20 contains at least a portion of NaCl, and the content of NaCl in the first portion 21 with respect to the carbon heat source 20 is the same as the carbon of NaCl in the second portion 22. It is larger than the content rate with respect to the heat source 20. For this reason, it is possible to prevent the combustion of the carbon heat source 20 from proceeding to the contact portion with the holder 30 containing the flavor generating source 40 due to the effect of preventing the spread of NaCl in the first portion 21. Further, according to the second embodiment, it is possible to realize a concentration gradient such that the concentration of the substance is low on the ignition end side of the carbon heat source 20 and the holder 30 side is high. Thereby, the amount of heat generated by the carbon heat source 20 can be controlled more precisely.
  • NaCl is effective in preventing the carbon heat source 20 from falling off. Moreover, it is not necessary to provide another member other than the carbon heat source 20 as described above, and an increase in manufacturing cost can be suppressed.
  • the weight ratio of NaCl and combustible in the first part is 0.35 or more, and the weight ratio of NaCl and carbonaceous material in the first part is 0.40 or more. In this case, a further sufficient fire spread preventing effect can be obtained.
  • FIGS. 8A to 8C are cross-sectional views along the axial direction of the carbon heat source according to the modified example of the present invention.
  • NaCl (dot portion in the figure) may be arranged on the outer peripheral portion of the first portion 21.
  • the first portion 21 is NaCl in the cross section along the axial direction of the holder 30 as it approaches the flavor generating source 40 (not shown in FIG. 8B).
  • the region including (dot portion in the figure) may be widened.
  • the portion of the first portion 21 that does not contain NaCl has a substantially triangular shape, but the portion does not necessarily have a triangular shape, and may have a pyramid shape, for example.
  • both the first portion 21 and the second portion 22 are regions containing NaCl as they approach the flavor generating source 40 in the cross section along the axial direction of the holder 30. May be configured to be wide.
  • the example in which NaCl is included in the entire axis AX of the first portion 21 has been described. However, it is sufficient that at least a portion of the first portion 21 includes NaCl. Only the first portion 21 that is not held by may be made to contain NaCl.
  • NaCl-containing region is variously changed in the carbon heat source 20
  • NaCl may be contained in different concentrations in the axial direction of the carbon heat source 20.
  • the configuration described in (2-2) including low concentration NaCl in the second portion 22 is an example.
  • the concentration gradient can be realized so that the NaCl concentration is low on the ignition end side of the carbon heat source 20 and the holder 30 side is high. Thereby, the amount of heat generated by the carbon heat source 20 can be controlled more precisely.
  • the preferred NaCl content varies depending on the shape and composition (calorific value) of the carbon heat source 20, but by the method shown in (2-3) or (2-4), the effect of preventing the spread of fire or NaCl can be set to an arbitrary content so that the effect of preventing the drop of fire can be achieved.
  • the outer shape of the carbon heat source 20 is cylindrical.
  • the present invention is not limited to the cylindrical shape, and various shapes such as a rectangular parallelepiped are also included in the present invention.
  • FIG. 9 is an overall schematic configuration diagram of the flavor suction tool 10 according to the third embodiment.
  • FIG. 10 is a cross-sectional view along the axial direction of the flavor suction tool 10.
  • the flavor suction tool 10 has an elongated cylindrical shape as in the first embodiment, and includes a carbon heat source 20, a holder 30, and a flavor generation source 40.
  • the flavor suction tool 10 heats the flavor generating source 40 with the heat generated from the carbon heat source 20 without burning or pyrolyzing the flavor generating source 40.
  • the carbon heat source 20 is provided at the end 30e (one end) in the axis AX direction of the holder 30.
  • the carbon heat source 20 is held by the end 30 e of the holder 30.
  • the carbon heat source 20 has a protruding portion 23 at least partially protruding from the holder 30.
  • the length of the protruding portion 23 can be 8 mm to 15 mm, for example. With such a configuration, the user can easily visually recognize the combustion state of the carbon heat source 20 during use. A more specific configuration of the carbon heat source 20 will be described later.
  • the carbon heat source 20 is obtained by molding a mixture containing a plant-derived carbonaceous material, an incombustible additive, an organic binder and water by a method such as extrusion.
  • the carbon heat source 20 includes a carbonaceous material, an organic binder, and a reinforcing agent.
  • the organic binder it is particularly preferable to use sodium carboxymethylcellulose (CMC) from the viewpoint of flavor.
  • CMC carboxymethylcellulose
  • other organic binders for example, ammonium alginate, are used, there is a possibility that the thermal decomposition product generated with combustion of the carbon heat source 20 may inhibit the flavor.
  • the degree of etherification of CMC is set to 0.3 or more. The degree of etherification is preferably less than 0.8.
  • the reinforcing agent is nonflammable at the combustion temperature of the carbon heat source 20, and at least one thermal decomposition product generated below the combustion temperature of the carbon heat source 20 is melted below the combustion temperature of the carbon heat source 20.
  • the reinforcing agent is nonflammable at 800 ° C. to 1200 ° C., which is the combustion temperature of the carbon heat source 20, and at least one pyrolyzate generated below the combustion temperature of the carbon heat source 20 is carbon dioxide. It has a characteristic of melting at a temperature lower than the combustion temperature of the heat source 20.
  • the reinforcing agent is preferably made of at least one of a soluble alkali metal salt or a soluble alkaline earth metal salt that satisfies the above-mentioned conditions.
  • a soluble alkali metal salt or a soluble alkaline earth metal salt include chlorides, carbonates, and sulfates.
  • sodium chloride, calcium chloride, magnesium chloride, potassium chloride, sodium carbonate, sodium hydrogen carbonate, sodium sulfate, magnesium sulfate can be mentioned, and sodium chloride (NaCl) can be preferably used.
  • NaCl sodium chloride
  • it is preferable that the content rate of NaCl is 5 wt% or less with respect to the weight of the carbon heat source 20.
  • the carbon heat source 20 breaks from the non-combustion portion due to an impact such as a hit to the ashtray during the combustion of the carbon heat source 20, and includes the combustion portion. It is possible to prevent a part of the carbon heat source 20 from dropping (fire type dropping).
  • the value of the reinforcing agent concentration of the carbon heat source 20 is selected so as to obtain a sufficient effect within a range that does not impair ignitability and other combustion characteristics.
  • NaCl specifically, it is sufficient that NaCl is contained in the carbon heat source 20 to some extent.
  • the mass percent concentration (NaCl concentration) of NaCl with respect to the carbon heat source 20 is 5 wt% or less, and can be employed without impairing the ignitability.
  • NaCl can be added as a granule or a solution when mixing a carbonaceous material, a binder, or the like during molding such as extrusion.
  • the degree of etherification of CMC is set to 0.3 or more. By doing in this way, even when the carbon heat source 20 contains a reinforcing agent, the carbon heat source 20 can be provided with strength that can withstand manufacturing and use.
  • CMC having a low degree of etherification When CMC having a low degree of etherification is used, the strength after molding and drying is poor, and the suitability for production and use may be significantly deteriorated. Further, for example, by using CMC having a degree of etherification of less than 0.8, it becomes possible to easily mold at the time of molding such as extrusion.
  • CMC can be contained in an amount of 1 to 10 wt%, and more preferably 1 wt% to 8 wt% from the viewpoint of flavor.
  • the carbon heat source 20 may have different reinforcing agent concentrations in the direction of the axis AX.
  • the content of the reinforcing agent with respect to the carbon heat source 20 on the other end 20b side of the carbon heat source 20 may be larger than the content of the reinforcing agent on the one end 20a side of the carbon heat source 20, more specifically.
  • a part of the carbon heat source 20, specifically, near the other end 20 b contains a soluble alkali metal salt or alkaline earth metal salt having a higher concentration than the portion including the one end 20 a (protruding portion). Also good.
  • the combustion of the carbon heat source 20 is stopped autonomously in the containing portion, and the carbon heat source 20 is transferred to the holder. Fire spread can be prevented more reliably.
  • the holder 30 is exposed by exposing at least a part of the portion (second portion) of the carbon heat source 20 containing the high-concentration soluble alkali metal salt or alkaline earth metal salt as described above.
  • the combustion of the carbon heat source 20 can be stopped before excessive heat is supplied to 30 or the like.
  • the length of the portion of the carbon heat source 20 containing a high concentration of soluble alkali metal salt or alkaline earth metal salt to be exposed from the holder 30 is 1 mm to 5 mm, more preferably 1.5 mm to 3 mm.
  • the soluble alkali metal salt or alkaline earth metal salt concentration to be contained on the other end portion 20b side of the carbon heat source 20 is sufficiently spread from the relationship with the carbonaceous material blending ratio in the carbon heat source 20 and the air flow path structure.
  • a numerical value that achieves the prevention function is appropriately selected. For example, when NaCl is used, NaCl is added so that the weight ratio of NaCl to combustible material (sum of carbonaceous material and organic binder) is 0.35 or more, or the weight ratio of NaCl to carbonaceous material is 0.40 or more.
  • the portion of the carbon heat source 20 containing a high concentration of soluble alkali metal salt or alkaline earth metal salt is obtained by, for example, replacing one end portion of the carbon heat source 20 having a size suitable for the flavor suction tool 10 with a soluble alkali. It can be formed by impregnating an aqueous solution containing a metal salt or an alkaline earth metal salt to a predetermined depth, holding it for a certain time, and then drying.
  • the content of the soluble alkali metal salt or alkaline earth metal salt in the other end portion 20b of the carbon heat source 20 can be arbitrarily controlled by the concentration of the soluble alkali metal salt or alkaline earth metal salt solution and the impregnation time. For example, when NaCl is used, the concentration of the NaCl aqueous solution used for impregnation is preferably 15 wt% to 26 wt%.
  • the carbon heat source 20 has an opening that communicates in the axis AX direction like a cylindrical shape, a soluble alkali metal salt or an alkaline earth metal salt is impregnated with an aqueous solution while passing through the opening.
  • the impregnation position of the alkali metal salt or alkaline earth metal salt can be controlled more accurately.
  • Carbonaceous material It is desirable to use a carbonaceous material from which volatile impurities have been removed by heat treatment or the like, but is not limited thereto.
  • the carbonaceous material can be included in the range of 10 wt% to 99 wt%, preferably 30 wt% to 70 wt%, and 40 wt% to 50 wt% to provide sufficient heat supply and combustion for preventing ash scattering, etc. Desirable from the viewpoint of characteristics.
  • nonflammable additives for example, carbonates or oxides composed of sodium, potassium, calcium, magnesium, silicon and the like can be used, and they can be contained in 40 to 89 wt%. In particular, it is preferable to contain 40 wt% to 55 wt% of calcium carbonate in the carbon heat source 20.
  • the total length of the carbon heat source 20 is preferably in the range of 10 mm to 30 mm, and more preferably in the range of 13 mm to 20 mm. Further, the outer diameter of the carbon heat source 20 is preferably in the range of 4 mm to 8 mm, and more preferably in the range of 5 mm to 7 mm. Thereby, it can be used suitably as a heat source of the flavor suction tool 10.
  • the carbon heat source 20 has the protruding portion 23 protruding from the holder 30. For this reason, the user can visually recognize the combustion state of the carbon heat source 20 easily.
  • the carbon heat source 20 contains a reinforcing agent and sodium carboxymethyl cellulose (CMC), and the degree of etherification of CMC is 0.3 or more. For this reason, even if the flavor suction tool 10 is struck against an ashtray or the like with a certain force or more while giving the carbon heat source 20 strength sufficient to withstand manufacture and use, the combustion part (fire type) can be prevented from falling.
  • CMC sodium carboxymethyl cellulose
  • the binder contained in the carbon heat source 20 is desirably CMC from the viewpoint of flavor, but in the production of a carbon heat source containing a reinforcing agent, when CMC having a degree of etherification of less than 0.3 is used, The strength after molding and drying is poor, and the suitability for production and use may be significantly deteriorated. That is, the inventor of the present application ensures the strength of the carbon heat source 20 that can withstand production and use by including NaCl and CMC in the carbon heat source 20 and setting the degree of etherification of CMC to 0.3 or more. In addition, they have acquired knowledge that fire omission can be effectively prevented.
  • the degree of etherification of CMC in the range of 0.3 to 0.8, it is possible to achieve both the guarantee of strength when the carbon heat source 20 is not burned and the ease of molding. Furthermore, in the direction of the axis AX of the flavor suction tool 10, the effect of preventing the spread of fire to the holder of the carbon heat source 20 is also achieved by imparting a concentration gradient to the reinforcing agent, particularly a soluble alkali metal salt or a soluble alkaline earth metal salt. Can do.
  • reinforcing agent density concentration different in the axis line AX direction of the carbon heat source 20, for example, in a part of carbon heat source 20, specifically, the other end part 20b side (2nd part).
  • concentration different in the axis line AX direction of the carbon heat source 20 for example, in a part of carbon heat source 20, specifically, the other end part 20b side (2nd part).
  • a higher concentration of reinforcing agent may be contained than the portion including the one end portion 20a (protruding portion), such a configuration is not essential for achieving the above-described effects of the present invention.
  • the supply of excessive heat to the holder is suppressed and the combustion or pyrolysis of the holder is prevented without providing another member other than the carbon heat source in the portion of the carbon heat source held by the holder. And a carbon heat source.

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  • Manufacture Of Tobacco Products (AREA)

Abstract

 A flavor inhalation tool (10) equipped with: a cylindrical holder (30) in which a flavor-generating source (40) is enclosed; and a carbon heat source (20) provided at one end part of the holder (30) in the axial (AX) direction thereof. The carbon heat source (20) is held by the holder (30) in the axial (AX) direction thereof, and has a first section (21), at least a part of which protrudes from the holder (30), and a second section (22) which is at the end part on the opposite side to the flavor-generating source (40). At least a part of the first section (21) contains a fire retardant which prevents the spread of fire from the carbon heat source (20).

Description

香味吸引具及び炭素熱源Flavor suction device and carbon heat source
 本発明は、炭素熱源を有し、かかる熱源から発生する熱によって生じる香味を吸引して味わうことができる香味吸引具及び炭素熱源に関する。 The present invention relates to a flavor suction tool and a carbon heat source that have a carbon heat source and can suck and taste the flavor generated by the heat generated from the heat source.
 シガレットや葉巻などの喫煙物品は、たばこ葉の燃焼により、たばこの香味成分を含む煙(エアロゾル)を発生させる代表的な香味吸引具である。また、近年では、炭素熱源から発生する熱によって香味発生源を加熱し、香味発生源の燃焼や熱分解を伴うことなく香味を吸引可能な香味吸引具が種々提案されている。 Smoking articles such as cigarettes and cigars are typical flavor suction tools that generate smoke (aerosol) containing tobacco flavor components by burning tobacco leaves. In recent years, various flavor suction devices have been proposed in which a flavor generating source is heated by heat generated from a carbon heat source, and the flavor can be sucked without burning or pyrolysis of the flavor generating source.
 このような炭素熱源を用いた香味吸引具において、アルミニウム合金などの熱伝導性要素で炭素熱源を部分的に被覆した構造が知られている(例えば、特許文献1)。このような構造によれば、香味発生源を内包したホルダとの接触部分まで炭素熱源の燃焼が進行してしまうことを防止し得る。 In a flavor suction device using such a carbon heat source, a structure in which the carbon heat source is partially covered with a heat conductive element such as an aluminum alloy is known (for example, Patent Document 1). According to such a structure, the combustion of the carbon heat source can be prevented from proceeding to the contact portion with the holder containing the flavor generation source.
 また、このような炭素熱源を用いた香味吸引具において、炭素熱源の外周部分を不燃性の部材で囲んだ構造も知られている(例えば、特許文献2)。このような構造によって、着火後の香味吸引具を灰皿などに一定以上の力で叩いても、炭素熱源が燃焼部分(火種)と非燃焼部分の境界で折れ、火種が香味吸引具から落下することを防止できる。 Further, in a flavor suction device using such a carbon heat source, a structure in which the outer peripheral portion of the carbon heat source is surrounded by a non-flammable member is also known (for example, Patent Document 2). With such a structure, even if the flavor suction tool after ignition is hit against an ashtray with a certain level of force, the carbon heat source breaks at the boundary between the combustion part (fire type) and the non-combustion part, and the fire type falls from the flavor suction tool. Can be prevented.
 しかしながら、上述した従来の香味吸引具には、次のような問題があった。すなわち、アルミニウム合金などの熱伝導性要素で炭素熱源を被覆するため、炭素熱源以外の別部材が必要となり、製造コストが増大する問題がある。 However, the conventional flavor suction tool described above has the following problems. That is, since the carbon heat source is covered with a heat conductive element such as an aluminum alloy, a separate member other than the carbon heat source is required, which increases the manufacturing cost.
特表2010-535530号公報(第1図)Special Table 2010-535530 (Fig. 1) 特開平2-86759号公報(第1図)Japanese Patent Laid-Open No. 2-86759 (FIG. 1)
 本発明の第1の特徴は、香味発生源(香味発生源40)と、前記香味発生源を内包する筒状のホルダ(ホルダ30)と、前記ホルダの軸線(軸線AX)方向における一端部(端部30e)に設けられる炭素熱源(炭素熱源20)とを備える香味吸引具(香味吸引具10)であって、前記炭素熱源は、前記軸線方向において、前記ホルダによって保持され、かつ少なくとも一部が前記ホルダから突出した第1部分(第1部分21)と、前記香味発生源と逆側の端部を含む第2部分(第2部分22)とを有し、前記第1部分の少なくとも一部は、前記炭素熱源の延焼を防止する延焼防止剤を含むことを要旨とする。 The first feature of the present invention is that a flavor generating source (flavor generating source 40), a cylindrical holder (holder 30) containing the flavor generating source, and one end portion in the axis (axis AX) direction of the holder ( A flavor suction tool (flavor suction tool 10) comprising a carbon heat source (carbon heat source 20) provided at the end 30e), the carbon heat source being held by the holder in the axial direction and at least partly Has a first part (first part 21) protruding from the holder and a second part (second part 22) including an end opposite to the flavor generating source, and at least one of the first parts The gist is that the part contains a fire spread inhibitor that prevents the carbon heat source from spreading.
 本発明の第2の特徴は、香味発生源を内包する筒状のホルダの軸線方向における一端部に設けられる炭素熱源であって、前記軸線方向において、前記ホルダによって保持され、かつ少なくとも一部が前記ホルダから突出するように設けられる第1部分と、前記香味発生源と逆側の端部を含むように設けられる第2部分とを有し、前記第1部分の少なくとも一部は、前記炭素熱源の延焼を防止する延焼防止剤を含むことを要旨とする。 A second feature of the present invention is a carbon heat source provided at one end portion in the axial direction of a cylindrical holder containing a flavor generating source, and is held by the holder in the axial direction, and at least a part thereof is retained. A first portion provided so as to protrude from the holder; and a second portion provided so as to include an end opposite to the flavor generating source, wherein at least a part of the first portion is the carbon. The gist is to contain a fire spread inhibitor that prevents the heat source from spreading.
 本発明の第3の特徴は、香味発生源(香味発生源40)と、前記香味発生源を内包する筒状のホルダ(ホルダ30)と、前記ホルダの軸線(軸線AX)方向における一端部(端部30e)に設けられる炭素熱源(炭素熱源20)とを備える香味吸引具(香味吸引具10)であって、前記炭素熱源は、前記軸線方向において、前記ホルダによって保持され、かつ少なくとも一部が前記ホルダから突出した第1部分(第1部分21)と、前記香味発生源と逆側の端部を含む第2部分(第2部分22)とを有し、前記炭素熱源は、少なくとも一部に塩化ナトリウムを含み、前記第1部分における前記塩化ナトリウムの前記炭素熱源に対する含有率は、前記第2部分における前記塩化ナトリウムの前記炭素熱源に対する含有率よりも大きいことを要旨とする。 The third feature of the present invention is that a flavor generating source (flavor generating source 40), a cylindrical holder (holder 30) containing the flavor generating source, and one end portion in the axis (axis AX) direction of the holder ( A flavor suction tool (flavor suction tool 10) comprising a carbon heat source (carbon heat source 20) provided at the end 30e), the carbon heat source being held by the holder in the axial direction and at least partly Has a first part (first part 21) protruding from the holder and a second part (second part 22) including an end opposite to the flavor generating source, and the carbon heat source is at least one The part contains sodium chloride, and the content of the sodium chloride in the first part with respect to the carbon heat source is required to be greater than the content of the sodium chloride with respect to the carbon heat source in the second part. To.
 本発明の第4の特徴は、香味発生源を内包する筒状のホルダの軸線方向における一端部に設けられる炭素熱源であって、前記軸線方向において、前記ホルダによって保持され、かつ少なくとも一部が前記ホルダから突出するように設けられる第1部分と、前記香味発生源と逆側の端部を含む第2部分とを有し、前記炭素熱源は、少なくとも一部に塩化ナトリウムを含み、前記第1部分における前記塩化ナトリウムの前記炭素熱源に対する含有率は、前記第2部分における前記塩化ナトリウムの前記炭素熱源に対する含有率よりも大きいことを要旨とする。 A fourth feature of the present invention is a carbon heat source provided at one end in the axial direction of a cylindrical holder containing a flavor generating source, and is held by the holder in the axial direction, and at least a part thereof is retained. A first portion provided so as to protrude from the holder; and a second portion including an end opposite to the flavor generating source, the carbon heat source including sodium chloride at least in part, The content rate of the sodium chloride with respect to the carbon heat source in one portion is larger than the content rate of the sodium chloride with respect to the carbon heat source in the second portion.
 本発明の第5の特徴は、香味発生源(香味発生源40)と、前記香味発生源を内包するホルダ(ホルダ30)と、前記ホルダの軸線(軸線AX)方向における一端部(端部30e)に設けられ、少なくとも一部が前記ホルダから突出した突出部分(突出部分23)を有する炭素熱源(炭素熱源20)とを備える香味吸引具(香味吸引具10)であって、前記炭素熱源は、炭質材料、有機バインダ及び補強剤を含み、前記補強剤は、前記炭素熱源の燃焼温度において不燃性であり、かつ前記補強剤または前記炭素熱源の燃焼温度以下で生成される少なくとも一つの熱分解物が、前記炭素熱源の燃焼温度以下で融解し、前記有機バインダは、カルボキシメチルセルロースナトリウムを含み、前記カルボキシメチルセルロースナトリウムのエーテル化度は0.3以上であることを要旨とする。 The fifth feature of the present invention is that a flavor generating source (flavor generating source 40), a holder (holder 30) containing the flavor generating source, and one end (end 30e) in the axis (axis AX) direction of the holder. ), And a carbon heat source (carbon heat source 20) having a protruding portion (protruding portion 23) at least a portion protruding from the holder. A carbonaceous material, an organic binder, and a reinforcing agent, wherein the reinforcing agent is nonflammable at the combustion temperature of the carbon heat source and is generated at a temperature equal to or lower than the combustion temperature of the reinforcing agent or the carbon heat source. And the organic binder contains sodium carboxymethylcellulose, and the carboxymethylcellulose sodium ether is melted below the combustion temperature of the carbon heat source. The degree and summarized in that less than 0.3.
 本発明の第6の特徴は、香味発生源を内包する筒状のホルダの軸線方向における一端部に設けられる炭素熱源であって、前記ホルダの軸線方向における一端部に設けられ、少なくとも一部が前記ホルダから突出した突出部分を有するとともに、炭質材料、有機バインダ及び補強剤を含み、前記補強剤は、前記炭素熱源の燃焼温度において不燃性であり、かつ前記補強剤または前記炭素熱源の燃焼温度以下で生成される少なくとも一つの熱分解物が、前記炭素熱源の燃焼温度以下で融解し、前記有機バインダは、カルボキシメチルセルロースナトリウムを含み、前記カルボキシメチルセルロースナトリウムのエーテル化度は0.3以上であることを要旨とする。 A sixth feature of the present invention is a carbon heat source provided at one end portion in the axial direction of a cylindrical holder containing a flavor generation source, provided at one end portion in the axial direction of the holder, at least a part of which is provided. The protrusion has a protruding portion protruding from the holder, and includes a carbonaceous material, an organic binder, and a reinforcing agent. The reinforcing agent is nonflammable at the combustion temperature of the carbon heat source, and the combustion temperature of the reinforcing agent or the carbon heat source. At least one thermal decomposition product generated below melts at a temperature lower than the combustion temperature of the carbon heat source, the organic binder contains sodium carboxymethyl cellulose, and the degree of etherification of the sodium carboxymethyl cellulose is 0.3 or more. This is the gist.
図1は、第1実施形態に係る香味吸引具の概略斜視図である。FIG. 1 is a schematic perspective view of a flavor suction device according to the first embodiment. 図2は、第1実施形態に係る香味吸引具の軸線方向に沿った断面図である。FIG. 2 is a cross-sectional view along the axial direction of the flavor suction device according to the first embodiment. 図3は、第1実施形態の実施例に係る炭素熱源の試験サンプルの概略構成を示す図である。FIG. 3 is a diagram illustrating a schematic configuration of a test sample of a carbon heat source according to an example of the first embodiment. 図4は、第1実施形態の実施例に係る喫煙器及び炭素熱源の概略構成を示す図である。FIG. 4 is a diagram illustrating a schematic configuration of a smoker and a carbon heat source according to an example of the first embodiment. 図5は、第1実施形態の変更例に係る炭素熱源の軸線方向に沿った断面図である。FIG. 5 is a cross-sectional view along the axial direction of the carbon heat source according to the modified example of the first embodiment. 図6は、第2実施形態に係る香味吸引具の概略斜視図である。FIG. 6 is a schematic perspective view of a flavor suction device according to the second embodiment. 図7は、第2実施形態に係る香味吸引具の軸線方向に沿った断面図である。FIG. 7 is a cross-sectional view along the axial direction of the flavor suction device according to the second embodiment. 図8は、第2実施形態の変更例に係る炭素熱源の軸線方向に沿った断面図である。FIG. 8 is a cross-sectional view along the axial direction of the carbon heat source according to the modified example of the second embodiment. 図9は、第3実施形態に係る香味吸引具の概略斜視図である。FIG. 9 is a schematic perspective view of a flavor suction device according to the third embodiment. 図10は、第3実施形態に係る香味吸引具の軸線方向に沿った断面図である。FIG. 10: is sectional drawing along the axial direction of the flavor suction tool which concerns on 3rd Embodiment.
 次に、本発明の実施形態について説明する。なお、以下の図面の記載において、同一または類似の部分には、同一または類似の符号を付している。ただし、図面は模式的なものであり、各寸法の比率などは現実のものとは異なることに留意すべきである。 Next, an embodiment of the present invention will be described. In the following description of the drawings, the same or similar parts are denoted by the same or similar reference numerals. However, it should be noted that the drawings are schematic and ratios of dimensions and the like are different from actual ones.
 したがって、具体的な寸法などは以下の説明を参酌して判断すべきものである。また、図面相互間においても互いの寸法の関係や比率が異なる部分が含まれていることは勿論である。 Therefore, specific dimensions should be determined in consideration of the following explanation. Moreover, it is a matter of course that portions having different dimensional relationships and ratios are included between the drawings.
 [第1実施形態]
 (1-1)香味吸引具の全体概略構成
 図1は、第1実施形態に係る香味吸引具10の全体概略構成図である。また、図2は、香味吸引具10の軸線方向に沿った断面図である。
[First Embodiment]
(1-1) Overall Schematic Configuration of Flavor Suction Tool FIG. 1 is an overall schematic configuration diagram of a flavor suction tool 10 according to the first embodiment. FIG. 2 is a cross-sectional view along the axial direction of the flavor suction tool 10.
 図1及び図2に示すように、香味吸引具10は、細長い円柱状であり、炭素熱源20、ホルダ30及び香味発生源40を有する。香味吸引具10は、エアロゾルの発生を抑制するため、炭素熱源20から発生する熱によって香味発生源40を加熱する。 As shown in FIGS. 1 and 2, the flavor suction device 10 has an elongated cylindrical shape, and includes a carbon heat source 20, a holder 30, and a flavor generation source 40. The flavor suction tool 10 heats the flavor generating source 40 with heat generated from the carbon heat source 20 in order to suppress the generation of aerosol.
 炭素熱源20は、ホルダ30の軸線AX方向における端部30e(一端部)に設けられる。炭素熱源20は、ホルダ30の端部30eによって保持される。炭素熱源20は、第1部分21と第2部分22とを有する。具体的には、第1部分21がホルダ30の端部30eによって保持される。 The carbon heat source 20 is provided at the end 30e (one end) in the axis AX direction of the holder 30. The carbon heat source 20 is held by the end 30 e of the holder 30. The carbon heat source 20 includes a first portion 21 and a second portion 22. Specifically, the first portion 21 is held by the end 30 e of the holder 30.
 つまり、第1部分21は、軸線AX方向において、ホルダ30によって保持され、かつ少なくとも一部がホルダ30から突出した部分である。また、第2部分22は、香味発生源40と逆側の端部を含む部分である。第1実施形態では、第2部分22は、第1部分21に隣接し、かつホルダ30から突出した部分である。 That is, the first portion 21 is a portion that is held by the holder 30 and at least a portion of the first portion 21 protrudes from the holder 30 in the direction of the axis AX. Further, the second portion 22 is a portion including an end portion on the opposite side to the flavor generation source 40. In the first embodiment, the second portion 22 is a portion that is adjacent to the first portion 21 and protrudes from the holder 30.
 第1部分21及び第2部分22のうち、少なくとも第1部分21は、炭素熱源20の延焼を防止する延焼防止剤を含む。これにより、ホルダ30が炭素熱源20の発生する熱によって延焼することが防止される。なお、炭素熱源20のより具体的な構成については、後述する。 Among the first portion 21 and the second portion 22, at least the first portion 21 includes a fire spread inhibitor that prevents the carbon heat source 20 from spreading. This prevents the holder 30 from spreading due to the heat generated by the carbon heat source 20. A more specific configuration of the carbon heat source 20 will be described later.
 ホルダ30は、香味発生源40を内包する筒状である。ホルダ30としては、例えば、矩形形状の厚紙を円筒状に湾曲させて両側縁部を合わせて中空の円筒体として形成された紙管によって構成できる。なお、ホルダ30内部において、炭素熱源20と香味発生源40との間に、空隙部または通気性を有する不燃部材を配置することによって、炭素熱源20と香味発生源40とが隣接しないように構成してもよい。 The holder 30 has a cylindrical shape containing the flavor generation source 40. For example, the holder 30 can be configured by a paper tube formed as a hollow cylindrical body by curving a rectangular cardboard into a cylindrical shape and aligning both side edges. In addition, in the holder 30, it arrange | positions so that the carbon heat source 20 and the flavor generation source 40 may not adjoin by arrange | positioning a space | gap part or a nonflammable member which has air permeability between the carbon heat source 20 and the flavor generation source 40. May be.
 香味発生源40は、炭素熱源20によって加熱されることによって、香味を発生する。香味発生源40としては、例えば、たばこ葉を用いることができ、シガレット(紙巻きたばこ)に使用される一般的な刻みたばこ、嗅ぎたばこに使用される粒状たばこ、ロールたばこ、または成形たばこなどのたばこ原料を採用することができる。なお、ロールたばこは、シート状の再生たばこをロール状に成形して得られ、内部に流路を有する。また、成形たばこは、粒状たばこを型成形することによって得られる。また、多孔質または非多孔質の担持体に、メンソールなどの香味成分を担持させてもよい。 The flavor generating source 40 generates flavor by being heated by the carbon heat source 20. As the flavor generating source 40, for example, tobacco leaf can be used. Tobacco raw materials such as general cigarettes used for cigarettes (cigarettes), granular tobacco used for snuff tobacco, roll tobacco, and molded tobacco are used. Can be adopted. Roll tobacco is obtained by forming sheet-like recycled tobacco into a roll shape, and has a flow path inside. In addition, molded tobacco is obtained by molding granular tobacco. Further, a flavor component such as menthol may be supported on a porous or non-porous support.
 (1-2)炭素熱源の構成
 次に、炭素熱源20の構成について具体的に説明する。上述したように、炭素熱源20は、軸線AX方向において、ホルダ30に隣接し、かつ少なくとも一部がホルダ30から突出するように設けられる第1部分21と、第1部分21に隣接し、かつホルダ30から突出するように設けられる第2部分22とを有する。第1実施形態では、第1部分21と第2部分22とは、一体として形成されている。
(1-2) Configuration of Carbon Heat Source Next, the configuration of the carbon heat source 20 will be specifically described. As described above, the carbon heat source 20 is adjacent to the holder 30 in the direction of the axis AX, and is adjacent to the first portion 21 that is provided so as to protrude at least partially from the holder 30, and And a second portion 22 provided so as to protrude from the holder 30. In the first embodiment, the first portion 21 and the second portion 22 are integrally formed.
 炭素熱源20は、植物由来の炭質材料、不燃添加物、有機または無機バインダ及び水を含む混合物を押出などの方法で成形することで得られる。 The carbon heat source 20 is obtained by molding a mixture containing a plant-derived carbonaceous material, an incombustible additive, an organic or inorganic binder and water by a method such as extrusion.
 炭素熱源20の全長は、10mmから30mmの範囲、望ましくは13mmから20mmの範囲とすることが好ましい。また、炭素熱源20の外径は、4mmから8mmの範囲、望ましくは5mmから7mmの範囲とすることが好ましい。これにより、香味吸引具10の熱源として好適に用い得る。 The total length of the carbon heat source 20 is preferably in the range of 10 mm to 30 mm, and preferably in the range of 13 mm to 20 mm. The outer diameter of the carbon heat source 20 is preferably in the range of 4 mm to 8 mm, and preferably in the range of 5 mm to 7 mm. Thereby, it can be used suitably as a heat source of the flavor suction tool 10.
 ホルダ30から突出している炭素熱源20の長さは、8mm~15mmとすることが好ましい。さらに、第1部分21の長さは、ホルダ30から突出している部分において、例えば、1mm~5mmの範囲、好ましくは1.5~3mmの範囲とすることができる。第1部分21のホルダ30に保持される部分は、例えば、3mm~10mmの範囲とすることができる。このような構成により、ホルダ30に過剰な熱が供給されることなく炭素熱源20を自律的に消火せしめ、かつ炭素熱源20がホルダ30から脱落することを防止し得る。 The length of the carbon heat source 20 protruding from the holder 30 is preferably 8 mm to 15 mm. Further, the length of the first portion 21 can be, for example, in the range of 1 mm to 5 mm, preferably in the range of 1.5 to 3 mm, in the portion protruding from the holder 30. The portion of the first portion 21 held by the holder 30 can be in the range of 3 mm to 10 mm, for example. With such a configuration, the carbon heat source 20 can be extinguished autonomously without excessive heat being supplied to the holder 30, and the carbon heat source 20 can be prevented from falling off the holder 30.
 また、第2部分22の長さは、例えば、8mm~10mmの範囲とすることができる。このような構成により、香味吸引具10の使用において、ユーザが十分な回数に亘って香味を吸引し得る。 Further, the length of the second portion 22 can be set in the range of 8 mm to 10 mm, for example. With such a configuration, when the flavor suction tool 10 is used, the user can suck the flavor a sufficient number of times.
 上述したように、第1部分21には炭素熱源20の延焼を防止する延焼防止剤が含まれる。つまり、炭素熱源20のホルダ30との接続部分に延焼防止剤を含有させることによって、ユーザが意識的に炭素熱源20を消火する行為を行わなくとも、延焼防止剤を含有する含有部にて自律的に燃焼が停止するため、ホルダ30などへの延焼を防止できる。ここで、炭素熱源20のホルダ30との接続部分から、延焼防止剤を含む第1部分21の少なくとも一部を露出させることが、ホルダ30などへの過剰な熱の供給を防ぐ観点から好ましい。 As described above, the first portion 21 includes a fire spread inhibitor that prevents the carbon heat source 20 from spreading. That is, by including the fire spreader in the connection portion of the carbon heat source 20 with the holder 30, even if the user does not consciously extinguish the carbon heat source 20, the containing part containing the fire spreader is autonomous. Since the combustion is stopped, the spread of fire to the holder 30 or the like can be prevented. Here, it is preferable to expose at least a part of the first portion 21 including the fire spread inhibitor from the connection portion of the carbon heat source 20 with the holder 30 from the viewpoint of preventing excessive heat supply to the holder 30 and the like.
 (1-3)延焼防止剤の特性
 次に、炭素熱源20の第1部分21に含まれる延焼防止剤の特性について説明する。第1部分21に含まれる延焼防止剤は、炭素熱源20の燃焼温度において不燃性であり、炭素熱源20の燃焼温度以下において吸熱反応を生じることが好ましい。また、吸熱反応として熱分解を生じる場合、熱分解生成物の少なくとも一つが炭素熱源20の燃焼温度において不燃性かつ不揮発性であることが好ましい。
(1-3) Characteristics of the fire spread inhibitor Next, the characteristics of the fire spread inhibitor contained in the first portion 21 of the carbon heat source 20 will be described. It is preferable that the fire spread inhibitor contained in the first portion 21 is nonflammable at the combustion temperature of the carbon heat source 20 and causes an endothermic reaction below the combustion temperature of the carbon heat source 20. Further, when thermal decomposition occurs as an endothermic reaction, it is preferable that at least one of the thermal decomposition products is nonflammable and non-volatile at the combustion temperature of the carbon heat source 20.
 すなわち、延焼防止剤としては、以下の条件を満たす無機物質を用い得る。
  ・ 炭素熱源の燃焼温度(800℃~1200℃)において不燃性である
  ・ 当該燃焼温度以下で融解ないしは熱分解などによる吸熱反応を生じる
  ・ 熱分解を生じる場合、少なくとも一つの熱分解生成物は当該燃焼温度において不燃性かつ不揮発性である。
That is, as the fire spread inhibitor, an inorganic substance that satisfies the following conditions can be used.
-Non-flammable at the combustion temperature of the carbon heat source (800 ° C-1200 ° C)-An endothermic reaction caused by melting or pyrolysis occurs below the combustion temperature-If thermal decomposition occurs, at least one pyrolysis product is Non-flammable and non-volatile at the combustion temperature.
 また、無機物質は、溶液、懸濁液、ペーストまたは粉粒体などの方法で炭素熱源に添加することができる。無機物質は、例えば、上述の条件を満たす可溶性または難溶性のアルカリ金属塩、或いは可溶性または難溶性のアルカリ土類金属塩を好適に用い得る。具体的には、延焼防止剤として、可溶性無機塩または難溶性無機塩を用い得る。可溶性無機塩としては、塩化物、炭酸塩または硫酸塩が挙げられる。また、難溶性無機塩としては、水酸化物、炭酸塩または硫酸塩が挙げられる。 In addition, the inorganic substance can be added to the carbon heat source by a method such as a solution, suspension, paste, or granular material. As the inorganic substance, for example, a soluble or hardly soluble alkali metal salt that satisfies the above-mentioned conditions, or a soluble or hardly soluble alkaline earth metal salt can be preferably used. Specifically, a soluble inorganic salt or a hardly soluble inorganic salt can be used as a fire spread inhibitor. Soluble inorganic salts include chlorides, carbonates or sulfates. Examples of the hardly soluble inorganic salt include hydroxide, carbonate or sulfate.
 さらに具体的には、例えば、塩化ナトリウム、塩化カルシウム、塩化マグネシウム、塩化カリウムなどの塩化物、炭酸ナトリウム、炭酸水素ナトリウムなどの炭酸塩、または硫酸ナトリウム、硫酸マグネシウムなどの硫酸塩及びそれらの水和物などが特に好ましい。また、水酸化マグネシウム、水酸化カルシウムなどの水酸化物、炭酸カルシウム、炭酸マグネシウムなどの炭酸塩、または硫酸カルシウムなどの硫酸塩及びそれらの水和物などが特に好ましい。 More specifically, for example, chlorides such as sodium chloride, calcium chloride, magnesium chloride and potassium chloride, carbonates such as sodium carbonate and sodium bicarbonate, or sulfates such as sodium sulfate and magnesium sulfate and hydration thereof. Particularly preferred are materials. Further, hydroxides such as magnesium hydroxide and calcium hydroxide, carbonates such as calcium carbonate and magnesium carbonate, sulfates such as calcium sulfate and hydrates thereof are particularly preferable.
 上述したような条件を纏めると、表1に示すような無機塩を延焼防止剤として用い得る。 Summarizing the conditions as described above, inorganic salts as shown in Table 1 can be used as a fire spread inhibitor.
Figure JPOXMLDOC01-appb-T000001
Figure JPOXMLDOC01-appb-T000001
 また、延焼防止剤として、例えば液体ガラスのような物質を用いることもできる。係る液体ガラスは、例えば、特許2538527号に開示されている方法によって常温で液体のコーティング剤として得ることができ、係るコーティング剤を塗工などの方法で炭素熱源20の第一部分21に添加後、常温から200℃程度の温度で乾燥することで、ケイ素若しくは金属の酸化物の少なくとも一方を含む被膜を形成することができる。 Also, as a fire spread inhibitor, for example, a substance such as liquid glass can be used. Such liquid glass can be obtained as a liquid coating agent at room temperature by the method disclosed in Japanese Patent No. 2538527, for example, and after adding the coating agent to the first portion 21 of the carbon heat source 20 by a method such as coating, By drying at room temperature to about 200 ° C., a film containing at least one of silicon or metal oxide can be formed.
 (1-4)延焼防止剤の添加方法
 次に、延焼防止剤の添加方法について説明する。延焼防止剤を含む第1部分21は、炭素熱源20の一部に延焼防止剤の溶液、懸濁液、ペースト、粉粒体を浸漬、噴霧、溶射、湿潤、塗工などの方法で添加することで作製できる。
(1-4) Method of adding fire spread inhibitor Next, a method of adding the fire spread inhibitor will be described. The first part 21 containing the fire spreader is added to a part of the carbon heat source 20 by a method such as dipping, spraying, spraying, wetting, or coating a solution, suspension, paste, or granular material of the fire spreader. Can be produced.
 例えば、香味吸引具10に好適なサイズに作製した炭素熱源20の一方の端部を、延焼防止剤を溶解或いは分散させた液体に所定の深さまで含浸し、一定時間保持した後、乾燥することで、任意の長さに亘って第1部分21を設けることができる。また、 第1部分21における延焼防止剤の含有量は、延焼防止剤の溶液濃度及び含浸時間によって任意に制御できる。さらに、炭素熱源20が円筒形状のように軸線AX方向に連通した開口部を有する場合、開口部に通気しながら延焼防止剤の溶液に含浸させることで、延焼防止剤の含浸位置をさらに精度よく制御できる。 For example, one end of a carbon heat source 20 produced to a size suitable for the flavor suction device 10 is impregnated to a predetermined depth in a liquid in which a fire spreader is dissolved or dispersed, held for a certain time, and then dried. Thus, the first portion 21 can be provided over an arbitrary length. Further, the content of the fire spread inhibitor in the first portion 21 can be arbitrarily controlled by the solution concentration of the fire spread inhibitor and the impregnation time. Furthermore, when the carbon heat source 20 has an opening that communicates in the axis AX direction, such as a cylindrical shape, the impregnation position of the fire spread inhibitor is more accurately obtained by impregnating the solution with the fire spread inhibitor while venting the opening. Can be controlled.
 第1部分21における好適な延焼防止剤の含有量及び当該加工部の長さは、選択する延焼防止剤と、加工する炭素熱源20の特徴(形状、組成など)との関係を考慮して、十分な延焼防止効果を得られる数値が選択される。また、延焼防止剤が可溶性の場合、炭素熱源20の内部まで浸透することによって、より高い延焼防止効果が得られる。 In consideration of the relationship between the selected fire spread inhibitor and the characteristics (shape, composition, etc.) of the carbon heat source 20 to be processed, the content of the suitable fire spread inhibitor and the length of the processed portion in the first portion 21 are as follows. A value that provides a sufficient fire spread prevention effect is selected. Further, when the fire spread inhibitor is soluble, a higher fire spread preventing effect can be obtained by penetrating into the carbon heat source 20.
 (1-5)炭素熱源のその他の特徴
 次に、炭素熱源20のその他の特徴について説明する。
(1-5) Other Features of Carbon Heat Source Next, other features of the carbon heat source 20 will be described.
 (1-5.1)可溶性アルカリ金属塩またはアルカリ土類金属塩による付加機能
 炭素熱源20の第2部分22には、表1で挙げた無機物質のうちの少なくとも一種をさらに含んでもよい。この場合、第2部分22に含まれる無機物質の炭素熱源20に対する含有率は、第1部分21に含まれる延焼防止剤の炭素熱源20に対する含有率よりも小さいことが好ましい。
(1-5.1) Additional Function with Soluble Alkali Metal Salt or Alkaline Earth Metal Salt The second portion 22 of the carbon heat source 20 may further include at least one of the inorganic substances listed in Table 1. In this case, the content of the inorganic substance contained in the second portion 22 with respect to the carbon heat source 20 is preferably smaller than the content of the fire spreader contained in the first portion 21 with respect to the carbon heat source 20.
 例えば、第2部分22に、可溶性アルカリ金属塩またはアルカリ土類金属塩のうちの少なくとも一方をさらに含有させることで、燃焼時において、灰皿への衝打などの衝撃によって炭素熱源20が非燃焼部から折れ、燃焼部を含む炭素熱源20が一部脱落すること(火種落ち)を防止し得る。かかる効果は、炭素熱源20のバインダとして熱分解温度の低い有機バインダを採用した場合に、特に顕著である。 For example, by adding at least one of a soluble alkali metal salt or an alkaline earth metal salt to the second portion 22, the carbon heat source 20 is not burned at the time of combustion due to an impact such as hitting an ashtray. Therefore, it is possible to prevent the carbon heat source 20 including the combustion part from dropping off (fire type dropping). Such an effect is particularly remarkable when an organic binder having a low thermal decomposition temperature is adopted as the binder of the carbon heat source 20.
 第1部分21に含まれる可溶性アルカリ金属塩またはアルカリ土類金属塩の含有量は、第2部分22に含まれる延焼防止剤の含有量よりも少ないことが好ましい。さらに、炭素熱源20の第1部分21以外の部分に、低濃度の可溶性アルカリ金属塩を含んでもよい。 The content of the soluble alkali metal salt or alkaline earth metal salt contained in the first portion 21 is preferably smaller than the content of the fire spreader contained in the second portion 22. Furthermore, a portion other than the first portion 21 of the carbon heat source 20 may contain a low-concentration soluble alkali metal salt.
 このような付加機能を実現し得る無機物質としては、以下の条件を満たすことが好ましい。
  ・ 炭素熱源の燃焼温度(800℃~1200℃)において不燃性
  ・ 無機物質または炭素熱源の燃焼温度以下で生成する少なくとも一つの熱分解物が、炭素熱源の燃焼温度以下で融解する。
As an inorganic substance that can realize such an additional function, the following conditions are preferably satisfied.
Incombustibility at the combustion temperature of the carbon heat source (800 ° C. to 1200 ° C.) At least one thermal decomposition product generated below the combustion temperature of the inorganic substance or the carbon heat source melts below the combustion temperature of the carbon heat source.
 このような条件を満たす無機物質としては、上述したように、表1で挙げた可溶性アルカリ金属塩やアルカリ土類金属塩を好適に用い得る。 As the inorganic material satisfying such conditions, as described above, the soluble alkali metal salts and alkaline earth metal salts listed in Table 1 can be suitably used.
 例えば、低濃度の可溶性アルカリ金属塩は、押出などの成形時に炭質材料やバインダなどを混合する際に固体や液体の形状で加えることができる。また、第1部分21を除く第2部分22の可溶性アルカリ金属塩濃度は、着火性及びその他の燃焼特性を阻害しない範囲で十分な効果を得られる数値が選択されるが、例えば、塩化ナトリウムが選択された場合、当該濃度は、5wt%以下であることが好ましく、0.5wt%以下であることがより好ましい。 For example, a low-concentration soluble alkali metal salt can be added in the form of a solid or liquid when a carbonaceous material or a binder is mixed during molding such as extrusion. The soluble alkali metal salt concentration of the second portion 22 excluding the first portion 21 is selected to be a value that provides a sufficient effect within a range that does not impair ignitability and other combustion characteristics. When selected, the concentration is preferably 5 wt% or less, and more preferably 0.5 wt% or less.
 (1-5.2)炭質材料
 炭質材料は、加熱処理などによって揮発性の不純物を除去したものを用いることが望ましいが、これに限定されるものではない。炭質材料は、10wt%~99wt%の範囲で含むことができ、30wt%~70wt%であることが好ましく、40wt%~50wt%とすることが、十分な熱量供給及び灰の飛散防止などの燃焼特性の観点から望ましい。
(1-5.2) Carbonaceous material It is desirable to use a carbonaceous material from which volatile impurities have been removed by heat treatment or the like, but is not limited thereto. The carbonaceous material can be included in the range of 10 wt% to 99 wt%, preferably 30 wt% to 70 wt%, and 40 wt% to 50 wt% to provide sufficient heat supply and combustion for preventing ash scattering, etc. Desirable from the viewpoint of characteristics.
 (1-5.3)バインダ
 バインダとしては、カルボキシメチルセルロースナトリウム(CMC)、アルギン酸アンモニウムなどの有機系バインダ、精製ベントナイトなどの鉱物系、またはコロイダルシリカ、水ガラス及びケイ酸カルシウムなどのシリカ系バインダを含む無機系バインダといった、当業者に公知のバインダを用い得る。
(1-5.3) Binder As the binder, organic binders such as sodium carboxymethyl cellulose (CMC) and ammonium alginate, minerals such as purified bentonite, or silica binders such as colloidal silica, water glass and calcium silicate are used. Binders known to those skilled in the art, such as inorganic binders, can be used.
 なお、有機バインダ、特にCMCを使用することが香味の観点から望ましい。また、炭素熱源20が表1に挙げた可溶性のアルカリ金属塩または可溶性のアルカリ土類金属塩を含み、かつCMCをバインダとして用いる場合、CMCのエーテル化度は0.3以上に設定される。このような構成により、製造・使用に耐え得る強度を炭素熱源20に付与し得る。エーテル化度が低いCMCを用いると、成形乾燥後の強度が乏しく、製造・使用適性が著しく悪化してしまう恐れがある。また、例えば、エーテル化度が0.8未満のCMCを使用することによって、押出などの成形時に容易に成形することが可能となる。 In addition, it is desirable from the viewpoint of flavor to use an organic binder, particularly CMC. Further, when the carbon heat source 20 includes the soluble alkali metal salt or the soluble alkaline earth metal salt listed in Table 1 and CMC is used as a binder, the degree of etherification of CMC is set to 0.3 or more. With such a configuration, the carbon heat source 20 can be given strength that can withstand manufacturing and use. When CMC having a low degree of etherification is used, the strength after molding and drying is poor, and the suitability for production and use may be significantly deteriorated. Further, for example, by using CMC having a degree of etherification of less than 0.8, it becomes possible to easily mold at the time of molding such as extrusion.
 具体的には、CMCは、1~10wt%含むことができ、1wt%~8wt%含むことが、香味の観点からより好ましい。 Specifically, CMC can be contained in an amount of 1 to 10 wt%, and more preferably 1 wt% to 8 wt% from the viewpoint of flavor.
 (1-5.4)不燃添加物
 不燃添加物としては、例えば、ナトリウム、カリウム、カルシウム、マグネシウム、ケイ素などからなる炭酸塩または酸化物を使用でき、40~89wt%含むことができる。特に、炭酸カルシウムを炭素熱源20中に40wt%~55wt%含むことが好ましい。
(1-5.4) Nonflammable Additive As the nonflammable additive, for example, a carbonate or oxide composed of sodium, potassium, calcium, magnesium, silicon, etc. can be used, and it can be contained in 40 to 89 wt%. In particular, it is preferable to contain 40 wt% to 55 wt% of calcium carbonate in the carbon heat source 20.
 (1-6)実施例
 次に、香味吸引具10を構成する炭素熱源20の実施例について説明する。
(1-6) Example Next, an example of the carbon heat source 20 constituting the flavor suction tool 10 will be described.
 (1-6.1)延焼防止剤
 (1-6.1.1)炭素熱源の組成・作製方法
 以下の方法によって、表2に示す組成の炭素熱源20を作製した。
  ・ 活性炭86g、炭酸カルシウム(CaCO)117gにエーテル化度0.6のCMC10.8gを混合し、さらに塩化ナトリウム2.2gを含む水250gを混合する
  ・ 上述した混合物を混練の後、外径6mm、内径4mmの円筒形状となるよう押出成型する
  ・成型物を乾燥後、13mmの長さに切断し、炭素熱源20を得る。
(1-6.1) Fire spread inhibitor (1-6.1.1) Composition and production method of carbon heat source A carbon heat source 20 having the composition shown in Table 2 was produced by the following method.
-86 g of activated carbon and 117 g of calcium carbonate (CaCO 3 ) are mixed with 10.8 g of CMC having a degree of etherification of 0.6, and 250 g of water containing 2.2 g of sodium chloride is further mixed. Extrusion molding so as to form a cylindrical shape of 6 mm and an inner diameter of 4 mm. After the molding is dried, it is cut into a length of 13 mm to obtain the carbon heat source 20.
Figure JPOXMLDOC01-appb-T000002
Figure JPOXMLDOC01-appb-T000002
 (1-6.1.2)試験サンプル
 上述した方法で作製した炭素熱源にNaCl水溶液を含浸させ、表3に示す試験用熱源A~Fを作製した。
(1-6.1.2) Test Sample The carbon heat source produced by the above-described method was impregnated with an aqueous NaCl solution to produce test heat sources A to F shown in Table 3.
Figure JPOXMLDOC01-appb-T000003
Figure JPOXMLDOC01-appb-T000003
 なお、試験用熱源A~Fについて、NaClの含浸は以下の方法で行った。
  ・ 内径5mmのチューブに13mmの熱源を10mm挿し込み、1000ml/分の空気を流しながら、それぞれのサンプルについて表3に示した濃度のNaCl水溶液に210秒間浸する
  ・ 試験用熱源を取り出し後、60℃で6時間乾燥し、NaCl含浸熱源を得る
The test heat sources A to F were impregnated with NaCl by the following method.
・ Insert a 13 mm heat source into a tube with an inner diameter of 5 mm, and immerse each sample in a NaCl aqueous solution having a concentration shown in Table 3 for 210 seconds while flowing air at 1000 ml / min. Dry at 6 ° C. for 6 hours to obtain a NaCl impregnation heat source
 また、含浸部分における炭素熱源中のNaCl含有量は、以下の式により算出した。
  1mm当NaCl含有量=
  (含浸後熱源乾燥重量-未含浸熱源乾燥重量)/ 熱源中NaCl含浸部長さ
Further, the NaCl content in the carbon heat source in the impregnated portion was calculated by the following equation.
1 mm equivalent NaCl content =
(Heat source dry weight after impregnation-dry weight of unimpregnated heat source) / length of NaCl impregnated part in heat source
 (1-6.1.3)延焼防止機能の評価方法
 以下の方法によって、模擬喫煙評価を実施した。
  ・ 内径6mmの紙管に熱源を3mm挿し込み、ボルグワルド社製喫煙器にセットする
  ・ 電気ライターで熱源を8秒間加熱後、それぞれのサンプルについて表3に示した容量で吸引し着火する
  ・ 上記容量で吸引する操作を30秒間隔で繰り返す
  ・ NaCl含浸部位にて延焼の防止可否を目視で確認する
(1-6.1.3) Evaluation method of fire spread prevention function Simulated smoking evaluation was performed by the following method.
-Insert a heat source 3 mm into a 6 mm inner diameter paper tube and set it in a Borgwald smoker.-Heat the heat source with an electric lighter for 8 seconds, then suck and ignite each sample with the capacity shown in Table 3-The above capacity Repeat the suction operation at 30 second intervals ・ Visually check whether or not the fire spread is prevented at the NaCl impregnation site
 (1-6.1.4)評価結果
 上述した評価の結果を表4に示す。
(1-6.1.4) Evaluation results Table 4 shows the results of the evaluations described above.
Figure JPOXMLDOC01-appb-T000004
Figure JPOXMLDOC01-appb-T000004
 表4に示すように、延焼防止剤の含浸部において、NaClと可燃物(炭質材料及び有機バインダの和)の重量比を0.35以上、またはNaClと炭質材料の重量比を0.40以上とすることで、延焼防止剤の含有部において自律的に燃焼が停止し、十分な延焼防止機能を得られている。 As shown in Table 4, the weight ratio of NaCl and combustible material (sum of carbonaceous material and organic binder) is 0.35 or more, or the weight ratio of NaCl and carbonaceous material is 0.40 or more in the impregnation part of the fire spreader. By doing so, combustion is stopped autonomously in the part containing the fire spread inhibitor, and a sufficient fire spread prevention function is obtained.
 (1-6.2)CaCO、Mg(OH)、液体ガラスの効果の検証
 (1-6.2.1)試験サンプル
 CaCO、Mg(OH)、液体ガラスの効果を検証するため、押出成形により、表5に示す組成であり、図3に示す形状を有する炭素熱源20の試験サンプルを作製した。
(1-6.2) Verification of effects of CaCO 3 , Mg (OH) 2 and liquid glass (1-6.2.1) Test sample To verify the effects of CaCO 3 , Mg (OH) 2 and liquid glass A test sample of the carbon heat source 20 having the composition shown in Table 5 and having the shape shown in FIG. 3 was produced by extrusion molding.
Figure JPOXMLDOC01-appb-T000005
Figure JPOXMLDOC01-appb-T000005
 また、含有部の長さが20mmとなるように、所定量のCaCOまたはMg(OH)の懸濁液もしくは二種類の液体ガラス(テリオスコートNP-360G及び360KT、株式会社日興製)を、炭素熱源20の外周部に塗布及び開孔部へ滴下し、表6に示す試験用熱源G~Jを作製した。 In addition, a predetermined amount of suspension of CaCO 3 or Mg (OH) 2 or two types of liquid glass (Terios Coat NP-360G and 360KT, manufactured by Nikko Co., Ltd.) so that the length of the containing part is 20 mm. Then, it was applied to the outer peripheral portion of the carbon heat source 20 and dropped onto the opening portion to prepare test heat sources G to J shown in Table 6.
Figure JPOXMLDOC01-appb-T000006
Figure JPOXMLDOC01-appb-T000006
 CaCOまたはMg(OH)の懸濁液もしくは液体ガラスの含浸部分における炭素熱源20中の延焼防止剤の含有量は、以下の式により算出した。
  ・1mm当延焼防止剤含有量=延焼防止剤添加量/熱源中の含浸部長さ
The content of the fire spread inhibitor in the carbon heat source 20 in the impregnated portion of the suspension or liquid glass of CaCO 3 or Mg (OH) 2 was calculated by the following equation.
・ 1mm present fire spreader content = addition amount of fire spread inhibitor / length of impregnated part in heat source
 (1-6.2.2)延焼防止機能の評価方法
 以下の方法によって、模擬喫煙評価を実施した。
  ・ 内径6mmの紙管に熱源を3mm挿し込み、ボルグワルド社製喫煙器にセットする
  ・ 電気ライターで熱源を8秒間加熱後、それぞれのサンプルについて55ml/2secで吸引し着火する
  ・ 上記容量で吸引する操作を15秒間隔で繰り返す
  ・ 延焼防止剤の含有部において燃焼が停止した場合、当該含有部と非含有部の境界から燃焼停止位置までの長さを測定する(図4参照)。
(1-6.2.2) Evaluation method of fire spread prevention function Simulated smoking evaluation was performed by the following method.
-Insert a heat source 3 mm into a 6 mm inner diameter paper tube and set it in a Borgwald smoker.-Heat the heat source with an electric lighter for 8 seconds, and then suck and ignite each sample at 55 ml / 2 sec. Repeat the operation at intervals of 15 seconds. When combustion is stopped in the part containing the flame spread inhibitor, the length from the boundary between the containing part and the non-containing part to the combustion stop position is measured (see FIG. 4).
 (1-6.2.3)評価結果
 上述した評価の結果を表7に示す。
(1-6.2.3) Evaluation results Table 7 shows the results of the evaluations described above.
Figure JPOXMLDOC01-appb-T000007
Figure JPOXMLDOC01-appb-T000007
 表7に示すように、本試験に使用した延焼防止剤(CaCO、Mg(OH)、液体ガラス)の何れも、所定量を炭素熱源20に含有させることで、延焼防止剤の含有部において自律的に燃焼を停止可能であることが確認できた。 As shown in Table 7, any of the fire spread inhibitors (CaCO 3 , Mg (OH) 2 , liquid glass) used in this test contains a predetermined amount in the carbon heat source 20, so that the content of the fire spread inhibitor is included. It was confirmed that combustion can be stopped autonomously at
 また、表7の評価結果から、さらに以下のことが推察される。
 ・ 使用する延焼防止剤の種類によって、燃焼停止に必要な添加量は異なる。例えば、Mg(OH)は、CaCOよりも燃焼停止の効果が高いと考えられる。Mg(OH)の方が、熱分解における吸熱量が大きいためと推察される。
 ・ 開孔内部と外周部への添加量の比率により、延焼防止効果が異なる。
Further, from the evaluation results in Table 7, the following can be further inferred.
・ The amount of addition required to stop combustion differs depending on the type of fire spread inhibitor used. For example, Mg (OH) 2 is considered to have a higher combustion stop effect than CaCO 3 . It is presumed that Mg (OH) 2 has a larger endothermic amount in pyrolysis.
・ The effect of preventing fire spread differs depending on the ratio of the amount added to the inside of the hole and the outer periphery.
 なお、表1において「×:燃焼持続」と判定されたサンプル(例えば、サンプルGー-3、H-5)についても、他のサンプルと同レベルの効果が得られないものの、一定の効果は得られたことに留意すべきである。 It should be noted that, although the same level of effect as the other samples cannot be obtained for the samples (for example, Samples G--3 and H-5) determined as “x: burning duration” in Table 1, the certain effects are It should be noted that it was obtained.
 (1-6.3)低濃度の可溶性アルカリ金属塩含有による火種落ち防止効果の検証
 (1-6.3.1)試験サンプル
 低濃度の可溶性アルカリ金属塩含有による火種落ち防止効果の検証するため、押出成形により、表8に示す組成の炭素熱源20(全長15mm、外径6mm)の試験サンプルを作製した。
(1-6.3) Verification of fire-disappearance prevention effect by containing a low concentration of soluble alkali metal salt (1-6.3.1) Test sample A test sample of a carbon heat source 20 (total length 15 mm, outer diameter 6 mm) having the composition shown in Table 8 was produced by extrusion molding.
Figure JPOXMLDOC01-appb-T000008
Figure JPOXMLDOC01-appb-T000008
 (1-6.3.2)火種落ち防止機能の評価方法
 以下の方法によって、模擬喫煙評価を実施した。
  ・ 作製した炭素熱源20を、外径6mmの紙管に3mm挿入し、評価サンプルとする
  ・ 炭素熱源20を着火し、燃焼中に任意のタイミングで、シガレットの灰を落とす要領で、評価サンプルを金属製灰皿に衝打する
  ・ 衝打時に炭素熱源20が非燃焼部で折れた場合は火種落ちが生じたと判定する
(1-6.3.2) Evaluation method of fire drop-off prevention function Simulated smoking evaluation was performed by the following method.
-Insert the produced carbon heat source 20 into a paper tube with an outer diameter of 6 mm 3 mm and use it as an evaluation sample.-Ignite the carbon heat source 20 and remove the cigarette ash at any timing during combustion. Hit the metal ashtray-If the carbon heat source 20 breaks in the non-combustion part at the time of hitting, it is determined that the fire type has dropped.
 (1-6.3.3)評価結果
 各サンプルの評価結果は以下のとおりであった。
  K:火種落ちが生じた。
  L:火種落ちは生じなかった。
  M:火種落ちは生じなかった。
  N:火種落ちは生じなかった。使用中に可視煙が生じた。
  O:火種落ちは生じなかった。使用中に可視煙が生じた。
(1-6.3.3) Evaluation Results The evaluation results for each sample were as follows.
K: A fire drop occurred.
L: No drop of fire occurred.
M: No drop of fire occurred.
N: No drop of fire occurred. Visible smoke was produced during use.
O: No drop of fire occurred. Visible smoke was produced during use.
 以上の結果より、炭素熱源20全体に低濃度のNaClを含有させることで火種落ちを防止可能であることが確認できた。 From the above results, it was confirmed that it was possible to prevent a fire drop from occurring by adding a low concentration of NaCl to the entire carbon heat source 20.
 なお、上述した試験条件においては、炭素熱源20におけるNaCl含有率を0.5wt%以上とすることで、十分な火種落ち防止効果を有することが確認できた。一方、NaCl含有率が3wt%以上の場合、使用中に可視煙が生じたことから、本試験に使用した炭素熱源20を無煙の香味吸引具の熱源として採用する際には、NaCl含有率は3wt%未満とすることが望ましい。 In addition, in the test conditions mentioned above, it has confirmed that it had sufficient fire-type fall-off prevention effect by making NaCl content rate in the carbon heat source 20 into 0.5 wt% or more. On the other hand, when the NaCl content was 3 wt% or more, visible smoke was generated during use. Therefore, when the carbon heat source 20 used in this test was adopted as the heat source of the smokeless flavor inhaler, the NaCl content was It is desirable to make it less than 3 wt%.
 (1-7)作用・効果
 以上説明したように、香味吸引具10及び炭素熱源20によれば、ホルダ30から突出した第1部分21には、炭素熱源20の延焼を防止する延焼防止剤が含まれる。このため、香味発生源40を内包したホルダ30との接触部分まで炭素熱源20の燃焼が進行してしまうことを防止し得る。
(1-7) Actions / Effects As described above, according to the flavor suction tool 10 and the carbon heat source 20, the first portion 21 protruding from the holder 30 has a fire spread inhibitor that prevents the carbon heat source 20 from spreading. included. For this reason, it is possible to prevent the combustion of the carbon heat source 20 from proceeding to the contact portion with the holder 30 containing the flavor generating source 40.
 また、上述したように炭素熱源20以外の別部材を設けることなく、ホルダ30への過剰な熱の供給を防止でき、ホルダ30の燃焼または熱分解を防止し得る。つまり、ホルダ30への過剰な熱の供給が防止されるため、ホルダ30に格別の耐熱性を付与する必要がなく、紙管などの素材でもホルダ30として好適に採用でき、製造コストの増大も抑制し得る。 Further, as described above, excessive heat supply to the holder 30 can be prevented without providing another member other than the carbon heat source 20, and combustion or thermal decomposition of the holder 30 can be prevented. That is, since supply of excessive heat to the holder 30 is prevented, it is not necessary to give the holder 30 special heat resistance, and even a material such as a paper tube can be suitably used as the holder 30 and the manufacturing cost is increased. Can be suppressed.
 (1-8)その他の実施形態
 上述したように、第1実施形態を通じて本発明の内容を開示したが、この開示の一部をなす論述及び図面は、本発明を限定するものであると理解すべきではない。この開示から当業者には様々な代替実施の形態が明らかとなろう。
(1-8) Other Embodiments As described above, the contents of the present invention have been disclosed through the first embodiment. However, it is understood that the description and drawings constituting a part of this disclosure limit the present invention. should not do. From this disclosure, various alternative embodiments will be apparent to those skilled in the art.
 例えば、炭素熱源20の第1部分21及び第2部分22の形状は、次のように変更してもよい。図5(a)~(c)は、本発明の変更例に係る炭素熱源の軸線方向に沿った断面図である。 For example, the shapes of the first portion 21 and the second portion 22 of the carbon heat source 20 may be changed as follows. 5A to 5C are cross-sectional views along the axial direction of the carbon heat source according to the modified example of the present invention.
 図5(a)に示すように、延焼防止剤(図中のドット部分)は、第1部分21の外周部分に配置されてもよい。また、図5(b)に示すように、第1部分21は、ホルダ30の軸線方向に沿った断面において、香味発生源40(図5(b)において不図示)に接近するに連れて延焼防止剤(図中のドット部分)を含む領域が広くなるように構成されてもよい。なお、図5(b)では、第1部分21の延焼防止剤を含まない部分が略三角形状だが、当該部分は、必ずしも三角形状でなくてもよく、例えば、ピラミッド状でもよい。 As shown in FIG. 5A, the fire spread inhibitor (dot portion in the figure) may be disposed on the outer peripheral portion of the first portion 21. Further, as shown in FIG. 5B, the first portion 21 spreads as it approaches the flavor generating source 40 (not shown in FIG. 5B) in the cross section along the axial direction of the holder 30. You may comprise so that the area | region containing an inhibitor (dot part in a figure) may become large. In FIG. 5B, the portion of the first portion 21 that does not contain the fire spread inhibitor is substantially triangular, but the portion does not necessarily have a triangular shape, and may be a pyramid shape, for example.
 さらに、図5(c)に示すように、第1部分21及び第2部分22の両方は、ホルダ30の軸線方向に沿った断面において、香味発生源40に接近するに連れて延焼防止剤を含む領域が広くなるように構成されてもよい。 Further, as shown in FIG. 5C, both the first portion 21 and the second portion 22 are provided with a fire spread inhibitor as they approach the flavor generating source 40 in the cross section along the axial direction of the holder 30. You may comprise so that the area | region to include may become large.
 また、上述した実施形態では、第1部分21の軸線AXにおける全体において延焼防止剤が含まれる例について説明したが、第1部分21の少なくとも一部に延焼防止剤が含まれていればよく、例えば、ホルダ30によって保持されていない第1部分21にのみ延焼防止剤を含むようにしてもよい。 In the above-described embodiment, the example in which the fire spreader is included in the entire axis AX of the first portion 21 has been described. However, it is sufficient that at least part of the first portion 21 includes the fire spread inhibitor. For example, the fire spreader may be included only in the first portion 21 that is not held by the holder 30.
 第1実施形態では、炭素熱源20において延焼防止剤の含有領域を種々変更する例を示したが、炭素熱源20の軸線方向において、当該物質を異なる濃度で含有させてもよい。(1-5.1)で述べた、低濃度の可溶性のアルカリ金属塩または可溶性のアルカリ土類金属塩を第2部分22に含む構成はその一例である。また、例えば、炭素熱源20の着火端側において当該物質の濃度を薄く、ホルダ30側が濃くなるよう濃度勾配を実現できる。これにより、より精密に炭素熱源20が発する熱量を制御し得る。 In the first embodiment, an example in which the flame spreader containing region is variously changed in the carbon heat source 20 has been shown, but the substance may be contained at different concentrations in the axial direction of the carbon heat source 20. An example of the configuration described in (1-5.1) is that the second portion 22 contains a low concentration of soluble alkali metal salt or soluble alkaline earth metal salt. Further, for example, the concentration gradient can be realized such that the concentration of the substance is thin on the ignition end side of the carbon heat source 20 and the holder 30 side is thick. Thereby, the amount of heat generated by the carbon heat source 20 can be controlled more precisely.
 また、好適な延焼防止剤の含有量(濃度)は、延焼防止剤の種類は勿論のこと、炭素熱源20の形状や組成(発熱量)によって異なるが、(1-4)に示した方法によって、延焼防止の効果を奏し得るように、延焼防止剤を任意の含有量に設定することができる。 Further, the preferable content (concentration) of the fire spread inhibitor varies depending on the shape and composition (calorific value) of the carbon heat source 20 as well as the type of the fire spread inhibitor, but it depends on the method shown in (1-4). In order to achieve the effect of preventing the spread of fire, the fire spread inhibitor can be set to an arbitrary content.
 第1実施形態では、炭素熱源20の外形は円柱状であったが、円柱状に限らず、直方体など、様々な形状も本発明に含まれることは勿論である。 In the first embodiment, the outer shape of the carbon heat source 20 is a cylindrical shape. However, the present invention is not limited to the cylindrical shape, and various shapes such as a rectangular parallelepiped are naturally included in the present invention.
 [第2実施形態]
 (2-1)香味吸引具の全体概略構成
 図6は、第2実施形態に係る香味吸引具10の全体概略構成図である。また、図7は、香味吸引具10の軸線方向に沿った断面図である。
[Second Embodiment]
(2-1) Overall Schematic Configuration of Flavor Suction Tool FIG. 6 is an overall schematic configuration diagram of the flavor suction tool 10 according to the second embodiment. FIG. 7 is a cross-sectional view of the flavor suction tool 10 along the axial direction.
 図6及び図7に示すように、香味吸引具10は、第1実施形態と同様に、細長い円柱状であり、炭素熱源20、ホルダ30及び香味発生源40を有する。香味吸引具10は、エアロゾルの発生を抑制するため、炭素熱源20から発生する熱によって香味発生源40を加熱する。 As shown in FIG. 6 and FIG. 7, the flavor inhaler 10 has an elongated cylindrical shape as in the first embodiment, and includes a carbon heat source 20, a holder 30, and a flavor generation source 40. The flavor suction tool 10 heats the flavor generating source 40 with heat generated from the carbon heat source 20 in order to suppress the generation of aerosol.
 (2-2)炭素熱源の構成
 次に、炭素熱源20の構成について具体的に説明する。炭素熱源20は、第1実施形態と同様に、軸線AX方向において、ホルダ30に隣接し、かつ少なくとも一部がホルダ30から突出するように設けられる第1部分21と、第1部分21に隣接し、かつホルダ30から突出するように設けられる第2部分22とを有する。第2実施形態では、第1部分21と第2部分22とは、一体として形成されている。
(2-2) Configuration of Carbon Heat Source Next, the configuration of the carbon heat source 20 will be specifically described. Similarly to the first embodiment, the carbon heat source 20 is adjacent to the holder 30 in the axis AX direction, and is adjacent to the first portion 21 and the first portion 21 provided so as to protrude at least partially from the holder 30. And a second portion 22 provided so as to protrude from the holder 30. In the second embodiment, the first portion 21 and the second portion 22 are integrally formed.
 第2実施形態では、第2部分22にも低濃度のNaCl(延焼防止剤の一例)を含むことができる。すなわち、第2部分22におけるNaClの炭素熱源20に対する含有率は、第1部分21におけるNaClの炭素熱源20に対する含有率よりも小さい。これにより、炭素熱源20の着火性を阻害することなく、ホルダ30が炭素熱源20の発生する熱によって延焼すること、及び香味吸引具10を灰皿などに一定以上の力で叩いても炭素熱源20の燃焼部分(火種)の落下を防止できる。かかる効果は、炭素熱源20のバインダとして熱分解温度の低い有機バインダを採用した場合に、特に顕著である。 In the second embodiment, the second portion 22 can also contain a low concentration of NaCl (an example of a fire spread inhibitor). That is, the content rate of NaCl in the second part 22 with respect to the carbon heat source 20 is smaller than the content rate of NaCl in the first part 21 with respect to the carbon heat source 20. Thus, the carbon heat source 20 can be produced even if the holder 30 is spread by the heat generated by the carbon heat source 20 without impeding the ignitability of the carbon heat source 20 and the flavor suction tool 10 is hit against an ashtray with a certain level of force. Can prevent the burning part (fire type) from falling. Such an effect is particularly remarkable when an organic binder having a low thermal decomposition temperature is adopted as the binder of the carbon heat source 20.
 (2-3)塩化ナトリウムの添加方法
 次に、塩化ナトリウム(NaCl)の添加方法について説明する。高濃度のNaClを含む第1部分21は、炭素熱源20の一部にNaClの溶液、懸濁液、ペースト、粉粒体を浸漬、噴霧、溶射、湿潤、塗工などの方法で添加することで作製できる。
(2-3) Method for Adding Sodium Chloride Next, a method for adding sodium chloride (NaCl) will be described. The first portion 21 containing high-concentration NaCl is added to a part of the carbon heat source 20 by immersing, spraying, spraying, wetting, coating, or the like a solution, suspension, paste, or powder of NaCl. Can be produced.
 例えば、香味吸引具10に好適なサイズに作製した炭素熱源20の一方の端部を、NaClを溶解或いは分散させた液体に所定の深さまで含浸し、一定時間保持した後、乾燥することで、任意の長さに亘って第1部分21を設けることができる。また、 第1部分21におけるNaClの含有量は、NaClの溶液濃度及び含浸時間によって任意に制御できる。さらに、炭素熱源20が円筒形状のように軸線AX方向に連通した開口部を有する場合、開口部に通気しながらNaClの溶液に含浸させることで、NaClの含浸位置をさらに精度よく制御できる。 For example, by impregnating one end of the carbon heat source 20 produced in a size suitable for the flavor suction tool 10 to a predetermined depth in a liquid in which NaCl is dissolved or dispersed, holding it for a certain time, and then drying, The first portion 21 can be provided over any length. The NaCl content in the first portion 21 can be arbitrarily controlled by the NaCl solution concentration and the impregnation time. Further, when the carbon heat source 20 has an opening communicating in the direction of the axis AX like a cylindrical shape, the NaCl impregnation position can be controlled with higher accuracy by impregnating with the NaCl solution while venting the opening.
 第1部分21における好適なNaClの含有量及び当該加工部の長さは、加工する炭素熱源20の特徴(形状、組成など)との関係を考慮して、十分な延焼防止効果を得られる数値が選択される。また、NaClを炭素熱源20の内部まで浸透することによって、より高い延焼防止効果が得られる。 A suitable NaCl content in the first portion 21 and the length of the processed portion are values that can obtain a sufficient fire spread prevention effect in consideration of the relationship with the characteristics (shape, composition, etc.) of the carbon heat source 20 to be processed. Is selected. Further, by infiltrating NaCl into the carbon heat source 20, a higher fire spread prevention effect can be obtained.
 (2-4)塩化ナトリウムによる火種落ち防止機能
 上述したように、炭素熱源20には、低濃度の塩化ナトリウム(NaCl)による火種(炭素熱源20)落ち防止機能を付与することができる。このような低濃度のNaClは、例えば、押出などの成形時に炭質材料やバインダなどを混合する際に固体や液体の形状で加えることができる。また、第1部分21を除く第2部分22のNaCl濃度は、着火性及びその他の燃焼特性を阻害しない範囲で十分な効果を得られる数値が選択されるが、例えば1wt%以下であることが好ましく、0.5wt%以下であることがより好ましい。
(2-4) Fire Type Drop Prevention Function by Sodium Chloride As described above, the carbon heat source 20 can be provided with a fire type (carbon heat source 20) fall prevention function by low concentration sodium chloride (NaCl). Such low-concentration NaCl can be added in the form of a solid or liquid when, for example, a carbonaceous material or a binder is mixed during molding such as extrusion. The NaCl concentration of the second portion 22 excluding the first portion 21 is selected to be a value that provides a sufficient effect within a range that does not impair the ignitability and other combustion characteristics, but may be, for example, 1 wt% or less. Preferably, it is 0.5 wt% or less.
 (2-5)炭素熱源のその他の特徴
 次に、炭素熱源20のその他の特徴について説明する。
(2-5) Other Features of Carbon Heat Source Next, other features of the carbon heat source 20 will be described.
 (2-5.1)炭質材料
 炭質材料は、加熱処理などによって揮発性の不純物を除去したものを用いることが望ましいが、これに限定されるものではない。炭質材料は、10wt%~99wt%の範囲で含むことができ、30wt%~70wt%であることが好ましく、40wt%~50wt%とすることが、十分な熱量供給及び灰の飛散防止などの燃焼特性の観点から望ましい。
(2-5.1) Carbonaceous material It is desirable to use a carbonaceous material from which volatile impurities have been removed by heat treatment or the like, but is not limited thereto. The carbonaceous material can be included in the range of 10 wt% to 99 wt%, preferably 30 wt% to 70 wt%, and 40 wt% to 50 wt% to provide sufficient heat supply and combustion for preventing ash scattering, etc. Desirable from the viewpoint of characteristics.
 炭質材料は、加熱処理などによって揮発性の不純物を除去したものを用いることが望ましいが、これに限定されるものではない。炭質材料は、10wt%~99wt%の範囲で含むことができ、30wt%~70wt%であることが好ましく、40wt%~50wt%とすることが、十分な熱量供給及び灰の飛散防止などの燃焼特性の観点から望ましい。 Although it is desirable to use a carbonaceous material from which volatile impurities have been removed by heat treatment or the like, the carbonaceous material is not limited to this. The carbonaceous material can be included in the range of 10 wt% to 99 wt%, preferably 30 wt% to 70 wt%, and 40 wt% to 50 wt% to provide sufficient heat supply and combustion for preventing ash scattering, etc. Desirable from the viewpoint of characteristics.
 (2-5.2)バインダ
 バインダとしては、カルボキシメチルセルロースナトリウム(CMC)、アルギン酸アンモニウムなどの有機系バインダ、精製ベントナイトなどの鉱物系、またはコロイダルシリカ、水ガラス及びケイ酸カルシウムなどのシリカ系バインダを含む無機系バインダといった、当業者に公知のバインダを用い得る。
(2-5.2) Binder As the binder, organic binders such as sodium carboxymethylcellulose (CMC) and ammonium alginate, minerals such as purified bentonite, or silica binders such as colloidal silica, water glass and calcium silicate are used. Binders known to those skilled in the art, such as inorganic binders, can be used.
 なお、有機バインダ、特にCMCを使用することが香味の観点から望ましい。また、CMCをバインダとして用いる場合、CMCのエーテル化度は0.3以上に設定される。このような構成により、製造・使用に耐え得る強度を炭素熱源20に付与し得る。エーテル化度が低いCMCを用いると、成形乾燥後の強度が乏しく、製造・使用適性が著しく悪化してしまう恐れがある。また、例えば、エーテル化度が0.8未満のCMCを使用することによって、押出などの成形時に容易に成形することが可能となる。 In addition, it is desirable from the viewpoint of flavor to use an organic binder, particularly CMC. Moreover, when using CMC as a binder, the degree of etherification of CMC is set to 0.3 or more. With such a configuration, the carbon heat source 20 can be given strength that can withstand manufacturing and use. When CMC having a low degree of etherification is used, the strength after molding and drying is poor, and the suitability for production and use may be significantly deteriorated. Further, for example, by using CMC having a degree of etherification of less than 0.8, it becomes possible to easily mold at the time of molding such as extrusion.
 具体的には、CMCは、1~10wt%含むことができ、1wt%~8wt%含むことが、香味の観点からより好ましい。 Specifically, CMC can be contained in an amount of 1 to 10 wt%, and more preferably 1 wt% to 8 wt% from the viewpoint of flavor.
 (2-5.3)不燃添加物
 不燃添加物としては、例えば、ナトリウム、カリウム、カルシウム、マグネシウム、ケイ素などからなる炭酸塩または酸化物を使用でき、40~89wt%含むことができる。特に、炭酸カルシウムを炭素熱源20中に40wt%~55wt%含むことが好ましい。
(2-5.3) Nonflammable Additives As the nonflammable additives, for example, carbonates or oxides composed of sodium, potassium, calcium, magnesium, silicon and the like can be used, and they can be contained in 40 to 89 wt%. In particular, it is preferable to contain 40 wt% to 55 wt% of calcium carbonate in the carbon heat source 20.
 (2-6)実施例
  次に、香味吸引具10を構成する炭素熱源20の実施例について説明する。
(2-6) Example Next, an example of the carbon heat source 20 constituting the flavor suction tool 10 will be described.
 (2-6.1)高濃度の塩化ナトリウムによる延焼防止効果の検証
 (2-6.1.1)炭素熱源の組成・作製方法
 以下の方法によって、表9に示す組成の炭素熱源20を作製した。
  ・ 活性炭86g、炭酸カルシウム(CaCO)117gにエーテル化度0.6のCMC10.8gを混合し、さらに塩化ナトリウム2.2gを含む水250gを混合する
  ・ 上述した混合物を混練の後、外径6mm、内径4mmの円筒形状となるよう押出成型する
  ・成型物を乾燥後、13mmの長さに切断し、炭素熱源20を得る。
(2-6.1) Verification of fire spread prevention effect by high concentration of sodium chloride (2-6.1.1) Composition and production method of carbon heat source Carbon heat source 20 having the composition shown in Table 9 is produced by the following method. did.
-86 g of activated carbon and 117 g of calcium carbonate (CaCO 3 ) are mixed with 10.8 g of CMC having a degree of etherification of 0.6, and 250 g of water containing 2.2 g of sodium chloride is further mixed. Extrusion molding so as to form a cylindrical shape of 6 mm and an inner diameter of 4 mm. After the molding is dried, it is cut into a length of 13 mm to obtain the carbon heat source 20.
Figure JPOXMLDOC01-appb-T000009
Figure JPOXMLDOC01-appb-T000009
 (2-6.1.2)試験サンプル
 上述した方法で作製した炭素熱源にNaCl水溶液を含浸させ、表10に示す試験用熱源A~Fを作製した。
(2-6.1.2) Test Sample Test heat sources A to F shown in Table 10 were produced by impregnating the carbon heat source produced by the above-described method with an aqueous NaCl solution.
Figure JPOXMLDOC01-appb-T000010
Figure JPOXMLDOC01-appb-T000010
 なお、試験用熱源A~Fについて、NaClの含浸は以下の方法で行った。
  ・ 内径5mmのチューブに13mmの熱源を10mm挿し込み、1000ml/分の空気を流しながら、それぞれのサンプルについて表11に示した濃度のNaCl水溶液に210秒間浸する
  ・ 試験用熱源を取り出し後、60℃で6時間乾燥し、NaCl含浸熱源を得る
The test heat sources A to F were impregnated with NaCl by the following method.
Insert a 10 mm heat source into a tube with an inner diameter of 5 mm and immerse each sample in a NaCl aqueous solution having the concentration shown in Table 11 for 210 seconds while flowing air at 1000 ml / min. Dry at 6 ° C. for 6 hours to obtain a NaCl impregnation heat source
 また、含浸部分における炭素熱源中のNaCl含有量は、以下の式により算出した。
  1mm当NaCl含有量=
  (含浸後熱源乾燥重量-未含浸熱源乾燥重量)/ 熱源中NaCl含浸部長さ
Further, the NaCl content in the carbon heat source in the impregnated portion was calculated by the following equation.
1 mm equivalent NaCl content =
(Heat source dry weight after impregnation-dry weight of unimpregnated heat source) / length of NaCl impregnated part in heat source
 (2-6.1.3)延焼防止機能の評価方法
 以下の方法によって、模擬喫煙評価を実施した。
  ・ 内径6mmの紙管に熱源を3mm挿し込み、ボルグワルド社製喫煙器にセットする
  ・ 電気ライターで熱源を8秒間加熱後、それぞれのサンプルについて表11に示した容量で吸引し着火する
  ・ 上記容量で吸引する操作を30秒間隔で繰り返す
  ・ NaCl含浸部位にて延焼の防止可否を目視で確認する
(2-6.1.3) Evaluation method of fire spread prevention function Simulated smoking evaluation was performed by the following method.
-Insert a heat source 3 mm into a 6 mm inner diameter paper tube and set it in a Borgwald smoker.-Heat the heat source with an electric lighter for 8 seconds, and then suck and ignite each sample at the capacity shown in Table 11-The above capacity Repeat the suction operation at 30 second intervals ・ Visually check whether or not the fire spread is prevented at the NaCl impregnation site
 (2-6.1.4)評価結果
 上述した評価の結果を表11に示す。
(2-6.1.4) Evaluation results Table 11 shows the evaluation results described above.
Figure JPOXMLDOC01-appb-T000011
Figure JPOXMLDOC01-appb-T000011
 表11に示すように、本実施例においては、高濃度のNaClの含浸部において、NaClと可燃物(炭質材料及び有機バインダの和)の重量比を0.35以上、またはNaClと炭質材料の重量比を0.40以上とすることで、延焼防止剤の含有部において自律的に燃焼が停止し、十分な延焼防止機能を得られている。 As shown in Table 11, in this example, in the high-concentration NaCl impregnated portion, the weight ratio of NaCl to combustible material (sum of carbonaceous material and organic binder) is 0.35 or more, or NaCl to carbonaceous material. By setting the weight ratio to 0.40 or more, combustion is stopped autonomously in the portion containing the fire spread inhibitor, and a sufficient fire spread prevention function is obtained.
 (2-6.2)低濃度の塩化ナトリウムによる火種落ち防止効果の検証
 (2-6.2.1)試験サンプル
 低濃度のNaCl含有による火種落ち防止効果の検証するため、押出成形により、表12に示す組成の炭素熱源20(全長15mm、外径6mm)の試験サンプルを作製した。
(2-6.2) Verification of fire drop-off prevention effect by low-concentration sodium chloride (2-6.2.1) Test sample A test sample of a carbon heat source 20 (total length: 15 mm, outer diameter: 6 mm) having the composition shown in FIG.
Figure JPOXMLDOC01-appb-T000012
Figure JPOXMLDOC01-appb-T000012
 (2-6.2.2)火種落ち防止機能の評価方法
 以下の方法によって、模擬喫煙評価を実施した。
  ・ 作製した炭素熱源20を、外径6mmの紙管に3mm挿入し、評価サンプルとする
  ・ 炭素熱源20を着火し、燃焼中に任意のタイミングで、シガレットの灰を落とす要領で、評価サンプルを金属製灰皿に衝打する
  ・ 衝打時に炭素熱源20が非燃焼部で折れた場合は火種落ちが生じたと判定する
(2-6.2.2) Evaluation method of fire type omission prevention function Simulated smoking evaluation was performed by the following method.
-Insert the produced carbon heat source 20 into a paper tube with an outer diameter of 6 mm 3 mm and use it as an evaluation sample.-Ignite the carbon heat source 20 and remove the cigarette ash at any timing during combustion. Hit the metal ashtray-If the carbon heat source 20 breaks in the non-combustion part at the time of hitting, it is determined that the fire type has dropped.
 (2-6.2.3)評価結果
 各サンプルの評価結果は以下のとおりであった。
  G:火種落ちが生じた。
  H:火種落ちは生じなかった。
  I:火種落ちは生じなかった。
  J:火種落ちは生じなかった。使用中に可視煙が生じた。
  K:火種落ちは生じなかった。使用中に可視煙が生じた。
(2-6.2.3) Evaluation results The evaluation results of each sample were as follows.
G: A fire drop occurred.
H: No drop of fire occurred.
I: No fire omission occurred.
J: No drop of fire occurred. Visible smoke was produced during use.
K: No fire omission occurred. Visible smoke was produced during use.
 以上の結果より、炭素熱源20全体に低濃度のNaClを含有させることで火種落ちを防止可能であることが確認できた。 From the above results, it was confirmed that it was possible to prevent a fire drop from occurring by adding a low concentration of NaCl to the entire carbon heat source 20.
 なお、上述した試験条件においては、炭素熱源20におけるNaCl含有率を0.5wt%以上とすることで、十分な火種落ち防止効果を有することが確認できた。一方、NaCl含有率が3wt%以上の場合、使用中に可視煙が生じたことから、本試験に使用した炭素熱源20を無煙の香味吸引具の熱源として採用する際には、NaCl含有率は3wt%未満とすることが望ましい。 In addition, in the test conditions mentioned above, it has confirmed that it had sufficient fire-type fall-off prevention effect by making NaCl content rate in the carbon heat source 20 into 0.5 wt% or more. On the other hand, when the NaCl content was 3 wt% or more, visible smoke was generated during use. Therefore, when the carbon heat source 20 used in this test was adopted as the heat source of the smokeless flavor inhaler, the NaCl content was It is desirable to make it less than 3 wt%.
 (2-7)作用・効果
 以上説明したように、炭素熱源20は、少なくとも一部にNaClを含み、第1部分21におけるNaClの炭素熱源20に対する含有率は、第2部分22におけるNaClの炭素熱源20に対する含有率よりも大きい。このため、第1部分21におけるNaClの延焼防止効果により、香味発生源40を内包したホルダ30との接触部分まで炭素熱源20の燃焼が進行してしまうことを防止し得る。また、第2実施形態によれば、炭素熱源20の着火端側において当該物質の濃度を薄く、ホルダ30側が濃くなるよう濃度勾配を実現できる。これにより、より精密に炭素熱源20が発する熱量を制御し得る。
(2-7) Action / Effect As described above, the carbon heat source 20 contains at least a portion of NaCl, and the content of NaCl in the first portion 21 with respect to the carbon heat source 20 is the same as the carbon of NaCl in the second portion 22. It is larger than the content rate with respect to the heat source 20. For this reason, it is possible to prevent the combustion of the carbon heat source 20 from proceeding to the contact portion with the holder 30 containing the flavor generating source 40 due to the effect of preventing the spread of NaCl in the first portion 21. Further, according to the second embodiment, it is possible to realize a concentration gradient such that the concentration of the substance is low on the ignition end side of the carbon heat source 20 and the holder 30 side is high. Thereby, the amount of heat generated by the carbon heat source 20 can be controlled more precisely.
 さらに、NaClは、炭素熱源20の火種落ちも防止にも効果を奏する。また、上述したように炭素熱源20以外の別部材を設ける必要がなく、製造コストの増大も抑制し得る。 Furthermore, NaCl is effective in preventing the carbon heat source 20 from falling off. Moreover, it is not necessary to provide another member other than the carbon heat source 20 as described above, and an increase in manufacturing cost can be suppressed.
 さらに、第1部分におけるNaClと可燃物との重量比は、0.35以上、第1部分におけるNaClと炭質材料との重量比は、0.40以上であることが好ましい。この場合、さらに十分な延焼防止効果が得られる。 Furthermore, it is preferable that the weight ratio of NaCl and combustible in the first part is 0.35 or more, and the weight ratio of NaCl and carbonaceous material in the first part is 0.40 or more. In this case, a further sufficient fire spread preventing effect can be obtained.
 (2-8)その他の実施形態
 上述したように、第2実施形態を通じて本発明の内容を開示したが、この開示の一部をなす論述及び図面は、本発明を限定するものであると理解すべきではない。この開示から当業者には様々な代替実施の形態が明らかとなろう。
(2-8) Other Embodiments As described above, the contents of the present invention have been disclosed through the second embodiment. However, it is understood that the description and drawings constituting a part of this disclosure limit the present invention. should not do. From this disclosure, various alternative embodiments will be apparent to those skilled in the art.
 例えば、炭素熱源20の第1部分21及び第2部分22の形状は、次のように変更してもよい。図8(a)~(c)は、本発明の変更例に係る炭素熱源の軸線方向に沿った断面図である。 For example, the shapes of the first portion 21 and the second portion 22 of the carbon heat source 20 may be changed as follows. FIGS. 8A to 8C are cross-sectional views along the axial direction of the carbon heat source according to the modified example of the present invention.
 図8(a)に示すように、NaCl(図中のドット部分)は、第1部分21の外周部分に配置されてもよい。また、図8(b)に示すように、第1部分21は、ホルダ30の軸線方向に沿った断面において、香味発生源40(図8(b)において不図示)に接近するに連れてNaCl(図中のドット部分)を含む領域が広くなるように構成されてもよい。なお、図8(b)では、第1部分21のNaClを含まない部分が略三角形状だが、当該部分は、必ずしも三角形状でなくてもよく、例えば、ピラミッド状でもよい。 As shown in FIG. 8A, NaCl (dot portion in the figure) may be arranged on the outer peripheral portion of the first portion 21. Further, as shown in FIG. 8B, the first portion 21 is NaCl in the cross section along the axial direction of the holder 30 as it approaches the flavor generating source 40 (not shown in FIG. 8B). The region including (dot portion in the figure) may be widened. In FIG. 8B, the portion of the first portion 21 that does not contain NaCl has a substantially triangular shape, but the portion does not necessarily have a triangular shape, and may have a pyramid shape, for example.
 さらに、図8(c)に示すように、第1部分21及び第2部分22の両方は、ホルダ30の軸線方向に沿った断面において、香味発生源40に接近するに連れてNaClを含む領域が広くなるように構成されてもよい。 Furthermore, as shown in FIG. 8C, both the first portion 21 and the second portion 22 are regions containing NaCl as they approach the flavor generating source 40 in the cross section along the axial direction of the holder 30. May be configured to be wide.
 また、上述した実施形態では、第1部分21の軸線AXにおける全体においてNaClが含まれる例について説明したが、第1部分21の少なくとも一部にNaClが含まれていればよく、例えば、ホルダ30によって保持されていない第1部分21にのみNaClを含むようにしてもよい。 In the above-described embodiment, the example in which NaCl is included in the entire axis AX of the first portion 21 has been described. However, it is sufficient that at least a portion of the first portion 21 includes NaCl. Only the first portion 21 that is not held by may be made to contain NaCl.
 第2実施形態では、炭素熱源20においてNaClの含有領域を種々変更する例を示したが、炭素熱源20の軸線方向において、NaClを異なる濃度で含有させてもよい。(2-2)で述べた、低濃度のNaClを第2部分22に含む構成はその一例である。また、例えば、炭素熱源20の着火端側においてNaClの濃度を薄く、ホルダ30側が濃くなるよう濃度勾配を実現できる。これにより、より精密に炭素熱源20が発する熱量を制御し得る。 In the second embodiment, an example in which the NaCl-containing region is variously changed in the carbon heat source 20 has been shown, but NaCl may be contained in different concentrations in the axial direction of the carbon heat source 20. The configuration described in (2-2) including low concentration NaCl in the second portion 22 is an example. Further, for example, the concentration gradient can be realized so that the NaCl concentration is low on the ignition end side of the carbon heat source 20 and the holder 30 side is high. Thereby, the amount of heat generated by the carbon heat source 20 can be controlled more precisely.
 また、好適なNaClの含有量(濃度)は、炭素熱源20の形状や組成(発熱量)によって異なるが、(2-3)または(2-4)に示した方法によって、延焼防止の効果或いは火種落ち防止の効果を奏し得るように、NaClを任意の含有量に設定することができる。 Further, the preferred NaCl content (concentration) varies depending on the shape and composition (calorific value) of the carbon heat source 20, but by the method shown in (2-3) or (2-4), the effect of preventing the spread of fire or NaCl can be set to an arbitrary content so that the effect of preventing the drop of fire can be achieved.
 第2実施形態では、炭素熱源20の外形は円柱状であったが、円柱状に限らず、直方体など、様々な形状も本発明に含まれることは勿論である。 In the second embodiment, the outer shape of the carbon heat source 20 is cylindrical. However, the present invention is not limited to the cylindrical shape, and various shapes such as a rectangular parallelepiped are also included in the present invention.
 [第3実施形態]
 (3-1)香味吸引具の全体概略構成
 図9は、第3実施形態に係る香味吸引具10の全体概略構成図である。また、図10は、香味吸引具10の軸線方向に沿った断面図である。
[Third Embodiment]
(3-1) Overall Schematic Configuration of Flavor Suction Tool FIG. 9 is an overall schematic configuration diagram of the flavor suction tool 10 according to the third embodiment. FIG. 10 is a cross-sectional view along the axial direction of the flavor suction tool 10.
 図9及び図10に示すように、香味吸引具10は、第1実施形態と同様に、細長い円柱状であり、炭素熱源20、ホルダ30及び香味発生源40を有する。香味吸引具10は、炭素熱源20から発生する熱によって、香味発生源40の燃焼や熱分解を伴うことなく香味発生源40を加熱する。 As shown in FIG. 9 and FIG. 10, the flavor suction tool 10 has an elongated cylindrical shape as in the first embodiment, and includes a carbon heat source 20, a holder 30, and a flavor generation source 40. The flavor suction tool 10 heats the flavor generating source 40 with the heat generated from the carbon heat source 20 without burning or pyrolyzing the flavor generating source 40.
 炭素熱源20は、ホルダ30の軸線AX方向における端部30e(一端部)に設けられる。炭素熱源20は、ホルダ30の端部30eによって保持される。炭素熱源20は、少なくとも一部がホルダ30から突出した突出部分23を有する。 The carbon heat source 20 is provided at the end 30e (one end) in the axis AX direction of the holder 30. The carbon heat source 20 is held by the end 30 e of the holder 30. The carbon heat source 20 has a protruding portion 23 at least partially protruding from the holder 30.
 突出部分23の長さは、例えば、8mm~15mmとすることができる。このような構成により、ユーザは使用時において、炭素熱源20の燃焼状態を容易に視認することが可能となる。なお、炭素熱源20のより具体的な構成については、後述する。 The length of the protruding portion 23 can be 8 mm to 15 mm, for example. With such a configuration, the user can easily visually recognize the combustion state of the carbon heat source 20 during use. A more specific configuration of the carbon heat source 20 will be described later.
 (3-2)炭素熱源の構成
 次に、炭素熱源20の構成について具体的に説明する。炭素熱源20は、植物由来の炭質材料、不燃添加物、有機バインダ及び水を含む混合物を押出などの方法で成形することで得られる。
(3-2) Configuration of Carbon Heat Source Next, the configuration of the carbon heat source 20 will be specifically described. The carbon heat source 20 is obtained by molding a mixture containing a plant-derived carbonaceous material, an incombustible additive, an organic binder and water by a method such as extrusion.
 炭素熱源20は、炭質材料、有機バインダ及び補強剤を含む。有機バインダとして、特にカルボキシメチルセルロースナトリウム(CMC)を使用することが、香味の観点から好ましい。その他の有機バインダ、例えば、アルギン酸アンモニウムを用いた場合、炭素熱源20の燃焼に伴い生成する熱分解物が、香味を阻害する恐れがある。CMCのエーテル化度は、0.3以上に設定される。また、当該エーテル化度は、0.8未満であることが好ましい。 The carbon heat source 20 includes a carbonaceous material, an organic binder, and a reinforcing agent. As the organic binder, it is particularly preferable to use sodium carboxymethylcellulose (CMC) from the viewpoint of flavor. When other organic binders, for example, ammonium alginate, are used, there is a possibility that the thermal decomposition product generated with combustion of the carbon heat source 20 may inhibit the flavor. The degree of etherification of CMC is set to 0.3 or more. The degree of etherification is preferably less than 0.8.
 補強剤は、炭素熱源20の燃焼温度において不燃性であり、かつ補強剤または炭素熱源20の燃焼温度以下で生成される少なくとも一つの熱分解物が、炭素熱源20の燃焼温度以下で融解する特性を有する。具体的には、補強剤は、炭素熱源20の燃焼温度である800℃~1200℃において不燃性であり、無機物質または炭素熱源20の燃焼温度以下で生成する少なくとも一つの熱分解物が、炭素熱源20の燃焼温度以下で融解する特性を有する。 The reinforcing agent is nonflammable at the combustion temperature of the carbon heat source 20, and at least one thermal decomposition product generated below the combustion temperature of the carbon heat source 20 is melted below the combustion temperature of the carbon heat source 20. Have Specifically, the reinforcing agent is nonflammable at 800 ° C. to 1200 ° C., which is the combustion temperature of the carbon heat source 20, and at least one pyrolyzate generated below the combustion temperature of the carbon heat source 20 is carbon dioxide. It has a characteristic of melting at a temperature lower than the combustion temperature of the heat source 20.
 補強剤は、上述の条件を満たす可溶性アルカリ金属塩または可溶性アルカリ土類金属塩の少なくとも一方からなることが好ましい。可溶性アルカリ金属塩または可溶性アルカリ土類金属塩としては、例えば、塩化物、炭酸塩または硫酸塩が挙げられる。 The reinforcing agent is preferably made of at least one of a soluble alkali metal salt or a soluble alkaline earth metal salt that satisfies the above-mentioned conditions. Examples of the soluble alkali metal salt or the soluble alkaline earth metal salt include chlorides, carbonates, and sulfates.
 より具体的には、塩化ナトリウム、塩化カルシウム、塩化マグネシウム、塩化カリウム、炭酸ナトリウム、炭酸水素ナトリウム、硫酸ナトリウム、硫酸マグネシウムが挙げられ、好ましくは、塩化ナトリウム(NaCl)を好適に用い得る。なお、NaClを用いる場合、NaClの含有率は、炭素熱源20の重量に対して5wt%以下であることが好ましい。 More specifically, sodium chloride, calcium chloride, magnesium chloride, potassium chloride, sodium carbonate, sodium hydrogen carbonate, sodium sulfate, magnesium sulfate can be mentioned, and sodium chloride (NaCl) can be preferably used. In addition, when using NaCl, it is preferable that the content rate of NaCl is 5 wt% or less with respect to the weight of the carbon heat source 20.
 このように、炭素熱源20に低濃度の補強剤を含有させることによって、炭素熱源20の燃焼時において、灰皿への衝打などの衝撃によって炭素熱源20が非燃焼部から折れ、燃焼部を含む炭素熱源20が一部脱落すること(火種落ち)を防止できる。 As described above, when the carbon heat source 20 contains the low-concentration reinforcing agent, the carbon heat source 20 breaks from the non-combustion portion due to an impact such as a hit to the ashtray during the combustion of the carbon heat source 20, and includes the combustion portion. It is possible to prevent a part of the carbon heat source 20 from dropping (fire type dropping).
 炭素熱源20の補強剤濃度は、着火性及びその他の燃焼特性を阻害しない範囲で十分な効果を得られる数値が選択される。例えば、NaClを用いる場合、具体的には、NaClは、炭素熱源20に多少なりとも含有されていればよい。より具体的には、NaClの炭素熱源20に対する質量パーセント濃度(NaCl濃度)は、5wt%以下とすることで、着火性を阻害することなく採用することができる。また、炭素熱源20の燃焼に伴う可視煙の発生を低減するためには、3wt%未満であることが好ましく、さらに好適には1wt%以下であることが好ましく、0.5wt%以下であることがより好ましい。NaClは、例えば、押出などの成形時において、炭質材料やバインダなどを混合する際に顆粒または溶液として加えることができる。 The value of the reinforcing agent concentration of the carbon heat source 20 is selected so as to obtain a sufficient effect within a range that does not impair ignitability and other combustion characteristics. For example, when using NaCl, specifically, it is sufficient that NaCl is contained in the carbon heat source 20 to some extent. More specifically, the mass percent concentration (NaCl concentration) of NaCl with respect to the carbon heat source 20 is 5 wt% or less, and can be employed without impairing the ignitability. Moreover, in order to reduce generation | occurrence | production of the visible smoke accompanying the combustion of the carbon heat source 20, it is preferable that it is less than 3 wt%, It is preferable that it is 1 wt% or less suitably, It is 0.5 wt% or less Is more preferable. For example, NaCl can be added as a granule or a solution when mixing a carbonaceous material, a binder, or the like during molding such as extrusion.
 上述したように、CMCをバインダとして用いる場合、CMCのエーテル化度は0.3以上に設定される。このようにすることで、補強剤を炭素熱源20に含有させた場合でも製造・使用に耐え得る強度を炭素熱源20に付与し得る。 As described above, when CMC is used as a binder, the degree of etherification of CMC is set to 0.3 or more. By doing in this way, even when the carbon heat source 20 contains a reinforcing agent, the carbon heat source 20 can be provided with strength that can withstand manufacturing and use.
 エーテル化度が低いCMCを用いると、成形乾燥後の強度が乏しく、製造・使用適性が著しく悪化してしまう恐れがある。また、例えば、エーテル化度が0.8未満のCMCを使用することによって、押出などの成形時に容易に成形することが可能となる。 When CMC having a low degree of etherification is used, the strength after molding and drying is poor, and the suitability for production and use may be significantly deteriorated. Further, for example, by using CMC having a degree of etherification of less than 0.8, it becomes possible to easily mold at the time of molding such as extrusion.
 具体的には、CMCは、1~10wt%含むことができ、1wt%~8wt%含むことが、香味の観点からより好ましい。 Specifically, CMC can be contained in an amount of 1 to 10 wt%, and more preferably 1 wt% to 8 wt% from the viewpoint of flavor.
 (3-3)炭素熱源のその他の特徴
 次に、炭素熱源20のその他の特徴について説明する。
(3-3) Other Features of Carbon Heat Source Next, other features of the carbon heat source 20 will be described.
 (3-3.1)延焼防止機能
炭素熱源20は、軸線AX方向で異なる補強剤濃度としてもよい。例えば、炭素熱源20の他端部20b側における補強剤の炭素熱源20に対する含有率は、炭素熱源20の一端部20a側における補強剤の含有率よりも大きくしてもよく、より具体的には、炭素熱源20の一部、具体的には、他端部20b寄りにおいて、一端部20aを含む部分(突出部分)よりも高濃度の可溶性のアルカリ金属塩またはアルカリ土類金属塩を含有させてもよい。このような高濃度の可溶性のアルカリ金属塩またはアルカリ土類金属塩を含有する部分(第2部分)では、含有部において炭素熱源20の燃焼を自律的に停止せしめ、炭素熱源20のホルダへの延焼をより確実に防止しうる。
(3-3.1) The fire spread prevention function The carbon heat source 20 may have different reinforcing agent concentrations in the direction of the axis AX. For example, the content of the reinforcing agent with respect to the carbon heat source 20 on the other end 20b side of the carbon heat source 20 may be larger than the content of the reinforcing agent on the one end 20a side of the carbon heat source 20, more specifically. In addition, a part of the carbon heat source 20, specifically, near the other end 20 b, contains a soluble alkali metal salt or alkaline earth metal salt having a higher concentration than the portion including the one end 20 a (protruding portion). Also good. In the portion containing the high-concentration soluble alkali metal salt or alkaline earth metal salt (second portion), the combustion of the carbon heat source 20 is stopped autonomously in the containing portion, and the carbon heat source 20 is transferred to the holder. Fire spread can be prevented more reliably.
 具体的には、上述したような高濃度の可溶性のアルカリ金属塩またはアルカリ土類金属塩を含有する炭素熱源20の部分(第2部分)の少なくとも一部をホルダ30から露出させることによって、ホルダ30などに過剰に熱が供給される前に炭素熱源20の燃焼を停止させることができる。ホルダ30から露出させるべき高濃度の可溶性のアルカリ金属塩またはアルカリ土類金属塩を含有する炭素熱源20の部分の長さは、1mm~5mm、より好ましくは1.5mm~3mmである。 Specifically, the holder 30 is exposed by exposing at least a part of the portion (second portion) of the carbon heat source 20 containing the high-concentration soluble alkali metal salt or alkaline earth metal salt as described above. The combustion of the carbon heat source 20 can be stopped before excessive heat is supplied to 30 or the like. The length of the portion of the carbon heat source 20 containing a high concentration of soluble alkali metal salt or alkaline earth metal salt to be exposed from the holder 30 is 1 mm to 5 mm, more preferably 1.5 mm to 3 mm.
 炭素熱源20の他端部20b側に含有すべき可溶性のアルカリ金属塩またはアルカリ土類金属塩濃度は、炭素熱源20中の炭質材料配合率や空気流路構造等との関連から、十分な延焼防止機能を達成する数値が適宜選択される。例えば、NaClを用いる場合、NaClと可燃物(炭質材料及び有機バインダの和)の重量比を0.35以上、またはNaClと炭質材料の重量比を0.40以上となるようにNaClを含有させた部分をホルダ30より2mmから3mm程度露出させることで、十分な延焼防止機能を得ることができる。 The soluble alkali metal salt or alkaline earth metal salt concentration to be contained on the other end portion 20b side of the carbon heat source 20 is sufficiently spread from the relationship with the carbonaceous material blending ratio in the carbon heat source 20 and the air flow path structure. A numerical value that achieves the prevention function is appropriately selected. For example, when NaCl is used, NaCl is added so that the weight ratio of NaCl to combustible material (sum of carbonaceous material and organic binder) is 0.35 or more, or the weight ratio of NaCl to carbonaceous material is 0.40 or more. By exposing the exposed portion from the holder 30 by about 2 mm to 3 mm, a sufficient fire spread prevention function can be obtained.
 高濃度の可溶性のアルカリ金属塩またはアルカリ土類金属塩を含有する炭素熱源20の部分は、例えば、香味吸引具10に好適なサイズに作製した炭素熱源20の一方の端部を、可溶性のアルカリ金属塩またはアルカリ土類金属塩を含む水溶液に所定の深さまで含浸し、一定時間保持した後、乾燥することによって形成できる。炭素熱源20の他端部20bにおける可溶性のアルカリ金属塩またはアルカリ土類金属塩含有量は、可溶性のアルカリ金属塩またはアルカリ土類金属塩溶液濃度及び含浸時間によって任意に制御できる。例えば、NaClを用いる場合、含浸に用いるNaCl水溶液の濃度は15wt%~26wt%であることが好ましい。 The portion of the carbon heat source 20 containing a high concentration of soluble alkali metal salt or alkaline earth metal salt is obtained by, for example, replacing one end portion of the carbon heat source 20 having a size suitable for the flavor suction tool 10 with a soluble alkali. It can be formed by impregnating an aqueous solution containing a metal salt or an alkaline earth metal salt to a predetermined depth, holding it for a certain time, and then drying. The content of the soluble alkali metal salt or alkaline earth metal salt in the other end portion 20b of the carbon heat source 20 can be arbitrarily controlled by the concentration of the soluble alkali metal salt or alkaline earth metal salt solution and the impregnation time. For example, when NaCl is used, the concentration of the NaCl aqueous solution used for impregnation is preferably 15 wt% to 26 wt%.
 また、炭素熱源20が円筒形状のように軸線AX方向に連通した開口部を有する場合、開口部に通気しながら可溶性のアルカリ金属塩またはアルカリ土類金属塩の水溶液に含浸させることで、可溶性のアルカリ金属塩またはアルカリ土類金属塩の含浸位置をさらに精度よく制御できる。 In addition, when the carbon heat source 20 has an opening that communicates in the axis AX direction like a cylindrical shape, a soluble alkali metal salt or an alkaline earth metal salt is impregnated with an aqueous solution while passing through the opening. The impregnation position of the alkali metal salt or alkaline earth metal salt can be controlled more accurately.
 (3-3.2)炭質材料
 炭質材料は、加熱処理などによって揮発性の不純物を除去したものを用いることが望ましいが、これに限定されるものではない。炭質材料は、10wt%~99wt%の範囲で含むことができ、30wt%~70wt%であることが好ましく、40wt%~50wt%とすることが、十分な熱量供給及び灰の飛散防止などの燃焼特性の観点から望ましい。
(3-3.2) Carbonaceous material It is desirable to use a carbonaceous material from which volatile impurities have been removed by heat treatment or the like, but is not limited thereto. The carbonaceous material can be included in the range of 10 wt% to 99 wt%, preferably 30 wt% to 70 wt%, and 40 wt% to 50 wt% to provide sufficient heat supply and combustion for preventing ash scattering, etc. Desirable from the viewpoint of characteristics.
 (3-3.3)不燃添加物
 不燃添加物としては、例えば、ナトリウム、カリウム、カルシウム、マグネシウム、ケイ素などからなる炭酸塩または酸化物を使用でき、40~89wt%含むことができる。特に、炭酸カルシウムを炭素熱源20中に40wt%~55wt%含むことが好ましい。
(3-3.3) Nonflammable Additives As the nonflammable additives, for example, carbonates or oxides composed of sodium, potassium, calcium, magnesium, silicon and the like can be used, and they can be contained in 40 to 89 wt%. In particular, it is preferable to contain 40 wt% to 55 wt% of calcium carbonate in the carbon heat source 20.
 (3-3.4)炭素熱源の形状
 炭素熱源20の全長は、10mmから30mmの範囲が好ましく、13mmから20mmの範囲とすることがより好ましい。また、炭素熱源20の外径は、4mmから8mmの範囲が好ましく、5mmから7mmの範囲とすることがより好ましい。これにより、香味吸引具10の熱源として好適に用い得る。
(3-3.4) Shape of carbon heat source The total length of the carbon heat source 20 is preferably in the range of 10 mm to 30 mm, and more preferably in the range of 13 mm to 20 mm. Further, the outer diameter of the carbon heat source 20 is preferably in the range of 4 mm to 8 mm, and more preferably in the range of 5 mm to 7 mm. Thereby, it can be used suitably as a heat source of the flavor suction tool 10.
 (3-4)実施例
 次に、香味吸引具10を構成する炭素熱源20の実施例について説明する。
(3-4) Example Next, an example of the carbon heat source 20 constituting the flavor suction tool 10 will be described.
 (3-4.1)試験サンプル
 低濃度の塩化ナトリウム(NaCl)による火種落ち防止効果の検証するため、押出成形により、表13に示す組成の炭素熱源20(全長15mm、外径6mm)の試験サンプルを作製した。
(3-4.1) Test sample Test of carbon heat source 20 (total length: 15 mm, outer diameter: 6 mm) having the composition shown in Table 13 by extrusion molding in order to verify the effect of preventing fire omission by low-concentration sodium chloride (NaCl). A sample was made.
Figure JPOXMLDOC01-appb-T000013
Figure JPOXMLDOC01-appb-T000013
 (3-4.2)火種落ち防止機能の評価方法
 以下の方法によって、模擬喫煙評価を実施した。
  ・ 作製した炭素熱源20を、外径6mmの紙管に3mm挿入し、評価サンプルとする
  ・ 炭素熱源20を着火し、燃焼中に任意のタイミングで、シガレットの灰を落とす要領で、評価サンプルを金属製灰皿に衝打する
  ・ 衝打時に炭素熱源20が非燃焼部で折れた場合は火種落ちが生じたと判定する
(3-4.2) Evaluation method of fire drop-off prevention function Simulated smoking evaluation was performed by the following method.
-Insert the produced carbon heat source 20 into a paper tube with an outer diameter of 6 mm 3 mm and use it as an evaluation sample.-Ignite the carbon heat source 20 and remove the cigarette ash at any timing during combustion. Hit the metal ashtray-If the carbon heat source 20 breaks in the non-combustion part at the time of hitting, it is determined that the fire type has dropped.
 (3-4.3)評価結果
 各サンプルの評価結果は以下のとおりであった。
  A:火種落ちが生じた。
  B:火種落ちは生じなかった。
  C:火種落ちは生じなかった。
  D:火種落ちは生じなかった。使用中に可視煙が生じた。
  E:火種落ちは生じなかった。使用中に可視煙が生じた。
(3-4.3) Evaluation results The evaluation results of each sample were as follows.
A: A fire drop occurred.
B: No drop of fire occurred.
C: No fire omission occurred.
D: No drop of fire occurred. Visible smoke was produced during use.
E: No fire omission occurred. Visible smoke was produced during use.
 以上の結果より、炭素熱源20全体に低濃度のNaClを含有させることで火種落ちを防止可能であることが確認できた。 From the above results, it was confirmed that it was possible to prevent a fire drop from occurring by adding a low concentration of NaCl to the entire carbon heat source 20.
 なお、上述した試験条件においては、炭素熱源20におけるNaCl含有率を0.5wt%以上とすることで、十分な火種落ち防止効果を有することが確認できた。一方、NaCl含有率が3wt%以上の場合、使用中に可視煙が生じたことから、本試験に使用した炭素熱源20を無煙の香味吸引具の熱源として採用する際には、NaCl含有率は3wt%未満とすることが望ましい。 In addition, in the test conditions mentioned above, it has confirmed that it had sufficient fire-type fall-off prevention effect by making NaCl content rate in the carbon heat source 20 into 0.5 wt% or more. On the other hand, when the NaCl content was 3 wt% or more, visible smoke was generated during use. Therefore, when the carbon heat source 20 used in this test was adopted as the heat source of the smokeless flavor inhaler, the NaCl content was It is desirable to make it less than 3 wt%.
 (3-5)作用・効果
 以上説明したように、炭素熱源20は、ホルダ30から突出した突出部分23を有する。このため、ユーザが炭素熱源20の燃焼状態を容易に視認できる。また、炭素熱源20は、補強剤及びカルボキシメチルセルロースナトリウム(CMC)を含み、CMCのエーテル化度は、0.3以上である。このため、製造・使用に耐え得る強度を炭素熱源20に付与しつつ、香味吸引具10を灰皿などに一定以上の力で叩いても燃焼部分(火種)の落下を防止できる。
(3-5) Action / Effect As described above, the carbon heat source 20 has the protruding portion 23 protruding from the holder 30. For this reason, the user can visually recognize the combustion state of the carbon heat source 20 easily. Moreover, the carbon heat source 20 contains a reinforcing agent and sodium carboxymethyl cellulose (CMC), and the degree of etherification of CMC is 0.3 or more. For this reason, even if the flavor suction tool 10 is struck against an ashtray or the like with a certain force or more while giving the carbon heat source 20 strength sufficient to withstand manufacture and use, the combustion part (fire type) can be prevented from falling.
 上述したように、炭素熱源20に含まれるバインダは、香味の観点からCMCを用いることが望ましいが、補強剤を含む炭素熱源の製造において、エーテル化度が0.3未満のCMCを用いると、成形乾燥後の強度が乏しく、製造・使用適性が著しく悪化してしまう恐れがある。すなわち、本願の発明者は、炭素熱源20にNaCl及びCMCを含ませ、かつCMCのエーテル化度を0.3以上とすることによって、製造・使用に耐え得る炭素熱源20の強度を確保しつつ、さらに火種落ちを効果的に防止できるとの知見を得たのである。 As described above, the binder contained in the carbon heat source 20 is desirably CMC from the viewpoint of flavor, but in the production of a carbon heat source containing a reinforcing agent, when CMC having a degree of etherification of less than 0.3 is used, The strength after molding and drying is poor, and the suitability for production and use may be significantly deteriorated. That is, the inventor of the present application ensures the strength of the carbon heat source 20 that can withstand production and use by including NaCl and CMC in the carbon heat source 20 and setting the degree of etherification of CMC to 0.3 or more. In addition, they have acquired knowledge that fire omission can be effectively prevented.
 また、CMCのエーテル化度は、0.3~0.8の範囲とすることによって、炭素熱源20の非燃焼時における強度の担保と、成形の容易性を両立し得る。さらに、香味吸引具10の軸線AX方向において、補強剤、特に可溶性のアルカリ金属塩または可溶性のアルカリ土類金属塩に濃度勾配を付与することによって炭素熱源20のホルダへの延焼防止効果も奏することができる。 Further, by setting the degree of etherification of CMC in the range of 0.3 to 0.8, it is possible to achieve both the guarantee of strength when the carbon heat source 20 is not burned and the ease of molding. Furthermore, in the direction of the axis AX of the flavor suction tool 10, the effect of preventing the spread of fire to the holder of the carbon heat source 20 is also achieved by imparting a concentration gradient to the reinforcing agent, particularly a soluble alkali metal salt or a soluble alkaline earth metal salt. Can do.
 (3-6)その他の実施形態
 上述したように、第3実施形態を通じて本発明の内容を開示したが、この開示の一部をなす論述及び図面は、本発明を限定するものであると理解すべきではない。この開示から当業者には様々な代替実施の形態が明らかとなろう。
(3-6) Other Embodiments As described above, the contents of the present invention have been disclosed through the third embodiment. However, it is understood that the description and drawings constituting a part of this disclosure limit the present invention. should not do. From this disclosure, various alternative embodiments will be apparent to those skilled in the art.
 例えば、第3実施形態では、炭素熱源20の軸線AX方向で異なる補強剤濃度としてもよいとし、例えば、炭素熱源20の一部、具体的には、他端部20b寄り(第2部分)において、一端部20aを含む部分(突出部分)よりも高濃度の補強剤を含有させてもよいとしたが、このような構成は、上述した本発明の効果を奏する上で必須ではない。 For example, in 3rd Embodiment, it is good also as a reinforcing agent density | concentration different in the axis line AX direction of the carbon heat source 20, for example, in a part of carbon heat source 20, specifically, the other end part 20b side (2nd part). Although a higher concentration of reinforcing agent may be contained than the portion including the one end portion 20a (protruding portion), such a configuration is not essential for achieving the above-described effects of the present invention.
 このように、本発明は、ここでは記載していない様々な実施の形態などを含むことは勿論である。したがって、本発明の技術的範囲は、上述の説明から妥当な特許請求の範囲に係る発明特定事項によってのみ定められるものである。 Thus, it goes without saying that the present invention includes various embodiments that are not described herein. Therefore, the technical scope of the present invention is defined only by the invention specifying matters according to the scope of claims reasonable from the above description.
 なお、日本国特許出願第2012-104143号(2012年4月27日出願)、日本国特許出願第2012-104148号(2012年4月27日出願)、日本国特許出願第2012-106201号(2012年5月7日出願)の全内容が、参照により、本願明細書に組み込まれている。 Japanese Patent Application No. 2012-104143 (filed on April 27, 2012), Japanese Patent Application No. 2012-104148 (filed on April 27, 2012), Japanese Patent Application No. 2012-106201 ( The entire contents of which was filed on May 7, 2012) are incorporated herein by reference.
 本発明の特徴によれば、ホルダによって保持されている炭素熱源の部分において炭素熱源以外の別部材を設けることなく、ホルダへの過剰な熱の供給を抑制し、ホルダの燃焼または熱分解を防止し得る香味吸引具及び炭素熱源を提供することができる。 According to the feature of the present invention, the supply of excessive heat to the holder is suppressed and the combustion or pyrolysis of the holder is prevented without providing another member other than the carbon heat source in the portion of the carbon heat source held by the holder. And a carbon heat source.

Claims (14)

  1.  香味発生源と、前記香味発生源を内包する筒状のホルダと、前記ホルダの軸線方向における一端部に設けられる炭素熱源とを備える香味吸引具であって、
     前記炭素熱源は、前記軸線方向において、
     前記ホルダによって保持され、かつ少なくとも一部が前記ホルダから突出した第1部分と、
     前記香味発生源と逆側の端部を含む第2部分と
    を有し、
     前記第1部分の少なくとも一部は、前記炭素熱源の延焼を防止する延焼防止剤を含む香味吸引具。
    A flavor suction device comprising: a flavor generation source; a cylindrical holder containing the flavor generation source; and a carbon heat source provided at one end in the axial direction of the holder,
    The carbon heat source is in the axial direction,
    A first portion held by the holder and at least partially protruding from the holder;
    A second portion including the end portion on the opposite side to the flavor generating source,
    At least one part of the said 1st part is a flavor suction tool containing the fire spread prevention agent which prevents the fire spread of the said carbon heat source.
  2.  前記延焼防止剤は、
     前記炭素熱源の燃焼温度において不燃性であり、
     前記炭素熱源の燃焼温度以下において吸熱反応を生じ、
     前記吸熱反応として熱分解を生じる場合、熱分解生成物の少なくとも一つが前記炭素熱源の燃焼温度において不燃性かつ不揮発性である請求項1に記載の香味吸引具。
    The fire spread inhibitor is
    Non-flammable at the combustion temperature of the carbon heat source,
    An endothermic reaction occurs below the combustion temperature of the carbon heat source,
    The flavor inhaler according to claim 1, wherein when pyrolysis occurs as the endothermic reaction, at least one of the pyrolysis products is nonflammable and non-volatile at a combustion temperature of the carbon heat source.
  3.  前記延焼防止剤は、可溶性または難溶性のアルカリ金属塩、或いは可溶性または難溶性のアルカリ土類金属塩である請求項2に記載の香味吸引具。 The flavor inhaler according to claim 2, wherein the fire spread inhibitor is a soluble or hardly soluble alkali metal salt, or a soluble or hardly soluble alkaline earth metal salt.
  4.  前記延焼防止剤は、可溶性のアルカリ金属塩または可溶性のアルカリ土類金属塩であり、
     前記可溶性のアルカリ金属塩または可溶性のアルカリ土類金属塩は、塩化物、炭酸塩または硫酸塩の何れかである請求項3に記載の香味吸引具。
    The fire spreader is a soluble alkali metal salt or a soluble alkaline earth metal salt,
    The flavor inhaler according to claim 3, wherein the soluble alkali metal salt or the soluble alkaline earth metal salt is any one of a chloride, a carbonate and a sulfate.
  5.  前記延焼防止剤は、難溶性のアルカリ金属塩または難溶性のアルカリ土類金属塩であり、
     前記難溶性のアルカリ金属塩または難溶性のアルカリ土類金属塩は、水酸化物、炭酸塩または硫酸塩の何れかである請求項3に記載の香味吸引具。
    The fire spread inhibitor is a hardly soluble alkali metal salt or a hardly soluble alkaline earth metal salt,
    The flavor inhaler according to claim 3, wherein the hardly soluble alkali metal salt or the hardly soluble alkaline earth metal salt is any one of a hydroxide, a carbonate and a sulfate.
  6.  前記延焼防止剤は、液体ガラスを含む請求項1に記載の香味吸引具。 The flavor inhaler according to claim 1, wherein the fire spread inhibitor includes liquid glass.
  7.  前記第2部分は、前記可溶性アルカリ金属塩または可溶性アルカリ土類金属塩のうちの少なくとも一方をさらに含み、
     前記第2部分に含まれる前記可溶性アルカリ金属塩または可溶性アルカリ土類金属塩の前記炭素熱源に対する含有率は、前記第1部分に含まれる延焼防止剤の前記炭素熱源に対する含有率よりも小さい請求項3に記載の香味吸引具。
    The second portion further includes at least one of the soluble alkali metal salt or the soluble alkaline earth metal salt,
    The content rate of the soluble alkali metal salt or soluble alkaline earth metal salt contained in the second part with respect to the carbon heat source is smaller than the content rate of the fire spreader contained in the first part with respect to the carbon heat source. 3. The flavor suction tool according to 3.
  8.  前記延焼防止剤として、塩化ナトリウムを含み、
     前記第1部分における前記塩化ナトリウムの前記炭素熱源に対する含有率は、前記第2部分における前記塩化ナトリウムの前記炭素熱源に対する含有率よりも大きい請求項1に記載の香味吸引具。
    As the fire spread inhibitor, sodium chloride is included,
    The flavor suction tool according to claim 1, wherein a content ratio of the sodium chloride in the first portion with respect to the carbon heat source is larger than a content ratio of the sodium chloride with respect to the carbon heat source in the second portion.
  9.  前記第1部分における前記塩化ナトリウムと可燃物との重量比は、0.35以上である請求項8に記載の香味吸引具。 The flavor inhaler according to claim 8, wherein a weight ratio of the sodium chloride and the combustible in the first part is 0.35 or more.
  10.  前記第1部分における前記塩化ナトリウムと炭質材料との重量比は、0.40以上である請求項8に記載の香味吸引具。 The flavor suction tool according to claim 8, wherein a weight ratio of the sodium chloride and the carbonaceous material in the first portion is 0.40 or more.
  11.  前記第2部分は塩化ナトリウムを含み、前記第2部分における前記塩化ナトリウムの質量パーセント濃度は、1wt%以下である請求項8に記載の香味吸引具。 The flavor inhaler according to claim 8, wherein the second part contains sodium chloride, and the mass percent concentration of the sodium chloride in the second part is 1 wt% or less.
  12.  前記ホルダから突出している前記炭素熱源の前記軸線方向に沿った長さは、8mm以上、15mm以下であり、
     前記第1部分の長さは、前記ホルダから突出している部分において、1mm以上、5mm以下であり、好ましくは1.5mm以上、3mm以下である請求項1に記載の香味吸引具。
    The length of the carbon heat source protruding from the holder along the axial direction is 8 mm or more and 15 mm or less,
    The flavor suction tool according to claim 1, wherein the length of the first portion is 1 mm or more and 5 mm or less, preferably 1.5 mm or more and 3 mm or less in a portion protruding from the holder.
  13.  前記第1部分と前記第2部分とは、一体として形成されている請求項1に記載の香味吸引具。 The flavor suction tool according to claim 1, wherein the first part and the second part are formed as a single unit.
  14.  香味発生源を内包する筒状のホルダの軸線方向における一端部に設けられる炭素熱源であって、
     前記軸線方向において、前記ホルダによって保持され、かつ少なくとも一部が前記ホルダから突出するように設けられる第1部分と、
     前記香味発生源と逆側の端部を含むように設けられる第2部分と
    を有し、
     前記第1部分の少なくとも一部は、前記炭素熱源の延焼を防止する延焼防止剤を含む炭素熱源。
    A carbon heat source provided at one end in the axial direction of the cylindrical holder containing the flavor generation source,
    A first portion that is held by the holder in the axial direction, and is provided so that at least a portion protrudes from the holder;
    A second part provided to include the end on the opposite side to the flavor generating source,
    At least a part of the first part is a carbon heat source including a fire spread inhibitor that prevents the carbon heat source from spreading.
PCT/JP2013/062491 2012-04-27 2013-04-26 Flavor inhalation tool and carbon heat source WO2013162028A1 (en)

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