WO2013150305A3 - Procédé de production d'alcool - Google Patents

Procédé de production d'alcool Download PDF

Info

Publication number
WO2013150305A3
WO2013150305A3 PCT/GB2013/050881 GB2013050881W WO2013150305A3 WO 2013150305 A3 WO2013150305 A3 WO 2013150305A3 GB 2013050881 W GB2013050881 W GB 2013050881W WO 2013150305 A3 WO2013150305 A3 WO 2013150305A3
Authority
WO
WIPO (PCT)
Prior art keywords
catalyst
precipitate
polyhydric alcohol
palladium
iron
Prior art date
Application number
PCT/GB2013/050881
Other languages
English (en)
Other versions
WO2013150305A2 (fr
Inventor
Shik Chi Edman Tsang
Cheng-Tar Wu
Kai Man YU
Original Assignee
Isis Innovation Limited
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Isis Innovation Limited filed Critical Isis Innovation Limited
Publication of WO2013150305A2 publication Critical patent/WO2013150305A2/fr
Publication of WO2013150305A3 publication Critical patent/WO2013150305A3/fr

Links

Classifications

    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/70—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper
    • B01J23/89—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with noble metals
    • B01J23/8906—Iron and noble metals
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/38—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of noble metals
    • B01J23/40—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of noble metals of the platinum group metals
    • B01J23/44—Palladium
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/38—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of noble metals
    • B01J23/54—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of noble metals combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36
    • B01J23/56—Platinum group metals
    • B01J23/60—Platinum group metals with zinc, cadmium or mercury
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/38—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of noble metals
    • B01J23/54—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of noble metals combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36
    • B01J23/56—Platinum group metals
    • B01J23/62—Platinum group metals with gallium, indium, thallium, germanium, tin or lead
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/38—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of noble metals
    • B01J23/54—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of noble metals combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36
    • B01J23/56—Platinum group metals
    • B01J23/63—Platinum group metals with rare earths or actinides
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/70—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper
    • B01J23/74—Iron group metals
    • B01J23/755—Nickel
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J35/00—Catalysts, in general, characterised by their form or physical properties
    • B01J35/30—Catalysts, in general, characterised by their form or physical properties characterised by their physical properties
    • B01J35/391—Physical properties of the active metal ingredient
    • B01J35/393—Metal or metal oxide crystallite size
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J37/00—Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
    • B01J37/02—Impregnation, coating or precipitation
    • B01J37/03—Precipitation; Co-precipitation
    • B01J37/031—Precipitation
    • B01J37/033—Using Hydrolysis
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C29/00—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C29/00—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring
    • C07C29/60—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring by elimination of -OH groups, e.g. by dehydration
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J37/00—Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
    • B01J37/08—Heat treatment
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
    • Y02P20/00—Technologies relating to chemical industry
    • Y02P20/50—Improvements relating to the production of bulk chemicals
    • Y02P20/52—Improvements relating to the production of bulk chemicals using catalysts, e.g. selective catalysts

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Catalysts (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)

Abstract

Cette invention concerne un procédé de production d'un alcool monohydroxylé par hydrogénolyse d'un polyol, ledit procédé consistant à traiter un polyol avec de l'hydrogène en présence d'un catalyseur solide qui comprend (a) de l'oxyde de fer et (b) un métal qui est un métal noble ou du nickel. Cette invention concerne en outre un catalyseur, qui comprend de l'oxyde de fer et des nanoparticules qui comprennent du palladium. Un procédé de production du catalyseur est également décrit, ledit procédé comprenant : (1) une étape de co-précipitation consistant à mettre en contact (a) une solution, qui comprend un sel de palladium et un sel de fer dissous dans un solvant, avec (b) une base, pour former un précipité qui comprend un ou plusieurs composés dont ledit fer et ledit palladium; (2) une étape de séparation, consistant à séparer le précipité du solvant; et (3) une étape de calcination, consistant à calciner le précipité par chauffage du précipité dans l'air. L'utilisation du catalyseur selon l'invention pout l'hydrogénolyse d'un polyol est également décrite.
PCT/GB2013/050881 2012-04-04 2013-04-04 Procédé de production d'alcool WO2013150305A2 (fr)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
GBGB1206042.2A GB201206042D0 (en) 2012-04-04 2012-04-04 Alcohol production process
GB1206042.2 2012-04-04

Publications (2)

Publication Number Publication Date
WO2013150305A2 WO2013150305A2 (fr) 2013-10-10
WO2013150305A3 true WO2013150305A3 (fr) 2013-11-28

Family

ID=46160329

Family Applications (1)

Application Number Title Priority Date Filing Date
PCT/GB2013/050881 WO2013150305A2 (fr) 2012-04-04 2013-04-04 Procédé de production d'alcool

Country Status (2)

Country Link
GB (1) GB201206042D0 (fr)
WO (1) WO2013150305A2 (fr)

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN107262045A (zh) * 2017-08-03 2017-10-20 中国科学院化学研究所 富勒烯‑mof复合材料在清除挥发性有机物中的应用
CN107490610A (zh) * 2017-09-05 2017-12-19 济南大学 一种手性mof‑石墨烯杂化材料及其制备方法和应用

Families Citing this family (8)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN103922893B (zh) * 2014-04-19 2015-11-25 青岛科技大学 一种复合催化剂催化甘油氢解制备1,2-丙二醇的方法
CN104086369B (zh) * 2014-06-18 2017-04-05 华南理工大学 木薯渣氢解制备低级醇的方法
CN104492436B (zh) * 2014-12-12 2016-09-07 中国科学院西双版纳热带植物园 一种碳基磁性固体碱催化剂及其应用
CN106565393A (zh) * 2015-10-13 2017-04-19 吴倍任 催化氢解反应之复合材料及其制备方法与用途
JP2018153735A (ja) * 2017-03-16 2018-10-04 株式会社東芝 化学反応システム
CN106902842A (zh) * 2017-03-20 2017-06-30 北京工业大学 一种以MOFs衍生碳基材料为载体的负载型钯催化剂的制备及应用
CN109304213B (zh) * 2017-07-28 2021-04-02 中国科学院宁波材料技术与工程研究所 一种加氢裂化催化剂及其制备方法与应用
CN108579810B (zh) * 2018-03-12 2020-09-11 北京科技大学 一种合成贵金属MOFs复合材料的方法

Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP1826180A1 (fr) * 2004-10-21 2007-08-29 Peking University Materiau composite compose de nanoparticules de metal de transition et d'oxyde ferrique magnetique, procede pour sa preparation et utilisations
WO2008156320A1 (fr) * 2007-06-19 2008-12-24 Postech Academy-Industry Foundation Composition de nanocatalyseur magnétique et procédé pour sa préparation
US20090088317A1 (en) * 2007-09-28 2009-04-02 Frye Jr John G Multi-metal reduction catalysts and methods of producing reduction catalysts

Patent Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP1826180A1 (fr) * 2004-10-21 2007-08-29 Peking University Materiau composite compose de nanoparticules de metal de transition et d'oxyde ferrique magnetique, procede pour sa preparation et utilisations
WO2008156320A1 (fr) * 2007-06-19 2008-12-24 Postech Academy-Industry Foundation Composition de nanocatalyseur magnétique et procédé pour sa préparation
US20090088317A1 (en) * 2007-09-28 2009-04-02 Frye Jr John G Multi-metal reduction catalysts and methods of producing reduction catalysts

Cited By (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN107262045A (zh) * 2017-08-03 2017-10-20 中国科学院化学研究所 富勒烯‑mof复合材料在清除挥发性有机物中的应用
CN107490610A (zh) * 2017-09-05 2017-12-19 济南大学 一种手性mof‑石墨烯杂化材料及其制备方法和应用
CN107490610B (zh) * 2017-09-05 2019-09-27 济南大学 一种手性mof-石墨烯杂化材料及其制备方法和应用

Also Published As

Publication number Publication date
GB201206042D0 (en) 2012-05-16
WO2013150305A2 (fr) 2013-10-10

Similar Documents

Publication Publication Date Title
WO2013150305A3 (fr) Procédé de production d'alcool
WO2011119638A3 (fr) Procédé de préparation d'oxydes métalliques stables, très poreux à structure de pores contrôlée
MX357222B (es) Catalizador para la obtencion de alcoholes superiores.
MX2014008253A (es) Catalizadores de hidrogenacion con soportes modificados con cobalto.
MY181068A (en) Recombinant microorganism for improved production of fine chemicals
EP3056482A4 (fr) Procédé de production d'acide carboxylique insaturé, et catalyseur supporté
SG11201408066UA (en) Catalyst for methanol production, method of producing the same and process of methanol production
SG11201509534VA (en) Porous metal oxide particles, production method thereof andapplication thereof
MX2015003077A (es) Metodo para preparar mentona a partir de isopulegol.
SG11201406833PA (en) Catalyst for production of butadiene, process for producing the catalyst, and process for producing butadiene using the catalyst
EP3056273A4 (fr) Catalyseur utilisé pour la déshydrogénation d'acide formique, procédé de déshydrogénation d'acide formique, et procédé de production d'hydrogène
WO2016110698A8 (fr) Microsphères de double hydroxyde stratifié de sio2 et leurs procédés de fabrication
WO2013015605A3 (fr) Procédé de production d'hydrocarbures aromatiques à partir des sous-produits issus de procédés de préparation d'acides carboxyliques aromatiques et/ou d'esters d'alkyle d'acides carboxyliques aromatiques
IN2014MN02182A (fr)
MX358006B (es) Catalizador de reformado de vapor y metodo para la fabricacion del mismo.
JP2011219344A5 (fr)
EP3046667A4 (fr) Catalyseur et procédé de préparation d'hydrogène gazeux à partir de formates et d'hydrogénation de carbonate d'hydrogène, et système de stockage d'hydrogène les utilisant
WO2016020656A3 (fr) Procédé de production de méthanol
WO2014135712A3 (fr) Polyester
AR092760A1 (es) Procedimiento para producir complejos de oxalato de metales nobles
MX341126B (es) Proceso integrado para produccion de ozono y oxigeno.
MY174111A (en) Method for producing tetrahydrofuran
WO2014179648A3 (fr) Addition anti-markovnikov directe d'acides sur des alcènes
IN2014DN07057A (fr)
BR112016015130A2 (pt) Processos contínuos para preparar n-butanol

Legal Events

Date Code Title Description
121 Ep: the epo has been informed by wipo that ep was designated in this application

Ref document number: 13715432

Country of ref document: EP

Kind code of ref document: A2

122 Ep: pct application non-entry in european phase

Ref document number: 13715432

Country of ref document: EP

Kind code of ref document: A2