WO2013138890A1 - Method of re-using solid waste from garbage recycling and civil engineering - Google Patents

Method of re-using solid waste from garbage recycling and civil engineering Download PDF

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Publication number
WO2013138890A1
WO2013138890A1 PCT/BR2013/000082 BR2013000082W WO2013138890A1 WO 2013138890 A1 WO2013138890 A1 WO 2013138890A1 BR 2013000082 W BR2013000082 W BR 2013000082W WO 2013138890 A1 WO2013138890 A1 WO 2013138890A1
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Prior art keywords
waste
solid
mixed
recycling
recovery
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PCT/BR2013/000082
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French (fr)
Portuguese (pt)
Inventor
Jair ANCIOTO
Antonio Donizete DE SÁ
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Ancioto Jair
De Sa Antonio Donizete
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Publication of WO2013138890A1 publication Critical patent/WO2013138890A1/en

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    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B16/00Use of organic materials as fillers, e.g. pigments, for mortars, concrete or artificial stone; Treatment of organic materials specially adapted to enhance their filling properties in mortars, concrete or artificial stone
    • C04B16/04Macromolecular compounds
    • C04B16/08Macromolecular compounds porous, e.g. expanded polystyrene beads or microballoons
    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B40/00Processes, in general, for influencing or modifying the properties of mortars, concrete or artificial stone compositions, e.g. their setting or hardening ability
    • C04B40/0082Processes, in general, for influencing or modifying the properties of mortars, concrete or artificial stone compositions, e.g. their setting or hardening ability making use of a rise in temperature, e.g. caused by an exothermic reaction

Definitions

  • the related patent relates to the operative concept in which a process for the manufacture of a viscous paste is made whose properties produce exothermic reaction, i. It is a chemical reaction in which energy is transferred from an interior to an external environment, or that releases heat with energy variation, therefore negative, in order to crystallize hydrated products, obtaining sufficient mechanical strength for use in construction. as a binding element.
  • This process presupposes, from the chemico-operative point of view, or crushing of granular and rigid granular plastic material (expanded polystyrene, EPS), by reducing the volume with the application of a common solvent, thus obtaining a first mix, and adding soil to make the material viscous, yielding a second viscous paste for mixing with construction debris, e.g. ex. ; or grinding the same expanded polystyrene (EPS) for mixing with layered debris, i. is: a certain amount of crushed material with a certain amount of rubble in a concrete mixer * , e.g. , and so on, in layers of mixing, obtaining a final paste, or the binder element itself for the manufacture of blocks, tiles, floors and similar materials for the building industry.
  • EPS expanded polystyrene
  • US6,941,720 B2 filed 9/10/2001, entitled: CONSTRUCTION COMPOSITION, refers to a material building compound comprising a lightweight core with fiber cement on one side of the core. Fiber cement is used in at least one of the phases; It is green and preferably formed by a mud-dehydration process. The material building compound is assembled in an uncured state and then cured.
  • US2010 / 0282672 Al filed 12/3/2008, titled: Process for Exothermic Treatment and Recovery of Solid, Semisolid, PAST, and / or WASTY WASTE, refers to a process for exothermic treatment and recovery masses comprising municipal solid waste (MSW), including wet and vegetable waste; sludge generated by industrial and non-industrial (treatment) water; solid, semi-solid, pasty solid waste and / or sludge from industrial, agricultural and food processing operations, soils and inert materials contaminated by pasty organic matrices, waste and / or hydrocarbon composite sludge, including asphalt and compost chemical and organic.
  • MSW municipal solid waste
  • solid, semi-solid, pasty solid waste and / or sludge from industrial, agricultural and food processing operations, soils and inert materials contaminated by pasty organic matrices, waste and / or hydrocarbon composite sludge, including asphalt and compost chemical and organic.
  • the present patent is a new operating concept insofar as it contemplates a process whose steps, Mechanicity and purposes are different from what is taught in common technique.
  • expanded polystyrene is reduced in volume through the use of common and unclaimed solvent, including and especially in situations where collection is at a location other than processing, also with a view to transporting the material for later.
  • this volume-reduced material becomes a viscous solution, ready for the next step, in which soil is added and a second solution with optimum viscosity is obtained for mixing with construction debris, eg ., which results in the bonding compound for the production of new building materials such as floors, bricks, blocks and the like.
  • US4,153,514 relates to an analysis or decomposition reaction that occurs by the action of high temperatures, whose concept is the rupture of the original molecular structure of the compound by the action of heat in an environment with little or no oxygen, whereas that the other documents listed report different concepts, such as mixing waste with plastic using a mechanical system, i. It is: screw extruder, feed hopper and mixing pressure up to 100 bar for US5, 376,156; the flow plan which includes a sealed compartment with an inlet with waste disposal device in the case of donor. US5,942,022; or the material building compound comprising a lightweight, fiber-cement core on one side of the core of the Doc.
  • the present object is a new conception in which an agglutinating compound is obtained from the treatment of solid and semi-solid waste.
  • EPS pre-ground extended polystyrene
  • a preferred process alternative is the pre-ground extended polystyrene (EPS) mixture for further volume reduction using a commonly used solvent to obtain a less viscous, lower volume mass, to which earth is added to facilitate the following mixing and beating steps, in which dry rubble from construction will be added, the humidity of which will be increased by the addition of water, water and slurry or just slurry.
  • EPS pre-ground extended polystyrene
  • the slurry extremely harmful to the environment because it is derived from biological, chemical and physical processes of decomposition of organic waste, as it only serves to moisten the mixture, can be used in the process under review, and is with Significant environmental savings as it is treated with common and unclaimed bactericides that eliminate the characteristic nauseating odor.
  • the process provides for beating in commonly used devices such as concrete mixers or agitators, resulting in a binder paste suitable for the manufacture of bricks and building materials of the same nature.
  • the related design starts from the grinding of extended polystyrene (EPS) which is thus mixed with the layered building debris.
  • EPS extended polystyrene
  • a certain amount of the crushed material is layered on a rubble surface within the beating or replacer device, and so on until an ideal amount is obtained for it to be moistened and added to the solvent and mixed by beating, thus obtaining binder paste ready to be used in the manufacture of bricks, slabs, blocks and other materials for construction or similar activities.
  • FIGURE 1 in block diagram depicts the preferred embodiment of the commenting process, i. is: extended polystyrene crushing (1) and further volume reduction (2) by the use of a commonly used solvent for the addition of earth (3) and beating (4), in which dry rubble (5) will be added, the humidity of which will be increased by the addition of water, water and slurry or just slurry (6).
  • FIGURE 2 also in block diagram depicts the alternative process embodiment, wherein grinding (1) of expanded polystyrene is succeeded by layer system mixing (4) in the dry rubble overlapping beating device ( 5) so that a certain amount of crushed expanded polystyrene (1) is layered onto a rubble surface (5) within the tapping or replacement device (4), and so on until an ideal amount is obtained. so that it is moistened (6) and added with solvent (2) and mixed by beating (4), thus obtaining a binder mass ready to be used in the manufacture of bricks, slabs, blocks and other materials for construction or activities of the same nature.
  • the process starts from grinding granular and rigid cellular plastic material such as expanded polystyrene, e.g., to be mixed with debris in a layered system, so that a certain amount of the crushed material is spread over a certain amount of debris in a concrete mixer or substitute device by adding water, water and slurry or just slurry and bathing, and so on until a final slurry is obtained or the slurry itself. and a binder helm for the manufacture of blocks, bricks, floors and similar materials for the construction industry.
  • granular and rigid cellular plastic material such as expanded polystyrene
  • the process of collating reuse of solid and semi-solid waste presupposes the physical and chemical process embodied in the grinding of expanded or substitute polystyrene, whose volume is reduced before or after grinding using a commonly used solvent, so that the rigid cellular plastic material, once crushed, can be mixed even in layer system directly with dust.
  • expanded polystyrene or substitute is reduced in volume by the use of common unclaimed solvent, including and especially in situations where collection is at a different location from processing for purposes of processing. also transport the material for later, in which case the The volume-reduced material becomes a solution with a certain viscosity which is improved by the addition of earth, so that it can be mixed with debris from the building industry, eg resulting in the binder compound.

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  • Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Ceramic Engineering (AREA)
  • Materials Engineering (AREA)
  • Structural Engineering (AREA)
  • Organic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Processing Of Solid Wastes (AREA)
  • Separation, Recovery Or Treatment Of Waste Materials Containing Plastics (AREA)

Abstract

A method is disclosed for re-using valuable chemical substances contained in solid and semisolid waste, in which method solid waste from recycled common garbage and debris from civil engineering and mixed and re-used for producing an agglomerate for manufacturing bricks and the like, involving an operational concept with stages, ingredients, mechanisms and means for re-using solid and semi-solid waste. A physical and chemical process based on the comminution of expanded polystyrene (EPS) is involved, in which the volume of EPS can be reduced before or after comminution with the use of a conventional solvent.

Description

PROCESSO DE APROVEITAMENTO DE RESÍDUOS SÓLIDOS ORIUNDOS DA RECICLAGEM DO LIXO E DA CONSTRUÇÃO CIVIL  PROCEDURE FOR SOLID WASTE RECYCLING AND CIVIL CONSTRUCTION
INTRODUÇÃO INTRODUCTION
A patente em re lato d iz respe ito a conceito ope rativo em que se consubstancia processo para a fabricação de uma pasta viscosa cuj as propriedades produzem reação exotérmica, i. é : reação qu ímica em que energia é transferida de um meio interior ao meio exterior, ou que libera calor com variação de energia, portanto, negativa, com o objetivo de cristalizar produtos hidratados , obte ndo resistê ncia mecânica suficiente para o emprego na construção civil como elemento aglomerante.  The related patent relates to the operative concept in which a process for the manufacture of a viscous paste is made whose properties produce exothermic reaction, i. It is a chemical reaction in which energy is transferred from an interior to an external environment, or that releases heat with energy variation, therefore negative, in order to crystallize hydrated products, obtaining sufficient mechanical strength for use in construction. as a binding element.
Referido processo pressupõe , do ponto de vista qu ímico- operativo, ou trituração de material plástico celu lar e rígido de constituição granular (poliestireno expandido, EPS) , mediante redução de volume com a aplicação de solvente de uso comum, obtendo-se assim uma prime ira mistura, e a adição de terra para tornar viscoso o material , obte ndo-se uma segunda pasta viscosa para mistura com entulhos provenientes da construção civil , p. ex. ; ou a trituração do mesmo poliestireno expandido (EPS) para mistura com entulhos em camadas, i. é : uma determinada quantidade do material triturado com uma determinada quantidade de entulho numa betoneira*, p .ex. , e assim sucessivamente em camadas de mistura, obtendo-se uma pasta final, ou o próprio elemento aglomerante para a fabricação de blocos, tij olos, pisos e materiais de mesma natureza para a construção civil . ESTADO DA TÉCNICA This process presupposes, from the chemico-operative point of view, or crushing of granular and rigid granular plastic material (expanded polystyrene, EPS), by reducing the volume with the application of a common solvent, thus obtaining a first mix, and adding soil to make the material viscous, yielding a second viscous paste for mixing with construction debris, e.g. ex. ; or grinding the same expanded polystyrene (EPS) for mixing with layered debris, i. is: a certain amount of crushed material with a certain amount of rubble in a concrete mixer * , e.g. , and so on, in layers of mixing, obtaining a final paste, or the binder element itself for the manufacture of blocks, tiles, floors and similar materials for the building industry. TECHNICAL STATE
Processos que reaproveitam resíduos sólidos e semissólidos, assim como produtos provenientes desse reaproveitamento, já são bastante difundidos no estado da técnica.  Processes that reuse solid and semi-solid waste, as well as products from this reuse, are already widespread in the state of the art.
Tanto que em buscas efetuadas na técnica comum foi possível selecionar vários documentos envolvendo diferentes concepções. Descartados aqueles de conceito diferente ou de aplicação diversa da proposta nesta patente, foram destacados os seguintes documentos:  So much so that in searches performed in the common technique it was possible to select several documents involving different conceptions. Discarding those of different concept or different application of the proposal in this patent, the following documents were highlighted:
US4,153 ,514, com data de depósito em 17/5/1976, sob título: PROCESSO DE PIRÓLISE DE RESÍDUOS SÓLIDOS , em que se privilegia a recuperação de valores químicos através de mistura em que se utiliza gás transportador em fluxo turbulento em zona de pirólise a uma temperatura variando entre 300°F e 2000°F, com posterior segregação e recuperação de valores químicos volatizáveis.  US4,153, 514, filed on 5/17/1976, under the title: SOLID WASTE PYROLYSIS PROCESS, in which the recovery of chemical values by mixing in a turbulent zone carrier gas is preferred. pyrolysis at a temperature ranging from 300 ° F to 2000 ° F, with subsequent segregation and recovery of volatile chemical values.
US5,376, 156, com data de depósito em 7/9/1993, sob título: US5,376,156, filed September 7, 1993, under the title:
MÉTODO DE APROVEITAMENTO DE RESÍDUOS PARTICULADOS DE LIGAÇÃO, TAIS COMO POEIRA, FIBRAS DE PAPEL, E RESÍDUOS DE METAIS OU SEMELHANTES, EM SÓLIDOS, que descreve um processo que consiste na mistura de resíduos com plástico mediante o emprego de sistema mecânico, i. é: extrusora com rosca, funil de alimentação e pressão na mistura de até 100 bar. METHOD FOR THE USE OF PARTICULAR CONNECTION WASTE, SUCH AS DUST, PAPER FIBERS, AND METAL OR SIMILAR WASTE, IN SOLID, which describes a process of mixing waste with plastic using a mechanical system, i. It is: screw extruder, feed hopper and mixing pressure up to 100 bar.
US5,942,022, com data de depósito em 1/6/1995 , sob título: UNIDADE DE COMPOSTAGEM PARA RESÍDUOS ORGÂNICOS E MÉTODO PARA TAL COMPOSTAGEM, revelando invenção relacionada com a separação de resíduos como lama, aparas de madeira, palha, estrume. Na verdade, trata-se de uma planta de fluxo que inclui compartimento selado com uma zona de entrada com dispositivo para a alimentação no lixo que é avançada a partir de uma planta de pré-processamento com comporta hermética, em que são utilizados agitadores por suspensão em um corredor para o avanço e a aeração dos resíduos. A planta prevê um sistema de troca de calor para a extração do calor por condensação com água, com temperatura mantida fixa entre 55-62°C e com tempo de permanência de 5 a 25 dias. US5,942,022, filed on 6/1/1995, under the heading: COMPOSITE UNIT FOR ORGANIC WASTE AND METHOD FOR SUCH COMPOUND, disclosing invention related to the separation of waste such as mud, wood chips, straw, manure. In fact, it is a flow plant that includes a sealed compartment with an inlet with waste disposal device that is advanced from a hermetic floodgate preprocessing plant where suspension stirrers are used in a corridor for waste advance and aeration. The plant provides a heat exchange system for the extraction of heat by condensation with water, with a fixed temperature of 55-62 ° C and a residence time of 5 to 25 days.
US6,476,084 B2, com data de depósito em 22/1/2001 , sob título: PROCESSO DE RECICLAGEM DE RESÍDUOS HETEROGÉNEOS, em que é descrita a reciclagem heterogénea de resíduos incluindo o passo inicial de submeter o produto heterogéneo de resíduos de pirólise para produzir um fluxo de gás de síntese que compreende pelo menos monóxido de carbono e hidrogénio, e um fluxo de produto fundido de pirólise , compreendendo pelo menos um material mineral e um material metálico.  US6,476,084 B2, filed January 22, 2001, entitled: Heterogeneous Waste Recycling Process, wherein heterogeneous waste recycling is described including the initial step of subjecting the heterogeneous pyrolysis waste product to produce a synthesis gas stream comprising at least carbon monoxide and hydrogen, and a pyrolysis melt stream comprising at least one mineral material and one metallic material.
US6, 941 ,720 B2, com data de depósito em 9/10/2001 , sob título: COMPOSIÇÃO PARA MATERIAL DE CONSTRUÇÃO, refere-se a um composto de construção de material compreendendo um núcleo leve, com fibrocimento em um lado do núcleo. O fibrocimento é usado em pelo menos uma das fases; é verde e preferentemente formado por um processo de desidratação-lama. O composto de construção de material é montado em um estado não curado e então curado.  US6,941,720 B2, filed 9/10/2001, entitled: CONSTRUCTION COMPOSITION, refers to a material building compound comprising a lightweight core with fiber cement on one side of the core. Fiber cement is used in at least one of the phases; It is green and preferably formed by a mud-dehydration process. The material building compound is assembled in an uncured state and then cured.
US7, 147,707 B2, com data de depósito em 22/12/2005, sob título: COMPOSTO PARA MATERIAL DE CONSTRUÇÃO E MÉTODO DE FABRICAÇÃO, relata composto que contem terra diatomácea, madeira, resíduos e endurecedor orgânico, ou ainda contem terra de campo e, se necessário, papel utilizado e/ou pedaços esmagados de tatame e telhas, e da terra esmagada. O composto é preparado de forma homogénea em mistura dos componentes, e depois por moldagem e cura do compósito. US7,449,517 B I , com data de depósito em 21/1/2004, sob título: MATERIAL DE CONSTRUÇÃO COMPOSTO, na verdade um composto extrudado de material constituído por resina termoplástica de material, uma mistura de ad itivos materiais e uma celulose de material, em que a resina termoplástica, a mistura de aditivos e de celulose são misturados em um compósito de material no qual o composto de material compreende entre 50% e 90% de celulose de material em peso, e em que a mistura composta de material é extrudado para formar o composto extrudado de construção de material. US7, 147.707 B2, filed on 12/22/2005, titled: COMPOSITE FOR CONSTRUCTION MATERIAL AND MANUFACTURING REPORT, reports compost that contains diatomaceous earth, wood, waste and organic hardener, or still contains field land and , if necessary, used paper and / or crushed pieces of mat and shingles, and of crushed earth. The compound is prepared homogeneously by mixing the components, and then by molding and curing the composite. US7,449,517 BI, filed January 21, 2004 under the heading: COMPOUND BUILDING MATERIAL, actually an extruded material composite consisting of thermoplastic resin material, a mixture of material additives and a material cellulose, wherein the thermoplastic resin, the admixture and the cellulose blend are mixed into a material composite wherein the material composite comprises between 50% and 90% cellulose by weight material, and wherein the composite material mixture is extruded. to form the extruded material building compound.
US2010/0282672 Al , com data de depósito em 12/3/2008, sob título: PROCESSO PARA TRATAMENTO EXOTÉRMICO E VALORIZAÇÃO DE RESÍDUOS SÓLIDOS, SEMIS SÓLIDOS, PASTOSOS E/OU ÚMIDOS, refere-se a um processo para o tratamento exotérmico e recuperação de massas compreendendo resíduos sólidos urbanos (RSU) , incluindo resíduos úmidos e de origem vegetal; lodo gerado pela água industrial e não industrial (de tratamento) ; sólido, semissólido, pastoso sólido, resíduo e/ou resíduos de lodo proveniente de operações industriais, agrícolas e do processamento de alimentos, solos e materiais inertes contaminados por matrizes orgânicas pastosas, resíduos e/ou de lamas de hidrocarbonetos compostos, incluindo asfalto e compostos químicos e orgânicos. Em particular, prevê a utilização de processo de reação exotérmica produzido pela mistura da massa a ser tratada com uma mistura de óxidos de cálcio (CaO); e/ou hidróxidos de cálcio Ca(OH)2, na presença de um catalisador inerte umedecido com água, na ausência de oxigénio. US2010 / 0282672 Al, filed 12/3/2008, titled: Process for Exothermic Treatment and Recovery of Solid, Semisolid, PAST, and / or WASTY WASTE, refers to a process for exothermic treatment and recovery masses comprising municipal solid waste (MSW), including wet and vegetable waste; sludge generated by industrial and non-industrial (treatment) water; solid, semi-solid, pasty solid waste and / or sludge from industrial, agricultural and food processing operations, soils and inert materials contaminated by pasty organic matrices, waste and / or hydrocarbon composite sludge, including asphalt and compost chemical and organic. In particular, it provides for the use of an exothermic reaction process produced by mixing the mass to be treated with a calcium oxide (CaO) mixture; and / or calcium hydroxides Ca (OH) 2 in the presence of an inert catalyst moistened with water in the absence of oxygen.
Portanto, a presente patente versa conceito operativo novo, na medida em que contempla processo cujas etapas, ingredientes, mecanicidade e fins são diferentes do que é ensinado na técnica comum. Therefore, the present patent is a new operating concept insofar as it contemplates a process whose steps, Mechanicity and purposes are different from what is taught in common technique.
O reaproveitamento de resíduos sólidos e semissólidos, objeto da patente, pressupõe processo físico e químico consubstanciado na trituração de poliestireno expandido (EPS), cujo volume pode reduzido antes ou depois da trituração mediante o emprego de solvente de uso comum, posto que o material plástico celular e rígido de constituição granular, uma vez triturado, pode ser misturado em sistema de camadas diretamente com entulho proveniente da construção civil, i. é: determinada quantidade de matéria triturada estendida em sobreposição a uma determinada quantidade de entulho estendido diretamente em dispositivos batedores, agitadores ou sucedâneos, e assim sucessivamente.  The reuse of solid and semi-solid waste, object of the patent, presupposes physical and chemical process embodied in the grinding of expanded polystyrene (EPS), the volume of which may be reduced before or after grinding by the use of common solvent, since the plastic material Cellular and rigid granular constitution, once crushed, can be mixed in a layered system directly with rubble from construction, i. is: a certain amount of ground material extended overlapping with a given amount of debris spread directly into beater, agitator or substitute devices, and so on.
Numa concepção alternativa, o poliestireno expandido (EPS) é reduzido em volume por meio do uso de solvente de uso comum e não reivindicado, inclusive e principalmente em situações em que a coleta seja em local diferente do processamento, tendo em vista também o transporte do material para posterior. Nesta operação, esse material reduzido em volume transforma-se numa solução que já é viscosa, pronta para a etapa seguinte, em que é adicionada terra e obtida uma segunda solução com viscosidade ideal para a mistura com entulhos provenientes da construção civil, p.ex., da qual resulta o composto aglutinador para a produção de novos materiais para construção, tais como: pisos, tijolos, blocos e outros de mesma natureza.  In an alternative design, expanded polystyrene (EPS) is reduced in volume through the use of common and unclaimed solvent, including and especially in situations where collection is at a location other than processing, also with a view to transporting the material for later. In this operation, this volume-reduced material becomes a viscous solution, ready for the next step, in which soil is added and a second solution with optimum viscosity is obtained for mixing with construction debris, eg ., which results in the bonding compound for the production of new building materials such as floors, bricks, blocks and the like.
Isto porque o documento US4,153,514 diz respeito a uma reação de análise ou decomposição que ocorre pela ação de altas temperaturas, cujo conceito é a ruptura da estrutura molecular original do composto pela ação do calor em um ambiente com pouco ou nenhum oxigénio, ao passo que os demais documentos elencados relatam conceitos diferentes, como, p.ex. , a mistura de resíduos com plástico mediante o emprego de sistema mecânico, i. é : extrusora com rosca, funil de alimentação e pressão na mistura de até 100 bar, no caso do documento US5, 376,156; a planta de fluxo que inclui compartimento selado com uma zona de entrada com dispositivo para a alimentação no lixo, no caso do doe. US5,942,022; ou o composto de construção de material compreendendo um núcleo leve, com fibrocimento em um lado do núcleo, do doe. US6,941 ,720 B2; e o processo para o tratamento exotérmico e recuperação de massas que prevê a utilização de processo de reação exotérmica produzido pela mistura da massa a ser tratada com uma mistura de óxidos de cálcio (CaO) e/ou hidróxidos de cálcio Ca(OH)2, na presença de um catalisador inerte umedecido com água, na ausência de oxigénio, no caso do doe. US2010/0282672 Al . This is because US4,153,514 relates to an analysis or decomposition reaction that occurs by the action of high temperatures, whose concept is the rupture of the original molecular structure of the compound by the action of heat in an environment with little or no oxygen, whereas that the other documents listed report different concepts, such as mixing waste with plastic using a mechanical system, i. It is: screw extruder, feed hopper and mixing pressure up to 100 bar for US5, 376,156; the flow plan which includes a sealed compartment with an inlet with waste disposal device in the case of donor. US5,942,022; or the material building compound comprising a lightweight, fiber-cement core on one side of the core of the Doc. US6,941, 720 B2; and the process for exothermic treatment and mass recovery which provides for the use of an exothermic reaction process produced by mixing the mass to be treated with a mixture of calcium oxides (CaO) and / or calcium hydroxides Ca (OH) 2 , in the presence of an inert catalyst moistened with water, in the absence of oxygen in the case of Doc. US2010 / 0282672 Al.
Apenas os documentos US7, 147,707 B2 e US7,449,517 B I referem-se a conceitos que se podem dizer algo próximos , embora o sejam muito mais entre si do que em relação ao presente objeto, visto que relatam, respectivamente, um composto que contem terra diatomácea, na verdade um sedimento amorfo originado de frústulas ou carapaças de organismos unicelulares vegetais, de natureza silicosa, além de madeira, resíduos e endurecedor orgânico, ou ainda terra de campo e , se necessário, papel utilizado e/ou pedaços esmagados de tatame e telhas, e da terra esmagada; um composto extrudado de material constituído por resina termoplástica de material, uma mistura de aditivos materiais e uma celulose.  Only US7, 147.707 B2 and US7,449,517 BI refer to concepts that can be said to be close, although they are much closer to each other than to the present object, as they report, respectively, a compound containing earth. diatom, in fact an amorphous sediment originating from frustules or carapaces of single-celled plant organisms of a silica nature, in addition to wood, waste and organic hardener, or field soil and, if necessary, used paper and / or crushed pieces of mat and shingles, and of the crushed earth; an extruded material composite consisting of thermoplastic resin material, a mixture of material additives and a cellulose.
Depreende-se que, no caso do documento US7, 147,707 B2, é ensinado um composto preparado de forma homogénea em mistura dos componentes e depois por moldagem e cura do compósito, e que, no caso do documento US7,449,517 B I , ensina-se o emprego de polímero de cadeia longa composto de um só monômero (glicose) , classificado como polissacarídeo ou carboidrato que compreende entre 50% e 90% de material em peso. It will be understood that in the case of US7, 147.707 B2, a homogeneously prepared compound is taught by mixing the components and then by molding and curing the composite, and that in the case of US7,449,517 B1, it is taught. the use of long chain polymer composed of a single monomer (glucose), classified as a polysaccharide or carbohydrate comprising between 50% and 90% material by weight.
SUMÁRIO DO ΟΒΪΕΤΟ DA PATENTE  PATENT ΟΒΪΕΤΟ SUMMARY
As concepções verificadas no estado da técnica, acima e retro referidas, dizem respeito a conceitos específicos que não os propostos no presente relato.  The above-mentioned prior art and prior art conceptions relate to specific concepts other than those proposed in the present report.
Trata-se, pois, o presente objeto, de uma concepção nova em que um composto aglutinador é obtido a partir do tratamento de resíduos sólidos e semissólidos.  Therefore, the present object is a new conception in which an agglutinating compound is obtained from the treatment of solid and semi-solid waste.
Numa alternativa preferencial do processo, trata-se da mistura de poliestireno estendido (EPS) previamente triturado para posterior redução de volume mediante o emprego de solvente de uso comum, a fim de obter-se uma massa ao mesmo tempo viscosa e de menor volume, à qual adiciona-se terra para a facilitação das etapas seguintes de mistura e batimento, nas quais será acrescentado entulho seco proveniente da construção civil, cuja umidade será elevada pela adição de água, água e chorume ou apenas chorume .  A preferred process alternative is the pre-ground extended polystyrene (EPS) mixture for further volume reduction using a commonly used solvent to obtain a less viscous, lower volume mass, to which earth is added to facilitate the following mixing and beating steps, in which dry rubble from construction will be added, the humidity of which will be increased by the addition of water, water and slurry or just slurry.
Vale dizer que o chorume, extremamente nocivo ao meio ambiente por ser derivado de processos biológicos, químicos e físicos da decomposição de resíduos orgânicos, uma vez que serve tão somente para umedecer a mistura, pode ser aproveitado no processo em comento, e o é com significativa economia ambiental, uma vez que é tratado com bactericidas de uso comum e não reivindicados, que eliminam o odor nauseante característico.  It is worth mentioning that the slurry, extremely harmful to the environment because it is derived from biological, chemical and physical processes of decomposition of organic waste, as it only serves to moisten the mixture, can be used in the process under review, and is with Significant environmental savings as it is treated with common and unclaimed bactericides that eliminate the characteristic nauseating odor.
Uma vez devidamente umedecida a mistura, o processo prevê o batimento em dispositivos também de uso comum, tais como betoneiras ou agitadores convencionais, do qual resulta uma pasta aglomerante propícia para a fabricação de tijolos e materiais para construção de mesma natureza. Numa segunda alternativa, a concepção em relato parte da trituração do poliestireno estendido (EPS) que é assim misturado com o entulho proveniente da construção civil em sistema de camadas. Once the mixture has been properly wetted, the process provides for beating in commonly used devices such as concrete mixers or agitators, resulting in a binder paste suitable for the manufacture of bricks and building materials of the same nature. In a second alternative, the related design starts from the grinding of extended polystyrene (EPS) which is thus mixed with the layered building debris.
Ou seja: uma determinada quantidade do material triturado é depositada em camada sobre uma superfície de entulho no interior do dispositivo de batimento ou sucedâneo, e assim sucessivamente até que se obtenha uma quantidade ideal para que seja umedecida e acrescida do solvente e misturada por batimento, obtendo-se, assim, massa aglomerante pronta para ser usada na fabricação de tijolos, placas, blocos e demais materiais para a construção civil ou atividades de mesma natureza.  That is: a certain amount of the crushed material is layered on a rubble surface within the beating or replacer device, and so on until an ideal amount is obtained for it to be moistened and added to the solvent and mixed by beating, thus obtaining binder paste ready to be used in the manufacture of bricks, slabs, blocks and other materials for construction or similar activities.
DESCRIÇÃO DOS EXEMPLARES DESENHATIVOS  DESCRIPTION OF DRAWING EXAMPLES
A caracterização do processo em comento é dada por meio de desenhos representativos da solução proposta, de tal forma que se possam visualizar suas etapas e resultados.  The characterization of the commented process is given through representative drawings of the proposed solution, so that its steps and results can be visualized.
A partir das representações desenhativas em comento, que expressam a forma preferencial de se realizar o objeto, fundamenta-se a descrição deste relatório, por meio de remissões numéricas e consecutivas, onde são aclarados aspectos construtivos e operativos porventura subentendidos pela representação adotada, determinando precisamente a tute la pleiteada.  From the descriptive representations in comment, which express the preferred way of realizing the object, is based the description of this report, through numerical and consecutive references, where are clarified constructive and operative aspects perhaps implied by the adopted representation, determining precisely the pleaded claim.
As figuras são meramente ilustrativas, podendo apresentar variações, desde que não fujam do inicialmente pleiteado.  The figures are merely illustrative and may vary, as long as they do not depart from the initially claimed.
Tem-se, pois, que:  It is therefore necessary to:
- A FIGURA 1 em diagrama de blocos, descreve a forma preferencial de consecução do processo em comento, i. é: trituração do poliestireno estendido (1 ) e posterior redução de volume (2) mediante o emprego de solvente de uso comum, para adição de terra (3) e batimento (4), nas quais será acrescentado entulho seco (5), cuja umidade será elevada pela adição de água, água e chorume ou apenas chorume (6). FIGURE 1 in block diagram depicts the preferred embodiment of the commenting process, i. is: extended polystyrene crushing (1) and further volume reduction (2) by the use of a commonly used solvent for the addition of earth (3) and beating (4), in which dry rubble (5) will be added, the humidity of which will be increased by the addition of water, water and slurry or just slurry (6).
- A FIGURA 2 também em diagrama de blocos, descreve a forma alternativa de consecução do processo, em que a trituração (1) do poliestireno expandido é sucedida pela mistura (4) em sistema de camadas no dispositivo de batimento por sobreposição ao entulho seco (5), de modo que uma determinada quantidade de poliestireno expandido triturado (1) seja depositada em camada sobre uma superfície de entulho (5) no interior do dispositivo de batimento ou sucedâneo (4), e assim sucessivamente até que se obtenha uma quantidade ideal para que seja umedecida (6) e acrescida do solvente (2) e misturada por batimento (4), obtendo-se, assim, massa aglomerante pronta para ser usada na fabricação de tijolos, placas, blocos e demais materiais para a construção civil ou atividades de mesma natureza.  FIGURE 2 also in block diagram depicts the alternative process embodiment, wherein grinding (1) of expanded polystyrene is succeeded by layer system mixing (4) in the dry rubble overlapping beating device ( 5) so that a certain amount of crushed expanded polystyrene (1) is layered onto a rubble surface (5) within the tapping or replacement device (4), and so on until an ideal amount is obtained. so that it is moistened (6) and added with solvent (2) and mixed by beating (4), thus obtaining a binder mass ready to be used in the manufacture of bricks, slabs, blocks and other materials for construction or activities of the same nature.
DESCRIÇÃO DETALHADA DO OBJETO DA PATENTE  DETAILED DESCRIPTION OF PATENT OBJECT
Processo para o reaproveitamento de valores químicos de resíduos sólidos e semissólidos, onde resíduos oriundos da reciclagem do lixo comum e entulhos provenientes da construção civil são misturados e reutilizados para a produção de massa aglomerante para a fabricação de tijolos e produtos congéneres, que ensina conceito operativo em que se produz uma pasta viscosa cujas propriedades reagem no sentido de se transferir energia de um meio interior ao meio exterior, cristalizando produtos hidratados com resistência mecânica suficiente para o emprego na construção civil como elemento aglomerante. Dito processo, partindo da trituração de material plástico celular e rígido de constituição granular, como o poliestireno expandido, p.ex. , mediante redução de volume com a aplicação de solvente de uso comum, produz uma prime ira mistura que é tornada viscosa no ponto ideal pe la ad ição de te rra, obte ndo-se uma segunda mistura, na verdade uma pasta viscosa ideal para a mistura com entulhos provenie ntes da construção civil. Process for the reuse of chemical values of solid and semi-solid waste, where waste from the recycling of common waste and rubble from construction are mixed and reused for the production of binder mass for the manufacture of bricks and similar products, which teaches operating concept. in which a viscous paste is produced whose properties react to transfer energy from an interior to an external environment, crystallizing hydrated products with sufficient mechanical strength for use in construction as a binder element. Said process, starting from the grinding of cellular and rigid plastic material of granular constitution, such as expanded polystyrene, for example, by volume reduction with the application of common solvent, produces a first mixture that is made viscous at the point. It is ideal for the addition of ground to obtain a second mixture, in fact a viscous paste ideal for mixing with debris from construction.
Numa forma alternativa de realização, o processo parte da trituração de mate rial plástico celular e rígido de constituição granular, como o poliestireno expandido, p.ex. , para que sej a misturado com entulhos em sistema de camadas, de modo que uma determinada quantidade do material triturado sej a estendido em sobreposição a uma determinada quantidade de entulho numa betoneira ou dispositivo sucedâneo, mediante adição de água, água e chorume ou apenas chorume e batime nto, e ass im sucessivamente até que se obtenha uma pasta final , ou o próprio e leme nto aglomerante para a fabricação de blocos, tij olos , p isos e materiais de mesma natureza para a construção civil .  In an alternate embodiment, the process starts from grinding granular and rigid cellular plastic material such as expanded polystyrene, e.g., to be mixed with debris in a layered system, so that a certain amount of the crushed material is spread over a certain amount of debris in a concrete mixer or substitute device by adding water, water and slurry or just slurry and bathing, and so on until a final slurry is obtained or the slurry itself. and a binder helm for the manufacture of blocks, bricks, floors and similar materials for the construction industry.
Assim, o processo de reaprove itamento em cotejo, de resíduos sólidos e semissólidos, pressupõe processo físico e químico consubstanciado na trituração de pol iestireno expandido ou sucedâneo , cuj o volume é reduzido antes ou depois da trituração mediante o emprego de solvente de uso comum, para que o material plástico celular e rígido, uma vez triturado , possa ser misturado inclusive em sistema de camadas diretamente com e ntulho.  Thus, the process of collating reuse of solid and semi-solid waste presupposes the physical and chemical process embodied in the grinding of expanded or substitute polystyrene, whose volume is reduced before or after grinding using a commonly used solvent, so that the rigid cellular plastic material, once crushed, can be mixed even in layer system directly with dust.
Noutra alternativa de real ização, o poliestireno expand ido ou sucedâneo é reduzido em volume por meio do uso de solvente de uso comum e não reivindicado, inclusive e principalmente em situações em que a coleta sej a em local difere nte do processamento , tendo em vista também o transporte do material para posterior, caso em que o material reduzido em volume transforma-se numa solução dotada de certa viscosidade que é melhorada pela adição de terra, a fim de que se possa realizar a mistura com entulhos provenientes da construção civil, p.ex. , resultando no composto aglutinador. In another embodiment, expanded polystyrene or substitute is reduced in volume by the use of common unclaimed solvent, including and especially in situations where collection is at a different location from processing for purposes of processing. also transport the material for later, in which case the The volume-reduced material becomes a solution with a certain viscosity which is improved by the addition of earth, so that it can be mixed with debris from the building industry, eg resulting in the binder compound.

Claims

REIVINDICAÇÕES
1 - PROCESSO PARA O REAPROVEITAMENTO DE VALORES QUÍMICOS DE RESÍDUOS SÓLIDOS E SEMISSÓLIDOS, ONDE RESÍDUOS SÓLIDOS ORIUNDOS DA RECICLAGEM DO LIXO COMUM E ENTULHOS PROVENIENTES DA CONSTRUÇÃO CIVIL SÃO MISTURADOS E REUTILIZADOS PARA A PRODUÇÃO DE MASSA AGLOMERANTE PARA A FABRICAÇÃO DE TIJOLOS E PRODUTOS CONGÉNERES, que compree nde processo para a fabricação de pasta viscosa de reação exotérmica com resistência mecânica adequada para servir de elemento aglomerante .  1 - PROCEDURE FOR THE RECOVERY OF CHEMICAL VALUES OF SOLID AND SEMISOLID WASTE, WHERE SOLID WASTE FROM THE RECYCLING OF CIVIL CONSTRUCTION ARE MIXED AND WASTE PRODUCED FOR PRODUCTS AND WASTE PRODUCTION comprising a process for the manufacture of exothermic viscous pulp having adequate mechanical strength to serve as a binder element.
2 - PROCESSO PARA O REAPROVEITAMENTO DE VALORES QUÍMICOS DE RESÍDUOS SÓLIDOS E SEMISSÓLIDOS , ONDE RESÍDUOS SÓLIDOS ORIUNDOS DA RECICLAGEM DO LIXO COMUM E ENTULHOS PROVENIENTES DA CONSTRUÇÃO CIVIL SÃO MISTURADOS E REUTILIZADOS PARA A PRODUÇÃO DE MASSA AGLOMERANTE PARA A FABRICAÇÃO DE TIJOLOS E PRODUTOS CONGÉNERES, de acordo com a reivind icação n° 1 , caracterizado pelo fato de ser consubstanciado na trituração de material plástico ce lular e rígido de constituição granular , mediante redução de volume com a aplicação de solvente de uso comum.  2 - PROCEDURE FOR THE RECOVERY OF CHEMICAL VALUES OF SOLID AND SEMISOLID WASTE, WHERE SOLID WASTE FROM RECYCLING OF CIVIL CONSTRUCTION ARE MIXED AND WASTE PRODUCED FOR PRODUCTS AND WASTE PRODUCTION according to claim 1, characterized in that it is embodied in the crushing of cellular and rigid granular plastic material by volume reduction with the application of a commonly used solvent.
3 - PROCESSO PARA O REAPROVEITAMENTO DE VALORES QUÍMICOS DE RESÍDUOS SÓLIDOS E SEMISSÓLIDOS, ONDE RESÍDUOS SÓLIDOS ORIUNDOS DA RECICLAGEM DO LIXO COMUM E ENTULHOS PROVENIENTES DA CONSTRUÇÃO CIVIL SÃO MISTURADOS E REUTILIZADOS PARA A PRODUÇÃO DE MASSA AGLOMERANTE PARA A FABRICAÇÃO DE TIJOLOS E PRODUTOS CONGÉNERES, de acordo com a reivindicação n° 1 , caracterizado pelo fato de a primeira mistura tornar-se viscosa pela adição de terra, resultando numa segunda pasta viscosa para mistura com entulhos provenientes da construção civil. 3 - PROCESS FOR THE RECOVERY OF CHEMICAL VALUES OF SOLID AND SEMISOLID WASTE, WHERE SOLID WASTE FROM RECYCLING OF CIVIL CONSTRUCTION ARE MIXED AND WASTE PRODUCED FOR PRODUCTS AND WASTE PRODUCTION according to claim 1, characterized by the fact that the first mixture becomes viscous by the addition of earth, resulting in a second viscous paste for mixing with construction debris.
4 - PROCESSO PARA O REAPROVEITAMENTO DE VALORES QUÍMICOS DE RESÍDUOS SÓLIDOS E SEMISSÓLIDOS, ONDE RESÍDUOS SÓLIDOS ORIUNDOS DA RECICLAGEM DO LIXO COMUM E ENTULHOS PROVENIENTES DA CONSTRUÇÃO CIVIL SÃO MISTURADOS E REUTILIZADOS PARA A PRODUÇÃO DE MASSA AGLOMERANTE PARA A FABRICAÇÃO DE TIJOLOS E PRODUTOS CONGÉNERES , de acordo com a reivindicação n° 1 , caracterizado pelo fato de promover a trituração de poliestireno expandido (EPS) para mistura com entulhos em camadas, e assim sucessivamente, obtendo-se o elemento aglomerante .  4 - PROCEDURE FOR THE RECOVERY OF CHEMICAL VALUES OF SOLID AND SEMISOLID WASTE, WHERE SOLID WASTE FROM RECYCLING OF CIVIL CONSTRUCTION ARE MIXED AND WASTE PRODUCED FOR PRODUCTS AND WASTE PRODUCTION Claim 1, characterized in that it promotes the grinding of expanded polystyrene (EPS) for mixing with layered debris, and thus successively obtaining the binder element.
PCT/BR2013/000082 2012-03-21 2013-03-14 Method of re-using solid waste from garbage recycling and civil engineering WO2013138890A1 (en)

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Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO2016074053A1 (en) * 2014-11-10 2016-05-19 Jair ANCIOTO Method for reusing solid waste from ordinary refuse rejected from conventional recycling processes and construction waste by mixing with a binding composite to make bricks or similar products

Citations (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
NL8200730A (en) * 1982-02-24 1983-09-16 Hubertus Zandbergen Building materials from mineral filler and thermoplastic - made by heating filler, esp. sand, and adding waste thermoplastic, esp. polystyrene foam to form shapable dough
DE19506065A1 (en) * 1995-02-22 1996-08-29 Marion Schiller Insulation brick for inner and outer walls
KR20010073490A (en) * 2000-01-15 2001-08-01 오주희 Method of manufacturing yellow charcoal boundary step stone soil product
US7449517B1 (en) * 2003-06-21 2008-11-11 James Rock Associates, Llc Composite building material
CN101376577A (en) * 2007-08-30 2009-03-04 北京曲全环保科技有限公司 Plastic and solid waste combined building material and production method thereof
CN101717238A (en) * 2009-12-10 2010-06-02 王军 Light heat-insulation solid waste baked brick

Patent Citations (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
NL8200730A (en) * 1982-02-24 1983-09-16 Hubertus Zandbergen Building materials from mineral filler and thermoplastic - made by heating filler, esp. sand, and adding waste thermoplastic, esp. polystyrene foam to form shapable dough
DE19506065A1 (en) * 1995-02-22 1996-08-29 Marion Schiller Insulation brick for inner and outer walls
KR20010073490A (en) * 2000-01-15 2001-08-01 오주희 Method of manufacturing yellow charcoal boundary step stone soil product
US7449517B1 (en) * 2003-06-21 2008-11-11 James Rock Associates, Llc Composite building material
CN101376577A (en) * 2007-08-30 2009-03-04 北京曲全环保科技有限公司 Plastic and solid waste combined building material and production method thereof
CN101717238A (en) * 2009-12-10 2010-06-02 王军 Light heat-insulation solid waste baked brick

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO2016074053A1 (en) * 2014-11-10 2016-05-19 Jair ANCIOTO Method for reusing solid waste from ordinary refuse rejected from conventional recycling processes and construction waste by mixing with a binding composite to make bricks or similar products

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