WO2013109493A1 - Blanket for health care use - Google Patents

Blanket for health care use Download PDF

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Publication number
WO2013109493A1
WO2013109493A1 PCT/US2013/021388 US2013021388W WO2013109493A1 WO 2013109493 A1 WO2013109493 A1 WO 2013109493A1 US 2013021388 W US2013021388 W US 2013021388W WO 2013109493 A1 WO2013109493 A1 WO 2013109493A1
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WO
WIPO (PCT)
Prior art keywords
health care
medical health
antimicrobial
blanket
agent
Prior art date
Application number
PCT/US2013/021388
Other languages
French (fr)
Inventor
Moshe Rock
Original Assignee
Mmi-Ipco, Llc
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Mmi-Ipco, Llc filed Critical Mmi-Ipco, Llc
Publication of WO2013109493A1 publication Critical patent/WO2013109493A1/en

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Classifications

    • DTEXTILES; PAPER
    • D06TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06MTREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M11/00Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising
    • D06M11/32Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising with oxygen, ozone, ozonides, oxides, hydroxides or percompounds; Salts derived from anions with an amphoteric element-oxygen bond
    • D06M11/36Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising with oxygen, ozone, ozonides, oxides, hydroxides or percompounds; Salts derived from anions with an amphoteric element-oxygen bond with oxides, hydroxides or mixed oxides; with salts derived from anions with an amphoteric element-oxygen bond
    • D06M11/44Oxides or hydroxides of elements of Groups 2 or 12 of the Periodic Table; Zincates; Cadmates
    • DTEXTILES; PAPER
    • D06TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06MTREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M11/00Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising
    • D06M11/32Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising with oxygen, ozone, ozonides, oxides, hydroxides or percompounds; Salts derived from anions with an amphoteric element-oxygen bond
    • D06M11/50Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising with oxygen, ozone, ozonides, oxides, hydroxides or percompounds; Salts derived from anions with an amphoteric element-oxygen bond with hydrogen peroxide or peroxides of metals; with persulfuric, permanganic, pernitric, percarbonic acids or their salts
    • AHUMAN NECESSITIES
    • A47FURNITURE; DOMESTIC ARTICLES OR APPLIANCES; COFFEE MILLS; SPICE MILLS; SUCTION CLEANERS IN GENERAL
    • A47GHOUSEHOLD OR TABLE EQUIPMENT
    • A47G9/00Bed-covers; Counterpanes; Travelling rugs; Sleeping rugs; Sleeping bags; Pillows
    • A47G9/007Bed-covers; Counterpanes; Travelling rugs; Sleeping rugs; Sleeping bags; Pillows comprising deodorising, fragrance releasing, therapeutic or disinfecting substances
    • AHUMAN NECESSITIES
    • A47FURNITURE; DOMESTIC ARTICLES OR APPLIANCES; COFFEE MILLS; SPICE MILLS; SUCTION CLEANERS IN GENERAL
    • A47GHOUSEHOLD OR TABLE EQUIPMENT
    • A47G9/00Bed-covers; Counterpanes; Travelling rugs; Sleeping rugs; Sleeping bags; Pillows
    • A47G9/02Bed linen; Blankets; Counterpanes
    • A47G9/0207Blankets; Duvets
    • A47G9/0223Blankets
    • AHUMAN NECESSITIES
    • A47FURNITURE; DOMESTIC ARTICLES OR APPLIANCES; COFFEE MILLS; SPICE MILLS; SUCTION CLEANERS IN GENERAL
    • A47GHOUSEHOLD OR TABLE EQUIPMENT
    • A47G9/00Bed-covers; Counterpanes; Travelling rugs; Sleeping rugs; Sleeping bags; Pillows
    • A47G9/02Bed linen; Blankets; Counterpanes
    • A47G9/0238Bed linen
    • AHUMAN NECESSITIES
    • A47FURNITURE; DOMESTIC ARTICLES OR APPLIANCES; COFFEE MILLS; SPICE MILLS; SUCTION CLEANERS IN GENERAL
    • A47GHOUSEHOLD OR TABLE EQUIPMENT
    • A47G9/00Bed-covers; Counterpanes; Travelling rugs; Sleeping rugs; Sleeping bags; Pillows
    • A47G9/02Bed linen; Blankets; Counterpanes
    • A47G9/0238Bed linen
    • A47G9/0253Pillow slips
    • DTEXTILES; PAPER
    • D03WEAVING
    • D03DWOVEN FABRICS; METHODS OF WEAVING; LOOMS
    • D03D1/00Woven fabrics designed to make specified articles
    • D03D1/0017Woven household fabrics
    • DTEXTILES; PAPER
    • D04BRAIDING; LACE-MAKING; KNITTING; TRIMMINGS; NON-WOVEN FABRICS
    • D04BKNITTING
    • D04B1/00Weft knitting processes for the production of fabrics or articles not dependent on the use of particular machines; Fabrics or articles defined by such processes
    • DTEXTILES; PAPER
    • D04BRAIDING; LACE-MAKING; KNITTING; TRIMMINGS; NON-WOVEN FABRICS
    • D04BKNITTING
    • D04B1/00Weft knitting processes for the production of fabrics or articles not dependent on the use of particular machines; Fabrics or articles defined by such processes
    • D04B1/02Pile fabrics or articles having similar surface features
    • D04B1/04Pile fabrics or articles having similar surface features characterised by thread material
    • DTEXTILES; PAPER
    • D04BRAIDING; LACE-MAKING; KNITTING; TRIMMINGS; NON-WOVEN FABRICS
    • D04BKNITTING
    • D04B21/00Warp knitting processes for the production of fabrics or articles not dependent on the use of particular machines; Fabrics or articles defined by such processes
    • D04B21/02Pile fabrics or articles having similar surface features
    • D04B21/04Pile fabrics or articles having similar surface features characterised by thread material
    • DTEXTILES; PAPER
    • D06TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06LDRY-CLEANING, WASHING OR BLEACHING FIBRES, FILAMENTS, THREADS, YARNS, FABRICS, FEATHERS OR MADE-UP FIBROUS GOODS; BLEACHING LEATHER OR FURS
    • D06L1/00Dry-cleaning or washing fibres, filaments, threads, yarns, fabrics, feathers or made-up fibrous goods
    • D06L1/12Dry-cleaning or washing fibres, filaments, threads, yarns, fabrics, feathers or made-up fibrous goods using aqueous solvents
    • D06L1/16Multi-step processes
    • DTEXTILES; PAPER
    • D06TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06MTREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M11/00Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising
    • D06M11/32Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising with oxygen, ozone, ozonides, oxides, hydroxides or percompounds; Salts derived from anions with an amphoteric element-oxygen bond
    • D06M11/36Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising with oxygen, ozone, ozonides, oxides, hydroxides or percompounds; Salts derived from anions with an amphoteric element-oxygen bond with oxides, hydroxides or mixed oxides; with salts derived from anions with an amphoteric element-oxygen bond
    • D06M11/46Oxides or hydroxides of elements of Groups 4 or 14 of the Periodic Table; Titanates; Zirconates; Stannates; Plumbates
    • DTEXTILES; PAPER
    • D06TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06MTREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M11/00Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising
    • D06M11/83Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising with metals; with metal-generating compounds, e.g. metal carbonyls; Reduction of metal compounds on textiles
    • DTEXTILES; PAPER
    • D06TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06MTREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M13/00Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment
    • D06M13/10Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment with compounds containing oxygen
    • D06M13/184Carboxylic acids; Anhydrides, halides or salts thereof
    • D06M13/188Monocarboxylic acids; Anhydrides, halides or salts thereof
    • DTEXTILES; PAPER
    • D06TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06MTREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M13/00Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment
    • D06M13/10Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment with compounds containing oxygen
    • D06M13/184Carboxylic acids; Anhydrides, halides or salts thereof
    • D06M13/192Polycarboxylic acids; Anhydrides, halides or salts thereof
    • DTEXTILES; PAPER
    • D06TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06MTREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M13/00Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment
    • D06M13/322Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment with compounds containing nitrogen
    • D06M13/325Amines
    • D06M13/342Amino-carboxylic acids; Betaines; Aminosulfonic acids; Sulfo-betaines
    • DTEXTILES; PAPER
    • D06TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06MTREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M15/00Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment
    • D06M15/19Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment with synthetic macromolecular compounds
    • D06M15/21Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds
    • D06M15/263Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds of unsaturated carboxylic acids; Salts or esters thereof
    • DTEXTILES; PAPER
    • D06TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06MTREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M16/00Biochemical treatment of fibres, threads, yarns, fabrics, or fibrous goods made from such materials, e.g. enzymatic
    • DTEXTILES; PAPER
    • D10INDEXING SCHEME ASSOCIATED WITH SUBLASSES OF SECTION D, RELATING TO TEXTILES
    • D10BINDEXING SCHEME ASSOCIATED WITH SUBLASSES OF SECTION D, RELATING TO TEXTILES
    • D10B2401/00Physical properties
    • D10B2401/13Physical properties anti-allergenic or anti-bacterial
    • DTEXTILES; PAPER
    • D10INDEXING SCHEME ASSOCIATED WITH SUBLASSES OF SECTION D, RELATING TO TEXTILES
    • D10BINDEXING SCHEME ASSOCIATED WITH SUBLASSES OF SECTION D, RELATING TO TEXTILES
    • D10B2503/00Domestic or personal
    • D10B2503/06Bed linen
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10TTECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
    • Y10T428/00Stock material or miscellaneous articles
    • Y10T428/23907Pile or nap type surface or component
    • Y10T428/23921With particles
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10TTECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
    • Y10T428/00Stock material or miscellaneous articles
    • Y10T428/23907Pile or nap type surface or component
    • Y10T428/2395Nap type surface
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10TTECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
    • Y10T428/00Stock material or miscellaneous articles
    • Y10T428/24Structurally defined web or sheet [e.g., overall dimension, etc.]
    • Y10T428/24479Structurally defined web or sheet [e.g., overall dimension, etc.] including variation in thickness
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10TTECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
    • Y10T442/00Fabric [woven, knitted, or nonwoven textile or cloth, etc.]
    • Y10T442/20Coated or impregnated woven, knit, or nonwoven fabric which is not [a] associated with another preformed layer or fiber layer or, [b] with respect to woven and knit, characterized, respectively, by a particular or differential weave or knit, wherein the coating or impregnation is neither a foamed material nor a free metal or alloy layer
    • Y10T442/2525Coating or impregnation functions biologically [e.g., insect repellent, antiseptic, insecticide, bactericide, etc.]

Definitions

  • This invention relates to blankets, and more particularly to blankets and similar fabric articles suited for use, e.g., in medical health care environments.
  • a typical woven hospital blanket formed by standard textile procedures may have a weight of 10.3 oz/yd 2 , thickness of 0.086 inch, CLO of 0.467, and CLO-to-weight ratio of 0.045.
  • Hospital blankets typically also only have a relatively short useful life, e.g., in some cases only a few months, after which the repeated exposure to the harsh conditions of industrial laundering, including high temperatures, bleach, and high pH, cause the blankets to fall apart and disintegrate.
  • a medical health care blanket comprises a fabric of micro-denier polymer fibers having at least one raised surface, and an antimicrobial system applied to the fabric and having durable antimicrobial properties after at least 50 industrial laundering cycles (e.g., at 160°F with alkali detergent and peroxide).
  • the polymer of the polymer fibers is selected from among polyester, polypropylene, polyamide, and combinations thereof.
  • the antimicrobial system has durable antimicrobial properties after at least 100 industrial laundering cycles, or after at least 150 industrial laundering cycles, or after at least 200 industrial laundering cycles.
  • the fabric has a double face knit configuration with velour/velour finish surfaces.
  • the antimicrobial system comprises an antimicrobial agent, a rechargeable sequestering agent isolating the antimicrobial agent, and a binding agent binding the sequestering agent to surfaces of the polymer fibers.
  • the antimicrobial agent comprises peroxide.
  • the sequestering agent is a complex of metal oxide, metal salt, metal peroxide, and hydrogen peroxide.
  • the metal is selected from the group of: zinc, magnesium, and zirconium.
  • the metal salt is selected from the group of: chloride, nitrate, acetate, and bromide.
  • the rechargeable sequestering agent comprises zinc oxide, or zinc hydroxide, or zinc salt, e.g. zinc oxide and/or zinc salt.
  • the sequestering agent is rechargeable by contact with peroxide antimicrobial agent.
  • the binding agent comprises an acrylate (or polyurethane).
  • the antimicrobial system comprises: an antimicrobial agent, and a rechargeable sequestering agent isolating the antimicrobial agent, the rechargeable sequestering agent being incorporated in the polymer fiber as micro-dimensioned or nano-dimensioned particles.
  • the micro-dimensioned or nano-dimensioned particles of the rechargeable sequestering agent are is distributed throughout the cross section of the polymer fibers.
  • the micro-dimensioned or nano-dimensioned particles of the rechargeable sequestering agent are distributed in a relatively greater concentration in an outer layer of the polymer fibers.
  • the micro-dimensioned or nano-dimensioned particles of the rechargeable sequestering agent are exposed on an outer surface of the polymer fibers.
  • a method of contributing to sanitary health care environment comprising: 1) providing a medical health care blanket as described above having a predetermined enhanced level of antimicrobial protection, and 2) subjecting the medical health care blanket to frequent industrial laundering cycles including contact with an aqueous solution of hydrogen peroxide, thereby to recharge antimicrobial protection provided by the medical health care blanket to at least a predetermined minimum acceptable level, and 3) repeating step 2) for at least 50 industrial laundering cycles.
  • Implementations of this aspect of the disclosure can include one or more of the following additional features.
  • the polymer of the polymer fibers is selected from among polyester, polypropylene, polyamide, and combinations thereof.
  • the multiple industrial laundering cycles comprises at least 100 industrial laundering cycles, or at least 150 industrial laundering cycles, or at least 200 industrial laundering cycles.
  • a medical health care fabric material comprises a fabric of micro-denier polymer fibers having at least one raised surface, and an antimicrobial system having durable antimicrobial properties after at least 50 industrial laundering cycles.
  • the antimicrobial system has durable antimicrobial properties after at least 100 industrial laundering cycles, or after at least 150 industrial laundering cycles, or at least 200 industrial laundering cycles.
  • the antimicrobial system comprises: an antimicrobial agent, a rechargeable sequestering agent isolating the antimicrobial agent, and a binding agent binding the sequestering agent to surfaces of the polymer fibers.
  • the antimicrobial system comprises: an antimicrobial agent, and a rechargeable sequestering agent isolating the antimicrobial agent, the rechargeable sequestering agent being incorporated in the polymer fiber as micro- dimensioned or nano-dimensioned particles.
  • the micro-dimensioned or nano-dimensioned particles of the rechargeable sequestering agent are distributed throughout the cross section of the polymer fibers.
  • the micro-dimensioned or nano-dimensioned particles of the rechargeable sequestering agent are distributed in a relatively greater concentration in an outer layer of the polymer fibers.
  • the micro-dimensioned or nano- dimensioned particles of the rechargeable sequestering agent are exposed on an outer surface of the polymer fibers.
  • a medical health care blanket of this disclosure formed of a micro-denier polyester polymer material, e.g., polyester, polypropylene, or polyamide, in a double face knit configuration, with velour/velour finish, can offer: e.g., relatively improved thermal insulation efficiency properties (e.g., a relatively higher CLO-to- weight ratio) as compared to conventional hospital blankets formed of cotton or a blend of polyester and cotton; and/or can retain relatively less water, e.g. about 31% less, as compared to traditional hospital blankets formed of cotton or polyester and cotton blend, resulting in significantly shorter drying times during industrial laundering cycles, e.g. about 70% less, with commensurate reduction in energy costs; and/or can have a relatively longer usable life than traditional hospital blankets formed of cotton or a blend of polyester and cotton.
  • relatively improved thermal insulation efficiency properties e.g., a relatively higher CLO-to- weight ratio
  • a medical health care blanket of this disclosure can serve as a first line of defense against transmission of disease and infection, e.g., in some implementations, a medical health care blanket of this disclosure can incorporated durable antimicrobial properties that assist patients to avoid contracting germs and/or bacteria, and thus create a more sanitary environment.
  • Antimicrobial fabrics of the disclosure can also be a factor in achieving health care objectives such as keeping the entire environment surrounding a medical patient (or other user) free, or at a reduced level, of infectious disease bacteria.
  • FIG. 1 is a perspective view of a medical health care blanket of the present disclosure, disposed upon a bed, e.g. in a hospital or other health care facility.
  • FIG. 2 is a somewhat diagrammatic side section view of the medical health care blanket of FIG. 1.
  • FIG. 3 is a similar somewhat diagrammatic side section view of another medical health care blanket of the disclosure.
  • a medical health care blanket 10 e.g. for use in the health care industry, is shown on a patient bed 12, e.g., in a hospital or other long-term patient care facility.
  • the blanket 10 must undergo frequent and repeated industrial laundering cycles under extreme conditions, including of high temperature water, disinfecting agents (e.g., hydrogen peroxide or bleach), and high pH, for reasons of sanitation and in efforts to combat transmission of disease and other unhealthy conditions.
  • disinfecting agents e.g., hydrogen peroxide or bleach
  • high pH disinfecting agents
  • This may be a particular concern in environments where the bed and blanket are subject to use sequentially for multiple patients, e.g. in a hospital or other short term case situation.
  • the medical health care blanket 10 is formed of suitable polymer, e.g. 100% polyester, or polypropylene, or polyamide material, or combinations thereof (e.g., micro-denier polyester material), e.g. in a double face knit configuration, with a knit body 14 and velour/velour finish surfaces 16, 18.
  • the double face knit material can be, e.g. in reverse plating terry sinker loop circular knit, double needle bar warp knit, or brushed woven.
  • Double face circular knit material can be produced by raising (e.g., napping) or by cut loop (off-line or on the knitting machine) of terry sinker loop.
  • the raised surface yarn (or pile yarn) of the material can be polyester flat yarn, e.g.
  • the pile yarn can also be broader than microdenier fibers (e.g., 0.3 to 3.0 dpi).
  • the fibers of the medical health care blanket polymer material may be treated with an antistatic chemical to reduce electrostatic build up that can be annoying to a user, e.g. due to uncomfortable static discharge, and/or that can interfere with operation of medical and/or communications devices in the vicinity.
  • An example of a commercial antistatic chemical for treating fabric is Lurotex A25 (a nonionic polyamide derivative available commercially from BASF Aktiengesellschaft, of Ludwigshafen, Germany), applied, e.g., at 2% to 4%.
  • the medical health care blanket 10 of the disclosure offers multiple advantages during use a medical care environment, e.g., as compared to conventional or traditional hospital blankets formed of cotton or a blend of polyester and cotton.
  • the medical health care blanket 10 exhibits improved thermal insulation properties, lower water retention, a longer usable life, and antimicrobial properties for resisting
  • the medical health care blanket 10 of the disclosure has relatively better thermal insulation efficiency properties than conventional hospital blankets made from cotton or a blend of polyester and cotton.
  • the medical health care blanket 10 of the disclosure has CLO of 0.812 (compared to CLO of 0.467 for a traditional hospital blanket) and a CLO-to-weight ratio of 0.140 (compared to 0.045 for traditional hospital blankets).
  • the medical health care blanket 10 is also thicker, e.g. having a thickness, T, of about 0.154 inch (as compared to a thickness of about 0.086 inch for a traditional hospital blanket).
  • a medical health care blanket 10 of the disclosure is also relatively lighter in weight than traditional hospital blankets, e.g. the medical health care blanket 10 of the disclosure may weigh about 5.8 ounces/yard 2 as compared to about 10.3 ounces/yard 2 for a traditional hospital blanket.
  • the medical health care blanket 10 of the disclosure also retains much less water during laundering, e.g. as compared to traditional hospital blankets formed of cotton or a blend of polyester and cotton. For example, the medical health care blanket 10 of the disclosure retains about 31% less water as compared to a traditional hospital blanket formed of cotton or a blend of polyester and cotton.
  • the drying time for the medical health care blanket 10 following laundering is approximately 70% of that required for drying a traditional hospital blanket of cotton or a blend of polyester and cotton.
  • the reduced water retention properties, resulting in shorter drying times, has the additional, particularly beneficial, effect of significantly lowering energy consumption and costs for the health care facility.
  • the micro-denier polymer blanket 10 of the disclosure also exhibits greater longevity (i.e., longer useful life), e.g. as compared to traditional hospital blankets formed of cotton or a blend of polyester and cotton, through repeated industrial laundering cycles under harsh conditions, including high water temperatures and exposure to bleach and high pH environments.
  • a traditional hospital blanket made of cotton or a blend of polyester and cotton can be expected to degrade and disintegrate to a point of being unusable within a just a few months of first use.
  • the medical health care blanket 10 of the disclosure, formed of micro-denier polymer material can be expected to have significantly longer usable life, e.g., extending 12 months or longer.
  • forming the medical health care blanket 10 of polyester material allows the blanket to be provided in a range of colors that remain stable (e.g., will not substantially fade or become discolored) during repeated industrial laundering cycles.
  • the medical health care blanket 10 of the disclosure has been developed with a capacity for killing GRAM-positive and/or GRAM-negative bacteria, even after numerous industrial laundering cycles.
  • a sample medical health blanket of the disclosure continued to show an acceptable level of antimicrobial performance after 50 industrial laundering cycles. Similar performance is projected for antimicrobial fabrics of the disclosure, e.g., after at least 100 industrial laundering cycles, or after at least 150 industrial laundering cycles, or after at least 200 industrial laundering cycles.
  • the medical heath care blanket 10 can serve as a first line of defense in a hospital, health care facility, or other similar environment, protecting the patient from contact transmission, droplet transmission, airborne transmission, etc.
  • the medical health care blanket 10, having a raised surface of, e.g., polyester fiber, and containing antimicrobial agents for killing GRAM-positive and/or GRAM-negative bacteria, can provide an important enhancement to reducing nosocomial infections, such as MRSA and/or klebsiella pneumonia.
  • antimicrobial agents examples include “Disinfection, Sterilization, and Preservation”, edited and partially written by Professor Seymour S. Block, Fourth Edition, published 1991 by Lea & Febiger, Pennsylvania, and in "Recent Advances in Antimicrobial Treatments of Textiles", Y. Gao and R. Cranston, TEXTILE RESEARCH JOURNAL Vol. 78(1), p 60-72 (2008), a review of antimicrobial treatment of textiles. The complete disclosures of both references are also incorporated herein by reference. Described below are examples of a few categories of antimicrobial agents that can be applied to polyester and other polymeric fibers of the medical health care blanket 10 in order to reduce transmission of infectious disease in the health care environment where the blanket 10 is employed.
  • a medical health care blanket 10 of the disclosure is treated with zinc oxide, zinc hydroxide, zinc peroxide, and/or zinc salt (which has very low solubility and, by itself, has mild antimicrobial properties), e.g. zinc oxide and/or zinc salt, to create a system for providing a peroxide antimicrobial agent, e.g. as described in Toreki et al. U.S. Patent Publication No. 2011/0171280, published July 14, 2011, and assigned on its face to Quick-Med Technologies, Inc., of Gainesville, Florida, the complete disclosure of which is incorporated herein by reference.
  • sequestering agents e.g. zinc oxide, zinc hydroxide, zinc peroxide, and/or zinc salt, e.g. zinc oxide and/or zinc salt
  • a binding agent e.g. an acrylate (or polyurethane).
  • the sequestering agent can be a complex of metal oxide, metal salt, metal peroxide, and hydrogen peroxide.
  • the metal can be zinc (or magnesium or zirconium).
  • the metal salts can contain chloride or nitrate (or acetate or bromide).
  • the complex has low solubility and it is deposited on the textile fabric or entrapped within the binder.
  • the binding agent on the surfaces of the polyester or other polymeric fibers then serves to secure the sequestering agents, e.g. against early dislodgement during repeated industrial laundering cycles.
  • the binder based, e.g., on acrylate, can entrap peroxide and contributes to the antimicrobial property.
  • the binder binds the metal oxide, metal peroxide, and/or metal salt to increase antimicrobial durability to withstand industrial laundering cycles.
  • the sequestering agents serve to sequester (or immobilize) the antimicrobial agent, i.e. the peroxide, on the surfaces of the blanket fibers, thereby to provide durable antimicrobial protection.
  • the medical health care blanket 10 is formed of polyester, polypropylene, or polyamide (or other suitable polymer or polymer blend) fibers that incorporate particles of sequestering agent, e.g. zinc oxide and/or zinc salt, of small characteristic dimension, e.g. particles of micro or nano dimension.
  • the zinc oxide and/or zinc salt particles may be added to feed of polymer chips or polymer melt during extrusion of the polymer fibers. In this manner, the zinc oxide and/or zinc salt particles are distributed (e.g., randomly) throughout the cross section of the fiber.
  • a relatively greater distribution or concentration of particles of sequestering agent can be preferentially provided in an outer (sheath) layer of the polymer fibers, and/or even exposed on the outer surface of the polyester fibers.
  • the polymer fibers formed, e.g., using core/sheath spinning technology may have the form of bicomponent fibers having an outer sheath with a relatively high concentration of zinc oxide and/or zinc salt particles, and an inner core with a relatively lower concentration of, or little or no, zinc oxide and/or zinc salt particles.
  • the medical care blanket 10 having polyester polymer fibers incorporating particles of zinc oxide and/or zinc salt, e.g. on the surface, in the outer layer, and/or distributed throughout the cross section can be treated with a disinfecting agent, such as hydrogen peroxide or percarboxylic acid, to produce a complex system of zinc oxide and/or zinc salt, zinc peroxide (generated by exposure of the zinc oxide and/or zinc salt to the hydrogen peroxide), as well as the hydrogen peroxide sequestered at a controlled pH on the surface of the textile fabric, e.g. the fibers of a raised surface blanket or linen.
  • the disinfecting agent may be applied to the fabric, e.g. in a textile mill, during an industrial laundering cycle, or as a separate step before or after the industrial laundering cycle.
  • the treated medical care blanket 10, after this hydrogen peroxide recharging or reloading process will typically have good antimicrobial properties and with high durability.
  • antimicrobial properties and capabilities of medical health care blanket 10 can be expected to degrade as the antimicrobial agent becomes depleted, e.g. is washed or worn away.
  • industrial laundering of the medical health care blanket 10, with application of an aqueous solution including hydrogen peroxide serves to recharge the sequestering agents with peroxide from the laundering solution, thus restoring the antimicrobial properties of the medical health care blanket 10.
  • Use of hydrogen peroxide as a disinfecting agent e.g., rather the bleach
  • Industrial laundries of the type discussed are also moving away from use of chlorine as a disinfectant (for example, for environmental reasons) and moving to peroxide as an alternative.
  • Silver-based antimicrobial agents can also be used in medical health care blankets 10 of the disclosure.
  • the silver can be in the form of, e.g. silver ions, silver ions embedded in Zeolite, and/or silver deposited on the surface of polyester or other suitable polymeric fibers by reduction-oxidation process. Any of these silver treatments can be combined with a polymer, e.g. polyester, nylon, and/or acrylic, during fiber manufacture.
  • the silver-loaded fibers can then be blended with untreated synthetic yarn in simple form to make blended spun yarn, or can be blended in filament form to be commingled with untreated synthetic filament yarn.
  • the silver-loaded fibers can also be added to the knit construction with untreated synthetic filaments.
  • Binders may be added to the silver ion during application in order to control, i.e. reduce, the level of leaching during laundering. Selection of a binder is crucial to improvement of the durability and longevity of the medical health care blanket 10 through repeated cycles of industrial laundering.
  • the binder, mixed with the antimicrobial agent can be applied by pad as is, or with an added cross-linking agent. After application, the treated fabric is dried and cured at 375°F for 60 seconds.
  • the binder must be stable under the conditions of industrial laundering, e.g.
  • a preferred binder is based on acrylate, but other binders based on polyurethane, silicon, etc. will be effective as well.
  • the family of quaternary ammonium silane (QAS) chemicals can also be used as antimicrobial agents in medical health care blankets 10 of the disclosure.
  • One suitable antimicrobial agent of this family is 3 (trimethoxysilyl) propyldimethyl octadecyl ammonium chloride. Trimethoxy silyl reacts with another trimethoxy silyl, or with the hydroxyl, carboxylic, amine, or amide on the fiber surface, and the octadecyl with the quaternary ammonium will puncture and rupture the outer wall of a bacteria cell.
  • This antimicrobial agent type does not leach out of the fibers in order to penetrate the bacteria, so the effective useful life of the medical health care blanket 10 is extended, and thus enhanced. Further enhancement of the durability of the medical health care blanket through repeated industrial laundering cycles (e.g. at 160°F with high PH and exposure to disinfecting agents, such as peroxide or bleach) may be obtained by addition of a chemical binder, with or without a cross-linking agent.
  • Polyhexamethylene bigunide can also be used as a antimicrobial agent in medical health care blankets 10 of the disclosure.
  • This agent may be applied to polyester or other suitable polymeric fabric by patting with addition of binder, and with or without cross linking agent.
  • disinfectant chemicals include, e.g., peracetic acid, ozone, etc., which can recharge the metal salt or metal oxide to generate the complex containing metal peroxide as an antimicrobial agent.
  • antimicrobial agents discussed above have broad "killing" capacity, targeting no specific moiety in the cell metabolism, and, as a result, will not generate bacteria resistance to antibiotic agents (so-called “super bug”). Transmission of drug resistant bacteria (like MRSA) can occur by contact transmission (direct or indirect), as well as by airborne transmission.
  • ISO 2073 is a standard quantitative test method for determining antimicrobial activity of immobilized antimicrobial agents.
  • Other or additional testing methods may also be utilized.
  • ATCC 147 is a form of qualitative testing
  • ASTM E 2149-01 Sonic Flask test
  • a sample of the medical health care blanket 10 of this disclosure (Material Sample Reference No. 08241 IB) was treated with the zinc-based peroxide antimicrobial agent system discussed above. Testing of antimicrobial properties was conducted on an unlaundered sample, and on a sample that had undergone 100 industrial laundering cycles of 160°F for 10 minutes each cycle. The samples were tested according to ISO 20743, AATCC 100, and JIS L 1902, with two different bacteria in different inoculum concentrations (shown in Table 1).
  • a medical health care blanket 10 of the disclosure may have a knit body 14' with only a single raised or fleece surface 16'.
  • the medical health care blanket can also be formed of a blend of polyester (or other suitable polymer) and natural fibers (e.g., cotton).
  • the zinc oxide or low solubility zinc salt of the rechargeable sequestering agent can be substituted by, e.g., magnesium oxide, zirconium oxide, or low solubility salt of magnesium or zirconium.
  • the yarn or fibers of the textile fabric may be chemically treated, e.g. with 4% Lurotex A-25 (available from BASF Aktiengesellschaft, of Ludwigshafen, Germany), a nonionic polyamide derivative that improves moisture transport in textiles composed of synthetic fibers, to increase the moisture content on the face of the fabric, to impart antistatic and soil release properties, as well as absorbing moisture from the air, e.g., to release hydrogen peroxide from sequestration on the surface of the fabric.
  • Lurotex A-25 available from BASF Aktiengesellschaft, of Ludwigshafen, Germany
  • a nonionic polyamide derivative that improves moisture transport in textiles composed of synthetic fibers, to increase the moisture content on the face of the fabric, to impart antistatic and soil release properties, as well as absorbing moisture from the air, e.g., to release hydrogen peroxide from sequestration on the surface of the fabric.
  • antimicrobial blanket fabric of the disclosure in other environments, e.g., in nursing homes, correctional facilities, hospitality environments (e.g., hotels, motels, cruise ships, etc.), dormitories, military facilities, schools, daycare facilities and kindergartens, private homes, and the like, is also contemplated.
  • hospitality environments e.g., hotels, motels, cruise ships, etc.
  • dormitories e.g., military facilities, schools, daycare facilities and kindergartens, private homes, and the like
  • other uses of antimicrobial fabrics of the disclosure are also contemplated.
  • use of the antimicrobial fabric material described herein for particular use in medical health care blankets might be expanded, e.g., to include bed sheets 22, which are generally formed woven fabric of cotton and/or blends of polyester (or other suitable polymer) and cotton, which, in fabrics of the present disclosure, could include relatively higher polyester (or other polymer) content in the polyester/cotton blends.
  • Antimicrobial fabrics of the disclosure might also be used, e.g., for other products in the home consumer textile market, such as pillow cases 24, window coverings 26, floor coverings 28, etc., all for use in medical health care environments (as shown) as well as other environments, and also for use in other types of products and/or markets. Accordingly, other embodiments are within the scope of the following claims.

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Abstract

A medical health care blanket or fabric, formed of micro-denier fibers, e.g., polyester or other suitable polymer, has at least one raised surface, and incorporates an antimicrobial system having durable antimicrobial properties after at least 50, 100, 150, or even up to 200 industrial laundering cycles. A method of contributing to a sanitary health care environment is also described.

Description

Blanket for Health Care Use
PRIORITY
This application claims priority to U.S. provisional application no. 61/587,275, filed on January 17, 2012, now pending, and to US provisional application no.
61/604,779, filed on February 29, 2012, now pending. The entire contents of both provisional applications are incorporated herein by reference.
TECHNICAL FIELD
This invention relates to blankets, and more particularly to blankets and similar fabric articles suited for use, e.g., in medical health care environments.
BACKGROUND
Blankets used in medical health care environments, e.g., in hospitals and long- term care facilities, are often formed of woven or knit fabric, e.g., formed of cotton or a blend of polyester and cotton. These blankets can be quite heavy, but generally have only a low value of CLO (a measure of thermal insulation wherein 1 CLO = 0.155 m2K/W), and, accordingly, only a low CLO-to-weight ratio. By way of example only, a typical woven hospital blanket formed by standard textile procedures may have a weight of 10.3 oz/yd2, thickness of 0.086 inch, CLO of 0.467, and CLO-to-weight ratio of 0.045.
Hospital blankets typically also only have a relatively short useful life, e.g., in some cases only a few months, after which the repeated exposure to the harsh conditions of industrial laundering, including high temperatures, bleach, and high pH, cause the blankets to fall apart and disintegrate.
SUMMARY
According to one aspect of the disclosure, a medical health care blanket comprises a fabric of micro-denier polymer fibers having at least one raised surface, and an antimicrobial system applied to the fabric and having durable antimicrobial properties after at least 50 industrial laundering cycles (e.g., at 160°F with alkali detergent and peroxide).
Implementations of this aspect of the disclosure can include one or more of the following additional features. The polymer of the polymer fibers is selected from among polyester, polypropylene, polyamide, and combinations thereof. The antimicrobial system has durable antimicrobial properties after at least 100 industrial laundering cycles, or after at least 150 industrial laundering cycles, or after at least 200 industrial laundering cycles. The fabric has a double face knit configuration with velour/velour finish surfaces. The antimicrobial system comprises an antimicrobial agent, a rechargeable sequestering agent isolating the antimicrobial agent, and a binding agent binding the sequestering agent to surfaces of the polymer fibers. The antimicrobial agent comprises peroxide. The sequestering agent is a complex of metal oxide, metal salt, metal peroxide, and hydrogen peroxide. The metal is selected from the group of: zinc, magnesium, and zirconium. The metal salt is selected from the group of: chloride, nitrate, acetate, and bromide. The rechargeable sequestering agent comprises zinc oxide, or zinc hydroxide, or zinc salt, e.g. zinc oxide and/or zinc salt. The sequestering agent is rechargeable by contact with peroxide antimicrobial agent. The binding agent comprises an acrylate (or polyurethane). The antimicrobial system comprises: an antimicrobial agent, and a rechargeable sequestering agent isolating the antimicrobial agent, the rechargeable sequestering agent being incorporated in the polymer fiber as micro-dimensioned or nano-dimensioned particles. The micro-dimensioned or nano-dimensioned particles of the rechargeable sequestering agent are is distributed throughout the cross section of the polymer fibers. The micro-dimensioned or nano-dimensioned particles of the rechargeable sequestering agent are distributed in a relatively greater concentration in an outer layer of the polymer fibers. The micro-dimensioned or nano-dimensioned particles of the rechargeable sequestering agent are exposed on an outer surface of the polymer fibers.
According to another aspect of the disclosure, a method of contributing to sanitary health care environment, comprising: 1) providing a medical health care blanket as described above having a predetermined enhanced level of antimicrobial protection, and 2) subjecting the medical health care blanket to frequent industrial laundering cycles including contact with an aqueous solution of hydrogen peroxide, thereby to recharge antimicrobial protection provided by the medical health care blanket to at least a predetermined minimum acceptable level, and 3) repeating step 2) for at least 50 industrial laundering cycles.
Implementations of this aspect of the disclosure can include one or more of the following additional features. The polymer of the polymer fibers is selected from among polyester, polypropylene, polyamide, and combinations thereof. The multiple industrial laundering cycles comprises at least 100 industrial laundering cycles, or at least 150 industrial laundering cycles, or at least 200 industrial laundering cycles.
According to another aspect of the disclosure, a medical health care fabric material comprises a fabric of micro-denier polymer fibers having at least one raised surface, and an antimicrobial system having durable antimicrobial properties after at least 50 industrial laundering cycles.
Implementations of this aspect of the disclosure can include one or more of the following additional features. The antimicrobial system has durable antimicrobial properties after at least 100 industrial laundering cycles, or after at least 150 industrial laundering cycles, or at least 200 industrial laundering cycles. The antimicrobial system comprises: an antimicrobial agent, a rechargeable sequestering agent isolating the antimicrobial agent, and a binding agent binding the sequestering agent to surfaces of the polymer fibers.
Other implementation of this aspect of the disclosure can include one or more of the following additional features. The antimicrobial system comprises: an antimicrobial agent, and a rechargeable sequestering agent isolating the antimicrobial agent, the rechargeable sequestering agent being incorporated in the polymer fiber as micro- dimensioned or nano-dimensioned particles. The micro-dimensioned or nano- dimensioned particles of the rechargeable sequestering agent are distributed throughout the cross section of the polymer fibers. The micro-dimensioned or nano-dimensioned particles of the rechargeable sequestering agent are distributed in a relatively greater concentration in an outer layer of the polymer fibers. The micro-dimensioned or nano- dimensioned particles of the rechargeable sequestering agent are exposed on an outer surface of the polymer fibers.
Implementations of this disclosure can incorporate one or more of the following advantages. For example, a medical health care blanket of this disclosure, formed of a micro-denier polyester polymer material, e.g., polyester, polypropylene, or polyamide, in a double face knit configuration, with velour/velour finish, can offer: e.g., relatively improved thermal insulation efficiency properties (e.g., a relatively higher CLO-to- weight ratio) as compared to conventional hospital blankets formed of cotton or a blend of polyester and cotton; and/or can retain relatively less water, e.g. about 31% less, as compared to traditional hospital blankets formed of cotton or polyester and cotton blend, resulting in significantly shorter drying times during industrial laundering cycles, e.g. about 70% less, with commensurate reduction in energy costs; and/or can have a relatively longer usable life than traditional hospital blankets formed of cotton or a blend of polyester and cotton.
When used as a hospital or long-term care facility bed blanket, a medical health care blanket of this disclosure can serve as a first line of defense against transmission of disease and infection, e.g., in some implementations, a medical health care blanket of this disclosure can incorporated durable antimicrobial properties that assist patients to avoid contracting germs and/or bacteria, and thus create a more sanitary environment.
Antimicrobial fabrics of the disclosure, e.g. in the form of blankets and/or in the form of bed sheets, pillow covers, etc., can also be a factor in achieving health care objectives such as keeping the entire environment surrounding a medical patient (or other user) free, or at a reduced level, of infectious disease bacteria.
The details of one or more implementations of the disclosure are set forth in the accompanying drawings and in the description below. Other features, objects, and advantages of the disclosure will be apparent from the description and drawings, and from the claims. DESCRIPTION OF DRAWINGS
FIG. 1 is a perspective view of a medical health care blanket of the present disclosure, disposed upon a bed, e.g. in a hospital or other health care facility.
FIG. 2 is a somewhat diagrammatic side section view of the medical health care blanket of FIG. 1.
FIG. 3 is a similar somewhat diagrammatic side section view of another medical health care blanket of the disclosure.
Like reference symbols in the various drawings indicate like elements.
DETAILED DESCRIPTION
Referring to FIG. 1, a medical health care blanket 10, e.g. for use in the health care industry, is shown on a patient bed 12, e.g., in a hospital or other long-term patient care facility. Over time, the blanket 10 must undergo frequent and repeated industrial laundering cycles under extreme conditions, including of high temperature water, disinfecting agents (e.g., hydrogen peroxide or bleach), and high pH, for reasons of sanitation and in efforts to combat transmission of disease and other unhealthy conditions. This may be a particular concern in environments where the bed and blanket are subject to use sequentially for multiple patients, e.g. in a hospital or other short term case situation.
Referring next to FIG. 2, the medical health care blanket 10 is formed of suitable polymer, e.g. 100% polyester, or polypropylene, or polyamide material, or combinations thereof (e.g., micro-denier polyester material), e.g. in a double face knit configuration, with a knit body 14 and velour/velour finish surfaces 16, 18. The double face knit material can be, e.g. in reverse plating terry sinker loop circular knit, double needle bar warp knit, or brushed woven. Double face circular knit material can be produced by raising (e.g., napping) or by cut loop (off-line or on the knitting machine) of terry sinker loop. The raised surface yarn (or pile yarn) of the material can be polyester flat yarn, e.g. round, trilobal, delta, or other profile, or textured yarn. The pile yarn can also be broader than microdenier fibers (e.g., 0.3 to 3.0 dpi). The fibers of the medical health care blanket polymer material may be treated with an antistatic chemical to reduce electrostatic build up that can be annoying to a user, e.g. due to uncomfortable static discharge, and/or that can interfere with operation of medical and/or communications devices in the vicinity. An example of a commercial antistatic chemical for treating fabric is Lurotex A25 (a nonionic polyamide derivative available commercially from BASF Aktiengesellschaft, of Ludwigshafen, Germany), applied, e.g., at 2% to 4%.
The medical health care blanket 10 of the disclosure offers multiple advantages during use a medical care environment, e.g., as compared to conventional or traditional hospital blankets formed of cotton or a blend of polyester and cotton. For example, the medical health care blanket 10 exhibits improved thermal insulation properties, lower water retention, a longer usable life, and antimicrobial properties for resisting
transmission of disease and other medical conditions. All of these features will be discussed in more detail below.
In particular, the medical health care blanket 10 of the disclosure has relatively better thermal insulation efficiency properties than conventional hospital blankets made from cotton or a blend of polyester and cotton. For example, the medical health care blanket 10 of the disclosure has CLO of 0.812 (compared to CLO of 0.467 for a traditional hospital blanket) and a CLO-to-weight ratio of 0.140 (compared to 0.045 for traditional hospital blankets). The medical health care blanket 10 is also thicker, e.g. having a thickness, T, of about 0.154 inch (as compared to a thickness of about 0.086 inch for a traditional hospital blanket). A medical health care blanket 10 of the disclosure is also relatively lighter in weight than traditional hospital blankets, e.g. the medical health care blanket 10 of the disclosure may weigh about 5.8 ounces/yard2 as compared to about 10.3 ounces/yard2 for a traditional hospital blanket. These features in
combination contribute to a medical health care blanket 10 allowing a patient increased comfort of a covering of relatively lighter weight, and with increased warmth and insulation of the thicker and thermally more efficient material, while also providing durable antimicrobial properties that contribute to a more sanitary environment through enhanced resistance to contracting germs and/or bacteria. The medical health care blanket 10 of the disclosure also retains much less water during laundering, e.g. as compared to traditional hospital blankets formed of cotton or a blend of polyester and cotton. For example, the medical health care blanket 10 of the disclosure retains about 31% less water as compared to a traditional hospital blanket formed of cotton or a blend of polyester and cotton. As a result, the drying time for the medical health care blanket 10 following laundering is approximately 70% of that required for drying a traditional hospital blanket of cotton or a blend of polyester and cotton. The reduced water retention properties, resulting in shorter drying times, has the additional, particularly beneficial, effect of significantly lowering energy consumption and costs for the health care facility.
The micro-denier polymer blanket 10 of the disclosure also exhibits greater longevity (i.e., longer useful life), e.g. as compared to traditional hospital blankets formed of cotton or a blend of polyester and cotton, through repeated industrial laundering cycles under harsh conditions, including high water temperatures and exposure to bleach and high pH environments. For example, a traditional hospital blanket made of cotton or a blend of polyester and cotton can be expected to degrade and disintegrate to a point of being unusable within a just a few months of first use. In contrast, the medical health care blanket 10 of the disclosure, formed of micro-denier polymer material, can be expected to have significantly longer usable life, e.g., extending 12 months or longer. Additionally, forming the medical health care blanket 10 of polyester material allows the blanket to be provided in a range of colors that remain stable (e.g., will not substantially fade or become discolored) during repeated industrial laundering cycles.
Also, in order to reduce or minimize transmission of drug resistant germs, e.g. MRS A (Methicillin-Resistant Staphylococcus Aureus), the medical health care blanket 10 of the disclosure has been developed with a capacity for killing GRAM-positive and/or GRAM-negative bacteria, even after numerous industrial laundering cycles. For example, in antimicrobial performance tests described in more detail below, a sample medical health blanket of the disclosure continued to show an acceptable level of antimicrobial performance after 50 industrial laundering cycles. Similar performance is projected for antimicrobial fabrics of the disclosure, e.g., after at least 100 industrial laundering cycles, or after at least 150 industrial laundering cycles, or after at least 200 industrial laundering cycles. The medical heath care blanket 10 can serve as a first line of defense in a hospital, health care facility, or other similar environment, protecting the patient from contact transmission, droplet transmission, airborne transmission, etc. The medical health care blanket 10, having a raised surface of, e.g., polyester fiber, and containing antimicrobial agents for killing GRAM-positive and/or GRAM-negative bacteria, can provide an important enhancement to reducing nosocomial infections, such as MRSA and/or klebsiella pneumonia.
Examples of types of antimicrobial agents are described, e.g., in "Disinfection, Sterilization, and Preservation", edited and partially written by Professor Seymour S. Block, Fourth Edition, published 1991 by Lea & Febiger, Pennsylvania, and in "Recent Advances in Antimicrobial Treatments of Textiles", Y. Gao and R. Cranston, TEXTILE RESEARCH JOURNAL Vol. 78(1), p 60-72 (2008), a review of antimicrobial treatment of textiles. The complete disclosures of both references are also incorporated herein by reference. Described below are examples of a few categories of antimicrobial agents that can be applied to polyester and other polymeric fibers of the medical health care blanket 10 in order to reduce transmission of infectious disease in the health care environment where the blanket 10 is employed.
(Zinc) Peroxide Antimicrobial Agents
In one implementation, a medical health care blanket 10 of the disclosure is treated with zinc oxide, zinc hydroxide, zinc peroxide, and/or zinc salt (which has very low solubility and, by itself, has mild antimicrobial properties), e.g. zinc oxide and/or zinc salt, to create a system for providing a peroxide antimicrobial agent, e.g. as described in Toreki et al. U.S. Patent Publication No. 2011/0171280, published July 14, 2011, and assigned on its face to Quick-Med Technologies, Inc., of Gainesville, Florida, the complete disclosure of which is incorporated herein by reference. In particular, during spinning of the polyester fibers that will be formed, e.g., by knitting, into the medical health care blanket 10 of the disclosure, sequestering agents, e.g. zinc oxide, zinc hydroxide, zinc peroxide, and/or zinc salt, e.g. zinc oxide and/or zinc salt, are added to the polymeric blend, along with a binding agent, e.g. an acrylate (or polyurethane). The sequestering agent can be a complex of metal oxide, metal salt, metal peroxide, and hydrogen peroxide. The metal can be zinc (or magnesium or zirconium). The metal salts can contain chloride or nitrate (or acetate or bromide). The complex has low solubility and it is deposited on the textile fabric or entrapped within the binder. In the medical health care blanket 10, the binding agent on the surfaces of the polyester or other polymeric fibers then serves to secure the sequestering agents, e.g. against early dislodgement during repeated industrial laundering cycles. The binder, based, e.g., on acrylate, can entrap peroxide and contributes to the antimicrobial property. The binder binds the metal oxide, metal peroxide, and/or metal salt to increase antimicrobial durability to withstand industrial laundering cycles. The sequestering agents, in turn, serve to sequester (or immobilize) the antimicrobial agent, i.e. the peroxide, on the surfaces of the blanket fibers, thereby to provide durable antimicrobial protection.
In another implementation, the medical health care blanket 10 is formed of polyester, polypropylene, or polyamide (or other suitable polymer or polymer blend) fibers that incorporate particles of sequestering agent, e.g. zinc oxide and/or zinc salt, of small characteristic dimension, e.g. particles of micro or nano dimension. The zinc oxide and/or zinc salt particles may be added to feed of polymer chips or polymer melt during extrusion of the polymer fibers. In this manner, the zinc oxide and/or zinc salt particles are distributed (e.g., randomly) throughout the cross section of the fiber.
Alternatively, a relatively greater distribution or concentration of particles of sequestering agent (zinc oxide and/or zinc salt) can be preferentially provided in an outer (sheath) layer of the polymer fibers, and/or even exposed on the outer surface of the polyester fibers. For example, the polymer fibers formed, e.g., using core/sheath spinning technology may have the form of bicomponent fibers having an outer sheath with a relatively high concentration of zinc oxide and/or zinc salt particles, and an inner core with a relatively lower concentration of, or little or no, zinc oxide and/or zinc salt particles.
As described above, the medical care blanket 10 having polyester polymer fibers incorporating particles of zinc oxide and/or zinc salt, e.g. on the surface, in the outer layer, and/or distributed throughout the cross section, can be treated with a disinfecting agent, such as hydrogen peroxide or percarboxylic acid, to produce a complex system of zinc oxide and/or zinc salt, zinc peroxide (generated by exposure of the zinc oxide and/or zinc salt to the hydrogen peroxide), as well as the hydrogen peroxide sequestered at a controlled pH on the surface of the textile fabric, e.g. the fibers of a raised surface blanket or linen. For example, the disinfecting agent may be applied to the fabric, e.g. in a textile mill, during an industrial laundering cycle, or as a separate step before or after the industrial laundering cycle. The treated medical care blanket 10, after this hydrogen peroxide recharging or reloading process, will typically have good antimicrobial properties and with high durability.
During use extended use and repeated industrial laundering cycles, the
antimicrobial properties and capabilities of medical health care blanket 10 can be expected to degrade as the antimicrobial agent becomes depleted, e.g. is washed or worn away. However, according to the present disclosure, industrial laundering of the medical health care blanket 10, with application of an aqueous solution including hydrogen peroxide, which is routinely used as a disinfecting agent, including processing in a textile mill (during industrial laundering, or separately, before or after laundering), serves to recharge the sequestering agents with peroxide from the laundering solution, thus restoring the antimicrobial properties of the medical health care blanket 10. Use of hydrogen peroxide as a disinfecting agent (e.g., rather the bleach) reduces discoloration of colored medical health care blankets during repeated industrial laundering cycles. Industrial laundries of the type discussed are also moving away from use of chlorine as a disinfectant (for example, for environmental reasons) and moving to peroxide as an alternative.
Silver Based Antimicrobial Agents
Silver-based antimicrobial agents can also be used in medical health care blankets 10 of the disclosure. The silver can be in the form of, e.g. silver ions, silver ions embedded in Zeolite, and/or silver deposited on the surface of polyester or other suitable polymeric fibers by reduction-oxidation process. Any of these silver treatments can be combined with a polymer, e.g. polyester, nylon, and/or acrylic, during fiber manufacture. The silver-loaded fibers can then be blended with untreated synthetic yarn in simple form to make blended spun yarn, or can be blended in filament form to be commingled with untreated synthetic filament yarn. The silver-loaded fibers can also be added to the knit construction with untreated synthetic filaments.
The silver ions loaded into the fibers leach out of the fiber material over time, migrating towards bacteria to react with its cell DNA and/or during repeated industrial laundering cycles. Binders may be added to the silver ion during application in order to control, i.e. reduce, the level of leaching during laundering. Selection of a binder is crucial to improvement of the durability and longevity of the medical health care blanket 10 through repeated cycles of industrial laundering. The binder, mixed with the antimicrobial agent, can be applied by pad as is, or with an added cross-linking agent. After application, the treated fabric is dried and cured at 375°F for 60 seconds. The binder must be stable under the conditions of industrial laundering, e.g. temperatures of 160°F, alkaline PH 10 ± 1, and bleaching chemicals (peroxide, Clorox, ozone). A preferred binder is based on acrylate, but other binders based on polyurethane, silicon, etc. will be effective as well.
Quaternary Ammonium Silane-Based Antimicrobial Agents
The family of quaternary ammonium silane (QAS) chemicals can also be used as antimicrobial agents in medical health care blankets 10 of the disclosure. One suitable antimicrobial agent of this family is 3 (trimethoxysilyl) propyldimethyl octadecyl ammonium chloride. Trimethoxy silyl reacts with another trimethoxy silyl, or with the hydroxyl, carboxylic, amine, or amide on the fiber surface, and the octadecyl with the quaternary ammonium will puncture and rupture the outer wall of a bacteria cell. This antimicrobial agent type does not leach out of the fibers in order to penetrate the bacteria, so the effective useful life of the medical health care blanket 10 is extended, and thus enhanced. Further enhancement of the durability of the medical health care blanket through repeated industrial laundering cycles (e.g. at 160°F with high PH and exposure to disinfecting agents, such as peroxide or bleach) may be obtained by addition of a chemical binder, with or without a cross-linking agent.
Polyhexamethylene Bigunide (PHMB) Antimicrobial Agents
Polyhexamethylene bigunide (PHMB) can also be used as a antimicrobial agent in medical health care blankets 10 of the disclosure. This agent may be applied to polyester or other suitable polymeric fabric by patting with addition of binder, and with or without cross linking agent.
Other types of disinfectant chemicals include, e.g., peracetic acid, ozone, etc., which can recharge the metal salt or metal oxide to generate the complex containing metal peroxide as an antimicrobial agent.
The antimicrobial agents discussed above have broad "killing" capacity, targeting no specific moiety in the cell metabolism, and, as a result, will not generate bacteria resistance to antibiotic agents (so-called "super bug"). Transmission of drug resistant bacteria (like MRSA) can occur by contact transmission (direct or indirect), as well as by airborne transmission.
Antimicrobial Performance Testing
Several standard testing methods are available for evaluation of the effectiveness of antimicrobial treatment of medical health care blankets as described herein. For example, ISO 2073 is a standard quantitative test method for determining antimicrobial activity of immobilized antimicrobial agents. Other or additional testing methods may also be utilized. For example, ATCC 147 is a form of qualitative testing, and ASTM E 2149-01 ("Shake Flask" test) tests antimicrobial activity of immobilized antimicrobial agents under dynamic contact conditions.
A sample of the medical health care blanket 10 of this disclosure (Material Sample Reference No. 08241 IB) was treated with the zinc-based peroxide antimicrobial agent system discussed above. Testing of antimicrobial properties was conducted on an unlaundered sample, and on a sample that had undergone 100 industrial laundering cycles of 160°F for 10 minutes each cycle. The samples were tested according to ISO 20743, AATCC 100, and JIS L 1902, with two different bacteria in different inoculum concentrations (shown in Table 1).
Table 1
Figure imgf000014_0001
*GRAM-positive
**GRAM-negative
Both the treated unlaundered and the treated laundered test samples were found to have good antimicrobial properties. Test results for the samples are provided below in Table 2.
Table 2
Figure imgf000014_0002
* * denotes full kill
As shown in these test results, the treated laundered sample maintained good antimicrobial properties and performed nearly as well as the treated unlaundered sample, even after undergoing 100 industrial laundering cycles. A number of embodiments of the disclosure have been described. Nevertheless, it will be understood that various modifications may be made without departing from the spirit and scope of the disclosure. For example, referring to FIG. 3, a medical health care blanket 10 Of the disclosure may have a knit body 14' with only a single raised or fleece surface 16'. The medical health care blanket can also be formed of a blend of polyester (or other suitable polymer) and natural fibers (e.g., cotton). Also, the zinc oxide or low solubility zinc salt of the rechargeable sequestering agent can be substituted by, e.g., magnesium oxide, zirconium oxide, or low solubility salt of magnesium or zirconium.
Also, in other implementations, the yarn or fibers of the textile fabric may be chemically treated, e.g. with 4% Lurotex A-25 (available from BASF Aktiengesellschaft, of Ludwigshafen, Germany), a nonionic polyamide derivative that improves moisture transport in textiles composed of synthetic fibers, to increase the moisture content on the face of the fabric, to impart antistatic and soil release properties, as well as absorbing moisture from the air, e.g., to release hydrogen peroxide from sequestration on the surface of the fabric.
Use of the antimicrobial blanket fabric of the disclosure in other environments, e.g., in nursing homes, correctional facilities, hospitality environments (e.g., hotels, motels, cruise ships, etc.), dormitories, military facilities, schools, daycare facilities and kindergartens, private homes, and the like, is also contemplated. Referring again to FIG. 1, other uses of antimicrobial fabrics of the disclosure are also contemplated. For example, in other implementations, use of the antimicrobial fabric material described herein for particular use in medical health care blankets might be expanded, e.g., to include bed sheets 22, which are generally formed woven fabric of cotton and/or blends of polyester (or other suitable polymer) and cotton, which, in fabrics of the present disclosure, could include relatively higher polyester (or other polymer) content in the polyester/cotton blends. Antimicrobial fabrics of the disclosure might also be used, e.g., for other products in the home consumer textile market, such as pillow cases 24, window coverings 26, floor coverings 28, etc., all for use in medical health care environments (as shown) as well as other environments, and also for use in other types of products and/or markets. Accordingly, other embodiments are within the scope of the following claims.

Claims

WHAT IS CLAIMED IS:
1. A medical health care blanket comprising:
a fabric of micro-denier polymer fibers having at least one raised surface, and an antimicrobial system applied to the fabric and having durable antimicrobial properties after at least 50 industrial laundering cycles.
2. A medical health care blanket of claim 1, wherein the polymer of the polymer fibers is selected from among polyester, polypropylene, polyamide, and combinations thereof.
3. The medical health care blanket according to claim 1, wherein the antimicrobial system has durable antimicrobial properties after at least 100 industrial laundering cycles.
4. The medical health care blanket according to claim 1, wherein the antimicrobial system has durable antimicrobial properties after at least 150 industrial laundering cycles.
5. The medical health care blanket according to claim 2, wherein the antimicrobial system has durable antimicrobial properties after at least 200 industrial laundering cycles.
6. The medical health care blanket of claim 1, wherein the fabric has a double face knit configuration with velour/velour surface finishes.
7. The medical health care blanket of claim 1, wherein the antimicrobial system comprises:
an antimicrobial agent,
a rechargeable sequestering agent isolating the antimicrobial agent, and a binding agent binding the sequestering agent to surfaces of the polymer fibers.
8. The medical health care blanket of claim 7, wherein the antimicrobial agent comprises peroxide.
9. The medical health care blanket of claim 7, wherein the sequestering agent is a complex of metal oxide, metal salt, metal peroxide, and hydrogen peroxide.
10. The medical health care blanket of claim 7, wherein the rechargeable sequestering agent comprises zinc oxide, or zinc hydroxide, or zinc salt.
11. The medical health care blanket of claim 7, wherein the rechargeable sequestering agent comprises zinc oxide and/or zinc salt.
12. The medical health care blanket of claim 9, wherein the metal is selected from the group of: zinc, magnesium, and zirconium.
13. The medical health care blanket of claim 9, wherein the metal salt is selected from the group of: chloride, nitrate, acetate, and bromide.
14. The medical health care blanket of claim 7, wherein the sequestering agent is rechargeable by contact with a peroxide antimicrobial agent.
15. The medical health care blanket of claim 7, where the binding agent comprises an acrylate or polyurethane.
16. The medical health care blanket of claim 1, wherein the antimicrobial system comprises:
an antimicrobial agent, and
a rechargeable sequestering agent isolating the antimicrobial agent, the rechargeable sequestering agent being incorporated in the polymer fibers as micro- dimensioned or nano-dimensioned particles.
17. The medical health care blanket of claim 16, wherein the micro-dimensioned or nano-dimensioned particles of the rechargeable sequestering agent are is distributed throughout the cross section of the polymer fibers.
18. The medical health care blanket of claim 16, wherein the micro-dimensioned or nano-dimensioned particles of the rechargeable sequestering agent are distributed in a relatively greater concentration in an outer layer of the polymer fibers.
19. The medical health care blanket of claim 17 or 18, wherein the micro- dimensioned or nano-dimensioned particles of the rechargeable sequestering agent are exposed on an outer surface of the polymer fibers.
20. A method of contributing to a sanitary health care environment, comprising:
1) providing a medical health care blanket of claim 1 having a predetermined enhanced level of antimicrobial protection, and
2) subjecting the medical health care blanket to frequent industrial laundering cycles including contact with an aqueous solution of hydrogen peroxide, thereby to recharge antimicrobial protection provided by the medical health care blanket to at least a predetermined minimum acceptable level, and
3) repeating step 2) for at least 50 industrial laundering cycles.
21. The method of claim 20, wherein the multiple industrial laundering cycles comprises at least 100 industrial laundering cycles.
22. The method of claim 20, wherein the multiple industrial laundering cycles comprises at least 150 industrial laundering cycles.
23. The method of claim 20, wherein the multiple industrial laundering cycles comprises at least 200 industrial laundering cycles.
24. A medical health care fabric material comprising:
a fabric of micro-denier polymer fibers having at least one raised surface, and an antimicrobial system having durable antimicrobial properties after at least 50 industrial laundering cycles.
25. A medical health care fabric material of claim 24, wherein the polymer of the polymer fibers is selected from among polyester, polypropylene, polyamide, and combinations thereof.
26. The medical health care fabric material of claim 24, wherein the antimicrobial system has durable antimicrobial properties after at least 100 industrial laundering cycles.
27. The medical health care fabric material of claim 24, wherein the antimicrobial system has durable antimicrobial properties after at least 150 industrial laundering cycles.
28. The medical health care fabric material of claim 24, wherein the antimicrobial system has durable antimicrobial properties after at least 200 industrial laundering cycles.
29. The medical health care fabric material of claim 24, wherein the antimicrobial system comprises:
an antimicrobial agent,
a rechargeable sequestering agent isolating the antimicrobial agent, and a binding agent binding the sequestering agent to surfaces of the polyester polymer fibers.
30. The medical health care fabric material of claim 24, wherein the antimicrobial system comprises:
an antimicrobial agent, and a rechargeable sequestering agent isolating the antimicrobial agent, the rechargeable sequestering agent being incorporated in the polymer fiber as micro- dimensioned or nano-dimensioned particles.
31. The medical health care fabric material of claim 30, wherein the micro- dimensioned or nano-dimensioned particles of the rechargeable sequestering agent are distributed throughout the cross section of the polymer fibers.
32. The medical health care fabric material of claim 30, wherein the micro- dimensioned or nano-dimensioned particles of the rechargeable sequestering agent are distributed in a relatively greater concentration in an outer layer of the polymer fibers.
33. The medical health care fabric material of claim 31 or 32, wherein the micro- dimensioned or nano-dimensioned particles of the rechargeable sequestering agent are exposed on an outer surface of the polymer fibers.
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