WO2013103204A1 - Solid composition for repelling birds - Google Patents

Solid composition for repelling birds Download PDF

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Publication number
WO2013103204A1
WO2013103204A1 PCT/KR2012/011057 KR2012011057W WO2013103204A1 WO 2013103204 A1 WO2013103204 A1 WO 2013103204A1 KR 2012011057 W KR2012011057 W KR 2012011057W WO 2013103204 A1 WO2013103204 A1 WO 2013103204A1
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Prior art keywords
algae
weight
essential oil
composition
solid
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PCT/KR2012/011057
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French (fr)
Korean (ko)
Inventor
박병권
박병관
윤효인
Original Assignee
Park Byeonggwon
Park Byeonggwan
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Application filed by Park Byeonggwon, Park Byeonggwan filed Critical Park Byeonggwon
Publication of WO2013103204A1 publication Critical patent/WO2013103204A1/en

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    • A—HUMAN NECESSITIES
    • A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N37/00—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom having three bonds to hetero atoms with at the most two bonds to halogen, e.g. carboxylic acids
    • A01N37/44—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom having three bonds to hetero atoms with at the most two bonds to halogen, e.g. carboxylic acids containing at least one carboxylic group or a thio analogue, or a derivative thereof, and a nitrogen atom attached to the same carbon skeleton by a single or double bond, this nitrogen atom not being a member of a derivative or of a thio analogue of a carboxylic group, e.g. amino-carboxylic acids
    • A—HUMAN NECESSITIES
    • A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N65/00—Biocides, pest repellants or attractants, or plant growth regulators containing material from algae, lichens, bryophyta, multi-cellular fungi or plants, or extracts thereof
    • A01N65/08—Magnoliopsida [dicotyledons]
    • A—HUMAN NECESSITIES
    • A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N25/00—Biocides, pest repellants or attractants, or plant growth regulators, characterised by their forms, or by their non-active ingredients or by their methods of application, e.g. seed treatment or sequential application; Substances for reducing the noxious effect of the active ingredients to organisms other than pests
    • A01N25/08—Biocides, pest repellants or attractants, or plant growth regulators, characterised by their forms, or by their non-active ingredients or by their methods of application, e.g. seed treatment or sequential application; Substances for reducing the noxious effect of the active ingredients to organisms other than pests containing solids as carriers or diluents
    • A—HUMAN NECESSITIES
    • A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N65/00—Biocides, pest repellants or attractants, or plant growth regulators containing material from algae, lichens, bryophyta, multi-cellular fungi or plants, or extracts thereof
    • A—HUMAN NECESSITIES
    • A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N65/00—Biocides, pest repellants or attractants, or plant growth regulators containing material from algae, lichens, bryophyta, multi-cellular fungi or plants, or extracts thereof
    • A01N65/08—Magnoliopsida [dicotyledons]
    • A01N65/22—Lamiaceae or Labiatae [Mint family], e.g. thyme, rosemary, skullcap, selfheal, lavender, perilla, pennyroyal, peppermint or spearmint
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02A—TECHNOLOGIES FOR ADAPTATION TO CLIMATE CHANGE
    • Y02A50/00—TECHNOLOGIES FOR ADAPTATION TO CLIMATE CHANGE in human health protection, e.g. against extreme weather
    • Y02A50/30—Against vector-borne diseases, e.g. mosquito-borne, fly-borne, tick-borne or waterborne diseases whose impact is exacerbated by climate change

Definitions

  • the present invention relates to a solid phase algae composition, and more particularly, it can prevent the loss in harsh environments such as high temperature and heavy rain, can be used even under severe environmental change conditions, new plant extract essential oil complex
  • the present invention relates to an environmentally friendly solid algae combatant composition that maximizes algae evacuation effect and exhibits useful algae evacuation effects in a wide range of affected areas such as telegraph poles, buildings and piers as well as orchards and abundant algae food.
  • a natural threat modeling product or a visual threat reduction product using a reflector or shiny tape As an algae control method used to protect crops and facilities from harmful algae, a natural threat modeling product or a visual threat reduction product using a reflector or shiny tape; Acoustically combative products such as alarm sounds, radio noise or ultrasonic waves; Contact products such as a protective net, a protective bag and a protective cap; And products mainly used in fruit farms such as wood vinegar, naphthalene, methyl anthranilate and anthraquinone.
  • the above methods are widely used to control algae that are harmful to fruit trees and facilities, but have many shortcomings and high costs.
  • Algae repellents which are used to protect crops and facilities from harmful algae, are largely divided into primary and secondary algae repellents.
  • Primary bird repellents are agents that prevent algae's access immediately by sight, taste, smell and touch, and have no feature of learning.
  • Secondary algae control agent is a preparation causing pain by the intake of food, means a preparation to prevent the intake of crops, etc. by the learning effect. Therefore, the secondary algae repellent is a substance that exhibits abnormal physiological and metabolic reactions when ingested, and a substance that can specifically react only with harmful birds is preferred.
  • the present inventor has disclosed a gel-like algae composition in the Republic of Korea Patent No. 10-0798290 (2008.02.04.).
  • the gel-like composition for combating algae is environmentally friendly and exerts a bird evacuation effect when applied to specific places such as telegraph poles, buildings, and piers, but when used in places where the area of damage is wide and birds feed, such as orchards
  • the present inventors can prevent the loss in the harsh environment such as high temperature and heavy rain, can be used even under severe environmental change conditions, by using a new plant extraction essential oil in combination to maximize the algae avoidance effect telegraph poles, buildings, piers
  • a new plant extraction essential oil in combination to maximize the algae avoidance effect telegraph poles, buildings, piers
  • we have developed an environmentally friendly solid algae control composition that exhibits useful algae avoidance effects in a wide range of affected areas such as orchards and very rich algae food.
  • the purpose of the present invention is to prevent the loss in the harsh environment such as high temperature and heavy rain can be used even under severe environmental change conditions, by using a new plant extract essential oil complex by maximizing algae avoidance effect telegraph pole, building
  • the present invention provides an environmentally friendly solid algae composition that exhibits a useful algal evacuation effect even in an environment where a wide range of damaged areas such as orchards and abundant algae food are abundant.
  • the present invention provides the following means.
  • the present invention 40 to 95% by weight of the curing agent, 0.05 to 20% by weight of thyme essential oil, 0.05 to 10% by weight of oregano essential oil, 0.1 to 20% by weight of citronella essential oil, 0.1 to 10% by weight spearmint essential oil, 0.1 ⁇ clove essential oil It provides a solid algae composition comprising 10% by weight, 0.2 to 20% by weight methyl anthranilate, 0.01 to 4% by weight ultraviolet absorber and 1 to 10% by weight emulsifier.
  • the curing agent is characterized in that the soap base.
  • the ultraviolet absorbent is characterized in that the hindered amine-based ultraviolet absorber.
  • the emulsifier is characterized in that the sorbitan fatty acid ester.
  • the solid algae composition according to the present invention can be prevented from being lost in the harsh environment such as high temperature and heavy rain, can be used even under severe environmental change conditions, algae avoidance effect by using a new plant extract essential oil complex
  • By maximizing the utility poles, buildings, bridges, as well as orchards, such as orchards have a wide range of damage and algae abundant food conditions have the advantage of having a good bird evasion effect.
  • 1 is a graph showing the number of attempts to land cross-sisters in a feeding container installed with an oregano essential oil-containing composition
  • Figure 2 is a graph showing the number of attempts to land the cross in the feeding container installed with the composition containing the thyme essential oil
  • Figure 3 is a graph showing the number of attempts to land the cross in the feeding container with the composition containing the cloves essential oil
  • Figure 4 is a graph showing the number of attempts to land the cross sister in the feeding container installed with the composition containing the spearmint essential oil
  • FIG. 5 is a graph showing the number of attempts to land the cross sister in a feeding container installed with a composition containing citronella essential oil
  • FIG. 6 is a graph showing the number of attempts to land the cross sisters on the perch provided with a solid bird repellent agent according to the present invention
  • FIG. 9 is a graph showing the damage rate of pear tree when the gel-based algae combatant composition is installed (C) and the solid algae exterminator (D) in the fruit farm.
  • the present inventor has filed a gel-like algae composition (Korean Patent No. 10-0798290) comprising cinnamon essential oil and peppermint essential oil.
  • a gel-like algae composition comprising cinnamon essential oil and peppermint essential oil.
  • the damage area is wide, such as an orchard, and is characterized by being able to sufficiently exert the algal evacuation effect even in a place with a lot of bird food.
  • Solid phase algae composition of the present invention Solid phase algae composition of the present invention
  • curing agent 40 to 95% by weight of curing agent, 0.05 to 20% by weight of thyme essential oil, 0.05 to 10% by weight of oregano essential oil, 0.1 to 20% by weight of citronella essential oil, 0.1 to 10% by weight of spearmint essential oil, 0.1 to 10% by weight of clove essential oil, 0.2 to 20% by weight of methyl anthranilate, 0.01 to 4% by weight of ultraviolet absorber and 1 to 10% by weight of emulsifier.
  • the solid algae composition of the present invention comprises a main component and a subcomponent, the main component including thyme essential oil, oregano essential oil, citronella essential oil, spearmint essential oil, cloves essential oil, methyl anthranilate and ultraviolet absorbent, Includes a curing agent and an emulsifier.
  • the thyme essential oil which is one of the main components of the present invention, contains thymol as the main active ingredient, and may exhibit a repelling effect due to olfactory repelling effect and eye irritation effect due to a strong irritating volatile scent. In addition, it has the advantage of strong initial stimulation, not the repelling effect by contact or ingestion, and also has excellent anti-bacterial, anti-fungal and repelling effect on pests, preventing external pollution or decay of the composition after the installation of algae repellents. The effect can be suppressed to be reduced.
  • the thyme essential oil is used in 0.05 to 20% by weight, preferably 1 to 15% by weight of the total composition.
  • the oregano essential oil contains carvacrol as the main active ingredient, and may exhibit a repelling effect due to olfactory repelling effect and eye irritation effect due to a strong irritating volatile scent.
  • it has the advantage of strong initial stimulation, not the repelling effect by contact or ingestion, and also has excellent anti-bacterial, anti-fungal and repelling effect on pests, preventing external pollution or decay of the composition after the installation of algae repellents. The effect can be suppressed to be reduced.
  • the oregano essential oil is used at 0.05 to 10% by weight, preferably 0.5 to 5% by weight of the total weight of the total composition.
  • the oregano essential oil when used in less than 0.05% by weight of the total composition of the total antimicrobial and antifungal effect is reduced, it may cause contamination by bacteria and fungi of the composition, when used in excess of 10% by weight decreases the hardness This can cause problems.
  • the citronella essential oil which is one of the main components of the present invention, contains citronellal as the main active ingredient, and may exhibit a repelling effect due to the olfactory repelling effect and the mucosal irritant effect due to the irritating volatile fragrance. In addition, it has the advantage of strong initial stimulation, not the repelling effect by contact or ingestion, and also has excellent anti-bacterial, anti-fungal and repelling effect on pests, preventing external pollution or decay of the composition after the installation of algae repellents. The effect can be suppressed to be reduced.
  • the citronella essential oil is used at 0.1 to 20% by weight, preferably 1 to 12% by weight of the total weight of the total composition.
  • citronella essential oil when citronella essential oil is used in less than 0.1% by weight of the total amount of the total composition, the antimicrobial and antifungal effects may be reduced, which may cause contamination by bacteria and fungi of the composition. Decreasing problems can be caused.
  • the spearmint essential oil one of the main components of the present invention, contains carbon (Carvone) as a main active ingredient, and may exhibit a repelling effect due to olfactory repelling effect and eye irritation effect due to a strong irritating volatile scent.
  • carbon Carvone
  • it has the advantage of strong initial stimulation, not the repelling effect by contact or ingestion, and also has excellent anti-bacterial, anti-fungal and repelling effect on pests, preventing external pollution or decay of the composition after the installation of algae repellents. The effect can be suppressed to be reduced.
  • the spearmint essential oil is used in 0.1 to 10% by weight, preferably 1 to 6% by weight of the total weight of the composition.
  • spearmint essential oil when used in less than 0.1% by weight of the total composition of the total antimicrobial and antifungal effect is reduced, it may cause contamination by bacteria and fungi of the composition, when used in excess of 10% by weight of hardness Problems may arise.
  • the clove essential oil contains eugenol as the main active ingredient, and may exhibit a repelling effect due to olfactory repelling effect and eye mucosal irritant effect due to a strong irritant volatile fragrance.
  • the initial stimulus not the repellent effect by contact or ingestion, is strong, and also has an excellent antibacterial and antifungal effect and a repellent effect against pests, thereby preventing external pollution or decay of the composition after the installation of the bird repellent, The effect of can be suppressed from being reduced.
  • the clove essential oil is used at 0.1 to 10% by weight, preferably 1 to 6% by weight of the total weight of the composition.
  • the clove essential oil when used in less than 0.1% by weight of the total composition of the total antimicrobial and antifungal effect is reduced, it may cause contamination by bacteria and fungi of the composition, when used in excess of 10% by weight of hardness Problems may arise.
  • the methyl anthranilate one of the main components of the present invention, is a Concord grape extract, and the fragrance is a pale or dark yellow liquid with grape, orange and neroli flavours.
  • Methyl anthranilate is a food additive registered with the US EPA and is known to irritate the eyes, nasal cavity or mucous membranes when ingested by algae. Algae repellents based on methyl anthranilate have already been commercialized, but the strength of the stimulus is relatively weak and the duration of the effect is 6-7 days.
  • methyl anthranilite in order to overcome the disadvantages of methyl anthranilite and to maximize the effect of stimulating the eye or nasal mucosa of the main action of algae, in combination with other main components to provide a single algae control composition.
  • the methyl anthranilate is used at 0.2 to 20% by weight, preferably 2 to 10% by weight of the total weight of the total composition.
  • the methyl anthranilate when used in less than 0.2% by weight of the total composition of the total composition does not exhibit the algal repellent effect, when used in excess of 20% by weight may cause toxic problems such as severe eye irritation and skin irritation. .
  • the ultraviolet absorber may have an effect of detecting an algae-treated region from a distance from an algae having a vision in the ultraviolet region, and may be affected by the aroma, ingestion, or contact of the algae extinguishing agent. It can cause the memory of discomfort and maximize the avoidance of the area.
  • the ultraviolet absorber used in the present invention is benzophenone-based, benzotriazole-based, cyanoacraylate-based, hindered amine-based, oxanilide-based and salicylic acid. It is selected from the group consisting of a salicylate system, and preferably a hindered amine system is used.
  • the ultraviolet absorber is used in 0.01 to 4% by weight, preferably 0.1 to 2% by weight of the total weight of the composition. At this time, when the ultraviolet absorber is used in less than 0.01% by weight of the total weight of the composition, the ultraviolet absorbing effect is weak, and even when used in excess of 4% by weight, no significant increase in the algal repelling effect is observed.
  • Subcomponents of the solid algae combating composition according to the present invention include a curing agent and an emulsifier.
  • the conventional gel-like algae composition has a problem that the gel-like algae composition is lost in a harsh environment such as high temperature and heavy rains, in the present invention, the solid algae to prevent loss or loss even under severe environmental changes It is characterized by the preparation of the combating composition.
  • a soap base is used, and the soap base promotes the hardening of the composition for combating algae and increases the hardness, so that moisture penetrates into the composition for combating algae in a wet climate such as snow or rain. Maintaining stability of the composition for combating algae by preventing the loss or denaturation of the main component, and acts to maintain the algae avoidance effect.
  • the curing agent is used 40 to 95% by weight, preferably 70 to 90% by weight of the total weight of the total composition.
  • the soap base is used in the manufacture of a conventional soap, it is possible to use a commercially available product.
  • the soap base may be, for example, an alkaline product obtained by directly saponifying or neutralizing fat or oil selected from animal or vegetable fats and oils such as tallow, palm, palm, palm kernel oil, etc. with caustic soda (NaOH) or caustic potassium (KOH). Fatty acid salts can be used.
  • sorbitan fatty acid esters which are variously used as emulsifiers and dispersants for pigments, printing inks, paints, textile preparations, lubricating oils, etc. are used for industrial purposes, and emulsifiers are plant essential oils and methyl anthranyl which are main components of the composition for combating algae.
  • the rate is used for the purpose of uniformly dispersing in the whole composition.
  • the sorbitan fatty acid ester is one or more selected from the group consisting of sorbitan monolaurate, sorbitan monopalmitate, sorbitan monooleate, sorbitan monostearate and sorbitan monobehenate, depending on the type of fatty acid Mixtures can be used.
  • sorbitan monooleate is used.
  • the emulsifier is used in 1 to 10% by weight, preferably 2 to 5% by weight of the total weight of the composition. In this case, when the emulsifier is used in less than 1% by weight of the total weight of the total composition, it may not be evenly mixed with the present composition by reducing the emulsification of thyme essential oil, origano essential oil, citronella essential oil, spearmint essential oil and clove essential oil. When used in excess of%, the hardness of the composition may be reduced, which may cause a problem that the algal repelling effect and the loss inhibiting effect of the composition are reduced.
  • a composition containing an oregano essential oil As the soap base, TEA (triethanolamine) -free transparent soap base manufactured by Sino Oil Co., Ltd. was used.
  • the composition containing the origano essential oil was molded so as to have a width ⁇ length ⁇ height of 18 ⁇ 7 ⁇ 5 mm to prepare an algae repellent.
  • the cross-border of the Sparrow-leaved beak family was used to confirm the effect of avoiding birds on a laboratory scale.
  • the cross sisters are widely bred in Korea as breeding tanks, so they are easy to use in experiments.
  • each algae repellent prepared in Preparation Examples 1 to 5 was attached to the upper portion of the feed container. After one week of purifying under laboratory conditions, a video camera was used for 24 hours to observe the number of accesses to the feeding container and the adverse reactions caused by contact of the composition.
  • each plant extract essential oil composition showed abnormal behavior of squat, grazing and quick beak trimming.
  • each plant extract essential oil shows the repellent effect of the algae.
  • Thyme essential oil, oregano essential oil, citronella essential oil, spearmint essential oil, cloves essential oil and emulsifier were added to the mixer, mixed evenly, and then mixed with UV absorber and methyl anthranilate. Then, the mixture was mixed and stirred in a melted soap base by heating, and then cooled to a temperature of 20 ° C. to prepare a solid algae composition.
  • As the soap base TEA (triethanolamine) -free transparent soap base manufactured by Sino Oil Co., Ltd. was used.
  • the solid algae combatant composition was molded to have a width ⁇ length ⁇ height of 25 ⁇ 25 ⁇ 40 mm to form a solid algae repellent.
  • each component is 0.5% by weight of thyme essential oil, 0.5% by weight of oregano essential oil, 1% by weight of citronella essential oil, 0.5% by weight of spearmint essential oil, 0.3% by weight of clove essential oil, 10% by weight sorbitan monooleate, 0.2 weight percent Ciba ® TINUVIN ® 123, 5 weight percent methyl anthranilate and 82 weight percent soap base were used.
  • the algae repellent effect of the solid algae repellent prepared in Examples 1 to 3 was confirmed on the laboratory scale of the cross-tailed family of the Sparrow beak family with high activity. After installing the solid algae repellent prepared in Examples 1 to 3 to the perch, the number of landings and behavioral abnormalities of the sisters were observed on the perch.
  • the solid algae repellent prepared in Example 3 has excellent physical properties such as the effects of hardness, temperature, and moisture, and when installed in fruit trees of fruit farms in the open air, in the natural environment such as rain or wind.
  • the loss of algae was found to be the least.
  • the cross-border of the Sparrow-leaved beak family was used to confirm the effect of avoiding birds on a laboratory scale.
  • the cross sisters are widely bred in Korea as breeding tanks, so they are easy to use in experiments.
  • test box was used for the width ⁇ length ⁇ height 150 ⁇ 50 ⁇ 50 cm, free feed and negative water.
  • the solid algae repellent prepared in Example 3 was attached to the perch. After a one-week purifying period under laboratory conditions, the number of landings and abnormal behaviors of the roosts were observed using a video camera for 24 hours.
  • Visual behavior of the target algae due to skin contact, taste, and aroma of the test substance may be affected by wiping, head shaking, hairlorection, quick-preening, and contact. The site was judged to shake violently and the reaction of algae was observed.
  • the animals exposed to the solid bird extinguishing agent for 24 hours were transferred to a breeding box without the solid bird extinguishing agent and purified for 1 week. After confirming the normal flight activity, it was moved to the breeding box installed with solid bird repellent and observed the number of times of landing on the perch and abnormal behavior by using a video camera for 24 hours.
  • the exposure of solid algae repellents was repeated four times at weekly intervals to confirm the learning effects of algae and adaptation of algae repellents.
  • Visual behavior of the target algae due to the contact and scent of the test substance can be affected by wiping, head shaking, piererection, quick-preening and contact areas. Judging by shaking or the like, the reaction of the algae was observed.
  • the solid-state algae control composition of the present invention was not observed by repeated exposure, it can be seen that exhibiting excellent algae avoidance effect by the learning effect.
  • the experiment site of the fruit farm was not a plain but a fruit tree located in a mountain field, which is a very close terrain to the mountain, and was easily accessible to wild birds. In spite of the damage caused by wild birds in the normal place, the bird was using damage to bird damage, but it was suffering from the continuous invasion of wild birds.
  • the place (B) where no algae repellent was installed during the period of August 2011 to October 2011 (3 months) was used in the apple trees as often as the wild birds. Invaded and damaged. At this time, out of 103 trees of wild birds attacked, 98 trees were injured or fallen, resulting in a 95.1% damage rate. These fruit trees averaged about 5 to 7 losses per apple tree.
  • the solid algae composition of the present invention constitutes a complex mixture of new harmful algae repellents and shows excellent algae control effect, and the repellents are more stabilized by minimizing the loss of the formulation to the external environment such as temperature and humidity.
  • the formulation was strengthened to enhance algal evacuation efficacy.
  • Cinnamon essential oil, peppermint essential oil, and an emulsifier were added to the mixer and mixed evenly, followed by kneading by adding a UV absorber and methyl anthranilate. Finally, polybutane and grease were added and mixed sufficiently to prepare a gel algae composition.
  • each component is 65% by weight of polybutane, 25% by weight of grease, 0.5% by weight of Ciba ® TINUVIN ® 99-2, 4% by weight of methyl anthranilate, 1.5% by weight of cinnamon essential oil, 3% by weight of peppermint essential oil and 1 wt% of sorbitan monooleate was used.
  • Gel-based algae control composition including cinnamon essential oil and peppermint essential oil for wild birds such as magpies, pigeons, and straight-eyed copper that damages fruit trees in fruit farms in Cheonan, Korea, where pears are grown.
  • Experiments were conducted to compare the efficacy of the algal combat composition. At this time, for an outdoor experiment, a comparison experiment was conducted for one month in a pear tree field of about 600 pyeong on a singer farm.
  • 30 g of the algae control composition prepared in Comparative Example 1 was placed in a plastic container in a pear tree field (C area, 49 pear trees) of about 300 pyeong and installed on a branch of three pears per tree.
  • Example 4 the solid algae repellent prepared in Example 4 was placed in a pear tree field (51 D pear trees) of about 300 pyeong in a non-woven container and installed on a branch of three pears per tree, and then invaded by wild birds. Damage was observed.
  • a pear tree field 51 D pear trees
  • the experiment site of the fruit farms is a plain area where wild birds are easily accessible, and it was a place where wild birds were normally damaged. there was.
  • the solid algae combatant composition according to the present invention includes five new plant-derived essential oils, through the outdoor clinical trials that the algal repellency effect is superior to the conventional gel-like algae control composition containing cinnamon essential oil and peppermint essential oil. Confirmed.

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  • Agricultural Chemicals And Associated Chemicals (AREA)

Abstract

The present invention relates to a solid composition for repelling birds, wherein the composition is technically characterized by comprising a hardener, refined thyme oil, refined oregano oil, refined citronella oil, refined spearmint oil, refined dried clove bud oil, methyl anthranilate, a UV absorbent, and an emulsifier, and the composition can be used in drastically changing environmental conditions and can be effective even in conditions in which damaged areas are broad and food for birds is abundant by preventing losses in a poor environment.

Description

고상의 조류퇴치 조성물Solid Algae Fighting Composition
본 발명은 고상의 조류퇴치 조성물에 관한 것으로서, 보다 상세하게는 높은 온도 및 집중호우와 같은 열악한 환경에서 손실되는 것을 방지할 수 있어 심한 환경의 변화 조건에서도 사용할 수 있으며, 새로운 식물추출 정유를 복합적으로 사용함으로 조류기피효능을 극대화하여 전신주, 건물, 교각뿐만 아니라 과수원과 같이 피해지역이 광범위하고 조류의 먹이가 매우 풍부한 환경에서도 유용한 조류기피효과를 발휘하는 환경 친화적인 고상의 조류퇴치 조성물에 관한 것이다.The present invention relates to a solid phase algae composition, and more particularly, it can prevent the loss in harsh environments such as high temperature and heavy rain, can be used even under severe environmental change conditions, new plant extract essential oil complex The present invention relates to an environmentally friendly solid algae combatant composition that maximizes algae evacuation effect and exhibits useful algae evacuation effects in a wide range of affected areas such as telegraph poles, buildings and piers as well as orchards and abundant algae food.
오랫동안 인류와 공존해 온 야생조류가 인류문명이 발달하여 도시화 및 산업화가 진행되어감에 따라 서식환경이 크게 바뀌게 되었는데, 이로 인하여 특정조류는 점차 종수가 줄어들어 보호종으로 되고 희귀조류가 되는 반면 다른 조류는 환경에 변화에 잘 적응하여 개체수가 늘어나고 있다.As wild algae, which have coexisted with humans for a long time, have undergone human civilization and urbanization and industrialization, the habitat environment has changed drastically. As a result, certain algae are gradually reduced in species, becoming protected species and rare algae. The population is well adapted to changes in the environment.
예전에는 미미하거나 거의 문제시 되지 않았던 조류에 의한 피해가 점차 커져 사회문제로 확대되고 있다. 그 실례로서 농작물뿐만 아니라 전신주의 감전, 공항, 양어장, 양봉지대, 주택가 및 기타 건축물 등의 피해는 갈수록 커지고 있는 실정이다.The damage caused by algae, which was once insignificant or rarely a problem, is gradually increasing and expanding into social problems. For example, damages not only to crops but also to electric poles, airports, fish farms, beekeeping areas, residential areas, and other buildings are increasing.
유해조류로부터 작물 및 시설물을 보호하는데 사용되고 있는 조류퇴치방법으로, 천적 모형물 또는 반사경이나 반짝이 테이프 등을 이용한 시각적 위협퇴치 제품; 경보음, 라디오의 소음 또는 초음파 등 청각적인 퇴치 제품; 방조망, 방조봉지, 방조캡 등 접촉성 제품; 및 목초액, 나프탈렌, 메틸 안트라닐레이트 및 안트라퀴논 등 과수농가에서 주로 사용하는 제품 등이 있다.As an algae control method used to protect crops and facilities from harmful algae, a natural threat modeling product or a visual threat reduction product using a reflector or shiny tape; Acoustically combative products such as alarm sounds, radio noise or ultrasonic waves; Contact products such as a protective net, a protective bag and a protective cap; And products mainly used in fruit farms such as wood vinegar, naphthalene, methyl anthranilate and anthraquinone.
상기의 방법들은 과수류 및 시설 등에 해를 주는 조류를 방제하는데 많이 사용되고 있지만, 단기효과와 고비용 등 많은 단점을 지니고 있다.The above methods are widely used to control algae that are harmful to fruit trees and facilities, but have many shortcomings and high costs.
유해조류로부터 작물 및 시설물을 보호하는데 사용되고 있는 조류퇴치제는 크게 일차적 및 이차적 조류퇴치제로 구분된다. 일차적 조류퇴치제는 시각, 미각, 후각 및 촉각 등에 의해 즉시적으로 조류의 접근을 방지하는 제제로 학습효과가 필요하지 않은 특징을 갖는다.Algae repellents, which are used to protect crops and facilities from harmful algae, are largely divided into primary and secondary algae repellents. Primary bird repellents are agents that prevent algae's access immediately by sight, taste, smell and touch, and have no feature of learning.
이차적 조류퇴치제는 음식물의 섭취에 의해 고통을 야기하는 제제로, 학습효과에 의해 작물의 섭취 등을 방지하는 제제를 의미한다. 그러므로 이차적 조류퇴치제는 섭취시 비정상적인 생리·대사적 반응을 나타내는 물질이며, 유해조류에만 특이적으로 반응할 수 있는 물질이 선호된다.Secondary algae control agent is a preparation causing pain by the intake of food, means a preparation to prevent the intake of crops, etc. by the learning effect. Therefore, the secondary algae repellent is a substance that exhibits abnormal physiological and metabolic reactions when ingested, and a substance that can specifically react only with harmful birds is preferred.
그러나 대부분의 이차적 조류퇴치제는 농약 및 화학물질로, 잔류 등에 의한 환경오염 및 인축독성 등을 야기시킬 수 있는 잠재적 문제점을 갖고 있다. However, most secondary algae killers are pesticides and chemicals, and have potential problems that may cause environmental pollution and human toxicity due to residues.
상기와 같은 종래의 조류퇴치제의 단점을 극복하기 위하여, 본 발명자는 대한민국등록특허 제10-0798290호(2008.02.04.)에 겔상의 조류퇴치용 조성물을 개시한 바 있다. 상기 겔상의 조류퇴치용 조성물은 친환경적이며 전신주, 건물, 교각과 같이 특정한 장소에 도포하는 경우에는 조류기피효능을 발휘하지만, 과수원과 같이 피해지역이 광범위하고 조류의 먹이가 많은 장소에 사용하는 경우에는 조류기피효능이 충분치 않으며, 높은 온도 및 집중호우와 같은 열악한 환경에서 겔상의 조류퇴치용 조성물이 손실되는 문제가 있다.In order to overcome the disadvantages of the conventional algae repellent as described above, the present inventor has disclosed a gel-like algae composition in the Republic of Korea Patent No. 10-0798290 (2008.02.04.). The gel-like composition for combating algae is environmentally friendly and exerts a bird evacuation effect when applied to specific places such as telegraph poles, buildings, and piers, but when used in places where the area of damage is wide and birds feed, such as orchards There is a problem that the algal repelling effect is not sufficient, and the composition for combating algae on the gel is lost in a harsh environment such as high temperature and heavy rain.
본 발명자는 높은 온도 및 집중호우와 같은 열악한 환경에서 손실되는 것을 방지할 수 있어 심한 환경의 변화 조건에서도 사용할 수 있으며, 새로운 식물추출 정유를 복합적으로 사용함으로 조류기피효능을 극대화하여 전신주, 건물, 교각뿐만 아니라 과수원과 같이 피해지역이 광범위하고 조류의 먹이가 매우 풍부한 환경에서도 유용한 조류기피효과를 발휘하는 환경 친화적인 고상의 조류퇴치 조성물을 개발하였다.The present inventors can prevent the loss in the harsh environment such as high temperature and heavy rain, can be used even under severe environmental change conditions, by using a new plant extraction essential oil in combination to maximize the algae avoidance effect telegraph poles, buildings, piers In addition, we have developed an environmentally friendly solid algae control composition that exhibits useful algae avoidance effects in a wide range of affected areas such as orchards and very rich algae food.
본 발명의 목적은 높은 온도 및 집중호우와 같은 열악한 환경에서 손실되는 것을 방지할 수 있어 심한 환경의 변화 조건에서도 사용할 수 있으며, 새로운 식물추출 정유를 복합적으로 사용함으로 조류기피효능을 극대화하여 전신주, 건물, 교각뿐만 아니라 과수원과 같이 피해지역이 광범위하고 조류의 먹이가 매우 풍부한 환경에서도 유용한 조류기피효과를 발휘하는 환경 친화적인 고상의 조류퇴치 조성물을 제공하는 것이다.The purpose of the present invention is to prevent the loss in the harsh environment such as high temperature and heavy rain can be used even under severe environmental change conditions, by using a new plant extract essential oil complex by maximizing algae avoidance effect telegraph pole, building In addition, the present invention provides an environmentally friendly solid algae composition that exhibits a useful algal evacuation effect even in an environment where a wide range of damaged areas such as orchards and abundant algae food are abundant.
상기 목적을 달성하기 위하여 본 발명은 다음과 같은 수단을 제공한다.In order to achieve the above object, the present invention provides the following means.
본 발명은, 경화제 40~95중량%, 백리향 정유 0.05~20중량%, 오리가노 정유 0.05~10중량%, 시트로넬라 정유 0.1~20중량%, 스피어민트 정유 0.1~10중량%, 정향 정유 0.1~10중량%, 메틸 안트라닐레이트(methyl anthranilate) 0.2~20중량%, 자외선 흡수제 0.01~4중량% 및 유화제 1~10중량%를 포함하는 것을 특징으로 하는 고상의 조류퇴치 조성물을 제공한다. The present invention, 40 to 95% by weight of the curing agent, 0.05 to 20% by weight of thyme essential oil, 0.05 to 10% by weight of oregano essential oil, 0.1 to 20% by weight of citronella essential oil, 0.1 to 10% by weight spearmint essential oil, 0.1 ~ clove essential oil It provides a solid algae composition comprising 10% by weight, 0.2 to 20% by weight methyl anthranilate, 0.01 to 4% by weight ultraviolet absorber and 1 to 10% by weight emulsifier.
상기 경화제는 비누베이스인 것을 특징으로 한다.The curing agent is characterized in that the soap base.
상기 자외선 흡수제는 힌더드 아민(Hindered amine)계 자외선 흡수제인 것을 특징으로 한다.The ultraviolet absorbent is characterized in that the hindered amine-based ultraviolet absorber.
상기 유화제는 솔비탄 지방산 에스테르인 것을 특징으로 한다.The emulsifier is characterized in that the sorbitan fatty acid ester.
본 발명에 따른 고상의 조류퇴치용 조성물은 높은 온도 및 집중호우와 같은 열악한 환경에서 손실되는 것을 방지할 수 있어 심한 환경의 변화 조건에서도 사용할 수 있으며, 새로운 식물추출 정유를 복합적으로 사용함으로 조류기피효능을 극대화하여 전신주, 건물, 교각뿐만 아니라 과수원과 같이 피해지역이 광범위하고 조류의 먹이가 매우 풍부한 조건에서도 유용한 조류기피효과를 발휘하는 장점이 있다.The solid algae composition according to the present invention can be prevented from being lost in the harsh environment such as high temperature and heavy rain, can be used even under severe environmental change conditions, algae avoidance effect by using a new plant extract essential oil complex By maximizing the utility poles, buildings, bridges, as well as orchards, such as orchards have a wide range of damage and algae abundant food conditions have the advantage of having a good bird evasion effect.
도 1은 오리가노 정유 포함 조성물 설치한 먹이통에 십자매의 착지 시도 횟수를 나타낸 그래프이고,1 is a graph showing the number of attempts to land cross-sisters in a feeding container installed with an oregano essential oil-containing composition,
도 2는 백리향 정유 포함 조성물 설치한 먹이통에 십자매의 착지 시도 횟수를 나타낸 그래프이고,Figure 2 is a graph showing the number of attempts to land the cross in the feeding container installed with the composition containing the thyme essential oil,
도 3은 정향 정유 포함 조성물 설치한 먹이통에 십자매의 착지 시도 횟수를 나타낸 그래프이고,Figure 3 is a graph showing the number of attempts to land the cross in the feeding container with the composition containing the cloves essential oil,
도 4는 스피어민트 정유 포함 조성물 설치한 먹이통에 십자매의 착지 시도 횟수를 나타낸 그래프이고,Figure 4 is a graph showing the number of attempts to land the cross sister in the feeding container installed with the composition containing the spearmint essential oil,
도 5는 시트로넬라 정유 포함 조성물 설치한 먹이통에 십자매의 착지 시도 횟수를 나타낸 그래프이고,5 is a graph showing the number of attempts to land the cross sister in a feeding container installed with a composition containing citronella essential oil,
도 6은 본 발명에 따른 고상의 조류퇴치제를 설치한 횃대에 십자매의 착지 시도 횟수를 나타낸 그래프이고,6 is a graph showing the number of attempts to land the cross sisters on the perch provided with a solid bird repellent agent according to the present invention,
도 7은 과수 농가에 고상의 조류퇴치제를 설치하지 않은 경우(B) 사과나무 누적 피해율을 나타낸 그래프이고,7 is a graph showing the cumulative damage rate of apple trees when the solid bird repellent is not installed in the fruit farm (B),
도 8은 과수 농가에 고상의 조류퇴치제를 설치한 경우(A) 사과나무 누적 피해율을 나타낸 그래프이고,8 is a graph showing the cumulative damage rate of apple trees when the solid bird repellent is installed in the fruit farm (A),
도 9는 과수 농가에 겔상의 조류퇴치 조성물을 설치한 경우(C) 및 고상의 조류퇴치제를 설치한 경우(D) 배나무 피해율을 나타낸 그래프.9 is a graph showing the damage rate of pear tree when the gel-based algae combatant composition is installed (C) and the solid algae exterminator (D) in the fruit farm.
이하, 본 발명을 상세히 설명하면 다음과 같다.Hereinafter, the present invention will be described in detail.
본 발명자는 계피정유와 박하정유를 포함하는 겔상의 조류퇴치 조성물(한국등록특허, 제10-0798290호)을 출원한 바 있다. 상기 겔상의 조류퇴치 조성물을 전신주, 건물, 교각과 같이 특정한 장소에 도포하는 경우에는 조류기피효능을 발현하지만, 과수원과 같이 피해지역이 광범위하며 조류의 먹이가 많은 장소에 사용하는 경우에는 조류기피효능이 충분히 발현되지 않았다.The present inventor has filed a gel-like algae composition (Korean Patent No. 10-0798290) comprising cinnamon essential oil and peppermint essential oil. When the gel-like algae composition is applied to a specific place, such as telegraph poles, buildings, piers express algae evacuation effect, algae evacuation effect when used in places where the damage area is wide, such as orchards and a lot of bird food This was not sufficiently expressed.
본 발명에서는 새로운 식물추출 정유를 복합적으로 사용하여 과수원과 같이 피해지역이 광범위하며 조류의 먹이가 많은 장소에서도 조류기피효능을 충분히 발휘할 수 있는 것에 특징이 있다.In the present invention, by using a new plant extraction essential oil complex, the damage area is wide, such as an orchard, and is characterized by being able to sufficiently exert the algal evacuation effect even in a place with a lot of bird food.
먼저 본 발명에 따른 고상의 조류퇴치 조성물에 대해 설명한다.First, the solid algae combating composition according to the present invention will be described.
본 발명의 고상의 조류퇴치 조성물은,Solid phase algae composition of the present invention,
경화제 40~95중량%, 백리향 정유 0.05~20중량%, 오리가노 정유 0.05~10중량%, 시트로넬라 정유 0.1~20중량%, 스피어민트 정유 0.1~10중량%, 정향 정유 0.1~10중량%, 메틸 안트라닐레이트(methyl anthranilate) 0.2~20중량%, 자외선 흡수제 0.01~4중량% 및 유화제 1~10중량%를 포함한다.40 to 95% by weight of curing agent, 0.05 to 20% by weight of thyme essential oil, 0.05 to 10% by weight of oregano essential oil, 0.1 to 20% by weight of citronella essential oil, 0.1 to 10% by weight of spearmint essential oil, 0.1 to 10% by weight of clove essential oil, 0.2 to 20% by weight of methyl anthranilate, 0.01 to 4% by weight of ultraviolet absorber and 1 to 10% by weight of emulsifier.
본 발명의 고상의 조류퇴치 조성물은 주성분 및 부성분으로 구성되는데, 상기 주성분은 백리향 정유, 오리가노 정유, 시트로넬라 정유, 스피어민트 정유, 정향 정유, 메틸 안트라닐레이트 및 자외선 흡수제를 포함하며, 상기 부성분은 경화제 및 유화제를 포함한다.The solid algae composition of the present invention comprises a main component and a subcomponent, the main component including thyme essential oil, oregano essential oil, citronella essential oil, spearmint essential oil, cloves essential oil, methyl anthranilate and ultraviolet absorbent, Includes a curing agent and an emulsifier.
먼저 본 발명의 고상의 조류퇴치 조성물의 주성분에 대해 설명한다.First, the main component of the solid algae combating composition of the present invention will be described.
본 발명의 주성분 중 하나인 상기 백리향 정유는 주요 활성성분으로 티몰(Thymol)을 함유하며, 강한 자극성 있는 휘발성 향기로 인한 후각 기피효과 및 안점막 자극효과로 인한 기피효과를 나타낼 수 있다. 또한 접촉이나 섭취 등에 의한 기피효과가 아닌 초기자극이 강하다는 장점을 갖고 있으며, 항균, 항진균 및 해충에 대한 기피효과도 뛰어나서 조류퇴치제의 설치 이후 외부오염이나 조성물의 부패 등을 방지하여, 조류퇴치제의 효력이 감소됨을 억제할 수 있다. 상기 백리향 정유는 전체 조성물 총 중량의 0.05~20중량%, 바람직하게는 1~15중량%로 사용된다. 이때, 백리향 정유가 전체 조성물 총 중량의 0.05중량% 미만으로 사용되면 항균 및 항진균 효과가 감소하여, 조성물의 세균 및 진균에 의한 오염이 발생할 수 있으며, 20중량% 초과하여 사용되면 경도가 감소하는 문제가 야기될 수 있다.The thyme essential oil, which is one of the main components of the present invention, contains thymol as the main active ingredient, and may exhibit a repelling effect due to olfactory repelling effect and eye irritation effect due to a strong irritating volatile scent. In addition, it has the advantage of strong initial stimulation, not the repelling effect by contact or ingestion, and also has excellent anti-bacterial, anti-fungal and repelling effect on pests, preventing external pollution or decay of the composition after the installation of algae repellents. The effect can be suppressed to be reduced. The thyme essential oil is used in 0.05 to 20% by weight, preferably 1 to 15% by weight of the total composition. At this time, when the thyme essential oil is used less than 0.05% by weight of the total composition of the antimicrobial and antifungal effect is reduced, the contamination by bacteria and fungi of the composition may occur, when used in excess of 20% by weight hardness problem May be caused.
본 발명의 주성분 중 하나인 상기 오리가노 정유는 주요 활성성분으로 카바크롤(Carvacrol)을 함유하며, 강한 자극성 있는 휘발성 향기로 인한 후각 기피효과 및 안점막 자극효과로 인한 기피효과를 나타낼 수 있다. 또한 접촉이나 섭취 등에 의한 기피효과가 아닌 초기자극이 강하다는 장점을 갖고 있으며, 항균, 항진균 및 해충에 대한 기피효과도 뛰어나서 조류퇴치제의 설치 이후 외부오염이나 조성물의 부패 등을 방지하여, 조류퇴치제의 효력이 감소됨을 억제할 수 있다. 상기 오리가노 정유는 전체 조성물 총 중량의 0.05~10중량%, 바람직하게는 0.5~5중량%로 사용된다. 이때, 오리가노 정유가 전체 조성물 총 충량의 0.05중량% 미만으로 사용되면 항균 및 항진균 효과가 감소하여, 조성물의 세균 및 진균에 의한 오염이 발생할 수 있으며, 10중량%를 초과하여 사용되면 경도가 감소하는 문제가 야기될 수 있다. One of the main components of the present invention, the oregano essential oil contains carvacrol as the main active ingredient, and may exhibit a repelling effect due to olfactory repelling effect and eye irritation effect due to a strong irritating volatile scent. In addition, it has the advantage of strong initial stimulation, not the repelling effect by contact or ingestion, and also has excellent anti-bacterial, anti-fungal and repelling effect on pests, preventing external pollution or decay of the composition after the installation of algae repellents. The effect can be suppressed to be reduced. The oregano essential oil is used at 0.05 to 10% by weight, preferably 0.5 to 5% by weight of the total weight of the total composition. At this time, when the oregano essential oil is used in less than 0.05% by weight of the total composition of the total antimicrobial and antifungal effect is reduced, it may cause contamination by bacteria and fungi of the composition, when used in excess of 10% by weight decreases the hardness This can cause problems.
본 발명의 주성분 중 하나인 상기 시트로넬라 정유는 주요 활성성분으로 시트로넬랄(Citronellal)을 함유하며, 자극성 있는 휘발성 향기로 인한 후각 기피효과 및 안점막 자극효과로 인한 기피효과를 나타낼 수 있다. 또한 접촉이나 섭취 등에 의한 기피효과가 아닌 초기자극이 강하다는 장점을 갖고 있으며, 항균, 항진균 및 해충에 대한 기피효과도 뛰어나서 조류퇴치제의 설치 이후 외부오염이나 조성물의 부패 등을 방지하여, 조류퇴치제의 효력이 감소됨을 억제할 수 있다. 상기 시트로넬라 정유는 전체 조성물 총 중량의 0.1~20중량%, 바람직하게는 1~12중량%로 사용된다. 이때, 시트로넬라 정유가 전체 조성물 총 충량의 0.1중량% 미만으로 사용되면 항균 및 항진균 효과가 감소하여, 조성물의 세균 및 진균에 의한 오염이 발생할 수 있으며, 20중량%를 초과하여 사용되면 경도가 감소하는 문제가 야기될 수 있다. The citronella essential oil, which is one of the main components of the present invention, contains citronellal as the main active ingredient, and may exhibit a repelling effect due to the olfactory repelling effect and the mucosal irritant effect due to the irritating volatile fragrance. In addition, it has the advantage of strong initial stimulation, not the repelling effect by contact or ingestion, and also has excellent anti-bacterial, anti-fungal and repelling effect on pests, preventing external pollution or decay of the composition after the installation of algae repellents. The effect can be suppressed to be reduced. The citronella essential oil is used at 0.1 to 20% by weight, preferably 1 to 12% by weight of the total weight of the total composition. At this time, when citronella essential oil is used in less than 0.1% by weight of the total amount of the total composition, the antimicrobial and antifungal effects may be reduced, which may cause contamination by bacteria and fungi of the composition. Decreasing problems can be caused.
본 발명의 주성분 중 하나인 상기 스피어민트 정유는 주요 활성성분으로 카르본(Carvone)을 함유하며, 강한 자극성 있는 휘발성 향기로 인한 후각 기피효과 및 안점막 자극효과로 인한 기피효과를 나타낼 수 있다. 또한 접촉이나 섭취 등에 의한 기피효과가 아닌 초기자극이 강하다는 장점을 갖고 있으며, 항균, 항진균 및 해충에 대한 기피효과도 뛰어나서 조류퇴치제의 설치 이후 외부오염이나 조성물의 부패 등을 방지하여, 조류퇴치제의 효력이 감소됨을 억제할 수 있다. 상기 스피어민트 정유는 전체 조성물 총 중량의 0.1~10중량%, 바람직하게는 1~6중량%로 사용된다. 이때, 스피어민트 정유가 전체 조성물 총 충량의 0.1중량% 미만으로 사용되면 항균 및 항진균 효과가 감소하여, 조성물의 세균 및 진균에 의한 오염이 발생할 수 있으며, 10중량%를 초과하여 사용되면 경도가 감소하는 문제가 야기될 수 있다. The spearmint essential oil, one of the main components of the present invention, contains carbon (Carvone) as a main active ingredient, and may exhibit a repelling effect due to olfactory repelling effect and eye irritation effect due to a strong irritating volatile scent. In addition, it has the advantage of strong initial stimulation, not the repelling effect by contact or ingestion, and also has excellent anti-bacterial, anti-fungal and repelling effect on pests, preventing external pollution or decay of the composition after the installation of algae repellents. The effect can be suppressed to be reduced. The spearmint essential oil is used in 0.1 to 10% by weight, preferably 1 to 6% by weight of the total weight of the composition. At this time, when the spearmint essential oil is used in less than 0.1% by weight of the total composition of the total antimicrobial and antifungal effect is reduced, it may cause contamination by bacteria and fungi of the composition, when used in excess of 10% by weight of hardness Problems may arise.
본 발명의 주성분 중 하나인 상기 정향 정유는 주요 활성성분으로 유제놀(eugenol)을 함유하며, 강한 자극성 있는 휘발성 향기로 인한 후각 기피효과 및 안점막 자극효과로 인한 기피효과를 나타낼 수 있다. 또한 접촉이나 섭취 등에 의한 기피효과가 아닌 초기자극이 강하다는 장점을 갖고 있으며, 항균 및 항진균 효과와 해충에 대한 기피효과도 뛰어나서 조류퇴치제의 설치 이후 외부오염이나 조성물의 부패 등을 방지하여, 조류퇴치제의 효력이 감소됨을 억제할 수 있다. 상기 정향 정유는 전체 조성물 총 중량의 0.1~10중량%, 바람직하게는 1~6중량%로 사용된다. 이때, 정향 정유가 전체 조성물 총 충량의 0.1중량% 미만으로 사용되면 항균 및 항진균 효과가 감소하여, 조성물의 세균 및 진균에 의한 오염이 발생할 수 있으며, 10중량%를 초과하여 사용되면 경도가 감소하는 문제가 야기될 수 있다. One of the main ingredients of the present invention, the clove essential oil contains eugenol as the main active ingredient, and may exhibit a repelling effect due to olfactory repelling effect and eye mucosal irritant effect due to a strong irritant volatile fragrance. In addition, it has the advantage that the initial stimulus, not the repellent effect by contact or ingestion, is strong, and also has an excellent antibacterial and antifungal effect and a repellent effect against pests, thereby preventing external pollution or decay of the composition after the installation of the bird repellent, The effect of can be suppressed from being reduced. The clove essential oil is used at 0.1 to 10% by weight, preferably 1 to 6% by weight of the total weight of the composition. At this time, when the clove essential oil is used in less than 0.1% by weight of the total composition of the total antimicrobial and antifungal effect is reduced, it may cause contamination by bacteria and fungi of the composition, when used in excess of 10% by weight of hardness Problems may arise.
본 발명의 주성분 중 하나인 상기 메틸 안트라닐레이트는 콩코드(Concord) 포도 추출물로서, 향기는 포도향, 오렌지향 및 네롤리유향이 있는 옅거나 짙은 노란색 액체이다. 메틸 안트라닐레이트는 미국 EPA에 등록된 식품첨가제로, 조류가 섭취할 경우 눈이나 비강이나 점막을 자극하는 것으로 알려져 있다. 이미 메틸 안트라닐레이트를 주성분으로 하는 조류 퇴치제가 상품화되어 있으나, 자극의 강도가 비교적 약하고 효과의 지속성이 6~7일로 비교적 짧은 단점을 갖고 있다. 본 발명에서는 메틸 안트레닐라이트의 단점을 극복하고 주작용인 조류의 눈이나 비강점막을 자극하는 효과를 극대화하기 위해 기타의 주성분과 병용하여 하나의 조류퇴치 조성물을 제공하였다. 상기 메틸 안트라닐레이트는 전체 조성물 총 중량의 0.2~20중량%, 바람직하게는 2~10중량%로 사용된다. 이때, 메틸 안트라닐레이트가 전체 조성물 총 충량의 0.2중량% 미만으로 사용되면 조류기피효과가 나타나지 않으며, 20중량%를 초과하여 사용되면 심한 안점막 자극 및 피부 자극 등의 독성 문제가 야기될 수 있다. The methyl anthranilate, one of the main components of the present invention, is a Concord grape extract, and the fragrance is a pale or dark yellow liquid with grape, orange and neroli flavours. Methyl anthranilate is a food additive registered with the US EPA and is known to irritate the eyes, nasal cavity or mucous membranes when ingested by algae. Algae repellents based on methyl anthranilate have already been commercialized, but the strength of the stimulus is relatively weak and the duration of the effect is 6-7 days. In the present invention, in order to overcome the disadvantages of methyl anthranilite and to maximize the effect of stimulating the eye or nasal mucosa of the main action of algae, in combination with other main components to provide a single algae control composition. The methyl anthranilate is used at 0.2 to 20% by weight, preferably 2 to 10% by weight of the total weight of the total composition. At this time, when the methyl anthranilate is used in less than 0.2% by weight of the total composition of the total composition does not exhibit the algal repellent effect, when used in excess of 20% by weight may cause toxic problems such as severe eye irritation and skin irritation. .
본 발명의 주성분 중 하나인 상기 자외선 흡수제는 자외선 영역의 시각을 가지고 있는 조류에게 조류퇴치제가 처리된 지역을 멀리서도 감지할 수 있도록 하는 효과를 거둘 수 있으며, 조류퇴치제의 향, 섭취 또는 접촉에 의한 불쾌감에 대한 기억을 야기시켜 해당지역에 대한 기피현상을 극대화할 수 있다. 본 발명에서 사용하는 자외선 흡수제는 벤조페논(Benzophenone)계, 벤조트리아졸(Benzotriazole)계, 시아노아크릴레이트(Cyanoacraylate)계, 힌더드 아민(Hindered amine)계, 옥사닐라이드(Oxanilide)계 및 살리실레이트(Salicylate)계로 구성된 군에서 선택되며, 바람직하게는 힌더드 아민계를 사용한다. 상기 자외선 흡수제는 전체 조성물 총 중량의 0.01~4중량%, 바람직하게는 0.1~2중량%로 사용된다. 이때, 자외선 흡수제가 전체 조성물 총 중량의 0.01중량% 미만으로 사용되면 자외선 흡수효과가 미약하며, 4중량%를 초과하여 사용되어도 조류기피효과의 현저한 증가는 관찰되지 않는다.The ultraviolet absorber, one of the main components of the present invention, may have an effect of detecting an algae-treated region from a distance from an algae having a vision in the ultraviolet region, and may be affected by the aroma, ingestion, or contact of the algae extinguishing agent. It can cause the memory of discomfort and maximize the avoidance of the area. The ultraviolet absorber used in the present invention is benzophenone-based, benzotriazole-based, cyanoacraylate-based, hindered amine-based, oxanilide-based and salicylic acid. It is selected from the group consisting of a salicylate system, and preferably a hindered amine system is used. The ultraviolet absorber is used in 0.01 to 4% by weight, preferably 0.1 to 2% by weight of the total weight of the composition. At this time, when the ultraviolet absorber is used in less than 0.01% by weight of the total weight of the composition, the ultraviolet absorbing effect is weak, and even when used in excess of 4% by weight, no significant increase in the algal repelling effect is observed.
다음은, 본 발명의 고상의 조류퇴치 조성물의 부성분에 대해 설명한다.Next, the subcomponent of the solid algae combating composition of the present invention will be described.
본 발명에 따른 고상의 조류퇴치 조성물의 부성분은 경화제와 유화제를 포함한다.Subcomponents of the solid algae combating composition according to the present invention include a curing agent and an emulsifier.
종래의 겔상의 조류퇴치 조성물은 높은 온도 및 집중호우와 같은 열악한 환경에서 겔상의 조류퇴치 조성물이 손실되는 문제가 있으므로, 본 발명에서는 심한 환경의 변화에 대해서도 손실 또는 유실을 방지할 수 있도록 고상의 조류퇴치 조성물로 제조함에 특징이 있다.The conventional gel-like algae composition has a problem that the gel-like algae composition is lost in a harsh environment such as high temperature and heavy rains, in the present invention, the solid algae to prevent loss or loss even under severe environmental changes It is characterized by the preparation of the combating composition.
상기 경화제로는 비누 베이스를 사용하며, 비누 베이스는 조류퇴치용 조성물의 경화를 촉진 및 경도를 높임으로써 눈이나 비 등의 수분이 많은 기후지역에서 조류퇴치용 조성물 내로 수분이 침투하여 조류퇴지제 내의 주성분의 손실이나 변성을 방지함으로써 조류퇴치용 조성물의 안정성을 유지하며, 조류기피효과를 지속시키는 작용을 한다. 상기 경화제는 전체 조성물 총 중량의 40~95중량%, 바람직하게는 70~90중량% 사용된다. 이때, 상기 경화제가 전체 조성물 총 중량의 40중량% 미만으로 사용되면 경화되는 성질이 불안정하여 조성물의 손실이 나타날 수 있으며, 95중량% 초과하여 사용되면 조류퇴치를 위한 주요성분이 줄어들어 조류기피효과가 감소되는 문제가 야기될 수 있다. 상기 비누 베이스(soap base)는 통상적인 비누의 제조에서 사용되는 것으로서, 시중에서 일반적으로 시판되고 있는 제품을 사용할 수 있다. 상기 비누 베이스는 예를 들어 우지, 야자, 팜, 팜핵유 등의 동물성 또는 식물성 유지로부터 선택된 유지(또는 그 지방산)를 가성소다(NaOH)나 가성칼륨(KOH) 등으로 직접 검화 또는 중화시킨 알칼리성의 지방산염 등을 사용할 수 있다. As the curing agent, a soap base is used, and the soap base promotes the hardening of the composition for combating algae and increases the hardness, so that moisture penetrates into the composition for combating algae in a wet climate such as snow or rain. Maintaining stability of the composition for combating algae by preventing the loss or denaturation of the main component, and acts to maintain the algae avoidance effect. The curing agent is used 40 to 95% by weight, preferably 70 to 90% by weight of the total weight of the total composition. At this time, if the curing agent is used in less than 40% by weight of the total composition of the composition is unstable hardening properties may appear a loss of the composition, when used in excess of 95% by weight of the main component for reducing the algae avoiding algae effect The problem of being reduced can be caused. The soap base is used in the manufacture of a conventional soap, it is possible to use a commercially available product. The soap base may be, for example, an alkaline product obtained by directly saponifying or neutralizing fat or oil selected from animal or vegetable fats and oils such as tallow, palm, palm, palm kernel oil, etc. with caustic soda (NaOH) or caustic potassium (KOH). Fatty acid salts can be used.
상기 유화제로는 공업용으로 안료, 인쇄잉크, 페인트, 섬유조제, 윤활유 등의 유화 및 분산제로 다양하게 이용되는 솔비탄 지방산 에스테르가 사용되며, 유화제는 조류퇴치용 조성물의 주성분인 식물 정유 및 메틸 안트라닐레이트가 전체 조성물 내에서 골고루 분산되도록 하는 목적으로 사용된다. 상기 솔비탄 지방산 에스테르는 지방산의 종류에 따라 솔비탄 모노라우레이트, 솔비탄 모노팔미테이트, 솔비탄 모노올레이트, 솔비탄 모노스테아레이트 및 솔비탄 모노베헤네이트로 구성된 군에서 선택된 어느 하나 또는 둘 이상의 혼합물을 사용할 수 있다. 바람직하게는 솔비탄 모노올레이트를 사용한다. 상기 유화제는 전체 조성물 총 중량의 1~10중량%, 바람직하게는 2~5중량%로 사용된다. 이때, 유화제가 전체 조성물 총 중량의 1중량% 미만으로 사용되면 백리향 정유, 오리가노 정유, 시트로넬라 정유, 스피어민트 정유 및 정향 정유의 유화정도를 감소시켜 본 조성물에 골고루 섞이지 않을 수 있으며, 10중량% 초과하여 사용되면 조성물의 경도가 감소하여 조류 기피효과 및 본 조성물의 손실 억제효과가 감소하는 문제가 야기될 수 있다.As the emulsifier, sorbitan fatty acid esters which are variously used as emulsifiers and dispersants for pigments, printing inks, paints, textile preparations, lubricating oils, etc. are used for industrial purposes, and emulsifiers are plant essential oils and methyl anthranyl which are main components of the composition for combating algae. The rate is used for the purpose of uniformly dispersing in the whole composition. The sorbitan fatty acid ester is one or more selected from the group consisting of sorbitan monolaurate, sorbitan monopalmitate, sorbitan monooleate, sorbitan monostearate and sorbitan monobehenate, depending on the type of fatty acid Mixtures can be used. Preferably sorbitan monooleate is used. The emulsifier is used in 1 to 10% by weight, preferably 2 to 5% by weight of the total weight of the composition. In this case, when the emulsifier is used in less than 1% by weight of the total weight of the total composition, it may not be evenly mixed with the present composition by reducing the emulsification of thyme essential oil, origano essential oil, citronella essential oil, spearmint essential oil and clove essential oil. When used in excess of%, the hardness of the composition may be reduced, which may cause a problem that the algal repelling effect and the loss inhibiting effect of the composition are reduced.
이하, 실시 예를 통하여 본 발명의 구성 및 효과를 더욱 상세히 설명하고자 한다. 이들 실시 예는 오로지 본 발명을 예시하기 위한 것을 뿐 본 발명의 범위가 이들 실시 예에 의해 제한되는 것은 아니다.Hereinafter, the configuration and effects of the present invention through the embodiments will be described in more detail. These examples are only for illustrating the present invention, but the scope of the present invention is not limited by these examples.
[제조예 1][Production Example 1]
오리가노 정유 10중량%와 열을 가해 녹인 비누 베이스 90중량%를 혼합 및 교반한 후에 상온에서 식혀서 오리가노 정유 포함 조성물을 제조하였다. 상기 비누 베이스는 중일유화(주)에서 제조한 TEA(트리에탄올아민)-Free 투명비누베이스를 사용하였다. 상기 오리가노 정유 포함 조성물을 가로×세로×높이가 18×7×5㎜가 되도록 성형하여 조류퇴치제를 만들었다.After mixing and stirring 10% by weight of oregano essential oil and 90% by weight of a soap base dissolved in heat, the mixture was cooled at room temperature to prepare a composition containing an oregano essential oil. As the soap base, TEA (triethanolamine) -free transparent soap base manufactured by Sino Oil Co., Ltd. was used. The composition containing the origano essential oil was molded so as to have a width × length × height of 18 × 7 × 5 mm to prepare an algae repellent.
[제조예 2][Production Example 2]
제조예 1에서 오리가노 정유 대신에 백리향 정유를 사용한 것을 제외하고 나머지는 동일하게 제조하였다.Except for using thyme essential oil instead of origano essential oil in Preparation Example 1 the remainder was prepared in the same manner.
[제조예 3][Manufacture example 3]
제조예 1에서 오리가노 정유 대신에 정향 정유를 사용한 것을 제외하고 나머지는 동일하게 제조하였다.Except for using clove essential oil instead of origano essential oil in Preparation Example 1, the rest was prepared in the same manner.
[제조예 4][Production Example 4]
제조예 1에서 오리가노 정유 대신에 스피어민트 정유를 사용한 것을 제외하고 나머지는 동일하게 제조하였다.Except for using spearmint essential oil instead of origano essential oil in Preparation Example 1, the rest was prepared in the same manner.
[제조예 5]Production Example 5
제조예 1에서 오리가노 정유 대신에 시트로넬라 정유를 사용한 것을 제외하고 나머지는 동일하게 제조하였다.Except for using citronella essential oil instead of origano essential oil in Preparation Example 1, the remainder was prepared in the same manner.
[실험예 1] 각각의 식물 추출정유 조성물의 십자매에 대한 조류기피 효능평가Experimental Example 1 Evaluation of Efficacy of Algae on Cross Sisters of Each Plant Extract Essential Oil Composition
1. 실험방법1. Experiment Method
1) 공시동물1) animals
참새목 납부리과의 십자매를 이용하여 실험실 규모에서 조류기피효과를 확인하였다. 십자매는 한국 내에서 사육조로 널리 사육되고 있어 실험에 사용하기가 용이하며, 성격이 활달하여 운동량이 많아 조류기피효과 및 적응 여부를 판정하기 용이하기 때문에 시험동물로 공시하였다.The cross-border of the Sparrow-leaved beak family was used to confirm the effect of avoiding birds on a laboratory scale. The cross sisters are widely bred in Korea as breeding tanks, so they are easy to use in experiments.
2) 사육환경2) Breeding environment
수컷 십자매(n=25)는 대전 인근 조류원에서 구입하여, 실험실 조건(온도 20-22℃, 습도 50-70% 및 암기 0:00-06:00 h) 하에서 일주일간의 순화기간을 거친 후, 건강한 개체를 무작위로 선발하여 시험에 공시하였다.Male cruciforms (n = 25) were purchased from an algae near Daejeon, followed by a week-long purifying period under laboratory conditions (temperature 20-22 ° C, humidity 50-70%, and memorization 0: 00-06: 00 h). Subjects were randomly selected and published in the trial.
시험사육상자(n=5)는 가로×세로×높이가 75×50×50 ㎝ 인 것을 사용하였으며, 사료와 음수는 자유급여하였다.The test breeding box (n = 5) was used to have a width × length × height of 75 × 50 × 50 cm, free feed and negative water.
3) 식물 추출정유 조성물의 기피효과평가3) Evasion effect evaluation of plant extract essential oil composition
각각의 식물 추출정유 조성물의 기피효과를 확인하기 위하여, 제조예 1 내지 5에서 제조한 각각의 조류퇴치제를 먹이통 상단 부분에 부착하였다. 실험실 조건하에서 1주일간의 순화기간 이후, 24시간 동안 비디오카메라를 이용하여, 먹이통에 접근하는 횟수 및 조성물의 접촉에 의한 이상 반응을 관찰하였다.In order to confirm the repellent effect of each plant extract essential oil composition, each algae repellent prepared in Preparation Examples 1 to 5 was attached to the upper portion of the feed container. After one week of purifying under laboratory conditions, a video camera was used for 24 hours to observe the number of accesses to the feeding container and the adverse reactions caused by contact of the composition.
2. 실험결과2. Experimental Results
1) 각각의 식물 추출정유 조성물의 기피효과1) The repelling effect of each plant extract essential oil composition
식물 추출정유 조성물을 설치하기 전인 순화기간 동안 대부분의 십자매는 사육상자 안에서 정상적인 비행 활동을 나타내었다.During the period of acclimation, prior to the installation of the plant extract essential oil composition, most of the crosses exhibited normal flight activity in the cage.
그러나 도 1 내지 도 5에 도시된 바와 같이, 먹이통에 각각의 식물 추출정유 조성물을 포함한 조류퇴치제를 설치한 이후 먹이통에 착지하려는 시도를 나타내었다. 일부 십자매는 시험상자의 횃대, 천장, 옆면 또는 바닥에 착지하였다.However, as shown in Figures 1 to 5, an attempt was made to land in the feed container after the algae repellent containing the respective plant extract essential oil composition was installed in the feed container. Some crosses landed on the perch, ceiling, sides or floor of the test box.
도 1에 도시된 바와 같이, 오리가노가 첨가된 조류퇴치제를 먹이통에 설치한 경우, 30분 이후에는 일부 십자매가 먹이통에 접근 후 바닥의 모퉁이에 모여 있거나 벽쪽 혹은 횃대에 잠시 이동하는 행동을 보이기도 하였다. 노출 1시간째에 먹이통에 일부 십자매가 시도하다 바로 방향을 바꿔 다른 곳으로 이동하였으며 2시간 이후부터 사육상자 안의 십자매는 먹이통에 착지하려는 시도를 하지 않았다.As shown in Figure 1, when the algae-added algae repellent is installed in the feed container, after 30 minutes, some cruciforms gathered in the corner of the bottom or moved to the wall or perch for a while. At 1 hour of exposure, some crusaders attempted to change their direction and moved to another location. After 2 hours, the crusaders in the cage did not attempt to land in the feeder.
도 2 및 도 3에 도시된 바와 같이, 백리향이 첨가된 조류퇴치제 및 정향이 첨가된 조류퇴치제를 먹이통에 설치한 경우, 노출 1시간 이후에 일부 십자매는 먹이통에 접촉한 후에 한쪽 구석에 모여 있거나 한쪽 벽이나 횃대에 위치하였다가 다른 곳으로 이동하였다. 노출 2시간째에 먹이통에 일부 십자매가 착지하려는 시도가 있었으나 잠시 동안 머물렀다 측면이나 횃대로 이동하였으며 3시간 이후부터 사육상자 안의 십자매는 먹이통에 착지하려는 시도를 하지 않았다.As shown in Figures 2 and 3, when the thyme-added algae and clove-added algae is installed in the feed container, after 1 hour of exposure, some crosses gather in one corner or in one corner after contacting the feed container. It was placed on a wall or perch and moved to another place. At 2 hours of exposure, some critters attempted to land in the feeder, but they stayed for a while and moved to the side or perch. After 3 hours, the crutches in the cage did not attempt to land in the feeder.
도 4 및 도 5에 도시된 바와 같이, 스피어민트가 첨가된 조류퇴치제 및 시트로넬라가 첨가된 조류퇴치제를 먹이통에 설치한 경우, 노출 1시간 이후에는 일부 십자매가 먹이통에 접근한 후 반대편 모퉁이에 모여 있었으며, 노출 2시간째 및 3시간째 먹이통에 계속적으로 접근하려 하였다. 그러나 잠시 먹이통에 머물다가 다시 바닥이나 횃대 등으로 날아가 버렸다. 그 이후로 사육상자 안의 먹이통에 착지하려는 시도는 관찰되지 않았다. As shown in Figures 4 and 5, when the spearmint-added algae and the citronella-added algae is installed in the feeder, after 1 hour of exposure, some crucifers gather in the opposite corner after approaching the feeder At 2 and 3 hours of exposure, they tried to access the feeder continuously. However, he stayed in the feeder for a while and flew back to the floor or perch. Since then no attempt has been made to land in the feeding bins.
또한 각각의 식물 추출정유 조성물에 접촉한 개체에서는 웅크림, 비벼댐 및 빠르게 부리 다듬음의 이상행동을 나타내었다. 상기 5가지 식물 추출정유를 이용한 조류기피효과 실험결과에서 각각의 식물 추출정유가 조류의 기피효능을 나타냄을 확인할 수 있었다.In addition, individuals in contact with each plant extract essential oil composition showed abnormal behavior of squat, grazing and quick beak trimming. In the algae avoidance effect test results using the five plant extract essential oils, it was confirmed that each plant extract essential oil shows the repellent effect of the algae.
[실시예 1]Example 1
백리향 정유, 오리가노 정유, 시트로넬라 정유, 스피어민트 정유, 정향 정유 및 유화제를 혼합기에 넣어 골고루 혼합한 뒤 UV 흡수제 및 메틸 안트라닐레이트를 첨가하여 혼합하였다. 그 다음에는 열을 가해 녹인 비누 베이스에 상기 혼합물을 혼합 및 교반한 후에 20℃의 온도로 식혀 고상의 조류퇴치 조성물로 제조하였다. 상기 비누 베이스는 중일유화(주)에서 제조한 TEA(트리에탄올아민)-Free 투명비누베이스를 사용하였다. 상기 고상의 조류퇴치 조성물을 가로×세로×높이가 25×25×40㎜가 되도록 성형하여 고상의 조류퇴치제를 만들었다.Thyme essential oil, oregano essential oil, citronella essential oil, spearmint essential oil, cloves essential oil and emulsifier were added to the mixer, mixed evenly, and then mixed with UV absorber and methyl anthranilate. Then, the mixture was mixed and stirred in a melted soap base by heating, and then cooled to a temperature of 20 ° C. to prepare a solid algae composition. As the soap base, TEA (triethanolamine) -free transparent soap base manufactured by Sino Oil Co., Ltd. was used. The solid algae combatant composition was molded to have a width × length × height of 25 × 25 × 40 mm to form a solid algae repellent.
이때, 각 성분의 함량은 각각 백리향 정유 0.5중량%, 오리가노 정유 0.5중량%, 시트로넬라 정유 1중량%, 스피어민트 정유 0.5중량%, 정향 정유 0.3중량%, 솔비탄 모노올레이트 10중량%, Ciba® TINUVIN® 123 0.2중량%, 메틸 안트라닐레이트 5중량% 및 비누 베이스 82중량%를 사용하였다.At this time, the content of each component is 0.5% by weight of thyme essential oil, 0.5% by weight of oregano essential oil, 1% by weight of citronella essential oil, 0.5% by weight of spearmint essential oil, 0.3% by weight of clove essential oil, 10% by weight sorbitan monooleate, 0.2 weight percent Ciba ® TINUVIN ® 123, 5 weight percent methyl anthranilate and 82 weight percent soap base were used.
[실시예 2]Example 2
백리향 정유 1.5중량%, 오리가노 정유 0.5중량%, 시트로넬라 정유 1중량%, 스피어민트 정유 0.5중량%, 정향 정유 0.3중량%, 솔비탄 모노올레이트 6중량%, Ciba®TINUVIN® 123 0.2중량%, 메틸 안트라닐레이트 4중량% 및 비누 베이스 86중량%를 사용하여 상기의 실시예 1과 동일한 방법으로 고상의 조류퇴치제를 제조하였다.1.5% thyme oil, 0.5% oregano oil, 1% citronella oil, 0.5% spearmint oil, 0.3% clove oil, 6% sorbitan monooleate, 0.2% by weight Ciba ® TINUVIN ® 123 Using 4 wt% methyl anthranilate and 86 wt% soap base, a solid algae repellent was prepared in the same manner as in Example 1 above.
[실시예 3]Example 3
백리향 정유 2중량%, 오리가노 정유 0.5중량%, 시트로넬라 정유 1.5중량%, 스피어민트 정유 0.5중량%, 정향 정유 0.3중량%, 솔비탄 모노올레이트 2중량%, Ciba® TINUVIN® 123 0.2중량%, 메틸 안트라닐레이트 3중량% 및 비누 베이스 90중량%를 사용하여 상기의 실시예 1과 동일한 방법으로 고상의 조류퇴치제를 제조하였다.2% thyme essential oil, 0.5% oregano essential oil, 1.5% citronella essential oil, 0.5% spearmint essential oil, 0.3% cloves essential oil, 2% sorbitan monooleate, 0.2% by weight Ciba ® TINUVIN ® 123 Solid algae repellent was prepared in the same manner as in Example 1 using 3 wt% methyl anthranilate and 90 wt% soap base.
[실험예 2] 고상의 조류퇴치제에 따른 조류기피효과Experimental Example 2 Algae Avoidance Effect of Solid Algae Control Agent
실시예 1 내지 3에서 제조한 고상의 조류퇴치제의 조류기피효과를 평가하기 위해 성격이 활달하여 운동량이 많은 참새목 납부리과의 십자매를 대상으로 실험실 규모에서 조류기피효과를 확인하였다. 실시예 1 내지 3에서 제조한 고상의 조류퇴치제를 횃대에 설치한 뒤 횃대에 십자매의 착지 횟수나 행동이상 등을 관찰하였다.In order to evaluate the algal repellent effect of the solid algae repellent prepared in Examples 1 to 3, the algae repellent effect was confirmed on the laboratory scale of the cross-tailed family of the Sparrow beak family with high activity. After installing the solid algae repellent prepared in Examples 1 to 3 to the perch, the number of landings and behavioral abnormalities of the sisters were observed on the perch.
횃대에 설치된 실시예 1 내지 3에서 제조한 고상의 조류퇴치제에 노출된 십자매는 횃대에 착지하려는 시도를 하지 않았으며, 고상의 조류퇴치제에 노출된 개체에서는 웅크림, 비벼댐, 머리 흔듦, 빠르게 부리 다듬음 및 접촉부위를 심하게 흔듦 등의 이상행동을 나타내는 등의 우수한 조류기피효과를 나타내었다.Cruciforms exposed to solid algae preparations prepared in Examples 1 to 3 installed on the perches did not attempt to land on the toe, and subjects exposed to solid algae exterminators squat, stir, shake hair, and quickly beak. It showed excellent algae avoidance effect such as abnormal behavior such as shaking the sound and contact area severely.
특별히, 실시예 3에서 제조한 고상의 조류퇴치제가 경도, 온도 및 수분에 의한 영향 등의 물리적 특성이 뛰어난 것으로 확인되었으며, 실제 야외에서 과수농가의 과수에 설치할 경우 비나 바람 등의 자연 환경에서 고상의 조류퇴치제가 유실되는 정도가 가장 적은 것으로 확인되었다.In particular, it was confirmed that the solid algae repellent prepared in Example 3 has excellent physical properties such as the effects of hardness, temperature, and moisture, and when installed in fruit trees of fruit farms in the open air, in the natural environment such as rain or wind. The loss of algae was found to be the least.
[실험예 3] 고상의 조류퇴치제의 십자매에 대한 효능평가Experimental Example 3 Evaluation of Efficacy of Solid Algae Repellent Cross
1. 실험방법1. Experiment Method
1) 공시동물1) animals
참새목 납부리과의 십자매를 이용하여 실험실 규모에서 조류기피효과를 확인하였다. 십자매는 한국 내에서 사육조로 널리 사육되고 있어 실험에 사용하기가 용이하며, 성격이 활달하여 운동량이 많아 조류기피효과 및 적응 여부를 판정하기 용이하기 때문에 시험동물로 공시하였다.The cross-border of the Sparrow-leaved beak family was used to confirm the effect of avoiding birds on a laboratory scale. The cross sisters are widely bred in Korea as breeding tanks, so they are easy to use in experiments.
2) 사육환경2) Breeding environment
수컷 십자매(n=10)는 대전 인근 조류원에서 구입하여, 실험실 조건(온도 20-22℃, 습도 50-70% 및 암기 0:00-06:00 h) 하에서 일주일간의 순화기간을 거친 후, 건강한 개체를 무작위로 선발하여 시험에 공시하였다.Male cruciforms (n = 10) were purchased from an algae near Daejeon, followed by a week-long purifying period under laboratory conditions (temperature 20-22 ° C, humidity 50-70%, and memorization 0: 00-06: 00 h). Subjects were randomly selected and published in the trial.
시험사육상자는 가로×세로×높이가 150×50×50 ㎝ 인 것을 사용하였으며, 사료와 음수는 자유급여하였다.The test box was used for the width × length × height 150 × 50 × 50 ㎝, free feed and negative water.
3) 고상의 조류퇴치제의 기피효과평가3) Evaluation of Evasive Effect of Solid Algae Repellent
실시예 3에서 제조한 고상의 조류퇴치제의 기피효과를 확인하기 위하여, 실시예 3에서 제조한 고상의 조류퇴치제를 횃대에 부착하였다. 실험실 조건하에서 1주일간의 순화기간 이후, 24시간 동안 비디오카메라를 이용하여, 횃대(roost)에 착지하는 횟수와 이상행동을 관찰하였다.In order to confirm the repellent effect of the solid algae repellent prepared in Example 3, the solid algae repellent prepared in Example 3 was attached to the perch. After a one-week purifying period under laboratory conditions, the number of landings and abnormal behaviors of the roosts were observed using a video camera for 24 hours.
시험물질의 피부접촉, 맛 및 향에 의한 대상조류의 육안적 행동 이상 유무는 비벼댐(Wiping), 머리 흔듦(Head shaking), 모근 기립(Piloerection), 빠르게 부리 다듬음(Quick-preening) 그리고 접촉부위를 심하게 흔듦 등으로 판정하여 조류의 반응을 관찰하였다.Visual behavior of the target algae due to skin contact, taste, and aroma of the test substance may be affected by wiping, head shaking, hairlorection, quick-preening, and contact. The site was judged to shake violently and the reaction of algae was observed.
4) 고상의 조류퇴치제의 적응여부 판별4) Determination of adaptation of solid algae repellent
실시예 3에서 제조한 고상의 조류퇴치제의 노출 후 적응여부를 확인하기 위하여, 24시간 동안 고상의 조류퇴치제에 노출된 공시동물을 다시 고상의 조류퇴치제가 설치되지 않은 사육상자로 옮긴 후 1주일간 순화시킨 뒤 정상적인 비행활동을 확인한 뒤 다시 고상의 조류퇴치제를 설치한 사육상자로 이동시킨 뒤 24시간 동안 비디오카메라를 이용하여 횃대에 착지하는 횟수와 이상행동 등을 관찰하였다.In order to confirm the adaptation after the exposure of the solid bird extinguishing agent prepared in Example 3, the animals exposed to the solid bird extinguishing agent for 24 hours were transferred to a breeding box without the solid bird extinguishing agent and purified for 1 week. After confirming the normal flight activity, it was moved to the breeding box installed with solid bird repellent and observed the number of times of landing on the perch and abnormal behavior by using a video camera for 24 hours.
1주일 간격으로 고상의 조류퇴치제의 노출을 4회 반복하여 공시조류의 학습 효과 및 조류기피제의 적응여부를 확인하였다. 시험물질의 접촉 및 향에 의한 대상조류의 육안적 행동이상 유무는 비벼댐(Wiping), 머리 흔듦(Head shaking), 모근 기립(Piloerection), 빠르게 부리 다듬음(Quick-preening) 그리고 접촉부위를 심하게 흔듦 등으로 판정하여 조류의 반응을 관찰하였다.The exposure of solid algae repellents was repeated four times at weekly intervals to confirm the learning effects of algae and adaptation of algae repellents. Visual behavior of the target algae due to the contact and scent of the test substance can be affected by wiping, head shaking, piererection, quick-preening and contact areas. Judging by shaking or the like, the reaction of the algae was observed.
2. 실험결과2. Experimental Results
1) 고상의 조류퇴치제의 기피효과1) Avoidance effect of solid algae repellent
순화기간 및 순화종류 후 고상의 조류퇴치제를 설치하기 전에는 대부분의 십자매는 횃대와 먹이통 및 물통을 번갈아가며 앉아 있으며, 정상적인 비행 활동을 나타내었다.After the period of acclimation and the type of acclimation, before the installation of the solid algae repellent, most crucifers alternated between perches, feeders and water bottles, and exhibited normal flight activity.
그러나 도 6에 도시된 바와 같이 고상의 조류퇴치제를 설치한 이후 횃대에 설치된 조류퇴치제에 착지하려는 시도를 나타내었다. 일부 십자매는 시험상자의 천장, 옆면, 또는 바닥에 착지하였다. 노출 30분 이후에는 모두 바닥이나 한쪽 구석에만 머물러 있었다. 종종 시험상자 내에서 횃대에 착지하려는 시도가 있었으나 천정이나 바닥 쪽으로 이동하였다.However, as shown in FIG. 6, an attempt was made to land on the bird repellent installed in the perch after installing the solid bird repellent. Some crosses landed on the ceiling, sides, or floor of the test box. After 30 minutes of exposure, all stayed in the floor or one corner. Often attempts were made to land on the perch within the test box but moved to the ceiling or floor.
고상의 조류퇴치제에 접촉한 개체에서는 웅크림, 비벼댐 및 빠르게 부리 다듬음 등의 이상행동을 나타내었다. 따라서 본 발명의 고상의 조류퇴치제는 우수한 조류기피효과를 나타냄을 알 수 있었다.Subjects in contact with solid algae control agents exhibited abnormal behaviors such as squatting, scrubbing and quick beak trimming. Therefore, it was found that the solid algae repellent of the present invention exhibited an excellent algal evacuation effect.
2) 고상의 조류퇴치제의 적응여부2) Adaptation of solid algae repellent
1회 고상의 조류퇴치제에 노출된 공시동물을 1주일간 고상의 조류퇴치제가 설치되지 않은 사육상자에서 정상적인 비행활동 및 행동양식을 회복한 것을 확인한 뒤 다시 고상의 조류퇴치제에 노출시킨 경우 모든 공시동물은 고상의 조류퇴치제에 접촉하지도 않았으며, 횃대에 착지하지 않는 양상을 보였다.When a test animal exposed to a solid bird repellent was recovered for one week in a cage without a solid bird repellent, it was found that normal flight activity and behavior had been restored, and then exposed again to the solid bird repellent. It did not touch solid algae and did not land on the perch.
간헐적으로 바닥과 먹이통 및 물통으로 이동할 뿐 고상의 조류퇴치가 설치된 횃대에는 착지하지 않았다. 이러한 결과는 고상의 조류퇴치제에 함유된 식물정유 및 메틸 안트라닐레이트 등의 강력한 향과 맛을 통한 자극이 있었으며, 고상의 조류기피제의 육안적 인지기능을 강화하기 위해 첨가된 자외선 흡수제 등을 첨가함으로써 십자매가 고상의 조류퇴치제에 노출되었던 경험에 의해 횃대에 착지하지 않은 것으로 판단된다. 이어서 계속되는 고상의 조류퇴치제의 노출과 순화과정의 반복에 의해서도 고상의 조류퇴치제에 적응하는 개체는 관찰되지 않았다.It only intermittently moved to the bottom, feeders, and buckets, and did not land on the perch with solid bird control. These results were stimulated through the powerful aroma and taste of plant essential oils and methyl anthranilate contained in the solid algae repellent, and by adding the ultraviolet absorber added to enhance the visual cognitive function of the solid algae repellent It is judged that they did not land on the perch based on their experience of being exposed to solid algae. Subsequent exposure of the solid algae control agent and repeated repetition of the purifying process were not observed in individuals adapting to the solids algae control agent.
모든 공시동물에서 고상의 조류퇴치제의 노출에 대한 학습효과로 고상의 조류퇴치제를 인지하고, 다시는 고상의 조류퇴치제가 설치되어 있는 횃대에 착지하지 않았으며, 이러한 고상의 조류퇴치제의 기피효과는 반복된 노출에도 적응을 보이지 않았다.All birds were recognized as a learning effect for exposure of solid bird repellents and never again landed on a perch with solid bird repellents. No exposure was observed.
따라서 본 발명의 고상의 조류퇴치 조성물은 반복적인 노출에 의한 적응이 관찰되지 않았으며, 학습효과에 의한 우수한 조류기피효과를 나타냄을 알 수 있었다.Therefore, the solid-state algae control composition of the present invention was not observed by repeated exposure, it can be seen that exhibiting excellent algae avoidance effect by the learning effect.
[실험예 4] 과수농가에서 고상의 조류퇴치제의 야생조류에 대한 실제 조류기피 효과평가Experimental Example 4 Evaluation of Actual Bird Avoidance Effect on Wild Algae of Solid Algae Repellent in Fruit Farms
1. 실험방법1. Experiment Method
사과를 재배하는 충주지역의 과수농가에서 과수에 피해를 주는 까치, 비둘기 및 직박구리 등의 야생조류에 대한 고상의 조류퇴치제의 효과를 알아보기 위해 실험을 실시하였다. 이때 야외실험을 위하여 가수농가 500평 규모의 사과나무 산밭을 가지고 실시예 3에서 제조한 고상의 조류퇴치제를 설치한 곳(A)과 설치하지 않은 곳(B)으로 나누어 조류퇴치효과를 평가하였다. 상기 고상의 조류퇴치제를 설치한 곳(A)과 설치하지 않은 곳(B)은 70m 떨어져 있는 산밭의 지형이었다. 실시예 3에서 제조한 고상의 조류퇴치제를 사과나무 한 그루당 3개씩 설치하되, 사과나무 가지의 위치와 높이를 달리하여 설치하였다.An experiment was conducted to investigate the effects of solid bird repellent on wild birds such as magpies, pigeons, and direct-copper dams in fruit farms in Chungju, Korea. At this time, the algae eradication effect was evaluated by dividing into a place (A) and a place (B) where the solid algae repellent prepared in Example 3 was prepared with an apple tree field of 500 pyeong in the singer's farm. The place (A) and the place (B) where the solid bird repellent was installed were 70m away from the mountainous terrain. Three algae repellents prepared in Example 3 were installed per apple tree, but were installed with different positions and heights of apple tree branches.
2. 실험결과2. Experimental Results
과수농가의 실험장소는 평야 지역이 아닌 산밭에 위치한 과수 지역으로 야산에 매우 밀접하게 위치한 지형으로서 야생 조류의 접근이 매우 용이한 장소였다. 평상시에도 야생 조류에 의한 피해가 있던 곳으로 새그물을 이용한 조류의 피해를 억제하는 방법을 사용했음에도 계속적인 야생조류의 침입으로 피해를 보고 있었다.The experiment site of the fruit farm was not a plain but a fruit tree located in a mountain field, which is a very close terrain to the mountain, and was easily accessible to wild birds. In spite of the damage caused by wild birds in the normal place, the bird was using damage to bird damage, but it was suffering from the continuous invasion of wild birds.
고상의 조류퇴치제의 설치 전에는 까치, 비둘기 및 직박구리 등의 야생조류에 의한 과수의 손실이 있었다.Prior to the installation of solid bird repellents, there was a loss of fruit trees by wild birds such as magpies, pigeons, and straight-eyed copper.
도 7에 도시된 바와 같이, 2011년 8월 ~ 2011년 10월(3개월) 동안 고상의 조류퇴치제를 설치하지 않은 곳(B)은 야생조류가 이전과 동일하게 과수나무에 수시로 사과나무 밭에 침입하여 피해를 주었다. 이때 야생조류의 공격에 의한 과수 103그루 중에 98그루의 과수에 상처나 낙과를 입혀 그 피해율을 약 95.1%의 결과를 나타내었다. 이들 과수나무는 평균적으로 사과나무 한 그루당 약 5개 내지 7개 정도의 손실을 보였다. As shown in FIG. 7, the place (B) where no algae repellent was installed during the period of August 2011 to October 2011 (3 months) was used in the apple trees as often as the wild birds. Invaded and damaged. At this time, out of 103 trees of wild birds attacked, 98 trees were injured or fallen, resulting in a 95.1% damage rate. These fruit trees averaged about 5 to 7 losses per apple tree.
그러나 도 8에 도시된 바와 같이, 2011년 8월 ~ 2011년 10월(3개월) 동안 실시예 3에서 제조한 고상의 조류퇴치제를 설치한 곳(A)은 설치 후 야생조류인 까치나 비둘기 등이 사과나무 밭에 거의 들어오지 않거나 이따금 산밭의 상공에서 비행하는 수준만을 관찰하였다. 실시예 3에서 제조한 고상의 조류퇴치제를 설치한 산밭에서 98그루의 사과나무에 다만 2그루의 나무만이 피해가 발생하여 약 2%에 해당하는 손실을 나타내었으며 이때의 피해를 보인 과실은 3개만 관찰되었다.However, as shown in FIG. 8, the place where the solid bird repellent prepared in Example 3 was installed during the period of August 2011 to October 2011 (3 months) (A) is a wild bird magpie or pigeon. We have only observed levels that rarely enter or occasionally fly over the field of apple trees. In the mountain field where the solid algae-reducing agent prepared in Example 3 was installed, only two trees were damaged by 98 apple trees, resulting in about 2% loss. Only dogs were observed.
따라서 본 발명의 고상의 조류퇴치 조성물은 새로운 유해조류 기피성분의 복합적인 혼합물을 구성하여 우수한 조류퇴치 효과를 나타내며, 또한 기피성분들이 온도, 습도 등 외부환경에 대한 제형의 손실을 최소화하여 보다 안정화된 제형을 구축함으로써 조류기피 효능을 강화시켰다.Therefore, the solid algae composition of the present invention constitutes a complex mixture of new harmful algae repellents and shows excellent algae control effect, and the repellents are more stabilized by minimizing the loss of the formulation to the external environment such as temperature and humidity. The formulation was strengthened to enhance algal evacuation efficacy.
[실시예 4]Example 4
백리향 정유 1중량%, 오리가노 정유 0.5중량%, 시트로넬라 정유 1중량%, 스피어민트 정유 1중량%, 정향 정유 1중량%, 솔비탄 모노올레이트 1중량%, Ciba® TINUVIN® 123 0.5중량%, 메틸 안트라닐레이트 4중량% 및 비누 베이스 90중량%를 사용하여 상기의 실시예 1과 동일한 방법으로 고상의 조류퇴치제를 제조하였다.1% by weight of thyme essential oil, 0.5% by weight of oregano essential oil, 1% by weight citronella essential oil, 1% by weight spearmint essential oil, 1% by weight clove essential oil, 1% by weight sorbitan monooleate, 0.5% by weight Ciba ® TINUVIN ® 123 Using 4 wt% methyl anthranilate and 90 wt% soap base, a solid algae repellent was prepared in the same manner as in Example 1 above.
[비교예 1] Comparative Example 1
계피정유, 박하정유, 유화제를 혼합기에 넣어 골고루 혼합한 뒤 UV 흡수제 및 메틸 안트라닐레이트를 첨가하여 혼련하였다. 마지막으로 폴리부탄 및 그리스를 첨가하여 충분히 혼합하여 겔상의 조류퇴치 조성물을 제조하였다. Cinnamon essential oil, peppermint essential oil, and an emulsifier were added to the mixer and mixed evenly, followed by kneading by adding a UV absorber and methyl anthranilate. Finally, polybutane and grease were added and mixed sufficiently to prepare a gel algae composition.
이때, 각 성분의 함량은 각각 폴리부탄 65중량%, 그리스 25중량%, Ciba® TINUVIN® 99-2 0.5중량%, 메틸 안트라닐레이트 4중량%, 계피정유 1.5중량%, 박하정유 3중량% 및 솔비탄 모노올레이트 1중량%를 사용하였다.At this time, the content of each component is 65% by weight of polybutane, 25% by weight of grease, 0.5% by weight of Ciba ® TINUVIN ® 99-2, 4% by weight of methyl anthranilate, 1.5% by weight of cinnamon essential oil, 3% by weight of peppermint essential oil and 1 wt% of sorbitan monooleate was used.
[실험예 5] 과수농가에서 겔상의 조류퇴치 조성물과 고상의 조류퇴치 조성물의 야생조류에 대한 실제 조류기피 효능평가Experimental Example 5 Evaluation of Actual Algae Efficacy on Wild Algae of Gel-like Algae and Solid-state Algae Composition in Fruit Farms
1. 실험방법1. Experiment Method
배를 재배하는 천안지역의 과수농가에서 과수에 피해를 주는 까치, 비둘기 및 직박구리 등의 야생조류에 대한 계피정유와 박하정유를 포함하는 겔상의 조류퇴치 조성물과 새로운 5가지 식물정유를 포함하는 고상의 조류퇴치 조성물에 대한 효능을 비교하기 위해 실험을 실시하였다. 이때 야외실험을 위하여 가수농가 약 600평 규모의 배나무 밭에서 1개월 동안 비교실험을 실시하였다. 약 300평의 배나무 밭(C 지역, 배나무 49그루)에 비교예 1에서 제조한 겔상의 조류퇴치 조성물 30g을 플라스틱 용기에 담아 배나무 한 그루당 3개씩 나뭇가지에 설치하였다. 또한, 약 300평의 배나무 밭(D 지역, 배나무 51그루)에 실시예 4에서 제조한 고상의 조류퇴치제를 부직포 용기에 담아 배나무 한 그루당 3개씩 나뭇가지에 설치한 후, 야생 조류의 침입에 의한 피해를 관찰하였다.Gel-based algae control composition including cinnamon essential oil and peppermint essential oil for wild birds such as magpies, pigeons, and straight-eyed copper that damages fruit trees in fruit farms in Cheonan, Korea, where pears are grown. Experiments were conducted to compare the efficacy of the algal combat composition. At this time, for an outdoor experiment, a comparison experiment was conducted for one month in a pear tree field of about 600 pyeong on a singer farm. 30 g of the algae control composition prepared in Comparative Example 1 was placed in a plastic container in a pear tree field (C area, 49 pear trees) of about 300 pyeong and installed on a branch of three pears per tree. In addition, the solid algae repellent prepared in Example 4 was placed in a pear tree field (51 D pear trees) of about 300 pyeong in a non-woven container and installed on a branch of three pears per tree, and then invaded by wild birds. Damage was observed.
2. 실험결과2. Experimental Results
과수농가의 실험 장소는 평야 지역으로 야생 조류의 접근이 용이한 곳이며, 평상시에도 야생 조류에 의한 피해가 있던 곳으로 여러 가지 조류의 피해를 억제하는 방법을 사용했음에도 야생조류의 침입으로 피해를 보고 있었다.The experiment site of the fruit farms is a plain area where wild birds are easily accessible, and it was a place where wild birds were normally damaged. there was.
도 9에 도시된 바와 같이, 겔상의 조류퇴치 조성물을 설치한 곳(C 지역)은 야생조류가 배나무 밭에 침입하여 많은 과수에 피해를 입힌 것을 관찰할 수 있었다. 이때 야생조류의 침입에 의한 과수 49그루 중에 43그루의 과수에 상처 입히거나 공격하여 낙과를 시킴으로써 그 피해율은 약 87.8%의 결과를 나타내었다. As shown in Figure 9, where the gel-like algae control composition (C region) was installed, it was observed that the algae invaded the pear field and caused damage to many fruits. At this time, the damage rate was about 87.8% by injuring or attacking 43 fruits of 49 fruits among wild birds.
그러나 고상의 조류퇴치제를 설치한 곳(D 지역)은 설치 후 야생조류인 까치나 비둘기 등이 배나무 밭에 가끔 들어오거나 상공에서 비행하는 수준만을 관찰하였다. 고상의 조류퇴치제를 설치한 곳(D 지역)에서는 51그루의 배나무에 다만 3그루의 나무만이 피해가 발생하여 약 5.9%에 해당하는 피해율을 보였으며 이때의 손실을 입힌 과실은 단지 6개만 관찰되었다. However, after installing the solid bird repellent (D area), they observed only wild magpies or pigeons, such as the occasional infestation of pear trees or flying over them. In the place where solid bird repellent was installed (D area), only 51 trees were damaged and only 3 trees suffered damage, which was about 5.9%, and only 6 fruits were lost. It became.
따라서 본 발명에 따른 고상의 조류퇴치 조성물은 새로운 5가지의 식물추출 정유를 포함함으로, 계피정유와 박하정유를 포함하는 종래의 겔상의 조류퇴치 조성물에 비해 조류기피효능이 뛰어남을 야외 임상실험을 통하여 확인하였다.Therefore, the solid algae combatant composition according to the present invention includes five new plant-derived essential oils, through the outdoor clinical trials that the algal repellency effect is superior to the conventional gel-like algae control composition containing cinnamon essential oil and peppermint essential oil. Confirmed.

Claims (4)

  1. 경화제 40~95중량%, 백리향 정유 0.05~20중량%, 오리가노 정유 0.05~10중량%, 시트로넬라 정유 0.1~20중량%, 스피어민트 정유 0.1~10중량%, 정향 정유 0.1~10중량%, 메틸 안트라닐레이트(methyl anthranilate) 0.2~20중량%, 자외선 흡수제 0.01~4중량% 및 유화제 1~10중량%를 포함하는 것을 특징으로 하는 고상의 조류퇴치 조성물.40 to 95% by weight of curing agent, 0.05 to 20% by weight of thyme essential oil, 0.05 to 10% by weight of oregano essential oil, 0.1 to 20% by weight of citronella essential oil, 0.1 to 10% by weight of spearmint essential oil, 0.1 to 10% by weight of clove essential oil, Solid phase algae composition comprising 0.2 to 20% by weight of methyl anthranilate, 0.01 to 4% by weight of ultraviolet absorber and 1 to 10% by weight of emulsifier.
  2. 제 1항에 있어서,The method of claim 1,
    상기 경화제는 비누베이스인 것을 특징으로 하는 고상의 조류퇴치 조성물.Solid-state algae composition, characterized in that the curing agent is a soap base.
  3. 제 1항에 있어서,The method of claim 1,
    상기 자외선 흡수제는 힌더드 아민(Hindered amine)계 자외선 흡수제인 것을 특징으로 하는 고상의 조류퇴치 조성물.The ultraviolet absorber is a hindered amine (Hindered amine) ultraviolet absorber, characterized in that the solid-state algae composition.
  4. 제 1항에 있어서,The method of claim 1,
    상기 유화제는 솔비탄 지방산 에스테르인 것을 특징으로 하는 고상의 조류퇴치 조성물.The emulsifier is sorbitan fatty acid ester, characterized in that the solid algae composition.
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KR100798290B1 (en) * 2007-05-28 2008-02-04 전진바이오팜 주식회사 Gel-type bird aversion compositions
KR20100012183A (en) * 2008-07-28 2010-02-08 이봉수 Bird-repellent solid substance, bird-repelling method utilizing same and method for storing same
JP2010059149A (en) * 2008-08-04 2010-03-18 Mitsubishi-Kagaku Foods Corp Antibacterial agent and disinfecting method

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN108124912A (en) * 2018-02-10 2018-06-08 王鹏飞 A kind of bird driving composition and preparation method thereof
CN108157398A (en) * 2018-02-10 2018-06-15 王鹏飞 A kind of bird driving composition based on soap base and preparation method thereof

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