WO2013054433A1 - Générateur de gaz d'hydrogène-oxygène - Google Patents

Générateur de gaz d'hydrogène-oxygène Download PDF

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Publication number
WO2013054433A1
WO2013054433A1 PCT/JP2011/073627 JP2011073627W WO2013054433A1 WO 2013054433 A1 WO2013054433 A1 WO 2013054433A1 JP 2011073627 W JP2011073627 W JP 2011073627W WO 2013054433 A1 WO2013054433 A1 WO 2013054433A1
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WO
WIPO (PCT)
Prior art keywords
electrolytic cell
hydrogen
oxygen gas
gas generator
electrolytic
Prior art date
Application number
PCT/JP2011/073627
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English (en)
Japanese (ja)
Inventor
好正 高部
Original Assignee
株式会社エスマック
株式会社昭和テックス
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by 株式会社エスマック, 株式会社昭和テックス filed Critical 株式会社エスマック
Priority to JP2013538406A priority Critical patent/JP5893637B2/ja
Priority to PCT/JP2011/073627 priority patent/WO2013054433A1/fr
Publication of WO2013054433A1 publication Critical patent/WO2013054433A1/fr

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    • C—CHEMISTRY; METALLURGY
    • C25—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES; APPARATUS THEREFOR
    • C25B—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES FOR THE PRODUCTION OF COMPOUNDS OR NON-METALS; APPARATUS THEREFOR
    • C25B15/00—Operating or servicing cells
    • C25B15/02—Process control or regulation
    • C—CHEMISTRY; METALLURGY
    • C25—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES; APPARATUS THEREFOR
    • C25B—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES FOR THE PRODUCTION OF COMPOUNDS OR NON-METALS; APPARATUS THEREFOR
    • C25B1/00—Electrolytic production of inorganic compounds or non-metals
    • C25B1/01—Products
    • C25B1/02—Hydrogen or oxygen
    • C25B1/04—Hydrogen or oxygen by electrolysis of water
    • C—CHEMISTRY; METALLURGY
    • C25—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES; APPARATUS THEREFOR
    • C25B—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES FOR THE PRODUCTION OF COMPOUNDS OR NON-METALS; APPARATUS THEREFOR
    • C25B9/00—Cells or assemblies of cells; Constructional parts of cells; Assemblies of constructional parts, e.g. electrode-diaphragm assemblies; Process-related cell features
    • C25B9/05—Pressure cells
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02E—REDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
    • Y02E60/00—Enabling technologies; Technologies with a potential or indirect contribution to GHG emissions mitigation
    • Y02E60/30—Hydrogen technology
    • Y02E60/36—Hydrogen production from non-carbon containing sources, e.g. by water electrolysis

Definitions

  • the present invention relates to an apparatus for generating hydrogen and oxygen gas by electrolysis, and more particularly to an apparatus capable of efficiently generating a mixed gas of hydrogen and oxygen in a compact size. is there.
  • an apparatus for producing hydrogen and oxygen by electrolyzing water As an apparatus for generating a mixed gas of hydrogen and oxygen, an apparatus for producing hydrogen and oxygen by electrolyzing water is known. Supplying water with a small amount of electrolytic substance into the electrolytic cell in which the anode and cathode electrodes are installed, and applying a DC voltage, a mixed gas of hydrogen and oxygen (generally a non-polluting energy source) , Also called “Brown Gas”). At this time, the generated hydrogen gas and oxygen gas are generated at a molar ratio of 2: 1 and are generated in the form of bubbles on the surface of the cathode electrode. The hydrogen gas and oxygen gas thus produced are mixed to form a mixed gas and are collected above the electrolytic solution in the electrolytic cell. By taking out the mixed gas of hydrogen gas and oxygen gas generated in this way from the electrolytic cell, it can be used as an environmentally friendly energy source that does not generate pollutants during combustion.
  • Patent Document 1 Japanese Patent Laid-Open No. 2000-129480.
  • the hydrogen-oxygen gas generator disclosed in Patent Document 1 has the following configuration. That is, A lower fixture 3 is coupled to a fastening groove 2 formed at equal intervals on the base 1, and rectangular electrode plates 4 and 5 are erected in an insertion groove 3c formed in the lower fixture 3.
  • the upper fixture 6 having an insertion groove formed on the bottom is coupled to the upper portion, and the stay bolts are inserted into the through holes 3d and 6d formed on both sides of the base 1, the lower fixture 3 and the upper fixture 6.
  • Electrode apparatus 10 in which electrode unit A formed integrally by combining 8 is aligned, and fin tubes 14 on both sides of cooling section 13 in which a certain length of gas rising pipe 11 and electrolyte lowering pipe 12 is bent in a meandering manner. And an electrolyte cooling device 20 having a cooling fan 15 installed in the center of the inside, a water level sensor 21 in the inside, a gas riser pipe 11 connected to the electrolysis device 10 in the lower part on one side, and a water supply in the upper part A gas exhaust pipe 26 connected to the tank 30 is installed, and an electrolyte descending pipe 12 connected to a certain part of the water supply pipe 28 is fixed to the bottom of the other side.
  • the hydrogen-oxygen gas generator of the invention disclosed in Patent Document 1 includes an electrolytic device 10 disposed on a lower electrolytic solution tank 40, an electrolytic solution cooling device 20 disposed on the electrolytic device 10, and an electrolytic solution.
  • an electrolytic device 10 disposed on a lower electrolytic solution tank 40
  • an electrolytic solution cooling device 20 disposed on the electrolytic device 10
  • an electrolytic solution By providing a complicated structure in which a gas collection tank 25 is further provided on the cooling device 20, the electrolyte is naturally circulated by gravity, and as a result, the hydrogen-oxygen gas generator is operated while the electrolyte is naturally cooled. The method of doing was adopted.
  • the entire hydrogen-oxygen gas generator is large, and even though the electrolyte is cooled, the electrolyte flows from the electrolyzer to the electrolyte cooler by natural convection and is cooled, In order to control the electrolyte temperature to a specific temperature range, it was not possible to cool it, and the generation efficiency of hydrogen-oxygen gas was not sufficient.
  • Patent Document 1 Japanese Patent Laid-Open No. 2000-129480
  • the present invention has been made from such a viewpoint, and by reducing the size of the hydrogen-oxygen gas generation device and improving the generation efficiency of the hydrogen-oxygen gas, the hydrogen-oxygen gas generation per unit volume of the device is achieved.
  • the purpose is to maximize the quantity.
  • a hydrogen-oxygen gas generator An electrolytic cell for generating a mixed gas of hydrogen and oxygen by electrolysis; A pure water supply tank for storing pure water to be connected to the electrolytic cell and supplied to the electrolytic cell; A heat dissipating device for controlling the electrolyte temperature to a predetermined temperature range by being forced to circulate the electrolyte in the electrolytic cell connected to the electrolytic cell, A control device for controlling the hydrogen-oxygen gas generator,
  • the electrolytic cell is attached to the electrolytic cell container, the electrolytic solution accommodated in the electrolytic cell container, the anode electrode and the cathode electrode disposed in the electrolytic solution, and the electrolytic cell container for measuring the electrolytic solution temperature.
  • a temperature sensor and an electrolytic cell container are provided, and are composed of an outlet port for taking out the generated mixed gas of hydrogen and oxygen
  • the heat dissipation device is connected to the electrolytic cell via a pipe, and includes a pump for forcibly circulating the electrolyte in the middle of the pipe between the electrolytic cell and the heat dissipation device.
  • the control device is a hydrogen-oxygen gas generator configured to control the electrolyte temperature within a predetermined temperature range by controlling the operation of the pump based on at least the electrolyte temperature measured by the temperature sensor.
  • the electrolytic cell further includes an anode terminal and a cathode terminal which are disposed in the electrolytic cell container and connected to the anode electrode and the cathode electrode, A direct current was input between the anode terminal and the cathode terminal.
  • the electrolyzer is configured to further include a relief port that is disposed in the electrolyzer vessel and relieves pressure inside the electrolyzer vessel.
  • the electrolytic cell is composed of a jammer plate disposed between the anode electrode and the cathode electrode, and a first plate and a second plate disposed to face the anode electrode and the cathode electrode, respectively. And a common electrode in which the second plate is connected across the jammer plate.
  • control device was configured to control the maximum temperature of the electrolyte solution to 70 ° C. or lower by controlling the operation of the pump.
  • control device is configured to control the maximum temperature of the electrolyte solution to 60 ° C. or less by controlling the operation of the pump.
  • the hydrogen-oxygen gas generator configured as described above is used to reduce the size of the hydrogen-oxygen gas generator and to improve the generation efficiency of the hydrogen-oxygen gas. It has become possible to provide a hydrogen-oxygen gas generator that maximizes the amount of hydrogen-oxygen gas generated per unit volume.
  • FIG. 1 shows a diagram of a hydrogen-oxygen gas generator according to the present invention.
  • FIG. 2 shows a plan view of the electrolytic cell of the hydrogen-oxygen gas generator according to the present invention.
  • FIG. 3 is a longitudinal sectional view of the electrolytic cell of the hydrogen-oxygen gas generating apparatus according to the present invention, and shows an arrow XX in FIG.
  • FIG. 4 is a longitudinal sectional view of the electrolytic cell of the hydrogen-oxygen gas generating apparatus according to the present invention, and shows a view YY in FIG.
  • FIG. 5 shows a hydrogen-oxygen gas generator according to the prior art.
  • FIG. 1 shows a diagram of a hydrogen-oxygen gas generator according to the present invention.
  • a hydrogen-oxygen gas generating apparatus 1 according to the present invention includes an electrolytic cell 10, a heat radiating device 30, a pure water replenishing tank 40, and a control device 50. Further, the hydrogen-oxygen gas generating device 1 is supplied with electric power from an external power source 60. Is to be supplied.
  • the electrolytic cell 10 has an anode terminal 12-1 and a cathode terminal 12-2 for receiving electric power supplied from a power source, and measures the temperature of the electrolyte stored in the electrolytic cell 10.
  • a thermocouple 19 a relief port 21 for releasing the pressure when the internal pressure of the electrolytic cell 10 rises above a predetermined pressure, and a pure water supply port 22 for supplying pure water into the electrolytic cell 10 are provided.
  • the electrolytic cell 10 is provided with a mixed gas extraction port 23 for extracting a mixed gas of hydrogen and oxygen generated in the electrolytic cell 10.
  • FIG. 2 shows one embodiment of the electrolytic cell 10, and shows a plan view of the electrolytic cell 10.
  • the thermocouple 19 the relief port 21, the pure water supply port 22, and the mixed gas take-out port 23 are omitted from illustration.
  • the electrolytic cell 10 further includes an electrolytic cell container 11, an electrolytic solution 18 accommodated in the electrolytic cell container, an anode electrode 14-1 and a cathode electrode 14-2 disposed in the electrolytic solution 18, and an anode electrode.
  • the lower electrode support plates 16 and 16 are composed of an anode electrode 14-1, a cathode electrode 14-2, and upper electrode support plates 17 and 17 that hold the common electrode 13 above.
  • the electrolytic cell container 11 has a watertight structure for containing the electrolytic solution 18 therein, and is made of a nonconductive material in order to prevent leakage of electricity.
  • a structure in which a cylindrical member made of polyvinyl chloride (PVC) and an upper and lower plate are joined to form a watertight structure is adopted, but a material in which the surface of a stainless steel plate is coated with polyvinyl chloride is used. By using it, the strength and durability of the container can be improved.
  • PVC polyvinyl chloride
  • the anode electrode 14-1 and the cathode electrode 14-2 arranged in the electrolytic solution 18 have a rectangular flat plate structure and are made of a conductive material such as a stainless steel plate. Between the anode electrode 14-1 and the cathode electrode 14-2, as shown in FIG. 3, a jammer plate 24 made of a non-conductive material such as polyvinyl chloride is disposed. The cathode electrode 14-2 is disposed in the electrolytic solution without directly facing it. Therefore, the common electrode 13 is disposed so as to face the anode electrode 14-1 and the cathode electrode 14-2. As shown in FIG.
  • the common electrode 13 includes a first plate 13-1 and a second plate 13-2, and a connecting portion 13 that connects the first plate 13-1 and the second plate 13-2. -3. And this connecting part 13-3 is arranged so as to straddle the jammer plate 24.
  • the common electrode 13 is made of a conductive material such as a stainless steel plate.
  • an intermediate electrode (not shown) is arranged between each of them. You may make it do.
  • the intermediate electrode in this case can also be composed of a conductive material such as a stainless steel plate.
  • anode electrode 14-1, cathode electrode 14-2, and common electrode 13 are held so as to be sandwiched from above and below by the lower electrode support plates 16 and 16 and the upper electrode support plates 17 and 17 ( (See Figures 2, 3, and 4).
  • anode electrode 14-1 and the cathode electrode 14-2 described above are connected to the anode terminal 12-1 and the cathode terminal 12-2 fixed to the electrolytic cell container 11, respectively, and the anode terminal 12-1, In addition, power can be supplied from an external power source 60 connected to the cathode terminal 12-2.
  • an aqueous electrolyte solution such as KOH or NaOH can be used.
  • 6% by weight of electrolytic NaOH was dissolved in pure water (distilled water).
  • An aqueous solution was used. Note that the concentration of the electrolytic solution is not limited to 6% by weight, and can be appropriately selected depending on use conditions and the like.
  • the electrolytic cell 10 also includes a relief port 21.
  • the relief port 21 is provided to relieve pressure when the pressure in the electrolytic cell 10 rises above a predetermined pressure.
  • a pipe is connected to the relief port 21, and an electromagnetic valve 25 is provided in the middle of the pipe.
  • This electromagnetic valve 25 is electrically connected to a control device 50 described later, and the control device 50 opens and closes the electromagnetic valve 25 based on the pressure in the electrolytic cell 10 detected by a pressure sensor (not shown) or the like. It is like that. Thereby, the pressure in the electrolytic cell 10 can be maintained below a predetermined pressure.
  • the electromagnetic valve is connected to the relief port 21, but the present invention is not limited to this, and a commonly used relief valve may be provided.
  • the electrolytic cell 10 is provided with a mixed gas extraction port 23.
  • the mixed gas take-out port 23 is provided for taking out a mixed gas of hydrogen and oxygen generated in the electrolytic cell 10.
  • a pipe is connected to the mixed gas take-out port 23, and a check valve is provided in the middle of the pipe so as to prevent the backflow of the mixed gas of hydrogen and oxygen.
  • the hydrogen-oxygen gas generator 1 includes a pure water supply tank 40.
  • This pure water replenishment tank 40 stores pure water (distilled water) in order to replenish pure water (distilled water) to the electrolytic cell 10 when the electrolytic solution 18 in the electrolytic cell 10 decreases. is there.
  • the pure water supply tank 40 is connected to the pure water supply port 22 of the electrolytic cell 10 by piping, and an electromagnetic valve 26 is provided in the middle of the piping.
  • This electromagnetic valve 26 is electrically connected to a control device 50, which will be described later, and based on the liquid level position of the electrolytic solution 18 in the electrolytic cell 10 detected by a level sensor (not shown) or the like, the control device 50 By opening and closing 26, pure water (distilled water) is supplied to the electrolytic cell 10.
  • the hydrogen-oxygen gas generator 1 includes a heat dissipation device 30.
  • This heat radiating device is used to maintain the temperature of the electrolytic solution 18 in the electrolytic cell 10 within a predetermined temperature range.
  • the oxygen gas generator 1 While operating the oxygen gas generator 1, it is very important to maintain the temperature of the electrolyte 18 preferably at 70 ° C or lower, more preferably at 60 ° C or lower.
  • the heat dissipating device 30 is used to maintain the temperature of the electrolyte solution 18 during operation of the hydrogen-oxygen gas generator 1 within the above temperature range.
  • the heat dissipation device 30 is connected to the electrolytic cell 10 by two pipes, and a pump 31 is disposed in the middle of the pipes.
  • This pump 31 is electrically connected to a control device 50 described later, and the control device 50 drives the pump 31 based on the electrolyte temperature measured by a thermocouple 19 (temperature sensor) provided in the electrolytic cell container 11. It comes to control.
  • the electrolytic solution 18 in the electrolytic cell 10 is forcibly circulated to the heat radiating device, and is radiated and cooled in the heat radiating device 30 to be controlled to a predetermined temperature.
  • the heat dissipation device 30 a structure having a structure in which an electrolytic solution is circulated in a plate having a large number of heat dissipation fins can be used.
  • the heat dissipation device 30 is not limited to such a structure.
  • the hydrogen-oxygen gas generator 1 includes a control device 50.
  • the control device 50 performs drive control of the pump 31 of the heat dissipation device 30 based on the temperature of the electrolytic solution 18, or the electromagnetic device connected to the pure water supply tank 40 based on the liquid level position of the electrolytic solution 18 in the electrolytic cell 10.
  • the valve 26 is opened and closed to supply pure water (distilled water) to the electrolytic cell 10, or the electromagnetic valve 25 connected to the relief port 21 is opened and closed based on the pressure in the electrolytic cell 10 to open and close the electrolytic cell 10
  • the internal pressure can be controlled to be within a predetermined pressure.
  • an external power source 60 provided separately from the hydrogen-oxygen gas generator 1 according to the present invention is for supplying power to the hydrogen-oxygen gas generator 1, and serves as an anode and a cathode of the power source 60.
  • the terminals are respectively connected to the anode terminal 12-1 and the cathode terminal 12-2 of the electrolytic cell 10 described above.
  • the power supplied from the power source 60 to the electrolytic cell 10 is DC 12 V, 19 to 22 A, but is not limited to this.
  • the output current of the power supply 60 can be controlled by the control device 50 described above.
  • Electrolysis tank 11 Electrolyzer container 12-1 Anode terminal 12-2 Cathode terminal 13 Common electrode 13-1 First plate 13-2 Second plate 13-3 Connecting part 14-1 Anode electrode 14-2 Cathode electrode 16 Lower electrode support plate 17 Upper electrode support plate 18 Electrolyte 19 Thermocouple (temperature sensor) 21 Relief port 22 Pure water supply port 23 Mixed gas removal port 24 Jama board 25 Solenoid valve 26 Solenoid valve 30 Heat dissipation device 31 Pump 40 Pure water supply tank 50 Control unit 60 power supply

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  • Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Electrochemistry (AREA)
  • Materials Engineering (AREA)
  • Metallurgy (AREA)
  • Organic Chemistry (AREA)
  • Inorganic Chemistry (AREA)
  • Automation & Control Theory (AREA)
  • Electrolytic Production Of Non-Metals, Compounds, Apparatuses Therefor (AREA)

Abstract

L'invention concerne un générateur de gaz qui comprend: une cellule électrolytique qui génère un mélange gazeux d'hydrogène et d'oxygène au moyen d'une électrolyse; un réservoir d'alimentation pour stocker de l'eau pure avec laquelle la cellule électrolytique est alimentée, le réservoir d'alimentation ayant été connecté à la cellule électrolytique ; un radiateur pour réguler la température d'une solution électrolytique à l'intérieur de la cellule électrolytique à une valeur dans une plage de température donnée en faisant circuler de manière forcée la solution électrolytique à travers le radiateur ; et un contrôleur pour contrôler le générateur de gaz. La cellule électrolytique est configurée de : un récipient ; une solution électrolytique maintenue dans le récipient ; une anode et une cathode qui ont été disposées dans la cellule électrolytique ; un capteur de température pour mesurer la température de la solution électrolytique, le capteur ayant été attaché au récipient ; et un orifice de sortie pour soutirer un mélange gazeux d'hydrogène et d'oxygène qui ont été générés, l'orifice de sortie ayant été disposé sur le récipient. Le radiateur a été connecté à la cellule électrolytique par une conduite et la conduite entre la cellule électrolytique et le radiateur est équipée quelque part dans celle-ci d'une pompe pour faire circuler de manière forcée la solution électrolytique. Le contrôleur contrôle le fonctionnement de la pompe au moins sur la base de la température de la solution électrolytique mesurée avec le capteur de température et permet ainsi de réguler la température de la solution électrolytique à une valeur dans une plage de température donnée.
PCT/JP2011/073627 2011-10-14 2011-10-14 Générateur de gaz d'hydrogène-oxygène WO2013054433A1 (fr)

Priority Applications (2)

Application Number Priority Date Filing Date Title
JP2013538406A JP5893637B2 (ja) 2011-10-14 2011-10-14 水素−酸素ガス発生装置
PCT/JP2011/073627 WO2013054433A1 (fr) 2011-10-14 2011-10-14 Générateur de gaz d'hydrogène-oxygène

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
PCT/JP2011/073627 WO2013054433A1 (fr) 2011-10-14 2011-10-14 Générateur de gaz d'hydrogène-oxygène

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Cited By (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO2016186572A1 (fr) * 2015-05-19 2016-11-24 Lien Chiow Tan Moteur thermique ambiant
US20170327960A1 (en) * 2016-05-13 2017-11-16 Honda Motor Co., Ltd. Water electrolysis system and temperature control method thereof
CN113549954A (zh) * 2021-08-10 2021-10-26 阳光新能源开发有限公司 一种电解制氢系统装置及其控制方法
EP4109018A4 (fr) * 2020-03-24 2023-08-02 Hefei Midea Refrigerator Co., Ltd. Module d'élimination d'oxygène, dispositif de conservation au frais et réfrigérateur

Citations (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP2001310188A (ja) * 2000-05-02 2001-11-06 Sanyo Electric Co Ltd 水処理用電極ユニット
JP2003265400A (ja) * 2002-01-09 2003-09-24 Denso Corp 食器洗浄装置
JP2004131746A (ja) * 2002-10-08 2004-04-30 Denso Corp 水素ガス供給装置
JP2009174043A (ja) * 2007-12-27 2009-08-06 Toshigoro Sato 水電解ガス発生装置
JP2010029841A (ja) * 2008-07-03 2010-02-12 Hiroshima Kasei Ltd 加水素水の製造方法
JP2011058015A (ja) * 2009-09-07 2011-03-24 Toyo Tanso Kk 電解装置

Family Cites Families (8)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CA1148497A (fr) * 1978-07-19 1983-06-21 Thomas G. Hart Electrolyse d'halo-acide obtenu a partir d'halogene et d'eau avec presence de carbone
US7459071B2 (en) * 2001-05-02 2008-12-02 Japan Techno Co., Ltd. Hydrogen-oxygen gas generator and method of generating hydrogen-oxygen gas using the generator
JP4095782B2 (ja) * 2001-09-28 2008-06-04 三菱重工業株式会社 ガス発生装置
JP2006263615A (ja) * 2005-03-24 2006-10-05 Noritz Corp ガス溶解水製造装置のガス充填方法
JP2006330116A (ja) * 2005-05-23 2006-12-07 Olympus Corp 複合光学レンズとその製造方法
KR20090030555A (ko) * 2007-09-20 2009-03-25 주식회사 이앤이 강제순환 수냉 냉각시스템 Ｂｒｏｗｎ'ｓ Ｇａｓ 발생장치
JP2010285679A (ja) * 2009-06-15 2010-12-24 Eiji Kino ブラウンガス発生装置
AU2011228059B2 (en) * 2010-03-19 2015-04-02 Taiko Pharmaceutical Co., Ltd. Electrolyzer

Patent Citations (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP2001310188A (ja) * 2000-05-02 2001-11-06 Sanyo Electric Co Ltd 水処理用電極ユニット
JP2003265400A (ja) * 2002-01-09 2003-09-24 Denso Corp 食器洗浄装置
JP2004131746A (ja) * 2002-10-08 2004-04-30 Denso Corp 水素ガス供給装置
JP2009174043A (ja) * 2007-12-27 2009-08-06 Toshigoro Sato 水電解ガス発生装置
JP2010029841A (ja) * 2008-07-03 2010-02-12 Hiroshima Kasei Ltd 加水素水の製造方法
JP2011058015A (ja) * 2009-09-07 2011-03-24 Toyo Tanso Kk 電解装置

Cited By (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO2016186572A1 (fr) * 2015-05-19 2016-11-24 Lien Chiow Tan Moteur thermique ambiant
US20170327960A1 (en) * 2016-05-13 2017-11-16 Honda Motor Co., Ltd. Water electrolysis system and temperature control method thereof
EP4109018A4 (fr) * 2020-03-24 2023-08-02 Hefei Midea Refrigerator Co., Ltd. Module d'élimination d'oxygène, dispositif de conservation au frais et réfrigérateur
CN113549954A (zh) * 2021-08-10 2021-10-26 阳光新能源开发有限公司 一种电解制氢系统装置及其控制方法

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