WO2013008337A1 - Procédé de carbonisation et dispositif de carbonisation de matières organiques présentes dans le sol - Google Patents

Procédé de carbonisation et dispositif de carbonisation de matières organiques présentes dans le sol Download PDF

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Publication number
WO2013008337A1
WO2013008337A1 PCT/JP2011/066114 JP2011066114W WO2013008337A1 WO 2013008337 A1 WO2013008337 A1 WO 2013008337A1 JP 2011066114 W JP2011066114 W JP 2011066114W WO 2013008337 A1 WO2013008337 A1 WO 2013008337A1
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Prior art keywords
soil
superheated steam
organic
carbonization
organic matter
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PCT/JP2011/066114
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English (en)
Japanese (ja)
Inventor
伊藤 智章
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株式会社ワンワールド
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Application filed by 株式会社ワンワールド filed Critical 株式会社ワンワールド
Priority to PCT/JP2011/066114 priority Critical patent/WO2013008337A1/fr
Priority to JP2013523759A priority patent/JP5784122B2/ja
Priority to CN201180072197.4A priority patent/CN103796769B/zh
Publication of WO2013008337A1 publication Critical patent/WO2013008337A1/fr

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    • BPERFORMING OPERATIONS; TRANSPORTING
    • B09DISPOSAL OF SOLID WASTE; RECLAMATION OF CONTAMINATED SOIL
    • B09CRECLAMATION OF CONTAMINATED SOIL
    • B09C1/00Reclamation of contaminated soil
    • B09C1/06Reclamation of contaminated soil thermally

Definitions

  • the present invention relates to a soil organic matter carbonization apparatus and a soil organic matter carbonization method that can carbonize organic matter in soil (organic waste such as waste plastics).
  • organic matter and “organic matter waste” are used in the meaning that does not include animal carcasses.
  • Organic industrial waste such as waste plastics is often buried and treated in the designated soil, but waste plastics buried in the soil are decomposed except for biodegradable plastics. There is almost nothing. It is preferable from an environmental viewpoint that such organic industrial wastes such as waste plastic products buried in the soil are converted into a natural form and returned to the soil.
  • a technique for carbonizing organic waste drying is performed by heating organic waste such as vegetable waste and sludge while stirring in a treatment tank in a reduced-pressure atmosphere to dry the waste until a predetermined moisture content is reached.
  • a waste treatment comprising: a treatment step; and a carbonization treatment step of further reducing the moisture content of the waste by supplying superheated steam into the treatment tank and then carbonizing and pyrolyzing the waste.
  • the method is known (see Patent Document 1).
  • Patent Document 1 is a technique in which waste is put into a treatment tank of a predetermined waste treatment system and the waste is dried and carbonized in the treatment tank. Embedded organic waste (waste plastics, etc.) cannot be treated in the embedded state.
  • the present invention has been made in view of such a technical background, and is an organic substance carbonization treatment apparatus in soil and an organic substance carbonization treatment in soil that can carbonize organic substances (such as waste plastic products) in the soil in an embedded state. It aims to provide a method.
  • the present invention provides the following means.
  • a boiler that generates water vapor
  • a superheated steam generator for generating superheated steam from the steam transferred from the boiler
  • a superheated steam supply unit for supplying superheated steam into the soil
  • An organic carbonization treatment apparatus in soil comprising: a supply pipe section that supplies superheated steam generated by the superheated steam generation apparatus to the superheated steam supply section.
  • the superheated steam supply unit includes a tube body in which a connection opening is provided on one end side in the lengthwise direction and a plurality of supply holes are provided in a side wall, and is connected to one end side of the tube body.
  • a cover body that can form an internal space with the upper surface of the soil to be treated and can suppress leakage of vaporized components existing in the internal space to the outside;
  • a condenser One end is connected to a connection hole provided in the cover body, the other end is connected to the condenser, and a recovery pipe that recovers vaporized components present in the internal space of the cover body to the condenser,
  • the soil organic carbonization apparatus according to any one of items 1 to 4, further comprising a recovery container for recovering the condensate condensed by the condenser.
  • the superheated steam supply unit includes a pipe body having a plurality of supply holes provided on a side wall, and disperses the superheated steam into the soil through the plurality of supply holes. Carbonization method.
  • the superheated steam supply unit is embedded in the soil to be treated during carbonization, and the superheated steam generated by the superheated steam generator is diffused into the soil via the superheated steam supply unit.
  • Organic matter in the soil can be carbonized.
  • superheated steam released from the superheated steam supply section into the soil can be freely diffused in the soil in all directions such as the vertical and horizontal directions, so that the organic matter in the soil to be treated can be carbonized sufficiently and efficiently. Can do.
  • the superheated steam supply section includes a tube body in which a connection opening is provided at one end side in the length direction and a plurality of supply holes are provided in a side wall, Since the supply pipe section is connected to the connection opening, the pipe body can be embedded simply by inserting it into the soil to be treated, and thus the superheated steam supply section can be embedded easily. There is an advantage that can be. Furthermore, since a plurality of supply holes are formed in the side wall of the tube body, the superheated steam can be efficiently diffused into the soil from the superheated steam supply section.
  • the high-temperature heating body since the high-temperature heating body is in a sheet form, the high-temperature heating body can be sufficiently brought into contact with the outer surface of the superheated steam supply section (the contact area can be increased), and the high-temperature heating body itself is Since the temperature can be increased to 800 ° C. or higher, the superheated steam at a higher temperature can be dissipated into the soil from the superheated steam supply unit, and the carbonization efficiency can be further improved.
  • a cover body that can form an internal space with the top surface of the soil to be treated and suppress leakage of vaporized components existing in the internal space, a condenser, and one end cover
  • the connection hole provided in the body is connected, the other end is connected to the condenser, the recovery pipe for recovering the vaporized components present in the internal space of the cover body to the container, and the condensate condensed by the condenser
  • Components water vapor, pyrolysis components from organic waste, oil, fatty acids, methane gas, water, etc.
  • organic wastes in the soil can be carbonized sufficiently and efficiently. As a result, volume reduction of the soil can be achieved.
  • the organic matter in the organic matter-containing water-containing soil can be carbonized efficiently and moisture can be removed (sprayed to the outside) to reduce the volume of the organic matter-containing water-containing soil. (Volume reduction) can be achieved.
  • the superheated steam generated by the superheated steam generator is supplied to the superheated steam supply section embedded in the soil to be treated, and the superheated steam is diffused into the soil from the superheated steam supply section. Since the superheated steam dissipated in the soil can freely diffuse in the soil in all directions, such as the vertical and horizontal directions, the organic matter in the soil (excluding animal carcasses) must be carbonized sufficiently and efficiently. Can do.
  • the superheated steam supply section includes a tube body having a plurality of supply holes provided in the side wall, the tube body can be embedded simply by piercing the soil to be treated.
  • the operation of embedding the superheated steam supply unit can be easily performed.
  • a plurality of supply holes are formed in the side wall of the tubular body, the superheated steam can be efficiently diffused into the soil from the plurality of supply holes.
  • organic wastes in soil (including one or more organic wastes selected from the group consisting of plastic products, food, fishing nets, tires, electric wires, FRP and wood) can be carbonized sufficiently and efficiently in an embedded state. As a result, volume reduction of the soil can be achieved.
  • the organic matter in the organic matter-containing water-containing soil can be carbonized efficiently and moisture can also be removed (sprayed to the outside), and the organic matter-containing water-containing soil can be reduced in volume. (Volume reduction) can be achieved.
  • FIG. 2 is a schematic plan view (a plan view showing an interconnected state of a supply main pipe 21, a branch flexible pipe 22, and a superheated steam supply unit 4) in which a cover body and a frame are deleted in FIG.
  • This soil organic carbonization device 1 carbonizes organic waste (organic waste such as plastic products, food, fishing nets, tires, electric wires, FRP, and wood) embedded in the soil in an embedded state. It is preferably used for carbonizing organic matter-containing water-containing soil (organic matter-containing sludge).
  • the “FRP” is an abbreviation for “fiber reinforced plastic product”.
  • the soil organic carbonization treatment apparatus 1 of the present invention includes a boiler 2, a superheated steam generator 3, a superheated steam supply unit 4, and a supply pipe unit 5.
  • the boiler 2 is a device that generates water vapor from water.
  • the steam generated by the boiler 2 is transferred to the superheated steam generator 3 through the communication pipe 31. That is, the boiler 2 and the superheated steam generator 3 are connected by a communication pipe 31 (see FIG. 1).
  • a communication pipe 31 see FIG. 1.
  • a once-through steam boiler etc. are mentioned.
  • the superheated steam generator 3 is a device that generates superheated steam from steam. That is, the superheated steam generator 3 generates superheated steam from the steam transferred from the boiler 2.
  • the superheated steam generator 3 is not particularly limited, and examples thereof include an induction superheated steam generator. Examples of the temperature of the superheated steam generated by the superheated steam generator 3 include 700 ° C., but are not particularly limited to such conditions.
  • the superheated steam supply unit 4 is composed of a pipe (pipe) in which a plurality of supply holes 4a are provided in a side wall.
  • a connection opening 4b is formed at one end (upper end) in the length direction of the superheated steam supply unit 4, and the other end (lower end) in the length direction is closed.
  • At least a part of the superheated steam supply unit 4 is embedded in the soil X to be treated during carbonization (see FIGS. 3 and 4).
  • the supply pipe section 5 includes a supply main pipe 21 and five branched flexible pipes 22 branched from one end of the supply main pipe 21.
  • the other end of the supply main pipe 21 is connected to the superheated steam generator 3, and each of the five branch flexible pipes 22 is connected to each of the connection openings 4 b at one end of the five superheated steam supply parts 4. ing. That is, one end of the supply pipe part 5 is connected to the superheated steam generator 3, and the other end of the supply pipe part 5 is connected to the superheated steam supply part 4.
  • the superheated steam generated by the superheated steam generator 3 can be supplied to the superheated steam supply section 4 through the supply pipe section 5.
  • the supply main pipe 21 is disposed in the inner space 40 of the cover body 11 through the insertion hole 11b of the cover body 11, and the distal end side is bent and extends along the horizontal direction (see FIG. 6).
  • the five branch flexible pipes 22 are branched and connected from a horizontal part (horizontal part in the cover) 21a of the supply main pipe 21, respectively.
  • the branch flexible tube 22 is not particularly limited, but a SUS (stainless steel) branch flexible tube is suitable.
  • the operation control panel 7 can instruct the start and stop of the operation of the boiler 2 and the superheated steam generator 3, and the temperature of the steam generated in the boiler 2, the pressure and temperature of the superheated steam generated in the superheated steam generator 3. Etc. can be controlled.
  • the superheated steam generator 3 In order to sufficiently carbonize organic wastes (waste plastics, food wastes, etc.) in the soil, it is preferable that the superheated steam generator 3 generates superheated steam at 150 ° C. or higher. In particular, it is particularly preferable to generate superheated steam at 160 ° C. to 1000 ° C. with the superheated steam generator 3 in order to sufficiently perform carbonization while suppressing energy costs.
  • a high-temperature heating body 6 is further provided.
  • the high-temperature heating body 6 is formed in a sheet shape, and the high-temperature heating body itself can be heated to 800 ° C. or higher. That is, the high-temperature heater 6 itself can be heated to a high temperature of 800 ° C. or higher by a power supply circuit (not shown).
  • Examples of the material of the high-temperature heating body 6 include Inconel (trade name) manufactured by Special Metals.
  • the high-temperature heating body 6 is wound around (covered) at least a part of the outer surface of the superheated steam supply unit 4 and used.
  • a cover body 11, a condenser 12, a recovery pipe 13, and a recovery container 14 are further provided.
  • the cover body 11 is stretched so as to form an internal space 40 between the top surface of the soil X to be treated (see FIG. 4). By stretching such a cover body 11 on the soil X to be treated, the internal space 40 on the upper surface of the soil X and the outside air are blocked.
  • the cover body 11 is normally in the form of a sheet, and the material thereof is not particularly limited, and examples thereof include synthetic resin and rubber.
  • 23 is an opening / closing part (entrance / exit part) provided on the cover body 11 for a person to enter and exit, and is configured to be freely opened and closed with a fastener.
  • reference numeral 24 in FIG. 1 and the like denotes a frame, which is used to stretch (suspend) the cover body 11 in a substantially dome shape.
  • the recovery pipe 13 can take in a vaporized component present in the internal space 40 of the cover body 11 and transfer it to the condenser 12. That is, the vaporized component existing in the internal space 40 of the cover body 11 enters the recovery pipe 13 through the connection hole 11 a of the cover body 11, passes through the recovery pipe 13, and enters the condenser 12. enter.
  • the connection hole 11a is preferably provided at the top (highest part) of the cover body 11 that is stretched.
  • the condenser 12 is a device that condenses the vaporized component into a liquid.
  • a water-cooling apparatus is employed.
  • the condenser 12 condenses the vaporized component (vaporized component existing in the internal space 40) transferred from the recovery pipe 13 into a liquid.
  • the collection container 14 is disposed below the condenser 12 and collects liquid (condensate) falling from the condenser 12.
  • a catalytic reactor 15 is disposed in the middle of the recovery pipe 13. This catalytic reactor 15 can remove chlorine, acid, etc., among the vaporized components in the recovery pipe 13.
  • the catalyst component used in the catalytic reactor 15 is not particularly limited, and examples thereof include iron oxide and sodium hydroxide.
  • the soil X containing organic waste is not particularly limited.
  • a final disposal site in which organic waste is buried for example, a final disposal site in various places such as a final disposal site on Yumenoshima in Tokyo). Etc.).
  • the superheated steam supply unit 4 is inserted and embedded in the soil X to be treated (see FIG. 4).
  • the cover body 11 is stretched so that an internal space 40 can be formed between the top surface of the soil X to be treated (see FIGS. 1 to 4).
  • the boiler 2, the superheated steam generator 3, the supply pipe unit 5, the condenser 12, the recovery pipe 13, the recovery container 14, and the catalytic reactor 15 are assembled so that the carbonization of organic matter in the soil is performed on site.
  • the processing apparatus 1 is installed (see FIGS. 1 to 4).
  • the boiler 2, the superheated steam generator 3, the condenser 12 and the like are operated. Steam generated in the boiler 2 is transferred to the superheated steam generator 3 through the communication pipe 31, and superheated steam is generated from the steam in the superheated steam generator 3, and the superheated steam is supplied to the superheated steam through the supply pipe unit 5. The superheated steam is supplied to the supply unit 4 and diffused into the soil X from the supply hole 4 a of the superheated steam supply unit 4.
  • the superheated steam can be diffused (diffused) into the soil via the superheated steam supply unit 4 buried in the soil X to be treated. Since it can diffuse freely in all directions such as the horizontal direction, the organic waste in the soil X to be treated can be carbonized sufficiently and efficiently. Carbide (charcoal) is generated by carbonization of such organic waste.
  • the temperature of the superheated steam generated by the superheated steam generator 3 is about 700 ° C.
  • the temperature of the soil is often about 600 ° C.
  • the high temperature heating body (800 degreeC or more) 6 is wound around the outer surface of the superheated steam supply part 4 in a contact state, the temperature of soil becomes a temperature higher than 600 degreeC.
  • the temperature of the superheated steam diffused from the superheated steam supply unit 4 is 150 ° C. or higher.
  • the temperature of the superheated steam dissipated from the superheated steam supply unit 4 is particularly preferably 160 ° C. to 1000 ° C. In this case, the energy cost can be suppressed and the organic waste in the soil X can be sufficiently carbonized. be able to.
  • the superheated steam supplied into the soil X to be treated is then converted into a vaporized component (which often contains water vapor, pyrolysis component from organic waste, water, methane gas, oil, fatty acid, etc.). It goes out of X, stays in the internal space 40 between the upper surface of the soil X and the cover body 11, and is sequentially collected in the collection pipe 13 through the connection holes 11a of the cover body 11. While passing through the recovery pipe 13, chlorine, acid and the like are removed by the catalytic reactor 15. The vaporized component that has passed through the recovery pipe 13 is collected in the condenser 12 and condensed in the condenser 12 to become a liquid (condensate), which is recovered in the recovery container. Since the vaporized component that has come out in the space above the treatment target soil X can be recovered by dissipating the superheated steam into the soil in this way, the environmental load can be reduced.
  • a vaporized component which often contains water vapor, pyrolysis component from organic waste, water, me
  • the organic matter carbonization treatment method in soil is merely an example, and is not particularly limited to such an embodiment.
  • the volume of the soil X to be treated is 400 m 3 (length 10 m ⁇ width 10 m ⁇ depth 4 m). That is, the soil X to be treated is a rectangular shape of 10 m in length and 10 m in width in a plan view, and a synthetic resin sheet is disposed along the dug shape in a state of being dug up to a depth of 4 m.
  • the recessed portion is filled with soil (containing 50 parts by mass of waste plastic product with respect to 100 parts by mass of soil) X. After passing through the soil X, the superheated steam dissipated in the soil X to be treated does not escape to the outside of the soil (horizontal direction, downward direction, etc.) from the dug recesses covered with the synthetic resin sheet.
  • the cover body 11 has a length of 20 m, a width of 20 m, and a maximum height of 2.5 m.
  • the internal volume of the internal space 40 between the cover body 11 and the upper surface of the soil is 1188 m 3 .
  • the temperature in the soil is 450 ° C.
  • Organic soil carbonization apparatus and soil organic carbonization method according to the present invention include, for example, organic wastes embedded in soil (plastic products, food, fishing nets, tires, electric wires, FRP, wood, factory waste, etc. It is preferably used for carbonizing organic waste), or used for carbonizing organic-containing water-containing soil (organic-containing sludge).
  • the organic waste and organic matter do not include animal carcasses.

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  • Physics & Mathematics (AREA)
  • Thermal Sciences (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Soil Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Environmental & Geological Engineering (AREA)
  • Processing Of Solid Wastes (AREA)
  • Separation, Recovery Or Treatment Of Waste Materials Containing Plastics (AREA)
  • Treatment Of Sludge (AREA)

Abstract

La présente invention se rapporte à un dispositif qui est destiné à la carbonisation de matières organiques présentes dans le sol et qui peut carboniser les matières organiques (déchets en plastiques et similaires) présentes dans le sol par enfoncement. La présente invention a une configuration pourvue : d'une chaudière (2) qui produit de la vapeur ; d'un dispositif de production de vapeur surchauffée (3) qui produit de la vapeur surchauffée à partir de la vapeur transférée depuis la chaudière ; d'une unité d'alimentation en vapeur surchauffée (4) qui est enfoncée dans le sol (X) qui doit être traité au cours de la carbonisation, et qui achemine la vapeur surchauffée dans le sol ; et d'une unité de tube d'alimentation (5) qui achemine la vapeur surchauffée produite par le dispositif de production de vapeur surchauffée (3) jusqu'à l'unité d'alimentation en vapeur surchauffée (4).
PCT/JP2011/066114 2011-07-14 2011-07-14 Procédé de carbonisation et dispositif de carbonisation de matières organiques présentes dans le sol WO2013008337A1 (fr)

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Application Number Priority Date Filing Date Title
PCT/JP2011/066114 WO2013008337A1 (fr) 2011-07-14 2011-07-14 Procédé de carbonisation et dispositif de carbonisation de matières organiques présentes dans le sol
JP2013523759A JP5784122B2 (ja) 2011-07-14 2011-07-14 土壌中有機物炭化処理装置及び炭化処理方法
CN201180072197.4A CN103796769B (zh) 2011-07-14 2011-07-14 土壤中有机物碳化处理装置及碳化处理方法

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US10346592B2 (en) 2014-10-21 2019-07-09 uBiome, Inc. Method and system for microbiome-derived diagnostics and therapeutics for neurological health issues
US10347379B2 (en) 2014-10-21 2019-07-09 uBiome, Inc. Method and system for microbiome-derived characterization, diagnostics and therapeutics for cutaneous conditions
US10347362B2 (en) 2014-10-21 2019-07-09 uBiome, Inc. Method and system for microbiome-derived diagnostics and therapeutics for endocrine system conditions
US10347368B2 (en) 2014-10-21 2019-07-09 uBiome, Inc. Method and system for microbiome-derived characterization, diagnostics, and therapeutics for cardiovascular disease conditions
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US10346589B2 (en) 2014-10-21 2019-07-09 uBiome, Inc. Method and system for microbiome-derived diagnostics and therapeutics
US10346588B2 (en) 2014-10-21 2019-07-09 uBiome, Inc. Method and system for microbiome-derived diagnostics and therapeutics
US10354756B2 (en) 2014-10-21 2019-07-16 uBiome, Inc. Method and system for microbiome-derived characterization, diagnostics and therapeutics for cutaneous conditions
US10354757B2 (en) 2014-10-21 2019-07-16 uBiome, Inc. Method and system for microbiome-derived characterization, diagnostics and therapeutics for cutaneous conditions
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