WO2012168584A1 - Émulsion huile dans eau ou eau dans l'huile à base d'huiles végétales en tant qu'adjuvant phytopharmaceutique - Google Patents
Émulsion huile dans eau ou eau dans l'huile à base d'huiles végétales en tant qu'adjuvant phytopharmaceutique Download PDFInfo
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- WO2012168584A1 WO2012168584A1 PCT/FR2012/050281 FR2012050281W WO2012168584A1 WO 2012168584 A1 WO2012168584 A1 WO 2012168584A1 FR 2012050281 W FR2012050281 W FR 2012050281W WO 2012168584 A1 WO2012168584 A1 WO 2012168584A1
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- oil
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- UHZZMRAGKVHANO-UHFFFAOYSA-M chlormequat chloride Chemical compound [Cl-].C[N+](C)(C)CCCl UHZZMRAGKVHANO-UHFFFAOYSA-M 0.000 description 1
- CWJSHJJYOPWUGX-UHFFFAOYSA-N chlorpropham Chemical compound CC(C)OC(=O)NC1=CC=CC(Cl)=C1 CWJSHJJYOPWUGX-UHFFFAOYSA-N 0.000 description 1
- SGMZJAMFUVOLNK-UHFFFAOYSA-M choline chloride Chemical compound [Cl-].C[N+](C)(C)CCO SGMZJAMFUVOLNK-UHFFFAOYSA-M 0.000 description 1
- 229960003178 choline chloride Drugs 0.000 description 1
- 239000012141 concentrate Substances 0.000 description 1
- 230000001143 conditioned effect Effects 0.000 description 1
- 230000003750 conditioning effect Effects 0.000 description 1
- 238000011109 contamination Methods 0.000 description 1
- 239000013068 control sample Substances 0.000 description 1
- 239000010949 copper Substances 0.000 description 1
- 229910052802 copper Inorganic materials 0.000 description 1
- 229910001956 copper hydroxide Inorganic materials 0.000 description 1
- 229910000365 copper sulfate Inorganic materials 0.000 description 1
- JZCCFEFSEZPSOG-UHFFFAOYSA-L copper(II) sulfate pentahydrate Chemical compound O.O.O.O.O.[Cu+2].[O-]S([O-])(=O)=O JZCCFEFSEZPSOG-UHFFFAOYSA-L 0.000 description 1
- KAATUXNTWXVJKI-UHFFFAOYSA-N cypermethrin Chemical compound CC1(C)C(C=C(Cl)Cl)C1C(=O)OC(C#N)C1=CC=CC(OC=2C=CC=CC=2)=C1 KAATUXNTWXVJKI-UHFFFAOYSA-N 0.000 description 1
- 229960005424 cypermethrin Drugs 0.000 description 1
- 238000010908 decantation Methods 0.000 description 1
- 230000003111 delayed effect Effects 0.000 description 1
- 235000005911 diet Nutrition 0.000 description 1
- 230000037213 diet Effects 0.000 description 1
- 201000010099 disease Diseases 0.000 description 1
- 208000037265 diseases, disorders, signs and symptoms Diseases 0.000 description 1
- 239000002270 dispersing agent Substances 0.000 description 1
- 238000001035 drying Methods 0.000 description 1
- 238000011156 evaluation Methods 0.000 description 1
- 238000001704 evaporation Methods 0.000 description 1
- 230000008020 evaporation Effects 0.000 description 1
- 235000019197 fats Nutrition 0.000 description 1
- 239000010685 fatty oil Substances 0.000 description 1
- 238000009950 felting Methods 0.000 description 1
- 230000004720 fertilization Effects 0.000 description 1
- 239000003337 fertilizer Substances 0.000 description 1
- 239000000945 filler Substances 0.000 description 1
- 238000011049 filling Methods 0.000 description 1
- 238000009472 formulation Methods 0.000 description 1
- IXORZMNAPKEEDV-UHFFFAOYSA-N gibberellic acid GA3 Natural products OC(=O)C1C2(C3)CC(=C)C3(O)CCC2C2(C=CC3O)C1C3(C)C(=O)O2 IXORZMNAPKEEDV-UHFFFAOYSA-N 0.000 description 1
- IXORZMNAPKEEDV-OBDJNFEBSA-N gibberellin A3 Chemical compound C([C@@]1(O)C(=C)C[C@@]2(C1)[C@H]1C(O)=O)C[C@H]2[C@]2(C=C[C@@H]3O)[C@H]1[C@]3(C)C(=O)O2 IXORZMNAPKEEDV-OBDJNFEBSA-N 0.000 description 1
- XDDAORKBJWWYJS-UHFFFAOYSA-N glyphosate Chemical compound OC(=O)CNCP(O)(O)=O XDDAORKBJWWYJS-UHFFFAOYSA-N 0.000 description 1
- 229940097068 glyphosate Drugs 0.000 description 1
- 238000003306 harvesting Methods 0.000 description 1
- 230000000887 hydrating effect Effects 0.000 description 1
- 239000003501 hydroponics Substances 0.000 description 1
- XLYOFNOQVPJJNP-UHFFFAOYSA-M hydroxide Chemical compound [OH-] XLYOFNOQVPJJNP-UHFFFAOYSA-M 0.000 description 1
- 239000001863 hydroxypropyl cellulose Substances 0.000 description 1
- 235000010977 hydroxypropyl cellulose Nutrition 0.000 description 1
- 230000004054 inflammatory process Effects 0.000 description 1
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- 229910052744 lithium Inorganic materials 0.000 description 1
- 150000002641 lithium Chemical group 0.000 description 1
- 229910001416 lithium ion Inorganic materials 0.000 description 1
- 150000002680 magnesium Chemical class 0.000 description 1
- 229910052748 manganese Inorganic materials 0.000 description 1
- 239000011572 manganese Substances 0.000 description 1
- 235000013310 margarine Nutrition 0.000 description 1
- 238000005259 measurement Methods 0.000 description 1
- 238000010297 mechanical methods and process Methods 0.000 description 1
- 239000001220 mentha spicata Substances 0.000 description 1
- NNCAWEWCFVZOGF-UHFFFAOYSA-N mepiquat Chemical compound C[N+]1(C)CCCCC1 NNCAWEWCFVZOGF-UHFFFAOYSA-N 0.000 description 1
- 229910052751 metal Inorganic materials 0.000 description 1
- 239000002184 metal Substances 0.000 description 1
- 229910044991 metal oxide Inorganic materials 0.000 description 1
- 150000004706 metal oxides Chemical class 0.000 description 1
- XWPZUHJBOLQNMN-UHFFFAOYSA-N metconazole Chemical compound C1=NC=NN1CC1(O)C(C)(C)CCC1CC1=CC=C(Cl)C=C1 XWPZUHJBOLQNMN-UHFFFAOYSA-N 0.000 description 1
- 229910052901 montmorillonite Inorganic materials 0.000 description 1
- 239000006199 nebulizer Substances 0.000 description 1
- 231100000252 nontoxic Toxicity 0.000 description 1
- 230000003000 nontoxic effect Effects 0.000 description 1
- 231100000956 nontoxicity Toxicity 0.000 description 1
- 235000015097 nutrients Nutrition 0.000 description 1
- XULSCZPZVQIMFM-IPZQJPLYSA-N odevixibat Chemical compound C12=CC(SC)=C(OCC(=O)N[C@@H](C(=O)N[C@@H](CC)C(O)=O)C=3C=CC(O)=CC=3)C=C2S(=O)(=O)NC(CCCC)(CCCC)CN1C1=CC=CC=C1 XULSCZPZVQIMFM-IPZQJPLYSA-N 0.000 description 1
- 230000009965 odorless effect Effects 0.000 description 1
- ZQPPMHVWECSIRJ-KTKRTIGZSA-N oleic acid group Chemical group C(CCCCCCC\C=C/CCCCCCCC)(=O)O ZQPPMHVWECSIRJ-KTKRTIGZSA-N 0.000 description 1
- IPCSVZSSVZVIGE-UHFFFAOYSA-N palmitic acid group Chemical group C(CCCCCCCCCCCCCCC)(=O)O IPCSVZSSVZVIGE-UHFFFAOYSA-N 0.000 description 1
- 229910052625 palygorskite Inorganic materials 0.000 description 1
- 239000010690 paraffinic oil Substances 0.000 description 1
- 244000045947 parasite Species 0.000 description 1
- 230000001717 pathogenic effect Effects 0.000 description 1
- 235000021017 pears Nutrition 0.000 description 1
- 230000000361 pesticidal effect Effects 0.000 description 1
- 229920001223 polyethylene glycol Polymers 0.000 description 1
- 229920000642 polymer Polymers 0.000 description 1
- 239000000843 powder Substances 0.000 description 1
- 238000001556 precipitation Methods 0.000 description 1
- 230000008569 process Effects 0.000 description 1
- 238000012545 processing Methods 0.000 description 1
- BUCOQPHDYUOJSI-UHFFFAOYSA-N prohexadione Chemical compound CCC(=O)C1C(=O)CC(C(O)=O)CC1=O BUCOQPHDYUOJSI-UHFFFAOYSA-N 0.000 description 1
- 230000035755 proliferation Effects 0.000 description 1
- 230000002685 pulmonary effect Effects 0.000 description 1
- 230000001698 pyrogenic effect Effects 0.000 description 1
- 238000010791 quenching Methods 0.000 description 1
- 230000003252 repetitive effect Effects 0.000 description 1
- 230000004044 response Effects 0.000 description 1
- 229920006395 saturated elastomer Polymers 0.000 description 1
- 229910052710 silicon Inorganic materials 0.000 description 1
- 239000010703 silicon Substances 0.000 description 1
- 239000000377 silicon dioxide Substances 0.000 description 1
- 238000004088 simulation Methods 0.000 description 1
- 239000010802 sludge Substances 0.000 description 1
- 235000010234 sodium benzoate Nutrition 0.000 description 1
- 239000004299 sodium benzoate Substances 0.000 description 1
- 239000002904 solvent Substances 0.000 description 1
- 241000894007 species Species 0.000 description 1
- 230000000087 stabilizing effect Effects 0.000 description 1
- 238000000528 statistical test Methods 0.000 description 1
- 239000000454 talc Substances 0.000 description 1
- 229910052623 talc Inorganic materials 0.000 description 1
- 235000007586 terpenes Nutrition 0.000 description 1
- 231100000331 toxic Toxicity 0.000 description 1
- 230000002588 toxic effect Effects 0.000 description 1
- 239000011573 trace mineral Substances 0.000 description 1
- 235000013619 trace mineral Nutrition 0.000 description 1
- 238000002054 transplantation Methods 0.000 description 1
- 230000017260 vegetative to reproductive phase transition of meristem Effects 0.000 description 1
- 210000003462 vein Anatomy 0.000 description 1
- 239000012873 virucide Substances 0.000 description 1
- 239000011782 vitamin Substances 0.000 description 1
- 235000013343 vitamin Nutrition 0.000 description 1
- 229940088594 vitamin Drugs 0.000 description 1
- 229930003231 vitamin Natural products 0.000 description 1
- 230000003442 weekly effect Effects 0.000 description 1
- MBBWTVUFIXOUBE-UHFFFAOYSA-L zinc;dicarbamodithioate Chemical compound [Zn+2].NC([S-])=S.NC([S-])=S MBBWTVUFIXOUBE-UHFFFAOYSA-L 0.000 description 1
Classifications
-
- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N25/00—Biocides, pest repellants or attractants, or plant growth regulators, characterised by their forms, or by their non-active ingredients or by their methods of application, e.g. seed treatment or sequential application; Substances for reducing the noxious effect of the active ingredients to organisms other than pests
- A01N25/02—Biocides, pest repellants or attractants, or plant growth regulators, characterised by their forms, or by their non-active ingredients or by their methods of application, e.g. seed treatment or sequential application; Substances for reducing the noxious effect of the active ingredients to organisms other than pests containing liquids as carriers, diluents or solvents
- A01N25/04—Dispersions, emulsions, suspoemulsions, suspension concentrates or gels
-
- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N25/00—Biocides, pest repellants or attractants, or plant growth regulators, characterised by their forms, or by their non-active ingredients or by their methods of application, e.g. seed treatment or sequential application; Substances for reducing the noxious effect of the active ingredients to organisms other than pests
- A01N25/08—Biocides, pest repellants or attractants, or plant growth regulators, characterised by their forms, or by their non-active ingredients or by their methods of application, e.g. seed treatment or sequential application; Substances for reducing the noxious effect of the active ingredients to organisms other than pests containing solids as carriers or diluents
Definitions
- the present invention relates to the use of a water-in-oil or oil-in-water emulsion as a plant-protection phytopharmaceutical product or as a phytopharmaceutical adjuvant.
- the present invention also relates to a phytopharmaceutical composition comprising the abovementioned adjuvant.
- the present invention also relates to the use of the plant protection composition to protect plants or plant products against all harmful organisms (insects, fungi ...) or to prevent their action.
- Plant protection products are defined by Directive 91/414 / EEC as preparations containing one or more active substances and which are intended to protect plants and their fruits against all harmful organisms or to prevent their actions.
- phytosanitary adjuvants correcting phytopharmaceutical formulas called: phytosanitary adjuvants.
- Phytosanitary adjuvants are substances without phytopharmaceutical activity, but they are capable of improving the technical qualities of phytosanitary active ingredients, in particular they improve the compatibility and stability of the emulsion or the aqueous solution of the treatment product when are added to it in extemporaneous mixture (in the tank).
- the main phytosanitary additives marketed on the market are generally formulated from the following basic materials: a mineral oil or terpene alcohols, sulfuric esters of fatty alcohol, sulphonated fatty acid esters, diethylene glycol abietate or alkoxylated triglycerides. It is mainly mineral oils that are used as adjuvants. Terpenic alcohols are pulmonary allergens and are thus less and less used. Oily adjuvants are generally formulated from paraffinic mineral oils to which emulsifying surfactants are added. These mineral oils have demonstrated their effectiveness as phytosanitary adjuvant, but have disadvantages in their handling and repetitive contact with the skin causes irritation, inflammation, in addition they are toxic and non-biodegradable (unfavorable carbon balance) .
- WO 1995 031898 discloses concentrated pesticidal compositions for use in agriculture and intended to be emulsified with water just prior to use.
- silicic derivatives such as precipitated or pyrogenic colloidal silicas
- thickener there are mentioned products known to those skilled in the art, such as mineral derivatives such as silicates (attapulgite, bentonites), magnesium aluminosilicates, organic derivatives, such as cellulosic products of the cellulose ether type (carboxymethylcellulose, hydroxypropylcellulose) or polymers, such as gums arabic or xanthan.
- EP 2 181 820 which describes a water-in-oil emulsion (w / o) or oil in water (h / e) composed of an oily phase comprising one or more oils of vegetable and / or mineral origin and / or of synthesis, at least one nonionic and / or anionic emulsifying surfactant, and an aqueous phase comprising water.
- the aqueous phase comprises in particular at least one layered silicate of formula Na + 0, 7 [(SisMgs Lio ⁇ ⁇ O ⁇ OH) ⁇ "0.7 so as to obtain a fluid and stable emulsion over time.
- This emulsion is intended to be used as a release agent and / or stripping.
- WO 2005/020685 discloses talc-based pesticide compositions in the form of sludge (thick slurries).
- the purpose of the invention is to propose a novel plant protection composition which avoids all or some of the aforementioned drawbacks.
- the invention relates to the use of a water-in-oil emulsion (w / o) or oil in water (h / e) composed of an oily phase comprising one or more oils of raw vegetable origin or refined, at least one nonionic and / or anionic emulsifying surfactant, and an aqueous phase comprising water and at least one phyllosilicate, as a plant protection product with mechanical action or as a phytopharmaceutical adjuvant intended to be associated with a phytopharmaceutical active.
- a water-in-oil emulsion w / o
- oil in water h / e
- aqueous phase comprising water and at least one phyllosilicate
- the subject of the present invention is also a plant protection composition
- a plant protection composition comprising at least one phytopharmaceutical active agent and at least one phytopharmaceutical adjuvant, characterized in that the said at least one phytopharmaceutical adjuvant is composed of a water-in-oil emulsion (w / h) or an oil in it.
- water (h / e) composed of an oily phase comprising one or more oils of crude or refined vegetable origin, at least one nonionic and / or anionic emulsifying surfactant, and an aqueous phase comprising water, characterized in that the aqueous phase comprises at least one phyllosilicate.
- the emulsion described above alone (as a phytopharmaceutical product) can, by its mechanical action, and in the pure or diluted state, prevent the appearance of harmful organisms, for example by allowing the smothering of larvae.
- 3L of emulsion / hectare diluted with water make it possible to treat the mites on fruit trees during the winter.
- the emulsion according to the invention thus acts as a phytosanitary product by mechanical action.
- mechanical action is meant that the emulsion creates a barrier between the harmful organism and the external environment preventing any contact with the air and therefore with the oxygen of the air or the emulsion is able to cover the harmful organisms and thus to smother them and to obstruct for example their airways.
- the emulsion according to the invention makes it possible not only to combine their effects, but also to effectively emulsify non-toxic and biodegradable way the phytopharmaceutical active.
- the emulsion according to the invention also facilitates the storage of the phytopharmaceutical composition over time.
- the compounds which will be described below are suitable both for the invention for use as a plant protection product with mechanical action or as a phytopharmaceutical adjuvant intended to be combined with a phytopharmaceutical active ingredient. and for the invention of phytopharmaceutical composition.
- the emulsion according to the present invention is of the oil-in-water (h / e) or water-in-oil (w / h) type and is preferably nonionic.
- an emulsion is a mixture of two immiscible substances that can be emulsified according to different formulations and different production techniques. Each substance is called phase.
- the microdroplet phase is the discontinuous phase, while the phase surrounding the microdroplets is called the continuous phase.
- a water-in-oil emulsion (w / h) is composed of an aqueous discontinuous phase dispersed in an oily continuous phase and, conversely, an oil-in-water emulsion (h / e) is composed of a discontinuous phase. Oily dispersed in a continuous aqueous phase.
- the w / o or w / o emulsion according to the invention is also fluid at ambient temperature (20-25 ° C.).
- the BINGHAM plastic viscosity can range, for example, from 5 mPa.s to 50 mPa.s, preferably from 8 mPa.s to 30 mPas.s when the viscosity is measured with a TVe-05 LAMY device with the measurement system MS DIN. 53019 (NF EN ISO 3219) at a temperature of 23 ° C between a speed of 3 (200 rpm) and 2 (100 rpm).
- the BINGHAM model makes it possible to characterize a product by its BINGHAM viscosity which is that of the product set in motion in the shear range analyzed (here, between the speeds 3 and 2). .
- the advantage of this modeling is to determine a viscosity value that is constant, in the range of gradients analyzed, instead of having a multitude of apparent viscosities, as well as the pressure to be exerted on the product to convey it. in this range of gradients.
- the emulsion according to the present invention comprises in its aqueous phase, in addition to water, at least one phyllosilicate.
- phyllosilicates minerals from the group of silicates, formed of particles whose basic units are two-dimensional infinite sheets, hence the name lamellar silicates. These sheets or lamellae consist of the combination of tetrahedral oxygen layers comprising a silicon or magnesium atom in the center and octahedral layers composed of oxygen and hydroxide, most often containing aluminum or magnesium atoms. In the center.
- the two major families of phyllosilicates are characterized by the type successive stackings of these octahedral (O) and tetrahedral (T) layers:
- a phyllosilicate suitable for the present invention belongs preferably to the family of smectites.
- the crystalline half-mesh at the base of two-dimensional sheets of smectites consists of seven superimposed atomic layers.
- the term half-mesh is used because two sheets are taken into account to define the repetition pattern in the direction.
- This half-mesh is decomposed into a layer of octahedra between two layers of tetrahedrons. It is also possible to break it down into a middle layer of metal oxide, between two layers of silica.
- the chaining of the half-stitches in the x and y directions forms a leaflet.
- interfoliar distance The distance between leaflets, called interfoliar distance, varies according to the type of "compensating" cations, that is to say according to the isomorphous substitutions of the middle layer of the half-mesh and the geological nature of the extraction soil. . These cations are most often of the Li + , Na + , Ca 2+ , K + and Mg 2+ type and these will be placed in the sterically less congested sites closest to the deficit centers.
- the phyllosilicate according to the invention belongs to the family of smectites of the hectorite type.
- a hectorite is in the form of a platelet or a disk with a lateral dimension of less than 1000 nm, preferably ranging from 10 nm to 800 nm and even more preferably having a lateral dimension ranging from 20 nm to 100 nm +/- 5 nm.
- a phyllosilicate suitable for the present invention may be for example pyrophylliles, montmorillonites, bentonites, lucentites or a phyllosilicate of general formula:
- the phyllosilicate has the formula below: Na + 0, 7 [(Si8Mg5 / 5Lio, 3) 0 2 O (OH) 4] "0 '7
- the ideal theoretical structure of the phyllosilicate have a filler. Neutral with six divalent magnesium ions in the octahedral layer, producing a positive charge of 12. However, in practice, some magnesium ions are replaced by lithium ions and some spaces remain empty to give a composition corresponding to the formula above.
- the stabilizing efficacy of specific phyllosilicates is related not only to their special chemical and crystallographic composition, but also to their overall negative ionic polarity after dispersion in water.
- the stability is improved with a phyllosilicate having an electrical charge insufficiency of 0.7, such as the phyllosilicate of formula [(Si 8 Mg 5 / 5Lio, 3) 0 2 o (OH) 4 ] "O ' 7 .
- the phyllosilicate of formula [(Si 8 Mg 5 / 5Lio, 3) 0 2 o (OH) 4 ] "O ' 7 to control the quality of this type of specific phyllosilicate, it is preferable to obtain them synthetically from pure and regular basic components. will preferably be milled to obtain a powdery, dry and easy-to-store phyllosilicate product.
- the stabilization of emulsions according to the present invention is not affected by temperature variations.
- the aqueous phase of the emulsion according to the invention advantageously comprises a hydrophilic adjuvant.
- hydrophilic adjuvants such as biocidal protectants, dispersants, chelants, antioxidants, thickeners, preservatives (such as an isothiazolone derivative), etc., well known to those skilled in the art.
- the adjuvants used are preferably biodegradable and liquid at room temperature (20 ° C).
- the oily phase of the emulsion according to the invention comprises, as indicated above, at least one crude or refined vegetable oil and at least one emulsifying surfactant.
- the vegetable oil of the w / o or h / e emulsion is chosen from: rapeseed, soya, sunflower, olive, palm, peanut, jojoba and coconut oil, and jatropha oil, or a mixture thereof.
- the nonionic and / or anionic emulsifying surfactant according to the invention is chosen from: a liquid at room temperature (around 20-25 ° C.), biodegradable and produced on a plant basis, and a biosurfactant, or a mixture thereof.
- the nonionic emulsifying surfactant is chosen from an ethoxylated fatty alcohol, an ester of fatty acids and polyols, a sorbitan ester, a polyethoxylated sorbitan ester, an ethoxylated castor oil, an alkoxylated fatty alcohol, a alkyl polyglucoside, and a polymeric surfactant, or a mixture thereof
- the anionic emulsifier surfactant is selected from an alkaline salt of fatty and rosin acids, an alkylarylsulfonate, an alkylsulfosuccinate, an alkyl sulphate, an alkyl ether sulphate, a sulphate ether amide, and a dodecylbenzene sulphonic derivative, or a mixture thereof.
- the nonionic or anionic emulsifying surfactant may also be chosen from biosurfactants.
- biosurfactants such as soy lecithins, egg lecithins, polysaccharide-protein surfactants, and exopolysaccharides (EPS) such as xanthan, or a mixture thereof are suitable for the present invention.
- soy lecithins, egg lecithins, polysaccharide-protein surfactants, and exopolysaccharides (EPS) such as xanthan, or a mixture thereof are suitable for the present invention.
- EPS exopolysaccharides
- the oily phase comprises at least one oleophilic adjuvant. It is indeed possible to add to the oily phase and at low dose, for example of the order of 0.001% to 2% by weight relative to the total weight of the emulsion, oleophilic adjuvants, such as antifoam anti-gels, anti-oxidation agents, colored tracers, etc., well known to those skilled in the art.
- oleophilic adjuvants such as antifoam anti-gels, anti-oxidation agents, colored tracers, etc.
- the oil or oils represent, by weight, 10% to 80%, the surfactant
- the emulsifying active ingredient represents, by weight, 0.5% to 20%
- the water represents, by weight, 10% to 90% and the phyllosilicate represents by weight from 0.01% to 20%.
- the vegetable oils represent, by weight, 5% to 50% and the emulsifying surfactant represents, by weight, 0.5% to 20% relative to the total weight of the oil-in-water emulsion ( Hey).
- this active agent is preferably chosen from: an insecticide (pyrhethrin, cypermethrin, bifenthrin, organophosphate such as chlorpiriphos), a fungicide (copper hydroxide, copper sulphate, sulfur wettable acid, zinc dithiocarbamate and manganese (mancozeb), morpholine, strobilurin), a herbicide (glyphosate, aminotriazole), a bactericide and a growth regulator (trinexapac-ethyl, ethephon, chlorocholine chloride, chlormequat, choline chloride, prohexadione, mepiquat, trinexapac-ethyl, tebuconazole, metconazole, chlorpropham, Mentha spicata oil, b-indole acid butyric, alpha-nap
- the subject of the present invention is the plant protection composition
- this comprises water.
- said at least one phytopharmaceutical adjuvant represents, by weight, 0.05% to 70% and said phytopharmaceutical active agent represents 0.05% to 10% by weight. and the water is 20% to 99.9% by weight.
- the percentages above depend on the desired action and therefore on the use of a herbicide, fungicide or insecticide, but also on the type of crop and the plants to be treated (for example, beet or banana) and are very variable according to the cases considered.
- the user will spray from 0.5 liters to 20 liters (L) per hectare of phytopharmaceutical active ingredient, 2 liters to 20 liters per hectare of pure emulsion according to the invention, all of which may be diluted with 0% to 90% water, depending on the type of application (manual or aerial sprayers).
- a method suitable for the present invention may be as follows and include the steps below:
- disperser or emulsifier a device for mixing, shear, effectively emulsify the emulsions, so as to obtain fine-cell emulsions.
- the process as described above makes it possible to obtain homogeneous and regular emulsions continuously, however, it is also possible to produce the emulsions according to the invention batchwise (batch process).
- the process for preparing the emulsions according to the invention also has the advantages of being simple and economical. Indeed, it is useless for example to perform phase inversions that require heating at high temperature (around 90 ° C) oil and water phases, and thus increase manufacturing costs.
- the mixing of the phases takes place at about 20 to 25 ° C.
- the phyllosilicate or phyllosilicates may be previously packaged in the form of gel or fluid soil.
- the vegetable oils suitable for the present invention are in particular: rapeseed oil, soybean oil, sunflower oil, olive oil, palm oil, peanut oil, jojoba oil, coconut oil, and jatropha oil, or a mixture thereof.
- palm oil is preferred with rapeseed oil.
- these oils are crude but purified. Purified means that these oils have been previously filtered at least.
- Palm oil is a fatty oil obtained from the pulp and stones of palm fruit, the most common being Elaeis guineensis.
- the extraction is carried out hot by different mechanical methods or by extraction with solvents of the hexane type. Because palm oil freezes at room temperature, storage and conditioning are carried out hot (45 ° C to 60 ° C).
- the raw palm oil obtained is then clarified by decantation and filtered. At this stage, it is marketed under the name CPO (Crude Palm Oil).
- the orange-colored CPO is rich in fatty acids (palmitic, stearic, oleic, linoleic), triglycerides, and contains carotenoids, vitamins and trace elements.
- CPO palm oils are therefore complex compositions and very variable depending on the origin or selection of palms, depending on the place and method of cultivation and the extraction method in production. Whatever the origins and modes of extraction of palm oils, these CPO oils are always characterized by their intense yellow-orange color and by their high melting point (35 ° C to 40 ° C); they therefore congeal at ordinary temperature (20 ° C) and are therefore not usable as such without heating and maintained.
- CPO palm oils are generally refined, bleached and marketed under the name RBD (Refined, Bleached, Desodorizided).
- RBD palm oils are color neutral or colorless, odorless, but their melting point is still as high as that of CPO (35 ° C to 38 ° C).
- RBD palm oils are used either in solid form (for fried foods) or in the form of water-in-oil type emulsions for producing, for example, margarines.
- An object of the present invention also relates to the use of the plant protection composition described above for treating plants against pests.
- FIG. 1 shows, in axial section, an emulsifier apparatus for obtaining the compositions according to the invention
- FIG. 2 is a partial and schematic representation of the rotor and stator vanes, pallets whose cooperation makes it possible to obtain a high shear rate and, consequently, an emulsion sufficiently fine to fit within the scope of FIG. the present invention
- FIG. 3 corresponds to a plan that incorporates the experimental device of the ILVO research station in Merelbeke, Belgium, implemented in example 7.
- the stator of the emulsifier has been designated as 1 as a whole.
- the stator 1 consists essentially of two parts 1a and 1b connected to each other by means of studs 2.
- the stator 1 receives a rotor designated by 3 as a whole, the rotor 3 being rotated relative to the stator by a shaft 4.
- the rotation of the rotor 3 and the shaft 4 relative to the stator 1 is permitted thanks to a sealed bearing system 5.
- the portion 1b of the stator comprises the arrival pipes of the products intended to constitute the emulsion: for example the aqueous phase is sent according to the arrow Fl and the oily phase of the emulsion is sent along the arrow F2 (or vice versa).
- the assembly enters the stator which comprises a circular blade holder 6 fixed by screws on the part 1b of the stator, the blades 6a of the blade carrier 6 being radial and directed towards the rotor 3, that is to say say on the opposite side to the arrival of products to emulsify.
- the end of the rotor 3 which is opposite the blade holder 6 is in the form of a plate which carries radial blades 3a.
- the blades 3a and 6a are arranged in concentric circles, the blades 3a being located in the circular annular spaces, which exist between two successive circles of blades 6a.
- the products to be emulsified come into the zone between the blade carrier 6 and the rotor 3 via a central circular orifice of the blade carrier 6, centrifugally cross the space between the blade carrier 6 and the rotor 3 and are ejected at the periphery of said space to be discharged out of the apparatus according to the arrow F3.
- the flow of incoming products undergoes successive shears between the fixed blades 6a and the blades 3a driven in rotation by the shaft 4.
- the fineness of the emulsion obtained depends, in particular, on the number of concentric circles of blades 3a and 6a, the radial space between the edges of said blades and the speed of rotation of the shaft 4.
- the characteristics of the emulsion obtained are a function of the speed of rotation of the rotor.
- a rotation speed of the order of 6,500 rpm is suitable for obtaining fluid emulsions according to the present invention.
- Example -2 emulsion based on palm oil RBD
- Example -3 Emulsion based on purified crude rapeseed oil
- Example -4 Prior Tests for Compatibility of the Emulsions Above (Examples 1 to 3) with Phytopharmaceutical Active Ingredients
- the emulsions of Examples 1 to 3 were carried out according to the aforementioned method. 1 L of each of the emulsions was then diluted with 0.25L of water (1/4 additional volume of water). 1% of each active ingredient above (percent by weight, based on the total weight of the diluted emulsion) was then mixed with each of the diluted emulsions.
- Example -5 Efficiency tests in arboriculture (small and large fruits) and comparative with phytopharmaceutical products of the prior art (all the tests were carried out confidentially).
- the objectives of this test are to prevent the development, namely the primary contamination, of scab on apple and pear, and also to prevent peach blister or gooseberry.
- the comparative test was conducted with a white oil (817 g / 1 mineral oil) insecticide, all crops, recommended in the winter and spring treatments of fruit trees and in the annual fight against citrus mealybugs.
- This white oil is sold under the trademark Acakill® by the company C.C. L.
- Test A Treatment of currant bushes over a period of two months (March and April 2010) during the phenological stage A and B of the buds.
- Example 1 For this test, the emulsion of Example 1 was used (30% of webbed). IL of this emulsion was then diluted with 0.25L of water (1/4 volume of water added).
- the emulsion according to the invention is used alone as a phytopharmaceutical product with mechanical action (that is, in order to quench and prevent the development of latent parasites), that is to say without additional phytopharmaceutical active ingredient.
- White oil of the prior art was also diluted with 0.25 L of additional water (1/4 volume of added water).
- An array A of currant bushes was treated with the emulsion according to the invention, a row B was treated with the white oil of the prior art and a row C was not treated at all.
- the application of the products was carried out by spraying.
- the emulsion according to the invention is just as effective as a product of the prior art as a phytopharmaceutical product with mechanical action (asphyxiation of larvae, aphids), and in particular for treating currant blisters.
- Test B Treatment every 15 days of apple, pear and peach over a period of 3 months (April to June 2010) during the phenological stage E2 to F2 (excluding flowering).
- Example 2 the emulsion according to the invention was used as a phytopharmaceutical adjuvant.
- IL of solution of Example 2 was used (30% palm oil) and was diluted with 30L of water and 100 grams of wettable sulfur (product according to the invention).
- White oil (80% oil) according to the prior art) was also diluted with 30L of water and 100 grams of wettable sulfur (comparative product) for comparison.
- an emulsion based on vegetable oils such as palm oil (30% oil) can be substituted for a white oil (80% paraffinic oil) as a phytosanitary adjuvant.
- Example 6 Efficacy test in phytosanitary preventive treatment of banana plantations and comparative (all the tests were carried out confidentially).
- the objectives of this test are to prevent the development of yellow Sigatoka fungus (Mycosphaerella musicola) and to prevent the development of black Sigatoka (Mycosphaerella fijiensis).
- the comparative test was carried out using a white oil (HB) type Banole HV® (paraffinic mineral oil: 825 gr / liter, ie approximately 80% oil) marketed by Total. 11 L of this white oil was diluted with 4 L of water, 0.1 L of an emulsifier: polyethylene glycol 4- tert-octyl phenyl ether (Triton X45® from Dow), and 0.4 L of fungicide pure (mancozeb) to obtain 15.5 liters of a solution according to the prior art (the preparation and the determination of the white oil corresponds to what is in common use). This composition is intended to be sprayed 15.5L / hectare.
- HB white oil
- Banole HV® paraffinic mineral oil: 825 gr / liter, ie approximately 80% oil
- the phytopharmaceutical composition according to the invention was prepared from: 4 L of emulsion according to Example 1 (30% of oil) which were diluted with 11.1 L of water and 0.4 L of pure fungicide (mancozeb) to obtain 15.5 liters of a phytopharmaceutical composition. This composition is also intended to be spread 15.5 L / hectare.
- EXAMPLE 7 Efficiency test of the emulsion according to the invention as phytopharmaceutical adjuvant for the preventive treatment by foliar spraying on a leek crop in the open field after artificial inoculation of Pseudomonas syringae pv. porri.
- the object of this experiment is to evaluate the ability of an emulsion according to the invention to increase the effectiveness of copper sulphate.
- Leeks are transplanted to the field in a test plot. They are pretreated by foliar spraying with different modalities (see below) and then inoculated with a bacterial suspension of Pseudomonas syringae pv porri. A reading is made after 8 weeks of field cultivation by observing the symptoms of the disease on the leaves.
- the emulsion according to the invention has the following composition:
- Copper sulphate, as well as the Phyton ® 27 product active ingredient comprising 21% of copper sulfate pentahydrate and 5.5% of copper metal
- ILVO Search Institute of Agriculture and Fisheries in Blegique
- the plant material is Allium porrum cv. Harston. It is in the young plant stage to be transplanted and is healthy.
- the strain of Pseudomonas syringae pv porri is G BBC 988 isolated in
- the variability factors are as follows:
- Modality 1 (Ml) is the negative control: the plants are treated with water.
- Modality 2 corresponds to plants treated with copper sulphate diluted in water (also called treatment slurry).
- the dosage is as follows: 600 g of copper sulphate per 100 L of water (ie a concentration of copper sulphate of 6 g / l).
- the conditions 5 (M5), 6 (M6) and 7 (M7) are equivalent to modality 2 (6 g of copper sulphate per liter of slurry) to which was added an increasing dose of the emulsion according to the invention. (2.5 mL (0.25%), 0.5 mL (0.5%) and 10 mL (1%) per 1 L of the treatment slurry were obtained according to the composition of the table. above.
- the mode 8 (M8) corresponding to a positive control which was treated with Phyton ® 27 so as to obtain a slurry comprising 0.12% Phyton ® 27 (the processing slurry comprises 1.2 mL Phyton ® 27 for 1 L).
- the trial thus includes a total of six modalities, including witnesses (modalities 1 and 8). Each modality was repeated twice in a complete random block device.
- Each experimental unit consists of 12 plants (3 lines of
- the bacterial inoculation is carried out in the field with a suspension of Pseudomonas syringae pv porri containing 10 9 cells per liter.
- the suspension was nebulized under pressure (8 bar) at a rate of 100 ml per experimental unit.
- the plane represented in FIG. 3 repeats the experimental device in the field and represents the plans processed according to the different modalities. Implementation and execution of the test:
- the treatments are carried out with a hand-held sprayer until the foliage is saturated (formation of drops and flow at the bottom of the leaves).
- the objective of the trial was to evaluate the ability of a rapeseed oil wetting agent to increase the effectiveness of a Bordeaux mixture applied preventively against "bacterial grease" on leek.
- modality 1 has more than 57% of attacked leaves.
- the application of the positive control product shows only 20% of the attacked leaves.
- modalities 5, 6 and 7 express a protection gradient which rises with respect to the wetting concentration. A step of + 5% uninfected leaves is marked between each concentration.
- the purpose of this experiment is to evaluate the ability of a wetting agent to increase the effectiveness of fungicide protection in the presence of rain leaching in the control of late blight, Phytophthora infestans .
- Minitubers from hydroponics are grown in a conditioned room for six weeks. After this period, the plants are treated according to the different modalities (see below). Modality 8 was added to the experimental set-up to evaluate the effectiveness of the fungicide in the absence of rain.
- the leaves are taken from the treated plants, inoculated in the laboratory using a suspension of sporangia of known concentration and incubated; the ability of sporangia to produce sporulating necrosis as an indicator of efficacy.
- the emulsion according to the invention has the following composition:
- the phytopharmaceutical principle is Dithane ® WG
- Potato Bintje was chosen for its high susceptibility to foliage downy mildew.
- the starting plant material is healthy and is derived from minitubers from a hydroponic culture. minitubers, previously pre-germinated, were planted in a vermiculite-based substrate, one mini-tuber per pot. After 6 weeks of culture, the plants are treated according to the different modalities. The plants are fertilized with a nutrient solution at a rate of 2 weekly intakes.
- the mildew strain, Phytophthora infestans is a strain collected in 2010 (reference: 10/044).
- the leaching is a rain corresponding to a precipitation of 20 mm. It is made on treated plants over a period of 30 minutes.
- Modality 1 (Ml) is the negative control: the plants are treated with water and are not leached.
- the modalities 2 (M2) and 3 (M3) correspond to the plants treated with the emulsion according to the invention at the dose of 1%, the first modality does not undergo leaching by the rain while the second undergoes rain.
- Modality 4 corresponds to the plants treated with the full-dose contact product (Dithane ® homolve dose) and undergoing rain.
- the modalities 5 (M5), 6 (M6) and 7 (M7) are equivalent to modality 4 to which was added an increasing dose of the emulsion according to the invention (respectively 0.25%, 0.5% and 1%). % of the treatment slurry); the plants were also leached by rain.
- Modality 8 has been added to the experimental set-up; it is equivalent to modality 4 without leaching and therefore corresponds to the positive control.
- the experimental unit consists of a plant receiving the application of a treatment (see modalities).
- Inoculation is performed on loose leaves; they are filed in a closed incubation box whose bottom is lined with a damp blotter.
- Each of the leaflets is inoculated with a suspension of sporangia (concentration of 50000 sporangia / ml) at the rate of 2 drops of 10 ⁇ l / leaflet (on both sides of the central vein).
- the incubation box containing the leaf is then placed in an incubator set at 16 ° C and a photoperiod of 16h.
- Note 1 Symptoms occur as black spot or black punctures at the site of the inoculum. All these punctuations occupy a surface corresponding to that of a drop of inoculum. No progression of necrosis beyond the point of inoculation is observed.
- Note 2 The symptoms are in the form of a black spot 0.5 to 1 cm in diameter. Its center is where the drop of inoculum was deposited. On the periphery of the spot, the necrosis takes on a nebulous appearance, the black coloration is less intense. No sporulation is visible to the naked eye.
- the symptoms are in the form of a black spot of 0.5 to 1 cm in diameter (idem note 2) with the periphery the presence of a slight felting mycelium (fructifications).
- the symptoms are in the form of a spot of 1 to 3cm. Abundant sporulation is present in and around the stain.
- the objective of the test was to evaluate the ability of an oil-based wetting agent to increase the effectiveness of a contact fungicide in the presence of rain on the development of potato late blight. .
- group 1 corresponds to modality 8 where the control of late blight is almost total (statistical measure d);
- group 3 (statistical measure a) corresponds to modalities 1, 2, 3, and 4 where mildew is not controlled;
- group 2 (statistical measure c) groups together the modalities composed of fungicide in combination with the wetting agent, the control of which is significantly greater than the fungicide applied alone.
- an increasing dose of wetting agent in the treatment slurry does not result in an increase in effectiveness.
- the dose of 1% of wetting agent has an efficacy result lower than the respective doses of 0.25% and 0.5%.
- some repetitions (modality 5, modality 6, modality 7) do not show control, the mildew sporulates on all the points of inoculation.
- wetting agent in the treatment slurry has a beneficial effect in the control of late blight in case of rain and the use of a contact fungicide.
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Abstract
Description
Claims
Priority Applications (5)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
CN2012800084326A CN103458682A (zh) | 2011-02-10 | 2012-02-09 | 作为植物药学佐剂的基于植物油的水包油或油包水乳液 |
US13/984,352 US20130345061A1 (en) | 2011-02-10 | 2012-02-09 | Vegetable oil-based oil-in-water or water-in-oil emulsion as phytopharmaceutical adjuvant |
PL12708888T PL2672814T3 (pl) | 2011-02-10 | 2012-02-09 | Emulsja olej w wodzie lub woda w oleju na bazie olejów roślinnych jako adiuwant fitofarmaceutyczny |
BR112013020279A BR112013020279A2 (pt) | 2011-02-10 | 2012-02-09 | "emulsão óleo em água ou água em óleo à base de óleos vegetais como adjuvante fitofarmacêutico" |
EP12708888.8A EP2672814B1 (fr) | 2011-02-10 | 2012-02-09 | Émulsion huile dans eau ou eau dans l'huile à base d'huiles végétales en tant qu'adjuvant phytopharmaceutique |
Applications Claiming Priority (2)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
FR1151096A FR2971399B1 (fr) | 2011-02-10 | 2011-02-10 | Emulsion huile dans eau ou eau dans l'huile a base d'huiles vegetales en tant qu'adjuvant phytopharmaceutique. |
FR1151096 | 2011-02-10 |
Publications (1)
Publication Number | Publication Date |
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WO2012168584A1 true WO2012168584A1 (fr) | 2012-12-13 |
Family
ID=44064692
Family Applications (1)
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PCT/FR2012/050281 WO2012168584A1 (fr) | 2011-02-10 | 2012-02-09 | Émulsion huile dans eau ou eau dans l'huile à base d'huiles végétales en tant qu'adjuvant phytopharmaceutique |
Country Status (11)
Country | Link |
---|---|
US (1) | US20130345061A1 (fr) |
EP (1) | EP2672814B1 (fr) |
CN (1) | CN103458682A (fr) |
BR (1) | BR112013020279A2 (fr) |
CL (1) | CL2013002297A1 (fr) |
CO (1) | CO6771424A2 (fr) |
EC (1) | ECSP13012872A (fr) |
FR (1) | FR2971399B1 (fr) |
MY (1) | MY157540A (fr) |
PL (1) | PL2672814T3 (fr) |
WO (1) | WO2012168584A1 (fr) |
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CN104429735A (zh) * | 2014-11-12 | 2015-03-25 | 浙江省农业科学院 | 含有食用油和有机硅混合的农药试剂以及用途 |
CN110692653A (zh) * | 2019-10-30 | 2020-01-17 | 凉山德农生物能源股份有限公司 | 一种小桐子源环境消毒剂及其制备方法 |
WO2022189385A1 (fr) * | 2021-03-11 | 2022-09-15 | Merck Patent Gmbh | Composition comprenant des particules en forme de plaquettes |
CN113040136B (zh) * | 2021-03-17 | 2022-05-06 | 湖南嘉诚农业科技有限公司 | 一种航空施药助剂及其制备方法和应用 |
Citations (3)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
WO1995031898A1 (fr) | 1994-05-24 | 1995-11-30 | Hoechst Schering Agrevo S.A. | Nouvelles compositions pesticides du type 'emulsion huile dans l'eau' |
WO2005020685A2 (fr) | 2003-08-29 | 2005-03-10 | Luzenac America, Inc. | Composition et methode pour une protection de recolte |
EP2181820A1 (fr) | 2008-10-31 | 2010-05-05 | Mexel Industries | Emulsion huile dans eau ou eau dans l'huile, liquide et stable, à base d'huiles végétales ou minérales |
Family Cites Families (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US5206021A (en) * | 1988-05-09 | 1993-04-27 | Rhone-Poulenc Ag Company | Stabilized oil-in-water emulsions or suspoemulsions containing pesticidal substances in both oil and water phases |
-
2011
- 2011-02-10 FR FR1151096A patent/FR2971399B1/fr not_active Expired - Fee Related
-
2012
- 2012-02-09 WO PCT/FR2012/050281 patent/WO2012168584A1/fr active Application Filing
- 2012-02-09 BR BR112013020279A patent/BR112013020279A2/pt not_active IP Right Cessation
- 2012-02-09 US US13/984,352 patent/US20130345061A1/en not_active Abandoned
- 2012-02-09 CN CN2012800084326A patent/CN103458682A/zh active Pending
- 2012-02-09 EP EP12708888.8A patent/EP2672814B1/fr not_active Not-in-force
- 2012-02-09 PL PL12708888T patent/PL2672814T3/pl unknown
- 2012-02-09 MY MYPI2013004449A patent/MY157540A/en unknown
-
2013
- 2013-07-22 CO CO13172853A patent/CO6771424A2/es unknown
- 2013-08-07 CL CL2013002297A patent/CL2013002297A1/es unknown
- 2013-09-10 EC ECSP13012872 patent/ECSP13012872A/es unknown
Patent Citations (3)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
WO1995031898A1 (fr) | 1994-05-24 | 1995-11-30 | Hoechst Schering Agrevo S.A. | Nouvelles compositions pesticides du type 'emulsion huile dans l'eau' |
WO2005020685A2 (fr) | 2003-08-29 | 2005-03-10 | Luzenac America, Inc. | Composition et methode pour une protection de recolte |
EP2181820A1 (fr) | 2008-10-31 | 2010-05-05 | Mexel Industries | Emulsion huile dans eau ou eau dans l'huile, liquide et stable, à base d'huiles végétales ou minérales |
Non-Patent Citations (2)
Title |
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CHOW; HO, JAOCS, vol. 73, no. 1, 1996 |
SCIENTA HORTICULTURAE, vol. 56, no. 2, December 1993 (1993-12-01), pages 107 - 117 |
Also Published As
Publication number | Publication date |
---|---|
FR2971399B1 (fr) | 2013-02-08 |
CL2013002297A1 (es) | 2014-05-23 |
EP2672814A1 (fr) | 2013-12-18 |
BR112013020279A2 (pt) | 2016-07-12 |
PL2672814T3 (pl) | 2015-05-29 |
EP2672814B1 (fr) | 2014-11-19 |
US20130345061A1 (en) | 2013-12-26 |
FR2971399A1 (fr) | 2012-08-17 |
ECSP13012872A (es) | 2014-04-30 |
CN103458682A (zh) | 2013-12-18 |
MY157540A (en) | 2016-06-15 |
CO6771424A2 (es) | 2013-10-15 |
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