WO2012153705A1 - Wet exhaust gas purification device - Google Patents

Wet exhaust gas purification device Download PDF

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Publication number
WO2012153705A1
WO2012153705A1 PCT/JP2012/061668 JP2012061668W WO2012153705A1 WO 2012153705 A1 WO2012153705 A1 WO 2012153705A1 JP 2012061668 W JP2012061668 W JP 2012061668W WO 2012153705 A1 WO2012153705 A1 WO 2012153705A1
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WIPO (PCT)
Prior art keywords
exhaust gas
liquid
demister
gas
cleaning
Prior art date
Application number
PCT/JP2012/061668
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French (fr)
Japanese (ja)
Inventor
隆道 細野
克浩 吉澤
広崇 ▲高▼田
英和 岩▲崎▼
元彦 西村
正憲 東田
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川崎重工業株式会社
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Publication of WO2012153705A1 publication Critical patent/WO2012153705A1/en

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    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01DSEPARATION
    • B01D46/00Filters or filtering processes specially modified for separating dispersed particles from gases or vapours
    • B01D46/10Particle separators, e.g. dust precipitators, using filter plates, sheets or pads having plane surfaces
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01DSEPARATION
    • B01D47/00Separating dispersed particles from gases, air or vapours by liquid as separating agent
    • B01D47/06Spray cleaning
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01DSEPARATION
    • B01D50/00Combinations of methods or devices for separating particles from gases or vapours
    • B01D50/60Combinations of devices covered by groups B01D46/00 and B01D47/00
    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F01MACHINES OR ENGINES IN GENERAL; ENGINE PLANTS IN GENERAL; STEAM ENGINES
    • F01NGAS-FLOW SILENCERS OR EXHAUST APPARATUS FOR MACHINES OR ENGINES IN GENERAL; GAS-FLOW SILENCERS OR EXHAUST APPARATUS FOR INTERNAL COMBUSTION ENGINES
    • F01N3/00Exhaust or silencing apparatus having means for purifying, rendering innocuous, or otherwise treating exhaust
    • F01N3/02Exhaust or silencing apparatus having means for purifying, rendering innocuous, or otherwise treating exhaust for cooling, or for removing solid constituents of, exhaust
    • F01N3/04Exhaust or silencing apparatus having means for purifying, rendering innocuous, or otherwise treating exhaust for cooling, or for removing solid constituents of, exhaust using liquids
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01DSEPARATION
    • B01D2247/00Details relating to the separation of dispersed particles from gases, air or vapours by liquid as separating agent
    • B01D2247/04Regenerating the washing fluid
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01DSEPARATION
    • B01D2247/00Details relating to the separation of dispersed particles from gases, air or vapours by liquid as separating agent
    • B01D2247/08Means for controlling the separation process
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01DSEPARATION
    • B01D2247/00Details relating to the separation of dispersed particles from gases, air or vapours by liquid as separating agent
    • B01D2247/10Means for removing the washing fluid dispersed in the gas or vapours
    • B01D2247/107Means for removing the washing fluid dispersed in the gas or vapours using an unstructured demister, e.g. a wire mesh demister
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01DSEPARATION
    • B01D2279/00Filters adapted for separating dispersed particles from gases or vapours specially modified for specific uses
    • B01D2279/30Filters adapted for separating dispersed particles from gases or vapours specially modified for specific uses for treatment of exhaust gases from IC Engines
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02TCLIMATE CHANGE MITIGATION TECHNOLOGIES RELATED TO TRANSPORTATION
    • Y02T10/00Road transport of goods or passengers
    • Y02T10/10Internal combustion engine [ICE] based vehicles
    • Y02T10/12Improving ICE efficiencies

Definitions

  • the present invention relates to a wet exhaust gas purification device, and more particularly to a wet exhaust gas purification device capable of removing dust such as unburned carbon components and unburned oil in exhaust gas discharged from a diesel engine.
  • a diesel engine such as a diesel engine is a combustion method in which liquid fuel such as light oil or A heavy oil is directly injected into a combustion chamber, and the evaporated fuel is burned while diffusing into the surrounding air. For this reason, mixing of fuel and air (oxygen) tends to be uneven, and particulate matter dust called particulate matter (hereinafter referred to as “PM”) is generated.
  • PM particulate matter dust
  • diesel engines tend to generate NOx (nitrogen oxides), but if the combustion temperature is lowered to a region where NOx is difficult to generate, the amount of PM emission further increases.
  • PM includes sulfur oxides produced by the reaction of sulfur in the fuel by combustion, soot produced from parts not in contact with the combustion air when the fuel burns, and fuel adhering to the walls of the combustion chamber, etc. And SOF (Soluble Organic Fraction: unburned portion of fuel and lubricant) etc. are included. These cause serious damage to the respiratory tract and are the most important substances to clean diesel exhaust.
  • dust contained in the gas to be treated is captured by bringing the gas to be treated introduced into the apparatus into contact with, for example, mist (mist) water sprayed from a spray nozzle.
  • mist mist
  • a wet exhaust gas purifier that passes a mixed atmosphere of gas and mist liquid through a demister to separate droplets and discharges the purified processing gas out of the system by a suction blower (for example, patents) (See Reference 2 and Patent Reference 3.)
  • the exhaust gas purification device disclosed in Patent Document 1 has a low collection efficiency of fine dust having a particle size of several ⁇ m or less, such as PM in exhaust gas discharged from a diesel engine, and a large amount of dust. In some cases, the filter is likely to be clogged.
  • the wet exhaust gas purification device disclosed in Patent Document 2 includes a demister and a filter that remove oil mist in the gas to be treated discharged from the kitchen space, and deposits adhered to the demister and the filter are heated by heating means. Wash with heated cleaning solution.
  • the wet exhaust gas purification device disclosed in Patent Document 3 cleans dust adhering to the scrubber with the cleaning water supplied from the water pump. Since the demister cleaning water uses the stored water in the apparatus, it is not necessary to supply the cleaning water from another system.
  • the conventional wet exhaust gas purifying apparatus sprays cleaning water from the top and bottom of the demister by means of a spray nozzle to clean and remove PM accumulated in the demister.
  • the PM deposit that closes the gap of the demister contains unburned fuel and lubricating oil, the deposit is very viscous and has low wettability with respect to the washing water. .
  • the present invention provides a wet exhaust gas purification device that can easily clean and remove PM deposited on a demister and that can use a demister with a high collection efficiency and a high exhaust gas purification efficiency. With the goal.
  • the wet exhaust gas purifying apparatus of the present invention is a dust containing liquid treatment means for storing a treatment liquid, a treatment liquid stored in the liquid storage means, and an exhaust gas discharged from a combustion apparatus in gas-liquid contact.
  • Gas-liquid contact means that absorbs and captures the liquid in the processing liquid
  • gas-liquid separation means that is disposed downstream of the gas-liquid contact means and separates the liquid from the exhaust gas after processing including the processing liquid that has captured dust.
  • It is a wet exhaust gas purification device.
  • This wet exhaust gas purification apparatus has a cleaning means for injecting a cleaning liquid to the gas-liquid separation means and removing dust adhering to the gas-liquid separation means, and a cleaning liquid heating means for heating the cleaning liquid.
  • PM deposited on the demister can be easily cleaned and removed. For this reason, it becomes possible to use the demister of the porosity with high collection efficiency, and can provide the wet exhaust gas purification apparatus with high purification efficiency of exhaust gas.
  • FIG. 1 is an overall configuration diagram showing an exhaust gas purification system according to an embodiment of the present invention. It is a schematic block diagram which shows the wet exhaust gas purification apparatus which concerns on embodiment of this invention. It is a schematic block diagram which shows the modification of the wet exhaust gas purification apparatus which concerns on embodiment of this invention.
  • a wet exhaust gas purification apparatus (hereinafter referred to as “scrubber”) according to an embodiment of the present invention will be described with reference to the accompanying drawings.
  • a scrubber suitable for removing dust in exhaust gas discharged from a combustion apparatus of a diesel engine mainly for ships, land-traveling vehicles, and stationary on land will be described.
  • the present invention can be similarly applied to a scrubber that removes dust in exhaust gas discharged from a combustion apparatus such as an industrial boiler or a gasification furnace.
  • liquid in the gas-liquid separation in the following embodiment means that the liquid is finally removed from the fluid in a liquid state, and is included in the fluid before removal. It is not always necessary to be in a “liquid” state.
  • Liquid in gas-liquid separation includes all particles that are suspended in the air but are not in the form of a single gas molecule.
  • the term “demister” is used to perform gas-liquid separation, but the concept of “demister” of the present invention includes what is called a “mist separator”.
  • reference numeral 1 denotes a diesel engine, and in this embodiment, a marine two-cycle diesel engine.
  • the diesel engine 1 has a water cooling jacket (not shown) in a cylinder head, a side wall portion, and the like, and the cooling water flows through the water cooling jacket to cool the portion to a predetermined temperature.
  • a first pipe 100 is connected to the exhaust pipe 10 of the diesel engine 1, and a second pipe 110 is connected to the intake pipe 11.
  • the diesel engine 1 is provided with a supercharger 2.
  • the supercharger 2 is configured by connecting a turbine rotor 20 and a compressor impeller 21 by a shaft body 22.
  • the turbine rotor 20 is connected to the first pipe line 100 (exhaust side), and the compressor impeller 21 is connected to the second pipe line 110 (intake side).
  • the heat energy of the exhaust gas is converted into rotational energy, and the compressor impeller 21 connected to the turbine rotor 20 rotates to air (fluid containing oxygen). From the atmosphere.
  • the air compressed by the compressor impeller 21 of the supercharger 2 is cooled by the air cooler 3 and then supplied to the combustion chamber of the diesel engine 1.
  • the filling rate of the combustion chamber of the diesel engine 1 is increased, and the output of the diesel engine 1 is increased.
  • exhaust gas recirculation for introducing a part of the combustion exhaust gas to the intake side is used.
  • the diesel engine 1 to which EGR is applied has a third pipeline 120 connected so as to bypass the first pipeline 100 and the second pipeline 110.
  • the scrubber 4 that captures PM contained in the exhaust gas of the diesel engine 1 in contact with the treated water in order from the upstream side of the gas flow, and the suction that sucks the treated gas purified by the scrubber 4
  • a blower 7 and a gas cooler 8 for cooling the processing gas are connected, and a part of the exhaust gas of the diesel engine 1 (for example, an exhaust gas amount corresponding to 30% of the total exhaust gas amount) is returned to the second pipe 110. And recirculated to the diesel engine 1.
  • the scrubber 4 can capture SOx (sulfur oxide) by bringing the exhaust gas into contact with the treated water.
  • the scrubber 4 is formed in a vertical cylindrical shape, and includes a lower casing 4a and an upper casing 4b provided on the upper portion of the lower casing 4a.
  • a liquid storage part 41 for storing the processed water (process liquid) 40 is formed.
  • the liquid storage unit 41 is provided with a heater 42 for heating the treated water 40 to a predetermined temperature, and the outside of the lower casing 4a is externally covered with a heat insulating material such as glass wool, so that the treated water 40 is heated to 60 ° C., for example. It is supposed to be retained.
  • treated gas introduction pipe 43 for introducing exhaust gas of the diesel engine 1 (hereinafter referred to as “treated gas”) into the scrubber 4.
  • treated gas exhaust gas of the diesel engine 1
  • a spray nozzle 44 as gas-liquid contact means for spraying mist-like treated water 40 downward with respect to the gas to be treated introduced into the scrubber 4 is disposed above the liquid reservoir 41.
  • a circulation pipe 451 having a circulation pump 45 for transferring the treated water 40 in the liquid reservoir 41 is connected to the spray nozzle 44.
  • the treated water 40 sprayed from the spray nozzle 44 is once collected in the liquid storage unit 41, transferred through a circulation pipe 451, and forms a circulation line for spraying from the spray nozzle 44 again.
  • impurities are removed from the treated water 40 transferred to the spray nozzle 44 by a filter 452.
  • the flow rate of the treated water 40 sprayed from the spray nozzle 44 can be changed as appropriate by adjusting the opening of the valve 453.
  • the mist-like treated water 40 sprayed from the spray nozzle 44 is brought into contact with the gas to be treated.
  • the treated water 40 in the liquid storage unit 41 is bubbled so that the gas and mist It is also possible to create a mixed atmosphere with the liquid and to bring it into contact with the gas to be processed.
  • a processing gas discharge pipe 46 for discharging the processing gas purified by the scrubber 4 is connected to the upper part of the upper casing 4b.
  • two demisters as gas-liquid separation means are arranged along the gas flow path 47.
  • the demisters are a demister 50 and a demister 51 from the gas flow upstream toward the gas flow downstream.
  • the demister 50 on the upstream side of the gas flow and the demister 51 on the downstream side of the gas flow are arranged with a predetermined distance.
  • the number of demisters can be changed as appropriate according to the amount of gas to be processed in the scrubber 4 and the properties of the gas to be processed.
  • the demisters 50 and 51 are structures in which flexible metal strands are entangled with each other to form a corrugated shape, and disk-like members are overlapped so that the corrugated shape is alternated.
  • the demisters 50 and 51 have a function of separating the liquid droplets by passing the mixed atmosphere of the gas sent from the lower casing 4 a and the mist-like liquid through the demisters 50 and 51.
  • the void ratio in the demister 50 and the void ratio in the demister 51 may be substantially the same. However, since the demister 50 on the upstream side of the gas flow may be easily clogged, the demister 50 on the upstream side of the gas flow may be clogged. It is preferable to set the porosity higher than the porosity of the demister 51 on the downstream side of the gas flow.
  • the “porosity” in the demister 50 (51) is, for example, the roughness of the lattice of a metal wire, and the coarser the mesh, the higher the porosity.
  • pressure gauges 520 and 521 are connected to the side wall of the upper casing 4b in order to check whether or not clogging has occurred inside the demisters 50 and 51.
  • the pressure gauges 520 and 521 measure the pressure difference (pressure loss) between the gas flow upstream side and the gas flow downstream side of each demister 50 and 51.
  • a cleaning spray nozzle for cleaning the demisters 50 and 51 is provided.
  • cleaning spray nozzles 53aa spraying cleaning water (cleaning liquid) upward from the vicinity of the gas flow toward the demister 50, and cleaning water spraying downward from the vicinity of the gas flow toward the demister 50.
  • cleaning spray nozzles 53ab are arranged.
  • the cleaning spray nozzles 53aa and 53ab and the cleaning spray nozzles 53ba and 53bb are connected to the branch pipe 54, respectively.
  • Each branch pipe 54 is connected to a branch pipe 55 having valves 550 and 551, and these are connected to a hot water heater 60 that is a cleaning liquid heating means via a hot water supply pipe 56.
  • a valve is provided in each branch pipe 54, and both of the spray nozzles 53aa and 53ab (53ba and 53bb) are used at the same time by independently controlling the opening and closing of these valves.
  • a configuration that can be used is also possible.
  • the water heater 60 is set so that the washing water becomes, for example, warm water of 60 ° C. Thereby, the washing water heated from the washing spray nozzles 53aa, 53ab, 53ba, 53bb is sprayed.
  • FIG. 3 is a modification of the scrubber 4 of the present embodiment.
  • two cleaning spray nozzles 53ba spraying upward cleaning water (cleaning liquid) from the vicinity of the gas flow upstream toward the central region 51a of the demister 51, and upward cleaning water toward the outer peripheral region 51b of the demister 51.
  • Two cleaning spray nozzles 53bb for spraying are disposed.
  • Two cleaning spray nozzles 53cb for spraying are disposed.
  • the branch pipe L1 connecting each of the cleaning spray nozzles 53ba and 53bb is provided with valves V1 and V2, and the opening and closing of these valves V1 and V2 are controlled independently to thereby control the spray nozzles 53ba and 53bb. Both can be used at the same time, or either one can be selected and used.
  • the branch pipe L1 connecting the cleaning spray nozzles 53ca and 53cb is also provided with valves V3 and V4.
  • both the spray nozzles 55ba and 55bb can be used at the same time, or one of them can be selected and used. . Thereby, even if the scrubber 4 is in operation, the demister 51 can be cleaned without sealing the demister 51 with cleaning water.
  • the number of spray nozzles can be changed as appropriate according to the amount of gas to be processed in the scrubber 4, the sizes of the scrubber 4 and the demisters 50 and 51, the desired cleaning range, and the like.
  • the heated washing water may be obtained by exchanging heat with another heat medium.
  • a heat exchanger 65 for recovering the sensible heat of exhaust gas from the diesel engine 1 is separately provided, and the normal temperature wash water supplied from the wash water supply source 70 is used as the heat exchanger.
  • the cleaning water heated to about 60 ° C. by supplying to 65 may be produced and supplied to the cleaning spray nozzles 53aa and 53ab and the cleaning spray nozzles 53ba and 53bb.
  • the heat exchanger 65 may recover the sensible heat of the cooling water (about 80 to 90 ° C.) of the diesel engine 1 instead of the one that recovers the exhaust gas sensible heat of the diesel engine 1.
  • a pipe 67 having a valve 671 is branched from the circulation pipe 451 and the pipe 67 is connected to the hot water supply pipe 56, and the treated water 40 at about 60 ° C. stored in the liquid storage section 41 is supplied.
  • the cleaning spray nozzles 53aa and 53ab and the cleaning spray nozzles 53ba and 53bb may be supplied.
  • the heat energy of the exhaust gas is converted into rotational energy, and the compressor impeller 21 connected to the turbine rotor 20 rotates to suck air (fluid containing oxygen) from the atmosphere.
  • the air compressed by the compressor impeller 21 of the supercharger 2 is cooled by the air cooler 3 and then supplied to the combustion chamber of the diesel engine 1.
  • the exhaust gas discharged from the supercharger 2 is diffused into the atmosphere through an exhaust silencer (not shown).
  • a part of the exhaust gas from the diesel engine 1 (for example, the exhaust gas amount corresponding to 30% of the total exhaust gas amount) is introduced into the scrubber 4 through the third pipe line 120 as the gas to be treated.
  • the scrubber 4 captures PM contained in the gas to be treated by bringing the water to be treated into contact with the gas to be treated.
  • the processing of the gas to be processed by the scrubber 4 will be described later with reference to FIG.
  • the processing gas purified by the scrubber 4 is discharged by the suction blower 7, cooled to a predetermined temperature by the gas cooler 8, and recirculated to the diesel engine 1 through the second pipe 110.
  • the gas to be treated introduced into the scrubber 4 is in countercurrent contact with the mist-like treated water 40 (about 60 ° C.) sprayed from the spray nozzle 44. Thereby, the PM contained in the gas to be treated is absorbed in the treated water 40 and captured. Thereafter, the mixed atmosphere of the gas and the mist-like liquid (treated water 40) is sent along the gas flow path 47 to demisters 50 and 51 as gas-liquid separation means in the upper casing 4b. The mixed atmosphere of the gas sent from the lower casing 4a and the mist-like liquid passes through the demisters 50 and 51, so that the liquid droplets are separated, and the liquid droplets are collected in the liquid storage part 41 in the lower casing 4a. Is done. On the other hand, the processing gas purified by passing through the demisters 50 and 51 is discharged by a suction blower (not shown).
  • the pressure difference (pressure loss) between the gas flow upstream side and the gas flow downstream side of each demister 50 and 51 is measured during the operation of the scrubber 4. It is preferable to monitor the indicated values of the pressure gauges 520 and 521 constantly or at regular intervals.
  • the demister 50 When the indicated value shows a predetermined value or more during operation, there is a high probability that the corresponding demister 50 (51) is clogged. In the description of this operation, it is assumed that the demister 50 is clogged. In this case, first, the water heater 60 is activated. Then, the valve 550 of the branch pipe 55 communicating with the cleaning spray nozzles 53aa and 53ab is opened, and the cleaning water heated to about 60 ° C. with respect to the demister 50 from the gas flow upstream side and the gas flow downstream side of the demister 50. Spray.
  • the spray of cleaning water on the demister 50 (51) may be continuous spraying. However, when the cleaning water is sprayed on the entire area of the demister 50 (51) as in the present embodiment, the water film of the cleaning water becomes the demister 50 (51). There is a possibility that the pressure difference (pressure loss) between the gas flow upstream side and the gas flow downstream side of the demister increases during cleaning. In such a case, as described in the modification of FIG. 3, each cleaning spray nozzle may be divided into partial regions, and a valve may be provided for each region so that the cleaning water is not sprayed on the entire surface of the demister.
  • the PM containing oil accumulated in the demister 50 comes into contact with the heated cleaning water, the PM deposit is warmed. As a result, the deposit containing oil begins to drip in the form of a heated low-viscosity liquid, and the PM deposit that has become liquid is easily washed away by the jet of cleaning water. In this case, since the PM containing oil accumulated in the demister 50 starts to drip in the form of a low-viscosity liquid by the heated washing water, the deposit is completely washed and removed. The cleaning time and cleaning water required are very small.
  • valve 550 of the branch pipe 55 is closed to stop the supply of the cleaning water to the cleaning spray nozzles 53aa and 53ab. It should be noted that the same procedure as described above is performed when the PM containing oil accumulated in the demister 51 is cleaned and removed.
  • the control means (not shown) of the scrubber 4 takes pressure measurement data and determines whether the demister 50 (51) is clogged, and then the heated cleaning water.
  • the spray control may be executed.
  • the spray of the cleaning water by the cleaning spray nozzles 53aa and 53ab may be sprayed simultaneously from the vertical direction to the demister 50 (51) as in the present embodiment.
  • the spray nozzle 53aa , 53ab (53ba, 53bb) may be added one by one, and either one of the upper direction and the lower direction may be selected and sprayed with cleaning water.
  • these spraying times may overlap each other or may not overlap each other.
  • the PM containing the oil accumulated in the demister 50 (51) is made into a low-viscosity liquid with the heated washing water, and then heated. Since the washed water is sprayed, the washing time and amount of washing water required for washing / removal are very small. After being cleaned and removed, the demister 50 (51) can be reused in a state almost similar to a new one.
  • the demister 50 (51) that has been cleaned and removed as described above can be reused in a state almost similar to a new one, a pressure difference (pressure) between the gas flow upstream side and the gas flow downstream side of the demister 50 (51). Loss), the power of the suction blower 7 due to an increase in pressure loss, and the problem that the suction blower 7 falls short of exhaust gas suction can be avoided. Further, even when a part of the exhaust gas of the diesel engine 1 (for example, the exhaust gas amount corresponding to 30% of the total exhaust gas amount) is recirculated to the diesel engine 1 as in the present embodiment, the exhaust gas recirculation is performed. There is no shortage of volume.
  • a demister with a low porosity (high collection efficiency) was clogged early and difficult to use, but in the present embodiment, it contains oil accumulated in the demister 50 (51). Since PM can be easily cleaned and removed, one having a low porosity (high collection efficiency) can be used. Thereby, the dust removal performance of the scrubber 4 is improved. Since the dust removal performance of the scrubber 4 is improved, the dust mixed in the suction blower 7, the gas cooler 8, and the diesel engine 1 connected thereto can be extremely reduced. As a result, the maintenance of those facilities becomes easy and the lifetime can be extended.

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  • Chemical & Material Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Engineering & Computer Science (AREA)
  • Combustion & Propulsion (AREA)
  • Mechanical Engineering (AREA)
  • General Engineering & Computer Science (AREA)
  • Separation Of Particles Using Liquids (AREA)
  • Treating Waste Gases (AREA)
  • Processes For Solid Components From Exhaust (AREA)
  • Exhaust Gas After Treatment (AREA)
  • Separating Particles In Gases By Inertia (AREA)

Abstract

 Provided is a wet exhaust gas purification device that enables the simple cleaning/removal of PM accumulated in a demister, enables the use of a low porosity, high collection efficiency demister, and exhibits high exhaust gas purification efficiency. After converting PM that is accumulated inside a demister (50, 51) and that contains an oil component into a low viscosity liquid using heated wash water, the wet exhaust gas purification device sprays the heated wash water so that the wash time and volume of wash water volume required for cleansing/removal are negligible. After cleansing/removal, the demister (50, 51) can be re-used in a state that is almost as good as new. Thus, the pressure drop between the gas stream upstream side and the gas stream downstream side of the demister (50, 51) is increased, the power of a suction blower (7) is increased by the increase in the pressure drop, and the problem of insufficient exhaust suction by the suction blower (7) is avoided.

Description

湿式排ガス浄化装置Wet exhaust gas purification device
 本発明は、湿式排ガス浄化装置に係り、特に、ディーゼル機関から排出される排ガス中の未燃焼炭素成分や未燃焼油分等のダストを除去可能な湿式排ガス浄化装置に関する。 The present invention relates to a wet exhaust gas purification device, and more particularly to a wet exhaust gas purification device capable of removing dust such as unburned carbon components and unburned oil in exhaust gas discharged from a diesel engine.
 ディーゼルエンジン等のディーゼル機関は、軽油又はA重油等の液体燃料を燃焼室内に直接噴射し、蒸発した燃料が周囲の空気に拡散しながら燃焼する燃焼方法である。このため、燃料と空気(酸素)との混合が不均一になりやすく、パティキュレートマター(以下、「PM」と称する。)と呼ばれる粒状物質のダストが発生する。また、一般的にディーゼル機関ではNOx(窒素酸化物)が発生しやすいが、NOxが発生しにくい領域まで燃焼温度を下げると、PMの排出量が更に増大する。 A diesel engine such as a diesel engine is a combustion method in which liquid fuel such as light oil or A heavy oil is directly injected into a combustion chamber, and the evaporated fuel is burned while diffusing into the surrounding air. For this reason, mixing of fuel and air (oxygen) tends to be uneven, and particulate matter dust called particulate matter (hereinafter referred to as “PM”) is generated. In general, diesel engines tend to generate NOx (nitrogen oxides), but if the combustion temperature is lowered to a region where NOx is difficult to generate, the amount of PM emission further increases.
 PMには、燃焼により燃料中の硫黄分が反応して生成される硫黄酸化物、燃料が燃焼する時に燃焼用空気と未接触の部分から生成する煤、及び燃焼室の壁等に付着した燃料や潤滑油に起因するSOF(Soluble Organic Fraction:燃料や潤滑油の未燃焼分)等が含まれている。これらは、呼吸器に重大な障害をもたらし、ディーゼル排ガスを浄化するうえで最も考慮すべき物質である。 PM includes sulfur oxides produced by the reaction of sulfur in the fuel by combustion, soot produced from parts not in contact with the combustion air when the fuel burns, and fuel adhering to the walls of the combustion chamber, etc. And SOF (Soluble Organic Fraction: unburned portion of fuel and lubricant) etc. are included. These cause serious damage to the respiratory tract and are the most important substances to clean diesel exhaust.
 従来、排ガス(被処理ガス)中のダストを除去して浄化する排ガス浄化装置が種々提案されている。その一例として、煙道にセラミックス製多孔質フィルタ(DPF:ディーゼルパティキュレートフィルタ)を設置してダストを濾過捕集し、更にフィルタを加熱することにより、捕集した未燃焼炭素成分や未燃焼油分等のダストを燃焼除去する排ガス浄化装置が知られている(例えば、特許文献1参照。)。 Conventionally, various exhaust gas purification apparatuses that remove and purify dust in exhaust gas (treated gas) have been proposed. As an example, a ceramic porous filter (DPF: Diesel Particulate Filter) is installed in the flue, and dust is filtered and collected, and further, the filter is heated to collect the unburned carbon components and unburned oil components. 2. Description of the Related Art An exhaust gas purifying apparatus that burns and removes such dust is known (for example, see Patent Document 1).
 他の一例として、装置内に導入された被処理ガスに、例えば、スプレーノズルから噴霧される霧状(ミスト状)の水を接触させることにより被処理ガス中に含まれるダストを捕捉し、その後、気体と霧状の液体との混合雰囲気をデミスタに通過させて液滴を分離し、浄化された処理ガスを吸引ブロワにより系外に排出する湿式排ガス浄化装置も知られている(例えば、特許文献2及び特許文献3参照。)。 As another example, dust contained in the gas to be treated is captured by bringing the gas to be treated introduced into the apparatus into contact with, for example, mist (mist) water sprayed from a spray nozzle. Also known is a wet exhaust gas purifier that passes a mixed atmosphere of gas and mist liquid through a demister to separate droplets and discharges the purified processing gas out of the system by a suction blower (for example, patents) (See Reference 2 and Patent Reference 3.)
特開2004-162626号公報JP 2004-162626 A 特開2006-231170号公報JP 2006-231170 A 実開平7-013420号公報Japanese Utility Model Publication No. 7-013420
 特許文献1に開示されている排ガス浄化装置は、ディーゼル機関から排出される排ガス中のPMのような数μm以下の粒径の微細なダストの捕集効率が低く、また、ダストの量が多い場合にはフィルタが目詰まりを起こしやすいという問題がある。 The exhaust gas purification device disclosed in Patent Document 1 has a low collection efficiency of fine dust having a particle size of several μm or less, such as PM in exhaust gas discharged from a diesel engine, and a large amount of dust. In some cases, the filter is likely to be clogged.
 特許文献2に開示されている湿式排ガス浄化装置は、厨房空間から排出された被処理ガス中のオイルミストを除去するデミスタとフィルタを有し、デミスタとフィルタに付着した付着物を、加熱手段により加熱された洗浄液で洗浄する。 The wet exhaust gas purification device disclosed in Patent Document 2 includes a demister and a filter that remove oil mist in the gas to be treated discharged from the kitchen space, and deposits adhered to the demister and the filter are heated by heating means. Wash with heated cleaning solution.
 また、特許文献3に開示されている湿式排ガス浄化装置は、水ポンプから供給される洗浄水でスクラバーに付着したダストを洗浄する。デミスタの洗浄水は、装置内の溜水を用いるので他の系統から洗浄水を供給する必要がない。 Also, the wet exhaust gas purification device disclosed in Patent Document 3 cleans dust adhering to the scrubber with the cleaning water supplied from the water pump. Since the demister cleaning water uses the stored water in the apparatus, it is not necessary to supply the cleaning water from another system.
 従来の湿式排ガス浄化装置において、被処理ガスとしてディーゼル排ガスを処理する場合、以下のような問題が起こり得る。気体と霧状の液体との混合雰囲気がデミスタを通過する際、液滴は分離できる。しかし、液滴の中にはPMが捕捉されているため、液滴と一緒に滴下しないPMがデミスタに一部残留する。また、ディーゼル排ガスに含まれるPMは数μm以下の非常に小さな粒径であることから、装置内で処理水を噴霧してもPMがガス流に乗って処理水の噴霧液滴を容易に迂回するため、液滴と慣性衝突して捕捉されないPMがデミスタに付着する。 In the conventional wet exhaust gas purification apparatus, when diesel exhaust gas is treated as the gas to be treated, the following problems may occur. When the mixed atmosphere of gas and mist liquid passes through the demister, the droplets can be separated. However, since the PM is trapped in the droplet, a part of the PM that does not drop together with the droplet remains in the demister. Also, since the PM contained in diesel exhaust gas has a very small particle size of several μm or less, even if the treated water is sprayed in the device, the PM rides on the gas flow and easily bypasses the spray droplets of the treated water Therefore, PM that is not captured due to inertial collision with the droplet adheres to the demister.
 PMがデミスタに付着すると、時間経過とともにデミスタの空隙部が徐々に狭まり、デミスタを通過する排ガスの速度が低下する。この速度低下によりPMが更に堆積する悪循環が生じ、デミスタのガス流上流側とガス流下流側の間における圧力差(圧力損失)が高くなり、吸引ブロワの動力が増大する。 When PM adheres to the demister, the gap of the demister gradually narrows with time, and the speed of the exhaust gas passing through the demister decreases. This speed reduction causes a vicious cycle in which PM accumulates further, the pressure difference (pressure loss) between the gas flow upstream side and the gas flow downstream side of the demister increases, and the power of the suction blower increases.
 さらに、デミスタ内でのPMの堆積が増加すると目詰まりが発生し、吸引ブロワが排ガス吸引不足に陥る。このデミスタの目詰まりの問題は、捕集効率の高いデミスタ(空隙率の低いデミスタ)であるほど早期に発生する。 Furthermore, when PM accumulation in the demister increases, clogging occurs and the suction blower falls into exhaust gas suction. The problem of clogging of the demister occurs earlier as the demister having a higher collection efficiency (a demister having a lower porosity).
 このため、従来の湿式排ガス浄化装置は、スプレーノズルによりデミスタの上下方向から洗浄水を噴霧し、デミスタ内に堆積しているPMを洗浄・除去していた。しかし、デミスタの空隙部を塞ぐPMの堆積物には燃料や潤滑油の未燃焼分が含まれていることから、その堆積物は非常に高粘度であり、洗浄水に対して濡れ性が低い。 For this reason, the conventional wet exhaust gas purifying apparatus sprays cleaning water from the top and bottom of the demister by means of a spray nozzle to clean and remove PM accumulated in the demister. However, since the PM deposit that closes the gap of the demister contains unburned fuel and lubricating oil, the deposit is very viscous and has low wettability with respect to the washing water. .
 しかし、単に洗浄水を噴霧するだけの従来の洗浄方法では、デミスタ内に堆積しているPMを完全に洗浄・除去すること(デミスタを使用前の状態に洗浄・除去すること)は困難であることに加えて、洗浄に時間を要し、多量の洗浄水を消費してしまう。 However, it is difficult to completely clean and remove the PM accumulated in the demister (cleaning and removing the demister to the state before use) by the conventional cleaning method in which the cleaning water is simply sprayed. In addition, it takes time for washing and consumes a large amount of washing water.
 このように、従来の湿式排ガス浄化装置では、デミスタに堆積したPMを完全に洗浄・除去することが困難であるため、捕集効率の高いデミスタ(空隙率の低いデミスタ)を用いることができず、排ガスの浄化効率の高い湿式排ガス浄化装置を提供できないという問題があった。 As described above, in the conventional wet exhaust gas purification device, it is difficult to completely clean and remove the PM deposited on the demister, and therefore it is not possible to use a demister with a high collection efficiency (a demister with a low porosity). There has been a problem that a wet exhaust gas purification device with high exhaust gas purification efficiency cannot be provided.
 したがって、本発明は、デミスタに堆積したPMを容易に洗浄・除去できるとともに、捕集効率の高い空隙率のデミスタを用いることが可能で、排ガスの浄化効率の高い湿式排ガス浄化装置を提供することを目的とする。 Accordingly, the present invention provides a wet exhaust gas purification device that can easily clean and remove PM deposited on a demister and that can use a demister with a high collection efficiency and a high exhaust gas purification efficiency. With the goal.
 本発明の湿式排ガス浄化装置は、処理液を貯留する液溜手段と、該液貯留手段に貯留された処理液と燃焼装置から排出された排ガスとを気液接触させ、排ガス中に含有するダストを処理液中に吸収して捕捉させる気液接触手段と、気液接触手段の下流側に配置され、ダストを捕捉した処理液を含む処理後の排ガスから液体を分離する気液分離手段とを有する湿式排ガス浄化装置である。この湿式排ガス浄化装置は、気液分離手段に洗浄液を噴射し、該気液分離手段に付着したダストを除去する洗浄手段と、洗浄液を加温する洗浄液加熱手段とを有している。 The wet exhaust gas purifying apparatus of the present invention is a dust containing liquid treatment means for storing a treatment liquid, a treatment liquid stored in the liquid storage means, and an exhaust gas discharged from a combustion apparatus in gas-liquid contact. Gas-liquid contact means that absorbs and captures the liquid in the processing liquid, and gas-liquid separation means that is disposed downstream of the gas-liquid contact means and separates the liquid from the exhaust gas after processing including the processing liquid that has captured dust. It is a wet exhaust gas purification device. This wet exhaust gas purification apparatus has a cleaning means for injecting a cleaning liquid to the gas-liquid separation means and removing dust adhering to the gas-liquid separation means, and a cleaning liquid heating means for heating the cleaning liquid.
 本発明によれば、デミスタに堆積したPMを容易に洗浄・除去できる。このため、捕集効率の高い空隙率のデミスタを用いることが可能となり、排ガスの浄化効率の高い湿式排ガス浄化装置を提供できる。 According to the present invention, PM deposited on the demister can be easily cleaned and removed. For this reason, it becomes possible to use the demister of the porosity with high collection efficiency, and can provide the wet exhaust gas purification apparatus with high purification efficiency of exhaust gas.
本発明の実施の形態に係る排ガス浄化システムを示す全体構成図である。1 is an overall configuration diagram showing an exhaust gas purification system according to an embodiment of the present invention. 本発明の実施の形態に係る湿式排ガス浄化装置を示す概略構成図である。It is a schematic block diagram which shows the wet exhaust gas purification apparatus which concerns on embodiment of this invention. 本発明の実施の形態に係る湿式排ガス浄化装置の変形例を示す概略構成図である。It is a schematic block diagram which shows the modification of the wet exhaust gas purification apparatus which concerns on embodiment of this invention.
 以下、本発明の実施の形態に係る湿式排ガス浄化装置(以下、「スクラバー」と称する。)について、添付図面に従って説明する。以下の実施の形態では、主として船舶用、陸上走行車両用、陸上定置用のディーゼル機関の燃焼装置から排出される排ガス中のダストを除去するのに好適なスクラバーを説明するが、本発明は例えば、工業用のボイラやガス化炉等の燃焼装置から排出される排ガス中のダストを除去するスクラバーにも同様に採用できる。 Hereinafter, a wet exhaust gas purification apparatus (hereinafter referred to as “scrubber”) according to an embodiment of the present invention will be described with reference to the accompanying drawings. In the following embodiments, a scrubber suitable for removing dust in exhaust gas discharged from a combustion apparatus of a diesel engine mainly for ships, land-traveling vehicles, and stationary on land will be described. The present invention can be similarly applied to a scrubber that removes dust in exhaust gas discharged from a combustion apparatus such as an industrial boiler or a gasification furnace.
 なお、以下の説明では、方向や位置を表す用語(例えば、「上部」、「下部」等)を便宜上用いるが、これらは発明の理解を容易にするためであり、それらの用語の意味によって本発明の技術的範囲が限定されるものではない。また、以下の説明は、本発明の一形態の例示に過ぎず、本発明、その適用物或いはその用途を制限することを意図するものではない。 In the following description, terms and directions (for example, “upper part”, “lower part”, etc.) are used for convenience, but these are for the purpose of facilitating the understanding of the invention. The technical scope of the invention is not limited. Further, the following description is merely an example of one embodiment of the present invention, and is not intended to limit the present invention, its application, or its use.
 なお、以下の実施の形態での気液分離における「液体」とは、最終的には液体の状態となって流体中から除去されるという程度の意味であり、除去前の流体中に含まれる状態において「液体」の状態であることを必ずしも必要としない。気液分離における「液体」は、空中に浮遊する粒子ではあるものの、単独の気体分子の状態ではない全てのものを含む。また、気液分離を行うものとして「デミスタ」の用語を使用するが、本発明の「デミスタ」の概念は、「ミストセパレータ」として呼ばれるものも含む。 Note that “liquid” in the gas-liquid separation in the following embodiment means that the liquid is finally removed from the fluid in a liquid state, and is included in the fluid before removal. It is not always necessary to be in a “liquid” state. “Liquid” in gas-liquid separation includes all particles that are suspended in the air but are not in the form of a single gas molecule. The term “demister” is used to perform gas-liquid separation, but the concept of “demister” of the present invention includes what is called a “mist separator”.
 図1に示すように、符号1はディーゼルエンジンを示し、本実施の形態においては、舶用の2サイクルディーゼルエンジンを示す。ディーゼルエンジン1は、シリンダヘッドや側壁部分等に図示しない水冷ジャケットを有し、冷却水が水冷ジャケット内を流れることにより当該部分が所定温度に冷却される。 As shown in FIG. 1, reference numeral 1 denotes a diesel engine, and in this embodiment, a marine two-cycle diesel engine. The diesel engine 1 has a water cooling jacket (not shown) in a cylinder head, a side wall portion, and the like, and the cooling water flows through the water cooling jacket to cool the portion to a predetermined temperature.
 ディーゼルエンジン1の排気管10には、第1の管路100が接続されており、吸気管11には第2の管路110が接続されている。図示するように、ディーゼルエンジン1には過給機2が備えられている。過給機2は、タービンロータ20と圧縮機インペラ21とが軸体22により連結されて構成されている。タービンロータ20は第1の管路100(排気側)に接続され、圧縮機インペラ21が第2の管路110(吸気側)に接続されている。 A first pipe 100 is connected to the exhaust pipe 10 of the diesel engine 1, and a second pipe 110 is connected to the intake pipe 11. As shown in the figure, the diesel engine 1 is provided with a supercharger 2. The supercharger 2 is configured by connecting a turbine rotor 20 and a compressor impeller 21 by a shaft body 22. The turbine rotor 20 is connected to the first pipe line 100 (exhaust side), and the compressor impeller 21 is connected to the second pipe line 110 (intake side).
 ディーゼルエンジン1の排ガスをタービンロータ20に供給することにより該排ガスの熱エネルギが回転エネルギに変換され、該タービンロータ20に連結されている圧縮機インペラ21が回転して空気(酸素を含む流体)を大気より吸引する。過給機2の圧縮機インペラ21で圧縮された空気はエアクーラ3により冷却された後、ディーゼルエンジン1の燃焼室へ供給される。この過給機2の作用によりディーゼルエンジン1の燃焼室への充填率が高まり、該ディーゼルエンジン1の出力が増大する。 By supplying the exhaust gas of the diesel engine 1 to the turbine rotor 20, the heat energy of the exhaust gas is converted into rotational energy, and the compressor impeller 21 connected to the turbine rotor 20 rotates to air (fluid containing oxygen). From the atmosphere. The air compressed by the compressor impeller 21 of the supercharger 2 is cooled by the air cooler 3 and then supplied to the combustion chamber of the diesel engine 1. By the action of the supercharger 2, the filling rate of the combustion chamber of the diesel engine 1 is increased, and the output of the diesel engine 1 is increased.
 ディーゼルエンジン1からNOxの発生量を抑制する手段として、燃焼排ガスの一部を吸気側へ導入する排気再循環(EGR)が用いられる。図示するように、EGRを適用したディーゼルエンジン1は第1の管路100と第2の管路110とをバイパスするように接続された第3の管路120を有する。第3の管路120には、ガス流上流側から順にディーゼルエンジン1の排ガス中に含まれるPMを処理水と接触させて捕捉するスクラバー4と、スクラバー4で浄化された処理ガスを吸引する吸引ブロワ7と、該処理ガスを冷却するガスクーラ8が接続されており、ディーゼルエンジン1の排ガスの一部(例えば、全排ガス量の3割に相当する排ガス量)を第2の管路110に還流させて該ディーゼルエンジン1に再循環するようにしてある。なお、スクラバー4では排ガスと処理水を接触させてSOx(硫黄酸化物)を捕捉することができる。 As a means for suppressing the amount of NOx generated from the diesel engine 1, exhaust gas recirculation (EGR) for introducing a part of the combustion exhaust gas to the intake side is used. As shown in the figure, the diesel engine 1 to which EGR is applied has a third pipeline 120 connected so as to bypass the first pipeline 100 and the second pipeline 110. In the third pipe line 120, the scrubber 4 that captures PM contained in the exhaust gas of the diesel engine 1 in contact with the treated water in order from the upstream side of the gas flow, and the suction that sucks the treated gas purified by the scrubber 4 A blower 7 and a gas cooler 8 for cooling the processing gas are connected, and a part of the exhaust gas of the diesel engine 1 (for example, an exhaust gas amount corresponding to 30% of the total exhaust gas amount) is returned to the second pipe 110. And recirculated to the diesel engine 1. The scrubber 4 can capture SOx (sulfur oxide) by bringing the exhaust gas into contact with the treated water.
 次に、本実施の形態のスクラバー4について、図2を参照して説明する。スクラバー4は、縦型の筒状に形成され、下部ケーシング4aと、下部ケーシング4aの上部に設けられた上部ケーシング4bとを有する。 Next, the scrubber 4 of the present embodiment will be described with reference to FIG. The scrubber 4 is formed in a vertical cylindrical shape, and includes a lower casing 4a and an upper casing 4b provided on the upper portion of the lower casing 4a.
 下部ケーシング4aの底部には、処理水(処理液)40を貯留する液貯留部41が形成されている。液貯留部41には、処理水40を所定温度に加温するヒータ42が設置されているとともに、下部ケーシング4aの外側をグラスウール等の断熱材で外装し、処理水40が例えば、60℃に保持されるようにしてある。 At the bottom of the lower casing 4a, a liquid storage part 41 for storing the processed water (process liquid) 40 is formed. The liquid storage unit 41 is provided with a heater 42 for heating the treated water 40 to a predetermined temperature, and the outside of the lower casing 4a is externally covered with a heat insulating material such as glass wool, so that the treated water 40 is heated to 60 ° C., for example. It is supposed to be retained.
 液貯留部41の上方位置であって下部ケーシング4aの側壁には、ディーゼルエンジン1の排ガス(以下、「被処理ガス」と称する。)をスクラバー4内に導入する被処理ガス導入管43が接続されている。 Connected to the side wall of the lower casing 4a above the liquid storage section 41 is a treated gas introduction pipe 43 for introducing exhaust gas of the diesel engine 1 (hereinafter referred to as “treated gas”) into the scrubber 4. Has been.
 液貯留部41の上方位置には、スクラバー4内に導入された被処理ガスに対し下向きに霧状の処理水40を噴霧する気液接触手段としてのスプレーノズル44が配置されている。スプレーノズル44には液貯留部41内の処理水40を移送するための循環ポンプ45を有する循環配管451が接続されている。スプレーノズル44から噴霧された処理水40は、液貯留部41内にいったん回収され、循環配管451により移送されて再びスプレーノズル44から噴霧する循環ラインを形成する。図示のとおり、スプレーノズル44に移送される処理水40はフィルタ452により不純物が除去される。なお、スプレーノズル44から噴霧される処理水40の流量は、バルブ453の開度を調節することにより適宜に変更できる。 A spray nozzle 44 as gas-liquid contact means for spraying mist-like treated water 40 downward with respect to the gas to be treated introduced into the scrubber 4 is disposed above the liquid reservoir 41. A circulation pipe 451 having a circulation pump 45 for transferring the treated water 40 in the liquid reservoir 41 is connected to the spray nozzle 44. The treated water 40 sprayed from the spray nozzle 44 is once collected in the liquid storage unit 41, transferred through a circulation pipe 451, and forms a circulation line for spraying from the spray nozzle 44 again. As illustrated, impurities are removed from the treated water 40 transferred to the spray nozzle 44 by a filter 452. The flow rate of the treated water 40 sprayed from the spray nozzle 44 can be changed as appropriate by adjusting the opening of the valve 453.
 本実施の形態では、スプレーノズル44から噴霧される霧状の処理水40を被処理ガスに接触させているが、これに代えて液貯留部41内の処理水40をバブリングさせて気体と霧状の液体との混合雰囲気を作り、これを被処理ガスに接触させてもよい。 In the present embodiment, the mist-like treated water 40 sprayed from the spray nozzle 44 is brought into contact with the gas to be treated. Instead, the treated water 40 in the liquid storage unit 41 is bubbled so that the gas and mist It is also possible to create a mixed atmosphere with the liquid and to bring it into contact with the gas to be processed.
 上部ケーシング4bの上部には、スクラバー4により浄化された処理ガスを排出する処理ガス排出管46が接続されている。 A processing gas discharge pipe 46 for discharging the processing gas purified by the scrubber 4 is connected to the upper part of the upper casing 4b.
 上部ケーシング4b内には、気液分離手段としてのデミスタがガス流路47に沿って2つ配置されている。各デミスタはガス流上流からガス流下流に向かってデミスタ50、デミスタ51とされている。ガス流上流側のデミスタ50と、ガス流下流側のデミスタ51は、それぞれ所定距離をもって配置されている。なお、デミスタの個数は、スクラバー4における被処理ガスの処理量や被処理ガスの性状等に応じて適宜に変更できる。 In the upper casing 4 b, two demisters as gas-liquid separation means are arranged along the gas flow path 47. The demisters are a demister 50 and a demister 51 from the gas flow upstream toward the gas flow downstream. The demister 50 on the upstream side of the gas flow and the demister 51 on the downstream side of the gas flow are arranged with a predetermined distance. The number of demisters can be changed as appropriate according to the amount of gas to be processed in the scrubber 4 and the properties of the gas to be processed.
 デミスタ50,51は、柔軟な金属素線を互いに絡め合わせて波形に形成し、その波形が互い違いになるように円板状の部材を重ね合わせた構造物である。デミスタ50,51は、下部ケーシング4a内から送り込まれてきた気体と霧状の液体との混合雰囲気をデミスタ50,51に通過させることにより液滴を分離する機能を有する。 The demisters 50 and 51 are structures in which flexible metal strands are entangled with each other to form a corrugated shape, and disk-like members are overlapped so that the corrugated shape is alternated. The demisters 50 and 51 have a function of separating the liquid droplets by passing the mixed atmosphere of the gas sent from the lower casing 4 a and the mist-like liquid through the demisters 50 and 51.
 ここで、デミスタ50における空隙率と、デミスタ51における空隙率は、略同一でも構わないが、ガス流上流側のデミスタ50が目詰まりしやすい場合もあることから、ガス流上流側のデミスタ50の空隙率を、ガス流下流側のデミスタ51の空隙率よりも高く設定することが好ましい。なお、デミスタ50(51)における「空隙率」とは、例えば、金属素線で構成される格子の目の粗さであり、目が粗いほど空隙率が高いことを意味する。 Here, the void ratio in the demister 50 and the void ratio in the demister 51 may be substantially the same. However, since the demister 50 on the upstream side of the gas flow may be easily clogged, the demister 50 on the upstream side of the gas flow may be clogged. It is preferable to set the porosity higher than the porosity of the demister 51 on the downstream side of the gas flow. The “porosity” in the demister 50 (51) is, for example, the roughness of the lattice of a metal wire, and the coarser the mesh, the higher the porosity.
 図示するように、上部ケーシング4bの側壁には、各デミスタ50、51の内部に目詰まりが発生しているか否かを確認するため圧力計520,521が接続されている。圧力計520,521は各デミスタ50、51のガス流上流側とガス流下流側の間における圧力差(圧力損失)を測定する。 As shown in the drawing, pressure gauges 520 and 521 are connected to the side wall of the upper casing 4b in order to check whether or not clogging has occurred inside the demisters 50 and 51. The pressure gauges 520 and 521 measure the pressure difference (pressure loss) between the gas flow upstream side and the gas flow downstream side of each demister 50 and 51.
 デミスタ50,51の近傍には、該デミスタ50,51を洗浄するための洗浄スプレーノズル(洗浄手段)が設けられている。具体的に、ガス流上流近傍からデミスタ50に向けて上向きに洗浄水(洗浄液)を噴霧する4つの洗浄スプレーノズル53aaと、ガス流下流近傍から該デミスタ50に向けて下向きに洗浄水を噴霧する4つの洗浄スプレーノズル53abが配置されている。 In the vicinity of the demisters 50 and 51, a cleaning spray nozzle (cleaning means) for cleaning the demisters 50 and 51 is provided. Specifically, four cleaning spray nozzles 53aa spraying cleaning water (cleaning liquid) upward from the vicinity of the gas flow toward the demister 50, and cleaning water spraying downward from the vicinity of the gas flow toward the demister 50. Four cleaning spray nozzles 53ab are arranged.
 デミスタ50とデミスタ51との間であって、デミスタ51のガス流上流近傍には、該デミスタ51に向けて上向きに洗浄水を噴霧する4つの洗浄スプレーノズル53baが配置され、デミスタ51のガス流下流近傍には該デミスタ51に向けて下向きに洗浄水を噴霧する4つの洗浄スプレーノズル53bbが配置されている。 Between the demister 50 and the demister 51, in the vicinity of the upstream of the gas flow of the demister 51, four cleaning spray nozzles 53 ba for spraying cleaning water upward toward the demister 51 are arranged. Four cleaning spray nozzles 53bb for spraying cleaning water downward toward the demister 51 are disposed in the vicinity of the downstream.
 洗浄スプレーノズル53aa,53ab、及び洗浄スプレーノズル53ba,53bbは、それぞれ分岐配管54に接続されている。各分岐配管54はバルブ550,551を有する分岐配管55に接続され、それらが温水供給配管56を介して洗浄液加熱手段である給湯器60に接続されている。なお、各分岐配管54にバルブを設け、それらのバルブの開閉をそれぞれ独立して制御することによりスプレーノズル53aa,53ab(53ba,53bb)の両方を同時に使用したり、いずれか一方を選択して使用したりできる構成にすることも可能である。給湯器60は洗浄水が例えば、60℃の温水になるように設定してある。これにより、洗浄スプレーノズル53aa,53ab、53ba,53bbから加温された洗浄水を噴霧される。 The cleaning spray nozzles 53aa and 53ab and the cleaning spray nozzles 53ba and 53bb are connected to the branch pipe 54, respectively. Each branch pipe 54 is connected to a branch pipe 55 having valves 550 and 551, and these are connected to a hot water heater 60 that is a cleaning liquid heating means via a hot water supply pipe 56. In addition, a valve is provided in each branch pipe 54, and both of the spray nozzles 53aa and 53ab (53ba and 53bb) are used at the same time by independently controlling the opening and closing of these valves. A configuration that can be used is also possible. The water heater 60 is set so that the washing water becomes, for example, warm water of 60 ° C. Thereby, the washing water heated from the washing spray nozzles 53aa, 53ab, 53ba, 53bb is sprayed.
 図3は、本実施の形態のスクラバー4の変形例である。本変形例では、ガス流上流近傍からデミスタ51の中央領域51aに向けて上向きの洗浄水(洗浄液)を噴霧する2つの洗浄スプレーノズル53baと、デミスタ51の外周領域51bに向けて上向きの洗浄水を噴霧する2つの洗浄スプレーノズル53bbが配置されている。また、デミスタ51のガス流下流近傍には、該デミスタ51の中央領域51aに向けて下向きの洗浄水を噴霧する2つの洗浄スプレーノズル53caと、デミスタ51の外周領域51bに向けて下向きの洗浄水を噴霧する2つの洗浄スプレーノズル53cbが配置されている。 FIG. 3 is a modification of the scrubber 4 of the present embodiment. In this modification, two cleaning spray nozzles 53ba spraying upward cleaning water (cleaning liquid) from the vicinity of the gas flow upstream toward the central region 51a of the demister 51, and upward cleaning water toward the outer peripheral region 51b of the demister 51. Two cleaning spray nozzles 53bb for spraying are disposed. Further, in the vicinity of the gas flow downstream of the demister 51, two cleaning spray nozzles 53ca spraying downward cleaning water toward the central region 51a of the demister 51, and downward cleaning water toward the outer peripheral region 51b of the demister 51. Two cleaning spray nozzles 53cb for spraying are disposed.
 洗浄スプレーノズル53ba,53bbのそれぞれを接続する分岐配管L1には、バルブV1,V2が設けられており、これらのバルブV1,V2の開閉をそれぞれ独立して制御することによりスプレーノズル53ba,53bbの両方を同時に使用したり、いずれか一方を選択して使用したりできる。洗浄スプレーノズル53ca,53cbのそれぞれを接続する分岐配管L1にもバルブV3,V4が設けられ、同様にスプレーノズル55ba,55bbの両方を同時に使用したり、いずれか一方を選択して使用したりできる。これにより、スクラバー4が操業中であってもデミスタ51を洗浄水で水封させることなくデミスタ51を洗浄できる。 The branch pipe L1 connecting each of the cleaning spray nozzles 53ba and 53bb is provided with valves V1 and V2, and the opening and closing of these valves V1 and V2 are controlled independently to thereby control the spray nozzles 53ba and 53bb. Both can be used at the same time, or either one can be selected and used. The branch pipe L1 connecting the cleaning spray nozzles 53ca and 53cb is also provided with valves V3 and V4. Similarly, both the spray nozzles 55ba and 55bb can be used at the same time, or one of them can be selected and used. . Thereby, even if the scrubber 4 is in operation, the demister 51 can be cleaned without sealing the demister 51 with cleaning water.
 なお、スプレーノズルの設置個数は、スクラバー4における被処理ガスの処理量、スクラバー4及びデミスタ50,51のサイズや、所望する洗浄範囲等に応じて適宜に変更できる。 The number of spray nozzles can be changed as appropriate according to the amount of gas to be processed in the scrubber 4, the sizes of the scrubber 4 and the demisters 50 and 51, the desired cleaning range, and the like.
 本実施の形態では、給湯器60で加温された洗浄水を作り、それを洗浄スプレーノズル53aa,53abと、洗浄スプレーノズル53ba,53bbに供給する例を説明しているがこれに限定するものではなく、他の熱媒体と熱交換することにより加温された洗浄水を得てもよい。具体的には、図2に示すように例えば、ディーゼルエンジン1の排ガス顕熱を回収するための熱交換器65を別途設け、洗浄水供給源70から供給される常温の洗浄水を熱交換器65に供給することで約60℃に加温された洗浄水を作り、これを洗浄スプレーノズル53aa,53abと、洗浄スプレーノズル53ba,53bbに供給してもよい。この場合、熱交換器65はディーゼルエンジン1の排ガス顕熱を回収するものに代えて、ディーゼルエンジン1の冷却水(約80~90℃)の顕熱を回収するものであってもよい。 In the present embodiment, an example is described in which cleaning water heated by the hot water heater 60 is made and supplied to the cleaning spray nozzles 53aa and 53ab and the cleaning spray nozzles 53ba and 53bb. Instead, the heated washing water may be obtained by exchanging heat with another heat medium. Specifically, as shown in FIG. 2, for example, a heat exchanger 65 for recovering the sensible heat of exhaust gas from the diesel engine 1 is separately provided, and the normal temperature wash water supplied from the wash water supply source 70 is used as the heat exchanger. The cleaning water heated to about 60 ° C. by supplying to 65 may be produced and supplied to the cleaning spray nozzles 53aa and 53ab and the cleaning spray nozzles 53ba and 53bb. In this case, the heat exchanger 65 may recover the sensible heat of the cooling water (about 80 to 90 ° C.) of the diesel engine 1 instead of the one that recovers the exhaust gas sensible heat of the diesel engine 1.
 また、図示するように、バルブ671を有する配管67を循環配管451から分岐させて該配管67を温水供給配管56に接続し、液貯留部41に貯留されている約60℃の処理水40を洗浄スプレーノズル53aa,53abと、洗浄スプレーノズル53ba,53bbに供給してもよい。 Further, as shown in the drawing, a pipe 67 having a valve 671 is branched from the circulation pipe 451 and the pipe 67 is connected to the hot water supply pipe 56, and the treated water 40 at about 60 ° C. stored in the liquid storage section 41 is supplied. The cleaning spray nozzles 53aa and 53ab and the cleaning spray nozzles 53ba and 53bb may be supplied.
 次に、上述のように構成されたスクラバー4の動作について、図1及び図2を参照して説明する。図1に示すように、先ず、ディーゼルエンジン1を起動すると、該ディーゼルエンジン1から排出される排ガスは排気管10にて静圧され、第1の管路100を経て過給機2に導かれる。 Next, the operation of the scrubber 4 configured as described above will be described with reference to FIGS. As shown in FIG. 1, first, when the diesel engine 1 is started, the exhaust gas discharged from the diesel engine 1 is statically pressured in the exhaust pipe 10 and guided to the supercharger 2 through the first pipe 100. .
 過給機2では、排ガスの持つ熱エネルギが回転エネルギに変換され、タービンロータ20に連結されている圧縮機インペラ21が回転して空気(酸素を含む流体)を大気より吸引する。過給機2の圧縮機インペラ21で圧縮された空気はエアクーラ3により冷却された後、ディーゼルエンジン1の燃焼室へ供給される。一方、過給機2より排出された排ガスは、図示しない排気消音器を介して大気放散される。 In the supercharger 2, the heat energy of the exhaust gas is converted into rotational energy, and the compressor impeller 21 connected to the turbine rotor 20 rotates to suck air (fluid containing oxygen) from the atmosphere. The air compressed by the compressor impeller 21 of the supercharger 2 is cooled by the air cooler 3 and then supplied to the combustion chamber of the diesel engine 1. On the other hand, the exhaust gas discharged from the supercharger 2 is diffused into the atmosphere through an exhaust silencer (not shown).
 一方、ディーゼルエンジン1の排ガスの一部(例えば、全排ガス量の3割に相当する排ガス量)は、被処理ガスとして第3の管路120を介してスクラバー4に導入される。スクラバー4では、被処理ガスに処理水を接触させることにより、被処理ガス中に含まれるPMが捕捉される。このスクラバー4での被処理ガスの処理については図2を用いて後述する。そして、スクラバー4で浄化された処理ガスは吸引ブロワ7により排出されるとともに、ガスクーラ8で所定温度に冷却され、第2の管路110を介してディーゼルエンジン1に再循環される。 On the other hand, a part of the exhaust gas from the diesel engine 1 (for example, the exhaust gas amount corresponding to 30% of the total exhaust gas amount) is introduced into the scrubber 4 through the third pipe line 120 as the gas to be treated. The scrubber 4 captures PM contained in the gas to be treated by bringing the water to be treated into contact with the gas to be treated. The processing of the gas to be processed by the scrubber 4 will be described later with reference to FIG. The processing gas purified by the scrubber 4 is discharged by the suction blower 7, cooled to a predetermined temperature by the gas cooler 8, and recirculated to the diesel engine 1 through the second pipe 110.
 図2に示すように、スクラバー4内に導入された被処理ガスは、スプレーノズル44から噴霧された霧状の処理水40(約60℃)と向流接触する。これにより、被処理ガス中に含まれるPMが処理水40中に吸収されて捕捉される。その後、気体と霧状の液体(処理水40)との混合雰囲気は、ガス流路47に沿って上部ケーシング4b内の気液分離手段としてのデミスタ50,51に送り込まれる。下部ケーシング4a内から送り込まれてきた気体と霧状の液体との混合雰囲気がデミスタ50,51を通過することにより液滴が分離され、該液滴が下部ケーシング4a内の液貯留部41に回収される。一方、デミスタ50,51を通過することにより浄化された処理ガスは、吸引ブロワ(図示せず)により排出される。 As shown in FIG. 2, the gas to be treated introduced into the scrubber 4 is in countercurrent contact with the mist-like treated water 40 (about 60 ° C.) sprayed from the spray nozzle 44. Thereby, the PM contained in the gas to be treated is absorbed in the treated water 40 and captured. Thereafter, the mixed atmosphere of the gas and the mist-like liquid (treated water 40) is sent along the gas flow path 47 to demisters 50 and 51 as gas-liquid separation means in the upper casing 4b. The mixed atmosphere of the gas sent from the lower casing 4a and the mist-like liquid passes through the demisters 50 and 51, so that the liquid droplets are separated, and the liquid droplets are collected in the liquid storage part 41 in the lower casing 4a. Is done. On the other hand, the processing gas purified by passing through the demisters 50 and 51 is discharged by a suction blower (not shown).
 [背景技術]の説明で述べたように、気体と霧状の液体との混合雰囲気がデミスタ50,51を通過する際、該デミスタ50,51で液滴は分離される。しかし、液滴の中にはPMが捕捉されているため、液滴と一緒に滴下しないPMがデミスタ50,51に一部残留する。また、ディーゼル排ガスに含まれるPMは数μm以下の非常に小さな粒径であることから、装置内で処理水を噴霧してもPMがガス流に乗って処理水の噴霧液滴を容易に迂回するため、液滴と慣性衝突して捕捉されないPMがデミスタに付着する。 As described in the description of [Background Art], when the mixed atmosphere of gas and mist-like liquid passes through the demisters 50 and 51, the droplets are separated by the demisters 50 and 51. However, since PM is trapped in the droplets, some PM that does not drop together with the droplets remains in the demisters 50 and 51. Also, since the PM contained in diesel exhaust gas has a very small particle size of several μm or less, even if the treated water is sprayed in the device, the PM rides on the gas flow and easily bypasses the spray droplets of the treated water Therefore, PM that is not captured due to inertial collision with the droplet adheres to the demister.
 PMがデミスタ50,51に付着すると、時間経過とともにデミスタ50,51の空隙部が徐々に狭まり、デミスタ50,51を通過する排ガスの速度が低下する。この速度低下によりPMが更に堆積する悪循環が生じ、デミスタ50,51のガス流上流側とガス流下流側の間における圧力差(圧力損失)が高くなるとともに、吸引ブロワ(図示せず)の動力が増大してスクラバー4の排ガス浄化効率が低下する。 When PM adheres to the demisters 50 and 51, the gaps of the demisters 50 and 51 gradually narrow with time, and the speed of the exhaust gas passing through the demisters 50 and 51 decreases. This speed reduction causes a vicious cycle in which PM accumulates further, the pressure difference (pressure loss) between the gas flow upstream side and the gas flow downstream side of the demisters 50 and 51 increases, and the power of the suction blower (not shown) Increases and the exhaust gas purification efficiency of the scrubber 4 decreases.
 デミスタ50,51の目詰まりによるスクラバー4の操業停止を回避するため、スクラバー4の操業中は各デミスタ50、51のガス流上流側とガス流下流側の間における圧力差(圧力損失)を測定する圧力計520,521の指示値を常時又は一定時間毎に監視することが好ましい。 In order to avoid the operation stop of the scrubber 4 due to clogging of the demisters 50 and 51, the pressure difference (pressure loss) between the gas flow upstream side and the gas flow downstream side of each demister 50 and 51 is measured during the operation of the scrubber 4. It is preferable to monitor the indicated values of the pressure gauges 520 and 521 constantly or at regular intervals.
 操業中にその指示値が所定値以上を示した場合、該当するデミスタ50(51)に目詰まりが発生している蓋然性が高い。本動作説明では、デミスタ50に目詰まりが発生したと仮定して説明する。この場合、先ず、給湯器60を起動する。そして、洗浄スプレーノズル53aa,53abと連通している分岐配管55のバルブ550を開き、デミスタ50のガス流上流側とガス流下流側から該デミスタ50に対し約60℃に加温された洗浄水を噴霧する。 When the indicated value shows a predetermined value or more during operation, there is a high probability that the corresponding demister 50 (51) is clogged. In the description of this operation, it is assumed that the demister 50 is clogged. In this case, first, the water heater 60 is activated. Then, the valve 550 of the branch pipe 55 communicating with the cleaning spray nozzles 53aa and 53ab is opened, and the cleaning water heated to about 60 ° C. with respect to the demister 50 from the gas flow upstream side and the gas flow downstream side of the demister 50. Spray.
 なお、デミスタ50(51)に対する洗浄水の噴霧は連続噴霧でもよいが、本実施の形態のようにデミスタ50(51)の全域に洗浄水を噴霧すると洗浄水の水膜がデミスタ50(51)の空隙部を塞いでしまい、洗浄中にデミスタのガス流上流側とガス流下流側の間における圧力差(圧力損失)が上昇する虞がある。そのような場合、図3の変形例で説明したように各洗浄スプレーノズルを部分領域に分け、領域毎にバルブを設けてデミスタの全面に洗浄水を噴霧しないようにすればよい。 The spray of cleaning water on the demister 50 (51) may be continuous spraying. However, when the cleaning water is sprayed on the entire area of the demister 50 (51) as in the present embodiment, the water film of the cleaning water becomes the demister 50 (51). There is a possibility that the pressure difference (pressure loss) between the gas flow upstream side and the gas flow downstream side of the demister increases during cleaning. In such a case, as described in the modification of FIG. 3, each cleaning spray nozzle may be divided into partial regions, and a valve may be provided for each region so that the cleaning water is not sprayed on the entire surface of the demister.
 デミスタ50内に堆積している油分を含んだPMが加温された洗浄水と接触することで、そのPMの堆積物が温められる。その結果、油分を含んだ堆積物は加温された低粘度の液体状になって滴下し始め、液体状になったPMの堆積物が洗浄水の噴出流によって容易に洗い流される。この場合、デミスタ50内に堆積している油分を含んだPMは、加温された洗浄水により低粘度の液体状になって滴下し始めているため、この堆積物を完全に洗浄・除去するに要する洗浄時間と洗浄水は極僅かで済む。 When the PM containing oil accumulated in the demister 50 comes into contact with the heated cleaning water, the PM deposit is warmed. As a result, the deposit containing oil begins to drip in the form of a heated low-viscosity liquid, and the PM deposit that has become liquid is easily washed away by the jet of cleaning water. In this case, since the PM containing oil accumulated in the demister 50 starts to drip in the form of a low-viscosity liquid by the heated washing water, the deposit is completely washed and removed. The cleaning time and cleaning water required are very small.
 デミスタ50に堆積していた油分を含むPMがほぼ完全に洗浄・除去されると、分岐配管55のバルブ550を閉にして洗浄スプレーノズル53aa、53abへの洗浄水の供給を停止させる。なお、デミスタ51に堆積している油分を含んだPMを洗浄・除去する場合も上述と同様の手順で実施する。 When the PM containing the oil accumulated in the demister 50 is almost completely cleaned and removed, the valve 550 of the branch pipe 55 is closed to stop the supply of the cleaning water to the cleaning spray nozzles 53aa and 53ab. It should be noted that the same procedure as described above is performed when the PM containing oil accumulated in the demister 51 is cleaned and removed.
 デミスタ50(51)内に堆積している油分を含んだPMの洗浄・除去については、ディーゼルエンジン1の排ガス又は冷却水(約80~90℃)の顕熱で加温した洗浄水や、液貯留部41に貯留されている約60℃の処理水40を用いた場合であっても同様に、デミスタ50(51)内に堆積している油分を含んだPMを短時間でほぼ完全に洗浄・除去できる。 For cleaning and removal of PM containing oil accumulated in the demister 50 (51), cleaning water or liquid heated by sensible heat of exhaust gas or cooling water (about 80 to 90 ° C) of the diesel engine 1 is used. Similarly, even when the treated water 40 of about 60 ° C. stored in the storage part 41 is used, the PM containing the oil accumulated in the demister 50 (51) is almost completely cleaned in a short time.・ Can be removed.
 なお、上述した各デミスタ50(51)のガス流上流側とガス流下流側の間における圧力損失の計測、デミスタ50(51)の目詰まりの判定、及び加温された洗浄水の噴霧は、作業者が実施してもよいし、例えば、スクラバー4の制御手段(図示せず)が圧力測定データを取り込んでデミスタ50(51)の目詰まりの判定を行った後、加温された洗浄水の噴霧制御を実行してもよい。 In addition, the measurement of the pressure loss between the gas flow upstream side and the gas flow downstream side of each demister 50 (51) described above, determination of clogging of the demister 50 (51), and spraying of the heated washing water are as follows: For example, the control means (not shown) of the scrubber 4 takes pressure measurement data and determines whether the demister 50 (51) is clogged, and then the heated cleaning water. The spray control may be executed.
 洗浄スプレーノズル53aa,53ab(53ba,53bb)による洗浄水の噴霧は、本実施の形態のように、デミスタ50(51)に対して上下方向から互いに同時に噴霧してもよいが、例えばスプレーノズル53aa,53ab(53ba,53bb)の手前にバルブを1個ずつ追加し、上方向又は下方向のいずれか一方を選択して洗浄水を噴霧してもよい。また、これらの噴霧時間は互いに重ならせてもよいし、重ならせなくてもよい。 The spray of the cleaning water by the cleaning spray nozzles 53aa and 53ab (53ba and 53bb) may be sprayed simultaneously from the vertical direction to the demister 50 (51) as in the present embodiment. For example, the spray nozzle 53aa , 53ab (53ba, 53bb) may be added one by one, and either one of the upper direction and the lower direction may be selected and sprayed with cleaning water. Moreover, these spraying times may overlap each other or may not overlap each other.
 このように、本実施の形態のスクラバー4によれば、加温された洗浄水によりデミスタ50(51)内部に堆積している油分を含んだPMを低粘度の液体状にした後、加温された洗浄水を噴霧するので、洗浄・除去に要する洗浄時間と洗浄水量が極僅かで済む。洗浄・除去された後のデミスタ50(51)は新品にほぼ近い状態で再使用できる。 As described above, according to the scrubber 4 of the present embodiment, the PM containing the oil accumulated in the demister 50 (51) is made into a low-viscosity liquid with the heated washing water, and then heated. Since the washed water is sprayed, the washing time and amount of washing water required for washing / removal are very small. After being cleaned and removed, the demister 50 (51) can be reused in a state almost similar to a new one.
 上述のように洗浄・除去された後のデミスタ50(51)は新品にほぼ近い状態で再使用できるため、デミスタ50(51)のガス流上流側とガス流下流側の間における圧力差(圧力損失)の増大、圧力損失が高くなること起因する吸引ブロワ7の動力が増大、及び吸引ブロワ7が排ガス吸引不足に陥るという問題を回避できる。また、本実施の形態のようにディーゼルエンジン1の排ガスの一部(例えば、全排ガス量の3割に相当する排ガス量)を該ディーゼルエンジン1に再循環させる場合であっても、排ガス再循環量が不足する事態に陥ることはない。 Since the demister 50 (51) that has been cleaned and removed as described above can be reused in a state almost similar to a new one, a pressure difference (pressure) between the gas flow upstream side and the gas flow downstream side of the demister 50 (51). Loss), the power of the suction blower 7 due to an increase in pressure loss, and the problem that the suction blower 7 falls short of exhaust gas suction can be avoided. Further, even when a part of the exhaust gas of the diesel engine 1 (for example, the exhaust gas amount corresponding to 30% of the total exhaust gas amount) is recirculated to the diesel engine 1 as in the present embodiment, the exhaust gas recirculation is performed. There is no shortage of volume.
 従来、空隙率の低い(捕集効率の高い)デミスタは早期に目詰まりして使用することが困難であったが、本実施の形態ではデミスタ50(51)内に堆積している油分を含んだPMの洗浄・除去を容易にできるため、空隙率の低い(捕集効率の高い)ものを使用できる。これにより、スクラバー4の脱塵性能が向上する。スクラバー4の脱塵性能が向上するため、該スクラバー4の下流側に配置されている吸引ブロワ7、ガスクーラ8、及びこれらと接続しているディーゼルエンジン1に混入するダストを極めて少なくできる。その結果、それらの設備のメンテナンスが容易になるとともに、寿命を延ばすことができる。 Conventionally, a demister with a low porosity (high collection efficiency) was clogged early and difficult to use, but in the present embodiment, it contains oil accumulated in the demister 50 (51). Since PM can be easily cleaned and removed, one having a low porosity (high collection efficiency) can be used. Thereby, the dust removal performance of the scrubber 4 is improved. Since the dust removal performance of the scrubber 4 is improved, the dust mixed in the suction blower 7, the gas cooler 8, and the diesel engine 1 connected thereto can be extremely reduced. As a result, the maintenance of those facilities becomes easy and the lifetime can be extended.
 今回、開示した実施の形態は例示であってこれに制限されるものではない。本発明は、上記で説明した範囲ではなく、特許請求の範囲によって示され、特許請求の範囲と均等の意味及び範囲での全ての変更を含む。 The embodiment disclosed this time is an example, and the present invention is not limited to this. The present invention is defined by the scope of the claims rather than the scope described above, and includes all modifications within the scope and meaning equivalent to the scope of the claims.
 1 ディーゼルエンジン
 2 過給機
 3 エアクーラ
 4 スクラバー
 4a 下部ケーシング
 4b 上部ケーシング
 7 吸引ブロワ
 8 ガスクーラ
 40 処理水
 41 液貯留部
 44 スプレーノズル
 47 ガス流路
 50,51 デミスタ
 53aa,53ab,53ba,53bb 洗浄スプレーノズル
DESCRIPTION OF SYMBOLS 1 Diesel engine 2 Supercharger 3 Air cooler 4 Scrubber 4a Lower casing 4b Upper casing 7 Suction blower 8 Gas cooler 40 Treated water 41 Liquid storage part 44 Spray nozzle 47 Gas flow path 50, 51 Demister 53aa, 53ab, 53ba, 53bb Cleaning spray nozzle

Claims (3)

  1.  処理液を貯留する液溜手段と、
     該液貯留手段に貯留された処理液と燃焼装置から排出された排ガスとを気液接触させ、前記排ガス中に含有するダストを前記処理液中に吸収して捕捉させる気液接触手段と、
     前記気液接触手段の下流側に配置され、前記ダストを捕捉した処理液を含む処理後の排ガスから液体を分離する気液分離手段とを有する湿式排ガス浄化装置であって、
     前記気液分離手段に洗浄液を噴射し、該気液分離手段に付着した前記ダストを除去する洗浄手段と、
     前記洗浄液を加温する洗浄液加熱手段とを有することを特徴とする湿式排ガス浄化装置。
    A liquid storage means for storing the processing liquid;
    Gas-liquid contact means for bringing the treatment liquid stored in the liquid storage means into contact with the exhaust gas discharged from the combustion apparatus in gas-liquid contact, and absorbing and capturing the dust contained in the exhaust gas in the treatment liquid;
    A wet exhaust gas purifier having gas-liquid separation means that is disposed downstream of the gas-liquid contact means and separates liquid from the treated exhaust gas containing the treatment liquid capturing the dust,
    Cleaning means for injecting a cleaning liquid onto the gas-liquid separating means and removing the dust adhering to the gas-liquid separating means;
    A wet exhaust gas purifier having a cleaning liquid heating means for heating the cleaning liquid.
  2.  前記洗浄液加熱手段は、熱媒体と熱交換することにより加温された洗浄液を得る熱交換器であって、前記熱媒体が前記燃焼装置から排出される燃焼排ガス又は前記燃焼装置を冷却した後の冷却水である請求項1に記載の湿式排ガス浄化装置。 The cleaning liquid heating means is a heat exchanger for obtaining a heated cleaning liquid by exchanging heat with a heat medium, wherein the heat medium cools the combustion exhaust gas discharged from the combustion apparatus or the combustion apparatus The wet exhaust gas purification apparatus according to claim 1, wherein the wet exhaust gas purification apparatus is cooling water.
  3.  前記燃焼装置は、ディーゼル機関であり、
     前記排ガスは、前記ディーゼル機関から排出される排ガスであって該排ガスに含まれるダストはパティキュレートマターである請求項1又は請求項2に記載の湿式排ガス浄化装置。
    The combustion device is a diesel engine;
    The wet exhaust gas purifying apparatus according to claim 1 or 2, wherein the exhaust gas is exhaust gas discharged from the diesel engine, and the dust contained in the exhaust gas is a particulate matter.
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Cited By (10)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN104307279A (en) * 2014-11-12 2015-01-28 广西天源生物之本环保科技有限公司 Wet dust removal and waste heat recovery device
CN105771490A (en) * 2016-02-03 2016-07-20 浙江湘牛环保科技发展有限公司 High-humidity dust processing system
EP3085911A1 (en) * 2015-04-22 2016-10-26 Wärtsilä Moss AS Inline scrubber with dual water system
CN106310843A (en) * 2016-08-18 2017-01-11 无锡飞达纺织印染机械有限公司 Industrial waste gas filtering device
CN108970299A (en) * 2018-08-14 2018-12-11 广州市迪瑞喷雾机械有限公司 It eliminates the unusual smell the waste gas purification processing spray system of refrigerating function with dedusting
CN109200697A (en) * 2018-11-02 2019-01-15 合肥林夏智能科技有限公司 A kind of automation dust-extraction unit
WO2019071705A1 (en) * 2017-10-13 2019-04-18 山东佩森环保科技股份有限公司 Washing tower for watercraft exhaust gas
CN110354608A (en) * 2019-07-04 2019-10-22 杨晓鑫 A kind of pressed brick powder environmental-friendly dust suppression equipment
CN112246018A (en) * 2020-07-23 2021-01-22 彭志南 Battery car tail gas processor
JP2021025451A (en) * 2019-08-02 2021-02-22 株式会社三井E&Sマシナリー Exhaust gas treatment device and control method therefor

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* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
KR101414108B1 (en) * 2014-04-09 2014-07-02 에너젠(주) Diesel generator with exhaust gas purifying function
KR101683966B1 (en) * 2014-06-13 2016-12-07 윤권중 emergency pump system
US10174662B2 (en) * 2014-12-08 2019-01-08 Wärtsilä Finland Oy Arrangement for treating exhaust gases of an internal combustion piston engine in a marine vessel and method of operating an arrangement for treating exhaust gases
CN106582121A (en) * 2017-01-11 2017-04-26 南京宇行环保科技有限公司 Tube bundle type dedusting and demisting device with liquid collection function
JP6995670B2 (en) * 2018-03-14 2022-01-14 三菱化工機株式会社 Scrubber, and scrubber system
JP7346959B2 (en) * 2019-07-16 2023-09-20 富士電機株式会社 Exhaust gas treatment equipment and exhaust gas treatment system
CN111804103B (en) * 2020-07-01 2021-09-07 河南城建学院 Road construction dust device

Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPH0299112A (en) * 1988-10-04 1990-04-11 Babcock Hitachi Kk Method for regenerating filter for use in exhaust gas of diesel engine
JPH0483401U (en) * 1990-11-30 1992-07-21
JP2002001042A (en) * 2000-06-19 2002-01-08 Mitsubishi Kakoki Kaisha Ltd Wet dust collecting method for exhaust gas
JP2005058812A (en) * 2003-08-11 2005-03-10 Fuji Heavy Ind Ltd Method and unit for removing oil mist in garbage sorting apparatus

Patent Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPH0299112A (en) * 1988-10-04 1990-04-11 Babcock Hitachi Kk Method for regenerating filter for use in exhaust gas of diesel engine
JPH0483401U (en) * 1990-11-30 1992-07-21
JP2002001042A (en) * 2000-06-19 2002-01-08 Mitsubishi Kakoki Kaisha Ltd Wet dust collecting method for exhaust gas
JP2005058812A (en) * 2003-08-11 2005-03-10 Fuji Heavy Ind Ltd Method and unit for removing oil mist in garbage sorting apparatus

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* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
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US10378401B2 (en) 2015-04-22 2019-08-13 Wärtsilä Moss As Inline scrubber with dual water system
EP3085911A1 (en) * 2015-04-22 2016-10-26 Wärtsilä Moss AS Inline scrubber with dual water system
WO2016171568A1 (en) * 2015-04-22 2016-10-27 Wärtsilä Moss As Inline scrubber with dual water system
CN107690511A (en) * 2015-04-22 2018-02-13 瓦锡兰莫斯公司 Inline washer with dual water system
CN105771490A (en) * 2016-02-03 2016-07-20 浙江湘牛环保科技发展有限公司 High-humidity dust processing system
CN106310843A (en) * 2016-08-18 2017-01-11 无锡飞达纺织印染机械有限公司 Industrial waste gas filtering device
WO2019071705A1 (en) * 2017-10-13 2019-04-18 山东佩森环保科技股份有限公司 Washing tower for watercraft exhaust gas
CN108970299A (en) * 2018-08-14 2018-12-11 广州市迪瑞喷雾机械有限公司 It eliminates the unusual smell the waste gas purification processing spray system of refrigerating function with dedusting
CN109200697A (en) * 2018-11-02 2019-01-15 合肥林夏智能科技有限公司 A kind of automation dust-extraction unit
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JP2021025451A (en) * 2019-08-02 2021-02-22 株式会社三井E&Sマシナリー Exhaust gas treatment device and control method therefor
JP7039790B2 (en) 2019-08-02 2022-03-23 株式会社三井E&Sマシナリー Exhaust gas treatment equipment and its control method
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CN112246018B (en) * 2020-07-23 2022-11-18 池州市金能供热有限公司 Battery car tail gas processor

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