WO2012151750A1 - 一种新型复合材料及其生产方法 - Google Patents

一种新型复合材料及其生产方法 Download PDF

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Publication number
WO2012151750A1
WO2012151750A1 PCT/CN2011/073962 CN2011073962W WO2012151750A1 WO 2012151750 A1 WO2012151750 A1 WO 2012151750A1 CN 2011073962 W CN2011073962 W CN 2011073962W WO 2012151750 A1 WO2012151750 A1 WO 2012151750A1
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WIPO (PCT)
Prior art keywords
layer
composite material
polypropylene material
polymer polypropylene
novel composite
Prior art date
Application number
PCT/CN2011/073962
Other languages
English (en)
French (fr)
Inventor
张文益
Original Assignee
Zhang Wenyi
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Zhang Wenyi filed Critical Zhang Wenyi
Priority to US13/207,409 priority Critical patent/US20120288633A1/en
Publication of WO2012151750A1 publication Critical patent/WO2012151750A1/zh

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Classifications

    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B33/00—Layered products characterised by particular properties or particular surface features, e.g. particular surface coatings; Layered products designed for particular purposes not covered by another single class
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B27/00—Layered products comprising a layer of synthetic resin
    • B32B27/06—Layered products comprising a layer of synthetic resin as the main or only constituent of a layer, which is next to another layer of the same or of a different material
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B38/00—Ancillary operations in connection with laminating processes
    • B32B2038/0052—Other operations not otherwise provided for
    • B32B2038/0076—Curing, vulcanising, cross-linking
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B2307/00—Properties of the layers or laminate
    • B32B2307/10—Properties of the layers or laminate having particular acoustical properties
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B2307/00—Properties of the layers or laminate
    • B32B2307/30—Properties of the layers or laminate having particular thermal properties
    • B32B2307/304—Insulating
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B2307/00—Properties of the layers or laminate
    • B32B2307/40—Properties of the layers or laminate having particular optical properties
    • B32B2307/402—Coloured
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B2307/00—Properties of the layers or laminate
    • B32B2307/50—Properties of the layers or laminate having particular mechanical properties
    • B32B2307/554—Wear resistance
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B38/00—Ancillary operations in connection with laminating processes
    • B32B38/14—Printing or colouring
    • B32B38/145—Printing

Definitions

  • the invention relates to the field of composite materials technology. Background technique:
  • PVC materials are commonly used in wood-like floor tiles, fan blades, imitation wood furniture, imitation wood doors and windows, decorative materials, etc. PVC materials are poorly recycled and are not easily degraded under natural conditions, which is not conducive to environmental protection.
  • the object of the present invention is to provide a novel composite material and a method for producing the same according to the deficiencies of the prior art, which have the characteristics of wide application, high temperature resistance, and good environmental performance.
  • the method for producing a novel composite material of the present invention comprises the following steps:
  • the color layer and the printed layer are combined with a heat-resistant copolymer of a wear-resistant layer made of a high-polymer polypropylene material.
  • the step of combining the bottom of the printing layer with the stable layer composite hot-melt copolymer made of a high-polymer polypropylene material is carried out after the step (2).
  • the step (4) of combining the bottom of the stabilizing layer with the composite heat-fusible copolymerization of the silencing gas-free layer made of the high-molecular polypropylene material is carried out after the step (3).
  • the step (5) of combining the bottom of the muffling getter layer with the heat insulating layer made of the high polymer polypropylene material is carried out after the step (4).
  • the composite hot melt copolymerization is carried out under the conditions of a pressure of 100 to 300 ° C and a pressure of 100 to 3000 kg.
  • the novel composite material of the present invention comprises, in order from top to bottom, a wear resistant layer composed of a high polymer polypropylene material, a color layer composed of an ink, and a printed layer composed of a high polymer polypropylene material.
  • the bottom layer composite hot melt copolymerization of the printing layer incorporates a stable layer made of a high polymer polypropylene material.
  • the stabilizing layer bottom composite hot melt copolymer incorporates a sound-absorbing getter layer made of a high polymer polypropylene material.
  • the sound-absorbing getter layer bottom composite hot melt copolymer incorporates a heat insulating layer made of a high polymer polypropylene material.
  • the invention has the advantages that: the material used has the characteristics of recyclability, easy degradation under natural conditions, and no glue chemical composition, strong bonding between the layers, and environmental protection is very good, and can be used for various products. Production; In addition, it also has very good high temperature resistance, no deformation at high temperatures, and outstanding fire performance. BRIEF DESCRIPTION OF THE DRAWINGS:
  • FIG. 1 is a schematic structural view of an embodiment of the present invention
  • Figure 2 is a cross-sectional view taken along line A-A of Figure 1;
  • Figure 3 is a second cross-sectional view taken along the line A-A of Figure 1.
  • the method for producing a novel composite material of the present invention comprises the following steps:
  • the novel composite material of the invention can be used for producing wood-like floor tiles, fan blades, wood-like furniture, wood-like doors and windows, packaging boxes, decorative materials and the like.
  • FIG. 1 and 2 are schematic structural views of a first embodiment of a fan blade 100 made of the novel composite material of the present invention, which includes, in order from top to bottom, a wear layer 10 composed of a high polymer polypropylene material.
  • a color layer 20 composed of a water-based ink, and a printing layer 30 composed of a biaxially oriented polypropylene material.
  • FIG. 3 is a schematic structural view of a second embodiment of the composite material of the present invention, which includes, in order from top to bottom, a wear layer 10 composed of a high polymer polypropylene material, a color layer 20 composed of an aqueous ink, and a bidirectional A printed layer 30 composed of a stretched polypropylene material, a stabilizing layer 40 composed of a high polymer polypropylene material, a sound-absorbing and gas-removing layer 50 composed of a polymer polypropylene material, and a foamed polypropylene polymer material
  • the heat insulating layer 60 is formed later.
  • the stabilizing layer 40, the muffling gettering layer 50, and the insulating layer 60 can be selected as needed.

Landscapes

  • Laminated Bodies (AREA)

Description

一种新型复合材料及其生产方法 技术领域：
本发明涉及复合材料技术领域。 背景技术：
目前， 仿木地砖、 风扇叶片、 仿木家具、 仿木门窗、 装饰材料等 普遍采用 PVC材料， 而 PVC材料回收性较差， 在自然条件下不容易 降解， 不利于环保。
发明内容：
本发明的目的就在于针对现有技术存在的不足之处而提供一种 新型复合材料及其生产方法， 该复合材料具有用途广泛、 耐高温、 以 及环保性能良好的特点。
为实现上述目的，本发明的新型复合材料的生产方法包括如下步 骤：
( 1 ) 用添加了架桥剂的油墨在由高聚物聚丙烯材料制成的印刷 层上进行印刷， 形成颜色层；
(2) 将颜色层和印刷层与由高聚物聚丙烯材料制成的耐磨层复 合热熔共聚结合在一起。
作为上述技术方案的优选， 在步骤 （2) 后进行将印刷层底部与 由高聚物聚丙烯材料制成的稳定层复合热熔共聚结合在一起的步骤 作为上述技术方案的优选， 在步骤 （3 ) 后进行将稳定层底部与 由高聚物聚丙烯材料制成的消音消气层复合热熔共聚结合在一起的 步骤 （4)。
作为上述技术方案的优选， 在步骤 （4) 后进行将消音消气层底 部与由高聚物聚丙烯材料制成的隔热层复合热熔共聚结合在一起的 步骤 （5 )。
作为上述技术方案的优选， 所述的复合热熔共聚结合在 100~300°C、 100~3000公斤压力的条件下进行。
本发明的新型复合材料从上到下依次包括有由高聚物聚丙烯材 料构成的耐磨层、 由油墨构成的颜色层、 由高聚物聚丙烯材料构成的 印刷层。
作为上述技术方案的优选，所述的印刷层底部复合热熔共聚结合 有由高聚物聚丙烯材料制成的稳定层。
作为上述技术方案的优选，所述的稳定层底部复合热熔共聚结合 有由高聚物聚丙烯材料制成的消音消气层。
作为上述技术方案的优选，所述的消音消气层底部复合热熔共聚 结合有由高聚物聚丙烯材料制成的隔热层。
本发明的有益效果在于： 其使用的材料具有可回收性、在自然条 件下容易降解的特点， 且各层之间无胶水化学成分、 粘接牢固， 环保 性非常好， 可用于多种产品的生产； 另外， 其还具有非常良好的耐高 温特性， 高温下不变形， 防火性能突出。 附图说明：
下面结合附图对本发明做进一步的说明：
图 1为本发明实施例的结构示意图；
图 2为图 1的 A-A向剖视图之一；
图 3为图 1的 A-A向剖视图之二。
具体实施方式：
以下所述仅为本发明的较佳实施例，并不因此而限定本发明的保 护范围。
本发明的新型复合材料的生产方法包括如下步骤：
( 1 ) 用双向拉伸聚丙烯材料 （BOPP ) 加水性油墨 （添加有 50%~70%的架桥剂以保护油墨的色素分子） 进行印刷， 形成表面的 颜色层 （可为各种图案， 如木紋型、 大理石型等） 和印刷层；
(2) 将颜色层和印刷层与由高聚物聚丙烯材料 （PP) 制成的耐 磨层在 100°C、 1000公斤的压力下复合热熔共聚结合在一起；
在上述两个步骤之后还可进行如下步骤：
(3 ) 将印刷层底部与由高聚物聚丙烯材料 （PP) 制成的稳定层 (加强层） 在 170°C、 1000公斤的压力下复合热熔共聚结合在一起， 以增加产品的强度；
(4) 将稳定层底部与由高聚物聚丙烯材料 （PP) 发泡后制成的 消音消气层在 170°C、 1000公斤的压力下复合热熔共聚结合在一起， 以增加产品的厚度；
(5 ) 将消音消气层底部与由高聚物聚丙烯材料 （PP) 制成的隔 热层在 170°C、 1000公斤的压力下复合热熔共聚结合在一起， 隔热层 底面呈凹凸不平状， 以使产品具有良好的隔热性能。
本发明的新型复合材料可用于生产仿木地砖、 风扇叶片、 仿木家 具、 仿木门窗、 包装盒、 装饰材料等。
图 1和图 2所示为由本发明的新型复合材料制成的风扇叶片 100 实施例一的结构示意图，其从上到下依次包括有由高聚物聚丙烯材料 构成的耐磨层 10、 由水性油墨构成的颜色层 20、 由双向拉伸聚丙烯 材料构成的印刷层 30。
图 3所示为本发明的复合材料实施例二的结构示意图，其从上到 下依次包括有由高聚物聚丙烯材料构成的耐磨层 10、 由水性油墨构 成的颜色层 20、 由双向拉伸聚丙烯材料构成的印刷层 30、 由高聚物 聚丙烯材料构成的稳定层 40、 由高聚物聚丙烯材料发泡后构成的消 音消气层 50、 由高聚物聚丙烯材料发泡后构成的隔热层 60。
需要说明的是： 稳定层 40、 消音消气层 50、 以及隔热层 60可根 据需要进行取舍。

Claims

权 利 要 求 书
1. 一种新型复合材料的生产方法， 其特征在于包括如下步骤：
( 1 ) 用添加了架桥剂的油墨在由高聚物聚丙烯材料制成的印刷 层上进行印刷， 形成颜色层；
(2) 将颜色层和印刷层与由高聚物聚丙烯材料制成的耐磨层复 合热熔共聚结合在一起。
2. 根据权利要求 1所述的新型复合材料的生产方法， 其特征在 于： 在步骤 （2) 后进行将印刷层底部与由高聚物聚丙烯材料制成的 稳定层复合热熔共聚结合在一起的步骤 （3 )。
3. 根据权利要求 2所述的新型复合材料的生产方法， 其特征在 于： 在步骤 （3 ) 后进行将稳定层底部与由高聚物聚丙烯材料制成的 消音消气层复合热熔共聚结合在一起的步骤 （4)。
4. 根据权利要求 3所述的新型复合材料的生产方法， 其特征在 于： 在步骤 （4) 后进行将消音消气层底部与由高聚物聚丙烯材料制 成的隔热层复合热熔共聚结合在一起的步骤 （5 )。
5. 根据权利要求 1至 4中任一项所述的新型复合材料的生产方 法， 其特征在于： 所述的复合热熔共聚结合在 100~300°C、 100-3000 公斤压力的条件下进行。
6. 由权利要求 1所述方法得到的新型复合材料， 其特征在于从 上到下依次包括有由高聚物聚丙烯材料构成的耐磨层、由油墨构成的 颜色层、 由高聚物聚丙烯材料构成的印刷层。
7. 根据权利要求 6所述的新型复合材料， 其特征在于： 所述的 印刷层底部复合热熔共聚结合有由高聚物聚丙烯材料制成的稳定层。
8. 根据权利要求 7所述的新型复合材料， 其特征在于： 所述的 稳定层底部复合热熔共聚结合有由高聚物聚丙烯材料制成的消音消 气层。
9. 根据权利要求 8所述的新型复合材料， 其特征在于： 所述的 消音消气层底部复合热熔共聚结合有由高聚物聚丙烯材料制成的隔 热层。
PCT/CN2011/073962 2011-05-06 2011-05-12 一种新型复合材料及其生产方法 WO2012151750A1 (zh)

Priority Applications (1)

Application Number Priority Date Filing Date Title
US13/207,409 US20120288633A1 (en) 2011-05-06 2011-08-10 Novel Composite Material and its Production Method

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
CN201110116548.9 2011-05-06
CN2011101165489A CN102275367A (zh) 2011-05-06 2011-05-06 一种新型复合材料及其生产方法

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CN (1) CN102275367A (zh)
WO (1) WO2012151750A1 (zh)

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Publication number Priority date Publication date Assignee Title
CN107407290B (zh) * 2015-04-08 2019-07-26 雷顿股份公司 风扇叶片及相关方法

Citations (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN1330290A (zh) * 2000-06-16 2002-01-09 林廷峻 灯箱型的彩色喷墨胶片
CN1233759C (zh) * 2003-11-07 2005-12-28 中山大学 水性塑料复合油墨
JP2006341595A (ja) * 2005-05-10 2006-12-21 Dainippon Ink & Chem Inc 熱成形用シートの成形方法および成形装置
CN201670410U (zh) * 2010-04-14 2010-12-15 杭州精瑞彩印包装有限公司 彩印复合聚丙烯吸塑托
CN101932455A (zh) * 2007-12-07 2010-12-29 联邦印刷厂有限公司 带有个性化信息的安全文件和/或重要文件的生产方法

Patent Citations (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN1330290A (zh) * 2000-06-16 2002-01-09 林廷峻 灯箱型的彩色喷墨胶片
CN1233759C (zh) * 2003-11-07 2005-12-28 中山大学 水性塑料复合油墨
JP2006341595A (ja) * 2005-05-10 2006-12-21 Dainippon Ink & Chem Inc 熱成形用シートの成形方法および成形装置
CN101932455A (zh) * 2007-12-07 2010-12-29 联邦印刷厂有限公司 带有个性化信息的安全文件和/或重要文件的生产方法
CN201670410U (zh) * 2010-04-14 2010-12-15 杭州精瑞彩印包装有限公司 彩印复合聚丙烯吸塑托

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