WO2012137827A1 - 不織布ロール - Google Patents
不織布ロール Download PDFInfo
- Publication number
- WO2012137827A1 WO2012137827A1 PCT/JP2012/059214 JP2012059214W WO2012137827A1 WO 2012137827 A1 WO2012137827 A1 WO 2012137827A1 JP 2012059214 W JP2012059214 W JP 2012059214W WO 2012137827 A1 WO2012137827 A1 WO 2012137827A1
- Authority
- WO
- WIPO (PCT)
- Prior art keywords
- nonwoven fabric
- roll
- fabric roll
- winding
- paper tube
- Prior art date
Links
- 239000004745 nonwoven fabric Substances 0.000 title claims abstract description 277
- 238000004804 winding Methods 0.000 claims description 115
- 239000000835 fiber Substances 0.000 claims description 55
- -1 polypropylene Polymers 0.000 claims description 49
- 239000004743 Polypropylene Substances 0.000 claims description 19
- 229920001155 polypropylene Polymers 0.000 claims description 19
- 229920000098 polyolefin Polymers 0.000 claims description 9
- 229920001169 thermoplastic Polymers 0.000 claims description 8
- 239000004416 thermosoftening plastic Substances 0.000 claims description 8
- 230000002209 hydrophobic effect Effects 0.000 claims description 6
- 239000000463 material Substances 0.000 claims description 5
- 239000000123 paper Substances 0.000 description 62
- 239000010410 layer Substances 0.000 description 32
- 238000000034 method Methods 0.000 description 28
- 238000011156 evaluation Methods 0.000 description 21
- 229920005989 resin Polymers 0.000 description 16
- 239000011347 resin Substances 0.000 description 16
- 238000012856 packing Methods 0.000 description 13
- 239000003795 chemical substances by application Substances 0.000 description 11
- 239000004744 fabric Substances 0.000 description 10
- 238000012545 processing Methods 0.000 description 10
- 238000009987 spinning Methods 0.000 description 9
- 238000002844 melting Methods 0.000 description 8
- 230000037303 wrinkles Effects 0.000 description 8
- 230000008018 melting Effects 0.000 description 7
- 208000028659 discharge Diseases 0.000 description 6
- 229920005862 polyol Polymers 0.000 description 6
- 150000003077 polyols Chemical class 0.000 description 6
- 239000004698 Polyethylene Substances 0.000 description 5
- 239000000306 component Substances 0.000 description 5
- 230000001771 impaired effect Effects 0.000 description 5
- 229920000573 polyethylene Polymers 0.000 description 5
- 229920000139 polyethylene terephthalate Polymers 0.000 description 5
- 239000005020 polyethylene terephthalate Substances 0.000 description 5
- 238000005507 spraying Methods 0.000 description 5
- 239000004902 Softening Agent Substances 0.000 description 4
- 229920001577 copolymer Polymers 0.000 description 4
- 229920001971 elastomer Polymers 0.000 description 4
- 238000005259 measurement Methods 0.000 description 4
- 235000021355 Stearic acid Nutrition 0.000 description 3
- 230000000052 comparative effect Effects 0.000 description 3
- 238000003851 corona treatment Methods 0.000 description 3
- POULHZVOKOAJMA-UHFFFAOYSA-N dodecanoic acid Chemical compound CCCCCCCCCCCC(O)=O POULHZVOKOAJMA-UHFFFAOYSA-N 0.000 description 3
- 238000001035 drying Methods 0.000 description 3
- 238000001125 extrusion Methods 0.000 description 3
- 238000011068 loading method Methods 0.000 description 3
- 238000004519 manufacturing process Methods 0.000 description 3
- 239000000155 melt Substances 0.000 description 3
- 150000002762 monocarboxylic acid derivatives Chemical class 0.000 description 3
- OQCDKBAXFALNLD-UHFFFAOYSA-N octadecanoic acid Natural products CCCCCCCC(C)CCCCCCCCC(O)=O OQCDKBAXFALNLD-UHFFFAOYSA-N 0.000 description 3
- 229920013716 polyethylene resin Polymers 0.000 description 3
- 238000005096 rolling process Methods 0.000 description 3
- 230000001629 suppression Effects 0.000 description 3
- 238000012546 transfer Methods 0.000 description 3
- VXNZUUAINFGPBY-UHFFFAOYSA-N 1-Butene Chemical compound CCC=C VXNZUUAINFGPBY-UHFFFAOYSA-N 0.000 description 2
- KWKAKUADMBZCLK-UHFFFAOYSA-N 1-octene Chemical compound CCCCCCC=C KWKAKUADMBZCLK-UHFFFAOYSA-N 0.000 description 2
- XDOFQFKRPWOURC-UHFFFAOYSA-N 16-methylheptadecanoic acid Chemical compound CC(C)CCCCCCCCCCCCCCC(O)=O XDOFQFKRPWOURC-UHFFFAOYSA-N 0.000 description 2
- ISPYQTSUDJAMAB-UHFFFAOYSA-N 2-chlorophenol Chemical compound OC1=CC=CC=C1Cl ISPYQTSUDJAMAB-UHFFFAOYSA-N 0.000 description 2
- WSSSPWUEQFSQQG-UHFFFAOYSA-N 4-methyl-1-pentene Chemical compound CC(C)CC=C WSSSPWUEQFSQQG-UHFFFAOYSA-N 0.000 description 2
- PEDCQBHIVMGVHV-UHFFFAOYSA-N Glycerine Chemical compound OCC(O)CO PEDCQBHIVMGVHV-UHFFFAOYSA-N 0.000 description 2
- 206010021639 Incontinence Diseases 0.000 description 2
- 229920002292 Nylon 6 Polymers 0.000 description 2
- 239000004793 Polystyrene Substances 0.000 description 2
- 239000002253 acid Substances 0.000 description 2
- 239000013543 active substance Substances 0.000 description 2
- 239000000853 adhesive Substances 0.000 description 2
- 230000001070 adhesive effect Effects 0.000 description 2
- 239000004840 adhesive resin Substances 0.000 description 2
- 229920006223 adhesive resin Polymers 0.000 description 2
- 238000005452 bending Methods 0.000 description 2
- WPYMKLBDIGXBTP-UHFFFAOYSA-N benzoic acid Chemical compound OC(=O)C1=CC=CC=C1 WPYMKLBDIGXBTP-UHFFFAOYSA-N 0.000 description 2
- 230000015572 biosynthetic process Effects 0.000 description 2
- 239000002131 composite material Substances 0.000 description 2
- 230000006835 compression Effects 0.000 description 2
- 238000007906 compression Methods 0.000 description 2
- NZNMSOFKMUBTKW-UHFFFAOYSA-N cyclohexanecarboxylic acid Chemical compound OC(=O)C1CCCCC1 NZNMSOFKMUBTKW-UHFFFAOYSA-N 0.000 description 2
- GPLRAVKSCUXZTP-UHFFFAOYSA-N diglycerol Chemical compound OCC(O)COCC(O)CO GPLRAVKSCUXZTP-UHFFFAOYSA-N 0.000 description 2
- UKMSUNONTOPOIO-UHFFFAOYSA-N docosanoic acid Chemical compound CCCCCCCCCCCCCCCCCCCCCC(O)=O UKMSUNONTOPOIO-UHFFFAOYSA-N 0.000 description 2
- 230000000694 effects Effects 0.000 description 2
- XMHIUKTWLZUKEX-UHFFFAOYSA-N hexacosanoic acid Chemical compound CCCCCCCCCCCCCCCCCCCCCCCCCC(O)=O XMHIUKTWLZUKEX-UHFFFAOYSA-N 0.000 description 2
- 239000000203 mixture Substances 0.000 description 2
- 235000014593 oils and fats Nutrition 0.000 description 2
- 239000005022 packaging material Substances 0.000 description 2
- 238000004806 packaging method and process Methods 0.000 description 2
- YWAKXRMUMFPDSH-UHFFFAOYSA-N pentene Chemical compound CCCC=C YWAKXRMUMFPDSH-UHFFFAOYSA-N 0.000 description 2
- 229920000728 polyester Polymers 0.000 description 2
- 229920000642 polymer Polymers 0.000 description 2
- 229920002223 polystyrene Polymers 0.000 description 2
- 230000000452 restraining effect Effects 0.000 description 2
- 229920005992 thermoplastic resin Polymers 0.000 description 2
- 239000004711 α-olefin Substances 0.000 description 2
- JNYAEWCLZODPBN-JGWLITMVSA-N (2r,3r,4s)-2-[(1r)-1,2-dihydroxyethyl]oxolane-3,4-diol Chemical compound OC[C@@H](O)[C@H]1OC[C@H](O)[C@H]1O JNYAEWCLZODPBN-JGWLITMVSA-N 0.000 description 1
- ATNNLHXCRAAGJS-QZQOTICOSA-N (e)-docos-2-enoic acid Chemical compound CCCCCCCCCCCCCCCCCCC\C=C\C(O)=O ATNNLHXCRAAGJS-QZQOTICOSA-N 0.000 description 1
- RNFJDJUURJAICM-UHFFFAOYSA-N 2,2,4,4,6,6-hexaphenoxy-1,3,5-triaza-2$l^{5},4$l^{5},6$l^{5}-triphosphacyclohexa-1,3,5-triene Chemical compound N=1P(OC=2C=CC=CC=2)(OC=2C=CC=CC=2)=NP(OC=2C=CC=CC=2)(OC=2C=CC=CC=2)=NP=1(OC=1C=CC=CC=1)OC1=CC=CC=C1 RNFJDJUURJAICM-UHFFFAOYSA-N 0.000 description 1
- QCHVBVDUBACNFH-UHFFFAOYSA-N 2-(hydroxymethyl)penta-2,3-diene-1,5-diol Chemical compound OCC=C=C(CO)CO QCHVBVDUBACNFH-UHFFFAOYSA-N 0.000 description 1
- KIHBGTRZFAVZRV-UHFFFAOYSA-N 2-Hydroxyoctadecanoic acid Natural products CCCCCCCCCCCCCCCCC(O)C(O)=O KIHBGTRZFAVZRV-UHFFFAOYSA-N 0.000 description 1
- TXBCBTDQIULDIA-UHFFFAOYSA-N 2-[[3-hydroxy-2,2-bis(hydroxymethyl)propoxy]methyl]-2-(hydroxymethyl)propane-1,3-diol Chemical compound OCC(CO)(CO)COCC(CO)(CO)CO TXBCBTDQIULDIA-UHFFFAOYSA-N 0.000 description 1
- JPUHAXBCXWSQMM-UHFFFAOYSA-N 2-hydroxyoctadec-2-enoic acid Chemical compound CCCCCCCCCCCCCCCC=C(O)C(O)=O JPUHAXBCXWSQMM-UHFFFAOYSA-N 0.000 description 1
- QLKSFCHONRVCOU-UHFFFAOYSA-N 3-[2-(2,3-dihydroxypropoxy)ethoxy]propane-1,2-diol Chemical compound OCC(O)COCCOCC(O)CO QLKSFCHONRVCOU-UHFFFAOYSA-N 0.000 description 1
- ALRHLSYJTWAHJZ-UHFFFAOYSA-N 3-hydroxypropionic acid Chemical compound OCCC(O)=O ALRHLSYJTWAHJZ-UHFFFAOYSA-N 0.000 description 1
- LXKCZUOSRQSRHW-UHFFFAOYSA-N 6-hydroxyoctadecanoic acid Chemical compound CCCCCCCCCCCCC(O)CCCCC(O)=O LXKCZUOSRQSRHW-UHFFFAOYSA-N 0.000 description 1
- 235000021357 Behenic acid Nutrition 0.000 description 1
- 239000005711 Benzoic acid Substances 0.000 description 1
- DPUOLQHDNGRHBS-UHFFFAOYSA-N Brassidinsaeure Natural products CCCCCCCCC=CCCCCCCCCCCCC(O)=O DPUOLQHDNGRHBS-UHFFFAOYSA-N 0.000 description 1
- FBPFZTCFMRRESA-FSIIMWSLSA-N D-Glucitol Natural products OC[C@H](O)[C@H](O)[C@@H](O)[C@H](O)CO FBPFZTCFMRRESA-FSIIMWSLSA-N 0.000 description 1
- VGGSQFUCUMXWEO-UHFFFAOYSA-N Ethene Chemical compound C=C VGGSQFUCUMXWEO-UHFFFAOYSA-N 0.000 description 1
- 239000005977 Ethylene Substances 0.000 description 1
- IAYPIBMASNFSPL-UHFFFAOYSA-N Ethylene oxide Chemical compound C1CO1 IAYPIBMASNFSPL-UHFFFAOYSA-N 0.000 description 1
- WQZGKKKJIJFFOK-GASJEMHNSA-N Glucose Natural products OC[C@H]1OC(O)[C@H](O)[C@@H](O)[C@@H]1O WQZGKKKJIJFFOK-GASJEMHNSA-N 0.000 description 1
- 241000692870 Inachis io Species 0.000 description 1
- 239000004594 Masterbatch (MB) Substances 0.000 description 1
- TUNFSRHWOTWDNC-UHFFFAOYSA-N Myristic acid Natural products CCCCCCCCCCCCCC(O)=O TUNFSRHWOTWDNC-UHFFFAOYSA-N 0.000 description 1
- 239000004677 Nylon Substances 0.000 description 1
- 229920002302 Nylon 6,6 Polymers 0.000 description 1
- 229910019142 PO4 Inorganic materials 0.000 description 1
- 239000004952 Polyamide Substances 0.000 description 1
- NINIDFKCEFEMDL-UHFFFAOYSA-N Sulfur Chemical compound [S] NINIDFKCEFEMDL-UHFFFAOYSA-N 0.000 description 1
- ZJCCRDAZUWHFQH-UHFFFAOYSA-N Trimethylolpropane Chemical compound CCC(CO)(CO)CO ZJCCRDAZUWHFQH-UHFFFAOYSA-N 0.000 description 1
- 239000011954 Ziegler–Natta catalyst Substances 0.000 description 1
- 150000001298 alcohols Chemical class 0.000 description 1
- 150000008051 alkyl sulfates Chemical class 0.000 description 1
- 125000000129 anionic group Chemical group 0.000 description 1
- 239000002216 antistatic agent Substances 0.000 description 1
- 229940116226 behenic acid Drugs 0.000 description 1
- 235000010233 benzoic acid Nutrition 0.000 description 1
- WQZGKKKJIJFFOK-VFUOTHLCSA-N beta-D-glucose Chemical compound OC[C@H]1O[C@@H](O)[C@H](O)[C@@H](O)[C@@H]1O WQZGKKKJIJFFOK-VFUOTHLCSA-N 0.000 description 1
- 239000011230 binding agent Substances 0.000 description 1
- 125000004432 carbon atom Chemical group C* 0.000 description 1
- 238000009960 carding Methods 0.000 description 1
- 239000003054 catalyst Substances 0.000 description 1
- 239000011248 coating agent Substances 0.000 description 1
- 238000000576 coating method Methods 0.000 description 1
- 239000003086 colorant Substances 0.000 description 1
- 238000001816 cooling Methods 0.000 description 1
- 239000008358 core component Substances 0.000 description 1
- 238000002425 crystallisation Methods 0.000 description 1
- 230000008025 crystallization Effects 0.000 description 1
- VZFUCHSFHOYXIS-UHFFFAOYSA-N cycloheptane carboxylic acid Natural products OC(=O)C1CCCCCC1 VZFUCHSFHOYXIS-UHFFFAOYSA-N 0.000 description 1
- 230000007423 decrease Effects 0.000 description 1
- 230000003247 decreasing effect Effects 0.000 description 1
- 230000007547 defect Effects 0.000 description 1
- 235000014113 dietary fatty acids Nutrition 0.000 description 1
- 229940105990 diglycerin Drugs 0.000 description 1
- 238000007598 dipping method Methods 0.000 description 1
- KFEVDPWXEVUUMW-UHFFFAOYSA-N docosanoic acid Natural products CCCCCCCCCCCCCCCCCCCCCC(=O)OCCC1=CC=C(O)C=C1 KFEVDPWXEVUUMW-UHFFFAOYSA-N 0.000 description 1
- 239000000806 elastomer Substances 0.000 description 1
- 238000004049 embossing Methods 0.000 description 1
- 230000007613 environmental effect Effects 0.000 description 1
- HQQADJVZYDDRJT-UHFFFAOYSA-N ethene;prop-1-ene Chemical group C=C.CC=C HQQADJVZYDDRJT-UHFFFAOYSA-N 0.000 description 1
- 239000003925 fat Substances 0.000 description 1
- 229930195729 fatty acid Natural products 0.000 description 1
- 239000000194 fatty acid Substances 0.000 description 1
- 150000004665 fatty acids Chemical class 0.000 description 1
- 239000003063 flame retardant Substances 0.000 description 1
- 230000004927 fusion Effects 0.000 description 1
- 239000008103 glucose Substances 0.000 description 1
- 235000011187 glycerol Nutrition 0.000 description 1
- 239000012760 heat stabilizer Substances 0.000 description 1
- 238000010438 heat treatment Methods 0.000 description 1
- 229920001903 high density polyethylene Polymers 0.000 description 1
- 239000004700 high-density polyethylene Substances 0.000 description 1
- 239000012510 hollow fiber Substances 0.000 description 1
- 239000012943 hotmelt Substances 0.000 description 1
- 239000008172 hydrogenated vegetable oil Substances 0.000 description 1
- 239000011256 inorganic filler Substances 0.000 description 1
- 229910003475 inorganic filler Inorganic materials 0.000 description 1
- 238000003475 lamination Methods 0.000 description 1
- 239000010985 leather Substances 0.000 description 1
- 230000014759 maintenance of location Effects 0.000 description 1
- 238000000691 measurement method Methods 0.000 description 1
- 238000002074 melt spinning Methods 0.000 description 1
- 150000002763 monocarboxylic acids Chemical class 0.000 description 1
- 239000000178 monomer Substances 0.000 description 1
- VLKZOEOYAKHREP-UHFFFAOYSA-N n-Hexane Chemical compound CCCCCC VLKZOEOYAKHREP-UHFFFAOYSA-N 0.000 description 1
- TVMXDCGIABBOFY-UHFFFAOYSA-N n-Octanol Natural products CCCCCCCC TVMXDCGIABBOFY-UHFFFAOYSA-N 0.000 description 1
- 229930014626 natural product Natural products 0.000 description 1
- 239000002667 nucleating agent Substances 0.000 description 1
- 229920001778 nylon Polymers 0.000 description 1
- ZWLPBLYKEWSWPD-UHFFFAOYSA-N o-toluic acid Chemical compound CC1=CC=CC=C1C(O)=O ZWLPBLYKEWSWPD-UHFFFAOYSA-N 0.000 description 1
- QIQXTHQIDYTFRH-UHFFFAOYSA-N octadecanoic acid Chemical compound CCCCCCCCCCCCCCCCCC(O)=O QIQXTHQIDYTFRH-UHFFFAOYSA-N 0.000 description 1
- 230000009965 odorless effect Effects 0.000 description 1
- 239000003921 oil Substances 0.000 description 1
- 235000019198 oils Nutrition 0.000 description 1
- 229920006280 packaging film Polymers 0.000 description 1
- 239000012785 packaging film Substances 0.000 description 1
- WXZMFSXDPGVJKK-UHFFFAOYSA-N pentaerythritol Chemical compound OCC(CO)(CO)CO WXZMFSXDPGVJKK-UHFFFAOYSA-N 0.000 description 1
- 230000035699 permeability Effects 0.000 description 1
- 235000021317 phosphate Nutrition 0.000 description 1
- 239000000049 pigment Substances 0.000 description 1
- 229920003207 poly(ethylene-2,6-naphthalate) Polymers 0.000 description 1
- 229920000747 poly(lactic acid) Polymers 0.000 description 1
- 229920002647 polyamide Polymers 0.000 description 1
- 239000004631 polybutylene succinate Substances 0.000 description 1
- 229920002961 polybutylene succinate Polymers 0.000 description 1
- 229920001707 polybutylene terephthalate Polymers 0.000 description 1
- 239000011112 polyethylene naphthalate Substances 0.000 description 1
- 239000004626 polylactic acid Substances 0.000 description 1
- QQONPFPTGQHPMA-UHFFFAOYSA-N propylene Natural products CC=C QQONPFPTGQHPMA-UHFFFAOYSA-N 0.000 description 1
- 125000004805 propylene group Chemical group [H]C([H])([H])C([H])([*:1])C([H])([H])[*:2] 0.000 description 1
- 238000004080 punching Methods 0.000 description 1
- 229920005604 random copolymer Polymers 0.000 description 1
- 239000002994 raw material Substances 0.000 description 1
- 150000003839 salts Chemical class 0.000 description 1
- 229920006300 shrink film Polymers 0.000 description 1
- 239000000779 smoke Substances 0.000 description 1
- 239000002904 solvent Substances 0.000 description 1
- 239000000600 sorbitol Substances 0.000 description 1
- 238000003860 storage Methods 0.000 description 1
- 239000011593 sulfur Substances 0.000 description 1
- 229910052717 sulfur Inorganic materials 0.000 description 1
- 239000002344 surface layer Substances 0.000 description 1
- LKOVPWSSZFDYPG-WUKNDPDISA-N trans-octadec-2-enoic acid Chemical compound CCCCCCCCCCCCCCC\C=C\C(O)=O LKOVPWSSZFDYPG-WUKNDPDISA-N 0.000 description 1
- 150000004670 unsaturated fatty acids Chemical class 0.000 description 1
- 235000021122 unsaturated fatty acids Nutrition 0.000 description 1
- 235000019871 vegetable fat Nutrition 0.000 description 1
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 1
Classifications
-
- D—TEXTILES; PAPER
- D04—BRAIDING; LACE-MAKING; KNITTING; TRIMMINGS; NON-WOVEN FABRICS
- D04H—MAKING TEXTILE FABRICS, e.g. FROM FIBRES OR FILAMENTARY MATERIAL; FABRICS MADE BY SUCH PROCESSES OR APPARATUS, e.g. FELTS, NON-WOVEN FABRICS; COTTON-WOOL; WADDING ; NON-WOVEN FABRICS FROM STAPLE FIBRES, FILAMENTS OR YARNS, BONDED WITH AT LEAST ONE WEB-LIKE MATERIAL DURING THEIR CONSOLIDATION
- D04H3/00—Non-woven fabrics formed wholly or mainly of yarns or like filamentary material of substantial length
- D04H3/005—Synthetic yarns or filaments
- D04H3/007—Addition polymers
-
- D—TEXTILES; PAPER
- D04—BRAIDING; LACE-MAKING; KNITTING; TRIMMINGS; NON-WOVEN FABRICS
- D04H—MAKING TEXTILE FABRICS, e.g. FROM FIBRES OR FILAMENTARY MATERIAL; FABRICS MADE BY SUCH PROCESSES OR APPARATUS, e.g. FELTS, NON-WOVEN FABRICS; COTTON-WOOL; WADDING ; NON-WOVEN FABRICS FROM STAPLE FIBRES, FILAMENTS OR YARNS, BONDED WITH AT LEAST ONE WEB-LIKE MATERIAL DURING THEIR CONSOLIDATION
- D04H3/00—Non-woven fabrics formed wholly or mainly of yarns or like filamentary material of substantial length
- D04H3/08—Non-woven fabrics formed wholly or mainly of yarns or like filamentary material of substantial length characterised by the method of strengthening or consolidating
- D04H3/16—Non-woven fabrics formed wholly or mainly of yarns or like filamentary material of substantial length characterised by the method of strengthening or consolidating with bonds between thermoplastic filaments produced in association with filament formation, e.g. immediately following extrusion
Definitions
- the present invention relates to a nonwoven fabric roll that retains the texture of the nonwoven fabric and has excellent handleability.
- the nonwoven fabric roll is generally wound around a paper tube (see, for example, Patent Document 1), but the rolled up form of the nonwoven fabric roll causes winding misalignment, or the paper tube as the core is misaligned, The paper tube sometimes came off. Furthermore, during processing using such a nonwoven fabric roll, meandering, a lot of fabric slack, or slippage between the paper tube and the nonwoven fabric occurred, and some roll products could not be used.
- non-woven fabrics there are a wide variety of non-woven fabrics, from soft to hard. Especially, non-woven fabrics with good texture and softness and good slipperiness on the surface may be damaged by winding during winding, and the texture of the nonwoven fabric may be impaired. Many of them are difficult to wind stably and in a long length.
- the length of the nonwoven fabric roll is increased, and the weight of the roll itself is also increased.
- the handling of the roll after packing the non-woven roll is generally performed in a vertical orientation with good transport and loading efficiency.
- the end face or corner of the roll tends to be subjected to a load, resulting in a compressive force and the formation of deformed wrinkles. It often ends up.
- An object of the present invention is to solve the above-described problems and provide a nonwoven fabric roll that is wound stably and in a long length without impairing the performance of a nonwoven fabric having a particularly good texture.
- the present invention is as follows. (1) A nonwoven fabric roll having a nonwoven fabric roll having a winding density (weight per unit area x winding length / cross-sectional area) of 0.175 g / cm 3 ⁇ (winding density) ⁇ 0.400 g / cm 3 . (2) The nonwoven fabric roll according to the above item 1, wherein the thickness ratio of the inner layer to the outer layer of the nonwoven fabric roll is 0.65 ⁇ (inner layer thickness / outer layer thickness) ⁇ 1.00 . (3) The nonwoven fabric roll according to 1 or 2 above, wherein the roll diameter of the nonwoven fabric roll is 30 cm or more, and the roll slip strength of the roll is 8.0 N ⁇ m or more.
- the polyolefin fiber contains at least a polypropylene fiber.
- the winding at the time of winding is small, the texture as a non-woven fabric is not impaired, and the slit is stably and long.
- a wound non-woven roll can be provided.
- the present invention is described in detail below.
- the method for producing the nonwoven fabric for forming the nonwoven fabric roll of the present invention is not particularly limited, and short fibers by so-called carding or papermaking may be used.
- a web is prepared by a wet papermaking method or an air-laying method, heated to a temperature at which the heat-fusible fibers are fused, and the intersections of the fibers are heat-fused to form a nonwoven fabric.
- any method such as an air-through method, a calender roll method, an embossing roll method, an ultrasonic method may be used.
- the fibers constituting the nonwoven fabric are preferably continuous filaments, and preferably contain long fibers.
- a continuous filament melt-spun by the spunbond method (S) is used as a web, and is formed by bonding the web.
- the state of lamination may be laminated with SS, SSS, SSSS, or may be laminated like SM, SMS, SMMS, SMSMS.
- thermocompression bonding / Can be done through the web between flat rolls.
- the area ratio of thermocompression bonding in partial thermocompression bonding is preferably 5 to 40%, more preferably 5 to 25%, from the viewpoint of strength retention and flexibility.
- the fiber constituting the nonwoven fabric is preferably a thermoplastic fiber, but is preferably a fiber that does not have a sticking property from the viewpoint of stability during unwinding.
- the thermoplastic fiber include polyolefin fibers such as polyethylene fiber, polypropylene fiber and copolymer polypropylene, polyethylene terephthalate fiber, polybutylene terephthalate fiber, polyester fiber such as polyethylene naphthalate fiber and copolymer polyester, and nylon-6 fiber.
- Polyamide fibers such as nylon-66 fiber and copolymer nylon, and biodegradable fibers such as polylactic acid, polybutylene succinate and polyethylene succinate are used.
- the polyolefin-type fiber is included from a viewpoint of texture.
- examples thereof include fibers made of resins such as polyethylene, polypropylene, and copolymers of these monomers and other ⁇ -olefins.
- Polypropylene may be a polymer synthesized by a general Ziegler Natta catalyst, or may be a polymer synthesized by a single site active catalyst typified by metallocene.
- Other ⁇ -olefins are those having 3 to 10 carbon atoms, such as propylene, 1-butene, 1-pentene, 1-hexane, 4-methyl-1-pentene and 1-octene. It is done. These may be used alone or in combination of two or more.
- the content of the adhesive resin is preferably 50% by weight or less in terms of handling and the like.
- a composite fiber may be a core sheath, side-by-side, split fiber or mixed fiber.
- the fiber shape includes not only ordinary circular fibers but also specially shaped fibers such as crimped fibers and hollow fibers.
- the main component is polypropylene from the viewpoint of strength and dimensional stability.
- the polypropylene component is preferably 75% by weight or more, particularly preferably 90% by weight or more.
- the thermoplastic fiber may be blended with a nucleating agent, a flame retardant, an inorganic filler, a pigment, a colorant, a heat stabilizer, an antistatic agent, and the like.
- the average single yarn fineness of the fibers constituting the nonwoven fabric is preferably 0.7 dtex or more and 3.5 dtex or less, more preferably 0.7 dtex or more and 3.0 dtex or less. From the viewpoint of spinning stability, it is preferably 0.7 dtex or more, and from the viewpoint of the texture and strength of the nonwoven fabric, it is preferably 3.5 dtex or less.
- Basis weight of the nonwoven fabric forming the nonwoven fabric roll of the present invention is preferably from 8 ⁇ 80g / m 2, more preferably 10 ⁇ 50g / m 2 in terms of texture of the nonwoven fabric.
- the paper tube used for the core of the nonwoven fabric roll of the present invention is preferably a general paper paper tube, but may be made of resin such as polystyrene or polypropylene. In view of cost, a paper tube is often used. As long as it is a non-woven fabric having hygroscopicity or a non-woven fabric subjected to a hydrophilic treatment, a hydrophobic paper tube laminated with a resin or a resin such as polyethylene is more preferable.
- the outer diameter size of the paper tube used for the core of the nonwoven fabric roll is not limited, but it is preferably 50 mm or more from the viewpoint of ease of winding because wrinkles or the like are likely to enter at the beginning of winding. 200 mm or less is preferable from the viewpoint of loading efficiency in terms of surface. Further, if the thickness of the paper tube is less than 4 mm, crushing is likely to occur, and a thickness of 4 mm or more is preferable.
- the facility for winding the nonwoven fabric is not particularly limited, and may be a general center drive type or surface drive type capable of adjusting the winding tension. Furthermore, if a restraining roller is used, the restraining pressure can be adjusted, which is preferable in that it can be wound more stably. Moreover, the slit to the required required width
- variety may be methods, such as a shear cut, a score cut, or a leather cut, and is not specifically limited.
- the winding density of the nonwoven fabric roll of the present invention is a value calculated by the basis weight of nonwoven fabric ⁇ roll winding length / roll cross-sectional area.
- the winding density is controlled mainly by the winding tension at the time of winding. In general, the lower the winding tension, the softer the winding tension, and the higher the winding tension, the harder the winding tension.
- the range of the winding tension varies depending on the properties of the nonwoven fabric to be wound, but is generally preferably adjusted in the range of 20 to 80 N / m.
- the winding density of the nonwoven fabric roll needs to be 0.175 to 0.400 g / cm 3 .
- the winding density is more preferably 0.175 to 0.310 g / cm 3 . Particularly preferred is 0.175 to 0.250 g / cm 3 .
- Further stable winding can be achieved by controlling the thickness ratio (inner layer thickness / outer layer thickness) between the inner layer and the outer layer of the nonwoven fabric roll in consideration of the winding density.
- the ratio of the thickness of the inner layer to the outer layer of the nonwoven fabric roll can be adjusted by the winding tension at the time of winding.For example, when using a suppression roller, the pressure decreases as the winding starts and ends. It is also possible to adjust by lowering.
- the inner layer and the outer layer of the nonwoven fabric roll are defined as the inner layer within 10% of the paper tube side of the distance obtained by subtracting the radius of the paper tube from the radius of the nonwoven fabric roll, and the outer layer within the outermost 10% of the nonwoven fabric roll.
- the thickness of the inner layer and the thickness of the outer layer indicate the thickness of one nonwoven fabric at a position within the above ranges.
- the thickness ratio (inner layer thickness / outer layer thickness) of the inner layer and the outer layer of the nonwoven fabric roll that can be stably wound is preferably 0.65 to 1.00. If the ratio of thickness is less than 0.65, a paper tube misalignment in which the paper tube comes out in the direction perpendicular to the end face of the nonwoven fabric roll is likely to occur, and it may come off the roll completely. Moreover, the winding deviation of the nonwoven fabric in which the end surfaces of the rolls are not aligned easily occurs.
- the thickness ratio is more preferably 0.80 to 1.00, and particularly preferably 0.85 to 0.96.
- the roll width of the nonwoven fabric roll of the present invention is not particularly limited, but a roll width of 60 mm or more is preferable from the viewpoint of winding stability. 80 mm or more is more preferable, and 100 mm or more is particularly preferable.
- the roll diameter of the nonwoven fabric roll of the present invention can be said to be a roll diameter of 30 cm or more in the sense of a long roll. That is, the range not exceeding the roll diameter of 30 cm can be easily wound without considering the problem solving means of the present invention. More preferably, it is 50 cm or more, More preferably, it is 70 cm or more. The range within 150 cm is preferable in terms of winding stability.
- the nonwoven fabric roll of the present invention preferably has a roll slip strength representing the degree of tightening of at least 8.0 N ⁇ m. It is more preferably 10.0 N ⁇ m or more, and particularly preferably 12.0 N ⁇ m or more.
- the roll slip strength can be adjusted with the winding tension at the time of winding.For example, when using a suppression roller, it is also possible to adjust the roll slip strength by decreasing the suppression pressure from the beginning of winding to the end of winding. is there. If the texture of the nonwoven fabric is maintained, the roll slip strength is preferably as large as possible. However, it is preferably 150 N ⁇ m or less, and preferably 100 N ⁇ m or less, as a guideline for preventing excessive tightening.
- the winding deviation of the nonwoven fabric roll of the present invention is preferably 0 to 8 mm.
- Winding misalignment refers to a state in which the nonwoven fabric is wound without being aligned with the end face of the roll when the nonwoven fabric roll is formed. That is, as the winding deviation distance increases, the winding is unstable.
- the winding deviation is more preferably within 5 mm from the viewpoint of stability in the processing step of the nonwoven fabric roll.
- the paper tube deviation of the nonwoven fabric roll of the present invention is preferably 0 to 8 mm.
- Paper tube misalignment refers to a state where the paper tube is not aligned with the end surface of the nonwoven fabric roll when forming the nonwoven fabric roll.
- the deviation of the paper tube is more preferably within 5 mm from the viewpoint of stability in the processing step of the nonwoven fabric roll.
- the winding diameter difference of the nonwoven fabric roll of the present invention is preferably 0 to 8 mm.
- the difference in the winding diameter indicates the unevenness of the surface of the nonwoven fabric roll, and is the difference between the maximum diameter and the minimum diameter in the width direction. That is, the larger the winding diameter difference, the more unstable the winding.
- the winding diameter difference is more preferably within 5 mm from the viewpoint of stability in the processing step of the nonwoven fabric roll.
- the surface friction coefficient MIU of the nonwoven fabric forming the nonwoven fabric roll of the present invention is preferably 0.050 to 0.400.
- the surface friction coefficient MIU exceeds 0.400, it becomes easy to cause the roll to be taken during the process or to tighten the nonwoven fabric roll.
- the surface friction coefficient MIU is less than 0.050, meandering or rolling due to slipping is likely to occur during the process.
- the surface friction coefficient MIU is more preferably 0.100 to 0.350, and particularly preferably 0.100 to 0.300.
- the nonwoven fabric roll of the present invention does not cause defects such as deformation wrinkles or scratches due to compression load during handling after packing, the both ends of the nonwoven fabric roll, or the outermost ends of a plurality of arranged nonwoven fabric rolls are suppressed with a curing sheet, and a film It is preferable to package with.
- Arranging a plurality of layers means arranging the end surfaces of the nonwoven fabric rolls so that the end surfaces are aligned so that the cores of the rolls are aligned. When arranging a plurality, it is common to arrange the same roll diameter.
- the outermost end surfaces are end surfaces that are outside the rolls arranged at both ends of a plurality of non-woven fabric rolls arranged. When packing, the outermost end surfaces may be cured with a curing sheet.
- the curing sheet is not particularly limited, and may be made of a thermoplastic resin such as polystyrene or polypropylene, or may be paper cardboard or cardboard.
- the size of the curing sheet is generally matched to the roll diameter size of the nonwoven fabric roll. When handling non-woven rolls after packing, the rolls are often stacked vertically in terms of transport and loading efficiency. For this reason, at least the diameter of the curing sheet on the roll end surface serving as the lower surface is preferably in the range of roll diameter ⁇ 10 mm because the curing effect of the corners of the roll is large. Further, from the viewpoint of preventing tearing of the packaging film, the range of ⁇ 10 mm to +5 mm is more preferable.
- the film used for the packaging is not particularly limited, but a polyolefin-based thermoplastic resin film such as polyethylene having moisture permeability that is not easily affected by environmental changes such as temperature and humidity during storage of the nonwoven fabric roll is preferable. Moreover, you may pack a nonwoven fabric roll using an automatic packing machine by hand packaging. It is preferable that the nonwoven fabric roll is wrapped and wrapped with a shrinkable film in terms of easy fixing. Furthermore, since the rolls are often stacked vertically during handling as described above, it is preferable that at least the corners which are the lower surfaces are wound more than the upper surfaces because the curing effect of the roll corners is large.
- the nonwoven fabric which forms the nonwoven fabric roll of the present invention is not limited, it is particularly effective as a nonwoven fabric roll wound up stably and a nonwoven fabric roll excellent in handling after packing, especially for a nonwoven fabric having a good texture. is there.
- the non-woven fabric having a good texture include a non-woven fabric in which a hydrophilic agent is attached to the non-woven fabric and a non-woven fabric containing a softening agent.
- hydrophilizing agent As a hydrophilizing agent that adheres to the nonwoven fabric, in consideration of safety to the human body and safety in the process, nonionic active agents in which ethylene oxide is added to higher alcohols, higher fatty acids, alkylphenols, etc., alkyl phosphates A single or mixture of anionic active agents such as salts and alkyl sulfates is preferably used.
- the amount of hydrophilic agent attached varies depending on the required performance, but for hygienic materials, for example, the range of 0.1 to 1.0 wt% is usually preferable with respect to the fiber, and is preferably from the standpoint of performance. 2 to 0.6 wt% is more preferable.
- hydrophilizing agent As a method of applying the hydrophilizing agent, existing methods such as a dipping method, a spraying method, and a coating (kiss coater, gravure coater) method can be generally employed using a diluted hydrophilizing agent, and as a drying method at that time Can be a known method using convective heat transfer, conduction heat transfer, radiant heat transfer, or the like, and can also be a drying method using hot air or infrared rays or a drying method using thermal contact.
- the softening agent contained in the nonwoven fabric is preferably, for example, an ester compound, and more preferably an ester compound of a tri to hexavalent polyol and a monocarboxylic acid.
- the tri- to hexavalent polyol include trivalent polyols such as glycerin and trimethylolpropane, tetravalent polyols such as pentaerythritol, glucose, sorbitan, diglycerin and ethylene glycol diglyceryl ether, triglycerin and trimethylolpropane diene.
- Examples include pentavalent polyols such as glyceryl ether, hexavalent polyols such as sorbitol, tetraglycerin, and dipentaerythritol.
- Examples of the monocarboxylic acid include octacarboxylic acid, dodecanoic acid, tetradecanoic acid, octadecanoic acid, docosanoic acid, hexacosanoic acid, octadecenoic acid, docosenoic acid and isooctadecanoic acid, and other alicyclic monocarboxylic acids such as cyclohexanecarboxylic acid.
- Aromatic monocarboxylic acids such as benzoic acid and methylbenzenecarboxylic acid, hydroxyaliphatic monocarboxylic acids such as hydroxypropionic acid, hydroxyoctadecanoic acid and hydroxyoctadecenoic acid, and sulfur-containing aliphatic monocarboxylic acids such as alkylthiopropionic acid Etc.
- the ester compound used as a softening agent need not be a single component, and may be a mixture of two or more. Oils and fats derived from natural products may be used. However, since ester compounds containing unsaturated fatty acids are easily oxidized and easily deteriorated during melt spinning, saturated aliphatic monocarboxylic acids or aromatic monocarboxylic acids are preferred. When natural oils and fats are used, hydrogenated ester compounds are preferably used because they are odorless and stable compared to raw material oils.
- the ester compound has a relatively high molecular weight of monocarboxylic acid and high lipophilicity.
- the content of the ester compound is preferably 0.3 wt% or more and 5.0 wt% or less with respect to the thermoplastic fiber. Even when the ester compound is added in a small amount, the bending flexibility and slipperiness are remarkably improved, and even if the content is increased, the performance improvement corresponding to the content is not observed. From this, considering the spinnability and smoke generation, 5.0 wt% or less is appropriate, more preferably 0.5 wt% to 3.5 wt%, particularly preferably 0.5 wt% to 2.0 wt%. .
- nonwoven fabric roll of the present invention is stably wound and is excellent in handling and processing suitability, it is particularly preferable for sanitary materials such as disposable diapers, sanitary napkins and incontinence pads that require a texture.
- non-woven fabrics for applications such as masks, warmers, tape base fabrics, tarpaulin base fabrics, patch base fabrics, first aid adhesive base fabrics, packaging materials, wipe products, medical gowns, bandages, clothing and skin care sheets can be used as a roll. *
- Non-woven surface friction coefficient MIU The MIU in the present invention uses a friction feeling tester KES-SE (manufactured by Kato Tech), cuts a non-woven fabric of length (MD direction) 30 cm ⁇ width (CD direction) 3 cm, and attaches it by applying a predetermined load of 20 g / cm. ,It was measured. A friction element and a sample in which ten contacts obtained by bending a piano wire with a diameter of 0.5 mm into a U-shape are arranged, and a standard measurement condition (SENS: H, SPEED: 1 mm / sec, pressure bonding pressure between the sample and the friction element: Friction at 50 gf) and MIU was measured. The vertical (MD) direction is measured three times, and the average is shown. A smaller value means less frictional resistance.
- KES-SE manufactured by Kato Tech
- Roll slip strength (N ⁇ m) Insert a rubber roll slip fixed shaft (paper tube inner surface contact rubber length 5 cm) into the paper tube of the non-woven roll, insert air into the shaft, apply a certain pressure, and tightly fix the inside of the paper tube and rubber. It was. Next, using a torque wrench, the roll slip fixed shaft was turned in the roll winding direction, and the strength when the paper tube was rotated was measured. That is, the roll slip strength indicates the degree of tightening of the nonwoven fabric around the paper tube. The lower the roll slip strength, the easier the paper tube slippage and paper tube slippage occur, and the paper tube during unwinding in the processing step. This means that problems such as slipping of the nonwoven fabric are likely to occur.
- Roll diameter of non-woven roll (cm) The nonwoven fabric roll was rolled and placed on the floor surface, and the distance from the floor surface to the top of the nonwoven fabric roll through the center of the end surface of the nonwoven fabric roll was measured using a ruler. This was measured at both end faces, and one third of the roll was rolled and measured in the same manner, and one third of the roll was rolled and measured in the same manner. The average value of a total of 6 points measured at 3 points on one end face and 3 points on the other end face was taken as the roll diameter of the nonwoven fabric roll.
- the inner layer and the outer layer of the nonwoven fabric roll are defined as the inner layer within 10% of the paper tube side of the distance obtained by subtracting the radius of the paper tube from the radius of the nonwoven fabric roll, and the outer layer within the outermost 10% of the nonwoven fabric roll.
- the thickness of the inner layer and the thickness of the outer layer indicate the thickness of a single nonwoven fabric at a position within the above ranges. Immediately after unwinding the nonwoven fabric roll, the thickness of the nonwoven fabric located in the range of the inner layer and the outer layer was arbitrarily measured with a peacock type thickness meter (100 g / cm 2 ), and the average thickness was calculated.
- Winding density (g / cm 3 ) The winding density (g / cm 3 ) of the nonwoven fabric roll is a value calculated by the basis weight of the nonwoven fabric ⁇ roll winding length / roll cross-sectional area.
- the fabric weight of the nonwoven fabric was measured at the same time as the above-mentioned thickness measurement by arbitrarily measuring the weight of three nonwoven fabric rolls of 1 m in the inner layer and outer layer, and measuring the value (roll width measured by a ruler ⁇ 1 m length ⁇ 3 sheets) ) Divided by the area value.
- the roll length of the nonwoven fabric was measured with a length measuring counter installed in a winder.
- the roll cross-sectional area of the nonwoven fabric was determined by obtaining the cross-sectional area from the roll diameter measured in 4 above and subtracting the paper tube outer diameter cross-sectional area used from that value.
- Winding deviation The difference between the outermost position and the innermost position of the end of the nonwoven fabric wound without being aligned with the end face of the nonwoven fabric roll was measured using a ruler. 8). Paper tube misalignment (mm) The distance from the end of the paper tube that slipped out from the end face of the nonwoven fabric roll and the end position of the nonwoven fabric at the start of winding was measured using a ruler.
- Roll diameter difference The roll diameter difference of a nonwoven fabric roll shows the unevenness
- Example 1 Polypropylene resin (MFR measured under the conditions of Table 1 of JIS-K7210 is 60) is spunbonded, while the yarn melt-extruded from the nozzle is cooled from the side near the nozzle, while air soccer etc. It was picked up by a traction puller. The yarn exiting the pulling / drawing device was passed through a charging device, opened, and then collected as a web on a moving wire mesh conveyor. This web was conveyed, passed between heated embossed rolls having a partial thermocompression area ratio of 7%, and partially thermocompression bonded to obtain a nonwoven fabric with a basis weight of 18 g / m 2 having a pinpoint-like dotted pattern. The fineness of the obtained nonwoven fabric was 2.0 dtex, and the surface friction coefficient MIU was 0.193.
- the nonwoven fabric roll was obtained.
- the obtained nonwoven fabric roll had a winding diameter of 760 mm, a winding density of 0.201 g / cm 3 , and a roll slip strength of 25 N ⁇ m, and there was no problem in winding deviation, paper pipe deviation, and winding diameter difference.
- the end surface of the nonwoven fabric roll was cured with a corrugated cardboard sheet having the same diameter as the roll diameter, and was automatically packed using a polyethylene shrink film so that the lower surface of the roll was wound twice more than the upper surface.
- the state of the nonwoven fabric roll after packing was free from deformation wrinkles due to handling.
- the evaluation results of the obtained nonwoven fabric roll are shown in Table 1.
- Example 2 A nonwoven fabric roll was obtained in the same manner as in Example 1 except that the winding tension was adjusted to 40 N / m.
- the resulting nonwoven fabric roll had a winding density of 0.190 g / cm 3 and a roll slip strength of 15 N ⁇ m.
- the evaluation results of the obtained nonwoven fabric roll are shown in Table 1.
- Example 3 A nonwoven fabric roll was obtained in the same manner as in Example 1 except that the winding tension was adjusted to 25 N / m.
- the resulting nonwoven fabric roll had a winding density of 0.186 g / cm 3 and a roll slip strength of 10 N ⁇ m.
- the evaluation results of the obtained nonwoven fabric roll are shown in Table 1.
- Example 4 A nonwoven fabric roll was obtained in the same manner as in Example 1 except that a nonwoven fabric obtained with a basis weight of 17 g / m 2 , a fineness of 1.1 dtex and a surface friction coefficient of 0.255 was slit into a width of 200 mm and wound up by 7000 m.
- the resulting nonwoven fabric roll had a winding density of 0.202 g / cm 3 and a roll slip strength of 35 N ⁇ m.
- the evaluation results of the obtained nonwoven fabric roll are shown in Table 1.
- Example 5 As a softening agent, a masterbatch of octadecanoic acid glyceride (hydrogenated vegetable oil and fat) having a melting point of 86 to 90 ° C. (average melting point of 88 ° C.) and polypropylene resin is added and mixed at the time of polypropylene melt extrusion, and octadecanoic acid glyceride 1
- the resulting nonwoven fabric roll had a winding density of 0.200 g / cm 3 and a roll slip strength of 45 N ⁇ m.
- the evaluation results of the obtained nonwoven fabric roll are shown in Table 1.
- Example 6 The nonwoven fabric obtained with a basis weight of 20 g / m 2 and a fineness of 2.8 dtex was passed through a corona discharge treatment machine under the condition of a discharge amount of 40 W ⁇ min / m 2 (discharge degree: 4.0 W / cm 2 ). A hydrophilizing agent is applied by a spraying method and then dried, and a non-woven fabric having a hydrophilizing agent attached and fixed at 0.3 wt% and a surface friction coefficient MIU of 0.150 is obtained from an outer diameter of 81 mm laminated with a polyethylene resin.
- a non-woven fabric roll was obtained in the same manner as in Example 1 except that the above-described hydrophobic paper tube was used for winding while adjusting the winding tension to be 50 N ⁇ m.
- the resulting nonwoven fabric roll had a winding density of 0.206 g / cm 3 and a roll slip strength of 25 N ⁇ m.
- the evaluation results of the obtained nonwoven fabric roll are shown in Table 1. Moreover, although the nonwoven fabric roll after packing was stored for one week in a room at a temperature of 40 ° C. and a humidity of 90%, a state in which the wetness of the paper tube was transferred to the nonwoven fabric was not observed.
- Example 7 The nonwoven fabric obtained with a basis weight of 15 g / m 2 and a fineness of 2.0 dtex was passed through a corona discharge treatment machine under a discharge amount of 40 W ⁇ min / m 2 (discharge degree: 4.0 W / cm 2 ).
- a hydrophilizing agent is applied by a spraying method and then dried, and a non-woven fabric having a hydrophilizing agent of 0.5 wt% attached and fixed and a surface friction coefficient MIU of 0.138 is laminated with a polyethylene resin from an outer diameter of 81 mm.
- a non-woven fabric roll was obtained in the same manner as in Example 1 except that the hydrophobic paper tube was adjusted so that the take-up tension was 45 N ⁇ m, slitted to a width of 100 mm, and taken up 12000 m.
- the resulting nonwoven fabric roll had a winding density of 0.191 g / cm 3 and a roll slip strength of 10 N ⁇ m.
- the evaluation results of the obtained nonwoven fabric roll are shown in Table 1.
- Example 8 The nonwoven fabric obtained with a basis weight of 20 g / m 2 and a fineness of 2.8 dtex was passed through a corona discharge treatment machine under the condition of a discharge amount of 40 W ⁇ min / m 2 (discharge degree: 4.0 W / cm 2 ).
- a hydrophilic agent is applied by a spraying method and then dried, and a non-woven fabric having a hydrophilic coefficient of 1.25 wt% attached and fixed and a surface friction coefficient MIU of 0.100 is laminated from an outer diameter of 81 mm laminated with a polyethylene resin.
- a non-woven fabric roll was obtained in the same manner as in Example 1 except that the winding tension was adjusted to 45 N ⁇ m using a hydrophobic paper tube, and slitting to a width of 60 mm and winding.
- the resulting nonwoven fabric roll had a winding density of 0.196 g / cm 3 and a roll slip strength of 8 N ⁇ m.
- the evaluation results of the obtained nonwoven fabric roll are shown in Table 1.
- Example 9 Polypropylene resin (MFR measured under the conditions of Table 1 of JIS-K7210 is 60) is spunbonded, while the yarn melt-extruded from the nozzle is cooled from the side near the nozzle, while air soccer etc. It was picked up by a traction puller. The yarn exiting the pulling / drawing device was passed through a charging device, opened, and then collected as a web on a moving wire mesh conveyor. Next, a polypropylene resin (MFR1000) was melt sprayed from the spinning nozzle on the web by a melt blow method, and collected as a laminated web.
- MFR1000 Polypropylene resin
- a web obtained by a spunbond method from a polypropylene resin (MFR measured under the conditions shown in Table 1 of JIS-K7210 is 60) was laminated.
- the collected laminated web (spunbond / meltblown / spunbond) is conveyed, passed between heated embossed rolls with a partial thermocompression area ratio of 12%, and partially thermocompressed to have an elliptical dot pattern 15 g / A non-woven fabric of m 2 was obtained.
- the nonwoven fabric obtained had a spunbond fineness of 2.00 dtex and a surface friction coefficient MIU of 0.200.
- the obtained nonwoven fabric was slit to a width of 395 mm, and wound on a paper tube having an outer diameter of 81 mm while taking up a winding tension of 65 N / m to obtain a nonwoven fabric roll.
- the resulting nonwoven fabric roll had a winding density of 0.182 g / cm 3 and a roll slip strength of 60 N ⁇ m.
- the evaluation results of the obtained nonwoven fabric roll are shown in Table 1.
- Example 10 Thread obtained by melt-extrusion of ethylene / propylene random copolymer resin (MFR measured under the conditions shown in Table 1 of JIS-K7210 of 24) having an ethylene component content of 4.3 mol% from a nozzle through a spunbond method. While being cooled from the side near the spinneret, it was taken up by a towing take-up device such as an air soccer. The yarn exiting the pulling / drawing device was passed through a charging device, opened, and then collected as a web on a moving wire mesh conveyor.
- MFR ethylene / propylene random copolymer resin
- This web was conveyed, passed between heated embossed rolls having a partial thermocompression area ratio of 7%, and partially thermocompression bonded to obtain a nonwoven fabric with a basis weight of 18 g / m 2 having a pinpoint-like dotted pattern.
- the fineness of the obtained nonwoven fabric was 1.5 dtex, and the surface friction coefficient MIU was 0.192.
- the nonwoven fabric roll was obtained.
- the resulting nonwoven fabric roll had a winding density of 0.218 g / cm 3 and a roll slip strength of 30 N ⁇ m.
- the evaluation results of the obtained nonwoven fabric roll are shown in Table 1.
- Example 11 A nylon 6 resin melt-extruded from a spinning nozzle by a spunbonding method was taken up by a pulling take-up device such as an air soccer while cooling from the side near the spinning nozzle.
- the yarn exiting the pulling / drawing device was passed through a charging device, opened, and then collected as a web on a moving wire mesh conveyor.
- This web was conveyed, passed between heated embossed rolls having a partial thermocompression area ratio of 11%, and partially thermocompression bonded to obtain a nonwoven fabric with a basis weight of 30 g / m 2 having a pinpoint-like dotted pattern.
- the fineness of the obtained nonwoven fabric was 2.2 dtex, and the surface friction coefficient MIU was 0.310.
- the nonwoven fabric roll was obtained.
- the resulting nonwoven fabric roll had a winding density of 0.181 g / cm 3 and a roll slip strength of 65 N ⁇ m.
- the evaluation results of the obtained nonwoven fabric roll are shown in Table 1.
- Example 12 A yarn obtained by melting and extruding a general-purpose polyethylene terephthalate resin from a spinning nozzle by a spunbond method was taken from a side near the spinning nozzle by a pulling / pulling device such as an air soccer.
- the yarn exiting the pulling / drawing device was passed through a charging device, opened, and then collected as a web on a moving wire mesh conveyor.
- the web was conveyed, passed between heated embossed rolls having a partial thermocompression area ratio of 11%, and partially thermocompression bonded to obtain a nonwoven fabric with a basis weight of 50 g / m 2 having a rectangular dotted pattern.
- the fineness of the obtained nonwoven fabric was 2.0 dtex, and the surface friction coefficient MIU was 0.350.
- the nonwoven fabric roll was obtained.
- the resulting nonwoven fabric roll had a winding density of 0.223 g / cm 3 and a roll slip strength of 40 N ⁇ m.
- the evaluation results of the obtained nonwoven fabric roll are shown in Table 1.
- Example 13 Polyolefin-based heat-fusible conjugate fiber made of high-density polyethylene having a single yarn fineness of 2.7 dtex, a fiber length of 20 mm, a sheath component of melting point 130 ° C., and a core component of melting point 165 ° C. by a wet process
- Heat treatment was performed at a temperature of 125 ° C. by an air-through method to obtain a nonwoven fabric composed of a polyolefin-based heat-fusible conjugate fiber.
- the resulting nonwoven fabric had a surface friction coefficient MIU of 0.145.
- the nonwoven fabric roll was obtained.
- the resulting nonwoven fabric roll had a winding density of 0.244 g / cm 3 and a roll slip strength of 15 N ⁇ m.
- the evaluation results of the obtained nonwoven fabric roll are shown in Table 1.
- Example 14 A yarn obtained by melting and extruding a general-purpose polyethylene terephthalate resin from a spinning nozzle by a spunbond method was taken from a side near the spinning nozzle by a pulling / pulling device such as an air soccer. The yarn exiting the pulling / drawing device was passed through a charging device, opened, and then collected as a web on a moving wire mesh conveyor. Next, polyethylene terephthalate (solution viscosity ⁇ sp / c 0.50) was melt sprayed from the spinning nozzle on the web by a melt blow method and collected as a laminated web. Further, a web obtained from a general-purpose polyethylene terephthalate resin by a spunbond method was laminated.
- the collected laminated web (spunbond / meltblown / spunbond) is conveyed, passed between heated embossed rolls with a partial thermocompression area ratio of 14.4%, and partially thermocompressed to have a textured dot pattern.
- a nonwoven fabric having a basis weight of 40 g / m 2 was obtained.
- the resulting nonwoven fabric had a spunbond fineness of 1.50 dtex and a surface friction coefficient MIU of 0.300.
- the nonwoven fabric roll was obtained.
- the resulting nonwoven fabric roll had a winding density of 0.307 g / cm 3 and a roll slip strength of 70 N ⁇ m.
- the evaluation results of the obtained nonwoven fabric roll are shown in Table 1.
- Example 15 A nonwoven fabric roll was obtained in the same manner as in Example 6 except that a paper tube having an outer diameter of 81 mm was used. The evaluation results of the obtained nonwoven fabric roll are shown in Table 1. Moreover, when the nonwoven fabric roll after packing was stored for one week in a room at a temperature of 40 ° C. and a humidity of 90%, the wet state of the paper tube was transferred to the nonwoven fabric.
- Example 16 A nonwoven fabric roll was obtained in the same manner as in Example 1 except that the end face of the nonwoven fabric roll was not cured with a corrugated cardboard sheet. As for the state of the nonwoven fabric roll after packing, there was no deformation wrinkle at the end face of the roll at the time of handling, but a dent was found. The evaluation results of the obtained nonwoven fabric roll are shown in Table 1.
- Example 17 A nonwoven fabric roll was obtained in the same manner as in Example 1 except that the upper surface of the end face of the nonwoven fabric roll had a roll diameter size and the lower surface had a roll diameter size of -20 mm and was cured with a corrugated cardboard sheet. The state of the non-woven roll after packing was free from deformation wrinkles, but dents were found at the corners of the roll end surface that was the lower surface. The evaluation results of the obtained nonwoven fabric roll are shown in Table 1.
- Example 18 25 wt% addition of a low-melting-point polypropylene resin polypropylene elastomer (18 MFR measured under the conditions of Table 1 of JIS-K7210) having a sticking property and a melting point of 104 ° C. to the polypropylene resin used in Example 1.
- the basis weight of the obtained nonwoven fabric was 17 g / m 2
- the fineness was 1.1 dtex
- the surface friction coefficient was 0.265
- the obtained nonwoven fabric was 350 mm wide.
- a nonwoven fabric roll was obtained in the same manner as in Example 1 except that the film was slit to 7000 m and wound up by 7000 m.
- the resulting nonwoven fabric roll had a winding density of 0.220 g / cm 3 and a roll slip strength of 65 N ⁇ m.
- the evaluation results of the obtained nonwoven fabric roll are shown in Table 1.
- Example 1 A nonwoven fabric roll was obtained in the same manner as in Example 1 except that the winding tension was adjusted to 15 N / m.
- the resulting nonwoven fabric roll had a winding density of 0.172 g / cm 3 and a roll slip strength of 5 N ⁇ m. Further, winding deviation was 11 mm and paper tube deviation was 10 mm, which was not stable winding.
- the evaluation results of the obtained nonwoven fabric roll are shown in Table 1.
- Example 2 A non-woven fabric roll of short fibers was obtained in the same manner as in Example 13 except that the winding tension was adjusted to 85 N / m.
- the resulting nonwoven fabric roll had a winding density of 0.522 g / cm 3 and a roll slip strength of 40 N ⁇ m. Further, the winding deviation was 9 mm and the paper tube deviation was 10 mm, and the winding was not stable. Further, due to the tightening, the thickness of the nonwoven fabric was crushed and the texture was impaired.
- the evaluation results of the obtained nonwoven fabric roll are shown in Table 1.
- Table 1 shows the following. Even if the nonwoven fabric roll of the present invention has a good texture and is soft and has a good surface slipperiness, it has a small length of winding and does not impair the texture as a nonwoven fabric, and can be slit stably and long. A wound non-woven roll can be provided. In addition, it is possible to provide a product with good handleability because it is difficult for deformation wrinkles to enter the end faces and corners after packing.
- nonwoven fabric roll of the present invention is stably wound and is excellent in handleability and processing suitability as a product, including sanitary materials such as disposable diapers, sanitary napkins and incontinence pads that are particularly required for the texture,
- sanitary materials such as disposable diapers, sanitary napkins and incontinence pads that are particularly required for the texture
- non-woven rolls for applications such as masks, warmers, tape base fabrics, tarpaulin base fabrics, patch medicinal base fabrics, first aid base fabrics, packaging materials, wipe products, medical gowns, bandages, clothing and skin care sheets Can be used.
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- Engineering & Computer Science (AREA)
- Textile Engineering (AREA)
- Nonwoven Fabrics (AREA)
- Storage Of Web-Like Or Filamentary Materials (AREA)
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CN (1) | CN103459696B (ko) |
MY (1) | MY161275A (ko) |
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WO2019230837A1 (ja) * | 2018-05-31 | 2019-12-05 | 東レ株式会社 | カーテン用不織布およびその製造方法 |
CN112590335A (zh) * | 2020-12-02 | 2021-04-02 | 东莞市海纳森非织造科技有限公司 | 一种石墨烯复合无纺布及其制作方法 |
Citations (4)
Publication number | Priority date | Publication date | Assignee | Title |
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WO2001066846A1 (fr) * | 2000-03-07 | 2001-09-13 | Kanebo, Limited | Rouleau de nontisse en elastomere thermoplastique |
WO2001096641A1 (fr) * | 2000-06-13 | 2001-12-20 | Idemitsu Unitech Co., Ltd. | Textile non-tisse file-lie et article absorbant |
JP2003052752A (ja) * | 2001-08-21 | 2003-02-25 | Asahi Kasei Corp | 衛生材料用トップシート |
JP2006027900A (ja) * | 2004-06-18 | 2006-02-02 | Japan Vilene Co Ltd | ロール状巻き物 |
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JP5412733B2 (ja) * | 2007-03-05 | 2014-02-12 | 東レ株式会社 | シート状物の巻取り装置 |
JP5022152B2 (ja) * | 2007-09-07 | 2012-09-12 | 日本バイリーン株式会社 | ロール状巻き物及びそれに用いられる巻芯 |
KR100908953B1 (ko) * | 2007-10-24 | 2009-07-22 | 노경일 | 부직포 가공 장치 및 방법 |
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- 2012-04-04 WO PCT/JP2012/059214 patent/WO2012137827A1/ja active Application Filing
- 2012-04-04 JP JP2013508903A patent/JP5690923B2/ja active Active
- 2012-04-04 CN CN201280016651.9A patent/CN103459696B/zh active Active
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Patent Citations (4)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
WO2001066846A1 (fr) * | 2000-03-07 | 2001-09-13 | Kanebo, Limited | Rouleau de nontisse en elastomere thermoplastique |
WO2001096641A1 (fr) * | 2000-06-13 | 2001-12-20 | Idemitsu Unitech Co., Ltd. | Textile non-tisse file-lie et article absorbant |
JP2003052752A (ja) * | 2001-08-21 | 2003-02-25 | Asahi Kasei Corp | 衛生材料用トップシート |
JP2006027900A (ja) * | 2004-06-18 | 2006-02-02 | Japan Vilene Co Ltd | ロール状巻き物 |
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CN103459696B (zh) | 2016-06-22 |
JPWO2012137827A1 (ja) | 2014-07-28 |
JP5690923B2 (ja) | 2015-03-25 |
MY161275A (en) | 2017-04-14 |
CN103459696A (zh) | 2013-12-18 |
TWI502108B (zh) | 2015-10-01 |
TW201250077A (en) | 2012-12-16 |
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