WO2012124940A3 - 저온 유동성을 개선한 경제적인 수첨 바이오디젤의 제조 방법 - Google Patents

저온 유동성을 개선한 경제적인 수첨 바이오디젤의 제조 방법 Download PDF

Info

Publication number
WO2012124940A3
WO2012124940A3 PCT/KR2012/001749 KR2012001749W WO2012124940A3 WO 2012124940 A3 WO2012124940 A3 WO 2012124940A3 KR 2012001749 W KR2012001749 W KR 2012001749W WO 2012124940 A3 WO2012124940 A3 WO 2012124940A3
Authority
WO
WIPO (PCT)
Prior art keywords
low temperature
improved low
temperature flowability
preparing hydrogenated
economically preparing
Prior art date
Application number
PCT/KR2012/001749
Other languages
English (en)
French (fr)
Other versions
WO2012124940A2 (ko
Inventor
주영환
김경록
유재욱
김도완
송종희
황윤맹
최선
Original Assignee
에스케이이노베이션 주식회사
에스케이에너지 주식회사
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by 에스케이이노베이션 주식회사, 에스케이에너지 주식회사 filed Critical 에스케이이노베이션 주식회사
Priority to EP12758212.0A priority Critical patent/EP2684938B1/en
Publication of WO2012124940A2 publication Critical patent/WO2012124940A2/ko
Publication of WO2012124940A3 publication Critical patent/WO2012124940A3/ko

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G3/00—Production of liquid hydrocarbon mixtures from oxygen-containing organic materials, e.g. fatty oils, fatty acids
    • C10G3/50—Production of liquid hydrocarbon mixtures from oxygen-containing organic materials, e.g. fatty oils, fatty acids in the presence of hydrogen, hydrogen donors or hydrogen generating compounds
    • C10G3/52—Hydrogen in a special composition or from a special source
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G3/00—Production of liquid hydrocarbon mixtures from oxygen-containing organic materials, e.g. fatty oils, fatty acids
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G3/00—Production of liquid hydrocarbon mixtures from oxygen-containing organic materials, e.g. fatty oils, fatty acids
    • C10G3/50—Production of liquid hydrocarbon mixtures from oxygen-containing organic materials, e.g. fatty oils, fatty acids in the presence of hydrogen, hydrogen donors or hydrogen generating compounds
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G45/00—Refining of hydrocarbon oils using hydrogen or hydrogen-generating compounds
    • C10G45/32—Selective hydrogenation of the diolefin or acetylene compounds
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G45/00—Refining of hydrocarbon oils using hydrogen or hydrogen-generating compounds
    • C10G45/58—Refining of hydrocarbon oils using hydrogen or hydrogen-generating compounds to change the structural skeleton of some of the hydrocarbon content without cracking the other hydrocarbons present, e.g. lowering pour point; Selective hydrocracking of normal paraffins
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G65/00—Treatment of hydrocarbon oils by two or more hydrotreatment processes only
    • C10G65/02—Treatment of hydrocarbon oils by two or more hydrotreatment processes only plural serial stages only
    • C10G65/04—Treatment of hydrocarbon oils by two or more hydrotreatment processes only plural serial stages only including only refining steps
    • C10G65/043—Treatment of hydrocarbon oils by two or more hydrotreatment processes only plural serial stages only including only refining steps at least one step being a change in the structural skeleton
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G65/00—Treatment of hydrocarbon oils by two or more hydrotreatment processes only
    • C10G65/02—Treatment of hydrocarbon oils by two or more hydrotreatment processes only plural serial stages only
    • C10G65/04—Treatment of hydrocarbon oils by two or more hydrotreatment processes only plural serial stages only including only refining steps
    • C10G65/06—Treatment of hydrocarbon oils by two or more hydrotreatment processes only plural serial stages only including only refining steps at least one step being a selective hydrogenation of the diolefins
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G65/00—Treatment of hydrocarbon oils by two or more hydrotreatment processes only
    • C10G65/02—Treatment of hydrocarbon oils by two or more hydrotreatment processes only plural serial stages only
    • C10G65/04—Treatment of hydrocarbon oils by two or more hydrotreatment processes only plural serial stages only including only refining steps
    • C10G65/08—Treatment of hydrocarbon oils by two or more hydrotreatment processes only plural serial stages only including only refining steps at least one step being a hydrogenation of the aromatic hydrocarbons
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10L—FUELS NOT OTHERWISE PROVIDED FOR; NATURAL GAS; SYNTHETIC NATURAL GAS OBTAINED BY PROCESSES NOT COVERED BY SUBCLASSES C10G, C10K; LIQUEFIED PETROLEUM GAS; ADDING MATERIALS TO FUELS OR FIRES TO REDUCE SMOKE OR UNDESIRABLE DEPOSITS OR TO FACILITATE SOOT REMOVAL; FIRELIGHTERS
    • C10L1/00—Liquid carbonaceous fuels
    • C10L1/02—Liquid carbonaceous fuels essentially based on components consisting of carbon, hydrogen, and oxygen only
    • C10L1/026—Liquid carbonaceous fuels essentially based on components consisting of carbon, hydrogen, and oxygen only for compression ignition
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10L—FUELS NOT OTHERWISE PROVIDED FOR; NATURAL GAS; SYNTHETIC NATURAL GAS OBTAINED BY PROCESSES NOT COVERED BY SUBCLASSES C10G, C10K; LIQUEFIED PETROLEUM GAS; ADDING MATERIALS TO FUELS OR FIRES TO REDUCE SMOKE OR UNDESIRABLE DEPOSITS OR TO FACILITATE SOOT REMOVAL; FIRELIGHTERS
    • C10L1/00—Liquid carbonaceous fuels
    • C10L1/04—Liquid carbonaceous fuels essentially based on blends of hydrocarbons
    • C10L1/08—Liquid carbonaceous fuels essentially based on blends of hydrocarbons for compression ignition
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G2300/00—Aspects relating to hydrocarbon processing covered by groups C10G1/00 - C10G99/00
    • C10G2300/80—Additives
    • C10G2300/802—Diluents
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G2400/00—Products obtained by processes covered by groups C10G9/00 - C10G69/14
    • C10G2400/04—Diesel oil
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02E—REDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
    • Y02E50/00—Technologies for the production of fuel of non-fossil origin
    • Y02E50/10—Biofuels, e.g. bio-diesel
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
    • Y02P30/00—Technologies relating to oil refining and petrochemical industry
    • Y02P30/20—Technologies relating to oil refining and petrochemical industry using bio-feedstock

Landscapes

  • Chemical & Material Sciences (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Engineering & Computer Science (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • General Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Crystallography & Structural Chemistry (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Production Of Liquid Hydrocarbon Mixture For Refining Petroleum (AREA)
  • Fats And Perfumes (AREA)

Abstract

본 발명은 트리글리세리드(Triglyceride, TG)를 함유하는 공급원료에 수소를 첨가하여 물, CO, CO2 형태로 산소를 제거하는데 있어서, 탈산소 반응의 결과물 중 일부를 이성화 반응시킨 후 재순환하여 신규 공급원료(Fresh Feed)를 희석한 상태로 다시 수첨 탈산소화 반응을 수행하여 바이오디젤을 제조하는 방법에 관한 것이다.
PCT/KR2012/001749 2011-03-11 2012-03-09 저온 유동성을 개선한 경제적인 수첨 바이오디젤의 제조 방법 WO2012124940A2 (ko)

Priority Applications (1)

Application Number Priority Date Filing Date Title
EP12758212.0A EP2684938B1 (en) 2011-03-11 2012-03-09 Method for economically preparing hydrogenated biodiesel with improved low temperature flowability

Applications Claiming Priority (4)

Application Number Priority Date Filing Date Title
KR10-2011-0021689 2011-03-11
KR20110021689 2011-03-11
KR1020120024181A KR20120103499A (ko) 2011-03-11 2012-03-09 저온 유동성을 개선한 경제적인 수첨 바이오디젤의 제조 방법
KR10-2012-0024181 2012-03-09

Publications (2)

Publication Number Publication Date
WO2012124940A2 WO2012124940A2 (ko) 2012-09-20
WO2012124940A3 true WO2012124940A3 (ko) 2012-12-27

Family

ID=47111534

Family Applications (1)

Application Number Title Priority Date Filing Date
PCT/KR2012/001749 WO2012124940A2 (ko) 2011-03-11 2012-03-09 저온 유동성을 개선한 경제적인 수첨 바이오디젤의 제조 방법

Country Status (4)

Country Link
EP (1) EP2684938B1 (ko)
KR (2) KR20120103499A (ko)
MY (1) MY173367A (ko)
WO (1) WO2012124940A2 (ko)

Families Citing this family (7)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
FR3024156B1 (fr) * 2014-07-25 2016-07-29 Ifp Energies Now Procede optimise pour la valorisation de bio-huiles en carburants hydrocarbones
FR3034099B1 (fr) * 2015-03-27 2019-05-10 IFP Energies Nouvelles Procede optimise de conversion de bio-huile avec stabilisation de la charge
US10385282B2 (en) 2016-11-14 2019-08-20 Korea Institute Of Energy Research Method and system for upgrading and separating hydrocarbon oils
KR20220030946A (ko) * 2019-07-05 2022-03-11 할도르 토프쉐 에이/에스 저압 분리기로부터의 액체 재순환이 있는 옥시게네이트 공급원료의 수소화처리
CZ2020118A3 (cs) * 2020-03-06 2021-08-18 Maneko, Spol. S R.O. Způsob výroby motorových paliv z triglyceridů mastných kyselin a zařízení k provádění způsobu
WO2022129361A1 (en) * 2020-12-17 2022-06-23 Topsoe A/S Process for operating sulfided hydroprocessing catalyst
EP4321600A1 (en) 2022-08-11 2024-02-14 Shell Internationale Research Maatschappij B.V. Process for producing kerosene and/or diesel from renewable sources

Citations (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US20040230085A1 (en) * 2002-09-06 2004-11-18 Juha Jakkula Process for producing a hydrocarbon component of biological origin
US20070010682A1 (en) * 2005-07-05 2007-01-11 Neste Oil Oyj Process for the manufacture of diesel range hydrocarbons
US20090163744A1 (en) * 2007-12-20 2009-06-25 Ramin Abhari Hydrodeoxygenation process
US20090300970A1 (en) * 2006-11-15 2009-12-10 Eni S.P.A. Process for producing hydrocarbon fractions from mixtures of a biological origin
WO2010011737A2 (en) * 2008-07-24 2010-01-28 Chevron U.S.A. Inc. Conversion of vegetable oils to base oils and transportation fuels

Family Cites Families (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US5897768A (en) * 1997-02-28 1999-04-27 Exxon Research And Engineering Co. Desulfurization process for removal of refractory organosulfur heterocycles from petroleum streams
JP5070170B2 (ja) * 2008-09-18 2012-11-07 Ｊｘ日鉱日石エネルギー株式会社 炭化水素油の製造方法

Patent Citations (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US20040230085A1 (en) * 2002-09-06 2004-11-18 Juha Jakkula Process for producing a hydrocarbon component of biological origin
US20070010682A1 (en) * 2005-07-05 2007-01-11 Neste Oil Oyj Process for the manufacture of diesel range hydrocarbons
US20090300970A1 (en) * 2006-11-15 2009-12-10 Eni S.P.A. Process for producing hydrocarbon fractions from mixtures of a biological origin
US20090163744A1 (en) * 2007-12-20 2009-06-25 Ramin Abhari Hydrodeoxygenation process
WO2010011737A2 (en) * 2008-07-24 2010-01-28 Chevron U.S.A. Inc. Conversion of vegetable oils to base oils and transportation fuels

Also Published As

Publication number Publication date
MY173367A (en) 2020-01-21
WO2012124940A2 (ko) 2012-09-20
EP2684938A4 (en) 2014-10-01
KR20140147068A (ko) 2014-12-29
EP2684938A2 (en) 2014-01-15
EP2684938B1 (en) 2018-02-07
KR101746905B1 (ko) 2017-06-14
KR20120103499A (ko) 2012-09-19

Similar Documents

Publication Publication Date Title
WO2012124940A3 (ko) 저온 유동성을 개선한 경제적인 수첨 바이오디젤의 제조 방법
MX345399B (es) Metodo de cultivo de celulas animales.
MX2019004568A (es) Produccion mejorada de derivados de acidos grasos.
CO6351813A2 (es) "metodos y composiciones para mejorar la produccion de productos en microorganismos"
WO2012166267A3 (en) Method to convert fermentation mixture into fuels
MY197101A (en) Methods of producing omega-hydroxylated fatty acid derivatives
WO2012103261A3 (en) Compositions and methods for succinate production
BR112012009828B8 (pt) Método para a produção de uma imunoglobulina glicosilada e seu uso
MY172288A (en) Cell systems and methods for improving fatty acid synthesis by expression of dehydrogenases
WO2014176552A3 (en) Methods to produce fuels
PH12014501212A1 (en) Compositions comprising 20-carbon fatty acids and methods of making and using same
WO2009035689A3 (en) Biofuel composition and manufacturing process
EP2734628A4 (en) SIMULTANEOUS SULFURMENT AND FERMENTATION (SSF) OF LIGNOCELLULOSE BIOMASS FOR THE MANUFACTURE OF SINGLE OIL BY OILED MICROORGANISMS
WO2013176948A3 (en) Method of operation of a syngas fermentation process
IN2014DN07094A (ko)
WO2012142302A3 (en) Biocatalytic process for preparing eslicarbazepine and analogs thereof
WO2012142094A3 (en) Compositions and methods for increased ethanol production from biomass
WO2014101902A8 (zh) 一种提高酶促油脂制备生物柴油产率的方法
Norazahar et al. Parametric optimization of kapok (Ceiba pentandra) oil methyl ester production using Taguchi approach
WO2012031166A3 (en) Expression of steady state metabolic pathways
WO2011145867A3 (ko) 알킬락테이트의 제조방법 및 이를 이용한 락타미드의 제조방법
WO2012125626A3 (en) Decorin compositions and use thereof
MY170588A (en) Method for producing internal olefin
GB2519468A (en) Process for preparing an extract of vegetable material, an extract prepared in this way and its use in animal food
MX344240B (es) Mejoramiento a la panificacion con un alto contenido de levadura.

Legal Events

Date Code Title Description
121 Ep: the epo has been informed by wipo that ep was designated in this application

Ref document number: 12758212

Country of ref document: EP

Kind code of ref document: A2

NENP Non-entry into the national phase

Ref country code: DE

WWE Wipo information: entry into national phase

Ref document number: 1301005065

Country of ref document: TH

WWE Wipo information: entry into national phase

Ref document number: 2012758212

Country of ref document: EP