WO2012113291A1 - 能增加云石胶韧性的添加剂 - Google Patents

能增加云石胶韧性的添加剂 Download PDF

Info

Publication number
WO2012113291A1
WO2012113291A1 PCT/CN2012/071045 CN2012071045W WO2012113291A1 WO 2012113291 A1 WO2012113291 A1 WO 2012113291A1 CN 2012071045 W CN2012071045 W CN 2012071045W WO 2012113291 A1 WO2012113291 A1 WO 2012113291A1
Authority
WO
WIPO (PCT)
Prior art keywords
additive
weight
marble
toughness
mpa
Prior art date
Application number
PCT/CN2012/071045
Other languages
English (en)
French (fr)
Inventor
杜昆文
杜昆武
Original Assignee
武汉市科达云石护理材料有限公司
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by 武汉市科达云石护理材料有限公司 filed Critical 武汉市科达云石护理材料有限公司
Priority to CA2828025A priority Critical patent/CA2828025C/en
Priority to AU2012220248A priority patent/AU2012220248A1/en
Priority to EP12749505.9A priority patent/EP2679649A4/en
Priority to RU2013142862/05A priority patent/RU2013142862A/ru
Priority to BR112013021551A priority patent/BR112013021551A2/pt
Publication of WO2012113291A1 publication Critical patent/WO2012113291A1/zh
Priority to ZA2013/06294A priority patent/ZA201306294B/en
Priority to US13/975,393 priority patent/US9371433B2/en

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K5/00—Use of organic ingredients
    • C08K5/04—Oxygen-containing compounds
    • C08K5/06—Ethers; Acetals; Ketals; Ortho-esters
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K5/00—Use of organic ingredients
    • C08K5/04—Oxygen-containing compounds
    • C08K5/05—Alcohols; Metal alcoholates
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
    • C09J11/00—Features of adhesives not provided for in group C09J9/00, e.g. additives
    • C09J11/02—Non-macromolecular additives
    • C09J11/06—Non-macromolecular additives organic
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
    • C09J167/00—Adhesives based on polyesters obtained by reactions forming a carboxylic ester link in the main chain; Adhesives based on derivatives of such polymers
    • C09J167/06—Unsaturated polyesters having carbon-to-carbon unsaturation

Definitions

  • the present invention relates to an additive or composition for marble glue, and more particularly to a force agent which increases the toughness of marble. Background technique
  • the bond strength of the adhesive is determined by the cohesive strength and adhesion strength of the colloid. If the rigidity of the gel is too strong, the interface of the adhesive surface of the adhesive will be broken. If the toughness of the adhesive is too large, the cohesive failure of the adhesive surface of the adhesive will occur. Therefore, only when the rigidity of the colloid is moderate, the bonding strength of the adhesive can be optimized. However, the existing marble glue product has a relatively large rigidity, and the bonding surface is easily detached after a long time, causing interface damage and affecting the bonding effect.
  • Silver streaks and cracks are very similar, except that the middle of the crack is empty, and the silver in the middle of the silver streak is connected by silver.
  • the silver grain develops thicker and the silver grain breaks, which is a crack.
  • the appearance and development of silver streaks quickly deteriorate the mechanical properties of materials.
  • styrene (crosslinking agent, thinner) in marble glue is easy to volatilize and self-polymerize to cause "water-splitting", which affects the operation.
  • the object of the present invention is to overcome the deficiencies of the above background art, and to add special additives to the marble glue, the addition thereof improves the toughness of the existing marble glue, inhibits the generation of the silver streaks, and makes the mechanical properties thereof. Better, bonding strength is higher and stronger. At the same time, it has also improved the existing "water-forming" of marble glue, reducing the cost of existing marble glue.
  • an additive capable of increasing the toughness of marble glue characterized in that the additive in the marble glue is: R-(C 6 H 4 )-CH 3 OH (wherein R is hydrogen or Alkane), R-0-(CH 2 ) 2 -0-(CH 2 ) 2 -OH, R-0-CH 2 -CH(OH)-CH 3 , R-0-(CH 2 ) 2 -OH
  • R is hydrogen or Alkane
  • R-0-CH 2 -CH(OH)-CH 3 R-0-(CH 2 ) 2 -OH
  • R-0(CH 2 ) 2 -OH One or more of (wherein R is an alkane) in an amount of from 0.5% to 10% by weight based on the content of the unsaturated polyester resin in the marble paste, in an amount by weight.
  • the additive is one or more of benzyl alcohol, diethylene glycol methyl ether, diethylene glycol ethyl ether
  • the additive dosage ratio is 1% to 5% of the content of the unsaturated polyester resin in the marble glue, and the amount is in parts by weight.
  • the additive dosage ratio is 5%-10% of the content of the unsaturated polyester resin in the marble glue, and the amount is in parts by weight.
  • the additive dosage ratio is 8% of the content of the unsaturated polyester resin in the marble glue, and the amount is in parts by weight.
  • the additive capable of increasing the toughness of marble adhesive has the following advantages: 1. Increasing the toughness of the marble glue, improving the adhesion performance of the bonding surface, thereby increasing the bonding strength of the marble glue; 2. suppressing the generation of the silver grain , improve the mechanical properties of marble glue; 3, reduce the viscosity of the colloid, optimize the compatibility of the colloid, improve the penetration of the colloid on the stone; 4, replace part of the styrene, thereby inhibiting styrene (existing cloud).
  • the use of styrene as a reactive diluent for the use of styrene as a reactive diluent, and the volatilization of the diluent is more volatile, thereby improving the "water-forming" of the marble glue; 5.
  • the additive has no irritating odor; Reduce the production cost of marble glue. detailed description
  • the invention can increase the toughness of the marble glue.
  • the additive in the marble glue is: R-(C 6 H 4 )-CH 3 OH (wherein R is hydrogen or an alkane), R-0-(CH 2 ) 2 One or several of -0-(CH 2 ) 2 -OH, R-0-CH 2 -CH(OH)-CH 3 , R-0-(CH 2 ) 2 -OH (wherein R is an alkane)
  • the dosage ratio is 0.5%-10% of the content of the unsaturated polyester resin in the marble glue, and the amount is in parts by weight.
  • the additive is one or more of benzyl alcohol, diethylene glycol methyl ether, diethylene glycol diethyl ether, propylene glycol methyl ether, and ethylene glycol methyl ether.
  • the additive dosage ratio is 0.5%-10% of the content of the unsaturated polyester resin in the marble glue, and the amount is in parts by weight. Yunshi shares technical requirements
  • the additive was 0.5 parts by weight of phenyl sterol. Tested: The compressive shear strength (MPa) is: 15.1, tensile shear strength (MPa): 16.4, flexural modulus (MPa): 5072.6, impact toughness (KJ/m2): 2.73.
  • MPa compressive shear strength
  • MPa tensile shear strength
  • MPa flexural modulus
  • KJ/m2 impact toughness
  • the additive was 1 part by weight of phenylhydrin. Tested: The compressive shear strength (MPa) is: 18.9, tensile shear strength (MPa): 17.5, flexural modulus (MPa): 4016.8, impact toughness (KJ/m2): 2.97.
  • MPa compressive shear strength
  • MPa tensile shear strength
  • MPa flexural modulus
  • KJ/m2 impact toughness
  • the additive was 5 parts by weight of phenylhydrin. Tested: The compressive shear strength (MPa) is: 17.3, tensile shear strength (MPa): 16.9, flexural modulus (MPa): 3740.5, impact toughness (KJ/m2): 3.34.
  • MPa compressive shear strength
  • MPa tensile shear strength
  • MPa flexural modulus
  • KJ/m2 impact toughness
  • the additive was 4 parts by weight of benzofuran and 4 parts by weight of diethylene glycol oxime ether.
  • the compressive shear strength (MPa) is: 16.7, tensile shear strength (MPa): 16.5, flexural modulus (MPa): 3510.7, impact toughness (KJ/m2): Example 6
  • the additive was 3 parts by weight of benzofuran, 3 parts by weight of diethylene glycol oxime ether, and 3 parts by weight of diethylene glycol diethyl ether.
  • the compressive shear strength (MPa) is: 15.2, tensile shear strength (MPa): 15.0, flexural modulus (MPa): 3341.9, impact toughness (KJ/m2): 3.67.
  • MPa compressive shear strength
  • MPa tensile shear strength
  • MPa flexural modulus
  • KJ/m2 impact toughness
  • the additive was 2 parts by weight of phenyl sterol, 3 parts by weight of diethylene glycol oxime ether, 2 parts by weight of diethylene glycol diethyl ether, and 3 parts by weight of propylene glycol oxime ether.
  • the compressive shear strength (MPa) is: 13.1, tensile shear strength (MPa): 13.4, flexural modulus (MPa): 3012.4, impact toughness (KJ/m2): 3.73.
  • MPa compressive shear strength
  • MPa tensile shear strength
  • MPa flexural modulus
  • KJ/m2 impact toughness
  • the additive was 3 parts by weight of phenyl decyl alcohol, 3 parts by weight of diethylene glycol oxime ether, 3 parts by weight of diethylene glycol ethyl ether, 3 parts by weight of propylene glycol oxime ether, and 3 parts by weight of ethylene glycol oxime ether.
  • the compressive shear strength (MPa) is: 9.8, tensile strength (MPa): 10.1, flexural modulus (MPa): 2321.0, impact toughness (KJ/m2): 4.01.
  • Example 1-8 are all transparent marble glue, and Examples 9-12 are variegated marble glue (colored).
  • the additive was 1 part by weight of propylene glycol oxime ether. Tested: The compressive shear strength (MPa) is: 13.8, tensile shear strength (MPa): 15.9, flexural modulus (MPa): 5134.7, impact toughness (KJ/m2): 2.34.
  • MPa compressive shear strength
  • MPa tensile shear strength
  • MPa flexural modulus
  • KJ/m2 impact toughness
  • the additive was 2 parts by weight of diethylene glycol oxime ether, 2 parts by weight of diethylene glycol ether, and 2 parts by weight of propylene glycol oxime ether.
  • the compressive shear strength (MPa) is: 15.3, tensile shear strength (MPa): 16.9, flexural modulus (MPa): 4324.1, impact toughness (KJ/m2): 2.98.
  • MPa compressive shear strength
  • MPa tensile shear strength
  • MPa flexural modulus
  • KJ/m2 impact toughness
  • the additive was 4 parts by weight of diethylene glycol oxime ether, 2 parts by weight of diethylene glycol diethyl ether, 3 parts by weight of propylene glycol oxime ether, and 4 parts by weight of ethylene glycol oxime ether.
  • the compressive shear strength (MPa) is: 9.2, tensile shear strength (MPa): 9.4, flexural modulus (MPa): 3216.5, impact toughness (KJ/m2): 3.43.
  • the additive of the present invention has a toughening effect on both transparent marble glue and variegated marble glue.
  • the toughness of the marble glue gradually increases. The reason may be that the addition of the additive reduces the appearance of silver streaks and prevents the spread of the silver streaks.

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Health & Medical Sciences (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Adhesives Or Adhesive Processes (AREA)
  • Macromonomer-Based Addition Polymer (AREA)

Abstract

能增加云石胶韧性的添加剂，云石胶内添加物为：R-(C6H4)-CH3OH、R-O-(CH2)2-O-(CH2)2-OH、R-O-CH2-CH(OH)-CH3、R-O-(CH2)2-OH中的一种或几种，其中R为氢或烷烃类，其用量比为云石胶中不饱和聚酯树脂含量的0.5%-10%，用量为重量份。本发明添加剂的加入提高了现有云石胶的韧性，抑制了银纹的产生，使得其机械性能更好、粘接强度更高更牢。同时也改善了现有云石胶"结冰凌"情况，降低了现有云石胶的成本。

Description

能增加云石胶韧性的添加剂
技术领域
本发明涉及一种云石胶的添加剂或组合物， 更具体地说它是一种能增加云石胶韧性 的 力口剂。 背景技术
胶粘剂的粘接强度是由胶体的内聚强度和粘附强度所共同决定的。 若胶体的刚性太 强， 则会造成胶粘剂的粘接面的界面破坏； 若胶粘剂的韧性太大， 则会造成胶粘剂的粘 接面的内聚破坏。 所以只有当胶体的刚性适中才能使胶粘剂的粘接强度达到最佳值。 而 现有的云石胶产品刚性较大， 时间久后粘接面易脱开， 造成界面破坏， 影响粘接效果。
且现有云石胶固化物内部均有不同程度的银紋出现。 银紋和裂紋极相似， 不同之处 在于裂紋中间是空的， 银紋中间的空洞中有银紋质相连。 银紋发展变粗， 银紋质断裂， 即成裂紋。 银紋的出现和发展， 使材料的机械性能迅速变差。 另外云石胶中苯乙烯（交 联剂、 稀释剂） 易挥发自聚造成"结水凌 "情况， 影响操作使用。
因此发明一种能增加云石胶韧性的添加剂， 使云石胶的强度适中， 且能克服云石胶 的"结水凌"现象和银紋的出现成为了一项迫切而重要的工作。 发明内容
本发明的目的在于克服上述背景技术的不足之处， 而在云石胶中添加了特殊助剂， 它的添加提高了现有云石胶的韧性， 抑制了银紋的产生， 使得其机械性能更好、 粘接强 度更高更牢。 同时也改善了现有云石胶"结水凌"情况， 降低了现有云石胶的成本。
为了克服上述问题， 本发明人通过无数次的科学试验， 在大量的化合物中， 筛选了 如下几种物质， 这些物质较好地解决了上述的问题。
本发明的目的是通过如下措施来达到的： 能增加云石胶韧性的添加剂， 其特征在于 云石胶内添加物为： R-(C6H4)-CH3OH (其中 R为氢或烷烃类）、 R-0-(CH2)2-0-(CH2)2-OH、 R-0-CH2-CH(OH)-CH3、 R-0-(CH2)2-OH (其中 R为烷烃类）中的一种或几种， 其用量比 为云石胶中不饱和聚酯树脂含量的 0.5%-10%, 用量为重量份。 在上述技术方案中， 所述添加物为： 苯甲醇、 二乙二醇甲醚、 二乙二醇乙醚、 丙二 醇甲醚、 乙二醇甲醚中的一种或几种。
在上述技术方案中， 所述添加物用量比为云石胶中不饱和聚酯树脂含量的 1%-5% , 用量为重量份。
在上述技术方案中， 所述添加物用量比为云石胶中不饱和聚酯树脂含量的 5%-10%, 用量为重量份。
在上述技术方案中， 所述添加物用量比为云石胶中不饱和聚酯树脂含量的 8% , 用 量为重量份。
本发明能增加云石胶韧性的添加剂具有如下优点： 1、增加云石胶的韧性， 提高粘接 面的粘附性能， 进而增加云石胶的粘接强度； 2、 抑制了银紋的产生， 提高了云石胶机械 性能； 3、 降低了胶体粘度， 优化了胶体的调和性， 提高了胶体对石材的浸润渗透性； 4、 取代了部分苯乙烯， 从而抑制了苯乙烯（现有云石胶多釆用苯乙烯作为活性稀释剂， 该 稀释剂挥发性较强）的挥发， 进而改善了云石胶"结水凌"情况； 5、 该类添加剂无较大刺 激性气味； 6、 降低了云石胶的生产成本。 具体实施方式
下面通过实施例详细说明本发明的实施情况， 但它们并不构成对本发明的限定， 仅 作举例而已。 同时通过说明本发明的优点将变得更加清楚和容易理解。
本发明能增加云石胶韧性的添加剂， 云石胶内添加物为： R-(C6H4)-CH3OH (其中 R 为氢或烷烃类）、 R-0-(CH2)2-0-(CH2)2-OH、 R-0-CH2-CH(OH)-CH3、 R-0-(CH2)2-OH (其 中 R为烷烃类）中的一种或几种，其用量比为云石胶中不饱和聚酯树脂含量的 0.5%-10% , 用量为重量份。
所述添加物为： 苯甲醇、 二乙二醇甲醚、 二乙二醇乙醚、 丙二醇甲醚、 乙二醇甲醚 中的一种或几种。
所述添加物用量比为云石胶中不饱和聚酯树脂含量的 0.5%-10%, 用量为重量份。 云石股技术要求
(中华人民共和国建材行业标准 J C / T 9 8 9— 2 0 0 6 ) 技术要求
项 目
优等品 合格品
为色泽均匀、细腻的粘稠膏状体，无明显 颜色、 外观及容器中状态 离析、凝胶及明显的粗颗粒，搅拌无困难，
各组分的颜色或包装应有明显区别。
弯曲弹性模量， (MPa) > 2000 1500 冲击韧性， ( KJ/m2 ) > 3.0 2.0 压剪粘接强度 ... _
, 、 石材 -石材 标准条件 8.0 7.0
( MPa ) > 实施例 1 (对比例）（不饱和聚酯树脂为 100重量份， 每份为重量份， 下同）
现有无本发明添加物的透明云石胶经检测： 其压缩剪切强度（ MPa) 为： 14.6, 拉 伸剪切强度（MPa): 16.2, 弯曲弹性模量（MPa): 5201.4, 冲击韧性（KJ/m2): 2.62。 实施例 2
添加物为苯曱醇 0.5重量份。 经检测： 其压缩剪切强度（MPa)为： 15.1, 拉伸剪切 强度（MPa): 16.4, 弯曲弹性模量（MPa): 5072.6, 冲击韧性（KJ/m2): 2.73。
若将苯曱醇替换成二乙二醇曱醚、 二乙二醇乙醚、 丙二醇曱醚、 乙二醇曱醚中的一 种， 效果基本相同。 实施例 3
添加物为苯曱醇 1重量份。 经检测： 其压缩剪切强度（MPa) 为： 18.9, 拉伸剪切 强度（MPa): 17.5, 弯曲弹性模量（MPa): 4016.8, 冲击韧性（KJ/m2): 2.97。 实施例 4
添加物为苯曱醇 5重量份。 经检测： 其压缩剪切强度（MPa) 为： 17.3, 拉伸剪切 强度（MPa): 16.9, 弯曲弹性模量（MPa): 3740.5, 冲击韧性（KJ/m2): 3.34。 实施例 5
添加物为苯曱醇 4重量份，二乙二醇曱醚 4重量份。经检测：其压缩剪切强度（MPa) 为： 16.7,拉伸剪切强度（MPa): 16.5,弯曲弹性模量（MPa): 3510.7,冲击韧性（KJ/m2): 实施例 6
添加物为苯曱醇 3重量份， 二乙二醇曱醚 3重量份， 二乙二醇乙醚 3重量份。 经检 测：其压缩剪切强度（MPa)为： 15.2,拉伸剪切强度（MPa): 15.0,弯曲弹性模量（MPa): 3341.9, 冲击韧性 ( KJ/m2 ): 3.67。 实施例 7
添加物为苯曱醇 2重量份， 二乙二醇曱醚 3重量份， 二乙二醇乙醚 2重量份， 丙二 醇曱醚 3重量份。 经检测： 其压缩剪切强度（MPa) 为： 13.1, 拉伸剪切强度（MPa): 13.4, 弯曲弹性模量（MPa): 3012.4, 冲击韧性（KJ/m2): 3.73。 实施例 8
添加物为苯曱醇 3重量份， 二乙二醇曱醚 3重量份， 二乙二醇乙醚 3重量份， 丙二 醇曱醚 3重量份， 乙二醇曱醚 3重量份。 经检测： 其压缩剪切强度（MPa) 为： 9.8, 拉 伸剪切强度（MPa): 10.1, 弯曲弹性模量（MPa): 2321.0, 冲击韧性（KJ/m2): 4.01。
以上实施例 1-8均为透明云石胶， 实施例 9-12为杂色云石胶（有色）。 实施例 9 (对比例）
现有无添加物杂色云石胶经检测： 其压缩剪切强度 (MPa) 为： 11.1, 拉伸剪切强 度（MPa): 14.4, 弯曲弹性模量（MPa): 5974.8, 冲击韧性（KJ/m2): 1.93。 实施例 10
添加物为丙二醇曱醚 1重量份。 经检测： 其压缩剪切强度（MPa) 为： 13.8, 拉伸 剪切强度（MPa): 15.9, 弯曲弹性模量（MPa): 5134.7, 冲击韧性（KJ/m2): 2.34。 实施例 11
添加物为二乙二醇曱醚 2重量份， 二乙二醇乙醚 2重量份， 丙二醇曱醚 2重量份。 经检测： 其压缩剪切强度（MPa ) 为： 15.3 , 拉伸剪切强度（MPa ): 16.9, 弯曲弹性模 量（MPa ): 4324.1 , 冲击韧性（ KJ/m2 ): 2.98。 实施例 12
所述添加物为二乙二醇曱醚 4重量份， 二乙二醇乙醚 2重量份， 丙二醇曱醚 3重量 份，乙二醇曱醚 4重量份。经检测：其压缩剪切强度（MPa )为： 9.2,拉伸剪切强度（MPa ): 9.4, 弯曲弹性模量（MPa ): 3216.5, 冲击韧性（KJ/m2 ): 3.43。
经试用本发明添加物对于透明云石胶和杂色云石胶都具有增韧效果。 结论： 由实施例可以看出， ①无添加物的云石胶冲击韧性较小， 随着添加物的不断 加入， 云石胶的韧性逐渐增加； 但加入量过大后其其它力学性能便有不同程度衰减。 不 难看出， 实施例 5中所述云石胶的综合性能最好。
②添加物加入后云石胶的韧性逐渐增加， 究其原因可能是由于添加物的加入减少了 银纹出现， 防止了银纹扩散。
③实施例 1、 9于 50°C烘箱测试， 放置 3个月后， 均有"结水凌 "情况出现， 其余实 施例中则未见 "结水凌"情况出现。 由此可见， 添加物的加入， 减緩了云石胶 "结水凌"产 生。
需要说明的是： 对于所属领域的技术人员来说， 在不改变本发明原理的前提下， 还 可以对本发明作出适当的改进和变形， 这同样属于本发明的保护范围。

Claims

权利要求 书
1、 能增加云石胶韧性的添加剂， 其特征在于云石胶内添加物为： R-(C6H4)-CH3OH、 R-0-(CH2)2-0-(CH2)2-OH、 R-0-CH2-CH(OH)-CH3、 R-0-(CH2)2-OH中的一种或几种， 其 中 R为氢或烷烃类， 其用量比为云石胶中不饱和聚酯树脂含量的 0.5%-10% , 用量为重 量份。
2、 根据权利要求 1所述的能增加云石胶韧性的添加剂， 其特征在于所述添加物为： 苯甲醇、 二乙二醇甲醚、 二乙二醇乙醚、 丙二醇甲醚、 乙二醇甲醚中的一种或几种。
3、 根据权利要求 1或 2所述的能增加云石胶韧性的添加剂，其特征在于所述添加物 用量比为云石胶中不饱和聚酯树脂含量的 1%-5% , 用量为重量份。
4、 根据权利要求 1或 2所述的能增加云石胶韧性的添加剂及其组合物，其特征在于 所述添加物用量比为云石胶中不饱和聚酯树脂含量的 5%-10% , 用量为重量份。
5、根据权利要求 4所述的能增加云石胶韧性的添加剂及其组合物，其特征在于所述 添加物用量比为云石胶中不饱和聚酯树脂含量的 8%, 用量为重量份。
PCT/CN2012/071045 2010-03-03 2012-02-13 能增加云石胶韧性的添加剂 WO2012113291A1 (zh)

Priority Applications (7)

Application Number Priority Date Filing Date Title
CA2828025A CA2828025C (en) 2011-02-24 2012-02-13 Additive for increasing toughness of marble glue
AU2012220248A AU2012220248A1 (en) 2011-02-24 2012-02-13 Additive for increasing toughness of marble glue
EP12749505.9A EP2679649A4 (en) 2011-02-24 2012-02-13 Additive for increasing toughness of marble glue
RU2013142862/05A RU2013142862A (ru) 2011-02-24 2012-02-13 Присадка для увеличения прочности мраморного клея
BR112013021551A BR112013021551A2 (pt) 2011-02-24 2012-02-13 aditivo para aumentar a tenacidade da cola de mármore
ZA2013/06294A ZA201306294B (en) 2011-02-24 2013-08-21 Additive for increasing toughness of marble glue
US13/975,393 US9371433B2 (en) 2010-03-03 2013-08-26 Additive for enhancing toughness of marble adhesive

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
CN201110043873.7 2011-02-24
CN201110043873.7A CN102181254B (zh) 2010-03-03 2011-02-24 增韧云石胶组合物

Related Child Applications (1)

Application Number Title Priority Date Filing Date
US13/975,393 Continuation-In-Part US9371433B2 (en) 2010-03-03 2013-08-26 Additive for enhancing toughness of marble adhesive

Publications (1)

Publication Number Publication Date
WO2012113291A1 true WO2012113291A1 (zh) 2012-08-30

Family

ID=46721521

Family Applications (1)

Application Number Title Priority Date Filing Date
PCT/CN2012/071045 WO2012113291A1 (zh) 2010-03-03 2012-02-13 能增加云石胶韧性的添加剂

Country Status (9)

Country Link
US (1) US9371433B2 (zh)
EP (1) EP2679649A4 (zh)
CN (1) CN102181254B (zh)
AU (1) AU2012220248A1 (zh)
BR (1) BR112013021551A2 (zh)
CA (1) CA2828025C (zh)
RU (1) RU2013142862A (zh)
WO (1) WO2012113291A1 (zh)
ZA (1) ZA201306294B (zh)

Families Citing this family (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN102181254B (zh) * 2010-03-03 2015-08-12 武汉市科达云石护理材料有限公司 增韧云石胶组合物
CN108329878B (zh) * 2018-01-24 2020-08-14 武汉市科达云石护理材料有限公司 一种玉石胶及其生产方法
CN108410408B (zh) * 2018-03-19 2021-01-15 江苏大力士投资有限公司 一种高韧性云石胶及其制备方法
CN112391132B (zh) * 2020-11-05 2022-03-15 江苏大力士投资有限公司 一种延长云石胶存储期的方法

Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US6245822B1 (en) * 1998-04-27 2001-06-12 Matsushita Electric Industrial Co. Ltd. Method and apparatus for decomposition treating article having cured thermosetting resin
EP1225172A1 (en) * 1999-09-17 2002-07-24 Kansai Paint Co., Ltd. Polyorthoester and curable composition containing the same
EP1832566A1 (en) * 2006-03-06 2007-09-12 AIDICO, Asociación de Industrias de la Epoxy and unsaturated polyester adhesives in aqueous emulsion for consolidating natural stones
CN102181254A (zh) * 2010-03-03 2011-09-14 武汉市科达云石护理材料有限公司 能增加云石胶韧性的添加剂

Family Cites Families (7)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPH06239912A (ja) * 1993-02-18 1994-08-30 Nippon Shokubai Co Ltd 重合体の製造方法
US5460632A (en) * 1994-12-29 1995-10-24 Olin Corporation Low-foaming, enhanced wetting dye-leveling agent
FI982256A (fi) * 1998-10-19 2000-04-20 Neste Oyj Tyydyttymättömiä polyesterihartseja
US20040024144A1 (en) * 2000-09-14 2004-02-05 Robert Solomon Aqueous dispersions of comb copolymers and coatings produced therefrom
US6548157B2 (en) * 2001-01-04 2003-04-15 Safas Corporation Stone-like laminates
US6939922B2 (en) * 2001-03-30 2005-09-06 Rohm And Haas Company Coating and coating composition
CN101857790A (zh) * 2010-06-08 2010-10-13 武汉市科达云石护理材料有限公司 一种专用有色石材勾缝胶

Patent Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US6245822B1 (en) * 1998-04-27 2001-06-12 Matsushita Electric Industrial Co. Ltd. Method and apparatus for decomposition treating article having cured thermosetting resin
EP1225172A1 (en) * 1999-09-17 2002-07-24 Kansai Paint Co., Ltd. Polyorthoester and curable composition containing the same
EP1832566A1 (en) * 2006-03-06 2007-09-12 AIDICO, Asociación de Industrias de la Epoxy and unsaturated polyester adhesives in aqueous emulsion for consolidating natural stones
CN102181254A (zh) * 2010-03-03 2011-09-14 武汉市科达云石护理材料有限公司 能增加云石胶韧性的添加剂

Also Published As

Publication number Publication date
ZA201306294B (en) 2014-04-30
AU2012220248A1 (en) 2013-09-12
RU2013142862A (ru) 2015-04-10
BR112013021551A2 (pt) 2016-11-01
EP2679649A4 (en) 2018-01-17
CA2828025C (en) 2016-08-02
CN102181254A (zh) 2011-09-14
US9371433B2 (en) 2016-06-21
EP2679649A1 (en) 2014-01-01
US20130338285A1 (en) 2013-12-19
CA2828025A1 (en) 2012-08-30
CN102181254B (zh) 2015-08-12

Similar Documents

Publication Publication Date Title
CN101967354B (zh) 低白化α-氰基丙烯酸酯胶粘剂
WO2012113291A1 (zh) 能增加云石胶韧性的添加剂
CN106978107A (zh) 多用途高级强力粘结剂
CN103484040B (zh) 一种环保建筑免钉胶及其制备方法
CN103642428B (zh) 一种扬声器组装用防水胶黏剂及其制备方法
CN105153980B (zh) 一种耐盐雾的sbs胶粘剂及其制备方法
TW201226505A (en) Composition of eco-friendly hot melt adhesive
RU2014108439A (ru) Композиции цемента с высокой фотокаталитической активностью и улучшенной реологией
JP2019147925A (ja) 接着剤組成物
CN104356964A (zh) 一种低气味环保丙烯酸酯结构胶的制备
CN107880837A (zh) 抗冲击剥离型硅烷改性聚醚胶黏剂及其制备方法
TW201323550A (zh) 黏著劑組合物
CN103059653A (zh) 一种js防水涂料
CN105176486A (zh) 一种瓷复合绝缘子用胶黏剂及其制备方法
CN104403609B (zh) 高强度抗裂接缝剂
CN109232874A (zh) 环氧树脂改性的云石胶不饱和聚酯树脂及其制备方法和用途
CN108130024A (zh) 一种石墨烯粘贴防水卷材胶粉
US20130008342A1 (en) Glue stick formulated with naturally occurring polymers
CN102304336B (zh) Sbs万能胶
FR2966159B1 (fr) Colle aqueuse pour substrats cartonnes a prise amelioree
CN105802489A (zh) 玻璃防碎胶组合物及玻璃制品及应用
CN103897638A (zh) 一种强力丁基橡胶粘胶剂
CN102943556A (zh) 一种新型橡胶复合地板
CN109280493A (zh) 盾构管片用胶黏剂
CN109021864A (zh) 地毯用胶黏剂

Legal Events

Date Code Title Description
121 Ep: the epo has been informed by wipo that ep was designated in this application

Ref document number: 12749505

Country of ref document: EP

Kind code of ref document: A1

ENP Entry into the national phase

Ref document number: 2828025

Country of ref document: CA

NENP Non-entry into the national phase

Ref country code: DE

WWE Wipo information: entry into national phase

Ref document number: 2012749505

Country of ref document: EP

ENP Entry into the national phase

Ref document number: 2012220248

Country of ref document: AU

Date of ref document: 20120213

Kind code of ref document: A

ENP Entry into the national phase

Ref document number: 2013142862

Country of ref document: RU

Kind code of ref document: A

REG Reference to national code

Ref country code: BR

Ref legal event code: B01A

Ref document number: 112013021551

Country of ref document: BR

ENP Entry into the national phase

Ref document number: 112013021551

Country of ref document: BR

Kind code of ref document: A2

Effective date: 20130823