WO2012102554A3 - 빠른 흡착속도를 가지는 산소 선택성 흡착제 및 이의 제조방법 - Google Patents
빠른 흡착속도를 가지는 산소 선택성 흡착제 및 이의 제조방법 Download PDFInfo
- Publication number
- WO2012102554A3 WO2012102554A3 PCT/KR2012/000610 KR2012000610W WO2012102554A3 WO 2012102554 A3 WO2012102554 A3 WO 2012102554A3 KR 2012000610 W KR2012000610 W KR 2012000610W WO 2012102554 A3 WO2012102554 A3 WO 2012102554A3
- Authority
- WO
- WIPO (PCT)
- Prior art keywords
- oxygen
- selective adsorbent
- preparation
- preparing
- particles
- Prior art date
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- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 title abstract 9
- 229910052760 oxygen Inorganic materials 0.000 title abstract 9
- 239000001301 oxygen Substances 0.000 title abstract 9
- 239000003463 adsorbent Substances 0.000 title abstract 6
- 238000002360 preparation method Methods 0.000 title 1
- 238000001179 sorption measurement Methods 0.000 title 1
- 239000002245 particle Substances 0.000 abstract 3
- 229910000517 norsethite Inorganic materials 0.000 abstract 2
- 239000001095 magnesium carbonate Substances 0.000 abstract 1
- ZLNQQNXFFQJAID-UHFFFAOYSA-L magnesium carbonate Chemical compound [Mg+2].[O-]C([O-])=O ZLNQQNXFFQJAID-UHFFFAOYSA-L 0.000 abstract 1
- 229910000021 magnesium carbonate Inorganic materials 0.000 abstract 1
- VTHJTEIRLNZDEV-UHFFFAOYSA-L magnesium dihydroxide Chemical compound [OH-].[OH-].[Mg+2] VTHJTEIRLNZDEV-UHFFFAOYSA-L 0.000 abstract 1
- 239000000347 magnesium hydroxide Substances 0.000 abstract 1
- 229910001862 magnesium hydroxide Inorganic materials 0.000 abstract 1
Classifications
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J20/00—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof
- B01J20/02—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof comprising inorganic material
- B01J20/04—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof comprising inorganic material comprising compounds of alkali metals, alkaline earth metals or magnesium
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J20/00—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof
- B01J20/02—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof comprising inorganic material
- B01J20/04—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof comprising inorganic material comprising compounds of alkali metals, alkaline earth metals or magnesium
- B01J20/041—Oxides or hydroxides
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D53/00—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols
- B01D53/02—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols by adsorption, e.g. preparative gas chromatography
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J20/00—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof
- B01J20/02—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof comprising inorganic material
- B01J20/04—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof comprising inorganic material comprising compounds of alkali metals, alkaline earth metals or magnesium
- B01J20/043—Carbonates or bicarbonates, e.g. limestone, dolomite, aragonite
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J20/00—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof
- B01J20/30—Processes for preparing, regenerating, or reactivating
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J20/00—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof
- B01J20/30—Processes for preparing, regenerating, or reactivating
- B01J20/3078—Thermal treatment, e.g. calcining or pyrolizing
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J20/00—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof
- B01J20/30—Processes for preparing, regenerating, or reactivating
- B01J20/32—Impregnating or coating ; Solid sorbent compositions obtained from processes involving impregnating or coating
- B01J20/3291—Characterised by the shape of the carrier, the coating or the obtained coated product
- B01J20/3293—Coatings on a core, the core being particle or fiber shaped, e.g. encapsulated particles, coated fibers
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- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
- C01B13/00—Oxygen; Ozone; Oxides or hydroxides in general
- C01B13/02—Preparation of oxygen
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- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01F—COMPOUNDS OF THE METALS BERYLLIUM, MAGNESIUM, ALUMINIUM, CALCIUM, STRONTIUM, BARIUM, RADIUM, THORIUM, OR OF THE RARE-EARTH METALS
- C01F11/00—Compounds of calcium, strontium, or barium
- C01F11/02—Oxides or hydroxides
- C01F11/04—Oxides or hydroxides by thermal decomposition
- C01F11/06—Oxides or hydroxides by thermal decomposition of carbonates
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- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01F—COMPOUNDS OF THE METALS BERYLLIUM, MAGNESIUM, ALUMINIUM, CALCIUM, STRONTIUM, BARIUM, RADIUM, THORIUM, OR OF THE RARE-EARTH METALS
- C01F11/00—Compounds of calcium, strontium, or barium
- C01F11/18—Carbonates
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D2251/00—Reactants
- B01D2251/40—Alkaline earth metal or magnesium compounds
- B01D2251/402—Alkaline earth metal or magnesium compounds of magnesium
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D2251/00—Reactants
- B01D2251/40—Alkaline earth metal or magnesium compounds
- B01D2251/408—Alkaline earth metal or magnesium compounds of barium
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D2251/00—Reactants
- B01D2251/60—Inorganic bases or salts
- B01D2251/602—Oxides
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D2251/00—Reactants
- B01D2251/60—Inorganic bases or salts
- B01D2251/606—Carbonates
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D2253/00—Adsorbents used in seperation treatment of gases and vapours
- B01D2253/10—Inorganic adsorbents
- B01D2253/112—Metals or metal compounds not provided for in B01D2253/104 or B01D2253/106
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D2257/00—Components to be removed
- B01D2257/10—Single element gases other than halogens
- B01D2257/104—Oxygen
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D2258/00—Sources of waste gases
- B01D2258/06—Polluted air
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J2220/00—Aspects relating to sorbent materials
- B01J2220/40—Aspects relating to the composition of sorbent or filter aid materials
- B01J2220/42—Materials comprising a mixture of inorganic materials
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- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01P—INDEXING SCHEME RELATING TO STRUCTURAL AND PHYSICAL ASPECTS OF SOLID INORGANIC COMPOUNDS
- C01P2002/00—Crystal-structural characteristics
- C01P2002/70—Crystal-structural characteristics defined by measured X-ray, neutron or electron diffraction data
- C01P2002/72—Crystal-structural characteristics defined by measured X-ray, neutron or electron diffraction data by d-values or two theta-values, e.g. as X-ray diagram
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01P—INDEXING SCHEME RELATING TO STRUCTURAL AND PHYSICAL ASPECTS OF SOLID INORGANIC COMPOUNDS
- C01P2002/00—Crystal-structural characteristics
- C01P2002/80—Crystal-structural characteristics defined by measured data other than those specified in group C01P2002/70
- C01P2002/88—Crystal-structural characteristics defined by measured data other than those specified in group C01P2002/70 by thermal analysis data, e.g. TGA, DTA, DSC
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- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01P—INDEXING SCHEME RELATING TO STRUCTURAL AND PHYSICAL ASPECTS OF SOLID INORGANIC COMPOUNDS
- C01P2004/00—Particle morphology
- C01P2004/01—Particle morphology depicted by an image
- C01P2004/03—Particle morphology depicted by an image obtained by SEM
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- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Analytical Chemistry (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Inorganic Chemistry (AREA)
- Thermal Sciences (AREA)
- Life Sciences & Earth Sciences (AREA)
- Physics & Mathematics (AREA)
- Geology (AREA)
- Engineering & Computer Science (AREA)
- General Chemical & Material Sciences (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Solid-Sorbent Or Filter-Aiding Compositions (AREA)
Abstract
본 발명은 공기 중의 산소를 선택적으로 흡착하는 산소 선택성 흡착제의 제조방법으로서, BaMg(CO3)2입자 또는 BaMg(CO3)2의 외부에 MgCO3 또는 Mg(OH)2가 부착된 입자를 제조하는 단계 및 상기 입자를 고온 소성하는 단계를 포함하는 것을 특징으로 하는 산소 선택성 흡착제의 제조방법 및 이에 따라 제조된 산소 선택성 흡착제를 제공한다.본 발명에 따른 산소 선택성 흡착제는 종래의 산소 선택성 흡착제보다 공기 중의 산소를 빠른 속도로 흡착시키면서도 높은 열적 안정성 및 우수한 산소 흡착능을 나타낸다.
Priority Applications (2)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
US13/980,094 US9192911B2 (en) | 2011-01-26 | 2012-01-26 | Oxygen-selective adsorbent having fast adsorption rate and preparation method thereof |
EP12739507.7A EP2669003B1 (en) | 2011-01-26 | 2012-01-26 | Preparation method of an oxygen-selective adsorbent having fast adsorption rate |
Applications Claiming Priority (2)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
KR10-2011-0007915 | 2011-01-26 | ||
KR1020110007915A KR101189593B1 (ko) | 2011-01-26 | 2011-01-26 | 빠른 흡착속도를 가지는 산소 선택성 흡착제 및 이의 제조방법 |
Publications (2)
Publication Number | Publication Date |
---|---|
WO2012102554A2 WO2012102554A2 (ko) | 2012-08-02 |
WO2012102554A3 true WO2012102554A3 (ko) | 2012-09-20 |
Family
ID=46581288
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
PCT/KR2012/000610 WO2012102554A2 (ko) | 2011-01-26 | 2012-01-26 | 빠른 흡착속도를 가지는 산소 선택성 흡착제 및 이의 제조방법 |
Country Status (4)
Country | Link |
---|---|
US (1) | US9192911B2 (ko) |
EP (1) | EP2669003B1 (ko) |
KR (1) | KR101189593B1 (ko) |
WO (1) | WO2012102554A2 (ko) |
Families Citing this family (7)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US7810743B2 (en) | 2006-01-23 | 2010-10-12 | Kimberly-Clark Worldwide, Inc. | Ultrasonic liquid delivery device |
US9283188B2 (en) * | 2006-09-08 | 2016-03-15 | Kimberly-Clark Worldwide, Inc. | Delivery systems for delivering functional compounds to substrates and processes of using the same |
KR101499694B1 (ko) | 2013-06-28 | 2015-03-11 | 한국에너지기술연구원 | 탈착이 용이한 산소 선택성 흡착제 및 이의 제조방법 |
US11167260B2 (en) | 2013-06-28 | 2021-11-09 | Korea Institute Of Energy Research | Oxygen selective adsorbent for easy desorption and preparation method thereof |
KR101554496B1 (ko) * | 2013-06-28 | 2015-09-22 | 한국에너지기술연구원 | 산소 선택성 흡착제 및 이의 제조방법 |
KR101470594B1 (ko) * | 2013-11-22 | 2014-12-10 | (주)제이원텍 | 유기발광소자 봉지공정의 인라인 질소정화시스템용 촉매 조성물의 제조방법 |
KR101589559B1 (ko) * | 2014-09-17 | 2016-01-29 | 한국에너지기술연구원 | 고압 수소 소성을 이용한 산화물계 산소 선택성 흡착제 제조방법 |
Citations (4)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US5135548A (en) * | 1991-05-08 | 1992-08-04 | Air Products And Chemicals, Inc. | Oxygen selective desiccants |
US5478543A (en) * | 1993-06-21 | 1995-12-26 | Santoku Metal Industry Co., Ltd. | Compound oxide having oxygen absorbing and desorbing capability and method for preparing same |
US5536302A (en) * | 1994-03-23 | 1996-07-16 | Air Products And Chemicals, Inc. | Adsorbent for removal of trace oxygen from inert gases |
JPH1085589A (ja) * | 1996-09-18 | 1998-04-07 | Tosoh Corp | 空気分離用吸着剤、及びそれを用いた酸素ガス製造方法 |
Family Cites Families (4)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US3324654A (en) * | 1966-09-29 | 1967-06-13 | Arthur M Squires | Method and apparatus for producing oxygen and power |
US3773680A (en) | 1972-04-07 | 1973-11-20 | Cons Natural Gas Svc | Acceptor compositions and method for oxygen enrichment processes |
US3903010A (en) | 1972-08-03 | 1975-09-02 | Cons Natural Gas Svc | Preparation of oxygen acceptor compositions and oxygen production process |
US4092264A (en) | 1976-12-27 | 1978-05-30 | The Bendix Corporation | Barium oxide coated zirconia particle for use in an oxygen extractor |
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2011
- 2011-01-26 KR KR1020110007915A patent/KR101189593B1/ko active IP Right Grant
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2012
- 2012-01-26 EP EP12739507.7A patent/EP2669003B1/en active Active
- 2012-01-26 WO PCT/KR2012/000610 patent/WO2012102554A2/ko active Application Filing
- 2012-01-26 US US13/980,094 patent/US9192911B2/en active Active
Patent Citations (4)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US5135548A (en) * | 1991-05-08 | 1992-08-04 | Air Products And Chemicals, Inc. | Oxygen selective desiccants |
US5478543A (en) * | 1993-06-21 | 1995-12-26 | Santoku Metal Industry Co., Ltd. | Compound oxide having oxygen absorbing and desorbing capability and method for preparing same |
US5536302A (en) * | 1994-03-23 | 1996-07-16 | Air Products And Chemicals, Inc. | Adsorbent for removal of trace oxygen from inert gases |
JPH1085589A (ja) * | 1996-09-18 | 1998-04-07 | Tosoh Corp | 空気分離用吸着剤、及びそれを用いた酸素ガス製造方法 |
Also Published As
Publication number | Publication date |
---|---|
US20130299737A1 (en) | 2013-11-14 |
KR20120099316A (ko) | 2012-09-10 |
KR101189593B1 (ko) | 2012-10-12 |
EP2669003A2 (en) | 2013-12-04 |
WO2012102554A2 (ko) | 2012-08-02 |
US9192911B2 (en) | 2015-11-24 |
EP2669003B1 (en) | 2019-01-23 |
EP2669003A4 (en) | 2017-12-20 |
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