WO2012093878A4 - Compositions répulsives pour arthropodes hématophages - Google Patents

Compositions répulsives pour arthropodes hématophages Download PDF

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Publication number
WO2012093878A4
WO2012093878A4 PCT/KR2012/000133 KR2012000133W WO2012093878A4 WO 2012093878 A4 WO2012093878 A4 WO 2012093878A4 KR 2012000133 W KR2012000133 W KR 2012000133W WO 2012093878 A4 WO2012093878 A4 WO 2012093878A4
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WO
WIPO (PCT)
Prior art keywords
vanillin
composition
plant essential
essential oil
arthropod
Prior art date
Application number
PCT/KR2012/000133
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English (en)
Korean (ko)
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WO2012093878A3 (fr
WO2012093878A2 (fr
Inventor
이성화
안용준
권형욱
박형호
김순일
Original Assignee
엘지전자 주식회사
서울대학교 산학협력단
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Priority claimed from KR1020120001336A external-priority patent/KR101430492B1/ko
Application filed by 엘지전자 주식회사, 서울대학교 산학협력단 filed Critical 엘지전자 주식회사
Priority to RU2013132015/10A priority Critical patent/RU2542485C1/ru
Priority to BR112013017173A priority patent/BR112013017173A2/pt
Publication of WO2012093878A2 publication Critical patent/WO2012093878A2/fr
Publication of WO2012093878A3 publication Critical patent/WO2012093878A3/fr
Publication of WO2012093878A4 publication Critical patent/WO2012093878A4/fr

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    • A—HUMAN NECESSITIES
    • A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N35/00—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom having two bonds to hetero atoms with at the most one bond to halogen, e.g. aldehyde radical
    • A01N35/04—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom having two bonds to hetero atoms with at the most one bond to halogen, e.g. aldehyde radical containing aldehyde or keto groups, or thio analogues thereof, directly attached to an aromatic ring system, e.g. acetophenone; Derivatives thereof, e.g. acetals
    • A—HUMAN NECESSITIES
    • A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N25/00—Biocides, pest repellants or attractants, or plant growth regulators, characterised by their forms, or by their non-active ingredients or by their methods of application, e.g. seed treatment or sequential application; Substances for reducing the noxious effect of the active ingredients to organisms other than pests
    • A01N25/08—Biocides, pest repellants or attractants, or plant growth regulators, characterised by their forms, or by their non-active ingredients or by their methods of application, e.g. seed treatment or sequential application; Substances for reducing the noxious effect of the active ingredients to organisms other than pests containing solids as carriers or diluents

Definitions

  • the present invention relates to a perspiration composition for an arthropod, which comprises a plant essential oil and vanillin, and is used as a vasculogenic arthropod for improving evapotranspiration against arteriosclerotic animals such as mosquitoes, To an animal repellent composition.
  • the vampire arthropods are very diverse, including mosquito, tick, fly (stable fly, tsetsefly), horse fly (bed fly) and bed bug.
  • mosquitoes which are the most important sites for blood-circulating arthropods, are the main mediators of malaria, including dengue fever, yellow fever, encephalitis and West Nile virus, affecting more than 300 million to 500 million people annually. Death is causing serious harm to more than 1 million people annually (Rozendaal, JA 1997. WHO Geneva, Switzerland.:http://www.who.int/water_sanitation_health / resources / vectorcontrol / en /).
  • repellents have been developed for vasodilated arthropods. These repellents are known to be the most effective means of preventing humans and livestock from vomiting by life-threatening insects (Curtis, CF, JD Lives, LU Baolib, and A. Renz 1990. Natural and synthetic repellents, 92. In CF Curtis [ed.], Appropriate technology in vector control. CRC Press, Boca Raton, FL .; Isman, M. B. 2006. Botanical insecticides, deterrents, and repellents in modern agriculture and increasingly regulated world. Annu. Rev. Entomol. 51: 45-66).
  • Plant essential oils are useful for plants because they contain a variety of bioactive materials and have relatively little impact on the environment and organisms and are relatively inexpensive compared to plant extracts.
  • the blood-sucking arthropod sensitive composition according to the present invention is characterized by comprising plant essential oil and vanillin.
  • a porous carrier comprising a blood-sucking arthropod catheter composition according to the present invention.
  • an apparatus for generating an avian influenza agent for arthropod according to the present invention.
  • the cage forms a frame with an iron frame, the material treatment zone 1 and the radiation cage 3 located at both ends are wrapped with a polyester net, and the centerless untreated zone 2 is wrapped with an acrylic plate.
  • the holes in the polyester net are illustrative and not proportional to the picture, and are small enough that the mosquito can not escape.
  • FIG. 2 is an illustration of a module comprising a bead preparation made in accordance with the present invention.
  • the blood-sucking arthropod detonator composition according to the present invention comprises plant essential oil and vanillin.
  • the blood-sucking arthropods to which the repellent composition of the present invention can be applied refers to all living things that take blood or body fluids from the skin of a mammal or bird, such as mosquitoes, insects, swallow flies, Flies, lobsters, lobsters, and the like.
  • the plant essential oil used in the present invention can be used without any particular limitation as long as it is known as a repellent for a vasodilated arthropod.
  • a repellent for a vasodilated arthropod Preferably it cinnamoyl stop Cassia (Cinnamomum cassia), rosemary bonus operational during the day lease (Rosmarinus officinalis), Eucalyptus tooth sheet Rio Dorado (Eucalyptus citriodora), crooked pogon Citra tooth (Cimbopogon citratus), jantok silreom Armadillo Tomb (Zanthoxylum armatum ), Cymbopogon nardus , and the like.
  • the plant essential oil of the present invention obtained from the above plants can be obtained by a cold precipitation method using a conventional solvent such as water, ethanol, acetone, methanol, propanol, ether, hexane, ethyl acetate, chloroform or a mixed solvent thereof, May be obtained by using one of the methods such as an immersion method, a hydrothermal extraction method (electronic method), a fermentation extraction method, a filtration leaching method, a supercritical fluid extraction method and the like, and more preferably, obtained by a steam distillation method. It may also be obtained from plant parts, such as roots, stems, leaves, flesh, flowers, fruits, seeds, and / or shells, respectively, or from whole plants.
  • a conventional solvent such as water, ethanol, acetone, methanol, propanol, ether, hexane, ethyl acetate, chloroform or a mixed solvent thereof
  • a conventional solvent such as water, ethanol, acetone,
  • the vanillin used in the present invention is 4-hydroxy-3-methoxybenzaldehyde as one of vanilla-flavored aromatic aldehydes.
  • a commercially available product can be purchased and used.
  • various substances have been known in connection with the pleure agent for blood-circulating arthropods, but vanillin is not known as an insect repellent agent.
  • the blood-sucking arthropod sensitive compositions according to the present invention are suitable for use in the production of cinnamomum cassia , Rosmarinus officinalis , Eucalyptus citriodora , Cimbopogon citratus, ), Zanthoxylum armatum , and Cymbopogon nardus , and vanillin.
  • the present invention also provides a method for producing a plant extract of the present invention.
  • the composition ratio of plant essential oil to vanillin is not particularly limited, but it is preferable that the weight ratio of (1 to 3): (1 to 3) is in view of solubility in solvents and mutual mixing.
  • the perspirant composition for vodka arthropod according to the present invention may contain two plant essential oils and vanillin.
  • plant essential oil composition ratio of another plant essential oil: vanillin is ): (1 to 3): (1 to 3) (v / v / w). (V / v / w) of 1: 1: 1, 3: 1: 1, 1: 3: 1, 1: 1: 3 or 8.5: 8.5: 3.
  • the blood-sucking faecal composition for arthropod according to the present invention may be formulated by further containing suitable additives, excipients or carriers depending on the purpose of use and application environment.
  • suitable additives excipients or carriers depending on the purpose of use and application environment.
  • the emulsifier include emulsions, emulsifiers, wetting agents, water-soluble agents, aerosols, pump sprayers, suspensions, ULV (Ultra Low Volume) preparations, handmade, granules, powders, powders, granules, capsules, Beads, tablets, extracts, fluid extracts, lotions, mets, and the like.
  • a cream, pump spray or aerosol formulation Preferably as a cream, pump spray or aerosol formulation.
  • the perspirant composition for vodka arthropod according to the present invention can be applied to a porous carrier for sustained release.
  • the porous carrier used herein is not particularly limited, and examples thereof include charcoal, silica gel, diatomaceous earth, and the like.
  • the porous carrier may be a gel formed to contain micropores by bonding between units constituting the polymer, or a viscopearl (Rengo, Tokyo, Japan) produced by pressing a polymer or polymer fiber .
  • the biscarprins provide excellent porosity and are thus suitable for the gradual release of the blood-borne arthropod crainer compositions according to the invention.
  • the route of application of the blood-sucking arthropods composition according to the present invention may be, but is not limited to, direct dispersal or distribution of the repellent composition in the area where blood-borne arthropods predominantly occur, It can be used directly on the skin of birds, or it can be applied to daily necessities such as clothes, bags, bands, tents, and indoors.
  • a porous carrier that continuously discharges the repellent composition can be mounted.
  • a capsule containing the repellent composition When the capsule is applied to daily necessities, a capsule containing the repellent composition is prepared, and the repellent composition, which is supported when the capsule is rubbed by friction, is added to the air It is possible to use it so that it emits an eruptive power or it is directly mixed and then gradually released into the air.
  • a repellent composition according to the present invention may be supported on a porous carrier. At this time, if the indicator is included in the device for gradually discharging the repellent composition, if the repellent composition as an effective substance is completely volatized, the service life can be displayed by, for example, discoloration.
  • the blood-sucking faecal composition for arthropod according to the present invention can also be applied to household appliances such as air purifiers, air conditioners, and air conditioners.
  • household appliances such as air purifiers, air conditioners, and air conditioners.
  • the application to such household appliances can be appropriately modified according to a conventional method.
  • the air purifier, the air conditioner, the air conditioner, or the like has a function of convecting the air inside the house, it is possible to cause the vapor permeable disposable diaper composition according to the present invention to dissipate in the purified air Especially useful.
  • Cinnamoyl stop Cassia (Cinnamomum cassia), rosemary bonus operational during the day lease (Rosmarinus officinalis), Eucalyptus tooth sheet Rio Dorado (Eucalyptus citriodora), crooked pogon Citra tooth (Cimbopogon citratus), crooked pogon Carry Traders (Cimbopogon nardus) and vanillin was purchased from Berje, Bloomfield, NJ, and Zanthoxylum armatum was purchased from Seema International, Deli, India. DEET was purchased from Sigma-Aldrich (St. Louis, Mo.).
  • One of the above-mentioned materials selected from plant essential oils and vanillin were dissolved in ethanol to prepare a composition.
  • the plant essential oil and vanillin were mixed at a ratio of 5%: 5% (v / w) and 5%: 15% (v / w) respectively and dissolved in ethanol to obtain a final 100 ⁇ l of each composition.
  • cymopogon ganoderma and zanthoxylum armatum and vanillin were prepared at a ratio of 8.5: 8.5: 3, with a ratio of eucalyptus citriodora, zanthoxylum armatum and vanillin of 8.5: 8.5: 3 (v / v / w).
  • Aegypti for the test was induced by direct immersion in the mouse with adult insects exposed to insecticide for several years without any exposure to pesticides, resulting in 10% (w / v) sugar water To obtain insufficient carbohydrates.
  • the larvae were placed in plastic trays (24 ⁇ 35 ⁇ 5 cm) to provide 0.5 g sterile artificial food (40-mesh cheese feed powder / yeast, 4: 1, w / w). These were kept at 26 ⁇ 2 ° C and 70 ⁇ 5% relative humidity, and the contrast was maintained at 16: 8 hours.
  • the composition obtained in the preparation of the material was uniformly applied to the surface of the skin of the tester exposed to a hole with a diameter of 5 cm in the back of a rubber glove to perform a skin test.
  • Trial men were healthy 21-40 year old men.
  • the control group treated only 100 ⁇ ⁇ of ethanol.
  • the complete avoidance duration was between the time of treatment and the time of the first blood vomiting, and a general linear analysis (GLM) was performed for the comparison between treatment averages.
  • GLM general linear analysis
  • Table 1 shows the complete repellency time (CPT) for the plant essential oils and the birds of Vanillin and plant essential oils and vanillin for the Egyptian mosquito adults. As controls, the complete repulsion duration (CPT) for the Egyptian mosquito adults of DEET alone is also described.
  • Table 2 shows the results of complete repulsive time (CPT) for two species of plant essential oils and vanillin composition for the Egyptian mosquito adults.
  • the CPT was 75 minutes in the case of 5% Shinnamomukkasia alone, 30 minutes in the Simbo fogon sheet Latatus and Zanthoxylum Armatum, and 22.5 minutes in the Eucalyptus triiodora and vanillin, respectively. 15 minutes, Rosemary nasal opisinaris did not show any effect. On the other hand, DEET showed the strongest evasive force at 127.5 minutes and improved to 15% at 247.5 minutes. On the other hand, as can be seen from the above Table 1, it can be seen that the composition including the plant essential oil and vanillin improves the synergistic effect as compared with the case of using each alone.
  • a repellent composition according to the present invention was prepared by mixing two plant essential oils and vanillin, and the same experiment was carried out. The results are shown in Table 2.
  • Table 2 Group a CPT average (range, minutes) 1: 1: 1 3: 1: 1 1: 3: 1 1: 1: 3 A 105 (90-120) 165 (150-180) 165 (120-210) 165 (150-180) B 142.5 (90-180) 82.5 (60-120) 150 (150) 240 (210-300) C 150 (120-180) 210 (180-240) 270 (210-330) 240 (180-300) D 140 (110-170) 200 (170-230) 240 (180-300) 220 (150-290)
  • Group B is Eucalyptus citriodora: Zanthoxum Armatumum: Vanillin
  • Group C is Shimbo Fogon Sheet Latous: Zanthoxum Armatumum: Vanillin
  • Group D is Shimbo Fogon Narders: Zanthox Samrum Armatum: Vanillin
  • the two plant essential oils and the vanillin blend exhibited far superior evacuation (CPT) than the single oil and vanillin blend. It can be seen that this effect produces synergies more than the increase in repelling duration by simple mixing of the constituents of these compositions. That is, the 1: 1: 1 standard values of the composition components obtained from the results of Table 2 were compared based on the CPT. 15 minutes, the experimental results obtained from the actual composition of Table 2 above are about 105 times more than the expected value, which is about twice the expected value. That is, it was confirmed that the detergent composition for vampire arthropod according to the present invention has a synergistic effect due to mixing of two plant essential oils and vanillin.
  • This test is intended to test whether mosquitoes enter the treatment area through a thick cardboard (building window) with a 10 cm hole in the middle, lying as a wall in the center of the test system. In addition, this test is intended to test an average blocking power of the bead formulation over time.
  • the test cage comprises a material frame 1, a non-treatment zone 2 and a radiation cage 3 with steel frames, the material treatment zone 1 and the radiation cage 3 are wrapped with a polyester net, (2) is an acrylic plate.
  • a thick cardboard was drilled with a 10 cm diameter hole.
  • the mouth and the bead treated with the repellent composition according to the present invention were placed in the material processing zone 1 before the start of the test so that they could not be immobilized by immobilizing one mouse as a mosquito ape in the material processing zone 1, .
  • the wastes treated with the composition were naturally dried for 1 minute, fixed to the upper end of the material treatment zone 1 by spatting and allowed to volatilize for 3 minutes. Thereafter, the adult female mosquitoes of the Egyptian forest prepared in the spinning cage 3 were spun. In this test, the natural movement flow of the mosquito is the material treatment zone (1) from the mosquito radiation cage (3).
  • the average rate of blocking the entry of mosquitoes into the material treatment zone 1 was calculated using the following equation:
  • the composition prepared in the composition ratio shown in Table 3 was directly treated on the foliar paper to examine the mosquito inflow inhibiting power into the treatment area. As a result, it was found that after 120 minutes from the test, the eucalyptus citriodora: At a ratio of 3: 1: 1, was able to inhibit penetration of 80% or more of mosquitoes except for the case where the composition was treated in a foliar condition.
  • a chamber test was conducted to determine the erodibility of the composition of the present invention in a large space.
  • the chamber (1.2 X 1.2 X 1.2 m) used for the test was made of an iron plate covered with an acrylic plate and a square hole (20 X 20 cm) was installed at the bottom of the front. The square hole was closed with a black cardboard with ten holes (each hole 1.5 x 1.5 cm).
  • a mosquito radiation cage (25 x 25 x 25 cm) was connected to the square hole.
  • Another collection cage was placed in the chamber. The spinning cage and the collection cage were connected by a card board, all wrapped in a polyester net.
  • a fan (model name: EFB-2-3, Hanil, Korea) was operated to promote the diffusion of components.
  • the bead agent is the same as that used in the cage test method.
  • the composition to be supported on the bead agent is a composition (using ethanol as a solvent) prepared by mixing Simpol Vorton sheet LatouszanthoxamineArmatum: vanillin at a ratio of 8.5: 8.5: 3 (v / v / w).
  • a module having the shape shown in FIG. 2 was manufactured for this experiment. Ten holes are formed in the module to control opening and closing and each of the holes contains the same amount of beads so that a total of about 10 to 11 g of beads is contained in one module, To 5.4 g of the composition is carried.
  • composition of the present invention having an excellent repellency of the mosquito repellent according to the present invention in a wide space and in particular a sympathetic fomentate sheet
  • Latouszanthoxylumarmatumum vanillin 8.5: 8.5: 3 (v / v / w) It can be confirmed that it is excellent in releasing force.
  • the total rejection rate is 83% or more and the rejection rate is 70% or more for a minimum of 60 minutes.
  • the sustainability period of the ephemeris of the blood-borne arthropod disposable composition according to the present invention was measured by an accelerated test.
  • the blood-borne arthropod disposable detergent composition is used on an average of about 8 hours a day.
  • the number of holes through which mosquitoes can move on the walls of the chamber used in the chamber test is 10, And the number of holes in the wall of the inner wall was 40.
  • the effect of the repulsive force over time after running for 8 days under the above conditions was measured.

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  • Life Sciences & Earth Sciences (AREA)
  • General Health & Medical Sciences (AREA)
  • Health & Medical Sciences (AREA)
  • Wood Science & Technology (AREA)
  • Plant Pathology (AREA)
  • Engineering & Computer Science (AREA)
  • Dentistry (AREA)
  • Agronomy & Crop Science (AREA)
  • Zoology (AREA)
  • Environmental Sciences (AREA)
  • Pest Control & Pesticides (AREA)
  • Toxicology (AREA)
  • Agricultural Chemicals And Associated Chemicals (AREA)

Abstract

La présente invention concerne une composition répulsive pour arthropodes hématophages. La composition répulsive comprend de la vanilline et un ou deux types d'huiles essentielles choisies dans l'ensemble consistant en Cinnamomum cassia, Rosmarinus officinalis, Eucalyptus citriodora, Cimbopogon citratus, Zanthoxylum armatum, et Cimbopogon nardus. Ainsi, la répulsion des arthropodes hématophages est améliorée et la durée de la répulsion est augmentée. En outre, l'invention concerne un véhicule poreux contenant la composition répulsive contre les arthropodes hématophages, et un appareil produisant le répulsif.
PCT/KR2012/000133 2011-01-06 2012-01-06 Compositions répulsives pour arthropodes hématophages WO2012093878A2 (fr)

Priority Applications (2)

Application Number Priority Date Filing Date Title
RU2013132015/10A RU2542485C1 (ru) 2011-01-06 2012-01-06 Репеллентная композиция для отпугивания кровососущих членистоногих
BR112013017173A BR112013017173A2 (pt) 2011-01-06 2012-01-06 composição repelente para artrópodes hematófagos, veículo poroso e aparelho de descarregamento de repelente

Applications Claiming Priority (4)

Application Number Priority Date Filing Date Title
KR20110001439 2011-01-06
KR10-2011-0001439 2011-01-06
KR1020120001336A KR101430492B1 (ko) 2011-01-06 2012-01-05 흡혈성 절지 동물용 기피제 조성물
KR10-2012-0001336 2012-01-05

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WO2012093878A2 WO2012093878A2 (fr) 2012-07-12
WO2012093878A3 WO2012093878A3 (fr) 2012-11-29
WO2012093878A4 true WO2012093878A4 (fr) 2013-01-17

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CN103548897B (zh) * 2013-10-24 2015-11-18 湖南中烟工业有限责任公司 一种防治烟青虫的植物源农药及其应用

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KR100478139B1 (ko) * 2004-05-31 2005-03-21 주식회사 내츄로바이오텍 모기, 개미, 진드기, 바퀴벌레 및 저장물 해충에 대한살충성 조성물
KR20100057135A (ko) * 2008-11-21 2010-05-31 주식회사 엘지생활건강 해충기피효과를 갖는 정유성분을 포함하는 자외선 차단 화장료 조성물
KR100955344B1 (ko) * 2009-05-22 2010-04-29 주식회사 내츄로바이오텍 잔톡실럼속 정유를 유효성분으로 함유하는 천연 기피제

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