WO2012052125A1 - Procédé de transport d'hydrogène par une conduite de gaz naturel - Google Patents

Procédé de transport d'hydrogène par une conduite de gaz naturel Download PDF

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Publication number
WO2012052125A1
WO2012052125A1 PCT/EP2011/005100 EP2011005100W WO2012052125A1 WO 2012052125 A1 WO2012052125 A1 WO 2012052125A1 EP 2011005100 W EP2011005100 W EP 2011005100W WO 2012052125 A1 WO2012052125 A1 WO 2012052125A1
Authority
WO
WIPO (PCT)
Prior art keywords
hydrogen
natural gas
line
gas line
partially
Prior art date
Application number
PCT/EP2011/005100
Other languages
German (de)
English (en)
Inventor
Dragan Griebel
Anton FÖRTIG
Original Assignee
Rehau Ag + Co
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Rehau Ag + Co filed Critical Rehau Ag + Co
Priority to EP11770703.4A priority Critical patent/EP2630401A1/fr
Publication of WO2012052125A1 publication Critical patent/WO2012052125A1/fr

Links

Classifications

    • F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F16—ENGINEERING ELEMENTS AND UNITS; GENERAL MEASURES FOR PRODUCING AND MAINTAINING EFFECTIVE FUNCTIONING OF MACHINES OR INSTALLATIONS; THERMAL INSULATION IN GENERAL
    • F16L—PIPES; JOINTS OR FITTINGS FOR PIPES; SUPPORTS FOR PIPES, CABLES OR PROTECTIVE TUBING; MEANS FOR THERMAL INSULATION IN GENERAL
    • F16L9/00—Rigid pipes
    • F16L9/18—Double-walled pipes; Multi-channel pipes or pipe assemblies
    • F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F16—ENGINEERING ELEMENTS AND UNITS; GENERAL MEASURES FOR PRODUCING AND MAINTAINING EFFECTIVE FUNCTIONING OF MACHINES OR INSTALLATIONS; THERMAL INSULATION IN GENERAL
    • F16L—PIPES; JOINTS OR FITTINGS FOR PIPES; SUPPORTS FOR PIPES, CABLES OR PROTECTIVE TUBING; MEANS FOR THERMAL INSULATION IN GENERAL
    • F16L1/00—Laying or reclaiming pipes; Repairing or joining pipes on or under water
    • F16L1/024—Laying or reclaiming pipes on land, e.g. above the ground
    • F16L1/028—Laying or reclaiming pipes on land, e.g. above the ground in the ground
    • F16L1/032—Laying or reclaiming pipes on land, e.g. above the ground in the ground the pipes being continuous
    • F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F16—ENGINEERING ELEMENTS AND UNITS; GENERAL MEASURES FOR PRODUCING AND MAINTAINING EFFECTIVE FUNCTIONING OF MACHINES OR INSTALLATIONS; THERMAL INSULATION IN GENERAL
    • F16L—PIPES; JOINTS OR FITTINGS FOR PIPES; SUPPORTS FOR PIPES, CABLES OR PROTECTIVE TUBING; MEANS FOR THERMAL INSULATION IN GENERAL
    • F16L11/00—Hoses, i.e. flexible pipes
    • F16L11/20—Double-walled hoses, i.e. two concentric hoses
    • F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F17—STORING OR DISTRIBUTING GASES OR LIQUIDS
    • F17D—PIPE-LINE SYSTEMS; PIPE-LINES
    • F17D1/00—Pipe-line systems
    • F17D1/02—Pipe-line systems for gases or vapours
    • F17D1/04—Pipe-line systems for gases or vapours for distribution of gas
    • F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F16—ENGINEERING ELEMENTS AND UNITS; GENERAL MEASURES FOR PRODUCING AND MAINTAINING EFFECTIVE FUNCTIONING OF MACHINES OR INSTALLATIONS; THERMAL INSULATION IN GENERAL
    • F16L—PIPES; JOINTS OR FITTINGS FOR PIPES; SUPPORTS FOR PIPES, CABLES OR PROTECTIVE TUBING; MEANS FOR THERMAL INSULATION IN GENERAL
    • F16L11/00—Hoses, i.e. flexible pipes
    • F16L11/04—Hoses, i.e. flexible pipes made of rubber or flexible plastics
    • F16L2011/047—Hoses, i.e. flexible pipes made of rubber or flexible plastics with a diffusion barrier layer
    • F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F17—STORING OR DISTRIBUTING GASES OR LIQUIDS
    • F17C—VESSELS FOR CONTAINING OR STORING COMPRESSED, LIQUEFIED OR SOLIDIFIED GASES; FIXED-CAPACITY GAS-HOLDERS; FILLING VESSELS WITH, OR DISCHARGING FROM VESSELS, COMPRESSED, LIQUEFIED, OR SOLIDIFIED GASES
    • F17C2221/00—Handled fluid, in particular type of fluid
    • F17C2221/01—Pure fluids
    • F17C2221/012—Hydrogen
    • F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F17—STORING OR DISTRIBUTING GASES OR LIQUIDS
    • F17C—VESSELS FOR CONTAINING OR STORING COMPRESSED, LIQUEFIED OR SOLIDIFIED GASES; FIXED-CAPACITY GAS-HOLDERS; FILLING VESSELS WITH, OR DISCHARGING FROM VESSELS, COMPRESSED, LIQUEFIED, OR SOLIDIFIED GASES
    • F17C2265/00—Effects achieved by gas storage or gas handling
    • F17C2265/06—Fluid distribution
    • F17C2265/068—Distribution pipeline networks
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02E—REDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
    • Y02E60/00—Enabling technologies; Technologies with a potential or indirect contribution to GHG emissions mitigation
    • Y02E60/30—Hydrogen technology
    • Y02E60/32—Hydrogen storage
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02E—REDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
    • Y02E60/00—Enabling technologies; Technologies with a potential or indirect contribution to GHG emissions mitigation
    • Y02E60/30—Hydrogen technology
    • Y02E60/34—Hydrogen distribution
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
    • Y02P90/00—Enabling technologies with a potential contribution to greenhouse gas [GHG] emissions mitigation
    • Y02P90/45—Hydrogen technologies in production processes

Definitions

  • the present invention relates to a method for transporting hydrogen through a natural gas line.
  • the hydrogen can be prepared in known manner, e.g. from water by electrolysis, the DC power required for the electrolysis being environmentally friendly, e.g. can be provided by solar power plants or wind turbines or tidal power plants.
  • the recovered hydrogen can react in a controlled manner with the oxygen of the ambient air to form water vapor, wherein the hydrogen emits electrons in this reaction, so that a current can be provided for the supply of any electrical load by this reaction.
  • the resulting waste heat can be used very efficiently in terms of combined heat and power.
  • Hydrogen as a fuel or energy source can be used in particular for the supply of buildings, such as households or offices, for this purpose, fuel cells are provided in the building or in the vicinity of the building, the supplied hydrogen for power generation for energizing electrical consumers, such as for example, use an electrically powered device, the respective building.
  • fuel cells are provided in the building or in the vicinity of the building, the supplied hydrogen for power generation for energizing electrical consumers, such as for example, use an electrically powered device, the respective building.
  • familiar solutions are usually resorting to existing natural gas networks or natural gas networks, in which case the hydrogen is admixed with the natural gas to be transported via the natural gas pipeline, so that the hydrogen together with the natural gas is transported via the gas pipeline to the building to be supplied.
  • the proportion of hydrogen in the total transported gas mixture is up to about 10 vol .-%. A higher concentration of hydrogen is usually difficult or impossible to achieve.
  • the present invention has for its object to provide a method for transporting hydrogen through a natural gas line, which is improved over known such methods.
  • the process according to the invention can provide a substantial improvement, in particular by avoiding
  • the hydrogen can be passed in nearly pure form through the hydrogen conduit.
  • the natural gas line can be made suitable for transport with hydrogen in almost pure form. It can therefore be dispensed with in the known method admixing of the hydrogen to the natural gas, which makes an acceptable transport only possible in known methods, since by the transport of hydrogen in this mixture too strong a permeation of very small hydrogen molecules through the wall of the Natural gas pipeline can be avoided.
  • the inventive method for the supply of a building allows the direct use of fuel cells, preferably low-temperature fuel cells, which may have an operating temperature of preferably 80 ° C to 120 ° C and a maximum of 180 ° C. It is not necessary to separate or extract the hydrogen from the hydrogen / natural gas mixture transported via the natural gas line in the case of known solutions and to do so in a very costly and expensive manner. Even a so-called reforming is not required.
  • the hydrogen has a purity within a range of 80 to 99.999 vol.%, Or within a range of 97 to 99.99 vol.%, Or within a range of 97.5 to 99, 9 vol .-% is.
  • the outside of the hydrogen pipe is at least partially applied flat on the inside of the natural gas line, in which case preferably the outside is connected at least partially flat with the inside of the natural gas line.
  • the hydrogen line is introduced by means of a Umstülpvons in the natural gas line.
  • the everting process may preferably be an everting process or inversion process known from the technical field of trenchless pipe laying.
  • the hydrogen line before introduction into the natural gas line initially in the form of a tube by means of Umstülpvons the hose is inserted by compressed air into the natural gas line and the tube interior swept to the outside and provided with the inside of the natural gas via a hose on the Adhesive layer, for example, thermally, cohesively can be connected.
  • the hydrogen line may also be introduced into the lumen of the natural gas line due to an outer diameter slightly smaller than the inner diameter of the natural gas line, so that the hydrogen line at least partially rests flat against the inside of the natural gas line, in which case preferably the outer side at least in areas, it is connected to the inside of the natural gas pipeline.
  • Portions of the hydrogen line to be connected to each other can advantageously be easily connected by means of fittings and sliding sleeves.
  • Fittinge and sliding sleeves can be made of brass or brass alloys or polymer material.
  • a hydrogen line is used, which consists at least partially of PE-X (cross-linked polyethylene).
  • a PE-X existing hydrogen pipe is particularly temperature resistant and mechanically resistant, so that the introduction of the hydrogen line in the natural gas line can be carried out particularly easily, in addition, such Hydrogen line withstands higher temperatures, which can occur, for example, in industrial plants.
  • a hydrogen line is particularly preferred, which consists of PE-X or PE-X, which is radically crosslinked, in particular a hydrogen line, which consists of PE-Xa (peroxide crosslinked PE) or contains PE-Xa, can be advantageously used ,
  • a hydrogen line is used, the inside of which is provided with a hydrogen barrier layer.
  • a hydrogen barrier layer on the inside of the hydrogen line, ie on the side facing the lumen of the hydrogen line, advantageously increases the diffusion-tightness of the hydrogen line, so that the permeation and thus the loss of hydrogen from the hydrogen line is reduced.
  • the hydrogen barrier layer on the outside of the hydrogen line, ie on the side facing away from the lumen of the hydrogen line. It is also possible that both the inner sides, as well as the outside of the hydrogen line has a hydrogen barrier layer. In the context of the present invention it can be provided that the hydrogen barrier layer consists at least partially of polysilazane.
  • a tube made of LDPE Low Density Polyethylene has a permeation rate of 200 cm 3 * mm / m 2 * d * atm.
  • Another hydrogen barrier is polyvinyl alcohol (EVAL, EVOH).
  • the present invention also most preferably comprises a hydrogen conduit formed in the form of a multilayer conduit consisting of at least two interconnected layers.
  • At least one layer consists at least partially of polyolefin.
  • a layer structure of the pipeline in which at least one layer consists at least partly of polyolefin has the advantage that this layer can be produced favorably in a plastic molding process, for example an extrusion process.
  • a hydrogen line comprises a metal layer, which is designed in particular very thin.
  • a metal layer for example of aluminum or another metal, a thickness of 1 to 50 pm, more preferably a thickness of 5 to 30 ⁇ have.
  • MKV tube metal-plastic tube
  • Such an MKV pipe can be integrated into an existing natural gas tion be inserted or introduced in the everting process in the natural gas line, because the thin metal layer tolerates the bending stress occurring during the Stülp compiler without damage.
  • such a hydrogen pipe network can be built from an existing natural gas network, without significant civil engineering work, trenching or earth movements are necessary. Only at a few selected locations, for example at junctions, are construction pits to be made.
  • the upgrading of the natural gas network to a hydrogen network is carried out by introducing a hydrogen line into a natural gas line.
  • 1 is a schematic representation for illustrating the introduction of a hydrogen pipe made of plastic material in a natural gas line by means of a Umstülp Kunststoffs,
  • FIG. 2 shows a schematic illustration for illustrating the transport of hydrogen through a hydrogen line arranged in a natural gas line
  • 3 and 4 each show a schematic sectional view of a natural gas line, in which by means of a Umstülpvons a hydrogen pipe made of plastic material was introduced.
  • FIG. 1 here illustrates the step of arranging or introducing a hydrogen line 10 made of plastic material into a natural gas line 14 laid in the ground 12 by means of a known everting method or inversion method.
  • the hydrogen pipe 10 is initially present in the form of a hose 10 prior to introduction into the natural gas pipe 14, whereby by means of the everting process the hose 10 can be introduced into the natural gas pipe 14 by compressed air and the hose interior is turned outwards and with the inside 15 of the natural gas line 14 via a provided on the hose 10 adhesive layer (not shown here) is materially connected.
  • the tube 10 is thereby supplied through the interior of a supply line 13 of the natural gas line 14 and is wound on a roll (not shown here), which is located inside a pressurizable container 1 1, to which the supply line 13 is connected.
  • FIG. 2 illustrates the flow through a hydrogen line 10 with hydrogen 16, which was previously arranged or introduced in a natural gas line 14, which is laid in the ground 12.
  • the hydrogen line 10 serves to supply a building 18 with pure hydrogen from a hydrogen tank 19, with a low-temperature fuel cell 20 being provided for generating DC power from the hydrogen supplied via the hydrogen line 10 in this exemplary embodiment.
  • the generated direct current can be converted into alternating current via an inverter, not shown here, so that the hydrogen 16 can be used to supply conventional electrical consumers 22, such as here in the form of a lamp.
  • 3 shows a schematic sectional view of a natural gas line 14 into which a hydrogen line 10 made of plastic material has been introduced by means of an everting process.
  • FIG. 4 shows a schematic sectional view of a natural gas line 14, in which by means of an everting process, a hydrogen line 10 made of plastic material has been introduced, which consists of two interconnected layers 24.

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  • Engineering & Computer Science (AREA)
  • General Engineering & Computer Science (AREA)
  • Mechanical Engineering (AREA)
  • Rigid Pipes And Flexible Pipes (AREA)

Abstract

L'invention concerne un procédé de transport d'hydrogène (16) par une conduite de gaz naturel (14), une conduite d'hydrogène (10) en matière plastique étant agencée dans la conduite de gaz naturel (14) et l'hydrogène (16) passant dans la conduite d'hydrogène (10) pour être transporté.
PCT/EP2011/005100 2010-10-18 2011-10-12 Procédé de transport d'hydrogène par une conduite de gaz naturel WO2012052125A1 (fr)

Priority Applications (1)

Application Number Priority Date Filing Date Title
EP11770703.4A EP2630401A1 (fr) 2010-10-18 2011-10-12 Procédé de transport d'hydrogène par une conduite de gaz naturel

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
DE102010048562.4 2010-10-18
DE102010048562A DE102010048562A1 (de) 2010-10-18 2010-10-18 Verfahren zum Transport von Wasserstoff durch eine Erdgasleitung

Publications (1)

Publication Number Publication Date
WO2012052125A1 true WO2012052125A1 (fr) 2012-04-26

Family

ID=45319049

Family Applications (1)

Application Number Title Priority Date Filing Date
PCT/EP2011/005100 WO2012052125A1 (fr) 2010-10-18 2011-10-12 Procédé de transport d'hydrogène par une conduite de gaz naturel

Country Status (3)

Country Link
EP (1) EP2630401A1 (fr)
DE (1) DE102010048562A1 (fr)
WO (1) WO2012052125A1 (fr)

Cited By (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP2569571B1 (fr) 2010-05-12 2017-07-19 Linde Aktiengesellschaft Infrastructure pour hydrogène
CN113932070A (zh) * 2021-03-17 2022-01-14 国家电投集团科学技术研究院有限公司 氢气输送系统和氢气输送方法
CN114396512A (zh) * 2022-03-24 2022-04-26 浙江大学 一种抗氢脆金属丝增强复合管
US20230304611A1 (en) * 2022-03-24 2023-09-28 Zhejiang University Anti-hydrogen embrittlement wire reinforced composite pipe

Families Citing this family (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
NL2021659B1 (nl) * 2018-09-18 2020-05-07 Alliander N V Werkwijze en systeem voor distributie van waterstof
DE102022129657A1 (de) 2022-11-09 2024-05-16 Westnetz Gmbh Messsystem und Verwendung eines Messsystems mit einer Erdleitung

Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US20040112427A1 (en) * 2002-12-16 2004-06-17 Ballard Generation Systems Hydrogen distribution systems and methods
US20090313896A1 (en) * 2008-06-20 2009-12-24 Cameron Glidewell Hydrogen generation and distribution system
WO2011107225A1 (fr) * 2010-03-01 2011-09-09 Rehau Ag + Co Utilisation d'un tube pour le transport d'hydrogène pur
WO2011141141A1 (fr) * 2010-05-12 2011-11-17 Linde Aktiengesellschaft Infrastructure pour hydrogène

Family Cites Families (3)

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Publication number Priority date Publication date Assignee Title
DE4429951A1 (de) * 1994-08-24 1996-02-29 Vorndran Heinrich Gmbh Verfahren zur Sanierung von Ver- und Entsorgungsleitungen und Schächten
DE102005027162A1 (de) * 2005-03-08 2006-09-14 Walter Stucke Isolierte Rohrleitungen aus Stahl für Gasleitungen
DE102008057694A1 (de) * 2008-11-17 2010-05-20 Karl-Heinz Tetzlaff Verfahren zur Nutzung von Wasserstoff mittels Brennstoffzellen in einem Erdgasnetz

Patent Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US20040112427A1 (en) * 2002-12-16 2004-06-17 Ballard Generation Systems Hydrogen distribution systems and methods
US20090313896A1 (en) * 2008-06-20 2009-12-24 Cameron Glidewell Hydrogen generation and distribution system
WO2011107225A1 (fr) * 2010-03-01 2011-09-09 Rehau Ag + Co Utilisation d'un tube pour le transport d'hydrogène pur
WO2011141141A1 (fr) * 2010-05-12 2011-11-17 Linde Aktiengesellschaft Infrastructure pour hydrogène

Cited By (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP2569571B1 (fr) 2010-05-12 2017-07-19 Linde Aktiengesellschaft Infrastructure pour hydrogène
CN113932070A (zh) * 2021-03-17 2022-01-14 国家电投集团科学技术研究院有限公司 氢气输送系统和氢气输送方法
CN114396512A (zh) * 2022-03-24 2022-04-26 浙江大学 一种抗氢脆金属丝增强复合管
US20230304611A1 (en) * 2022-03-24 2023-09-28 Zhejiang University Anti-hydrogen embrittlement wire reinforced composite pipe

Also Published As

Publication number Publication date
DE102010048562A1 (de) 2012-04-19
EP2630401A1 (fr) 2013-08-28

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