Classifications

• • C—CHEMISTRY; METALLURGY
  • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
  • C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
  • C09D11/00—Inks
  • C09D11/16—Writing inks
  • C09D11/17—Writing inks characterised by colouring agents
• • C—CHEMISTRY; METALLURGY
  • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
  • C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
  • C09D11/00—Inks
  • C09D11/16—Writing inks
  • C09D11/18—Writing inks specially adapted for ball-point writing instruments
• • C—CHEMISTRY; METALLURGY
  • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
  • C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
  • C09D7/00—Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
  • C09D7/40—Additives
  • C09D7/41—Organic pigments; Organic dyes
• • C—CHEMISTRY; METALLURGY
  • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
  • C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
  • C09D7/00—Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
  • C09D7/40—Additives
  • C09D7/60—Additives non-macromolecular
  • C09D7/61—Additives non-macromolecular inorganic

Definitions

• the disclosure is generally related to highlighting ink formulations and writing instruments containing the same. More particularly, the disclosure is related to highlighting ink formulations having at least one anti- smear agent.
• Highlighting a previously applied marking is typically performed by applying a highlighting ink over the previously applied marking.
• the highlighting ink has a translucent quality to allow for a user to apply the highlighting ink and yet still see the previously applied marking under the fluorescent highlighting ink marking.
• Prior art highlighting ink formulations can undesirably smear, smudge, or blur, the previously applied marking, thereby causing the underlying text to become unsightly and/or difficult to read.
• the highlighting ink formulations of the disclosure have one or more advantages, such as, for example, causing substantially no smearing of a previously applied marking when applied thereover (at least when compared to known highlighting ink formulations).
• the highlighting ink has one or more advantages, such as, for example, causing substantially no smearing of a previously applied marking when applied thereover (at least when compared to known highlighting ink formulations).
• formulations of the disclosure can attract attention to selected previously applied markings without substantially smearing, smudging, or otherwise blurring the previously applied marking (at least when compared to known highlighting ink formulations).
• the disclosure provides a highlighting ink
• formulation having a solvent system, a colorant dispersed or dissolved in the solvent system, and an anti-smear agent dispersed or dissolved in the solvent system, wherein the anti-smear agent comprises at least one monovalent cation.
• the disclosure provides a highlighting ink formulation comprising a solvent system, a colorant dispersed or dissolved in the solvent system, and an anti- smear agent dispersed or dissolved in the solvent system, the anti-smear agent comprising a salt of a monovalent cation, wherein the anti-smear agent is included in an amount in a range of about 5 wt.% to about 40 wt.%.
• the disclosure provides a highlighting ink formulation comprising a solvent system, a dye dissolved in the solvent system, and an anti- smear agent dispersed or dissolved in the solvent system, wherein the anti- smear agent comprises a cation selected from the group consisting of monovalent cations, divalent cations, and combinations thereof.
• the disclosure provides a highlighting ink formulation comprising a solvent system, a dye dissolved in the solvent system, and an anti-smear agent dispersed or dissolved in the solvent system, the anti-smear agent comprising a lithium cation.
• the disclosure provides a writing instrument, such as, for example, a pen or a marker, containing a highlighting ink formulation according to any one of the above-described first, second, third, and fourth embodiments.
• the disclosure provides a method of
• highlighting a previously applied marking the method comprising applying a highlighting ink formulation according to any one of the above-described first, second, third, and fourth embodiments of the disclosure over the previously applied marking, without substantially smearing, smudging, or otherwise blurring the previously applied marking (at least when compared to known highlighting ink formulations).
• Figure 1 A is an image showing a comparison of the smears produced by an ink formulation in accordance with the disclosure and commercially available ink formulations when the respective formulations are used to highlight a previously applied ink marking.
• Figure IB is an image showing the isolated smears of the smear comparison of Figure 1A.
• Figure 1C is a graph of the data showing the area of the smears of the smear comparison of Figure 1A.
• the highlighting ink formulations of the disclosure have one or more advantages, such as, for example, causing substantially no smearing of a previously applied marking when applied thereover (at least when compared to known highlighting ink formulations).
• the highlighting ink formulations of the disclosure can be applied over a previously applied marking without substantially smearing, smudging, or blurring the marking (at least when compared to known highlighting ink formulations).
• the highlighting ink formulations of the disclosure can better attract attention to a selected previously applied marking because a user's visual perception (of the now highlighted marking) is substantially unaffected by smearing, smudging, or blurring of the previously applied marking (at least when compared to known highlighting ink formulations).
• the highlighting ink formulations can be incorporated into a writing instrument, such as a pen or marker.
• the highlighting ink formulations of the disclosure include at least one anti- smear agent and a colorant dispersed or dissolved in a solvent system.
• the anti-smear agent can include monovalent cations, divalent cations, or mixtures thereof.
• the ink formulation comprises an anti-smear agent including a monovalent cation or a combination of monovalent cations.
• the ink formulation comprises an anti-smear agent having a divalent cation or a combination of divalent cations.
• the ink formulation comprises an anti- smear agent including a combination of one or more monovalent cations and one or more divalent cations.
• a previously written or applied marking can be highlighted using the ink formulations in accordance with the disclosure by applying the ink formulation over the previously applied marking.
• the highlighting ink formulations according to the disclosure cause little to no smearing, smudging, or blurring of the previously applied marking (particularly when compared to known highlighting ink formulations).
• the smear created by the ink formulations of the disclosure can have an area of less than about 1 mm , less than about 0.9 mm 2 , less than about 0.8 mm 2 , less than about 0.7 mm 2 , less than about 0.6 mm 2 , less than about 0.5 mm 2 , less than about 0.4, mm 2 , less than about 0.3 mm 2 , less than about 0.2 mm 2 , or less than about 0.1 mm 2.
• an ink formulation of the disclosure including lithium chloride as an anti-smear agent can generate a smear of less than about 0.3 mm .
• commercially available highlighting ink formulations create significantly larger smears, with an average smear area of about 2.6 mm 2 .
• the anti-smear agent included in the ink formulation comprises a cation selected from the group consisting of monovalent cations, divalent cations, and combinations thereof.
• the anti-smear agent can include one or more monovalent cations, one or more divalent cations, or a combination of monovalent and divalent cations.
• suitable monovalent cations include sodium, lithium, potassium, copper (I), silver (I), gold (I), and combinations thereof.
• suitable divalent cations include magnesium, calcium, copper (II), zinc, iron (II), tin (II), and combinations thereof.
• the monovalent or divalent cation can be provided, for example, in the form of a salt.
• the anion used as the opposed ion can be, for example, chloride, nitride, sulfate, acetate, citrate, propionate, borate, and phosphate.
• Suitable salts of monovalent cations include, but are not limited to, lithium chloride, lithium acetate, lithium carbonate, lithium borate, lithium nitrate, lithium phosphate, sodium chloride, sodium acetate, sodium carbonate, sodium borate, sodium nitrate, sodium phosphate, potassium acetate, potassium chloride, potassium carbonate, potassium borate, potassium phosphate, potassium nitrate, copper (I) chloride, copper (I) nitride, copper (I) sulfate, copper (I) acetate, copper (I) citrate, copper (I) propionate, copper (I) borate, copper (I) phosphate, silver
• Suitable salts of divalent cations include, but are not limited to, magnesium chloride, magnesium acetate, magnesium carbonate, magnesium borate, magnesium nitrate, magnesium phosphate, calcium chloride, calcium acetate, calcium carbonate, calcium borate, calcium nitrate, calcium nitrate, calcium phosphate, zinc chloride, zinc acetate, zinc carbonate, zinc nitrate, zinc phosphate, copper (II) chloride, copper (II) acetate, copper (II) carbonate, copper
• the anti-smear agent can include a combination of compounds having monovalent and/or divalent cations.
• the anti- smear agent can include lithium and sodium, for example, in the form of lithium chloride and sodium acetate. Other combination of monovalent and/or divalent cations can also be included to provide the anti-smear agent.
• the anti-smear agent whether provided as a compounds having one or more monovalent cations, one or more divalent cations, or a combination of monvalent and divalent cations, can be included in the ink formulation in a range of about 1 weight percent (wt.%) to about 40 wt.%, about 5 wt.% to about 40 wt.%, about 5 wt.% to about 30 wt.%, about 10 wt.% to about 25 wt.%, or about 15 wt.% to about 20 wt.% based on the total weight of the ink formulation.
• anti-smear agent examples include, for example, about 1, 2, 3, 4, 5, 6, 7, 8, 9, 10, 11, 12 , 13, 14, 15, 16, 17, 18, 19, 20, 21, 22, 23, 24, 25, 26, 27, 28, 29, 30, 31, 32, 33, 34, 35, 36, 37, 38, 39, and 40 wt.% based on the total weight of the ink formulation.
• the anti- smear agent can be included up to the solubility limit of the anti-smear agent in the ink formulation.
• cap off time refers to the last time interval that a writing instrument including the ink formulation was capable of producing an unbroken continuous line.
• inclusion of about 12 wt.% to about 30 wt.%, about 14 wt.% to about 25 wt.%, and/or about 15 wt.% to about 20 wt.% of the anti-smear agent LiCl can dramatically increase the cap off time of the ink formulation.
• Suitable amounts of the anti- smear agent for increasing the cap-off time include about 12, 13, 14, 15, 16, 17, 18, 19, 20, 21, 22, 23, 24, 25, 26, 27, 28, 29, or 30 wt.%.
• a cap off time of greater than 90 hours can be achieved for an ink formulation containing about 15 wt.% LiCl.
• the aforementioned improvement in cap-off time achieved with about 15 wt.% LiCl entails a surprising and unexpected improvement.
• the anti-smear agent can include a combination of monovalent and/or divalent cations.
• first and second anti-smear agents including first and second cations can be included in the ink formulation such that the total amount of anti-smear agent in the ink formulation is less than or equal to about 40 wt.% based on the total weight of the ink formulation.
• the anti-smear agent can be dispersed or dissolved in a solvent system comprising one or more solvents. Typically, the anti-smear agent is dissolved in the solvent system.
• the ink formulation is typically aqueous, and therefore, includes water (preferably deionized water) as the major component of the solvent system.
• Water can be included in the ink formulation in a range of about 10 wt.% to about 90 wt.%, about 20 wt.% to about 80 wt.%, about 30 wt.% to about 70 wt.%, about 40 wt.% to about 60 wt.%, and about 40 wt.% to about 90 wt.% based on the total weight of the ink formulation.
• Specific amounts of solvent systems can include about 10, 15, 20, 25, 30, 35, 40, 45, 50, 55, 60, 65, 70, 75, 80, 85, and 90 wt.% based on the total weight of the ink formulation.
• the ink formulation solvent system can further include other co-solvents, for example, water soluble solvents.
• suitable co-solvents include glycerin, propylene glycol, ethylene glycol, diglycerine, triglycerine, diglycol, dipropylene glycol, butylene glycols, hexylene glycols, diethylene glycol, triethylene glycol, and combinations thereof.
• Other suitable glycols can include, for example, (a) glycol ethers, such as, for example, ethylene glycol monomethyl ether, ethylene glycol monoethyl ether, ethylene glycol monobutyl ether, ethylene glycol
• glycol ether acetates such as, for example, ethylene glycol monomethyl ether acetate, ethylene glycol monoethyl ether acetate, ethylene glycol monobutyl ether acetate, ethylene glycol monophenyl ether acetate, diethylene glycol monomethyl ether acetate, diethylene glycol monoethyl ether acetate, diethylene glycol monobutyl ether acetate, diethylene glycol monophenyl ether acetate, diethylene glycol monomethyl ether acetate, diethylene glycol monoethyl ether acetate, diethylene glycol monobutyl ether acetate, diethylene glycol monophenyl ether acetate, diethylene glycol monoisopropyl ether acetate, ethylene glycol dimethyl ether acetate,
• the co-solvent can be included in the ink formulation in a range of about 1 wt.% to about 40 wt.%, about 5 wt.% to about 30 wt.%, about 10 wt.% to about 20 wt.%, or about 5 wt.% to about 15 wt.% based on the total weight of the ink formulation.
• Specific amounts of the co-solvent include, for example, about 1, 2, 3, 4, 5, 6, 7, 8, 9, 10, 11, 12 , 13, 14, 15, 16, 17, 18, 19, 20, 21, 22, 23, 24, 25, 26, 27, 28, 29, 30, 31, 32, 33, 34, 35, 36, 37, 38, 39, and 40 wt.% based on the total weight of the ink formulation.
• the ink formulation can include a colorant.
• the colorant is a fluorescent colorant.
• the colorant can be included in the ink formulation in a range of about 0.1 wt.% to about 30 wt.%, about 0.5 wt.% to about 25 wt.%, about 1 wt.% to about 20 wt.%, and about 5 wt.% to about 15 wt.% based on the total weight of the ink formulation.
• Specific suitable amounts of colorant include, for example, about 0.1, 0.5, 1, 5, 10, 15, 20, 25, and 30 wt.% based on the total weight of the ink formulation.
• the colorant can be, for example, a dye.
• Suitable dyes include, but are not limited to, basic dyes, acid dyes, solvent dyes, fluorescent dyes, and direct dyes.
• Xanthene dyes coumarin dyes, benzoxanthene dyes, naphthalimide dyes,
• benzothioxanthene dyes and acridine dyes can be used.
• specific dyes include, but are not limited to, Pyranine cone. 1020, SPECTRAMINE ® TURQUOISE
• RHOD AMINE BIJ crude (Spectra Colors Corp.), Auramine O, Basic Yellow 2, Basic
• Direct Yellow dyes Nos. 4, 11, 12, 27, 28, 33, 34, 39, 50, 58, 86, 100, 106, 107, 110, 118, 127, 132, 142, 157, and the like
• anthraquinone dyes monoazo dyes; disazo dyes; phthalocyanine derivatives, including, for example, various phthalocyanine sulfonate salts; aza annulenes; formazan copper complexes; triphenodioxazines; BERNACID Red 2BMN; PONT AMINE ® dyes such as PONTAMINE ® Brilliant Bond Blue A;
• Cibacron Brilliant Red 38-A i.e., Reactive Red 4
• Drimarene Brilliant Red X-2B i.e., Reactive Red 56
• LEVAFIX ® Brilliant Red E- 4B Mobay Chemical, Haledon, New Jersey
• LEVAFIX ® Brilliant Red E-6BA Mobay Chemical
• PROCION ® Red H8B i.e., Reactive Red 31
• CARTASOL ® Yellow GTF Presscake Sandoz, Inc.
• CARTASOL ® Yellow GTF Liquid Special 110 Sandoz, Inc.
• Yellow Shade 16948 Tricon
• BASACID ® Black X34 i.e., BASF X- 34
• Carta Black 2GT Sandoz, Inc.
• NEOZAPON ® Red 492 BASF
• AIZEN SPILON Red C-BH Hodogaya Chemical Company
• KAYANOL Red 3BL Nippon Kayaku Company
• LEVANOL Brilliant Red 3BW Mobay Chemical Company
• LEVADERM ® Lemon Yellow Mobay Chemical Company
• Spirit Fast Yellow 3G AIZEN SPILON Yellow C-GNH (Hodogaya Chemical Company);
• DERMACARBON 2GT (Sandoz); PYRAZOL ® Black BG (ICI); MORFAST ® Black Concentrate A (Morton-Thiokol); DIAZOL Black RN Quad (ICI); ORASOL ® Blue GN (Ciba-Geigy); SAVINYL ® Blue GLS (Sandoz, Inc.); LUXOL ® Blue MBSN (Morton-Thiokol); SEVRON ® Blue 5GMF (ICI); BASACID ® Blue 750 (BASF); BERNACID Red (Berncolors, Poughkeepsie, N.Y.); BERNCOLOR A.Y. 34;
• the dye can be included in the ink formulation in a range of about 0.1 wt.% to about 5 wt.%, about 0.5 wt.% to about 4.5 wt.% about 1 wt.% to about 4 wt.%, or about 2 wt.% to about 3 wt.% based on the total weight of the ink formulation.
• Specific amounts of the dye include, for example, about 0.1, 0.2, 0.3, 0.4, 0.5, 1, 1.5, 2, 2.5, 3, 3.5, 4, 4.5, and 5 wt.% based on the total weight of the ink formulation.
• the colorant can comprise a pigment in addition to the dye.
• the colorant can comprise a pigment as an alternative to a dye.
• Pigments useful in the disclosed ink formulation are often included in the ink formulation in the form of pigment dispersions, in which a pigment is dispersed, dissolved, or otherwise distributed in a resin.
• the pigment dispersions can further include a surfactant.
• the pigment dispersions can also be formed, for example, by combining a solvent such as water with a resin and a pigment.
• the pigment dispersion resin can be, for example, an acrylic resin.
• any pigment can be used as the colorant in the ink formulations according to the disclosure.
• organic pigments, inorganic pigments, and pigment precursors can be used as the colorant in the pigment dispersion.
• pigments for use in the ink formulations of the disclosure include, but are not limited to, phthalocyanine pigments, quinacridone pigments, benzimidazolone pigments, beta-naphthol pigments, carbon black pigments.
• Specific pigments include, but are not limited to, titanium dioxide, zinc oxide, calcium carbonate, lead white (lead carbonate), barium sulfate, iron blue, cobalt blue, ultramarine blue, black iron oxide (Iron (II, III) oxide), logwood, brown iron oxide, cadmium red, red iron oxide, cadmium yellow (CdS, CdZnS), curcuma yellow, yellow iron oxide, green chromate oxide, malachite, ferrocyanides, ferricyanides, manganese violet (manganese ammonium pyrophosphate), various aluminum salts and so on.
• Pigment precursors including, but not limited to, those described in U.S. Patent No. 6,524,382, the disclosure of which is
• Suitable commercially available pigment dispersions include, but are not limited to, BLAZE ORANGE ECX 15 (DayGlo, OH), CORONA MAGENTA ECX- 21 (DayGlo), and LUMIKOL Fluorescent Pigment Dispersions (United Mineral & Chemical Corp, NJ).
• BLAZE ORANGE ECX 15 DayGlo, OH
• CORONA MAGENTA ECX- 21 DayGlo
• LUMIKOL Fluorescent Pigment Dispersions United Mineral & Chemical Corp, NJ.
• Other DayGlo ECX pigment dispersions may be also suitable for use as the pigment dispersion.
• the pigment dispersion can be included in the ink formulation in a range of about 1 wt.% to about 20 wt.%, about 5 wt.% to about 15 wt.%, and about 7 wt.% to about 10 wt.% based on the total weight of the ink formulation.
• Specific suitable amounts include, for example, about 1, 2, 3, 4, 5, 6, 7, 8, 9, 10, 11, 12, 13, 14, 15, 16, 17, 18, 19, and 20 wt.% based on the total weight of the ink formulation.
• the pigment dispersion can further include one or more additives, including, for example, a surfactant and/or dispersing aid.
• exemplary dispersing aids include, but are not limited to, dispersing aids sold under the SOLSPERSETM trade name, including, SOLSPERSETM 44000 (Lubrizol Advanced Materials, Inc., Manchester UK), the NUOSPERSE ® trade name, for example, NUOSPERSE ® FA 196 (Elementis Specialty, NJ), the TEGO ® trade name, for example, TEGO ® Dispers 652 (Tego Chemie Service USA, VA); and YELKIN ® TS lecithin (Archer Daniels Midland Company, Decatur, ⁇ 1.).
• the ink formulation can include one or more additives.
• the additives can include, for example, biocides, pH adjusters, lightfastness imparting agents, and sometimes humectants.
• Suitable biocides include, for example, ACTICIDE B-20 (Thor Specialties, Inc., CT), and broad-spectrum biocides, such as, l,2,-benzisothiazolin-3-one, sold as a solution or dispersion under the trade name PROXEL.
• suitable biocides include, but are not limited to, PROXEL GXL, PROXEL BD20, and PROXEL XL2 (Avecia Biocides, Wilmington, Delaware.)
• Other suitable biocides include, but are not limited to, potassium sorbate, sodium benzoate, and pentachlorophenyl sodium.
• the biocide can be included in the ink formulation in an amount in a range of about 0.01 wt.% to about 20 wt.%, about 0.05 wt.% to about 15 wt.%, about 0.05 wt.% to about 10 wt.%, about 0.1 wt.% to about 10 wt.%, about 0.5 wt.% to about 5 wt.%, about 1 wt.% to about 10 wt.%, about 5 wt.% to about 7 wt.% based on the total weight of the ink formulation.
• biocide examples include, but are not limited to, about 0.01, 0.05, 0.1, 0.15, 0.2, 0.25, 0.3, 0.35, 0.4, 0.45, 0.5, 0.55, 0.6, 0.65, 0.7, 0.75, 0.8, 0.85, 0.9, 1, 5, 10, 15, and 20 wt.% based on the total weight of the ink formulation.
• Suitable pH adjusters include, for example, urea and triethanolamine, available, for example, from Univar USA as Triethanol Amine 9.
• the pH adjuster can be included in the ink formulation in a range of about 0.01 wt.% to about 20 wt.%, about 0.05 wt.% to about 15 wt.%, about 0.05 wt.% to about 10 wt.%, about 0.1 wt.% to about 10 wt.%, about 0.5 wt.% to about 5 wt.%, about 1 wt.%, to about 10 wt.%, about 5 wt.% to about 7 wt.% based on the total weight of the ink formulation.
• Suitable amounts include about 0.01, 0.05, 0.1,0.15, 0.2, 0.25, 0.3, 0.35, 0.4, 0.45, 0.5, 0.55, 0.6, 0.65, 0.7, 0.75, 0.8, 0.85, 0.9, 1, 5, 10, 15, and 20 wt.% based on the total weight of the ink formulation.
• Suitable lightfastness imparting agents include, for example, antioxidants, antiozonants, UV absorbing compounds, and the like, as well as mixtures thereof.
• the lightfastness imparting agent can be sucrose (for example, pure cane sugar).
• suitable lightfastness imparting agents include UV absorbing compounds, such as glycerol p-amino benzoate, available as ESCALOL 106 (Van Dyk Corporation); resorcinol mono benzoate, available as RBM (Eastman Chemicals); octyl dimethyl amino benzoate, available as ESCALOL 507 (Van Dyk Corporation); hexadecyl 3,5-di-tert-butyl-4-hydroxy-benzoate, available as
• antioxidants examples include didodecyl 3,3'-thiodipropionate, available as CYANOX LTDP, and as D12,840-6 (Aldrich Chemical Company);
• ditridecyl 3,3'-thiodipropionate available as CYANOX 711 and as 41,311-9 (Aldrich Chemical Company); ditetradecyl 3,3'-thiodipropionate, available as CYANOX MTDP and as 41,312-7 (Aldrich Chemical Company); dicetyl 3,3'-thiodipropionate, available as EVANSTAB 16 (Evans Chemetics Corporation); dioctadecyl 3,3'- thiodipropionate, available as CYANOX STDP and as 41,310-0 (Aldrich Chemical Company); triethyleneglycol bis(3-(3'-tert-butyl-4'-hydroxy-5'-methylphenyl) propionate), available as IRGANOX 245 (Ciba-Geigy Corporation); octadecyl 3-(3,5- di-tert-butyl-4-hydroxyphenyl)propionate, available as ULTRA
• hydrocinnamate available as IRGANOX 259 (Ciba-Geigy Corporation);
• IRGANOX 1010 Ciba-Geigy Corporation
• thiodiethylenebis(3,5di-tert-butyl-4- hydroxy) hydrocinnamate available as IRGANOX 1035 (Ciba-Geigy Corporation); octadecyl 3,5-di-tert-butyl-4-hydroxy hydrocinnamate, available as IRGANOX 1076 (Ciba-Geigy Corporation); N,N'-hexamethylenebis(3,5di-tert-butyl-4-hydroxy hydrocinnamide), available as IRGANOX 1098 (Ciba-Geigy Corporation); 2,2-bis(4- (2-(3,5-di-tert-butyl-4-hydroxyhydrocinnamoyloxy))ethoxy phenyl) propane,
• phenyl)phosphite available as LANKROMARK LE 109 (Harcros Corporation); tris(2,4-di-tert-butyl-phenyl)phosphite, available as WYTOX 240 (Olin Corporation); 2,2'-ethylidene bis(4,6-di-tert-butylphenyl) fluorophosphonite, available as
• ETHANOX 398 (Ethyl Corporation); octylated diphenylamine, available as
• ANCHOR ODPA Anchor Corporatio n
• ⁇ , ⁇ '- ⁇ , ⁇ -naphthalene-p-phenylenediamine available as ANCHOR DNPD (Anchor Corporation); 4,4'-methylene-bis(dibutyldithio carbamate), available as VANLUBE 7723 (Vanderbilt Corporation); antimony dialkyldithio carbamate, available as VANLUBE 73 (Vanderbilt Corporation), antimony dialkylphosphorodithioate, available as VANLUBE 622 (Vanderbilt Corporation); molybdenum oxysulfide dithio carbamate, available as VANLUBE 622 (Vanderbilt Corporation); 2,2,4-trimethyl-l,2-hydroquinoline, available as
• VULKANOX HS Mobay Corporation
• Suitable antiozonants include N-isopropyl-N'-phenyl- phenylene diamine, available as SANTOFLEX IP (Monsanto Chemicals), N-(l,3- dimethylbutyl)-N'-phenyl-phenylene diamine, available as SANTOFLEX 13
• ANTOZITE-1 Vanderbilt Corporation
• N,N'-bis(l,4-dimethyl pentyl)-p-phenylene diamine available as SANTOFLEX 77 (Monsanto Chemicals); 2,4,6-tris-(N-l,4- dimethyl pentyl-p-phenylene diamino)-l,3,5-triazine, available as DURAZONE 37 (Uniroyal Corporation): 6ethoxy-l,2-dihydro-2,2,4-trimethyl quinoline, available as SANTOFLEX AW (Monsanto Chemicals): bis(l,2,3,6tetrahydrobenzaldehyde) pentaerythritol acetal, available as VULKAZON AFS/LG (Mobay Corporation); paraffin wax, available as PETROLITE C-700 and PETROLITE C-1035 (Petrolite Corporation); and the like, as well as mixtures thereof.
• the lightfastness imparting agent can be included in the ink formulation in a range of about 1 wt.% to about 40 wt.%, about 5 wt.% to about 30 wt.%, and about 10 wt.% to about 20 wt.% based on the total weight of the ink formulation.
• Specific amounts of the lightfastness imparting agent include, but are not limited to, about 1, 5, 10, 15, 20, 25, 30, 35, and 40 wt.% based on the total weight of the ink formulation.
• Suitable writing instruments to deliver the highlighting ink formulation include, but are not limited to, pens, such as, for example, ball-point pens and porous tip pens, and markers, such as, for example, capillary action markers, valve action markers, and the like.
• the writing instruments generally include a reservoir containing the ink formulation and a writing point or nib coupled to and in fluid communication with reservoir.
• the reservoirs should generally be inert to the ink formulations according to the disclosure.
• An example of a suitable reservoir is a melt-blown fibrous reservoir from Filtrona Company (Colonial Height, VA).
• the reservoirs can be of any dimensions as long as the dimensions are sufficient for storing a predetermined amount of the ink formulation and for permitting the reservoir to fit into the desired marker body or other writing instrument housing.
• Reservoirs for use in the markers according to the disclosure preferably have a reservoir fiber density between about 0.10 gram/cubic centimeter (g/cc) and about 0.50 g/cc.
• the reservoir fibers can be manufactured from thermoplastic polymers such as, for example, polyesters, nylons, polypropylenes, and mixtures thereof.
• the fibers inside the reservoir can be linearly- oriented or entangled.
• the reservoir can be wrapped with a sheet of polypropylene or nylon.
• the writing points or nibs should allow for continual delivery of the ink formulations contained in the reservoirs. Fibers of the nibs should be compatible with the various solvent systems of the compositions.
• An exemplary nib is a
• Suitable nib fibers can be manufactured from thermoplastic polymers such as, for example, polyester, polypropylene, nylon, and mixtures thereof.
• the nib fibers are typically bound by a second resin, which also should be insoluble in the ink formulation solvent system.
• Exemplary second resins include polyacetal and melamine
• the writing instrument can be a capillary action marker, which generally includes a reservoir for storing the ink formulation coupled to and in fluid communication with a porous nib.
• the capillary action marker includes a porous reservoir for storing the ink formulation joined in capillary coupling relation to a porous nib. Both capillary action markers and valve action markers are known.
• the viscosity of the ink formulation at about 25°C can be between about 1 centipoises (cP) and 40 cP, for example, between about 2 cP and about 10 cP, about 3 cP and about 15 cP, about 1 cP and about 40 cP, about 5 cP and 10 cP, about 3 cP and about 4 cP, about 4 cP and about 5 cP, and about 5 cP to about 6 cP, as measured by a Brookfield viscosity meter.
• Specific Brookfield viscosities include, for example, about 2, 3, 4, 5, 6, 7, 8, 9, 10, 11, 12, 13, 14, 15, 16, 17, 18, 19, and 20 cP.
• the ranges provided above can shift higher or lower depending on the nature of the writing instrument, and, for example, the porosity of the nibs and/or the fiber density of the ink reservoirs (if employed). pH
• the pH of the ink formulation is generally in a range of about 7 to about 11 , about 8 to about 10, about 7 to 10, about 7.5 to about 10.5, and about 7.5 to about 8.5.
• the ink formulation can have a pH of about 7, 7.5, 8, 8.5, 9, 9.5, 10, 10.5, or 11.
• the ink formulation can have a surface tension in a range of about 25 mN/M to about 70 mN/M, about 30 mN/M to about 65 mN/M, about 35 mN/M to about 60 mN/M, about 40 mN/M to about 50 mN/M, about 55 mN/M to about 70 mN/M, about 50 mN/M to about 60 mN/M, and about 25 mN/M to about 40 mN/M.
• the ink formulation can have a surface tension of about 25, 30, 35, 40, 45, 50, 55, 60, 65, or 70 mN/M.
• the ink formulation can have a conductivity in a range of about 10 ms to about 40 ms, about 15 ms to about 35 ms, and about 20 ms to about 30 ms.
• the ink formulation can have a conductivity of about 10, 15, 20, 25, 30, 35, or 40 ms.
• the ink formulation can have a specific gravity of about 1 to about 2, about 1.1 to about 1.8, about 1.1 to about 1.15, about 1.15 to about 1.3, and about 1.2, to about 1.5.
• the ink formulation can have a specific gravity of about 1, 1.1, 1.15, 1.2, 1.25, 1.3, 1.35, 1.4, 1.45, 1.5, 1.55, 1.6, 1.65, 1.7, 1.75, 1.8, 1.85, 1.9, 1.95, or 2.
• a yellow ink was prepared by mixing deionized water with lithium chloride in a container for about 15 minutes. Sodium acetate was then added slowly to the mixture and mixing was continued for about 15 additional minutes. Pure cane powered sugar (sucrose) was added to the mixture and the mixture was stirred for about 1 to 10 more minutes. Glycerin, ACTICIDE B-20, and triethanolamine were added to the mixture and mixing was continued for about 5 additional minutes.
• pyranine cone. 1020 dye was added to the container and the mixture was mixed for about 30 additional minutes.
• the components were used in the amounts shown below.
• the ink had a Brookfield viscosity at 25°C in a range of about 4 to about 5.2 cP, a pH in a range of about 7.5 to about 10.5, a surface tension in a range of about 55 to about 70 mN/M, and a specific gravity in a range of about 1.15 to about 1.2.
• a green ink was prepared by mixing deionized water with sodium acetate in a container for about 15 minutes. Pure cane powered sugar (sucrose) was added to the mixture and mixing was continued for about 1 to 10 additional minutes. Propylene glycol, ACTICIDE B-20, and triethanolamine were added to the mixture and mixing was continued for about 5 more minutes. Finally, pyranine cone. 1020 and
• the ink had a Brookfield viscosity at 25°C in a range of about 5 to about 6 cP, a pH in a range of about 7.5 to about 10.5, a surface tension in a range of about 50 to about 60 mN/M, and a specific gravity in a range of about 1.15 to about 1.2.
• a blue ink was prepared by mixing deionized water with lithium chloride in a container for about 15 minutes. Pure cane powered sugar was added to the mixture and mixing was continued for about 1 to 10 additional minutes. Propylene glycol and ACTICIDE B-20 were added to the mixture and mixing was continued for about 5 more minutes. Finally, HID ACID ® FTM Blue 9 was added to the mixture and mixing continued for about 30 additional minutes. The components were used in the amounts shown below.
• the ink had a Brookfield viscosity at 25°C in a range of about 3 to about 4 cP, a pH in a range of about 7 to about 8.5, a surface tension in a range of about 45 to about 60 mN/M, and a specific gravity in a range of about 1.1 to about 1.15.
• An orange ink was prepared by mixing deionized water with sodium acetate in a container for about 15 minutes. Pure cane powered sugar was added to the mixture and mixing was continued for about 1 to 10 additional minutes. Propylene glycol and ACTICIDE B-20 were added to the mixture and mixing was continued for about 5 more minutes.
• the ink had a Brookfield viscosity at 25°C in a range of about 4 to about 5 cP, a pH in a range of about 7 to about 8.5, a surface tension in a range of about 25 to about 40 mN/M, and a specific gravity in a range of about 1.1 to about 1.15.
• An orange ink was prepared by mixing deionized water with sodium acetate in a container for about 15 minutes. Pure cane powered sugar was added to the mixture and mixing was continued for about 1 to 10 additional minutes. Propylene glycol and ACTICIDE B-20 were added to the mixture and mixing was continued for about 5 more minutes. SPECTRA EOSINE OJ cone, and SPECTRACIDE RHOD AMINE BIJ Crude were added to the mixture and mixed for about 30 additional minutes. BLAZE ORANGE EXC 15 (DayGlo) pigment dispersion was then added to the mixture and mixing was continued for about 15 minutes. The components were used in the amounts shown below.
• the ink had a Brookfield viscosity at 25°C of about 4.2 cP, a pH in a range of about 7 to about 8.5, a surface tension in a range of about 40 to about 50 mN/M, and a specific gravity in a range of about 1.1 to about 1.15.
• An orange ink was prepared by mixing deionized water with sodium acetate in a container for about 15 minutes. Pure cane powered sugar was added to the mixture and mixing was continued for about 1 to 10 additional minutes. Propylene glycol and ACTICIDE B-20 were added to the mixture and mixing was continued for about 5 more minutes. SPECTRA EOSINE OJ cone, was added to the mixture and mixing was continued for about 30 additional minutes. CORONA MAGENTA ECX- 21 (DayGlo) pigment dispersion was then added to the mixture and mixing was continued for about 15 more minutes. The components were used in the amounts shown below. Component Function Amount
• the ink had a Brookfield viscosity in a range of about 3 to about 4 cP, a pH in a range of about 7 to about 8.5, a surface tension in a range of about 24 to about 40 mN/M, and a specific gravity in a range of about 1.1 to about 1.15.
• a yellow ink also referred to herein as A29, was prepared by mixing deionized water with lithium chloride in a container for about 15 minutes. Pure cane powered sugar was added to the mixture and mixing was continued for about 1 to 10 additional minutes. Glycerin, ACTICIDE B-20, and triethanolamine were added to the mixture and mixing was continued for about 5 more minutes. Finally, Pyranine CONC. 1020 dye was added to the mixture and mixing was continued for about 30 additional minutes. The components were used in the amounts shown below.
• the ink had a Brookfield viscosity of about 11.7 cP, a pH of about 8.3, and a surface tension of about 43.37 mN/M.
• a yellow ink was prepared by mixing deionized water with lithium chloride in a container for about 15 minutes. Sodium acetate was added to the mixture and mixing was continued for about 15 additional minutes. Pure cane powered sugar was added to the mixture and mixing was continued for about 1 to 10 more minutes. Glycerin, ACTICIDE B-20, and triethanolamine were added to the mixture and mixing was continued for about 5 more minutes. Finally, pyranine cone. 1020 dye was added to the mixture and mixing was continued for about 30 additional minutes. The components were used in the amounts shown below.
• the ink had a Brookfield viscosity of about 6.3 cP, a pH of about 8.85, a surface tension of about 34.23 mN/M, and a conductivity of about 34.4 ms.
• a yellow ink was prepared by mixing deionized water with magnesium chloride hexahydrate in a container for about 15 minutes. Sodium acetate was added to the mixture and mixing was continued for about 15 additional minutes. Pure cane powered sugar (sucrose) was added to the mixture and mixing was continued for about 1 to 10 additional minutes. Glycerin, ACTICIDE B-20, and triethanolamine were added to the mixture and mixing was continued for about 5 more minutes. Finally, pyranine cone. 1020 dye was added to the mixture and mixing was continued for about 30 additional minutes. The components were used in the amounts shown below.
• the ink had a Brookfield viscosity of about 6.61 cP, a pH of about 9.01, a surface tension of about 36.47 mN/M, and a conductivity of about 24.6 ms.
• a yellow ink was prepared by mixing deionized water with magnesium chloride hexahydrate in a container for about 15 minutes. Potassium acetate was added to the mixture and mixing was continued for about 15 additional minutes. Pure cane powered sugar (sucrose) was added to the mixture and mixing was continued for about 1 to 10 additional minutes. Glycerin, ACTICIDE B-20, and triethanolamine were added to the mixture and mixing was continued for about 5 more minutes. Finally, pyranine cone. 1020 dye was added to the mixture and mixing was continued for about 30 additional minutes. The components were used in the amounts shown below. Component Function Amount
• the ink had a Brookfield viscosity of about 5.28 cP, a pH of about 9.2, a surface tension of about 42.35 mN/M, and a conductivity of about 30.5 ms.
• a yellow ink was prepared by mixing deionized water with sodium acetate in a container for about 15 minutes. Pure cane powered sugar (sucrose) was added to the mixture and mixing was continued for about 1 to 10 additional minutes. Glycerin, ACTICIDE B-20, and triethanolamine were added to the mixture and mixing was continued for about 5 more minutes. Finally, pyranine cone. 1020 dye was added to the mixture and mixing was continued for about 30 additional minutes. The components were used in the amounts shown below.
• the ink had a Brookfield viscosity of about 8.16 cP, a pH of about 8,83, a surface tension of about 53.31 mN/M, and a conductivity of about 13.6 ms.
• a yellow ink was prepared by mixing deionized water with potassium acetate in a container for about 15 minutes. Pure cane powered sugar (sucrose) was added to the mixture and mixing was continued for about 1 to 10 additional minutes. Glycerin, ACTICIDE B-20, and triethanolamine were added to the mixture and mixing was continued for about 5 more minutes. Finally, pyranine cone. 1020 dye was added to the mixture and mixing was continued for about 30 additional minutes. The components were used in the amounts shown below.
• the ink had a Brookfield viscosity of about 6.16 cP, a pH of about 9.01, a surface tension of about 52.46 mN/M, and a conductivity of about 18.3 ms.
• a yellow ink was prepared by mixing deionized water with sodium chloride in a container for about 15 minutes. Sodium acetate was added to the mixture and mixing was continued for about 15 additional minutes. Pure cane powered sugar (sucrose) was added to the mixture and mixing was continued for about 1 to 10 additional minutes. Glycerin, ACTICIDE B-20, and triethanolamine were added to the mixture and mixing was continued for about 5 more minutes. Finally, pyranine cone. 1020 dye was added to the mixture and mixing was continued for about 30 additional minutes. The components were used in the amounts shown below. Component Function Amount
• the ink had a Brookfield viscosity of about 7.98 cP, a pH of about 8.83, a surface tension of about 52.38 mN/M, and a conductivity of about 33.5 ms.
• a yellow ink was prepared by mixing deionized water with sodium acetate in a container for about 15 minutes. Pure cane powered sugar (sucrose) was added to the mixture and mixing was continued for about 1 to 10 additional minutes. Glycerin, ACTICIDE B-20, and triethanolamine were added to the mixture and mixing was continued for about 5 more minutes. Finally, pyranine cone. 1020 dye was added to the mixture and mixing was continued for about 30 additional minutes. The components were used in the amounts shown below.
• the ink had a Brookfield viscosity of about 6.06 cP.
• a yellow ink was prepared by mixing deionized water with lithium chloride in a container for about 15 minutes. Potassium acetate was added to the mixture and mixing was continued for about 15 additional minutes. Pure cane powered sugar (sucrose) was added to the mixture and mixing was continued for about 1 to 10 additional minutes. Glycerin, ACTICIDE B-20, and triethanolamine were added to the mixture and mixing was continued for about 5 more minutes. Finally, pyranine cone. 1020 dye was added to the mixture and mixing was continued for about 30 additional minutes. The components were used in the amounts shown below.
• the ink had a Brookfield viscosity of about 5.49 cP.
• a yellow ink was prepared by mixing deionized water with sodium chloride in a container for about 15 minutes. Sodium acetate was added to the mixture and mixing was continued for about 15 additional minutes. Pure cane powered sugar (sucrose) was added to the mixture and mixing was continued for about 1 to 10 additional minutes. Glycerin, ACTICIDE B-20, and triethanolamine were added to the mixture and mixing was continued for about 5 more minutes. Finally, pyranine cone. 1020 dye was added to the mixture and mixing was continued for about 30 additional minutes. The components were used in the amounts shown below. Component Function Amount
• the ink had a Brookfield viscosity of about 5.73 cP and surface tension 37.8.
• a yellow ink was prepared by mixing deionized water with lithium chloride in a container for about 15 minutes. Pure cane powered sugar (sucrose) was added to the mixture and mixing was continued for about 1 to 10 additional minutes.
• Propylene glycol, SOLSPERSE 44000, ACTICIDE B-20, and triethanolamine were added to the mixture and mixing was continued for about 5 more minutes.
• pyranine cone. 1020 dye was added to the mixture and mixing was continued for about 30 additional minutes. The components were used in the amounts shown below.
• a green ink was prepared by mixing deionized water with sodium chloride in a container for about 15 minutes. Sodium acetate was added to the mixture and mixing was continued for about 15 additional minutes. Pure cane powered sugar (sucrose) was added to the mixture and mixing was continued for about 1 to 10 additional minutes. Propylene glycol, ACTICIDE B-20, and triethanolamine were added to the mixture and mixing was continued for about 5 more minutes. Finally, pyranine cone. 1020 dye and PONT AMINE FAST TURQUOISE 8GL Liquid dye were added to the mixture and mixing was continued for about 30 additional minutes. The components were used in the amounts shown below.
• a blue ink was prepared by mixing deionized water with lithium chloride in a container for about 15 minutes. Pure cane powered sugar (sucrose) was added to the mixture and mixing was continued for about 1 to 10 additional minutes. Propylene glycol and ACTICIDE B-20 were added to the mixture and mixing was continued for about 5 more minutes. Finally, HID ACID FTM Blue 9 dye was added to the mixture and mixing was continued for about 30 additional minutes. The components were used in the amounts shown below. Component Function Amount
• Example 7 was compared to inks contained in Avery HI- LITER ® marker, Stabilo Boss ® Executive marker, and Stabilo Boss ® Inkjet generation marker. A comparison was also made to the commercially available highlighting ink formulation HL5030, the formulation of which is shown below.
• the extent of smearing of ink markings on standard paper was measured by first producing a smear trace over the ink marking.
• the ink marking can be in the form of a straight line, while the smear trace can be in the form of a wavy or zigzag line.
• the smear trace can be trimmed so that at least one edge of the trace is parallel to the ink marking.
• the ink marking and the smear trace can be formed, for example, using a write test machine, such as an Anja W10B Write Test Machine.
• the write test machine has the ability to draw a straight line for at least 100 cm, the ability to drawn a wavy/zigzag line for at least 100 cm, a five minute pause between the ink marking line and the smear trace line, and the ability to control point load.
• the smear image is then digitized, using for example, a flatbed digital scanner, for example an Epson Perfection V700 Photo, and Epson PerfectionV750 Photo, or similar scanner. If needed, the scanner bulb can be first warmed-up by allowing it to scan the blank background for at least two minutes, and preferably five minutes. The smear image is then scanned into a computer for further processing and analysis.
• a flatbed digital scanner for example an Epson Perfection V700 Photo, and Epson PerfectionV750 Photo, or similar scanner. If needed, the scanner bulb can be first warmed-up by allowing it to scan the blank background for at least two minutes, and preferably five minutes. The smear image is then scanned into a computer for further processing and analysis.
• the ink smear can be electronically isolated from the digitized image, using, for example, a computer program such as Photoshop CS3 and smear extraction software. Further processing of the extracted smears can be performed prior to smear analysis.
• the extracted smear image can be converted to a black and white image using a threshold value, for example, of 241.
• the white pixels of the converted image represent the pixels of the image whose value is in the threshold range, while the black pixels represent the pixels of the image outside of the threshold range.
• small portions of the smears that have a direction against the direction of travel when the writing instrument or machine generates the smear can be eliminated.
• the ink smear can then be analyzed to determine, for example, the area of the smear.
• the analysis can be done, for example, using a computer program designed to analyze and measure the smear.
• the image analysis software PAX-itTM (MIS, IL), can be used to analyze the smear.
• Cap off time was measured by first conditioning the writing instruments containing the ink formulations to be tested and the substrates in the room in which the cap off testing was conducted. For example, the writing instruments having the caps on and the substrates can be placed in the room for a period of time of about four hours. The writing instruments should be fresh, unused writing instruments. Next an initial marking in a sinusoidal pattern is written on the substrate using each of the writing instruments containing the ink formulations to be tested to ensure that the writing instrument is writing properly, and each writing instrument is then recapped.
• the writing instruments are then all uncapped and a timer is started. Testing for cap-off can be conducted using any suitable time interval. At each time interval a marking in a sinusoidal pattern is written on the substrate using each of the writing instruments. The markings are then compared to the initial marking and analyzed to determine whether a continuous, unbroken line is produced. If such a line is produced, the writing instrument is tested at the next time interval by again marking a sinusoidal pattern on the substrate, comparing the marking to the initial marking, and analyzing the marking to determine whether a continuous, unbroken line is produced. Once the line produced by the writing instrument becomes discontinuous or broken as compared to the initial marking, the test can be stopped.
• the cap-off time of the writing instrument is the last tested time interval that the writing instrument was capable of producing an unbroken, continuous line.
• Ten yellow ink formulations were tested using the above-described cap-off testing method— Formulations 21 A through 21 J. It can be ascertained from the data provided in the table below that by increasing the amount of lithium chloride content to greater than 10 wt.%, for example to about 15 wt.%, dramatic increases in cap off time can be achieved. Glycerin is typically expected to increase cap off time. The data, however, demonstrates that the increase in cap off time achieved with the formulations having greater than 15 wt.% lithium chloride is not attributable to the amount of glycerin included in the formulation.

Landscapes

• Chemical & Material Sciences (AREA)
• Life Sciences & Earth Sciences (AREA)
• Engineering & Computer Science (AREA)
• Materials Engineering (AREA)
• Wood Science & Technology (AREA)
• Organic Chemistry (AREA)
• Inorganic Chemistry (AREA)
• Inks, Pencil-Leads, Or Crayons (AREA)

Priority Applications (3)

Applications Claiming Priority (2)

Publications (1)

Family

ID=44736049

Family Applications (1)

Country Status (5)

Families Citing this family (6)

Citations (6)

Family Cites Families (8)

• 2010
  • 2010-09-21 US US12/887,440 patent/US8562729B2/en active Active
• 2011
  • 2011-09-15 JP JP2013530194A patent/JP2013543024A/ja active Pending
  • 2011-09-15 CN CN201180049925XA patent/CN103154160A/zh active Pending
  • 2011-09-15 WO PCT/US2011/051680 patent/WO2012040023A1/en not_active Ceased
  • 2011-09-15 EP EP11764388.2A patent/EP2614120A1/en not_active Withdrawn

Patent Citations (6)

Also Published As

Similar Documents

Legal Events