WO2011159352A3 - Production de gaz à faible teneur en goudrons dans un gazéificateur étagé - Google Patents

Production de gaz à faible teneur en goudrons dans un gazéificateur étagé Download PDF

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Publication number
WO2011159352A3
WO2011159352A3 PCT/US2011/001080 US2011001080W WO2011159352A3 WO 2011159352 A3 WO2011159352 A3 WO 2011159352A3 US 2011001080 W US2011001080 W US 2011001080W WO 2011159352 A3 WO2011159352 A3 WO 2011159352A3
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WO
WIPO (PCT)
Prior art keywords
reactor
char
partial oxidation
higher temperature
media
Prior art date
Application number
PCT/US2011/001080
Other languages
English (en)
Other versions
WO2011159352A2 (fr
Inventor
Thomas J. Paskach
John P. Reardon
Paul Evans
Jerod Smeenk
Original Assignee
Frontline Bio Energy,Llc
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Frontline Bio Energy,Llc filed Critical Frontline Bio Energy,Llc
Publication of WO2011159352A2 publication Critical patent/WO2011159352A2/fr
Publication of WO2011159352A3 publication Critical patent/WO2011159352A3/fr

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Classifications

    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10J—PRODUCTION OF PRODUCER GAS, WATER-GAS, SYNTHESIS GAS FROM SOLID CARBONACEOUS MATERIAL, OR MIXTURES CONTAINING THESE GASES; CARBURETTING AIR OR OTHER GASES
    • C10J3/00—Production of combustible gases containing carbon monoxide from solid carbonaceous fuels
    • C10J3/46—Gasification of granular or pulverulent flues in suspension
    • C10J3/48—Apparatus; Plants
    • C10J3/485—Entrained flow gasifiers
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10J—PRODUCTION OF PRODUCER GAS, WATER-GAS, SYNTHESIS GAS FROM SOLID CARBONACEOUS MATERIAL, OR MIXTURES CONTAINING THESE GASES; CARBURETTING AIR OR OTHER GASES
    • C10J3/00—Production of combustible gases containing carbon monoxide from solid carbonaceous fuels
    • C10J3/46—Gasification of granular or pulverulent flues in suspension
    • C10J3/463—Gasification of granular or pulverulent flues in suspension in stationary fluidised beds
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10J—PRODUCTION OF PRODUCER GAS, WATER-GAS, SYNTHESIS GAS FROM SOLID CARBONACEOUS MATERIAL, OR MIXTURES CONTAINING THESE GASES; CARBURETTING AIR OR OTHER GASES
    • C10J3/00—Production of combustible gases containing carbon monoxide from solid carbonaceous fuels
    • C10J3/46—Gasification of granular or pulverulent flues in suspension
    • C10J3/466—Entrained flow processes
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10J—PRODUCTION OF PRODUCER GAS, WATER-GAS, SYNTHESIS GAS FROM SOLID CARBONACEOUS MATERIAL, OR MIXTURES CONTAINING THESE GASES; CARBURETTING AIR OR OTHER GASES
    • C10J3/00—Production of combustible gases containing carbon monoxide from solid carbonaceous fuels
    • C10J3/46—Gasification of granular or pulverulent flues in suspension
    • C10J3/48—Apparatus; Plants
    • C10J3/482—Gasifiers with stationary fluidised bed
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10J—PRODUCTION OF PRODUCER GAS, WATER-GAS, SYNTHESIS GAS FROM SOLID CARBONACEOUS MATERIAL, OR MIXTURES CONTAINING THESE GASES; CARBURETTING AIR OR OTHER GASES
    • C10J3/00—Production of combustible gases containing carbon monoxide from solid carbonaceous fuels
    • C10J3/72—Other features
    • C10J3/721—Multistage gasification, e.g. plural parallel or serial gasification stages
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10J—PRODUCTION OF PRODUCER GAS, WATER-GAS, SYNTHESIS GAS FROM SOLID CARBONACEOUS MATERIAL, OR MIXTURES CONTAINING THESE GASES; CARBURETTING AIR OR OTHER GASES
    • C10J3/00—Production of combustible gases containing carbon monoxide from solid carbonaceous fuels
    • C10J3/72—Other features
    • C10J3/82—Gas withdrawal means
    • C10J3/84—Gas withdrawal means with means for removing dust or tar from the gas
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10J—PRODUCTION OF PRODUCER GAS, WATER-GAS, SYNTHESIS GAS FROM SOLID CARBONACEOUS MATERIAL, OR MIXTURES CONTAINING THESE GASES; CARBURETTING AIR OR OTHER GASES
    • C10J2300/00—Details of gasification processes
    • C10J2300/09—Details of the feed, e.g. feeding of spent catalyst, inert gas or halogens
    • C10J2300/0913—Carbonaceous raw material
    • C10J2300/0916—Biomass
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10J—PRODUCTION OF PRODUCER GAS, WATER-GAS, SYNTHESIS GAS FROM SOLID CARBONACEOUS MATERIAL, OR MIXTURES CONTAINING THESE GASES; CARBURETTING AIR OR OTHER GASES
    • C10J2300/00—Details of gasification processes
    • C10J2300/09—Details of the feed, e.g. feeding of spent catalyst, inert gas or halogens
    • C10J2300/0913—Carbonaceous raw material
    • C10J2300/0946—Waste, e.g. MSW, tires, glass, tar sand, peat, paper, lignite, oil shale
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10J—PRODUCTION OF PRODUCER GAS, WATER-GAS, SYNTHESIS GAS FROM SOLID CARBONACEOUS MATERIAL, OR MIXTURES CONTAINING THESE GASES; CARBURETTING AIR OR OTHER GASES
    • C10J2300/00—Details of gasification processes
    • C10J2300/09—Details of the feed, e.g. feeding of spent catalyst, inert gas or halogens
    • C10J2300/0953—Gasifying agents
    • C10J2300/0956—Air or oxygen enriched air
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10J—PRODUCTION OF PRODUCER GAS, WATER-GAS, SYNTHESIS GAS FROM SOLID CARBONACEOUS MATERIAL, OR MIXTURES CONTAINING THESE GASES; CARBURETTING AIR OR OTHER GASES
    • C10J2300/00—Details of gasification processes
    • C10J2300/09—Details of the feed, e.g. feeding of spent catalyst, inert gas or halogens
    • C10J2300/0953—Gasifying agents
    • C10J2300/0959—Oxygen
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10J—PRODUCTION OF PRODUCER GAS, WATER-GAS, SYNTHESIS GAS FROM SOLID CARBONACEOUS MATERIAL, OR MIXTURES CONTAINING THESE GASES; CARBURETTING AIR OR OTHER GASES
    • C10J2300/00—Details of gasification processes
    • C10J2300/09—Details of the feed, e.g. feeding of spent catalyst, inert gas or halogens
    • C10J2300/0983—Additives
    • C10J2300/0993—Inert particles, e.g. as heat exchange medium in a fluidized or moving bed, heat carriers, sand
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10J—PRODUCTION OF PRODUCER GAS, WATER-GAS, SYNTHESIS GAS FROM SOLID CARBONACEOUS MATERIAL, OR MIXTURES CONTAINING THESE GASES; CARBURETTING AIR OR OTHER GASES
    • C10J2300/00—Details of gasification processes
    • C10J2300/18—Details of the gasification process, e.g. loops, autothermal operation
    • C10J2300/1807—Recycle loops, e.g. gas, solids, heating medium, water
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02E—REDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
    • Y02E50/00—Technologies for the production of fuel of non-fossil origin
    • Y02E50/30—Fuel from waste, e.g. synthetic alcohol or diesel
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
    • Y02P20/00—Technologies relating to chemical industry
    • Y02P20/141—Feedstock
    • Y02P20/145—Feedstock the feedstock being materials of biological origin

Landscapes

  • Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Combustion & Propulsion (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Organic Chemistry (AREA)
  • Industrial Gases (AREA)
  • Devices And Processes Conducted In The Presence Of Fluids And Solid Particles (AREA)

Abstract

La présente invention concerne un système de gazéification de matières solides à plusieurs étages utilisé pour la production d'un gaz combustible à faible teneur en goudrons. Ledit système comprend un premier réacteur à lit fluidisé permettant la production d'un gaz contenant de l'hydrogène, des vapeurs de pyrolyse, des goudrons et des particules de résidu carboné à une température inférieure à la température de sortie du second réacteur et des zones de post-combustion à oxydation partielle présentant une température supérieure. Un second réacteur comprend une zone d'oxydation partielle présentant une température supérieure en vue de l'activation de l'hydrogène et du craquage de composés à noyau aromatique, un lit granulaire mobile à co-courant comportant un étage de gazéification des résidus carbonés en vue de la catalyse de la réduction des goudrons et de la régulation du temps de résidence des résidus carbonés et un support comprenant un tamis métallique parallèle orienté pratiquement à la verticale et supportant le milieu granulaire.
PCT/US2011/001080 2010-06-16 2011-06-16 Production de gaz à faible teneur en goudrons dans un gazéificateur étagé WO2011159352A2 (fr)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
US39776510P 2010-06-16 2010-06-16
US61/397,765 2010-06-16

Publications (2)

Publication Number Publication Date
WO2011159352A2 WO2011159352A2 (fr) 2011-12-22
WO2011159352A3 true WO2011159352A3 (fr) 2014-03-27

Family

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Family Applications (1)

Application Number Title Priority Date Filing Date
PCT/US2011/001080 WO2011159352A2 (fr) 2010-06-16 2011-06-16 Production de gaz à faible teneur en goudrons dans un gazéificateur étagé

Country Status (2)

Country Link
US (1) US20110308155A1 (fr)
WO (1) WO2011159352A2 (fr)

Families Citing this family (30)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US9476001B2 (en) * 2010-05-14 2016-10-25 Ansac Pty Ltd Process and apparatus for the treatment of tar in syngas
AU2011284780B2 (en) * 2010-07-27 2015-06-18 Renergi Pty Ltd A method of gasifying carbonaceous material and a gasification system
DE202011004328U1 (de) * 2011-03-22 2012-06-25 Big Dutchman International Gmbh Schachtvergaser zum Betrieb bei einer unterstöchiometrischen Oxidation
US10738249B2 (en) 2012-01-30 2020-08-11 Aries Gasification, Llc Universal feeder for gasification reactors
US20180094199A1 (en) * 2012-01-30 2018-04-05 Aries Gasification, Llc Burner nozzle with backflow prevention for a fluidized bed biogasifier
US9242219B2 (en) 2012-01-30 2016-01-26 PHG Energy, LLC Fluidized bed biogasifier and method for gasifying biosolids
CN102585856B (zh) * 2012-03-13 2014-03-12 程培胜 一种高温裂解生物质、城市废弃物制煤气的方法
PL2834328T3 (pl) * 2012-04-03 2023-10-02 Frontline Bioenergy, Llc Sposób redukcji smoły w zgazowywaniu materiałów zawierających węgiel
CN103450923B (zh) * 2012-06-01 2015-02-25 中国石油天然气股份有限公司 一种重质油热接触轻质化的方法
CN102796568B (zh) * 2012-09-06 2015-07-08 刘宗礼 一种生产纯净水煤气和一氧化碳的装置及工艺
JP6594206B2 (ja) * 2012-12-10 2019-10-23 サザン カンパニー 段階的ガス化における第２段ガス化装置
GB2503065B (en) 2013-02-20 2014-11-05 Recycling Technologies Ltd Process and apparatus for treating waste comprising mixed plastic waste
CN103965969B (zh) * 2014-05-19 2015-12-09 北京蓝天利源科技有限公司 组合型煤热解气化系统
CN106573219B (zh) 2014-06-09 2020-02-18 哈奇有限公司 具有内部再循环流化床的平推流反应器
CN105542857A (zh) * 2014-10-28 2016-05-04 通用电气公司 合成气的生产系统及方法
CN105623760A (zh) * 2014-10-28 2016-06-01 通用电气公司 合成天然气的生产系统及方法
CN104713867B (zh) * 2015-01-30 2017-07-11 中国科学院广州能源研究所 一种用于生物燃气在线激光拉曼光谱分析仪的预处理装置及其使用方法
DE102015108552A1 (de) * 2015-02-27 2016-09-01 Fraunhofer-Gesellschaft zur Förderung der angewandten Forschung e.V. Pyrolyseöl und Verfahren zu dessen Herstellung
EP3098514A1 (fr) * 2015-05-29 2016-11-30 Siemens Aktiengesellschaft Agencement de chambre de combustion
US20160365592A1 (en) * 2015-06-15 2016-12-15 Kashong Llc Solid waste gasification system with anode gas recycling arrangement
CN105001891B (zh) * 2015-07-21 2017-12-01 北京神雾电力科技有限公司 一种中低阶煤热解气化系统及热解气化方法
US10029203B2 (en) * 2016-01-15 2018-07-24 White's Equipment Rental, Llc Separation apparatus for a gas component from spent drilling mud
NL2016437B1 (en) * 2016-03-15 2017-10-02 Torrgas Tech B V Process to prepare a char product and a syngas mixture.
US10982151B2 (en) 2016-09-29 2021-04-20 Expander Energy Inc. Process for converting carbonaceous material into low tar synthesis gas
CN106701118B (zh) * 2016-12-08 2019-10-01 哈尔滨工业大学 一种双旋风生物质熔融热解气化炉
CN108467750B (zh) * 2017-02-23 2020-09-04 中国石油化工股份有限公司 复合式分级气化反应装置及其方法
CN107805510B (zh) * 2017-10-25 2023-09-15 浙江科技学院 一种固体有机质热解气化耦合重整净化反应器
US11697779B2 (en) * 2019-03-22 2023-07-11 King Fahd University Of Petroleum And Minerals Co-gasification of microalgae biomass and low-rank coal to produce syngas/hydrogen
CN110699122B (zh) * 2019-10-09 2020-11-24 安徽桐煜能源科技有限公司 一种生物质气化炉除尘除焦装置
CN111778072A (zh) * 2020-06-28 2020-10-16 东南大学 一种富氧高温脱除可燃固废气化焦油的装置和方法

Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US5804066A (en) * 1996-02-08 1998-09-08 Aerojet-General Corporation Injector for SCWO reactor
US20090019770A1 (en) * 2007-07-20 2009-01-22 Pall Corporation Catalytic element
US20090090053A1 (en) * 2007-10-09 2009-04-09 Silvagas Corporation Systems and methods for oxidation of synthesis gas tar

Family Cites Families (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPS59176391A (ja) * 1983-03-28 1984-10-05 Hitachi Ltd 石炭ガス化炉
DE4235412A1 (de) * 1992-10-21 1994-04-28 Metallgesellschaft Ag Verfahren zum Vergasen von brennbare Bestandteile enthaltenden Abfallstoffen
US5900224A (en) * 1996-04-23 1999-05-04 Ebara Corporation Method for treating wastes by gasification

Patent Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US5804066A (en) * 1996-02-08 1998-09-08 Aerojet-General Corporation Injector for SCWO reactor
US20090019770A1 (en) * 2007-07-20 2009-01-22 Pall Corporation Catalytic element
US20090090053A1 (en) * 2007-10-09 2009-04-09 Silvagas Corporation Systems and methods for oxidation of synthesis gas tar

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Publication number Publication date
WO2011159352A2 (fr) 2011-12-22
US20110308155A1 (en) 2011-12-22

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