WO2011154596A1 - Manufacturing of stone coating - Google Patents

Manufacturing of stone coating Download PDF

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Publication number
WO2011154596A1
WO2011154596A1 PCT/FI2011/050522 FI2011050522W WO2011154596A1 WO 2011154596 A1 WO2011154596 A1 WO 2011154596A1 FI 2011050522 W FI2011050522 W FI 2011050522W WO 2011154596 A1 WO2011154596 A1 WO 2011154596A1
Authority
WO
WIPO (PCT)
Prior art keywords
coating
stone
crushed stone
tinting
tinted
Prior art date
Application number
PCT/FI2011/050522
Other languages
French (fr)
Inventor
Jani Rutanen
Original Assignee
Tikkurila Oyj
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Tikkurila Oyj filed Critical Tikkurila Oyj
Priority to EA201291186A priority Critical patent/EA023485B1/en
Priority to EP11736119.6A priority patent/EP2576709A1/en
Priority to UAA201213626A priority patent/UA107496C2/en
Publication of WO2011154596A1 publication Critical patent/WO2011154596A1/en

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B41/00—After-treatment of mortars, concrete, artificial stone or ceramics; Treatment of natural stone
    • C04B41/45—Coating or impregnating, e.g. injection in masonry, partial coating of green or fired ceramics, organic coating compositions for adhering together two concrete elements
    • C04B41/46—Coating or impregnating, e.g. injection in masonry, partial coating of green or fired ceramics, organic coating compositions for adhering together two concrete elements with organic materials
    • C04B41/48—Macromolecular compounds
    • C04B41/483—Polyacrylates
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D5/00—Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
    • C09D5/28—Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes for wrinkle, crackle, orange-peel, or similar decorative effects
    • C—CHEMISTRY; METALLURGY
    • C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B41/00—After-treatment of mortars, concrete, artificial stone or ceramics; Treatment of natural stone
    • C04B41/45—Coating or impregnating, e.g. injection in masonry, partial coating of green or fired ceramics, organic coating compositions for adhering together two concrete elements
    • C04B41/50—Coating or impregnating, e.g. injection in masonry, partial coating of green or fired ceramics, organic coating compositions for adhering together two concrete elements with inorganic materials
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D7/00—Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
    • C09D7/40—Additives
    • C09D7/66—Additives characterised by particle size
    • C09D7/69—Particle size larger than 1000 nm
    • E—FIXED CONSTRUCTIONS
    • E04—BUILDING
    • E04F—FINISHING WORK ON BUILDINGS, e.g. STAIRS, FLOORS
    • E04F13/00—Coverings or linings, e.g. for walls or ceilings
    • E04F13/02—Coverings or linings, e.g. for walls or ceilings of plastic materials hardening after applying, e.g. plaster
    • E—FIXED CONSTRUCTIONS
    • E04—BUILDING
    • E04F—FINISHING WORK ON BUILDINGS, e.g. STAIRS, FLOORS
    • E04F13/00—Coverings or linings, e.g. for walls or ceilings
    • E04F13/07—Coverings or linings, e.g. for walls or ceilings composed of covering or lining elements; Sub-structures therefor; Fastening means therefor
    • E04F13/08—Coverings or linings, e.g. for walls or ceilings composed of covering or lining elements; Sub-structures therefor; Fastening means therefor composed of a plurality of similar covering or lining elements
    • E04F13/14—Coverings or linings, e.g. for walls or ceilings composed of covering or lining elements; Sub-structures therefor; Fastening means therefor composed of a plurality of similar covering or lining elements stone or stone-like materials, e.g. ceramics concrete; of glass or with an outer layer of stone or stone-like materials or glass

Definitions

  • the invention relates to the manufacture of construction coatings and concerns the manufacturing method of a stone coating containing natural stone.
  • socles, facades or inner walls can be coated with coloured stone coatings that contain crushed stone.
  • a pigment is generally mixed with a binder phase and the coatings are opaque, whereby the pattern or colour of the crushed stone is not visible.
  • coatings be used, which comprise a transparent binder, whereby the rock material gives the coating a special colour.
  • pre-dyed rock material is then used.
  • the specification GB 2 412 377 discloses one such coating. It contains methacrylic ester-acrylic ester binder, thickener, filler, and dyed quartz sand, in particular.
  • the coating that is manufactured according to the invention contains crushed stone, which is not dyed in advance and which is obtained from natural stone by crushing and screening it into a grain size of over 0.2 mm - 3 mm at the most, an acrylate binder, and water.
  • the coating is tinted by mixing with it one or more colourants that contains one or more pigments.
  • the colourant is used in such an amount that the amount of pigment is 0.001 - 0.5% of the weight of the coating.
  • a transparent coating can be manufactured, which is tinted with the colourant and, in this way, the pattern of the crushed stone can be made visible, whereby the colour of the crushed stone also influences the overall shade. Because of the diversity of the stone (the colour, surface pattern, and shape of the stone), the appearance of the surface thus deviates from that of an equally-coloured, covering paint or coating, and of a coating that contains dyed crushed stone.
  • the visual appearance of the coating according to the invention bears a resemblance to the rock material, and yet tinting into desired shades can be achieved.
  • the coating can be manufactured so that a tinting base is mixed from binder dispersion, crushed stone, possible additives, and water, the base being then tinted with the colourant.
  • the colour and intensity of the tinting base can be controlled to a desired standard.
  • the tinting can be made manually by adding colourants to the tinting base and mixing or, most suitably, by a tinting machine.
  • the tinting bases are preferably manufactured from a few different crushed stone grades.
  • a limitless number of stone coatings of different colours can be obtained, wherein the pattern of the crushed natural stone is still visible.
  • the coating that is manufactured according to the invention contains an acrylate binder.
  • the binder is specifically an aqueous dispersion, which the crushed stone is mixed with.
  • the dispersion is generally prepared by an emulsion polymerization method from one or more esters of acrylic acid and/or methacrylic acid with alka- nol that contains 1-8 carbons, such as methyl acrylate, ethyl acrylate, n-butyl acrylate, isobutyl acrylate, t-butyl acrylate, or lauryl acrylate, and possibly from other comonomers.
  • comonomers for example, styrene, vinyl acetate, vinyl versatate, ethylene, vinyl chloride, vinyl laurate, and vinyl ester can be used.
  • the aqueous dispersions of polyacrylate or polymethacrylate can be manufactured, for example, according to the processes disclosed in the US patents 2,795,564 and 2,754,280.
  • the polymer dispersions that are manufactured by the emulsion polymerization method of monomers are preferably finely dispersed.
  • the particle size of the polymer in the dispersion may vary within about 0.01 and about 1 micrometers.
  • the practice of the emulsion polymerization is presented in detail, for example, in D.C. Blackley's book Emulsion Polymerization (Wiley, 1975).
  • the amount of binder can be, for example, 2.5-40%, preferably 2.5-20%, most preferably 4-15% of the weight of the coating.
  • the amount of dispersion that contains 50% of dry matter is 5-80%, preferably 5-40%, most preferably 8-30% of the weight of the coating.
  • the crushed stone used in the coating is manufactured from natural stone by crushing and screening. The crushed stone is screened into a grain size of over 0.2 mm - 3 mm at the most, preferably over 0.6 - 1.4 mm at the most.
  • the crushed stone can contain, for example, limestone, dolomite, granite (such as grey or red granite) or gabbro (such as black gabbro).
  • the content of crushed stone in the stone coating can be, for example, 20-95 weight-%, preferably 40-80 weight- %, most preferably 50-70 weight-%.
  • the crushed stone is not dyed, for example, with an organic or inorganic colouring agent or with an organic or inorganic coating, such as epoxy.
  • the stone coating can be tinted to thousands of shades by adding colourant by a tinting machine.
  • the pigments in the colourants can be, for example, the following pigments of a colour index, and their mixtures: PW6, PY74, PY42, PR101 , PG7, PB15:3, and PBk7.
  • Typical colourants include, for example, universal colourants that are water-thinnable and free of VOC, such as the colourants of the Tikkurila Avatint tinting system.
  • the raw materials of the colourant comprise pigments, sol- vents, additives and, in some technologies, binders.
  • Tinting is a controlled colouring method. The accuracy and repeatability of the colour of a coating made by tinting are excellent.
  • the coating can be tinted in a tinting machine. This can be made in a retail outlet. In the tinting machine, the colourants are dosed into the tinting base in the propor- tion according to a specific tinting formula and shaken in a shaker to obtain an even shade. By using the colourants, an extremely large selection of coating of different colours can be produced by using a few tinting bases only. By means of the colourants, a wide colour scale of coatings can be managed and the need for storing can be reduced.
  • the amount of pigment is 0.001-0.5%, preferably 0.002-0.3 % of the weight of the coating. Such small portions of pigment can provide a transparent coating, where the patterning of natural stone also becomes visible and the colour of the natural stone contributes to the overall shade.
  • the tinting can be made in the retail outlet by the same tinting machine as the tinting of paints. No more than one tinting base from each crushed stone grade is necessarily needed.
  • the tinting base is preferably one that contains no pigment at all.
  • additives can also be used for the manufacture of the stone coating.
  • these include, for example, water, rheological additives, such as thickeners, preservatives, anti-foam agents, solvents, such as film-forming solvents, dry-film biocides, and matting agents.
  • the additives are preferably added as early as in connection with the manufacture of the tinting base.
  • the raw materials of the colourants include pigments, solvents, additives and, in some technologies, binders.
  • the applications of the coating in- elude, for example, socles, mineral facades and the wall and trim surfaces of balconies outdoors and wall and ceiling surfaces and accessories, such as the outer surfaces of fireplaces, and ornaments indoors.
  • the application methods can include, for example, spreading with a (steel) trowel, spraying, and roller application. When needed, the surface can be patterned with a brush, rubber or plasterer's comb after spreading.

Abstract

The invention relates to a method of manufacturing a tinted stone coating. The coating contains undyed crushed stone, which is obtained from natural stone by crushing and screening and the grain size of which is over 0.2 mm - 3 mm at the most. In the method, a tinting base that contains an acrylate binder, crushed stone, and water, is tinted by mixing therewith a colourant in such an amount that the coating contains 0.001-0.5% of pigment of the weight of the coating. In this way, a transparent coating can be manufactured, where the pattern of the crushed stone and the colourfulness of natural stone are visible and the colour influences the overall shade.

Description

MANUFACTURING OF STONE COATING
Description
Technical field
The invention relates to the manufacture of construction coatings and concerns the manufacturing method of a stone coating containing natural stone.
Background art
For example, socles, facades or inner walls can be coated with coloured stone coatings that contain crushed stone. In such coatings, a pigment is generally mixed with a binder phase and the coatings are opaque, whereby the pattern or colour of the crushed stone is not visible. It has also been suggested that coatings be used, which comprise a transparent binder, whereby the rock material gives the coating a special colour. In particular, pre-dyed rock material is then used. The specification GB 2 412 377 discloses one such coating. It contains methacrylic ester-acrylic ester binder, thickener, filler, and dyed quartz sand, in particular. General description of the invention
A method of manufacturing a tinted stone coating, a composition and its use have now been invented, according to the independent claims.
The coating that is manufactured according to the invention contains crushed stone, which is not dyed in advance and which is obtained from natural stone by crushing and screening it into a grain size of over 0.2 mm - 3 mm at the most, an acrylate binder, and water. The coating is tinted by mixing with it one or more colourants that contains one or more pigments. The colourant is used in such an amount that the amount of pigment is 0.001 - 0.5% of the weight of the coating.
According to the invention, a transparent coating can be manufactured, which is tinted with the colourant and, in this way, the pattern of the crushed stone can be made visible, whereby the colour of the crushed stone also influences the overall shade. Because of the diversity of the stone (the colour, surface pattern, and shape of the stone), the appearance of the surface thus deviates from that of an equally-coloured, covering paint or coating, and of a coating that contains dyed crushed stone. The visual appearance of the coating according to the invention bears a resemblance to the rock material, and yet tinting into desired shades can be achieved. The coating can be manufactured so that a tinting base is mixed from binder dispersion, crushed stone, possible additives, and water, the base being then tinted with the colourant. The colour and intensity of the tinting base can be controlled to a desired standard. The tinting can be made manually by adding colourants to the tinting base and mixing or, most suitably, by a tinting machine. The tinting bases are preferably manufactured from a few different crushed stone grades.
According to the invention, a limitless number of stone coatings of different colours can be obtained, wherein the pattern of the crushed natural stone is still visible.
Detailed description of some embodiments of the invention
The coating that is manufactured according to the invention contains an acrylate binder. The binder is specifically an aqueous dispersion, which the crushed stone is mixed with. The dispersion is generally prepared by an emulsion polymerization method from one or more esters of acrylic acid and/or methacrylic acid with alka- nol that contains 1-8 carbons, such as methyl acrylate, ethyl acrylate, n-butyl acrylate, isobutyl acrylate, t-butyl acrylate, or lauryl acrylate, and possibly from other comonomers. As comonomers, for example, styrene, vinyl acetate, vinyl versatate, ethylene, vinyl chloride, vinyl laurate, and vinyl ester can be used.
The aqueous dispersions of polyacrylate or polymethacrylate can be manufactured, for example, according to the processes disclosed in the US patents 2,795,564 and 2,754,280. The polymer dispersions that are manufactured by the emulsion polymerization method of monomers are preferably finely dispersed. The particle size of the polymer in the dispersion may vary within about 0.01 and about 1 micrometers. The practice of the emulsion polymerization is presented in detail, for example, in D.C. Blackley's book Emulsion Polymerization (Wiley, 1975). The amount of binder can be, for example, 2.5-40%, preferably 2.5-20%, most preferably 4-15% of the weight of the coating. In that case, for example the amount of dispersion that contains 50% of dry matter is 5-80%, preferably 5-40%, most preferably 8-30% of the weight of the coating. The crushed stone used in the coating is manufactured from natural stone by crushing and screening. The crushed stone is screened into a grain size of over 0.2 mm - 3 mm at the most, preferably over 0.6 - 1.4 mm at the most. The crushed stone can contain, for example, limestone, dolomite, granite (such as grey or red granite) or gabbro (such as black gabbro). The content of crushed stone in the stone coating can be, for example, 20-95 weight-%, preferably 40-80 weight- %, most preferably 50-70 weight-%. The crushed stone is not dyed, for example, with an organic or inorganic colouring agent or with an organic or inorganic coating, such as epoxy.
The stone coating can be tinted to thousands of shades by adding colourant by a tinting machine. The pigments in the colourants can be, for example, the following pigments of a colour index, and their mixtures: PW6, PY74, PY42, PR101 , PG7, PB15:3, and PBk7. Typical colourants include, for example, universal colourants that are water-thinnable and free of VOC, such as the colourants of the Tikkurila Avatint tinting system. The raw materials of the colourant comprise pigments, sol- vents, additives and, in some technologies, binders.
Tinting is a controlled colouring method. The accuracy and repeatability of the colour of a coating made by tinting are excellent.
The coating can be tinted in a tinting machine. This can be made in a retail outlet. In the tinting machine, the colourants are dosed into the tinting base in the propor- tion according to a specific tinting formula and shaken in a shaker to obtain an even shade. By using the colourants, an extremely large selection of coating of different colours can be produced by using a few tinting bases only. By means of the colourants, a wide colour scale of coatings can be managed and the need for storing can be reduced. The amount of pigment is 0.001-0.5%, preferably 0.002-0.3 % of the weight of the coating. Such small portions of pigment can provide a transparent coating, where the patterning of natural stone also becomes visible and the colour of the natural stone contributes to the overall shade. The tinting can be made in the retail outlet by the same tinting machine as the tinting of paints. No more than one tinting base from each crushed stone grade is necessarily needed. The tinting base is preferably one that contains no pigment at all.
In addition to the binder, crushed stone, and colourant, additives can also be used for the manufacture of the stone coating. These include, for example, water, rheological additives, such as thickeners, preservatives, anti-foam agents, solvents, such as film-forming solvents, dry-film biocides, and matting agents. The additives are preferably added as early as in connection with the manufacture of the tinting base. The raw materials of the colourants include pigments, solvents, additives and, in some technologies, binders. The applications of the coating in- elude, for example, socles, mineral facades and the wall and trim surfaces of balconies outdoors and wall and ceiling surfaces and accessories, such as the outer surfaces of fireplaces, and ornaments indoors. The application methods can include, for example, spreading with a (steel) trowel, spraying, and roller application. When needed, the surface can be patterned with a brush, rubber or plasterer's comb after spreading.
Example 1
280.8 g of water and 7.5 g of hydroxyethylcellulose (Natrosol 250 HHBR) were added to 288 grams of the copolymer dispersion of acrylate and methacrylate (dry content 50 weight-%), mixed for 5 minutes. To the mixture thus obtained, 864 g of crushed grey granite stone with a size of 0.6-1.2 mm were slowly added, while mixing constantly. The mixture was transferred to a closable shakeproof container and 0.52 g of the PR101 pigment in the form of a colourant was added thereto by the COROB™ D300 tinting machine. The container was closed and shook by the COROB™ SIMPLEshake 40 device to colour the mixture evenly transparent with the pigment. The final pigment content of the stone coating was 0.28 weight-%.

Claims

CLAIMS:
1. A method of manufacturing a tinted stone coating, which contains crushed stone that is obtained from natural stone by crushing and screening, characterized in that a tinting base, which contains an acrylate binder, water, and undyed crushed stone of a grain size of over 0.2 mm - 3 mm at the most, is tinted by mixing with it one or more colourants that contain one or more pigments, in such an amount that the coating contains 0.001-0.5% of pigment of the weight of the coating.
2. A method according to claim 1 , characterized in that the amount of pigment is 0.002-0.3%.
3. A method according to claim 1 or 2, characterized in that the crushed stone is screened into a grain size of over 0.6 mm - 1.4 mm at the most.
4. A method according to any of claims 1-3, characterized in that the amount of crushed stone is 20-95% of the weight of the coating.
5. A method according to any of claims 1-4, characterized in that the amount of binder is 2.5-40% of the weight of the coating.
6. A method according to any of claims 1-5, characterized in that the crushed stone contains limestone, dolomite, granite, or gabbro.
7. A method according to any of claims 1-6, characterized in that the tinting is carried out by a tinting machine.
8. A composition that contains crushed stone obtained from natural stone by crushing and screening, a binder, and water, characterized in that the composition contains an acrylate binder, that the crushed stone is undyed and its grain size is over 0.2 mm - 3 mm at the most, and that the composition can be tinted into a coating by mixing therewith one or more colourants that contain one or more pigments, in such an amount that the coating contains 0.001-0.5% of pigment of the weight of the coating.
9. The use of the composition according to claim 8 for the manufacture of a tinted stone coating.
PCT/FI2011/050522 2010-06-07 2011-06-06 Manufacturing of stone coating WO2011154596A1 (en)

Priority Applications (3)

Application Number Priority Date Filing Date Title
EA201291186A EA023485B1 (en) 2010-06-07 2011-06-06 Method of manufacturing a stone coating
EP11736119.6A EP2576709A1 (en) 2010-06-07 2011-06-06 Manufacturing of stone coating
UAA201213626A UA107496C2 (en) 2010-06-07 2011-06-06 Manufacturing of stone coating

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
FI20105638A FI123441B (en) 2010-06-07 2010-06-07 Manufacture of stone coatings
FI20105638 2010-06-07

Publications (1)

Publication Number Publication Date
WO2011154596A1 true WO2011154596A1 (en) 2011-12-15

Family

ID=42308095

Family Applications (1)

Application Number Title Priority Date Filing Date
PCT/FI2011/050522 WO2011154596A1 (en) 2010-06-07 2011-06-06 Manufacturing of stone coating

Country Status (5)

Country Link
EP (1) EP2576709A1 (en)
EA (1) EA023485B1 (en)
FI (1) FI123441B (en)
UA (1) UA107496C2 (en)
WO (1) WO2011154596A1 (en)

Cited By (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN103709846A (en) * 2013-12-12 2014-04-09 上海汇丽涂料有限公司 Water-based environmental agate marble coating and preparation and construction methods thereof
CN104109439A (en) * 2014-07-28 2014-10-22 漳州三德利油漆涂料有限公司 Heat preserving really stone paint and preparation method thereof
JP2015078288A (en) * 2013-10-16 2015-04-23 アイカ工業株式会社 Sand wall-like aqueous coating composition and method for applying the same

Families Citing this family (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
RU2729759C1 (en) * 2019-12-11 2020-08-12 Денис Александрович Фомахин Method of producing decorative art coating on the surface of flat cork panels
CN112126295A (en) * 2020-09-16 2020-12-25 漆仙姑新材料技术重庆有限公司 Nano hydrophobic texture real stone paint

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US3098053A (en) * 1959-09-29 1963-07-16 Macmillan & Bloedel Ltd Wood patching composition containing acrylic ester polymer and method of use
US5681639A (en) * 1994-09-21 1997-10-28 Revall Co., Ltd. Waterproof lightweight grain-tone decorative panel
US5891948A (en) * 1995-06-19 1999-04-06 Curios Co., Ltd. Coating material for forming variegated patterns of granite tone and resin flakes
JP2003126771A (en) * 2001-10-26 2003-05-07 Sk Kaken Co Ltd Method for forming decorative coating film
JP2003231862A (en) * 2002-02-08 2003-08-19 Kikusui Chemical Industries Co Ltd Aggregate-containing coating material and metal panel coated with the same
US20070106008A1 (en) * 2003-12-25 2007-05-10 Sk Kaken Co., Ltd. Aqueos coating composition

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US3098053A (en) * 1959-09-29 1963-07-16 Macmillan & Bloedel Ltd Wood patching composition containing acrylic ester polymer and method of use
US5681639A (en) * 1994-09-21 1997-10-28 Revall Co., Ltd. Waterproof lightweight grain-tone decorative panel
US5891948A (en) * 1995-06-19 1999-04-06 Curios Co., Ltd. Coating material for forming variegated patterns of granite tone and resin flakes
JP2003126771A (en) * 2001-10-26 2003-05-07 Sk Kaken Co Ltd Method for forming decorative coating film
JP2003231862A (en) * 2002-02-08 2003-08-19 Kikusui Chemical Industries Co Ltd Aggregate-containing coating material and metal panel coated with the same
US20070106008A1 (en) * 2003-12-25 2007-05-10 Sk Kaken Co., Ltd. Aqueos coating composition

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Title
DATABASE CA [online] CHEMICAL ABSTRACTS SERVICE, COLUMBUS, OHIO, US; 19 August 2006 (2006-08-19), SUZUKI, AKIRA ET AL: "Aggregate-containing coating materials and their application on metal panels", XP002657189, retrieved from STN Database accession no. 2003:644583 *
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Cited By (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP2015078288A (en) * 2013-10-16 2015-04-23 アイカ工業株式会社 Sand wall-like aqueous coating composition and method for applying the same
CN103709846A (en) * 2013-12-12 2014-04-09 上海汇丽涂料有限公司 Water-based environmental agate marble coating and preparation and construction methods thereof
CN104109439A (en) * 2014-07-28 2014-10-22 漳州三德利油漆涂料有限公司 Heat preserving really stone paint and preparation method thereof

Also Published As

Publication number Publication date
EA201291186A1 (en) 2013-09-30
FI20105638L (en) 2011-12-08
FI123441B (en) 2013-05-15
FI20105638A0 (en) 2010-06-07
EP2576709A1 (en) 2013-04-10
EA023485B1 (en) 2016-06-30
UA107496C2 (en) 2015-01-12

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