FI123441B - Manufacture of stone coatings - Google Patents
Manufacture of stone coatings Download PDFInfo
- Publication number
- FI123441B FI123441B FI20105638A FI20105638A FI123441B FI 123441 B FI123441 B FI 123441B FI 20105638 A FI20105638 A FI 20105638A FI 20105638 A FI20105638 A FI 20105638A FI 123441 B FI123441 B FI 123441B
- Authority
- FI
- Finland
- Prior art keywords
- stone
- coating
- weight
- tinting
- binder
- Prior art date
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Classifications
-
- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B41/00—After-treatment of mortars, concrete, artificial stone or ceramics; Treatment of natural stone
- C04B41/45—Coating or impregnating, e.g. injection in masonry, partial coating of green or fired ceramics, organic coating compositions for adhering together two concrete elements
- C04B41/46—Coating or impregnating, e.g. injection in masonry, partial coating of green or fired ceramics, organic coating compositions for adhering together two concrete elements with organic materials
- C04B41/48—Macromolecular compounds
- C04B41/483—Polyacrylates
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D5/00—Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
- C09D5/28—Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes for wrinkle, crackle, orange-peel, or similar decorative effects
-
- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B41/00—After-treatment of mortars, concrete, artificial stone or ceramics; Treatment of natural stone
- C04B41/45—Coating or impregnating, e.g. injection in masonry, partial coating of green or fired ceramics, organic coating compositions for adhering together two concrete elements
- C04B41/50—Coating or impregnating, e.g. injection in masonry, partial coating of green or fired ceramics, organic coating compositions for adhering together two concrete elements with inorganic materials
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D7/00—Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
- C09D7/40—Additives
- C09D7/66—Additives characterised by particle size
- C09D7/69—Particle size larger than 1000 nm
-
- E—FIXED CONSTRUCTIONS
- E04—BUILDING
- E04F—FINISHING WORK ON BUILDINGS, e.g. STAIRS, FLOORS
- E04F13/00—Coverings or linings, e.g. for walls or ceilings
- E04F13/02—Coverings or linings, e.g. for walls or ceilings of plastic materials hardening after applying, e.g. plaster
-
- E—FIXED CONSTRUCTIONS
- E04—BUILDING
- E04F—FINISHING WORK ON BUILDINGS, e.g. STAIRS, FLOORS
- E04F13/00—Coverings or linings, e.g. for walls or ceilings
- E04F13/07—Coverings or linings, e.g. for walls or ceilings composed of covering or lining elements; Sub-structures therefor; Fastening means therefor
- E04F13/08—Coverings or linings, e.g. for walls or ceilings composed of covering or lining elements; Sub-structures therefor; Fastening means therefor composed of a plurality of similar covering or lining elements
- E04F13/14—Coverings or linings, e.g. for walls or ceilings composed of covering or lining elements; Sub-structures therefor; Fastening means therefor composed of a plurality of similar covering or lining elements stone or stone-like materials, e.g. ceramics concrete; of glass or with an outer layer of stone or stone-like materials or glass
Landscapes
- Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Ceramic Engineering (AREA)
- Materials Engineering (AREA)
- Organic Chemistry (AREA)
- Structural Engineering (AREA)
- Life Sciences & Earth Sciences (AREA)
- Wood Science & Technology (AREA)
- Inorganic Chemistry (AREA)
- Nanotechnology (AREA)
- Paints Or Removers (AREA)
Description
KIVIPINNOITTEEN VALMISTUS SelitysSTONE COATING MANUFACTURE Explanation
Tekniikan ala 5 Keksintö liittyy rakennuspinnoitteiden valmistukseen ja koskee luonnonkiveä sisältävän kivipinnoitteen valmistusmenetelmää.TECHNICAL FIELD The invention relates to the manufacture of building coatings and relates to a method of manufacturing a stone coating containing natural stone.
Tekniikan taustaTechnology background
Esimerkiksi sokkeleita, julkisivuja tai sisäseiniä voidaan pinnoittaa kivirouhetta sisältävillä värjätyillä kivipinnoitteilla. Tämmöiset pinnoitteet ovat läpikuultamatto-10 mia, jolloin kivirouheen kuvio tai värisävy ei niissä näy. Tunnetaan myös pinnoitteita, joissa käytetään värjättyä kiviainesta, joka antaa pinnoitteelle oman sävynsä.For example, plinths, facades, or interior walls can be coated with colored stone coatings containing crushed stone. These types of coatings are opaque to 10 mms, which prevents the appearance of stone crust or color. Coatings are also known which use dyed aggregate which gives the coating its own color.
Keksinnön yleinen kuvausGeneral description of the invention
Nyt on keksitty itsenäisten patenttivaatimusten mukaisesti menetelmä sävytetyn kivipinnoitteen valmistamiseksi, koostumus ja sen käyttö.In accordance with the independent claims, a process for the preparation of a tinted stone coating, its composition and its use has now been invented.
15 Keksinnön mukaisesti valmistettava pinnoite sisältää luonnonkivestä murskaamalla ja seulomalla raekokoon yli 0,2 mm-enintään 3 mm saatua vääjäämätöntä kivirouhetta, akrylaattisideainetta, vettä ja yhtä tai useampaa väripigmenttiä. Väri-pigmentin määrä on 0,001-0,5 % pinnoitteen painosta.The coating to be prepared according to the invention contains unavoidable crushed stone, acrylate binder, water and one or more color pigments obtained by crushing and screening natural stone over a grain size greater than 0.2 mm to a maximum of 3 mm. The amount of color pigment is 0.001-0.5% by weight of the coating.
Keksinnön mukaisesti voidaan valmistaa läpikuultava pinnoite ja näin saada kivi-20 rouheen kuvio näkyviin, jolloin myös rouheen väri vaikuttaa kokonaissävyyn. Pinnan ulkonäkö poikkeaa näin kivikirjavuudellaan tasavärisen peittävän maalin tai pinnoitteen ja värjättyä kivirouhetta sisältävän pinnoitteen ulkonäöstä. Keksinnön mukaisen pinnoitteen visuaalinen ilme on kiviaineksen näköinen ja silti voidaan saada aikaan sävytys haluttuihin sävyihin.According to the invention, a translucent coating can be made and thus the stone-20 grain pattern is visible, whereby the color of the grain also affects the overall tone. The surface appearance thus differs from the appearance of a stone-colored overcoat or coating and a coating containing colored coarse stone. The coating of the invention has the visual appearance of a rock material and still can be tinted to the desired shades.
25 Pinnoite voidaan valmistaa siten, että sekoitetaan sideainedispersiosta, kivirouheesta, mahdollisista apuaineista ja vedestä sävytyspohja, joka sitten sävytetään sävytyspastalla. Sävytys voidaan tehdä sävytyskoneella. Sävytyspohjia valmistetaan edullisesti muutamista erilaisista kivirouheista.The coating may be prepared by mixing a binder dispersion, a crushed stone, any excipients and water, which is then tinted with a tinting paste. Tinting can be done with a tinting machine. The tinting bases are preferably made from a few different types of rock crumb.
Keksinnön mukaisesti voidaan saada rajattomasti eri sävyisiä kivipinnoitteita, joissa 30 kuitenkin luonnonkivirouheen kuvio näkyy.In accordance with the invention, unlimited stone coatings of various shades can be obtained, however, the pattern of natural rock crush is visible.
22
Keksinnön eräiden suoritusmuotojen yksityiskohtainen kuvausDetailed description of some embodiments of the invention
Pinnoite sisältää akrylaattisideainetta. Sideaine on erityisesti vesidispersiona, johon kivirouhe sekoitetaan. Dispersio valmistetaan yleensä emulsiopolymerointimene-telmällä yhdestä tai useammasta akryylihapon ja/tai metakryylihapon esteristä 1-8 5 hiiltä sisältävän alkanolin kanssa, kuten metyyliakrylaatista, etyyliakrylaatista, n-butyyliakrylaatista, isobutyyliakrylaatista, t-butyyliakrylaatista tai lauryyliakrylaatis-ta, ja mahdollisesti muista ko-monomeereistä. Ko-monomeereinä voidaan käyttää esimerkiksi styreeniä, vinyyliasetaattia, vinyyliversataattia, etyleeniä, vinyyliklori-dia, vinyylilaureaattia ja vinyyliesteriä.The coating contains an acrylate binder. In particular, the binder is in the form of an aqueous dispersion to which rock chippings are mixed. The dispersion is generally prepared by the emulsion polymerization method from one or more esters of acrylic acid and / or methacrylic acid with 1-8 carbon-containing alkanol such as methyl acrylate, ethyl acrylate, n-butyl acrylate, isobutyl acrylate, t-butyl acrylate, t-butyl acrylate, t-butyl acrylate. As co-monomers, for example, styrene, vinyl acetate, vinyl versatate, ethylene, vinyl chloride, vinyl laureate and vinyl ester may be used.
10 Polyakrylaatin tai polymetakrylaatin vesidispersiot voidaan valmistaa esimerkiksi US-patenteissa 2,795,564 ja 2,754,280 esitettyjen prosessien mukaisesti. Mono-meerien emulsiopolymerointimenetelmällä valmistetut polymeeridispersiot ovat edullisesti hienoksi dispergoituja. Polymeerin hiukkaskoko dispersiossa voi vaihdella noin 0,01 ja noin 1 mikronin välillä. Emulsiopolymeroinnin käytäntö on esitetty 15 yksityiskohtaisesti esimerkiksi D.C. Blackleyn kidassa Emulsion Polymerization (Wiley, 1975).Aqueous dispersions of polyacrylate or polymethacrylate may be prepared, for example, according to the processes disclosed in U.S. Patent Nos. 2,795,564 and 2,754,280. The polymer dispersions prepared by the emulsion polymerization process of the monomers are preferably finely dispersed. The polymer particle size in the dispersion can vary from about 0.01 to about 1 micron. The practice of emulsion polymerization is described in detail in, for example, D.C. Emulsion Polymerization (Wiley, 1975) in Blackley Kid.
Sideaineen määrä voi olla esimerkiksi 2,5 - 40 %, edullisesti 2,5-20 %, edullisimmin 4-15 % pinnoitteen painosta. Tällöin esimerkiksi 50 % kuiva-ainetta sisältävän dispersion määrä on 5-80 %, edullisesti 5-40 %, edullisimmin 8-30 % pin-20 noitteen painosta.The amount of binder may be, for example, from 2.5 to 40%, preferably from 2.5 to 20%, most preferably from 4 to 15% by weight of the coating. Thus, for example, the amount of the dispersion containing 50% solids is 5-80%, preferably 5-40%, most preferably 8-30% by weight of the pin-20 binder.
Pinnoitteessa käytettävät kivirouheet ovat valmistetut luonnonkivestä murskaamalla ja seulomalla. Kivirouhe on seulottu raekokoon yli 0,2 mm-enintään 3 mm, edullisesti yli 0,6-enintään 1,4 mm. Kiviaineena voidaan käyttää esimerkiksi harmaata ja punaista graniittia, kalkkikiveä, dolomiittia ja mustaa gabroa. Kiviaineen 25 pitoisuus kivipinnoitteessa voi olla esimerkiksi 20-95 paino-%, edullisesti 40-80 paino-%, edullisimmin 50-70 paino-%. Kivirouhetta ei ole pinnoitettu esimerkiksi orgaanisella tai epäorgaanisella väriaineella tai orgaanisella tai epäorgaanisella pinnoitteella kuten esimerkiksi epoksilla.Coarse grains used in the coating are made from natural stone by crushing and screening. The rock grit is screened to a grain size greater than 0.2 mm to no more than 3 mm, preferably greater than 0.6 to no more than 1.4 mm. The aggregates used are, for example, gray and red granite, limestone, dolomite and black gabbro. The content of aggregate 25 in the stone coating may be, for example, 20-95% by weight, preferably 40-80% by weight, most preferably 50-70% by weight. The rock crush is not coated with, for example, an organic or inorganic dye or an organic or inorganic coating such as epoxy.
Kivipinnoite on mahdollista väijätä tuhansin värisävyin sävytyskoneella. Väripig-30 mentteinä voidaan käyttää esimerkiksi seuraavia väri-indeksin väripigmenttejä ja niiden seoksia: PW6, PY74, PY42, PR101, PG7, PB15:3 ja PBk7. Parhaiten väripigmentti lisätään seokseen sävytyspastan muodossa. Tyypillisiä sävytyspastoja ovat esimerkiksi Monicolor C tai Monicolor E sävytysjäijestelmän pastat.It is possible to ambush the stone coating in thousands of colors with a tinting machine. As color pigments, the following color index color pigments and mixtures thereof may be used: PW6, PY74, PY42, PR101, PG7, PB15: 3 and PBk7. Preferably, the color pigment is added to the mixture in the form of a tinting paste. Typical tinting pastes are, for example, Monicolor C or Monicolor E tinting pastes.
3 Väripigmentin määrä on 0,001-0,5 %, edullisesti 0,002-0,3 %, pinnoitteen painosta. Näin pienellä pigmenttipitoisuudella voidaan aikaansaada sävytetty mutta läpikuultava pinnoite, jossa myös luonnonkiven kuviointi saadaan näkyviin ja jossa luonnonkiven väri osaltaan vaikuttaa kokonaissävyyn. Sävytys voidaan tehdä 5 myyntipisteessä samalla sävytyskoneella kuin maalien sävytyskin.The amount of color pigment is 0.001-0.5%, preferably 0.002-0.3%, by weight of the coating. With such a low pigment content, a tinted but translucent coating can be achieved, where the natural stone pattern is also visible and the color of the natural stone contributes to the overall tone. Tinting can be done in 5 outlets using the same tinting machine as paint tinting.
Kivipinnoitteen valmistamiseen voidaan sideaineen, kivirouheen ja väripigmentin lisäksi käyttää apuaineita. Näitä voivat olla esimerkiksi vesi, Teologiset apuaineet, kuten paksuntajat, säilöntäaineet, vaahdonestäjät, liuottimet, kuten kalvonmuo-dostusliuottimet, kuivan kalvon biosidit ja himmennysaineet.In addition to the binder, the crushed stone and the color pigment, adjuvants may be used to make the stone coating. These may include, for example, water, theological excipients such as thickeners, preservatives, anti-foaming agents, solvents such as film-forming solvents, dry film biocides, and antifouling agents.
10 Pinnoitteen käyttökohteita ovat esimerkiksi ulkona sokkelit, mineraaliset julkisivut ja parvekkeiden seinä- ja pielipinnat ja sisällä sisäseinä- ja kattopinnat sekä varusteet, kuten takkojen ulkopinnat, ja koriste-esineet. Työstötapoina voi olla esimerkiksi (teräs)lastalevitys, ruiskutus ja telaus. Tarvittaessa pinta voidaan levityksen jälkeen kuvioida harjalla, hiertimellä tai kuviointilastalla.10 Coating applications include outdoor plinths, mineral façades, wall and ceiling surfaces in balconies, and interior wall and ceiling surfaces, as well as fixtures such as fireplaces and decorative items. Machining methods may include, for example, (steel) blade application, spraying and rolling. If necessary, the surface can be patterned with a brush, a trowel or a trowel after application.
15 Esimerkki 1 288 grammaan akrylaatin ja metakrylaatin kopolymeeridispersiota (kuiva-aine 50 paino-%) lisättiin 280,8 g vettä sekä 7,5 g hydroksietyyliselluloosaa (Natrosol 250 HHBR) sekoitettiin 5 minuuttia. Näin saatuun seokseen lisättiin hitaasti 864 g harmaata g ra n i i tti ki vi rou hetta kooltaan 0,6-1,2 mm koko ajan sekoittaen. Seos siirret- 20 tiin suljettavaan ravistuksen kestävään astiaan ja siihen lisättiin COROB™ D300 sävytyskoneella PR101 väripigmenttiä sävytyspastan muodossa 0,52 g. Astia suljettiin ja ravistettiin COROB™ SIMPLEshake 40 laitteella seoksen värjäämiseksi ta-savärisen kuultavaksi väripigmentillä. Kivipinnoitteen lopullinen väripigmenttipitoi-suus oli 0,28 p-%.Example 1 288.8 g of water were added to 288 g of a copolymer dispersion of acrylate and methacrylate (dry weight 50%) and 7.5 g of hydroxyethylcellulose (Natrosol 250 HHBR) was stirred for 5 minutes. To the mixture thus obtained was slowly added 864 g of a gray g granitic crush of 0.6 to 1.2 mm in size with constant stirring. The mixture was transferred to a sealable shake-resistant vessel and 0.52 g of the color pigment in the form of a tinting paste was added to the COROB ™ D300 PR101 tinting machine. The vessel was sealed and shaken with a COROB ™ SIMPLEshake 40 instrument to stain the mixture to even color with a pigment. The final color pigment content of the stone coating was 0.28% by weight.
2525
Claims (9)
Priority Applications (5)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
FI20105638A FI123441B (en) | 2010-06-07 | 2010-06-07 | Manufacture of stone coatings |
EA201291186A EA023485B1 (en) | 2010-06-07 | 2011-06-06 | Method of manufacturing a stone coating |
PCT/FI2011/050522 WO2011154596A1 (en) | 2010-06-07 | 2011-06-06 | Manufacturing of stone coating |
UAA201213626A UA107496C2 (en) | 2010-06-07 | 2011-06-06 | Manufacturing of stone coating |
EP11736119.6A EP2576709A1 (en) | 2010-06-07 | 2011-06-06 | Manufacturing of stone coating |
Applications Claiming Priority (2)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
FI20105638 | 2010-06-07 | ||
FI20105638A FI123441B (en) | 2010-06-07 | 2010-06-07 | Manufacture of stone coatings |
Publications (3)
Publication Number | Publication Date |
---|---|
FI20105638A0 FI20105638A0 (en) | 2010-06-07 |
FI20105638L FI20105638L (en) | 2011-12-08 |
FI123441B true FI123441B (en) | 2013-05-15 |
Family
ID=42308095
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
FI20105638A FI123441B (en) | 2010-06-07 | 2010-06-07 | Manufacture of stone coatings |
Country Status (5)
Country | Link |
---|---|
EP (1) | EP2576709A1 (en) |
EA (1) | EA023485B1 (en) |
FI (1) | FI123441B (en) |
UA (1) | UA107496C2 (en) |
WO (1) | WO2011154596A1 (en) |
Families Citing this family (5)
Publication number | Priority date | Publication date | Assignee | Title |
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JP6177657B2 (en) * | 2013-10-16 | 2017-08-09 | アイカ工業株式会社 | Sand wall-like water-based paint composition and construction method thereof |
CN103709846A (en) * | 2013-12-12 | 2014-04-09 | 上海汇丽涂料有限公司 | Water-based environmental agate marble coating and preparation and construction methods thereof |
CN104109439B (en) * | 2014-07-28 | 2016-03-30 | 漳州三德利油漆涂料有限公司 | True mineral varnish of a kind of insulation and preparation method thereof |
RU2729759C1 (en) * | 2019-12-11 | 2020-08-12 | Денис Александрович Фомахин | Method of producing decorative art coating on the surface of flat cork panels |
CN112126295A (en) * | 2020-09-16 | 2020-12-25 | 漆仙姑新材料技术重庆有限公司 | Nano hydrophobic texture real stone paint |
Family Cites Families (6)
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US3098053A (en) * | 1959-09-29 | 1963-07-16 | Macmillan & Bloedel Ltd | Wood patching composition containing acrylic ester polymer and method of use |
US5681639A (en) * | 1994-09-21 | 1997-10-28 | Revall Co., Ltd. | Waterproof lightweight grain-tone decorative panel |
JP2832424B2 (en) * | 1995-06-19 | 1998-12-09 | クリオス株式会社 | Coating materials for forming granite-like colorful patterns and resin flakes used for them |
JP3835678B2 (en) * | 2001-10-26 | 2006-10-18 | エスケー化研株式会社 | Method for forming decorative coating |
JP2003231862A (en) * | 2002-02-08 | 2003-08-19 | Kikusui Chemical Industries Co Ltd | Aggregate-containing coating material and metal panel coated with the same |
WO2005063899A1 (en) * | 2003-12-25 | 2005-07-14 | Sk Kaken Co., Ltd. | Aqueous coating composition |
-
2010
- 2010-06-07 FI FI20105638A patent/FI123441B/en active IP Right Grant
-
2011
- 2011-06-06 EP EP11736119.6A patent/EP2576709A1/en not_active Withdrawn
- 2011-06-06 UA UAA201213626A patent/UA107496C2/en unknown
- 2011-06-06 WO PCT/FI2011/050522 patent/WO2011154596A1/en active Application Filing
- 2011-06-06 EA EA201291186A patent/EA023485B1/en not_active IP Right Cessation
Also Published As
Publication number | Publication date |
---|---|
EA201291186A1 (en) | 2013-09-30 |
FI20105638A0 (en) | 2010-06-07 |
FI20105638L (en) | 2011-12-08 |
UA107496C2 (en) | 2015-01-12 |
WO2011154596A1 (en) | 2011-12-15 |
EP2576709A1 (en) | 2013-04-10 |
EA023485B1 (en) | 2016-06-30 |
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