WO2011150588A1 - 废旧塑料、轮胎、废机油的再生能源综合利用生产装备 - Google Patents

废旧塑料、轮胎、废机油的再生能源综合利用生产装备 Download PDF

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WO2011150588A1
WO2011150588A1 PCT/CN2010/075550 CN2010075550W WO2011150588A1 WO 2011150588 A1 WO2011150588 A1 WO 2011150588A1 CN 2010075550 W CN2010075550 W CN 2010075550W WO 2011150588 A1 WO2011150588 A1 WO 2011150588A1
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gas
water
waste
oil
pipe
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PCT/CN2010/075550
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English (en)
French (fr)
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李国声
许文姬
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华南再生资源(中山)有限公司
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Publication of WO2011150588A1 publication Critical patent/WO2011150588A1/zh

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    • CCHEMISTRY; METALLURGY
    • C01INORGANIC CHEMISTRY
    • C01GCOMPOUNDS CONTAINING METALS NOT COVERED BY SUBCLASSES C01D OR C01F
    • C01G1/00Methods of preparing compounds of metals not covered by subclasses C01B, C01C, C01D, or C01F, in general
    • C01G1/10Sulfates
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02PCLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
    • Y02P20/00Technologies relating to chemical industry
    • Y02P20/10Process efficiency
    • Y02P20/129Energy recovery, e.g. by cogeneration, H2recovery or pressure recovery turbines
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02PCLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
    • Y02P20/00Technologies relating to chemical industry
    • Y02P20/10Process efficiency
    • Y02P20/133Renewable energy sources, e.g. sunlight

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  • the invention discloses a comprehensive utilization production equipment for waste energy of waste plastics, tires and waste engine oil, in particular, all kinds of substances generated in the whole process of the production process directly pass all the residual slag, gas and water through the interconnection system of the equipment. All of them cause products with greater economic value.
  • the combustible gas (non-toxic gas) produced in waste plastics and tire refining is only burned back to the furnace, but in actual production, when the gas is generated and the burning time for the cracking furnace is two concepts, the gas is burned back at the furnace. By the time the cracking is completed, the gas is only burned back to two-thirds, and the remaining combustible gas can only be discharged to the sky. From the above-mentioned environmentally-friendly recycling equipment, it is actually not environmentally friendly and may cause another The problem of secondary pollution, while wasting a lot of economically valuable reusable resources, is indeed a defect.
  • the regenerative energy comprehensive utilization production equipment of the invention generally comprises a cracking catalytic furnace, which is horizontally built-in and can be rotated 360 degrees in reverse, and has an automatic random scraping wall reaction kettle, as the applicant first
  • the tail gas environmental protection device system is the fuel cracking furnace tail gas treatment system mentioned in the application file of the applicant's prior application patent application number CN201010168879.2; and the water washer provided with the double water seal safety device for ensuring the safe movement of the gas.
  • the purpose of the invention is to solve the defects of the existing recycling environmental protection equipment, and provide a complete set of production equipment for comprehensive utilization of renewable resources of waste plastics, tires and waste engine oil, which can fully utilize the renewable energy to make slag, water and gas.
  • the development and utilization of thermal energy cycle has formed a circular environmental protection production chain with considerable economic value, which has greatly changed the individual functions of existing equipment.
  • This kind of waste plastics, tires, and waste engine oil comprehensive utilization production equipment including the main equipment, second-stage equipment, third-pole equipment, cracking furnace tail gas treatment and environmental protection system, flammable gas power generation recycling system, hot gas Recycling system and environmentally friendly high energy low sulfur coal system.
  • the main equipment includes: a pneumatic automatic feeding machine that transports petroleum product waste to a rail by using a conveyor belt as a starting point, and the raw material is pushed into a cracking catalytic furnace for cracking and catalyzing to obtain an oil and gas mixture, and the cracking catalytic furnace belt There is a reactor with a scraping knife that is automatically and randomly set. At the same time, the furnace body is connected with a cracking tail gas environmental protection device system. With the subsequent equipment sequence, the gas wax oil separator is used as the first separation of the oil and gas in the oil and gas produced by the cracking catalytic furnace.
  • the tool is further connected with a first-stage condenser, a water-sealed gas oil separator, a water seal safety device, a water-sealed negative pressure device, and a heavy oil carrying container, and when the oil and gas mixture enters the mixed oil carrying container through the horizontal condenser, The flammable gas that has not been liquefied then enters the vertical gas neutralizing water scrubber.
  • the water scrubber is equipped with a double water seal safety device, and the combustible gas is washed by the water washer and then enters the recycling system of the combustible gas power generation.
  • the second stage device comprises a distillation catalytic tower, the distillate of the device is derived from the mixed oil in the mixed oil carrying container in the main equipment, and the heating method of the distillation catalytic tower adopts the thyristor intermediate frequency heating method and has an intermediate frequency heating method.
  • the device is connected with the distillation catalytic tower.
  • the third-stage device is a diesel scouring machine gasoline degumming device, which is started from a first-stage chemical decarburization and de-synthesis synthesizer, and is subjected to a carbon removal polishing device, a dewaxing degumming device, and the second-stage device.
  • the oil in the diesel and gasoline carrying container enters the dewaxing and degreasing device through an input pipe.
  • the dewaxing degreaser is a cone-shaped cone agitator, the vertical baffle is arranged in the stirrer, and the bottom is provided with agitating
  • the boiling device stirs the flow pattern in a shear flow mode; the chemical agent device to be added is disposed in the additive container, and is divided into a chemical agent addition zone and an alkaline liquid addition zone, and the treated useful product is then transported to the slag liquid.
  • the separator is filtered from 200 mesh to 350 mesh, and the filtered fluid is sent to the refined oil synthesis tank.
  • the working form of the tank is separated by secondary filtration.
  • the first stage is reverse pressure filtration, and the second stage is smooth.
  • the secondary filter layer is provided with a filter medium carrying orifice plate, the filter medium is a solid granular material, and the chemical additive added to the filtrate is placed in the additive container, and the obtained oil is inspected after the above treatment.
  • the waste generated by each refining stage is transported by the special conveying device to the environmentally-friendly high-energy low-sulfur coal system for reuse.
  • the exhaust gas and waste smell generated by each refining stage pass through the special exhaust pipe through the water bath and the activated carbon filter. discharge.
  • the decarburization and decontamination synthesizer, the decarburization degreasing device, the lower end of the dewaxing degumming device are connected with the waste residue removing pipeline and are sent to the environmental high-energy low-sulfur coal system by compressed air pressure, and the slag liquid separating machine to the refined oil synthesis
  • An additive container is also provided between the cans.
  • the cracking furnace tail gas treatment environmental protection device system is connected to the exhaust port of the thermal cracking furnace, and the system comprises a multiple water curtain exhaust pipe, and the exhaust port of the multiple water curtain exhaust pipe is connected to the furnace body combustion chamber, the middle It is equipped with a hot gas water buffer chamber.
  • the lower part of the buffer chamber is equipped with a double wet carbon particle filter, and the other end is connected with a double tower type wet gas-solid separator.
  • the tail end of the gas-solid separator is connected to the air inlet by a pipe, and the lower end is connected by a pipe.
  • the water pipe in the rear part of the device uses the pressure of the air inlet to push the water into the chimney at the tail of the equipment.
  • the chimney consists of three parts, the lower part is a water-gas separator of the drum-shaped body, and the middle is used for gas phase separation.
  • the heat exchanger has an exhaust pipe at the upper part and an alkaline water sprayer in the middle of the pipe.
  • the combustible gas power generation recycling system is connected to the gas pipeline in the main equipment, and when the gas is compressed to 0.5 MPA by a special gas compressor and simultaneously acts as a first-stage gas dehydration, the gas is sent to the second-stage special gas.
  • the compressor which compresses the gas to 1MPA and simultaneously acts as a second gas dehydration, sends the combustible gas to the gas storage container, the reservoir is provided with two air outlets, and the air outlet is connected to the heat of the main device.
  • the cracking furnace is used as the fuel of the furnace, and the gas passing method is sent by the second pressure reduction.
  • the first decompression is decompressed to 0.4-0.5 MPA by the decompression device, and 0.4-0.5 by the second decompression device.
  • the MPA is reduced to 0.1-0.2MPA and sent to the furnace for combustion; the other outlet is connected to the gas fuel generator (42), and the flammable gas is passed through another decompression device to reduce the pressure to 0.1-0.5 MPA before entering the gaseous fuel.
  • the generator and generator are mechanically mixed.
  • the hot gas recovery system collects hot gas generated by the working operation of the generator through a gas-water exchanger, and the gas-water exchanger adopts a heat conduction type of a heat conduction pipe, and the heat transfer system of the copper is 1000 times or more through the heat conduction pipe.
  • the heat is transferred to the circulating water, and the hot water is sent to the wind cabinet through the heat pump, and then the hot air of 120 degrees or more is sent to the drying equipment of the environmental protection high-energy low-sulfur coal system through the hot air outlet pipe, and the heat exchange is performed by the heat exchange. After the hot air is cooled by the heat exchanger, it is discharged through the flue gas passage.
  • the heat conducting pipe is a plurality of vacuum heat pipes, and a metal heat dissipating wheel is disposed at one end of the vacuum heat pipe, and a smoke water partition layer and a heat insulating layer are disposed between the adjacent vacuum heat pipes, and the gas-water exchanger is disposed at one end.
  • a hot gas introduction pipe and a muffler There is a hot gas introduction pipe and a muffler, a carbon dust cleaning port is arranged at the bottom, a sewage discharge port is arranged at one end of the hot gas introduction pipe, and a circulating hot water pipe is connected to the heat pump and the gas-water heat exchanger, and the heat exchange is performed.
  • the device is disposed at the other end of the oppositely disposed sewage discharge port of the gas-water heat exchanger, the upper and lower ends of the heat exchanger are provided with a circulating cold water outlet, the upper end is provided with a circulating cold water inlet, and the end is provided with a circulating hot water pipe and a wind cabinet Connected.
  • the environmentally-friendly high-energy low-sulfur coal system reuses waste plastics, waste tires, and residual slag which cannot be vaporized during refining, that is, crude black carbon, including artificial aging devices for aging coarse carbon black, and then
  • the steam treatment is carried out, and the treated crude carbon black is used as the main material, and the compatibility materials are added thereto, and the compatibility materials are raw coal, ferrocene, hexamethylene tetraammonium, sodium hydroxide, quicklime and binder, forming
  • the coal base material wherein the main material accounts for 45%-60% by weight of the coal base material; then the coal base material is made into finished coal, and the crude carbon black is conveyed through the ground auger and the carbon black input belt.
  • Integrating the individuality of existing equipment compared with the single environmentally friendly production concept of the existing single technology, can effectively eliminate the secondary pollution caused by the residues of environmentally friendly production on the land and air environment, or because of a single environmentally friendly production method.
  • the more dangerous pollution before; the system equipment of the invention is a set of environmentally-friendly production and recycling equipment, from the first environmental protection production to the residual slag and harmful gases, high temperature gas for the second environmentally friendly production Reuse, can play a circular industrial chain of real waste environmental protection production, may achieve or achieve no sewage discharge, smokeless dust emissions, no room temperature emissions, no harmful gas emissions, no odor, no irritating odor emissions, low noise, self-produce Good benefits of energy recycling.
  • Figure 1 is a general view of the production equipment for the comprehensive utilization of recycled energy of waste plastics, tires and waste engine oil.
  • Figure 2 is a perspective view of the main body of Figure 1.
  • Figure 3 is another view of the main unit of Figure 2.
  • FIG. 4A is a cross-sectional view of the reactor of FIG. 1.
  • Figure 4B is a diagram of a cracking furnace cooperating with Figure 4A.
  • Figure 5 is a diagram showing the third stage device being a diesel refining machine for gasoline degumming.
  • Figure 6 is a system diagram of the environmental protection device for the cracking furnace tail gas treatment.
  • Figure 7 is a chimney diagram of Figure 6.
  • Figure 8 is a diagram of a hot gas recovery system.
  • Figure 9 is a diagram of a combustible gas power generation reuse system.
  • Figure 10 is a diagram of an environmentally friendly high-energy low-sulfur coal system.
  • the recycled energy comprehensive utilization production equipment of waste plastics, tires and waste engine oil includes the main equipment, the second-stage device, the third-pole device, the cracking furnace tail gas treatment and environmental protection system. Recycling system for combustible gas power generation, hot gas recovery system, and environmentally friendly high-energy low-sulfur coal system.
  • the main equipment includes: a pneumatic automatic feeder 1 for transporting petroleum product waste to a rail by using a conveyor belt 2 as a starting point, and propelling the raw material into a cracking catalytic furnace 3 for cracking and catalyzing to obtain an oil and gas mixture, the cracking
  • the catalytic furnace is provided with an automatically randomly arranged reaction vessel 5 with a scraping knife 4, and the furnace body is connected with a cracking tail gas environmental protection device system, and the subsequent stage equipment is sequentially produced by the pyrolysis catalyst furnace as a gas wax oil separator 6
  • the first separation tool for the wax oil in the oil and gas and then connected with the first stage condenser 7, the water-sealed gas oil separator 8, the water seal safety device 9, the water seal type negative pressure device 10, the heavy oil carrying container 11, when the oil and gas mixture
  • the horizontal condenser 12 enters the mixed oil carrying container 13 , and the flammable gas that has not been liquefied enters the vertical gas neutralizing water washer 14 , and the water washer is
  • the second stage device comprises a distillation catalytic tower 16, the distillate of the device is derived from the mixed oil in the mixed oil carrying container 13 in the main equipment, and the heating method of the distillation catalytic tower adopts the thyristor intermediate frequency heating method, and has a
  • the intermediate frequency heating device 17 is connected to the distillation catalytic tower.
  • the third-stage device is a diesel refining machine gasoline degumming device, which is started from a first-stage chemical decarburization and decontamination synthesizer 21, and is subjected to a decarburization polishing device 22 and a dewaxing degumming device 23,
  • the oil in the diesel and gasoline carrying container 11 in the secondary device enters the dewaxing and degreaser through an input pipe, and the dewaxing and degreaser is a cone-shaped agitator, and the vertical baffle is arranged in the stirrer.
  • the bottom is provided with a stirring boiling device, and the stirring flow type is agitated by a shear flow; the chemical device to be added is disposed in the additive container 24, and is divided into a chemical agent addition zone and an alkaline liquid addition zone, and the treated utility is processed.
  • the machine filter from 200 mesh to 350 mesh
  • the filtered fluid is sent to the refined oil synthesis tank 26
  • the working mode of the tank is separated by secondary filtration
  • the first stage is reverse pressure Filtration
  • the second stage is the forward filtration
  • the secondary filtration layer is provided with a filter medium bearing orifice plate
  • the filter medium is a solid granular material
  • the chemical additive added to the filtrate is placed in the additive container 24, After the oil obtained after treatment, it has passed the inspection.
  • the waste generated by each refining stage is transported by the special conveying device to the environmentally-friendly high-energy low-sulfur coal system for reuse.
  • the exhaust gas and waste smell generated by each refining stage pass through the special bath and pass through the water bath and the activity.
  • the carbon filter is discharged.
  • the decarburization and decontamination synthesizer 21, the carbon removal refiner 22, the dewaxing and degumming device 23 are connected to the waste residue removal pipe 49 at the lower end, and are compressed by the compressed air 50 to the environmentally-friendly high-energy low-sulfur coal system for separation in the slag liquid.
  • An additive container 24 is also provided between the machine and the refined oil synthesis tank 26.
  • the cracking furnace tail gas treatment environmental protection device system is connected to the exhaust port of the thermal cracking furnace, and the system comprises a multiple water curtain exhaust pipe 27, and the exhaust port of the multiple water curtain exhaust pipe is connected to the furnace body combustion chamber.
  • the middle part is provided with a hot gas water buffer chamber 28, the lower part of the buffer chamber is provided with a double wet carbon particle filter 29, and the other end is connected with a double tower type wet gas-solid separator 30, and the tail end of the gas-solid separator is connected to the air blower 31 by a pipe, and the lower end
  • the water pipe of the rear part of the air blower is connected by a pipe, and the water pipe pushes the water gas into the chimney 32 at the tail of the equipment by using the pressure of the air blower.
  • the chimney is composed of three parts, and the lower part is a water gas separator 33 of the drum can body.
  • the middle portion is a heat exchanger 34 for gas phase separation, and the upper portion is an exhaust pipe 35, and an intermediate water liquid shower 36 is installed in the middle of the pipe.
  • the combustible gas power generation recycling system is connected to the gas pipeline 37 in the main equipment, and when the gas is compressed to 0.5 MPA by a special gas compressor and simultaneously acts as a first-stage gas dehydration, the gas is sent to the second-stage dedicated
  • the gas compressor 38 which compresses the gas to 1MPA and simultaneously performs the second gas dehydration, sends the combustible gas to the gas storage container 39.
  • the reservoir is provided with two air outlets, and one air outlet leads to the main body.
  • the thermal cracking furnace of the equipment is used as the fuel of the furnace, and the gas passing method is sent through the second pressure reduction.
  • the first decompression is decompressed to 0.4-0.5 MPA by the decompression device 40, and then passed through the second decompression device.
  • the generator 41 is reduced from 0.4-0.5 MPA to 0.1-0.2 MPA and sent to the furnace for combustion; the other outlet port leads to the gas fuel generator 42, and the flammable gas passing method is decompressed to 0.1-0.5 MPA by another decompression device.
  • the generator uses mechanical internal mixing.
  • the hot gas recovery system collects hot air generated by the working operation of the generator 42 through the gas-water exchanger 43 for heat transfer, and the gas-water exchanger adopts a heat conduction type of a heat transfer tube, and a heat transfer system of copper through the heat transfer tube 51. More than 1000 times of heat is transferred to the circulating water, and the hot water is sent to the wind cabinet 45 through the heat pump 44, and then the hot air of 120 degrees or more is sent to the drying equipment of the environmentally-friendly high-energy low-sulfur coal system by the hot air outlet tube 62.
  • the hot air of the heat exchanger that has undergone heat exchange is cooled by the heat exchanger 46 and then discharged through the flue gas passage 63.
  • the heat conducting pipe is a plurality of vacuum heat pipes 51, and a metal heat dissipating gun 54 is disposed at one end of the vacuum heat pipe, and a smoke water partition 55 and a heat insulating layer 64 are disposed between the adjacent vacuum heat pipes, the gas-water One end of the exchanger 43 is provided with a hot gas introduction pipe 52 and a muffler 53, a carbon dust cleaning port 56 is disposed at the bottom, and a sewage discharge port 57 is disposed at one end of the hot gas introduction pipe, and a circulating hot water pipe 58 is connected to the heat pump 44.
  • the gas-water heat exchanger 43 is disposed at the other end of the oppositely disposed sewage discharge port of the gas-water heat exchanger.
  • the upper and lower ends of the heat exchanger are provided with a circulating cold water outlet 59, and the upper end is provided with circulating cold water.
  • the inlet 60 is connected to the wind cabinet by a circulating hot water pipe 61.
  • the environmentally-friendly high-energy low-sulfur coal system reuses the waste plastic, the waste tire, and the residual slag which cannot be vaporized in the refining process, that is, the crude black carbon, including the artificial aging device 47 for aging the coarse carbon black, and then After being treated by the hot steam processor 48, the treated crude carbon black is used as a main material, and the compatibility materials are added thereto, and the compatibility materials are raw coal, ferrocene, hexamethylene tetraammonium, sodium hydroxide, quicklime and binder. Forming a coal base in which the weight percentage of the main material in the coal base material is 45% to 60%; then the coal base material is made into a finished coal, and the crude carbon black passes through the ground auger 64 and carbon black The input belt 65 is transported.
  • the water content is reduced to 20%, and the hot air is derived from the hot gas recovery system of Figure 8.
  • the work is processed by the heat energy collector 66, and the dried waste plastic is continuously sent to the thermal cracking furnace 3 through the conveyor belt, and the feeding amount is 14 tons (calculated by two furnaces), and the fuel is used from the start of heating to the completion of the cracking.
  • the additional materials are catalysts such as aluminum, zinc and calcium oxide.
  • the ratio is 1.5% of the weight of the added raw materials after dehydration, the equipment power is 336 degrees, the production cycle time is 28 hours, and the production gas and diesel mixed oil is 11.62.
  • Tons the residue of cracking, that is, 60Kg of crude carbon black, is sent to the high-energy low-sulfur coal production system for reuse treatment together with the wet carbon powder collected in the exhaust gas environmental protection treatment system of the thermal cracking furnace, and at the same time through the refining process.
  • the flammable gas produced is about 872 M3, this combustible gas Co20-24%, carbon dioxide Co2 1-3%, hydrogen H2 8-12%, CmHn is mainly methane 3-4.2%, etc., and the combustible gas is cleaned and tar removed and compressed and sent to the gas storage container 39 for gas power generation.
  • the mixed oil after cracking enters the second-stage device.
  • the daily processing capacity of the system is 14 tons.
  • the heating tool of the device is 110KW of the thyristor intermediate frequency heating device, and the produced gas and diesel mixed oil are cut after the line is cut. It takes 750 degrees of electricity.
  • the diesel and gasoline in the fraction are sent to the refining device for treatment, and after cleaning, deodorization, decolorization, degumming, dewaxing, etc., the total amount of diesel and gasoline obtained is 10.67 tons.
  • the diesel oil is processed and synthesized, it can reach the national standard II, and the gasoline is 93# gasoline.
  • the residue in the treatment process is alkalized, and the fully sealed conveying tool is generally used to feed the high-energy low-sulfur coal production system for reuse. deal with.
  • the combustible gas output from the gas storage container is decompressed and then enters the internal mixed gas generator.
  • the 500KW/h product of the Jinan Diesel Generator Factory can be used, and the above-mentioned 872m3 after the second stage treatment can be used.
  • the gas can generate 3,925 degrees of heat, and the hot gas generated during the power generation process is replaced by hot air by the heat recovery and reuse system, and the hot water of the hot cracking furnace is replaced by the hot water to be fed into the first stage. Air drying equipment is reused.
  • This embodiment takes waste plastic refining as an example, and all the principles and basic structures are the same as or similar to those of the present embodiment, and are within the protection scope of the present invention.
  • the integration of the individual items of the existing equipment can effectively eliminate the secondary pollution caused by the residues of the environmentally friendly production to the land and the air environment, compared with the single environmentally friendly production concept of the existing single technology.
  • the system equipment of the present invention is a group of environmentally friendly production and recycling equipment, from the first environmentally friendly production to the remaining slag and harmful gases, high temperature gases.
  • environmental protection production reuse it can play a real waste environmental protection production cycle economic chain, which may reach or achieve no sewage discharge, smokeless dust emission, no room temperature emission, no harmful gas emissions, no odor, no irritating smell Good benefits of emissions, low noise, and self-produced energy recycling.

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  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Inorganic Chemistry (AREA)
  • Production Of Liquid Hydrocarbon Mixture For Refining Petroleum (AREA)
  • Separation, Recovery Or Treatment Of Waste Materials Containing Plastics (AREA)
  • Processing Of Solid Wastes (AREA)

Description

废旧塑料、轮胎、废机油的再生能源综合利用生产装备 技术领域
本发明公开一套废旧塑料、轮胎、废机油的再生能源综合利用生产装备,特别是该装备在全程的生产过程中所产生的各类物质直接通过设备的互联系统将所有剩余渣、气、水等全部造成具较大经济价值的产品。
背景技术
随着环保工业的持续发展,已将环保处理的实质应用日趋商业化方向,发展废旧塑料、轮胎、废机油的再生资源利用也趋向成熟,但是这些项目现时大部分都是在单一利用和发展,在再生利用过程中的剩余产物没有进行循环利用的全面思考。例如:以单一废旧塑料、轮胎炼油设备为例,大多数的设备基本没有考虑到真正的尾气环保处理,也没有考虑到热气回收再利用的课题,对于炼油的剩余物粗杂黑的安全环保处理更是轻描淡说或根本置于不理。在废旧塑料、轮胎炼油所产生的可燃气体(无毒气体),只是回炉燃烧,但是在实在生产中,当产生气体的时间与用于裂解炉的燃烧时间是两个概念,根本在气体回炉燃烧至裂解完成的这一时间内,气体的回烧量只有三分之二,剩余的可燃烧气体就只能向天排放,从上述所指出的环保再生设备,其实还是不环保的,可能再次造成二次污染问题,同时把大量有经济价值的可再利用资源白白浪费,的确是一种缺陷。本发明的再生能源综合利用生产装备,一般来说,包括有裂解催化炉,该裂解催化炉是卧式内置可顺逆旋转360度,并带自动随机刮壁式反应釜,如申请人在先申请的专利申请号为CN201010148298.2及CN201010147465.1的申请文件中所提到的反应釜刮壁器和与其配合的一种卧式废旧塑料、轮胎裂解炉;同时,该裂解炉体接有的尾气环保装置系统如申请人在先申请的专利申请号为CN201010168879.2的申请文件中提到的燃料裂解炉尾气处理系统;以及为了确保燃气安全运动而设置有附设双重水封安全装置的水洗器,具体结构在发明人在先申请且已授权的专利号为CN200510037543.1的申请文件中所提及;另外,该系统设备中用到的蒸馏催化塔的加热方式采用可控硅中频加热方法,具体结构在发明人直属子公司在先申请且已授权的专利号为CN200510101143.2的申请文件中所提及;该系统设备中用到的环保高能低硫煤系统具体使用方法在申请人在先申请的专利申请号为CN201010148172.5的申请文件中已经提及。
技术问题
发明的目的在于解决现有再生环保设备的缺陷问题,而提供一整套废旧塑料、轮胎、废机油的再生资源综合利用的生产设备,该设备能够较充分的利用再生能源,使渣、水、气、热能循环发展利用,形成具有可观经济价值的循环环保生产链,大大改变了现有装备的单项功能。
技术解决方案
为实现上述目的,本发明采用了下述技术方案:
这种废旧塑料、轮胎、废机油的再生能源综合利用生产装备,包括相互配合的主体设备、第二级装置、第三极装置、裂解炉尾气处理环保系统、可燃气体发电的再利用系统、热气回收系统以及环保高能低硫煤系统。
其中所述的主体设备包括:由输送带为起点,将石油产品废弃物输送到由路轨移动的气压式自动进料机,将原料推进裂解催化炉进行裂解催化得到油气混合物,该裂解催化炉带有一个自动随机设置的带有刮壁刀的反应釜,同时炉体接有裂解尾气环保装置系统,随之后级设备顺序为气蜡油分离器作为由裂解催化炉所产生油气里蜡油首次分离工具,再依次连接有第一级冷凝器、水封式气油分离器、水封安全装置、水封式负压装置、重油承载容器,当油气混合物经卧式冷凝器进入混合油承载容器,未能液化的可燃气体随之进入立式燃气中和水洗器),该水洗器附设双重水封安全装置,可燃气体经水洗器水洗后进入可燃气体发电的再利用系统。
所述的第二级装置包括蒸馏催化塔,该设备的被蒸馏物来自于主体设备中的混合油承载容器中的混合油,蒸馏催化塔的加热方式采用可控硅中频加热方法,有一中频加热装置与蒸馏催化塔相连,当裂解后的废旧塑料油、轮胎油或者废机油进入蒸馏塔处理后根据各种物料的不同气化温度的切线进入立式冷凝器再经水封安全器,进入柴、汽油承载容器。
所述的第三级装置是柴油精练机汽油脱胶设备,该设备由第一级化学脱碳除杂合成器为起点,经除碳精漂器、脱蜡除胶器,所述第二级装置中的柴、汽油承载容器中的油品经输入管道进入该脱蜡除胶器,该脱蜡除胶器为圆桶锥形搅拌器,搅器内设有立向挡板,底部设有鼓动沸腾装置,搅拌流型以切流方式搅动;所需添加的化学剂装置设置于添加剂容器内,并分为化学剂添加区及碱性液体添加区,经处理后的有用物再输送到渣液分离机,该机滤目从200目至350目,经过滤过的流体输送到精炼油合成罐,该罐的工作形式分开二级过滤,第一级为逆向加压力过滤,第二级为顺向过滤,此二级的过滤层均设置有过滤介质承载孔板,其过滤介质为固体粒状物,被过滤物所要添加化学剂添加物置于添加剂容器内,经以上处理之后所得油品经检查合格后进入油库储存区,同时由各个精炼阶段所产生的废料由专用输送装置输送至环保高能低硫煤系统再利用,经各个精炼阶段所产生的废气、废味经专用排气管道通过水浴池及活性碳过滤器排出。
所述的脱碳除杂合成器、除碳精漂器、脱蜡除胶器下端均连接废渣排除管道并采用压缩空气压送往环保高能低硫煤系统,在渣液分离机至精炼油合成罐之间同样设置有添加剂容器。
所述的裂解炉尾气处理环保装置系统与热裂解炉的排烟口相连,该系统包括有带多重水帘排气管道,该多重水帘排气管道的排气口连接炉体燃烧室,中间装有热气水缓冲室,缓冲室下部装有双重湿碳粒过滤器,另一端连接双塔型湿式气固分离器,气固分离器尾端由管道连接引风器,下端由管道连接引风器的后部分水管,引水管利用引风器的压力将水气推入设备尾部的烟囱,烟囱由三部分组成,下部为圆桶罐状体的水气分离器,中为用于气相分离的热交换器,上部为排气管道,该管道中部装有碱性水液喷淋器。
所述的可燃气体发电再利用系统连接于主体设备中的燃气管道,经专用燃气压缩机将燃气压缩到0.5MPA同时起到第一级燃气脱水作用时,再将气体送到第二级专用燃气压缩机,此压缩机再将燃气压缩至1MPA同时起到第二次燃气脱水作用时,将可燃气体送到燃气储存容器,储存器设置有两个出气口,一个出气口通往主体设备的热裂解炉作为该炉的燃料,其气体通过方法是经二次减压送出,第一次减压是经减压设备减压到0.4-0.5MPA,再经第二个减压设备由0.4-0.5MPA减至0.1-0.2MPA送到炉膛燃烧;另一个出气口通往气体燃料发电机(42),其可燃气体通过方法是经另一减压设备减压到0.1-0.5MPA后再进入气体燃料发电机,发电机采用机械内混方式。
所述的热气回收系统由发电机工作运行所产生的炽热气体通过气-水交换器对热气收集,该气-水交换器采用导热管导热式,通过导热管以铜的传热系统1000倍以上导热至循环水中,热水经热泵送到风柜,再由风柜通过热空气输出管将120度以上的热空气送到环保高能低硫煤系统的烘干设备利用,所经过热交换的发电机热空气再经热交换器降温后,经烟气道排出。
所述的导热管道是若干真空热导管,在真空导热管一端设置有金属散热轮,在相邻真空热导管之间设置有烟水隔层以及保温层,所述的气-水交换器一端设置有热气引入管以及消声器,底部设置有碳尘清洁口,并在设置热气引入管的一端设置有污水排放口,以及循环热水管用以连接热泵与气-水热交换器,所述的热交换器设置于气-水热交换器的相对设置污水排放口另一端,该热交换器上下端设置有循环冷水出口,上端设置有循环冷水入口,同时该端通过设置有循环热水管与风柜相连。
所述的环保高能低硫煤系统将废塑料、废轮胎、炼油过程中所不能气化的余渣即粗黑碳再利用,包括有将粗碳黑进行陈化的人工陈化器,再经热蒸气处理器处理,再将处理过的粗炭黑作为主料,在其中添加配伍物料,配伍材料为原煤、二茂铁、六次甲基四铵、氢氧化钠、生石灰和黏结剂,形成煤基料,其中主料在煤基料中所占的重量百分比为45%-60%;然后将煤基料制成成品煤,所述的粗碳黑通过地搅龙及碳黑输入带输送。
有益效果
通过上述技术方案从而该发明具有下述有益效果:
将现有设备的单项性进行整合,相对现有单项技术的单一环保生产概念来说,能够有效杜绝环保生产后的剩余物对土地及空气环境造成的二次污染,或者是因为单一环保方式生产前的更具危害性的污染;本发明的系统装备是一组循环环保生产及再利用设备,从第一次的环保生产到剩余渣物及有害气体、高温气体再作第二次的环保生产再利用,能够起到真正废弃物环保生产循环经济链,可能达到或达到无污水排放、无烟尘排放、无室温排放、无有害气体排放、无恶臭、无刺激性气味排放、噪音低、自产能源循环利用的良好的有益效果。
附图说明
图1为本这种废旧塑料、轮胎、废机油的再生能源综合利用生产装备整体图。
图2为图1中主体设备的主体视图。
图3图2中主体设备的另一视图。
图4A是图1反应釜的截面图。
图4B是与图4A配合的裂解炉图。
图5为第三级装置是柴油精练机汽油脱胶设备图。
图6为裂解炉尾气处理环保装置系统图。
图7为图6中烟囱图。
图8为热气回收系统图。
图9为可燃气体发电再利用系统图。
图10为环保高能低硫煤系统图。
本发明的最佳实施方式
下面结合附图对本发明作出进一步的说明。
如图1至图10所示,这种废旧塑料、轮胎、废机油的再生能源综合利用生产装备,包括相互配合的主体设备、第二级装置、第三极装置、裂解炉尾气处理环保系统、可燃气体发电的再利用系统、热气回收系统以及环保高能低硫煤系统。
其中所述的主体设备包括:由输送带2为起点,将石油产品废弃物输送到由路轨移动的气压式自动进料机1,将原料推进裂解催化炉3进行裂解催化得到油气混合物,该裂解催化炉带有一个自动随机设置的带有刮壁刀4的反应釜5,同时炉体接有裂解尾气环保装置系统,随之后级设备顺序为气蜡油分离器6作为由裂解催化炉所产生油气里蜡油首次分离工具,再依次连接有第一级冷凝器7、水封式气油分离器8、水封安全装置9、水封式负压装置10、重油承载容器11,当油气混合物经卧式冷凝器12进入混合油承载容器13,未能液化的可燃气体随之进入立式燃气中和水洗器14,该水洗器附设双重水封安全装置15,可燃气体经水洗器水洗后进入可燃气体发电的再利用系统。
所述的第二级装置包括蒸馏催化塔16,该设备的被蒸馏物来自于主体设备中的混合油承载容器13中的混合油,蒸馏催化塔的加热方式采用可控硅中频加热方法,有一中频加热装置17与蒸馏催化塔相连,当裂解后的废旧塑料油、轮胎油或者废机油进入蒸馏塔处理后根据各种物料的不同气化温度的切线进入立式冷凝器18再经水封安全器19,进入柴、汽油承载容器20。
所述的第三级装置是柴油精练机汽油脱胶设备,该设备由第一级化学脱碳除杂合成器21为起点,经除碳精漂器22、脱蜡除胶器23,所述第二级装置中的柴、汽油承载容器11中的油品经输入管道进入该脱蜡除胶器,该脱蜡除胶器为圆桶锥形搅拌器,搅器内设有立向挡板,底部设有鼓动沸腾装置,搅拌流型以切流方式搅动;所需添加的化学剂装置设置于添加剂容器24内,并分为化学剂添加区及碱性液体添加区,经处理后的有用物再输送到渣液分离机25,该机滤目从200目至350目,经过滤过的流体输送到精炼油合成罐26,该罐的工作形式分开二级过滤,第一级为逆向加压力过滤,第二级为顺向过滤,此二级的过滤层均设置有过滤介质承载孔板,其过滤介质为固体粒状物,被过滤物所要添加化学剂添加物置于添加剂容器24内,经以上处理之后所得油品经检查合格后进入油库储存区,同时由各个精炼阶段所产生的废料由专用输送装置输送至环保高能低硫煤系统再利用,经各个精炼阶段所产生的废气、废味经专用排气管道通过水浴池及活性碳过滤器排出。
所述的脱碳除杂合成器21、除碳精漂器22、脱蜡除胶器23下端均连接废渣排除管道49并采用压缩空气50压送往环保高能低硫煤系统,在渣液分离机至精炼油合成罐26之间同样设置有添加剂容器24。
所述的裂解炉尾气处理环保装置系统与热裂解炉的排烟口相连,该系统包括有带多重水帘排气管道27,该多重水帘排气管道的排气口连接炉体燃烧室,中间装有热气水缓冲室28,缓冲室下部装有双重湿碳粒过滤器29,另一端连接双塔型湿式气固分离器30,气固分离器尾端由管道连接引风器31,下端由管道连接引风器的后部分水管,引水管利用引风器的压力将水气推入设备尾部的烟囱32,烟囱由三部分组成,下部为圆桶罐状体的水气分离器33,中为用于气相分离的热交换器34,上部为排气管道35,该管道中部装有碱性水液喷淋器36。
所述的可燃气体发电再利用系统连接于主体设备中的燃气管道37,经专用燃气压缩机将燃气压缩到0.5MPA同时起到第一级燃气脱水作用时,再将气体送到第二级专用燃气压缩机38,此压缩机再将燃气压缩至1MPA同时起到第二次燃气脱水作用时,将可燃气体送到燃气储存容器39,储存器设置有两个出气口,一个出气口通往主体设备的热裂解炉作为该炉的燃料,其气体通过方法是经二次减压送出,第一次减压是经减压设备40减压到0.4-0.5MPA,再经第二个减压设备41由0.4-0.5MPA减至0.1-0.2MPA送到炉膛燃烧;另一个出气口通往气体燃料发电机42,其可燃气体通过方法是经另一减压设备减压到0.1-0.5MPA后再进入气体燃料发电机,发电机采用机械内混方式。
所述的热气回收系统由发电机42工作运行所产生的炽热气体通过气-水交换器43对热气收集,该气-水交换器采用导热管导热式,通过导热管51以铜的传热系统1000倍以上导热至循环水中,热水经热泵44送到风柜45,再由风柜通过热空气输出管62将120度以上的热空气送到环保高能低硫煤系统的烘干设备利用,所经过热交换的发电机热空气再经热交换器46降温后,经烟气道63排出。
所述的导热管道是若干真空热导管51,在真空导热管一端设置有金属散热枪54,在相邻真空热导管之间设置有烟水隔层55以及保温层64,所述的气-水交换器43一端设置有热气引入管52以及消声器53,底部设置有碳尘清洁口56,并在设置热气引入管的一端设置有污水排放口57,以及循环热水管58用以连接热泵44与气-水热交换器43,所述的热交换器46设置于气-水热交换器的相对设置污水排放口另一端,该热交换器上下端设置有循环冷水出口59,上端设置有循环冷水入口60,同时该端通过设置有循环热水管61与风柜相连。
所述的环保高能低硫煤系统将废塑料、废轮胎、炼油过程中所不能气化的余渣即粗黑碳再利用,包括有将粗碳黑进行陈化的人工陈化器47,再经热蒸气处理器48处理,再将处理过的粗炭黑作为主料,在其中添加配伍物料,配伍材料为原煤、二茂铁、六次甲基四铵、氢氧化钠、生石灰和黏结剂,形成煤基料,其中主料在煤基料中所占的重量百分比为45%-60%;然后将煤基料制成成品煤,所述的粗碳黑通过地搅龙64及碳黑输入带65输送。
在具体的生产利用过程中,第一阶段,将含水量40%的废旧塑料经热空气烘干设备烘干后,含水量减少为20%,其热空气来源于图8热气回收系统,具体收集工作由热能收集器66进行处理,经烘干后的废旧塑料经输送带源源不断送入热裂解炉3,送料量为14吨(以两条炉计算),从加热开始至裂解完成,所用燃油1100Kg,附加材料为铝、锌及氧化钙等催化剂,其比例为所加入原料去水分后重量的平均1.5%,设备用电为336度,生产周期时间为28小时,生产气、柴油混合油11.62吨,裂解剩余物即粗炭黑为60Kg,此粗炭黑连同在热裂解炉的尾气环保处理系统所收的湿碳粉送至高能低硫煤生产系统作再利用处理,同时通过炼油过程中所产生的可燃气体约872 m³,此可燃气Co20-24%、二氧化碳Co2 1-3%、氢气H2 8-12%、CmHn主要为甲烷3-4.2%等,该可燃气经清洁除焦油及压缩送入燃气储存容器39作为燃气发电用途。
第二阶段,经过裂解后的混合油进入第二级装置,该系统日处理量为14吨,该装置的加热工具为可控硅中频加热设备110KW,将生产的气、柴油混合油切线后所需用电750度。
第三阶段,经第二级装置处理后,将馏分中的柴、汽油送入精炼装置处理,经清洁、除味、脱色、脱胶、脱蜡等工序,所得柴、汽油的总量为10.67吨,柴油经处理合成后可到达国II标准,汽油为93#汽油,在处理过程中的剩余物经碱化处理,利用全密封的输送工具一般为管道送入高能低硫煤生产系统作再利用处理。
第四阶段,由燃气储存容器输出的可燃气体经减压后进入内混式燃气发电机,具体可采用济南柴油发电机厂500KW/h产品,上述经所述的第二阶段处理后的872m³可燃气可发电3925度,在发电过程中产生的热气经热回收再利用系统换成热空气,连同热裂解炉的尾气处理剩余热水热换成热空气联合送入第一阶段中起始的热空气烘干设备再用。
本实施以废旧塑料炼油为例,凡有与之原理和基本结构与本实施例相同或近似的,均在本发明保护范围之内。
与现有技术相比,将现有设备的单项性进行整合,相对现有单项技术的单一环保生产概念来说,能够有效杜绝环保生产后的剩余物对土地及空气环境造成的二次污染,或者是因为单一环保方式生产前的更具危害性的污染;本发明的系统装备是一组循环环保生产及再利用设备,从第一次的环保生产到剩余渣物及有害气体、高温气体再作第二次的环保生产再利用,能够起到真正废弃物环保生产循环经济链,可能达到或达到无污水排放、无烟尘排放、无室温排放、无有害气体排放、无恶臭、无刺激性气味排放、噪音低、自产能源循环利用的良好的有益效果。

Claims (10)

  1. 一种废旧塑料、轮胎、废机油的再生能源综合利用生产装备,其特征在于:包括相互配合的主体设备、第二级装置、第三极装置、裂解炉尾气处理环保系统、可燃气体发电的再利用系统、热气回收系统以及环保高能低硫煤系统。
  2. 如权利要求1所述的废旧塑料、轮胎、废机油的再生能源综合利用生产装备,其特征在于:其中所述的主体设备包括:由输送带(2)为起点,将石油产品废弃物输送到由路轨移动的气压式自动进料机(1),将原料推进裂解催化炉(3)进行裂解催化得到油气混合物,该裂解催化炉带有一个自动随机刮壁刀(4)的反应釜(5),同时炉体接有裂解尾气环保装置系统,随之后级设备顺序为气蜡油分离器(6)作为由裂解催化炉所产生油气里蜡油首次分离工具,再依次连接有第一级冷凝器(7)、水封式气油分离器(8)、水封安全装置(9)、水封式负压装置(10)、重油承载容器(11),当油气混合物经卧式冷凝器(12)进入混合油承载容器(13),未能液化的可燃气体随之进入立式燃气中和水洗器(14),该水洗器附设双重水封安全装置(15),可燃气体经水洗器水洗后进入可燃气体发电的再利用系统。
  3. 如权利要求1所述的废旧塑料、轮胎、废机油的再生能源综合利用生产装备,其特征在于:所述的第二级装置包括蒸馏催化塔(16),该设备的被蒸馏物来自于主体设备中的混合油承载容器(13)中的混合油,蒸馏催化塔的加热方式采用可控硅中频加热方法,有一中频加热装置(17)与蒸馏催化塔相连,当裂解后的废旧塑料油、轮胎油或者废机油进入蒸馏塔处理后根据各种物料的不同气化温度的切线进入立式冷凝器(18)再经水封安全器(19),进入柴、汽油承载容器(20)。
  4. 如权利要求1所述的废旧塑料、轮胎、废机油的再生能源综合利用生产装备,其特征在于:所述的第三级装置是柴油精练及汽油脱胶设备,该设备由第一级化学脱碳除杂合成器(21)为起点,经除碳精漂器(22)、脱蜡除胶器(23),所述第二级装置中的柴、汽油承载容器(20)中的油品经输入管道进入该脱蜡除胶器,该脱蜡除胶器为圆桶锥形搅拌器,搅器内设有立向挡板,底部设有鼓动沸腾装置,搅拌流型以切流方式搅动;所需添加的化学剂装置设置于添加剂容器(24)内,并分为化学剂添加区及碱性液体添加区,经处理后的有用物再输送到渣液分离机(25),该机滤目从200目至350目,经过滤过的流体输送到精炼油合成罐(26),该罐的工作形式分开二级过滤,第一级为逆向加压力过滤,第二级为顺向过滤,此二级的过滤层均设置有过滤介质承载孔板,其过滤介质为固体粒状物,被过滤物所要添加化学剂添加物置于添加剂容器(24)内,经以上处理之后所得油品经检查合格后进入油库储存区,同时由各个精炼阶段所产生的废料由专用输送装置输送至环保高能低硫煤系统再利用,经各个精炼阶段所产生的废气、废味经专用排气管道通过水浴池及活性碳过滤器排出。
  5. 如权利要求4所述的废旧塑料、轮胎、废机油的再生能源综合利用生产装备,其特征在于:所述的脱碳除杂合成器(21)、除碳精漂器(22)、脱蜡除胶器(23)下端均连接废渣排除管道(49)并采用压缩空气(50)压送往环保高能低硫煤系统,在渣液分离机至精炼油合成罐(26)之间同样设置有添加剂容器(24)。
  6. 如权利要求1所述的废旧塑料、轮胎、废机油的再生能源综合利用生产装备,其特征在于:所述的裂解炉尾气处理环保装置系统与热裂解炉的排烟口相连,该系统包括有带多重水帘排气管道(27),该多重水帘排气管道的排气口连接炉体燃烧室,中间装有热气水缓冲室(28),缓冲室下部装有双重湿碳粒过滤器(29),另一端连接双塔型湿式气固分离器(30),气固分离器尾端由管道连接引风器(31),下端由管道连接引风器的后部分水管,引水管利用引风器的压力将水气推入设备尾部的烟囱(32),烟囱由三部分组成,下部为圆桶罐状体的水气分离器(33),中为用于气相分离的热交换器(34),上部为排气管道(35),该管道中部装有碱性水液喷淋器(36)。
  7. 如权利要求1所述的废旧塑料、轮胎、废机油的再生能源综合利用生产装备,其特征在于:所述的可燃气体发电再利用系统连接于主体设备中的燃气管道(37),经专用燃气压缩机将燃气压缩到0.5MPA同时起到第一级燃气脱水作用时,再将气体送到第二级专用燃气压缩机(38),此压缩机再将燃气压缩至1MPA同时起到第二次燃气脱水作用时,将可燃气体送到燃气储存容器(39),储存器设置有两个出气口,一个出气口通往主体设备的热裂解炉作为该炉的燃料,其气体通过方法是经二次减压送出,第一次减压是经减压设备(40)减压到0.4-0.5MPA,再经第二个减压设备(41)由0.4-0.5MPA减至0.1-0.2MPA送到炉膛燃烧;另一个出气口通往气体燃料发电机(42),其可燃气体通过方法是经另一减压设备减压到0.1-0.5MPA后再进入气体燃料发电机,发电机采用机械内混方式。
  8. 如权利要求1所述的废旧塑料、轮胎、废机油的再生能源综合利用生产装备,其特征在于:所述的热气回收系统由发电机(42)工作运行所产生的炽热气体通过气-水交换器(43)对热气收集,该气-水交换器采用导热管导热式,通过的导热管(43)以铜的传热系数1000倍以上导热至循环水中,热水经热泵(44)送到风柜(45),再由风柜通过热空气输出管(62)将120度以上的热空气送到环保高能低硫煤系统的烘干设备利用,所经过热交换的发电机热空气再经热交换器(46)降温后,经烟气道(63)排出。
  9. 如权利要求8所述的废旧塑料、轮胎、废机油的再生能源综合利用生产装备,其特征在于:所述的导热管道是若干真空热导管(51),在真空导热管一端设置有金属散热轮(54),在相邻真空热导管之间设置有烟水隔层(55)以及保温层(64),所述的气-水交换器(43)一端设置有热气引入管(52)以及消声器(53),底部设置有碳尘清洁口(56),并在设置热气引入管的一端设置有污水排放口(57),以及循环热水管(58)用以连接热泵(44)与气-水热交换器(43),所述的热交换器(46)设置于气-水热交换器的相对设置污水排放口另一端,该热交换器上下端设置有循环冷水出口(59),上端设置有循环冷水入口(60),同时该端通过设置有循环热水管(61)与风柜相连。
  10. 如权利要求1所述的废旧塑料、轮胎、废机油的再生能源综合利用生产装备,其特征在于:所述的环保高能低硫煤系统将废塑料、废轮胎、炼油过程中所不能气化的余渣即粗黑碳再利用,包括有将粗碳黑进行陈化的人工陈化器(47),再经热蒸气处理器(48)处理,再将处理过的粗炭黑作为主料,在其中添加配伍物料,配伍材料为原煤、二茂铁、六次甲基四铵、氢氧化钠、生石灰和黏结剂,形成煤基料,其中主料在煤基料中所占的重量百分比为45%-60%;然后将煤基料制成成品煤。
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