WO2011148066A8 - Procédé de production anaérobie d'hydrogène - Google Patents

Procédé de production anaérobie d'hydrogène Download PDF

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Publication number
WO2011148066A8
WO2011148066A8 PCT/FR2011/000362 FR2011000362W WO2011148066A8 WO 2011148066 A8 WO2011148066 A8 WO 2011148066A8 FR 2011000362 W FR2011000362 W FR 2011000362W WO 2011148066 A8 WO2011148066 A8 WO 2011148066A8
Authority
WO
WIPO (PCT)
Prior art keywords
hydrogen
flow
steam
production method
hydrogen production
Prior art date
Application number
PCT/FR2011/000362
Other languages
English (en)
Other versions
WO2011148066A3 (fr
WO2011148066A2 (fr
Inventor
Béatrice Fischer
Fabrice Giroudiere
Sylvain Rethore
Marc Quemeneur
Original Assignee
IFP Energies Nouvelles
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by IFP Energies Nouvelles filed Critical IFP Energies Nouvelles
Publication of WO2011148066A2 publication Critical patent/WO2011148066A2/fr
Publication of WO2011148066A3 publication Critical patent/WO2011148066A3/fr
Publication of WO2011148066A8 publication Critical patent/WO2011148066A8/fr

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    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B3/00—Hydrogen; Gaseous mixtures containing hydrogen; Separation of hydrogen from mixtures containing it; Purification of hydrogen
    • C01B3/02—Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen
    • C01B3/32—Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen by reaction of gaseous or liquid organic compounds with gasifying agents, e.g. water, carbon dioxide, air
    • C01B3/34—Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen by reaction of gaseous or liquid organic compounds with gasifying agents, e.g. water, carbon dioxide, air by reaction of hydrocarbons with gasifying agents
    • C01B3/38—Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen by reaction of gaseous or liquid organic compounds with gasifying agents, e.g. water, carbon dioxide, air by reaction of hydrocarbons with gasifying agents using catalysts
    • C01B3/382—Multi-step processes
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B3/00—Hydrogen; Gaseous mixtures containing hydrogen; Separation of hydrogen from mixtures containing it; Purification of hydrogen
    • C01B3/02—Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen
    • C01B3/32—Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen by reaction of gaseous or liquid organic compounds with gasifying agents, e.g. water, carbon dioxide, air
    • C01B3/34—Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen by reaction of gaseous or liquid organic compounds with gasifying agents, e.g. water, carbon dioxide, air by reaction of hydrocarbons with gasifying agents
    • C01B3/38—Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen by reaction of gaseous or liquid organic compounds with gasifying agents, e.g. water, carbon dioxide, air by reaction of hydrocarbons with gasifying agents using catalysts
    • C01B3/388—Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen by reaction of gaseous or liquid organic compounds with gasifying agents, e.g. water, carbon dioxide, air by reaction of hydrocarbons with gasifying agents using catalysts the heat being generated by superheated steam
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B3/00—Hydrogen; Gaseous mixtures containing hydrogen; Separation of hydrogen from mixtures containing it; Purification of hydrogen
    • C01B3/02—Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen
    • C01B3/32—Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen by reaction of gaseous or liquid organic compounds with gasifying agents, e.g. water, carbon dioxide, air
    • C01B3/34—Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen by reaction of gaseous or liquid organic compounds with gasifying agents, e.g. water, carbon dioxide, air by reaction of hydrocarbons with gasifying agents
    • C01B3/48—Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen by reaction of gaseous or liquid organic compounds with gasifying agents, e.g. water, carbon dioxide, air by reaction of hydrocarbons with gasifying agents followed by reaction of water vapour with carbon monoxide
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B3/00—Hydrogen; Gaseous mixtures containing hydrogen; Separation of hydrogen from mixtures containing it; Purification of hydrogen
    • C01B3/50—Separation of hydrogen or hydrogen containing gases from gaseous mixtures, e.g. purification
    • C01B3/501—Separation of hydrogen or hydrogen containing gases from gaseous mixtures, e.g. purification by diffusion
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B2203/00—Integrated processes for the production of hydrogen or synthesis gas
    • C01B2203/02—Processes for making hydrogen or synthesis gas
    • C01B2203/0205—Processes for making hydrogen or synthesis gas containing a reforming step
    • C01B2203/0227—Processes for making hydrogen or synthesis gas containing a reforming step containing a catalytic reforming step
    • C01B2203/0244—Processes for making hydrogen or synthesis gas containing a reforming step containing a catalytic reforming step the reforming step being an autothermal reforming step, e.g. secondary reforming processes
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B2203/00—Integrated processes for the production of hydrogen or synthesis gas
    • C01B2203/02—Processes for making hydrogen or synthesis gas
    • C01B2203/0283—Processes for making hydrogen or synthesis gas containing a CO-shift step, i.e. a water gas shift step
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B2203/00—Integrated processes for the production of hydrogen or synthesis gas
    • C01B2203/04—Integrated processes for the production of hydrogen or synthesis gas containing a purification step for the hydrogen or the synthesis gas
    • C01B2203/0405—Purification by membrane separation
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B2203/00—Integrated processes for the production of hydrogen or synthesis gas
    • C01B2203/04—Integrated processes for the production of hydrogen or synthesis gas containing a purification step for the hydrogen or the synthesis gas
    • C01B2203/0465—Composition of the impurity
    • C01B2203/0495—Composition of the impurity the impurity being water
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B2203/00—Integrated processes for the production of hydrogen or synthesis gas
    • C01B2203/06—Integration with other chemical processes
    • C01B2203/066—Integration with other chemical processes with fuel cells
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B2203/00—Integrated processes for the production of hydrogen or synthesis gas
    • C01B2203/08—Methods of heating or cooling
    • C01B2203/0872—Methods of cooling
    • C01B2203/0877—Methods of cooling by direct injection of fluid
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B2203/00—Integrated processes for the production of hydrogen or synthesis gas
    • C01B2203/08—Methods of heating or cooling
    • C01B2203/0872—Methods of cooling
    • C01B2203/0888—Methods of cooling by evaporation of a fluid
    • C01B2203/0894—Generation of steam
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B2203/00—Integrated processes for the production of hydrogen or synthesis gas
    • C01B2203/12—Feeding the process for making hydrogen or synthesis gas
    • C01B2203/1288—Evaporation of one or more of the different feed components
    • C01B2203/1294—Evaporation by heat exchange with hot process stream

Abstract

L'invention concerne un procédé catalytique de production d'hydrogène par reformage d'une charge hydrocarbonée comprenant les étapes consistant à: a) soutirer d'un ballon de vapeur de la vapeur d'eau à température de saturation à la pression P du procédé, b) surchauffer ladite vapeur d'eau issue de l'étape - (a), c) introduire la vapeur d'eau surchauffée issue de l'étape (b) dans un réacteur de reformage autotherme avec la charge hydrocarbonée et de l'oxygène pur, de façon à produire un reformat, d) introduire ledit reformat issu de l'étape (c) dans un réacteur de conversion du monoxyde de carbone à l'eau, de façon à produire un flux enrichi en hydrogène, e) séparer ledit flux enrichi en hydrogène issu de l'étape (d) en au moins un flux d'hydrogène et un flux d'eau, f) purifier ledit flux d'hydrogène issu de l'étape (e).
PCT/FR2011/000362 2010-05-25 2011-06-23 Procédé de production anaérobie d'hydrogène WO2011148066A2 (fr)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
FR1002179A FR2960450B1 (fr) 2010-05-25 2010-05-25 Procede de production anaerobie d'hydrogene
FR10/02179 2010-05-25

Publications (3)

Publication Number Publication Date
WO2011148066A2 WO2011148066A2 (fr) 2011-12-01
WO2011148066A3 WO2011148066A3 (fr) 2012-03-22
WO2011148066A8 true WO2011148066A8 (fr) 2012-11-29

Family

ID=43416403

Family Applications (1)

Application Number Title Priority Date Filing Date
PCT/FR2011/000362 WO2011148066A2 (fr) 2010-05-25 2011-06-23 Procédé de production anaérobie d'hydrogène

Country Status (2)

Country Link
FR (1) FR2960450B1 (fr)
WO (1) WO2011148066A2 (fr)

Families Citing this family (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN104953147B (zh) * 2015-07-02 2017-07-25 北京建筑大学 一种自供应氢气燃料电池系统及其工作方法
ES2828799T3 (es) 2017-08-10 2021-05-27 Sener Ing & Sist Sistema de reformado de alcohol y producción de hidrógeno, unidades del sistema y su método asociado
EP3693338B1 (fr) 2019-02-07 2021-09-01 Sener Ingenieria Y Sistemas, S.A. Système auto-thermique haute pression pour réformer de l'alcool et produire de l'hydrogène, et procédé correspondant

Family Cites Families (9)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP1144301A1 (fr) * 1999-10-05 2001-10-17 Ballard Power Systems Inc. Systeme de generation d'energie de pile a combustible a reformeur autothermique
US6596424B2 (en) 2001-03-30 2003-07-22 General Motors Corporation Apparatus for mixing fuel and an oxidant
US7399329B2 (en) 2003-08-22 2008-07-15 Syntroleum Corporation Process for production of synthesis gas using an oxygen-containing gas
WO2005118126A1 (fr) * 2004-05-28 2005-12-15 Hyradix, Inc. Procede de generation d'hydrogene par reformage a la vapeur/oxydation partielle
US7601302B2 (en) * 2005-09-16 2009-10-13 Idatech, Llc Self-regulating feedstock delivery systems and hydrogen-generating fuel processing assemblies and fuel cell systems incorporating the same
FR2924358B1 (fr) 2007-11-30 2010-08-13 Inst Francais Du Petrole Nouveau reacteur permettant la mise en oeuvre de reactions a tres haute temperature et haute pression
US8894967B2 (en) * 2008-03-28 2014-11-25 IFP Energies Nouvelles Process for the production of highly thermally-integrated hydrogen by reforming a hydrocarbon feedstock
US8216324B2 (en) 2008-03-28 2012-07-10 IFP Energies Nouvelles Process for the production of hydrogen with a thermally-integrated desulfurization unit
US8163046B2 (en) 2008-03-28 2012-04-24 IFP Energies Nouvelles Start-up process for a unit for producing highly thermally-integrated hydrogen by reforming a hydrocarbon feedstock

Also Published As

Publication number Publication date
FR2960450B1 (fr) 2013-02-22
WO2011148066A3 (fr) 2012-03-22
FR2960450A1 (fr) 2011-12-02
WO2011148066A2 (fr) 2011-12-01

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