WO2011129567A4 - Gas storage vessel, hydrogen-charging method, and hydrogen-charging apparatus - Google Patents

Gas storage vessel, hydrogen-charging method, and hydrogen-charging apparatus Download PDF

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Publication number
WO2011129567A4
WO2011129567A4 PCT/KR2011/002536 KR2011002536W WO2011129567A4 WO 2011129567 A4 WO2011129567 A4 WO 2011129567A4 KR 2011002536 W KR2011002536 W KR 2011002536W WO 2011129567 A4 WO2011129567 A4 WO 2011129567A4
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Prior art keywords
hydrogen
gas
container
candy
material
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PCT/KR2011/002536
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French (fr)
Korean (ko)
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WO2011129567A3 (en )
WO2011129567A2 (en )
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조건환
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Cho Keon-Hwan
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    • AHUMAN NECESSITIES
    • A23FOODS OR FOODSTUFFS; THEIR TREATMENT, NOT COVERED BY OTHER CLASSES
    • A23GCOCOA; COCOA PRODUCTS, e.g. CHOCOLATE; SUBSTITUTES FOR COCOA OR COCOA PRODUCTS; CONFECTIONERY; CHEWING GUM; ICE-CREAM; PREPARATION THEREOF
    • A23G3/00Sweetmeats; Confectionery; Marzipan; Coated or filled products
    • A23G3/34Sweetmeats, confectionery or marzipan; Processes for the preparation thereof
    • AHUMAN NECESSITIES
    • A23FOODS OR FOODSTUFFS; THEIR TREATMENT, NOT COVERED BY OTHER CLASSES
    • A23GCOCOA; COCOA PRODUCTS, e.g. CHOCOLATE; SUBSTITUTES FOR COCOA OR COCOA PRODUCTS; CONFECTIONERY; CHEWING GUM; ICE-CREAM; PREPARATION THEREOF
    • A23G3/00Sweetmeats; Confectionery; Marzipan; Coated or filled products
    • A23G3/34Sweetmeats, confectionery or marzipan; Processes for the preparation thereof
    • A23G3/50Sweetmeats, confectionery or marzipan; Processes for the preparation thereof characterised by shape, structure or physical form, e.g. products with supported structure
    • AHUMAN NECESSITIES
    • A23FOODS OR FOODSTUFFS; THEIR TREATMENT, NOT COVERED BY OTHER CLASSES
    • A23GCOCOA; COCOA PRODUCTS, e.g. CHOCOLATE; SUBSTITUTES FOR COCOA OR COCOA PRODUCTS; CONFECTIONERY; CHEWING GUM; ICE-CREAM; PREPARATION THEREOF
    • A23G3/00Sweetmeats; Confectionery; Marzipan; Coated or filled products
    • A23G3/34Sweetmeats, confectionery or marzipan; Processes for the preparation thereof
    • A23G3/50Sweetmeats, confectionery or marzipan; Processes for the preparation thereof characterised by shape, structure or physical form, e.g. products with supported structure
    • A23G3/56Products with edible or inedible supports, e.g. lollipops
    • AHUMAN NECESSITIES
    • A61MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61KPREPARATIONS FOR MEDICAL, DENTAL, OR TOILET PURPOSES
    • A61K9/00Medicinal preparations characterised by special physical form
    • A61K9/48Preparations in capsules, e.g. of gelatin, of chocolate
    • A61K9/4841Filling excipients; Inactive ingredients
    • A61K9/4875Compounds of unknown constitution, e.g. material from plants or animals
    • AHUMAN NECESSITIES
    • A61MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61KPREPARATIONS FOR MEDICAL, DENTAL, OR TOILET PURPOSES
    • A61K9/00Medicinal preparations characterised by special physical form
    • A61K9/0012Galenical forms characterised by the site of application
    • A61K9/0053Mouth and digestive tract, i.e. intraoral and peroral administration
    • A61K9/0056Mouth soluble or dispersible forms; Suckable, eatable, chewable coherent forms; Forms rapidly disintegrating in the mouth; Lozenges; Lollipops; Bite capsules; Baked products; Baits or other oral forms for animals

Abstract

The present invention relates to a technique for delivering gases into the human body or generating gases inside the human body, such as a method for encapsulating gases and a gas storage vessel. The present invention relates to a gas storage capsule and to a method for producing the gas storage capsule, wherein the capsule is dissolved in water such that the air-tightness thereof is gradually degraded and the gas contained in the capsule can be gradually leaked to the outside of the capsule. The present invention also relates to a hydrogen-generating material which directly generates hydrogen gases in vivo, and to a hydrogen-generating candy for directly encapsulating hydrogen using the material and delivering the thus-encapsulated hydrogen into the intestines, as well as to a method for producing the candy.

Description

Gas storage vessel, and Hydrogen charging method Hydrogen charging device

The present invention relates to a technique for generating in the gas storage vessel, hydrogen sealing method, and relates to a hydrogen filling apparatus, in particular the hydrogen filled container, sugar to generate hydrogen, and supplying gas directly into the body or the body.

There capsules are widely used as a storage and packaging of health food or a medicine for taking orally, it may be called a hard capsules and soft capsules, have been used for the purpose of storage of the powder or liquid, depending on the capsule material. Capsule container is often depending on the storage contents of a non-confidential elements are necessary.

Also if you use hard candy packaging of health foods and medicines for oral or symbolic foods. The case of using the hydrogen as a sugar-free way to help the minimal crystallization (crystallization of the crystalline polyol) to take on the stability in the case in the method for producing the high water content of the hard candy was added saccharide based on a composition (syrup) carbohydrates Patent gotta it has introduced a special Publication 0,163,252.

Various contents contained in the center of and is built into the vacant space on the candy body and the main body a blank containing the various contents, and water is well coating the capsule with a capsule having a water-soluble coating to melt (liquid, powder, solid) About Capsule gotta have candy yirwojyeo to introduce patent Application Publication No. 10-2009-009794.

Soft capsules are mixed with the main component and an excipient, or after the prepared chargeable contents liquid through the solubilized using a surface active agent, to manufacture the thickness of the liquid contents during filling film generally 0.60~0.80mm along a forming process of a soft capsule prepared and is added to an oral drug delivery system it has to be absorbed in the stomach or the most commonly used.

The soft capsule is mainly which is produced by gelatin, between the molten gelatin spreader box (Spreader Box) was placed in a pair of die rollers while applying unfold the molten gelatin in a rotating drum rollers to the desired thickness in the form of a sheet in the spreader box was passed through a molding is generally in the form of a capsule.

Patent No. 11 the May 23 announcement Registration No. 10-0647034 years 2006 the "soft capsules and a manufacturing method thereof." This has been disclosed an apparatus for manufacturing soft capsules recently published on September 11, 2009 registered Announcements there is 20-0445951 devised. Apparatus of the invented is comprising: a capsule recovery unit for the sheet-forming unit, the number of times the capsule forming unit, the molded capsule having a die roller and the raw liquid discharge nozzle having a spreader box and the cooling drum, a gelatin soft capsule unfold the molten gelatin in a rotating drum roller molten gelatin to the desired thickness into the spreader box in the form of a sheet, and injecting the contents from the contents of the stock solution discharge nozzle was passed through between a pair of die rollers, cutting the gelatin sheet, bonding by to produce a capsule.

Conventional soft capsule These were primarily used as a container for packing a liquid or solid contents, and such a solid powder or liquid: and a packing (for example, omega-three) were used to make it easier to take orally.

It has focused on the role of hydrogen these days with regard to human health. When the active oxygen is excessive and would be harmful to the human body is widely known, be one, also known as rich in hydrogen containing a lot of hydrogen is found to be excellent is adult disease prevention and therapeutic effects, such as cancer, diabetes been actively studied for this in the recent home and abroad is. In addition there is a theory that the water containing rich in hydrogen, erasing the free radicals that cause various diseases, effective to inhibit the oxidizing action of the active oxygen receiving a lot of attention from the medical community in recent years.

Due to the lack of the enzyme, or is not found in the digestive system is linked to the large intestine by not been hydrolyzed in the small intestine of hydrogen gas and carbon dioxide and some of which occur during the process of fermentation as food for bacteria, the group in the colon is the mixed gas containing the methane gas is the fact that creation is known by a number of experiments and reports published under that name that donghan fart and breath hydrogen (breath hydrogen). This is mainly discomfort caused by excessive production of flatulence life should or production of bio-bio-rhythms and gas, or chronic Soldiers (celiac deasese) including a bottle of physiological (pathophysiological) symptoms or intestinal gas generated to improve or cure it the study and how to improve them regarding inhibition is known.

Study the biochemical Prevention (biochemical preventive) how hydrogen molecules respiratory tract, the theory that the fire extinguisher, according to the various types of vessels are transported to inside the cell an effective antioxidant appeared in recent years, and take advantage of the food crops that can be seen as part of the Food Chemicals many animal studies and some clinical experiments through a number of reports related to the effect of hydrogen molecules generated in the intestines Japan, China, and there is increasing gradually through case studies published in the United States and so on. Especially in academic meetings of hydrogen Society of Japan it deals with reports on the effect of hydrogen molecules generated by enteric bacteria. In addition, and as a result generated a lot of gas containing hydrogen gas in the large intestine, because the mechanism of action to prevent and cure diabetes, obesity, some carbohydrates are absorbed in the small intestine.

A device for generating a beverage containing rich in hydrogen, using the electrolysis, hydrogen reduction handwritten filter structure to generate a reductive hydrogen by attaching a hydrogen reduced water using hydrogen reduction catalyst to a conventional water purifier Republic of Korea Patent Application Unexamined 10 gotta have introduced -0686945.

Attaching a bubble generator and the ceramic rod with the conventional water purifier in the hydrogen-rich cold water supply, the on purifiers for generating hydrogen can gotta description of the Republic of Korea Patent Publication No. 10-0552003 Patent.

By reaction of a beverage with the magnesium particles contained in the bottle to change the drinking water to generate hydrogen gas as a hydrogen abundant containing rich in hydrogen is enriched hydrogen for purifying drinking water by the particles forming process, and the Republic of Korea Patent Application No. abundant number generator hydrogen gotta have introduced special 10-0529006.

Hydrogen reduction handwriting and the bubble generator by electrolysis can not be used in places that are not water purifier is installed, and is used because the power required range and spread St. side difficulties receive a number of limitations in the ceramic rod calcium is generated reacts with water There are limitations to the dissolution of metal hydroxide, while by reacting the magnesium particles in the beverage abundant hydrogen to make the number of rich hydrogen generator is a magnesium particle in the drinking water of a specially manufactured plastic bottles have turned periodically to all characters Luce (hydrogen stick) , and the hygiene point of PET bottles and chairs Luce tricky and it is difficult to get a place and time constraints that you can drink the abundant hydrogen.

The research and development about the intake of the substances extracted etc. oligosaccharide, polysaccharide and edible spices present in the food crop to selectively reduce the production of unwanted gas by bacteria in the colon to a minimum as much as possible lead to the production of useful hydrogen gas As for the bar is not yet known.

About the method for generating hydrogen gas directly from the body by using a characteristic of the oligosaccharide or polysaccharide it is not introduced until the bar now.

It is known how to make if the intake and stored in a hard candy, a soft film solidifying the hydrogen gas is not introduced, can be maintained confidential and save gas in the pressure and flow, such as hydrogen safely supplied far vivo no bar.

The present invention is intended to carry or provide a technique for generating a gas in the human body, the method of packaging a gas and the gas storage container, such as a gas into the human body.

The present invention is to provide a method for packing the contents into the gas storage vessel and a method of manufacturing the same, and capsule.

The present invention is intended to provide a gas capsule for storage so that it extends to the Capsule container is melted by the airtightness is gradually destroyed as the gas storage container is gas inside gradually leak to the outside.

The present invention after oral administration packed in the container to seal the hydrogen gas, for the packing of hydrogen in the method of manufacturing the same, and a capsule and the capsule for the hydrogen gas storage to to come out after a certain amount of time is the airtight container destruction leak the hydrogen gas intended to provide a way.

The present invention is to provide a method for producing a hard candy hydrogen form of a capsule as a container for storing the hydrogen.

The present invention uses a small amount of heat the material more as the capsule material, and by increasing the storage capacity per container using a flexible film material, the production of which can reduce the consumed compared to hydrogen gas calorie intake gas storage container and the accompanying intended to provide a method of filling hydrogen gas and sealing the containers.

The present invention is intended to provide a hydrogen-generating material and the means and methods for the packing of hydrogen directly to carry far intestine by using the material to generate hydrogen gas directly in the body using the characteristics of a simple sugar or polysaccharide.

The invention is by human consumption fermented by bacteria in the colon beneficial to ensure that the hydrogen gas is generated, by sorting the material extracted etc. oligosaccharide, polysaccharide and edible spices present in food crops properly added to the candy material is blended It intended to provide a candy material.

The present invention further provides a candy container material for storing hydrogen gas, it is the human consumption fermented by bacteria in the large intestine a simple sugar which is a hydrogen gas is generated, polysaccharides and appropriate substances extracted etc. edible spices selectively, candy the hydrogen gas generated in the hydrogen gas and the candy material storage container to the interior of the vessel so the combined intended to provide a more capsule-type hydrogen to bring a hydrogen storage container and a method of manufacturing the same effect occurs.

To the present invention is a hydrogen storage container or to hydrogen-producing packaging the candy container and shipping, or storing a secure, is made into a polyethylene water jacket filled with water or fire-resistant anti-freeze, one for when the melt and discharge the water or the fire-resistant anti-freeze in Celsius 120 degrees intended to provide a packaging material.

The present invention, without passing through the storing body, made of a material that is in contact with the water soluble, a small container with a closed empty space therein to store the gas, if the water deposited on the container of the container airtight It is gradually destroyed and the gas in the interior to leak out to the outside.

The gas storage vessel is supposed may be considering the pressure applied to the interior and the exterior of the cylinder to withstand the pressure changes in the atmospheric pressure, the outer diameter of the length of the 8mm, the outer cylinder supposed to 5 ~ 10mm preferably preferably 8 ~ 20mm 14mm, and the total length of the container (2) that is a sum of the end plate 10 of the both ends is preferably 10 ~ 25mm is a 22mm.

The invention the container is a soft candy, amorphous hard candy, sugar-free sugar is used as the material of the hard candy, maltose, and saccharides such as syrup, starch, maltitol, mannitol, sorbitol, iso malteu carbohydrate syrup mixture with a polyol such as xylitol (Polyols ) mixture, one or will the composition in the above mixture, if necessary, gelatin, glycerin, iron (ferrous fumarate), vitamin C, vitamin E, polyphenols (polyphenol), carotene (carotene), a calcium, a selected, etc., etc. of the addition of more additives.

Gas to be stored in the vessel is a hydrogen gas, the purity is at least 99.999%, preferably not less than 99.99999%.

The present invention temporarily in a state of inserting the hydrogen as a method for sealing by filling in a compact container, using a melting chamber material to a gas storage container to heat, to the interior from one side to the hydrogen filling nozzle with space size of a volume of hydrogen is filled a temporary container-molding step for molding the vessel, equipped with a heat shrink band to areas other than the length of a predetermined hydrogen-filled space, and then taken out through the hydrogen filling nozzle the air in the inner space of the temporary container, an atmospheric pressure of hydrogen than filling in the step of retracting the hydrogen filling nozzle to the heat shrink band end portion and sealed to the temporary container inlet was added to heat the heat shrink band tightening the band, and, and fully retracting the hydrogen filling nozzle out of the temporary container, the sealing comprising the step of finishing the area. In the temporary container-molding step, and selecting a container material sugar, maltose, and saccharides such as syrup, starch, maltitol, mannitol, sorbitol, iso malteu, the mixture of carbohydrate syrup mixture and the polyol (Polyols), such as xylitol, at least one, etc. , gelatin, glycerin, iron (ferrous fumarate), vitamin C, vitamin E, polyphenols (polyphenol), carotene (carotene), added calcium, calcium hydride, at least one additive selected, etc. as an option to create a maese cute, state this It may be molded into a mold. Wherein the chamber material in a well the confidentiality of at least air, low in calories and well thermal deformation at the time to be squeezed by applying heat, and a glass transition temperature of the mixture or selection of 38 o C or higher sugar with a water content of at least 3% the purity of hydrogen gas to be filled in the container is preferably not less than 99.999%.

Apparatus of the present invention is composed of n number of hydrogen filling nozzle and the auxiliary device to be inserted into a temporary container to be molded in a mold frame, hydrogen hydrogen filling nozzle unit for pumping the inside of the temporary container of the charging period with vacuum or filled with hydrogen gas and, connected to the hydrogen filling nozzle portion and the hydrogen charge which the passage of the vacuum gas passage or hydrogen gas meshed pipe and, connected to the hydrogen charging meshed pipe and a vacuum pump for pumping the internal temporary container to be a vacuum unit, a hydrogen filling mesh connected to the pipe and supplying a hydrogen gas and connected to the flow rate and the hydrogen gas supply unit for controlling the pressure, the hydrogen charge is meshed pipe includes a nitrogen gas supply which is responsible for purging the safety of the hydrogen gas filling system.

The invention also has a large inner space than the volume of the gas storage vessel to the outside of the gas storage container, iphyeoseo to accommodate the gas storage vessel to the inside upon with more rigid capsule for sealing from the outside, to below atmospheric pressure inside the gas storage vessel hydrogen gas is stored is to primarily the airtightness of the hydrogen gas is maintained by the outer atmospheric pressure, the air-tightness of the hydrogen gas secondly by the hard capsules and supplemented, buffer a change in pressure by the space between the gas storage container and the hard capsule .

It provides a hydrogen capsule to be put deep into the digestion period of life by storing the hydrogen gas in very small containers to be added for oral.

Gas storage vessels of the flexible film substrate storage container of the invention is where the gas is sealed to the container, but the rust, the water composition in the soft film is an organic solvent that is poorly soluble.

The gas is hydrogen, and the container is the thickness of the molding and cooling the dry film in consideration of the pressure change of the atmospheric pressure is 0.7 ~ 1.0mm, thickness of the joint is 0.6 ~ 0.95mm and the thickness of the restored nozzle insertion hole is 0.7 ~ 1.0mm .

The material forming the soft film on a plain gelatin, succinate gelatin, glycerol, starch, sorbitol, sorbitan as a plasticizer or softening agent, or a sol-byte sequence, polyglycidyl toll syrup, trehalose, mannitol, xylitol, maltose, reduced maltose syrup to sucrose , to select the maltitol, polyethylene glycol, and the composition of at least one or a mixture selected from among, purified water, etc. at least one black iron oxide, red iron oxide using a base material of the film.

In a gas contained in the vessel is a hydrogen gas is 70-97 volume%, soybean oil, safflower oil, refined fish oil, the purification is shared, sesame oil, red pepper seed oil, wheat germ oil, grape seed oil, olive oil, rapeseed oil, evening primrose oil, fruit flavor oil, and at least one component selected to be 3 to 30% by volume.

The method of the present invention, there is provided a method of filling and sealing the hydrogen gas in the gas storage vessel as a soft coating, a step to create a soft film temporary containers into sealing the holding therein of the flexible film, insert a hydrogen filling nozzle in the temporary container to comprise the step of withdrawing the temporary holding in the container, and injecting the hydrogen gas, by subtracting out the hydrogen filling nozzle out of the container, sealing the nozzle insertion hole bored in the temporary container by a hydrogen filling nozzle into the grouting material. The hydrogen will compete nozzle pointed like a needle, leaving a 3 to 30% to maintain when drawing out the held in the temporary container.

In the human colon, based on the fact that hydrogen gas is generated, by finding a substance that generates hydrogen gas well in the large intestine taking mixed with sugar or two to create a container for storing hydrogen gas, Chapter of the person taking it in such that hydrogen is generated.

The present invention is a hydrogen-producing candy by mixing with sugar in a ratio of 30% to 70% against the material to generate hydrogen gas in the colon by the intestinal flora (bacteria flora colon) to the candy.

Candy of the invention is to select the one or more, etc. as a material for generating hydrogen gas, lactose, raktyul as agarose, raffinose, stachyose, member bath coarse, curcumin, capsaicin, inulin, jinjeorol, allicin, subquery, glutenin .

The present invention, by intestinal bacteria group containing the substance and sugar to generate hydrogen gas in the large intestine, the material is a candy container made of a mixture such that at least 30% relative to the sugar, which comprises a hydrogen filled in the candy container a hydrogen-producing candy container.

The invention which boil up to a method for manufacturing a hydrogen-producing candy, wheat titol, mannitol, sorbitol, iso malteu, a mixture of alcohols at least one of (polyols), sugars such as xylitol under atmospheric pressure 150 ~ 200 ℃ evaporate most of the moisture the steps for creating the water of sugar removed every segyu agent (massecuites); Step lactose, and trehalose in raktyul, raffinose, stachyose, select the server bath coarse, curcumin, capsaicin, inulin, jinjeorol, allicin, etc. One or more subqueries, glutenin to add to the sheet segyu agent; The sheet segyu agent is achieved, including the step of molding or injection molding candy.

The present invention comprises a step to create a by a method for manufacturing a hydrogen-producing candy container, boiled the mixture evaporated to remove most of the moisture is water in the candy sheet segyu agent (massecuites); Step lactose, and trehalose in raktyul, raffinose, stachyose, select the server bath coarse, curcumin, capsaicin, inulin, jinjeorol, allicin, etc. One or more subqueries, glutenin to add to the sheet segyu agent; And a step of molding or injection molding the sheet segyu bit sugar container, and a step of charging the hydrogen gas was sealed in the container formed candy.

The present invention is one in order to pack the hydrogen-producing candy container, shipping, or storing a safe, made up of polyethylene, the water jacket of the thin cushion-shaped filled with water or fire-resistant anti-freeze, so as to melt and discharge the water or the fire resistance antifreeze when the degrees of 120 degrees will be.

According to the present invention has a closed empty space therein, and can be filled with gas in a compact vessel in which the water is in contact with the airtight destruction and storage and delivery.

Drink by dissolving the hydrogen storage container according to the present invention for oral administration or drinking water with normal drinking water it is possible to supply hydrogen gas to the inside of a living body.

The present invention can be deviated from the place and time constraints that may be taken to an active hydrogen.

The hydrogen storage container manufacturing method and apparatus of the present invention is able also to the compact packaging of a gas other than hydrogen.

When manufacturing a hydrogen storage container to the apparatus and method of the present invention, it is possible to easily adjust the consumption of hydrogen gas, and the contrast, the active hydrogen active oxygen is generated to adjust properly the supply, able to be loaded at a lower cost than the conventional method can do.

When using a flexible film substrate storage container of the present invention the hydrogen storage container, and remarkably improve the hydrogen gas storage capacity per container, the stretch corresponding to the outside temperature is improved, to reduce the calorie intake is effective.

The present invention is by ingestion of the sintered metal and gold water-based substance to extend the body feed rate of hydrogen is harmless to the human body without having to use the conventional method that generates a metal hydroxide to produce the hydrogen within the body.

According to the present invention, a person can be adjusted so that the gas generated inside the sheet and the food intake to normal by generating lots of hydrogen gas is beneficial.

The present invention is excellent in terms of safety than the human body to consume the calcium hydride acids by baking the calcium carbonate.

The present invention is electrolytic reduced water can be solved by the number of minority pouch, the number of hydrogen-rich, and to generate a stick can not resolve time and space constraints, and the concentration decreased.

The present invention is one can increase the efficiency of uptake of hydrogen by the hydrogen supply capacity than the smallest container with a compact container or the flexible film using a sugar which only functions to keep a larger hydrogen.

According to the invention there is an effect that it is possible to ensure the measuring of the difficult to solve in the conventional method because the quality and quantity can be a capsule unit upon administration to the inside of the human body.

Packaging material of the hydrogen-producing candy container of the present invention even when the hydrogen leak during storage due to any inadvertent or is a hydrogen storage container are exposed to a fire, there is an effect to prevent explosion to reach far.

Fig. 1 a), b) are cross-sectional views of the hydrogen storage container accommodated in the gas storage vessel / hard capsules according to an embodiment of the invention.

Figure 2 a), b), c), d), e) illustrates a flow chart for charging a gas storage vessel formed and hydrogen gas according to an embodiment of the invention.

Figure 3 a), b) it is a schematic view of the hydrogen gas filling system of the present invention,

4 is a cross-sectional view and a front view of the soft capsules (soft coating gas storage container) according to the present invention;

5 and 6 is a process explanatory diagram for explaining the hydrogen injection and the encapsulation method of the invention.

7 is a grouting nozzle and the solid-phase bonding the rod structural view for sealing after gas injection from the storage container of the present invention.

8 is a plan view and a side view showing the water jacket constituting the hydrogen-producing candy storage container of the present invention.

** Description of main reference numerals

1: a hydrogen storage container 2: a gas storage container 16: Hard capsule

6: a cylindrical vessel 7: hydrogen gas 21: temporary container

22: a top-sealed container 25: a hydrogen filling nozzle

26: Circular heat shrink band 41; Maintaining pumps,

42; Pumping holding control valve, and 44; Maintaining the discharge valve (drain valve)

45; Pumping keeping isolation valve 46; Pumping maintaining meshed pipe,

62; Hydrogen gas, 51; Soft coating gas storage vessel, 52; Out of the container,

53; The container, 54; Connecting parts of the container, 55; External length of the container,

56; the outer diameter of the container, 57; The restored nozzle insertion hole, 58; Maintaining balance

61; Soft film temporary container, 62; Keeping the contents, 63; Hydrogen filling nozzle insertion port,

64; Hydrogen filling nozzle, 65; Damaged nozzle insertion port 66; Grouting nozzles.

71; Melt adhesive rods injection unit (nozzle) 72; Solid adhesive rod heating section (heater),

73; Solid adhesive support rods (holda), 74; Solid adhesion rods

81; Unit water jacket 82; The convex portion of the water jacket,

83; Recess of the water jacket 84; female hook (male hook),

85; Male hook (female hook)

It will be described with reference to figures 1-8 than in the embodiments of the invention.

Hydrogen filling to the hydrogen storage container to be absorbed hydrogen to the human body, have a purity of absorption or metabolism are capable quality than 99.999% in the human body, the impurity in the hydrogen gas may be at a lower value than the concentration shown in Table 1 below .

Table 1

Item O 2 H 2 O CO CO 2 CH 4 N 2 Ar
Impurities in the hydrogen gas (ppm) 0.2 2 0.2 0.2 0.2 N / A N / A
Of purified hydrogen impurities (ppb) 10 10 10 10 10 10 10

Stage: the dust may contain not more than 1 per 0.1 micrometer (um) particles of 1 or less cubic feet (ft 3).

Hydrogen gas is a colorless, odorless, tasteless, non-toxic, suffocating gases flash point of explosion in the 550 ℃ and 4% to 74% limit the air volume ratio, the limited space within the a volume ratio of 18% to 59% limit as a combustible material, safe need to be stored or used within the range, the hydrogen atom may be the most compact and lightweight and the diameter from the element to be easily separated from the water molecules, becomes to rapidly spread in the air disappear into the air, there is a characteristic that can pass through even the human skin cells .

According to some published theory of the study with respect to hydrogen-decomposing enzyme, hydrogen lyase of the bacteria present in the soil microorganisms play an important role in the anaerobic metabolism as an enzyme that promotes the reversible oxidation of the hydrogen molecule, making the hydrogen molecule and also the other hand, and also degradation separated into hydrogen ions and electrons of hydrogen molecules, can also been found in recent mechanism using iron as a catalyst.

Molecular hydrogen (H 2) while the oxidation to give the electron to the electron acceptor (Electron acceptor), such as oxygen (O 2), carbon dioxide (CO 2), hydrogen is ionized. A low molecular weight compound and a ferredoxin (ferredoxins, ssito chromium c (Cyt ℃ hrome c), proteins such as are known to be related to the physical and hydrogen lyase opening electron can be an electron acceptor.

H 2 + A ox -> 2H + + A red

2H + + D red -> H 2 + D ox

Enzymes associated with the electron transfer are low oxidation-is to keep the reduction potential (ORP) is known to be essential for anaerobic metabolism.

Hydrogen gas in the hydrogen storage container and drinking by oral input such as drinking water, or dissolved in drinking water is decomposed by the hydrogen lyase (Hydrogenase) present in the bacterium of the microorganisms present in the body during metabolism in the body as molecular hydrogen proton and electron It is known to be separated by and. The separated hydrogen ions is responsible for clearing the hydrogen radicals as the active hydrogen atom.

There is known to be about 2% of the oxygen that is normally closed by an intake turned into active oxygen, and the amount of about 2,000 cc of oxygen to be sucked in one minute that is 40cc in a minute amount that varies by the active oxygen it is 24 times are a 57,600cc . On the other hand, according to Hayashi Hide "hydrogen-rich water can revolution" Mitsui book, the number of seeds and the dissolved hydrogen can be dissolved up to saturation in the water with a small amount of 1.49ppm, magnesium stick dissolved hydrogen amount of abundant hydrogen by is formulated as a 1.203ppm, to supply the hydrogen gas into the hydrogen-rich be any type of body, and shows the amount limit of a hydrogen storage container of the present invention is much higher than the ratio of hydrogen-rich compared to the active hydrogen radicals and to provide a method capable of supplying hydrogen gas.

The development of hydrogen gas packaging container suitable for oral administration in order to ensure that the hydrogen is absorbed by the body is necessary. And carrying will be reach the sheet after the oral administration period of time, the container which then has a hydrogen to diffuse out leak, that is in contact with water for a period of time develop such a container to be confidential while not being destroyed slowly confidential destruction this is necessary. A container of a capsule form a first selection is a sugar to be suitable for this purpose.

As the capsule material container for storing the hydrogen gas, marzipan and hydrogen gas in an environment in which the temperature and pressure changes need to select a material with a condition that the long-term storage can be secured to the interior of the candy.

The material of the sugar is the confidentiality of the air or nitrogen gas complete, well-confidential for the hydrogen gas according to a conventional soft candy, amorphous hard candy, conventional method of manufacturing a candy, etc. Sugar-free hard candy, calories 10Kcal per capsule or less, and a high tensile strength, and good thermal deformation in the process of manufacturing the container for storing the hydrogen and the glass transition temperature is more than 38 the content of the water in more than 3%, the organization and structure of the glass at room temperature to create a similar mixture is preferred.

As a material of the conventional sugar that may be applied to the mixture in the sugar and starch, maltitol, mannitol, sorbitol, iso malteu carbohydrate syrup mixture of xylitol and the mixture of the polyol (Polyols) such as sugar, maltose, syrup one or the composition may be in more of a mixture, can be used as additives also gelatin, glycerin is used as a raw material of the capsule.

When put in the molding of these materials in a given a from the removed lumps (Massecuites) the upper part of the possible capsule shaped oral In open flask moisture created by creating a thin area of ​​the one side is open to the interior of the candy cylindrical If the first space and then filled with hydrogen gas of atmospheric pressure or less compressed to seal the opening where the vacuum is a hydrogen storage vessel is a hydrogen gas is stored. If the candy composition and organization similar to the glass of the external air will mothana not penetrate into the interior portion of the molecular hydrogen in the interior is applying the principle could lead to leakage out of the sugar, but does not leak as the pressure less than atmospheric occurs. To be acceptable to a gas storage container in order to safely store hydrogen gas in the conventional hard capsule is a good tightness to increase 2 confidentiality drive the three airtight drive by putting heat-pressing the packing structure of the pocket both the upper and lower portions of the aluminum layer to prepare a hydrogen storage container in addition.

Hard candy is usually referred to as hard candy (hard sweets) or hard candy (hard boiled candies). These are basically the products obtained by strongly dehydrating a carbohydrate syrup as an amorphous solid is danggwaryu. Basically a so-called hard candy containing amorphous sugar or polyols may also be obtained by use of carbohydrate syrups in which hydrogen is in the carbohydrate syrup or some digestion added. Sugar-free hard candies have been receiving increasingly popular, since there is little inhibited, and the amount of heat than the conventional sugar hard candy to be also the tooth erosion is generated indicating a sugar-free hard candies are similar sensory characteristics. In general, sugar-free hard candy is prepared by boiling a mixture of the polyol is dissolved in water. Mixtures of these polyols boiled under atmospheric pressure to 150 ℃ -200 ℃ to evaporate most of the moisture. Performing a normal brewing process in vacuum to further reduce the content of the water, and wherein the normal moisture content, the lower the value is low if more than 2.5%, to 1.5% or less. So many substances the resulting message is cute (massecuite), for example (scented) in, coloring in, a powerful sweetener in, mountains, plant extracts of, vitamins and or extruded on the insert into the mold to cool it again after adding the active jeyakseong those rolls create a shape by. Techniques for such hard candy is well described in Korea Patent Registration No. No. 0,163,252.

Or less, with respect to the hydrogen storage container and a method of manufacturing the same according to an embodiment of the present invention with reference to the accompanying drawings will be described.

Figure 1 and given like reference numerals to like parts of Figure 2, and is omitted the detailed description thereof.

Example 1.

As shown in Figure 1a, a gas storage vessel of the present invention is made so as to create a candy gapsel the capsule-shaped storing hydrogen gas. A gas storage container (2) is made including rigid capsule (16) having a space therein. Into the gas storage vessel (2) therein made by bonding the bottom 3 of the rigid upper capsule (4) and a hard capsule of a nitrogen gas atmosphere. So hard capsules, the bonding portion of hydrogen storage container (1) 5 is formed is created.

A gas storage container (2) is such, semi-spherical in the vessel cylinder 6 and the cylindrical outside (8) of the container, and the cylindrical inside (9) of the candy, both ends of the outside of the cylinder shown in cross-sectional view of the substrate storage container of Figure 1b the end plate 10 of the can consists of one body, the hydrogen gas (7) below atmospheric pressure stored in the cylinder inside (9), is made of a possible oral feed size.

The tensile strength in consideration of the pressure applied to the interior and the exterior of the vessel cylinder 6 is subject to withstand 1.1 times the atmospheric pressure, the outer diameter (D, 14) is 8mm, a length of the outer cylinder (L2) is 14mm , and the total length (L1) of the container combining the end plate 10 at both ends does not exceed 22mm.

Assuming that a pressure variation trend of the hydrogen gas stored within the hydrogen storage container (1) according to the external temperature change as an ideal gas look are shown in Table 2, below, on the assumption as an ideal gas the hydrogen gas charged with 1 atmosphere at 15 ℃ the space of the container and the capsule between the response to the gas storage vessel (2) and a rigid capsule (16) to the temperature change as a 0.87 kg / cm 2 at minus 30 ℃ and indicating at 30 ℃ 1.09 kg / cm 2 with a 17, a space H of when to place the internal cylinder of the container 9, the pressure is higher than the pressure in the cylinder outside (8) of more than 1% of the interval of the external diameter (14) of the container barrel cylinder interior (9) go out to a part of the gas (7) transmitting a cylindrical outer (8) is locked together with the nitrogen in the vessel and the capsule space 17, whereas when the pressure in the cylinder interior (9) lower than the pressure in the cylinder outer 8 gathyeotdeon hydrogen gas south up reversible transmission back to the cylinder inside (9) As to absorb some of the pressure change applied to the gas storage vessel (2) it can be a buffer action.

Table 2

Temperature ℃ -45 -30 -15 0 15 30 45
K 228.15 243.15 258.15 273.15 288.15 303.15 318.15
Charge pressure of the hydrogen gas (kg / cm 2) 0.98
The pressure fluctuation of the hydrogen gas (kg / cm 2) 0.82 0.87 0.93 0.98 1.03 1.09 1.14
Cylindrical internal volume change (at 15 1) 0.95 1.00 1.05 1.10
Cylindrical outside diameter change (1 in 15 ℃) 1.00 1.03 1.05
The required spacing between the outer diameter of the cylindrical capsule with sugar% 0 2 3

The material of the gas storage container (2) according to the method of manufacturing a conventional sugar etc. conventional candy, amorphous hard candy, sugar-free hard candies and the confidentiality of the air or nitrogen gas complete, well-confidential for the hydrogen gas, heat is or less 10Kcal per capsule, high tensile strength, and good thermal deformation in the process of manufacturing the candy container for storing hydrogen, a glass transition temperature of the content of water being at least 38 ℃ at least 3%, of the glass at room temperature it is preferred that the tissue and configured to create a similar mixture.

As a material of the conventional sugar that may be applied to the mixture in the sugar and starch, maltitol, mannitol, sorbitol, iso malteu carbohydrate syrup mixture of xylitol and the mixture of the polyol (Polyols) such as sugar, maltose, syrup one or the composition may be a mixture of at least, and can be used as additives also gelatin, glycerin is used as a raw material of the capsule.

A gas storage container (2) purity of the hydrogen gas is at least 99.999% is filled in, the dust contained in the hydrogen gas is less than 1 per 0.1 mouth self 1 ft 3 of less than one micrometer. Hydrogen gas (7) to be filled below the atmospheric pressure outside of the gas storage container 2, air or nitrogen gas introduced from the outside, but blocks the gas storage vessel (2) a hydrogen gas inside is when the atmospheric pressure Lee Sangil the hydrogen chamber 6 of as it may be some leakage, but the leakage of the hydrogen gas when the pressure of the hydrogen gas inside the gas storage container equal to the atmospheric pressure or lower does not occur.

Example 2;

Method of filling hydrogen gas in a gas storage vessel (2) is as shown in the flow chart for charging the hydrogen gas of the present invention of Figure 2,

a) the mold, as shown in the figure that at the option of the conventional candy ingredients into each necessary additives in sugars, a mixture of carbohydrate syrup, lumps of a predetermined water and the mixture made with a raw material of polyol removal (Massecuites) and cooled put in to make their appearance. The additives, the iron (Ferrous fumarate) promoter for decomposing hydrogen molecules into hydrogen atoms (active hydrogen), vitamin C, vitamin E to assist the antioxidant role, polyphenols (Polyphenol), carotene (Carotene), calcium, etc. It may also be included. Iron is preferably not exceeding 4mg per capsule.

Flask of the container is the same as the method for molding the conventional candies and the flask is made of a shape and structure that can be molded, a temporary container 21 of Fig. 2 a), the lower the capsule shape and the upper part a circular column the structure align the upper projection 24 of the container so that it can be pressed by the shrink band 26 and the lower portion of the temporary container 21 the center of a hydrogen filling nozzle (25) of a metal forming the insert holding the form has the. The length of the temporary container 21 is equal to the sum of the height of the closed upper container portion to the total length (L1) (28) of the containers the width of the circular heat shrink band 26 is equal to the end plate 10, the thickness of the container.

b) there is an upper projection 24 of the temporary container 21 filled with a circular heat shrink band (26), 10 -1 Torr (Torr) by pumping the degree of vacuum by the inside of the hydrogen filling nozzle 25 to the vacuum pump and an I, and then filled with hydrogen gas from a hydrogen gas supply below the atmospheric pressure.

c) the length of the inner cylinder as shown in the hydrogen filling nozzle 25 is 2 c be allowed to warm to the glass transition temperature or higher) by the built-in heater (

Figure PCTKR2011002536-appb-I000001
) And is retracted to an end of the length plus the width of the circular heat shrink band (26) container. At this time, the cylinder length of the temporary container 21 is the length of the inner cylinder of the vessel (
Figure PCTKR2011002536-appb-I000002
) And it is equal to the sum of the width of the circular heat shrink band (26). Throttle of the temperature (glass transition temperature) of heat shrink band 26 or more increases in which can be modified upper projection 24 of the container by when the hydrogen filling nozzle retract the device on a circular heat shrink band (26), heater ( 27) equal to the circumference of the lower heat shrink band (26) the temporary container 21 by the tightened until the sealing is completely pressed by the length corresponding to the width of the circular heat shrink band (26). When the pressure for sealing the inside of the temporary container 21 is made of a cylindrical interior (9) of the container it is closed, leaving only the upper portion (28) of the container. And it controls the temperature and moisture in the temporary container 21 by the control device in order to prevent cracking of the container in the course of sealing and crimping the upper projection (24) to balance.

d) the cylindrical interior (9 of the container 22, the top is sealed, such as in Fig. 2 d)) is a length of the inner cylinder (

Figure PCTKR2011002536-appb-I000003
), The hydrogen gas (7) having a thickness and an upper closed portion 28 hydrogen filling nozzle (25 in a state with a high sum of the upper part of the is filled to below the atmospheric pressure the cylindrical outer (8) the end plate 10) as completely out retract and remove the round and heat shrink band (26). Break could not be forced to sealing should grouting (Grouting) as a starting material of candies.

e) while the application of heat to a temperature at which the top can be a modified upper closed portion 28 of the sealed container 22 namgyeonotgo by a thickness of the end plate 10. FIG. e. 2 after the removal of the upper closing part 28) a gas storage container (2) shown in Figure 1 to the closed end plate of the top 10 in a semi-spherical, such as to complete manufacturing.

Example 3;

When Figure 3 is described, as shown in a schematic view of the hydrogen gas filling system of the present invention, Figure 3a, relative to the case where hydrogen filling mesh pipe part connected to the hydrogen filling nozzle used to combine the pumping and filling,

Hydrogen gas filling system comprising: a hydrogen filling nozzle 31 consisting of n number of hydrogen filling nozzle 25 and the auxiliary device, and a hydrogen charge meshed pipe 32 and a hydrogen filling mesh connected to the hydrogen filling nozzle 31 pipe 32 is connected a vacuum pump 41 and the pumped gas control valve 42 is a vacuum pumping unit and, connected to the hydrogen charging meshed pipe 32 and hydrogen gas source 33, the hydrogen gas pressure regulator (34 having a ), and a hydrogen gas supply unit having a hydrogen gas control valve 35 and the hydrogen gas filter 36, connected in parallel with a hydrogen gas supply in the hydrogen filling mesh pipe 32 and the nitrogen gas supply source 37, a nitrogen gas the pressure regulator 38, nitrogen gas control valve 39 and nitrogen gas filter 40, a nitrogen gas supply and the pumping gas exhaust valve 44 to the pump gas exhaust, supply gas discharged to purge the feed gas having and a valve 43.

3 of b) is a case where the hydrogen filling nozzle portion and connected to the hydrogen charging meshed piping and pumping gas meshed pipe separated using a hydrogen filling nozzle section (31, consisting of n number of hydrogen filling nozzle 25 and the auxiliary device) and , n of pumping gas separation connected to the valve 45, the hydrogen filling nozzle 31 and the hydrogen filling mesh tubing pumping gas mesh tubing (46) (32) is separated, it is associated with the hydrogen filling nozzle 31 by a vacuum pump 41 and the pumped gas control valve 42 is a vacuum pumping unit and, n of pumping gas separating hydrogen filling nozzle by the valve 45, 31 and the hydrogen filling mesh tubing (32) is connected having and, pumping a gas exhaust valve for a nitrogen gas supply unit, and a pumped gas in parallel with the above hydrogen gas supply part of the connected to the hydrogen charging meshed pipe 32, a hydrogen gas supply in the hydrogen filling mesh tubing (32) exhaust ( 44), and the exhaust gas supply valve 43 and pumping the gas to the purge gas supply Comprising a hydrogen gas-filled system.

In the hydrogen gas filling system of the present invention, referring to the charging process in Fig. 3 a), the hydrogen gas control valves 35, the nitrogen gas control valve 39, the feed gas exhaust valve 43 and pumping the gas control valve close and 42 by opening the pumped gas exhaust valve 44 pumping gas control valve 42 after the operation the vacuum pump 41 in a state placed in the operating state, closing the pump gas exhaust valve 44 is left open for hydrogen pumping the inside of the mesh filling pipe 32 and the hydrogen filling nozzle portion (31) of n hydrogen filling nozzle 25 of the vacuum will be larger the degree of vacuum to 10 -1 Torr (Torr). If a n number of hydrogen filling nozzle (25) and their passage reaches a predetermined degree of vacuum close the pumped gas control valve (42), n number of hydrogen filling nozzle 25 by opening the hydrogen gas control valves 35 in the hydrogen gas supply to be filled with hydrogen gas via the hydrogen gas pressure regulator 34 and filter 36 from the hydrogen gas source 33 to reach the atmospheric pressure. When a predetermined hydrogen gas charging is completed, hydrogen gas control valve 35 to close stopping the supply, each of the upper projecting portion of the hard candy in accordance with thermo-compression bonding process as described by each of the circular heat shrink band (26) described above ( crimp 24) to seal the charged hydrogen gas.

Nitrogen gas in the nitrogen gas supply is maintained or when an emergency nitrogen gas pressure regulator 38 and the filter by opening the gas control valve 39, the nitrogen to be for use in the when to purge the interior of the filling system from the nitrogen gas supply source 37 to the through 40, and supplies the nitrogen gas. Nitrogen gas can also be used as nitrogen rod incorporated inside the system at the time of plant tissue, and the exhaust gas supply valve 43 can exhaust the hydrogen gas by opening a valve, as needed, and may discharge the nitrogen gas.

Looking at the filling process in Fig. 3b) in the hydrogen gas filling system according to the invention, n of pumping a gas separation valve 45 pumping gas control valve 42 is in the separated state and the hydrogen filled mesh pipe 32 by closing the close pumping gas meshed pipe by opening the pumped gas control valve 42 after the laying open the pump gas exhaust valve (44) operating the vacuum pump 41 is put in the operating state, closing the pump gas exhaust valve 44 (46) and the hydrogen pump the inside of the filling nozzle portion (31) of n hydrogen filling nozzle 25 of the 10-1 torr (Torr) to increase the degree of vacuum to. If a n number of hydrogen inside of the filling nozzle 25 and the passage reaches a predetermined degree of vacuum close the pumped gas control valve 42, by closing the n pumping gas separation valve 45 is communicated with a hydrogen filled mesh pipe 32 a later, hydrogen gas control valve 35, the opening of n hydrogen filling nozzle 25, the hydrogen gas supply hydrogen gas pressure regulator 34 and filter 36 from 33 to reach the atmospheric pressure of a hydrogen gas supply the via is filled with hydrogen gas. When a predetermined hydrogen gas charging is completed, the hydrogen-gas control valve 35 to close stopping the supply, each of the circular heat shrink band (26) each candy upper projection 24, depending on the thermal compression process of the by pressing the lower portion is sealed to the charged hydrogen gas. Function of the nitrogen gas supply is the same as described above.

When the manufacturing process clean up the top of the point as follows:

Preparing the removed lumps (Massecuites) moisture in the raw material for the candy, and preparing a candy flask after cooling, by addition of necessary additives, and properly installed at a height set to a hydrogen filling nozzle in a position central portion, and hydrogen in the interior of the flask placing a maese acute while the filling nozzle is inserted to form a temporary container.

When filling the circular heat shrink band to the upper projecting portion of the temporary container and pump vacuum the inside of the hydrogen filling nozzle and filled with hydrogen gas inside the hydrogen filling nozzle, increasing the temperature of the hydrogen gas filling nozzle retracted into the end of the upper projection temporary container the inside is formed.

Tighten by the circular heat shrink band compression until the upper projection is a rule sealing a top-sealed container.

Fully retracted out of the hydrogen filling nozzle and grouting, if necessary after removal of the circular heat shrink band, removing the upper closed portion of the upper container is sealed and closed to be a hard decision of the upper ends the production of gas storage vessels.

When put into the adhesive to seal the gas storage containers in hard capsules in an atmosphere of nitrogen, and ends the production of the hydrogen storage container according to the present invention. Processes packaging the completed structure of the hydrogen storage container to the medicine pocket with a layer of aluminum on the top and the bottom.

Example 4.

It describes a method for producing a gas storage vessel of further improving the storage vessel for gas non-rigid soft.

Materials used in the production of the temporary gas storage of the flexible film container is a conventional as used in the soft capsule manufacturing, succinic acid, which are normal gelatin, amino group derived from natural collagen is substituted with a carboxyl increase the disintegration stability (succinic acid), gelatin, sorbitol, sorbitan or solbiyi as glycerin, sea bass glycerin, starch, a plasticizer or softener bit series, polyglycidyl toll syrup, trehalose, mannitol, xylitol as sucrose, maltose, reduced maltose syrup, maltitol, alone or in mixture of more, etc. polyethylene glycol a composition, and to select one or more species in a purified water, black iron oxide, red iron oxide are mixed, swollen, dissolved, and defoamed to prepare a base material of the film (gel mass).

The contents of the flexible inner vessel temporary coating is used to keep a material that can stabilize the film without a surface active agent between the film and the contents because it is substituted with hydrogen gas after the container is manufactured. As the base to keep the soya bean oil, safflower oil, refined fish oil, the purification is shared, sesame oil, red pepper seed oil, wheat germ oil, grape seed oil, olive oil, rapeseed oil, evening primrose oil, one or more selected from holding bars ilhyang oil.

How to create a temporary soft coating vessel as shown in the conventional manufacturing method, putting the contents in the middle of the two sheets of the film base material makes a temporary soft capsule with integrated sealing the contents to adhere the two films with oval.

In which ordinary rotary automatic devices (molding machine), creating a film with a film thickness uniform gel was cooled to about 12 ~ 20 o C, relative humidity of the cold air of about 20-30% in the following will be transferred to the molding machine. The content is filled via the predetermined ryangssik charger.

Towing a uniform film on the side of both ends of the spread box (spread box) of the charger, and to seal both sides of the film adhered by a die roll (die roll) mechanical pressure and electrical heat (35 ~ 40 o C) of by the balance of leaks or moisture content in the bonding portion (seam) in a sealed coating film lost Do not get variant of the constellation.

The flexible film substrate storage container, as shown in the sectional view of Figure 4, the longitudinal section is an elliptical cross-sectional view has an outer shape like a rugby ball which is circular. A gas storage container is a flexible film made of a capsule form a hydrogen gas (7) with a predetermined pressure, with a basis of the contents and maintain a small amount of the remaining amount (58) is stored the flexible film substrate storage container 51. It is also possible to structure that can be accommodated with a predetermined space inside the hard capsules to protect a hard capsule to the outside.

The flexible film substrate storage container 51 and the outer 52, inner 53, the joint 54 and the hydrogen end plate is restored nozzle insertion port 57 parts damaged during charging of the container of the vessel of the container is formed, and interior 53 of the container has a structure that hydrogen does not exceed two times the atmospheric pressure gas held in 7 and 3 to 30% level (58) are stored, the external length of the vessel: and (55 L) the outer diameter of the container (56: D) is prepared as a possible oral input standard. .

Dissolution time of the flexible film substrate storage container is to be within 12 minutes as far as to the reinforcement of a rigid capsule, and to within as long as 30 minutes to take into soft capsules alone or with standard considering the pressure on the inside and the outside of the gas storage vessel tensile force (tension) or elastic (elasticity) is able to withstand 1.1 times the predetermined pressure, the film thickness of the flexible film temporary container 61 during the molding is 0.8 ~ 1.1mm in thickness, and dried after cooling in a conventional manner It will be a 0.7 ~ 1.0mm. The thickness of the seam 54 of the container is to be 0.6 ~ 0.95mm by cooling after drying, the thickness of the restored nozzle insertion port 57 causes a 0.7 ~ 1.0mm with a cooling dry basis.

Manufacturing method of the flexible film substrate storage container and is in the process of filling and sealing the molding process and the hydrogen gas of the flexible film substrate storage container.

In the molding step of the flexible film temporary container 61, to prepare a soft capsule is sealed to keep the inside as in the conventional technology, the process step described in Fig. 5 for discharging the internal retention of the soft capsule was filled with a hydrogen gas even and as it is shown in FIG.

The method is a conventional soft capsule manufacturing and, in the practice of the process for producing a soft coating gas storage vessel (51) by sealing and filled with hydrogen gas in a compact soft film temporary container 61 as shown in a) of Figure 5, first makes a soft film temporary container 61 with a joint 54 of a given a certain thickness to enhance the tensile strength and elasticity, and filling and sealing the maintenance contents 62 to the interior of the vessel to a component of the flexible film to be used .

Next, 5 of b) and, as a temporary container 61 that establish the joint 54 hydrogen filling nozzle insertion port 63 in the container in the lower end plate portion of the container in a state located in the vertical, insertion of the nozzle (63 ) through the insert in a direction that corresponds to a hydrogen filling nozzle 64 of the sharp needle-shaped central portion to maintain the depth within the temporary container 61 from the bottom length.

Then, as shown in c) of Figure 5, the inner moving length temporary container 61 for the hydrogen filling nozzle 64 after checking the airtightness of the hydrogen filling nozzle insertion port 63, the depth of holding remaining in the interior maintained and the contents 62 is discharged by pumping through the hydrogen filling nozzle, and then become a state in which the holding level 58 in the temporary container remaining after charging the hydrogen gas is laid on the floor of 3 to 30% containers, hydrogen filled with a gas (7) to a predetermined pressure. The filling pressure is not to exceed two times the atmospheric pressure.

Next, as shown in d) of Figure 5, and confidentiality film formed on its own by the holding capacity (58) and fully retracted out through the filling nozzle insertion port 63 of the hydrogen filling nozzle 64, the temporary container 61 by the elasticity of the film itself it should be provisionally held in confidence to the damaged nozzle insertion port 65.

And as shown e in Fig. 5), the temporary container 61 temporarily while confidentiality is injected from being maintained by the grouting nozzle 66 a of the flexible film material to the damaged nozzle insertion port 65, a predetermined injection pressure and this causes the grouting (grouting) process by bonding, by an electrical temperature (200 o C or less).

The grouting nozzle 66 as shown in Figure 7, the molten adhesive is injected into contact that penetrates the damaged nozzle insertion port 65 can be a bar is bonded in the solid phase melt the damaged nozzle insertion port 65 for use in grouting process the rod and the injection unit (71), 200 o and C solid state bonding bar heating unit 72 with the available electrical heater and the heat conductor is heated up, the rod adhesion of the solid line to push through the cylindrical passage and the passage to move towards the nozzles a number of solid-phase bonding rod support portion 73, and a solid phase bonding bar 74 is inserted into the solid adhesive rod support portion having a push rod (pusher), which is configured.

The material of the flexible film for grouting is to be able to melt, so that the penetration portion the flexible film material as a main component from the gelatine and as an adhesive rods in a strong solid state adhesive 200 o C or less in damage to the body.

Implantation method of the flexible film material, the position of the damaged nozzle insertion port 65 causes the side above and adjusting the direction of the temporary container 61, the solid-phase welding rod 74 in a state inserted into the solid adhesive rod support portion 73 a melt adhesive rods injection section 71 and in close contact with the nozzle insertion port 65 is damaged, the nozzle, by using a plunger with a solid phase bonding rod support portion 73, while as much as possible to push the melt-bonding the rod inlet 71 orientation solid adhesive rod inserting the electrical heater of the heating portion 72 penetrates sealed to the nozzle insertion port 65 is damaged while the front part is melted by the melt adhesive rods implanted region 71 of the solid-phase welding rod 74 in more than 200 o C the nozzle insertion port 57 It is restored and is sealed.

So, as shown in f) of Figure 5, the hydrogen gas and maintain the flexible film gas storage vessel (51 the residual amount the seal) to the interior is produced is in a state ready to be received in the interior of the protective rigid capsule has been completed.

In this embodiment, the system for charging the hydrogen is used in the hydrogen gas filling system shown in, Figure 3b, as described in the third embodiment.

First temporary container, keeping the loading of the temporary container sealed inside the unit hydrogen filling nozzle and, n of pumping maintained separated by closing the valve 45 additional hydrogen filling nozzle hydrogen filling mesh tubing (32) and separated for the hydrogen gas-filled in the state, closes the pump holding control valve 42 is at a maintenance discharge valve 44 to open and operate to maintain pump 41 discharges the held pump keep the inlet line, and then maintained while keeping the maintenance pump operation state discharged to close the valve 44 is kept pumping opening the pumping holding control valve 42 is meshed pipe 46 and the n number of hydrogen filling nozzle 64 and the flexible film a gas storage vessel 51 of the hydrogen filling nozzle 31 by pumping the holding in the discharges. At this time, to control extent that the amount of the maintenance in the temporary container remaining after charging the hydrogen gas remaining 58 is 3 to 30% is maintained attached to the container so that the retained attached to the filling nozzle 64 remains reasonably need. So when the pressure in the pump inlet to maintain a certain degree remain inside with the passage of n hydrogen filling nozzle (64) reaches a predetermined negative pressure in size to close the pumping holding control valve (42), the n pumping maintain separation valve ( 45) the opening is in communication with the meshed pipe 32 additional hydrogen filling nozzle hydrogen charging. After doing this, by opening the hydrogen gas control valve 35 in the hydrogen gas supply unit n of the hydrogen filling nozzle 25, the hydrogen gas pressure regulator 34 and the filter from the hydrogen gas source 33 to reach the predetermined pressure through 36 to charge the hydrogen gas. When a predetermined hydrogen gas charging is completed, hydrogen gas control valve 35, the closing stop the hydrogen gas supply, and out by subtracting from the temporary container to back the hydrogen gas filling nozzle, the nozzle insertion port of the temporary container for grouting nozzles (66) in place of connected to (65) will be bonded to the grout (grouting) treatment following the introduction of the flexible film material with a predetermined nozzle insertion port 65 is damaged by injection pressure and temperature (below 200 o C). This is the state that the hydrogen gas and maintain the flexible film sealing a gas storage vessel (51) remaining inside are prepared ready to be received in the interior of the protective rigid capsule has been completed.

Example 5:

Mixed with sugar by the intestinal flora to be 30% to 70% against the material to generate hydrogen gas in the large intestine in the candy will be described according to create hydrogen-producing candy.

Flatulence (flatulence) is there is released is delivered to the job by the interlocking (peristallic) action of the digestive system, such that the slurry as a gas mixture out as a by-product in the digestive process in a mammal pulled down from the large intestine, the main of the fart of that of the non-toxic, odorless component is commonly known looks like this: Table 3.

TABLE 3

Item nitrogen Oxygen Hydrogen carbon dioxide methane
main ingredient 20 to 90% 0 to 10% 0 to 30% 10-30% 0 to 10%
Average 55% 5% 15% 20% 5%
Generator When the air intake When the air intake Fermented in the large intestine Fermented in the large intestine Fermented in the large intestine (30% of the adult only)

As coming from among the non-toxic, odorless flatulence nitrogen and oxygen in the air we swallow, oxygen is absorbed by the body, but the nitrogen is not so not absorbed is discharged via the flatulence. The hydrogen gas from a hydrogen gas, carbon dioxide and methane gases generated in the colon is termed a large amount is carried in the blood vessel, unwanted carbon dioxide and methane gas is released through the many flatulence.

On the other hand, the odor Castle fart, the compounds containing sulfur, such as chiol (methaneethiol), hydrogen sulfide, di-methyl sulfide (diemthylsulfide) in that methane by the meat protein, such as scale tolyl, indole and ammonia is in its components and in the large intestine It corresponds to about 1% of the gas produced.

People with adult reference to emit by dividing the 500 ~ 700 cm 3 gas per day about 15 circuit, the hydrogen gas that is generated from that is the 75 ~ 105 cm 3 per day, such as some of the other gas through the anus in that emission and the other part enters into the blood stream of the barrier by the process of the lumen (lumen) that is higher than the partial pressure of the blood diffusion (diffusion) through the passage of nutrients to pass through in the field. The hydrogen gas delivery along the blood flow, and also penetrate into the cells, and also a part of which is the blood out from the blood when it passes through the lungs and exhalation discharge with (exhale). Carbon dioxide and methane gas are generated as this time is mostly being discharged through the anus into the blood stream and some of the barriers is integrated with the other carbon of the varicose veins.

It is fermented by bacteria in the colon group look at the research that generates hydrogen and support that the generated hydrogen is a powerful antioxidant;

In practice the process of experimental physiology for medical students breath hydrogen test of hydrogen gas generation in the gut - Breath hydrogen testing as a physiology laboratory exercise for medical students, Ramon G. Montes, Richard F. Gottal, School of Medicine, Johns Hopkins University, accepted Dec 23 1991 - breathing as a way to identify the absorption reduction of carbohydrates from hydrogen tests, for analysis by the ssaempeul collected when the exhalation in the practice of BHT as a learning tool, through the nose, well prongs (nasal prong) described in gas chromatography geotinde, was as a result of lactose, fructose and raktyul more to malabsorption of the students is the small intestine than those who consumed the monosaccharide is glucose or sucrose intake OSU hydrogen gas is detected in which the enzyme rakte Izu (lactase) a report that due to the deficiency.

The test results of the breath hydrogen is affected by factors that are relevant to quantitative or qualitative aspects of the Enterobacteriaceae group. The purpose of the study was to whether changing the discharge capacity of the hydrogen gas after oral administration of trehalose to raktyul when there is a loss in the original state of the colon. - Influence of colectomy on hydrogen excretion in breath, Francesc Casellas, Francesc Casellas, A. Torrejon, accepted Oct 14 2008 - The test results of hydrogen gas in the patient embellish completely in the small intestine than in the colon of patients with well-managed or partially resected this is significantly lower emissions report.

An enzyme hydrolyzing raffinose to the female alpha-D-galactosidase to the intake come Days (aD galactosidase) and to track the pattern of biological rhythms, was used as the hydrogen breath test method (BHT) -Circadian rhythm of breath hydrogen in young women, Mieko Kagaya, Mayumi Iwata, accepted Jan 23. 1998) - results of the tests in this report sect - ingestion than (24 ppm) when not ingesting D-galactosidase coming Days (17 ppm) is 7 ppm lower when also a lot of dietary fiber intake as that hydrogen gas may be further generated, it can be inferred that girls are more common hydrogen gas is by eating lots of dietary fiber containing a simple sugar.

The eight that the foundation of the numeric curry ingredients of curcumin (curcumin) for a gyeongang subject ingested a curry and non-curry containing ssaempeul and collected and analyzed by gas chromatography. - Effect on dietary turmeric on breath hydrogen, Akito Shimouchi, Kazutoshi Nose, Dig Dis Sci. 2009; 54 (8): 1725-1729 - the result is a curry containing emitter numeric had increased notably to breathe hydrogen remarkable than otherwise Curry stylized reduce the elapsed time of the small intestine, activating the intestinal party power and carbohydrate colon in the entry into force of that a report.

Antioxidant and anti-inflammatory effects of curcumin, is for the therapeutic effect of the active mode and pathological conditions. - Antioxidant and anti-inflammatory properties of curcumin, Venugopal P, Menon and Adluri Ram Sudheer, IE Magazine, Sep 2001 - Cylooxygenase-2, the nitric oxide synthase Lypooxygenase and derivatives of curcumin are the enzymes that mediate the inflammatory process. Inflammation is in a close relationship to the promotion of a tumor, has chemopreventive properties on carcinogenic factors, active peroxide damage to the lipid membrane to oxygen is involved, oxidative damage of DNA (DNA) and proteins that are associated with a chronic pathologic complications as a report, it is inferred that the intestinal hydrogen generation and association of curcumin.

Curcumin has been shown to inhibit the skin, mouth, intestines, mechanisms that protect against cancer-causing factors (carcinogenesis) of the colon, and the creation of new blood vessels from existing blood vessels in the tumor models of various animals (angiogenesis) and metastasis .- Cancer chemopreventive effects of curcumin, Young-Joon Surh, Kyung-Soo Chun, Advances in Experimental Medicine and Biology, vol 595 - curcumin inhibits cancer cell proliferation of, by trapping them in the different stages of the cell cycle, and induce the death of a programmed cell. In addition, curcumin is inferred that there is a report that inhibit the biological activation of carcinogens by inhibiting the cytochrome P450 isozyme that the detoxified drug by the electron transfer chain, this is also associated with intestinal generating hydrogen gas of curcumin.

The curcumin, capsaicin and edible spices through the mice induced hyperlipidemia on lipid-lowering and beneficial effects of antioxidants on the health of the evaluation was to ensure that the synergy effects of bio-active compounds .- Hypolipidemic and antioxidant effects of dietary curcumin and capsaicin in induced hypercholesterolemic rats, H. Manjunatha and K. Srinivasan, published on line, Oct. 2007 - curcumin, and capsaicin were from mice in the liver and lowers cholesterol in the blood lipid peroxide, ascorbic acid has been strengthened between in the normal rats, as well report that the reducing agent glutathione in the strengthening of hyperlipidemia rats, curcumin and / or intestinal production by capsaicin is inferred that there is associated with the hydrogen gas.

Due to the lack of the enzyme does not exist in the digestive tract of a person not being absorbed due in the small intestine by hydrolysis eventually be fermented as food for bacteria soldiers bacteria present in the part of the large intestine colon, detoxification, including hydrogen gas As the material which promotes the formation of an odorless gas;

First, is contained in dairy products, including milk, and lactose (lactose) that corresponds to a simple sugar of the carbohydrate, there is fructose (fructose), and raktyul Ross (lactulose), synthetic artificial, singer of the material reached adulthood decomposition it is an enzyme that causes a rise rakte (lactase) deficiency is to do not decompose in the intestine.

Second, is contained or the like legumes, cabbage, broccoli, asparagus, raffinose system (RFO) corresponding to a simple sugar of the carbohydrate include trisaccharides of raffinose (raffinose), 4 saccharide of stachyose (stachyose) and 5 sugars in burr Bath coarse (verbascose) is representative inde, enzyme alpha hydrolysis of the material - does not decompose absorbed in the small intestine because the galactosidase City Days (a-galactosidase, a-GAL) not in the digestive tract of a person .

Third, curcumin of turmeric (turmeric) are used as edible spices (curcumin), capsaicin belonging to the acid amides of the pepper (capsaicin), pig potato, burdock the polysaccharide inulin (inulin) containing the like, jinjeorol of ginger (gingerrol), allicin of the sulfur compounds contained in garlic (allicin) or the like are not be degraded and absorbed in the small intestine because these respective hydrolase is not present in the digestive tract of a person.

Fourth, wheat, vain (gluten) in the endosperm (endosperm) of rye, barley, oats, etc. is composed of a protein called gliadin (gliadin) and glutenin (glutenin), glutenin is involved in the interconnection of delusion since the enzyme is deficient for those who do not decompose in the intestine's absorption with the sulfur atom to decompose vain singer.

Embodiment, a method of manufacturing a candy Example 2 a) The mixture according to a predetermined step of the removed message tyuteu water produced by a raw material, adding a compound to the sugar vessel or sugar induced to produce a beneficial hydrogen gas in the intestine in in the step of, adding one or more compounds, etc. raktyul Ross (lactulose) a synthesis of lactose (lactose) and artificial as fructose and galactose derived from dairy products, including milk, or legumes, cruciferous vegetables, the cabbage, broccoli etc., asparagus, kale, radishes, trisaccharides of raffinose (raffinose), 4 saccharide of stachyose (stachyose) and 5 saccharide of member bath coarse (verbascose) of raffinose system (RFO) of extracting, etc. cabbage one or adding more compounds, or curcumin (curcumin) derived from turmeric (turmeric) are used as edible spices, peppers of capsaicin (capsaicin), If potato, inulin (inulin) extracted etc. burdock, jinjeorol (gingerrol) extracted from ginger, and add one or more compounds, etc. allicin (allicin) extracted from garlic, or wheat, rye, barley, in the endosperm (endosperm) of oats by adding one or more compounds derived from a subquery (gluten) and glutenin (glutenin) by cooling the message to the acute or injection molding to produce a hydrogen-producing intestinal sugar.

In step a component of the message is cute the first adjusting drive in the step of the candy vessel or candy add a compound that generates induced a beneficial hydrogen gas in the intestines as lactose, raktyul trehalose, raffinose, stachyose, member Bath by adding one or more compounds, etc. coarse, curcumin, capsaicin, inulin, jinjeorol, allicin, subquery, glutenin by cooling the message to the acute or injection molding to produce a hydrogen-producing intestinal sugar.

In the message acute made from a mixture of sugar alcohol, in order to further increase the hydrogen gas produced in the field, adding only the compound to induce eliminate the ability to store hydrogen gas therein, to produce a beneficial hydrogen gas in the intestine more to, lactose, raktyul as agarose, raffinose, stachyose, member bath coarse, curcumin, capsaicin, inulin, jinjeorol, allicin, subquery, message to the molding or injection in addition to one or select more compounds, etc. glutenin by cooling the acute for the production of hydrogen-producing intestinal sugar, at this time it does not place particular limitations on the shape and size of the candy.

The ideal way to measure the beneficial gases to be added to produce in the intestine by the intestinal uptake of hydrogen generation candy is conventional breath hydrogen test; follows (breath hydrogen test BHT) method. Taps suck a sufficient amount required for analysis into a plastic syringe with the amount of test subjects with every breath by the nose, fine prongs (nasal prong) system within 12 hours after ingestion. Analysis of the hydrogen gas contained in the wash gave ssaempeul is performed by gas chromatography for the semiconductor (gas chromatography). In BHT normal adult will be this breath hydrogen levels 6 ~ 14 ppm, and the increased amount of hydrogen gas to the intestinal hydrogen-producing candy when the intake is combined with the hydrogen stored in the inner container 2 ~ 10 ppm, preferably at least 2 ppm adjusts the hydrogen gas in the components of the message bogwanryang acute or container.

Example 6,

In the gas storage vessel (2) for oral together with drinking water in order to ensure that dissolved after a period of time in human intestine, into the lower portion 3 of the conventional hard capsules in a nitrogen gas atmosphere, covered with a top (4) of the rigid capsule the next bonding process the bond portion 5 of the hard capsule bottom 3 and the top of hard capsules (4) overlap the ends of the production of a hydrogen storage container (1).

Hard capsules 16 is air-tightness and moisture resistance and the area of ​​adhering the upper and lower portions of the capsule overlap in order to increase the tensile strength of the ttareuna how conventional manufacture than conventional hard capsules for pharmaceutical means for receiving granular or powder Air position is the larger as much as possible and the bonding portion, as shown in FIG. 1 and to the center of the rigid capsule 16 in order to protect against external impact, as shown in Fig.

Hard capsule is a water-soluble cellulose derivative, and a gelling agent such as a material, or, or a polyethylene glycol (PEG), glycerin or the like gelatin (Gelatin) as the material, can be also added in nanoeun coating, to 37 oC high viscosity at high temperatures the dissolved test in a warm purified water and select that which can be dissolved within 15 minutes.

A rigid gapsel once to such, but also after directly wrapping the flexible film substrate storage containers, preventing damage caused by carelessness in transportation, and further dissolved after a predetermined time in the human gut by introduced for oral with a gas storage container with the drinking water good to better packaging. So hydrogen if hydrogen gas is adhesion treated the bonding portion of the filled soft coating gas into the storage container covered with the upper portion of the hard capsules, and then the hard capsule bottom and the hard capsule in the upper overlapping section of the lower portion of the conventional hard capsules in a nitrogen gas atmosphere. and it ends the production of containers.

In selecting a packaging method of a hydrogen storage container (1), in view of the safety from the long-term storage and fire in the pocket-type pharmaceutical packaging structures developed in the prior art, around the aluminum layer nylon layer and a high density polyethylene (HDPE), Terre put terephthalate (PET) or polyvinyl chloride (PVC) of after the laminated up and down, and heat punching one forming at spherical dome portion molded upper film, the hydrogen in the dome storage container (1), an aluminum foil layer (Press through pack foil) to close to the lower film and, selected from those which can be sealed by fusing the vinyl resin, polyurethane resin, or thermosetting adhesive resin column, blocking effect for the penetration of such external humid air, sunshine in order to increase the may be used to add a drying air layer between the aluminum layer of the upper film and the HDPE.

In order the packaging structure of the hydrogen storage container to the long-term storage to the transport is small and the aluminum pack, and an insulated using aluminum crimp seal type pack is more preferred.

Figure 8 is directed towards showing an illustrative diagram of a fire protection water jacket in accordance with an embodiment of the invention, the upper figure is a plan view of the water jacket, the lower figure is a side view of a water jacket.

Of a material of one or more compounds, etc. for the secure storage and transportation of the candy packaging and packaging this product to keep the hydrogen gas, polypropylene, low density polyethylene, high density polyethylene, which can melt at least 120 ℃ environment as shown in FIG. 8 to make the basic unit of cushion-shaped unit with water jacket (1). To hold water or antifreeze refractory and inside, so that the convex portion of the water jacket (2) and concave portions 3 are alternately arranged to be folded in accordance with the standard. Unit water jacket (1) a long side of one end to a plastic hook arm 4 and the other end of the metal in the end by placing a male hook (5), designed to be connected to each other.

Using two sheets of the water jacket is closed in the horizontal longitudinal direction when the actual packing container the hydrogen-producing candy. One that is wrapped back and forth, while the other is closed from side to side. So in a conventional manner and then closed by the water jacket is when packing it in the box.

That is, it in storage to transport the box to wrap an entire six surfaces of the product packaging is another cross to the water jacket, fire protection, fire extinguishing, to take the cooling function at high temperatures, the unit water jacket in accordance with the specifications of the shipping box by both sides will be able to use the hook to connect multiple sheets.

Example 7

If and store the gas to be in contact with water, the dissolution is made of a material that is a gas leakage of the cylindrical capsule type vessel gas storage container in addition to hydrogen and filled with carbon monoxide, nitrous oxide, xenon, helium, and the like supplied to the human body different It can bring a medical effect.

There are pharmaceutical gas molecules to provide a solution of medicine, in addition to the traditional well-known medical gas molecules of oxygen (O 2) and nitrous oxide (N 2 O), with the development of medical technology, carbon monoxide (CO), nitrogen monoxide (NO), which contains the report of the medical profession have been announced recently a lot about the role of xenon (Xe) and helium (He).

To summarize the effects on the human body of molecular gas, hydrogen gas (Hydrogen) is the most widespread the antioxidant to protect the tissue by preventing the cell damage caused by oxidation in the body of the mammal and healing, including humans, as previously described it is reported that a number of effects on removal of the - to, in particular, hydroxyl radical (OH *) and peroxy nitrite (ONOO) for the strong active oxygen generated in the body parts.

A carbon monoxide (Carbon monoxide) is in a high concentration in the toxic gas by reducing the oxygen-carrying capacity of the blood lead to hypoxia in cells but low concentrations (ppm units) in hypoxia (ischemia), such as ischemia reperfusion disorders by its antioxidant role preventing the oxidative damage of by cells, and superoxide radical generated by the mitochondria for synthesis of energy in the body (O 2 -) can be the removal of, and is reported to be a synergistic effect in combination therapy with a hydrogen gas .

Nitric oxide (Nitric oxide), but the effect of increasing the blood supply in the blood vessel as a signaling molecule in the case of a low concentration vivo and protects the tissues from oxidative damage to the cells, high concentration of the peroxy nitrite one active oxygen because it is counterproductive to increase (Peroxynitrite) it reported that calls attention to the maintenance of balance.

Xe (Xenon) and helium (Helium) have been reported that it is effective to protect against oxidation of the cells helping the activity of the low concentration signal when the body as a rare gas in the inert prevent ischemia-reperfusion disorders of heart muscle.

Those gas molecules may each offer to the human body by taking, sealing the gas storage container. Gas storage container and the filling method and container manufacturing method and the like can be applied to the already described as described above to seal the hydrogen gas.

Claims (19)

  1. And the storage of gas in contact with water, dissolved gas, is characterized by the form of a cylindrical capsule made from a material that is gas leakage storage container.
  2. The method according to claim 1,
    The material of the container, a soft candy, amorphous hard candy, sugar-free sugar is used as the material of the hard candy, maltose, and saccharides such as syrup, starch, maltitol, mannitol, sorbitol, iso malteu carbohydrate syrup mixture of xylitol with polyol (Polyols) mixture, composition, etc., or a mixture of one or more messages of the cute,
    The material of the vessel is gelatin, glycerin, Iron (Ferrous fumarate), vitamin C, vitamin E, polyphenols (Polyphenol), carotene (Carotene), which is characterized by the addition of calcium, one or more additives selected, etc. gas storage vessel .
  3. The method according to claim 1,
    The cylindrical capsule form outside the outer vessel is larger than the in the installation of thin ttukke hard capsules in duplicate characterized in that the stored hydrogen gas storage container.
  4. A packaging method of sealing a hydrogen therein in a small vessel,
    Column using a soluble material, a temporary container molding method comprising: forming a temporary container surrounding the hydrogen filling nozzle with space size of a volume of hydrogen is charged,
    After mounting the heat shrink band to areas other than the length of the filling space as hydrogen and taken out through a hydrogen filling nozzle the air in the inner space of the temporary container, filling the hydrogen to less than atmospheric pressure, and
    Heat shrink band and the end of retraction, hydrogen sealing comprises sealing the temporary container inlet was added to the column by tightening the band in the heat shrink band to a hydrogen filling nozzle.
  5. The method according to claim 4,
    In the temporary container-molding step, the container material, sugar, maltose, and saccharides such as syrup, starch, maltitol, mannitol, sorbitol, iso malteu, the mixture of carbohydrate syrup mixture and the polyol (Polyols), such as xylitol, at least one, etc. select and
    By the addition of gelatin, glycerin, Iron (Ferrous fumarate), vitamin C, vitamin E, polyphenols (Polyphenol), carotene (Carotene), calcium, one or more additives selected, etc. as an option to create a maese acute, put it into the flask forming it is characterized by a hydrogen seal method.
  6. The method according to claim 4, in the temporary container-molding step,
    The material of the container in a well the confidentiality of at least air, low heat applying heat well thermal deformation at the time to be squeezed, and the glass transition temperature is selected that the moisture content is greater than at least 3% 38 o C,
    The purity of the hydrogen gas to be filled in the container is at least 99.999% hydrogen is characterized by the sealing method
  7. The method according to claim 1,
    Capsule form of the cylindrical vessel is in that the composition of the soft coating, but has melted water-insoluble organic solvent, characterized in vessel gas storage container.
  8. The system according to claim 7,
    Material forming the flexible film is common gelatin, succinate gelatin, glycerol, starch, sorbitol, sorbitan as a plasticizer or softening agent, or a sol-byte sequence, polyglycidyl toll syrup, a sucrose agarose, mannitol, xylitol, maltose, reduced maltose syrup, maltitol, polyethylene and the composition of one or a mixture of two or more selected from glycol, purified water, is characterized by selecting one or more etc. black iron oxide, red iron oxide used as a base film of the gas storage container.
  9. The system according to claim 7,
    Within the vessel is a hydrogen gas is 70-97 volume%, and soybean oil, safflower oil, refined fish oil, the purification is shared, sesame oil, red pepper seed oil, wheat germ oil, grape seed oil, olive oil, rapeseed oil, evening primrose oil, fruit flavor oil, selected from in that one or more components is 3 to 30% by volume characterized in gas storage container.
  10. The system according to claim 7,
    Wherein the gas is hydrogen, the container is that the film thickness of the molding in consideration of the change in pressure, cooled in a dry atmospheric pressure is 0.7 ~ 1.0mm, thickness of the joint is 0.6 ~ 0.95mm and the thickness of the restored nozzle insertion hole is 0.7 ~ 1.0mm characterized by a gas storage vessel.
  11. A method for filling and sealing the hydrogen gas in the gas storage vessel as a soft coating,
    The steps for creating a soft coating into a temporary container seal to maintain the inside of the flexible film,
    By inserting a hydrogen filling nozzle in the temporary container to take-in the temporary holding container, and injecting the hydrogen gas,
    Subtracting out the hydrogen filling nozzle out of the container, the hydrogen gas filling method for a nozzle insertion hole bored in the temporary container by a hydrogen filling nozzle comprising the step of sealing a grouting material.
  12. The method according to claim 11,
    Will the hydrogen filling nozzle is pointed like a needle,
    It is characterized by a method of filling hydrogen gas to maintain when drawing out the held in the temporary container, leaving a 3 to 30%
  13. Mixed with sugar by the intestinal flora to be 30% to 70% against the material to generate hydrogen gas in the large intestine to candy to create hydrogen-producing candy.
  14. And sugar container made by mixing sugar (30 to 70) :( 70 to 30): material to generate hydrogen gas in the colon by the intestinal bacteria group
    Candy hydrogen generation candy characterized by charging hydrogen to the inside of the container.
  15. The method according to claim 13 or 14,
    Material for generating the hydrogen gas,
    Lactose, trehalose, raffinose, stachyose, coarse member bath, the hydrogen-producing sugar characterized by selecting using the curcumin, capsaicin, inulin, jinjeorol, allicin, etc. One or more subqueries, glutenin to raktyul.
  16. A method for producing a hydrogen-producing candy,
    Steps to Create teueul sheet segyu to the mixture as a raw material;
    Step lactose, and trehalose in raktyul, raffinose, stachyose, select the server bath coarse, curcumin, capsaicin, inulin, jinjeorol, allicin, subquery, glutenin, one or more, etc., which add to the sheet segyu agent;
    The method of hydrogen-producing candy containing sugar molding step for molding or injection every segyu agent.
  17. The method according to claim 16,
    The method of hydrogen-producing candy for molding the candy container to store the gas in the candy forming step, a step of filling hydrogen gas into the candy and the container sealed.
  18. The method according to claim 1,
    Capsule form of the cylindrical vessel is selected from one of the medical gas, hydrogen gas, carbon monoxide, nitrous oxide, xenon, helium, store characterized in that the gas storage container.
  19. In order to pack the hydrogen storage container or the hydrogen-producing candy carry or store safely, it is one made with water or containing polyethylene water refractory antifreeze jacket melt when more than 120 ° C to emit water or the refractory antifreeze characteristics hydrogen packaging materials produced candy containers.
PCT/KR2011/002536 2010-04-15 2011-04-11 Gas storage vessel, hydrogen-charging method, and hydrogen-charging apparatus WO2011129567A4 (en)

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KR20100127087A KR101311697B1 (en) 2010-12-13 2010-12-13 Candy capsule for hydrogen production
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