WO2011100885A1 - Method for obtaining renewable energy sources from waste heat - Google Patents
Method for obtaining renewable energy sources from waste heat Download PDFInfo
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- WO2011100885A1 WO2011100885A1 PCT/CN2011/000260 CN2011000260W WO2011100885A1 WO 2011100885 A1 WO2011100885 A1 WO 2011100885A1 CN 2011000260 W CN2011000260 W CN 2011000260W WO 2011100885 A1 WO2011100885 A1 WO 2011100885A1
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- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F01—MACHINES OR ENGINES IN GENERAL; ENGINE PLANTS IN GENERAL; STEAM ENGINES
- F01K—STEAM ENGINE PLANTS; STEAM ACCUMULATORS; ENGINE PLANTS NOT OTHERWISE PROVIDED FOR; ENGINES USING SPECIAL WORKING FLUIDS OR CYCLES
- F01K27/00—Plants for converting heat or fluid energy into mechanical energy, not otherwise provided for
Definitions
- the invention relates to renewable energy sources. Background technique
- Heating is the main source of energy for humans. "China's energy structure accounts for 90%, and other developed countries account for 85%. Therefore, in a sense, the development and utilization of energy is largely the development and utilization of thermal energy.” [Note 3] Enriched and heated [Note 4], it can become a future star of renewable energy. This is because the "biofuels” that were originally hotly debated have been suspended from planting by the United Nations, Africa, the United Kingdom, and the United States because of the suspicion of "competing food with the people.” Nuclear energy that many countries yearn for also loses their appeal because of safety, nuclear waste, and the inversion of input and output [Note 5]. In contrast, the heat that gets a few electricity is a multiple of the direct electric heating equivalent.
- waste heat such as air and surface water (river, lake, sea and sea). It is particularly pointed out that this waste heat is not the waste heat of power plants and steel plants. Use, but environmental waste heat without temperature difference with the surrounding environment. "Getting heat from the sputum” is rooted in the circulation of heat demand. It not only has no gas pollution, but also absorbs hot dirt. It is an energy model that is comparable in function to plants and absorbs the heat of the earth. It has neither exhausted nor The waste of commission, the economic feasibility of investing in the year, should be the fundamental long-term solution for human thermal demand.
- Kano's hypothetical working fluid is an ideal gas with no force between the molecules.
- the heating effect of the heat pump is precisely due to the gravitational existence between the working medium molecules.
- the gravitational force acts between the molecules. Condensed into droplets, the degree of freedom changes and the phase change is exothermic, which gives us a "regeneration heat".
- the result is better than the "ideal" inverse Carnot cycle (see a'dcba' cycle ratio inverse in Figure 1).
- Card Connaught cycle adcba saves the area of aba'-block work, the real gas is used as the evaporation process of the refrigerant, the heat absorbed by the isothermal expansion of the Carnot cycle is much higher (poor heat of vaporization), because there are Gravity, the phase change heat release during liquefaction, and the more Joule heat obtained by the simple compression of the ideal gas, let us see that the effect of the real gas exceeds the result of the "ideal" gas. This result has great theoretical significance.
- the phenomenon of ignoring innocence and the negative temperature phenomenon, Xu Yelin's experiment [Note 16] are the same source, as detailed in the first section.
- the Kano theory born in the thermal theory has four defects, and repositioning is inevitable.
- the entropy increase law is based on the distribution of "power” and "maximum disorder” as the state law of the robbery. There is no objection to its wide application.
- the state laws that exist at the same time are not limited to the principle of minimum potential energy, the velocity distribution is dominated by the bell-shaped curve, and the energy distribution is divided into the bottom of the law.
- the atomic structure of all matter is 2n 2 rule. ... These are the laws of the state.
- the first argument is a premise error
- the second argument is that the logic error of Carnot's law is indeed wrong: the ideal heat engine not only requires the ideal to operate (reversible, frictionless assumptions guarantee the ideal of operation) but also the pattern ideal, the Carnot cycle
- isothermal compression is used to make the working fluid return to the origin only on the surface.
- the assumption of "infinite” cold source masks the consequences of entropy increase. "The outside world” does not.
- the Carnot engine is not the most efficient and ideal heat engine. Only by removing the entropy increase process of "isothermal compression" in the cycle and replacing it with the entropy reduction process, can the real ideal heat engine be obtained.
- the ideal heat engine for three-dimensional circulation will have higher efficiency, which is what Kano said. "The height is high, there is no middle school.” [Note 18] The height.
- if there is a heat engine that exceeds the Carnot efficiency formula and the refrigerator there will be a phenomenon that violates the 'Kai’s expression' - a single heat source. In other words, it is possible to obtain "regeneration work" from the waste heat such as the air called Fu from the result of "joining".
- thermoelectric engine that dominates the industrial revolution is only one of the "heat power conversion".
- heat quality theory is abolished, it is because the idea of "heat mass falling” must have a temperature difference to work hard [Note 19], and it is still stored in "temperature difference thermodynamics", and its selling quality is heated by heating to obtain expansion.
- the limitation of the cylinder the expansion proceeds in one direction and is ordered, and the work is obtained by intercepting the piston.
- a traditional thermoelectric heat engine it can also be explained by the above-mentioned "interception”.
- Kelvin's expression is not the same as other expressions and can be cut and separated.
- Vs V should be a negative entropy process, although This process is obtained with the help of external work compression, but the energy required for work compression is released at the hot end with a lot of Joule heat. It is not because of the energy loss caused by the "negative entropy flow" that brings negative entropy.
- the real gas is mainly caused by the attraction of gas molecules to a certain distance.
- Kelvin's expression is not the same as other expressions, can be cut, separated
- thermodynamics The second law of thermodynamics is developed as a study of the law of heat transfer. When people study this law, they understand the irreversible property of the development of things. It should be said that Krebs expression is an irreversible expression of heat conduction, only in the process of irreversibility. One, but it was quickly proved to be in communication with Kelvin. This section will explain the meaning of the same but it is not the same meaning, as Yan Jici said: "The thermodynamics like this refers to the science of studying all changes, the name of thermodynamics has been too narrow" [Note 22]
- Kelvin expressing the law of thermal power conversion is the law within the true sense of thermodynamics: it contains the "single heat source can not work”, “the second type of perpetual motion impossible” and the efficiency formula It is the expression of the same intercommunication. Due to the challenge of experimental facts, its correctness needs to be studied again. The most controversial topic in history, it should be time to freeze, it is irreversible with a single process, including the single heat conduction process. Irreversible, can be cut and separated. They do not affect each other's new positioning.
- Figure 6 The left picture is a logical diagram of the textbook view. A is irreversible, B is entropy law, C is Kelvin, D is Kelvin, and Figure 6 shows A is the same relationship with B, C, and D. .
- Figure 6 The right picture shows our point of view: B belongs to A, B.
- the two irreversible processes of E and C are the heat of heat and the heat of heat C, both of which are entropy increases in the irreversible process, and "irreversible"
- the law of the universe is a subordinate relationship. It is a mistake to confuse the irreversible and entropy law, the Kline expression, and the Kelvin expression because it rejects the same irreversible, but it is another negative entropy process X.
- Entropy increase and entropy reduction are two ways to describe "more chaotic” or “more orderly” in the case of neither zero nor maximal. Dynamic description. Entropy, entropy, and entropy are all conditional and each is born by power. It is an irresistible irreversible process.
- Kelvin is the initiator of the "Kai's expression”. He still carefully puts the expression outside of "life” in the "thermal dynamic theory”. He said, “It is impossible to use the role of inanimate matter to cool any part of the material below the temperature of the coldest object around it to produce a mechanical effect," which is later called a single heat source. Kale’s statement. We believe that Kelvin defines the scope of expression as "inanimate” material. Although the style of study is prudent, it should not be bounded by life. Life is an orderly miracle. It stores the absorbed heat and light energy in the structure, and even Schrödinger profoundly says that "life is negative entropy.” The petrochemical resources that we used today are still the solar energy storage of the year.
- the non-opening process can, should, and does exist.
- the composition of the heat quality theory has two parts.
- the heat quality was said to be abolished only by the fact that "the heat quality is not indestructible". Another important idea is that the "temperature difference can only work” has been preserved until now. The amount is determined by the “quality” in the temperature difference.
- the word “quantity” is changed to "quantity”. "No cold, heat will be useless", the metaphor of waterfalls and turbines all reflect the idea of temperature difference, which is "we are orderly.”
- the understanding of the nature of the interception is completely different. "The temperature difference can be done” is no mistake, but it is a mistake to regard it as the only one.
- the Carnot mode can be a mode in the conversion of thermal power, but it is a mistake to regard it as the best. The two errors stem from the error. The understanding of the essence is wrong, and the logic is wrong. Let's open the dusty History, take a look at the shortcomings of Kano's theory.
- Heat is a particle flow that does not produce weight in any process and does not disappear. "The degree of heat and cold of an object determines how much it contains heat.”
- the work of the heat engine is the process of entropy reduction of a system, that is, a part of the system becomes disordered, and its essence is completely different from the waterfall.
- the metaphorical heat engine has the same waterfall 100
- Carnot heat engine is to change the volume of work, both in the case of the thermal expansion of the working medium to get "work", there is a problem of working fluid expansion.
- the cd process of the Carnot cycle (Fig. 7) aims to solve the problem of expansion of the process.
- Using the process of external work and isothermal compression to solve the problem it has indeed received the result of volume from c to d, but external work, cold source heat is a work heat, orderly change disorder entropy increase process, and The purpose of getting the negative entropy as much as possible for the heat engine is flawed.
- the so-called ideal heat engine is not a process without friction. It is also necessary to consider whether the Carnot heat engine is the most ideal heat engine from the model of the process. It is the cd process seen from its design scheme. This birthmark is described later. A three-dimensional loop without a cd positive entropy process is more efficient than it.
- the maximum number of electrons possible for each shell calculated by the Pauli exclusion principle is 2n 2 , and for each layer of K, L, M, N ⁇ 8, 18, 32 ⁇ E-electronics.
- the configuration of an inert element having an outer layer of 8 electrons is a ruin.
- the electron is at a higher energy level, it always waits for an opportunity to return to its steady state, 2n 2 , and the Eight Laws...
- thermodynamics Mg / 4 ⁇ r 2 KT
- n. Mg / 4 ⁇ r 2 KT
- Other thermodynamic functions can be derived from these three basic functions.
- the role of the force field is not considered in the equation of state.
- This P should be in the equation of state P is equal to n.
- KT Mg / 4 Ji r 2 , ie ⁇ .
- the P / KT equation of state is more comprehensive, that is, ⁇ . It is determined by four factors, among which M, g, and r are the same, so ⁇ . It is only inversely proportional to T. T large n Q becomes smaller, is expansion, T is small n. It is big, it is shrinking, this is everyone knows. But let's assume that M and g can also change, then n when g or M becomes larger. It also becomes larger, and instead n Q becomes smaller. That is to say n. Smaller expansion can also be determined by two other factors beside T, which gives us a more delusion.
- the second revelation is the free expansion that was originally exemplified as the entropy increase phenomenon, but a special case when g is zero, (g ⁇ 0, n() ⁇ 0), that is, in the presence of the Earth's gravitational field.
- g zero
- n n()
- the combination of the minimum energy principle and the entropy increase leads to the establishment of the law of the gas equation.
- Entropy increase is not an unconditional behavior.
- Entropy increase, entropy decrease, and entropy maximization have certain conditions.
- the reason for the above phenomenon is the state law of the minimum energy principle, which requires the particles to move as far as possible to the minimum potential energy.
- the law from the composition of the atom to the state of the atmosphere obeys this law. Under normal conditions, the electrons tend to be exhausted. May have the lowest energy level. The filling of the electron shell begins with the lowest energy level of the shell and then proceeds to the higher energy level. If for some reason it transitions to a high energy level, it will emit a corresponding electromagnetic wave and return to the low energy level.
- the atmosphere must follow the entropy increase law of expansion, diffusion, and maximum disorder, and follow the principle of minimum energy that shrinks, gathers, and returns to the minimum potential.
- the state of the atmosphere is the result of the combination of the two.
- abed and ab ' e ' d ' are two A-states and B-states with equal areas. That is to say, the two states of B and B contain the same amount of heat.
- the temperatures are TV and ⁇ 2 respectively.
- From the ⁇ state to the ⁇ state is the positive entropy process (8, to S 2 ).
- the change from the A state to the B state is a negative entropy process, the entropy becomes S 2 , and the temperature can rise from ⁇ to T 2 , S.
- S 2 is an entropy reduction process that is not allowed by the thermal law, but it occurs under the condition that the degree of freedom changes.
- H the kinetic energy of particles in an object, which is determined by temperature.
- the internal work J is a state function determined by the structure of the molecule.
- U the physical quantity of the internal work J
- the C atom constitutes a new molecular structure.
- the heat absorbed or released is what people call chemical energy. Combustion is only one form.
- phase transitions Crystallization, melting, liquefaction, and gasification at the molecular level are called phase transitions, and they also release or absorb heat because of structural changes.
- the above four items reveal the relationship between structure and energy.
- the classical theory only studies the limited part of the structural exothermic (combustion) conversion into work in C.
- the heat pump originally explained by the "reverse Kano cycle” is simply a low-order energy conversion that absorbs or releases heat from the phase change.
- Ordering can be that the particles have the same direction of motion or a stable structure, both of which have an entropy of zero. Disorder is the loss of thermal motion in the same direction.
- dQ 0, in an isolated system, the transition between dH, dJ, and dW summarizes the nature of all energy conversions. Since the stable structural entropy is zero, the stable structure becomes a process of negative entropy. This process often brings us a lot of heat (release), which is what we often call "energy”. The intensity is nuclear and atom. , structural changes in the molecule. If negative entropy occurs, it is expressed as absorbing heat and hiding it in the "higher energy level" of the structure. Only negative temperature phenomena and photosynthesis of plants exist in life phenomena.
- the higher the internal energy the more the number of possible microscopic states of the system, that is, the entropy increases monotonously with the internal energy, so the temperature is constant.
- the entropy decreases, which causes the temperature to push out the negative sign.
- the system is called in the "negative temperature" state. The reason we think this is the first law mentioned in 3.4.
- the medium energy form does not contain dJ, that is, the basic equation does not reflect the force. Reflecting the fact that the force field and potential energy are related. The increase in internal energy in the negative temperature phenomenon is obtained by the increase of the force field, and the enhanced potential energy of the particles in the force field. If dJ is added to the basic equation, it can objectively and truthfully reflect the change of things. It is not dH but dJ that is recognized to increase, and entropy decreases when dJ increases. Thus, when the force field is reversed, the dJ reflecting the potential energy should be expressed by a symbol, so that T is not necessarily negative. Let the truth not be awkward, is it better?
- the negative temperature is considered to be infinite after the force field is reversed.
- the force field reversal time is very short, because the power is inversely proportional to time, the shorter the time, the higher the power, any heating method.
- the force field allows each particle to receive commands, each going to a higher structural high (ie, the so-called energy level is limited), and then immediately reversed, Each particle has to be "migrated" for the second time.
- the action is highly consistent. Because there is no effective interception, the force field can only be driven in the form of heat to the dj after it is high, and the dw after it is reversed and accelerated. The dH it originally had all heat up in an instant (in a sense, it can be called an explosion), which gives a very high temperature.
- the Maxwell rate distribution curve (Fig. 11) expresses that the molecular velocity distribution is always a bell curve, that is, the ratio of the middle in the most probable state is the largest, and the left and right legs of the curve respectively indicate the ratio of the low rate and the high rate. If the high-speed molecules at the right foot are greatly reduced due to evaporation, the entire curve will shift to the left due to cooling, but it is valuable that the McGregor curve is still the target of the new distribution, even if it falls to ⁇ 2 The right foot still extends to the vertical line shadow, that is to say, there are high-speed molecules.
- Negative entropy needs to be born in the case of negative entropy flow. This has two more points: a When the absolute value of the negative entropy flow is greater than the entropy generation, the negative entropy is obtained - this is the theory of cost. This is obtained by the negative entropy flow to generate the de-entropy. b The negative entropy brought by the negative entropy flow exceeds the entropy to produce pure negative entropy. This is the theme of the third part of the "entropy can be positive and negative”. Root According to the concept of b, a three-dimensional cycle is designed (Fig. 12).
- the 1 cycle starts from a point a on the isotherm, and the heat absorbed by the working medium heats up along the ab line to reach the point b which is in equilibrium with the external atmospheric pressure, and the external work of the heat engine is abf) '.
- thermal power conversion is that when molecular motion appears to be consistent, timely interception of this order becomes mechanical work. It is a process in which disorder is directed to order and intercepted in an orderly manner. Order is the primary condition, and interception is a necessary process. The wind is an orderly movement of the air. If there is no windmill to intercept, it will return to disorder quickly. If the river is undoubtedly orderly to the sea but there is no turbine, it will not be able to generate electricity. It is the eddy current in the transformer, and it is also because there is no interception and waste. Using this point of view to look at the Carnot heat engine, first of all, the heat engine is based on the temperature difference to give birth orderly.
- the cylinder is used to limit the expansion in other directions. Only the direction of the piston can be expanded and ordered. The piston receives the impact of the working medium molecules to intercept the order.
- the degree of turbulence is the entropy.
- the essence of thermal power conversion is chaotic. The only change is the direction of particle motion. Only when this is consistently transmitted is intercepted and turned into mechanical work, it will cool down. Because the disorder is changed to order, the entropy value must be reduced. But where the heat comes from, there is no requirement, which makes it possible to use waste heat as a source.
- ⁇ ⁇ is the conclusion of the orphan system, where the equal sign refers to "the end of the whole process" - that is, the non-single process with the existence of negative entropy flow.
- the other single process is the less than sign, and since then its potential contradiction with the first law no longer exists.
- the negative entropy flow only acts as a "catalyst". At the end of the process, it has no loss and plays a role. The only role is to promote the conversion of heat to work. This is also the order in nature that can become a negative entropy flow. Coupling" and constantly creating new and orderly reasons.
- the invention provides a method, which can make waste heat which has been played as air, surface water (river, river and sea), ground source heat, etc. into renewable energy, and is characterized by: 1. Waste heat from air and the like as a heat source, working medium Absorbing the waste heat and expanding in a vacuum; 2. The instruction to change the charge on the working medium to obey the electric field will turn the disorder into order; 3. Inductive current is obtained in the secondary by electromagnetic induction.
- the barrel of the drawing is to be explained
- FIG. 5 The loops in nature are formed by the irreversible process.
- the abc process cannot be returned by cba, but must be the irreversible process of another power.
- Figure 6 shows that since the theory of "dissipative structure" is established, there can be a negative entropy process X, where A is the irreversible law B is the entropy increase rate, C is the Kelvin expression D is the motion order F is the structure order.
- Figure 7 is a schematic diagram of the Carnot cycle.
- Figure 8 shows the isotherm family ⁇ and the atmospheric pressure intersection 00 ' 0" and the corresponding volume.
- Figure 9 is a negative entropy diagram. The heat contained in ⁇ and ⁇ is equal, but the temperature is different. A to B is a negative entropy process, and B is a positive entropy process.
- Figure 10 shows that the important reason for the birth of negative temperature is force field reversal.
- Figure 11 shows Maxwell's bell curve. Although the temperature is lowered to T 2 but in the shadow of high-speed molecules, the "foot" of ⁇ 2 still extends, which means that high-speed molecules are still born.
- FIG. 12 Schematic diagram of three-digit cycle
- Figure 15 is a diagram of the present invention.
- the ab and be processes are isothermal expansion and adiabatic expansion.
- the cd process is a negative entropy process, which is born under the change of the force field, and the de process returns to the origin.
- FIG. 16 Schematic diagram of the orderly energy brought by the three-dimensional cycle
- FIG. 17 Schematic diagram of thermal energy brought by three-dimensional cycle.
- Experimental diagram B The best way to achieve the present invention.
- Figure 16 B 1 is a copper tube with fins.
- the copper tube is in the middle of the refrigerant, the copper tube is heated by the fins, and 2 is the refrigerant charging chamber where the charge is supplied by 2.1, expanded by 3, and condensed into 4 Liquid,
- Figure 6 is the power supply to accelerate the condensation and let the inflation gas be charged to become the primary current when passing through 3, and the electromagnetic induction causes the output current at AB.
- Figure 17 B is slightly different, 4.1 has a liquid that accepts heat, and is accepted by the refrigerant. The heat. Industrial applicability
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Abstract
A method for obtaining renewable energy sources from waste heat. The method involves using air or waste heat as a heat source, and using working medium to absorb the waste heat and expand in vacuum. The working medium is condensed to liquid. The expanding gas is charged by a supply power (6) so as to create a primary current. An inductive current is created in a secondary coil through electromagnetic induction. The method can produce renewable energy sources from air, surface water and so on.
Description
一种从废热中获取可再生能源的方法 技术领域 Method for obtaining renewable energy from waste heat
本发明涉及可再生能源。 背景技术 The invention relates to renewable energy sources. Background technique
在新能源的开发中, 常能听到太阳能、风能、生物质能 …… 却没有将 空气、 地表水(江河湖海)、 土壤中的环境热视作可再生能源, 这可在 "中华 人民共和国可再生能源法" 中不予列入得到佐证。 上一世纪中叶, 中国物理 学家严济慈曾提出利用环境热的设想【注 1】,只因当时石油价廉而未曾实现。 第一次石油危机后, 先进国家着手实施了 "严氏设想", 效果很好。 我们在某 校三年的试用中获得同样效果, 淋浴用的热水中有 2/3到 4/5 (夏) 的热量 来自空气, 热水成本降低 3- 4倍, 与太阳能相比, 尽管要用电但所费不多, 不受天气影响、又不受楼层影响,加热可日夜兼程, (夜电是发电厂鼓励使用 的谷电)规模又是太阳能无法企及的(即能流密度高于太阳能), 可以说它是 寄存在空气中的、 包括太阳能在内的各种逸散能【注 2】被集中收回, 虽然 说不上富矿, 但却有采不完的长处, 称 "可再生能源"完全够格。 In the development of new energy, solar energy, wind energy and biomass energy can often be heard... but the air, surface water (river, river and sea), and environmental heat in the soil are not regarded as renewable energy, which can be seen in the "Chinese people." The Republic’s Renewable Energy Law is not included in the evidence. In the middle of the last century, Chinese physicist Yan Jici once proposed the idea of using environmental heat [Note 1], but it was not realized because of the low price of oil at that time. After the first oil crisis, advanced countries began to implement the "Yan's vision", which is very effective. We achieved the same effect in a three-year trial in a school. Two to three to four (5) of the hot water for showers came from the air, and the cost of hot water was reduced by 3-4 times, compared with solar energy, although It takes less electricity, but it is not costly, it is not affected by the weather, and it is not affected by the floor. Heating can be done day and night. (Night power is the electricity that the power plant encourages to use.) The scale is not compatible with solar energy (that is, the energy density is high). In solar energy, it can be said that it is stored in the air, including solar energy, various kinds of fugitive energy [Note 2] is concentrated to recover, although it is not rich, but there are endless advantages, called "renewable energy "Exactly qualified.
人类的能源需求中供热是主要的。 "我国的能源结构中占 90% , 其他发 达国家占 85 % , 因此从某种意义上说, 能源的开发利用在很大程度上是对 热能的开发利用。"【注 3】把怃中热富集起来供热 【注 4】, 可以成为可再生 能源的未来明星。 这是因为, 原来热议的 "生物燃料" 因有 "与民争粮"之 嫌, 己被联合国、 非洲、 英国、 美国下令暂停种植。 许多国家向往的核能也 因为安全、 核废、 投入产出日趋倒置而失去吸引力【注 5】, 相比之下化一份 电却得到数份电的热, 是电直接发热当量的数倍, 其中除了一份电发的焦耳 热之外, 其他几份都来自被称为秌的空气、 地表水 (江河湖海) 等废热, 要 特别指出的是, 此废热不是电厂、 钢厂的余热利用, 而是与周围环境无温度 差的环境废热。 "妩中取热"是把热需求根植在循环中, 不但没有气污, 而且 吸收热污, 是功能可与植物媲美的、 吸收地球热的一种能源模式, 既无枯竭 之虞, 又无佣浪费, 更有投入可当年回收的经济可行性, 应该成为人类热能 需求的根本的长远出路。 为此我曾在中科院旗下的杂志 "高科技与产业化" 上撰文呼吁, 称该废热制热取代燃烧制热的办法是最科学、 最绿色、 最经济 的取热办法【注 6】。 如被政府解读, 采用 "以秌代煤"的方法获取热能, 那 该是何等巨大的节能减排措施? 我们假设全国原用于发热的电量是三峡所发 的电量, (其实远远不止) 那废热制热的效果就相当于又建了三个三峡水电 站。
今天我们要进一步阐明两个问题: 1、 上述再生热的获得, 出现了比"逆 卡诺循环"更好的效果, 吸引我们深入探讨它的机制, 以便回答. "再生热" 能不能提高温度和效率, 以期更为广泛的应用。 2、 要讨论是否能获取"再生 功", 如可能, 要回答如何获取的方法。 这 2个问题都涉及到经典理论。 鼓励 我们知难而上的因素除了上述两个议题有令人神往的经济效益之外, 还有 2 个前人留下的宝贵科研成果作支撑: 1、 1951 年哈佛大学珀塞耳和庞德在试 验中发现了负温度状态, 正如 "热力学分析"一书所说该实验 "对开氏表述 提出了新的质疑"【注 7】; 2、 上世纪获得诺贝尔奖的普利高津在耗散结构理 论中揭示了大量的负熵事实【注 8】动摇了开氏表述的理论支撑。 Heating is the main source of energy for humans. "China's energy structure accounts for 90%, and other developed countries account for 85%. Therefore, in a sense, the development and utilization of energy is largely the development and utilization of thermal energy." [Note 3] Enriched and heated [Note 4], it can become a future star of renewable energy. This is because the "biofuels" that were originally hotly debated have been suspended from planting by the United Nations, Africa, the United Kingdom, and the United States because of the suspicion of "competing food with the people." Nuclear energy that many countries yearn for also loses their appeal because of safety, nuclear waste, and the inversion of input and output [Note 5]. In contrast, the heat that gets a few electricity is a multiple of the direct electric heating equivalent. In addition to a part of the electric hair's Joule heat, the other parts are from waste heat such as air and surface water (river, lake, sea and sea). It is particularly pointed out that this waste heat is not the waste heat of power plants and steel plants. Use, but environmental waste heat without temperature difference with the surrounding environment. "Getting heat from the sputum" is rooted in the circulation of heat demand. It not only has no gas pollution, but also absorbs hot dirt. It is an energy model that is comparable in function to plants and absorbs the heat of the earth. It has neither exhausted nor The waste of commission, the economic feasibility of investing in the year, should be the fundamental long-term solution for human thermal demand. To this end, I once wrote in the magazine "High-tech and Industrialization" of the Chinese Academy of Sciences, saying that the waste heat heating method to replace combustion and heat is the most scientific, greenest and most economical way to take heat [Note 6]. If the government interprets it and uses the method of “reducing coal by using coal”, what kind of huge energy-saving and emission reduction measures should it be? We assume that the electricity used for heat in the country is the electricity generated by the Three Gorges. (In fact, it is far more than that.) The effect of waste heat and heat is equivalent to the construction of three Three Gorges hydropower stations. Today we have to clarify two issues: 1. The above-mentioned regenerative heat has a better effect than the "anti-Carnot cycle", which attracts us to explore its mechanism in order to answer. "Regeneration heat" can increase the temperature And efficiency, with a wider range of applications. 2. Discuss whether you can get "regeneration work" and, if possible, answer the method of how to get it. Both of these questions involve classical theory. In addition to the fascinating economic benefits of the above two issues, there are two valuable scientific research results supported by the predecessors: 1. 1951 Harvard University Perse and Pound In the test, a negative temperature state was found. As the book "Thermodynamic Analysis" said, the experiment "has raised new questions about the expression of Kay's" [Note 7]; 2. The Probel Prize in the last century won the Nobel Prize. The theory of negative structure reveals a large number of negative entropy facts [Note 8] shaken the theoretical support of Kelvin's expression.
鉴于热力学经典理论确立以来的 200年中, 人类的认识已有 2次革命性 进步, 首先, 人们抛弃了热质说、 构建了分子运动论和熵理论; 上一世纪中 叶又诞生了畑理论以及耗散结构理论, 理论的每一进步都如智慧的灯塔, 让 我们离真理的彼岸更进了一步。 应该感谢普利高津的坦率和科学精神, 这位 耗散结构理论的创始人称 "问题依然存在"并寄希望于东方文化【注 9】。 我 们认为, 理论的确还有缺憾: ①热质说的退出不够彻底, 经典中还有它的遗 存, ②耗散结构的负熵理论尚可再进一步。 只有在理论探索获得共识后, 才 能给 "从空气等废热中获得可再生能源"提供科学依据并藉此得到可行的方 法, 我们将仿照贝尼德蒂当年质疑亚里士多德的 "自由落体定律" 的办法从 经典理论的逻辑缺陷切入,以便在该课题的必要性和可能性上尽快取得共识。 In the 200 years since the establishment of the classical theory of thermodynamics, human understanding has made two revolutionary advances. First, people abandoned the thermal theory and constructed the theory of molecular motion and entropy. In the middle of the last century, the theory of 畑 was born. Dissipative structure theory, every advancement of theory is like a beacon of wisdom, let us take a step further from the other side of the truth. Thanks to Plygotsu's frankness and scientific spirit, the founder of the dissipative structure theory called "the problem still exists" and hopes for the Eastern culture [Note 9]. We believe that the theory does have some shortcomings: 1 The exit of the thermal theory is not thorough enough, and there are still its remains in the classics. The negative entropy theory of the dissipative structure can go a step further. Only after the theoretical exploration has gained consensus can we provide a scientific basis for "recovering renewable energy from waste heat such as air" and use this to obtain a feasible method. We will follow Benedetti's questioning of Aristotle's "free fall". The law of the law cuts in from the logical flaws of classical theory in order to reach a consensus as soon as possible on the necessity and possibility of the subject.
回顾历史, 我们知道卡诺在缔造经典时是热质说占统治地位的时候。 当 时社会要求回答热机的最高效率是多少。 卡诺用热质说和第一定律的雏形论 证【注 10】 了他的卡诺定律: "工作在二个热源之间的一切热机, 以可逆机 的效率为最高 "【注 11】他以此为大前提, 小前提是把二个等温二个绝热过 程的卡诺热机称为可逆机, 这样就得到了所有热机中效率最高的公式—— η Looking back at history, we know that Kano was the time when thermal theory dominated the creation of classics. At that time, the society asked for the highest efficiency of answering the heat engine. Carnot uses the thermal theory and the prototype law of the first law [Note 10] his Carnot law: "All heat engines working between two heat sources, with the highest efficiency of the reversible machine" [11] This is a major premise. The small premise is that the two Isothermal two adiabatic processes are called reversible machines, which gives the most efficient formula for all heat engines - η
1 一 T 2/ T i式子告诉我们当 T i = T 2时 ΐ! =0, 即 "没有温差就不可能作 功" 的结论一一①没多久因焦耳等人的实验结束了热质说的统治, 卡诺定律 因前提缺失而产生生存困难, 由于上述推理是演绎推理, 作为大前提的卡诺 定律如果失效, 结论必然无法生存, 即效率公式适用所有热机的结论要退到 原范围(即只适用卡诺模式)。如果当时对危机作深入思考也许是一个极好的 纠错机会。但开尔文为挽救卡诺定律, 直接确认"单一热源无法作功" —— ② 这一命题【注 12】 因为不引用前提, 不加论证, 正如教科书所说属 "公 理"之列。 1 A T 2 / T i formula tells us that when T i = T 2 ΐ! =0, that is, "no work can be done without temperature difference" conclusion 1 1 soon after the experiment of Joule et al. ended the thermal mass The rule of saying, Carnot's law is difficult to survive due to the lack of premise, because the above reasoning is deductive reasoning, if Carnot's law as a major premise fails, the conclusion will inevitably survive, that is, the conclusion that the efficiency formula applies to all heat engines should be reverted to the original scope. (ie only the Carnot mode). If you think deeply about the crisis at the time, it might be an excellent opportunity for error correction. However, in order to save Carnot's law, Kelvin directly confirmed that "a single heat source can't work" - 2 this proposition [Note 12] because it does not quote the premise, without argumentation, as the textbook says is "axiom".
很明显, ②和①是同一意思, 所不同的地方仅是适用范围不同。 结论① 来源于个别案例的规律, 即仅仅是二个等温、 二个绝热这一模式推导而得的 公式【注 13】, 要上升为所有热机的最高效率, 必须由卡诺定律作前提, 方
能将特殊案例推向普遍适用,否则会犯以点定面的逻辑错误,正是这个原因, 卡诺才先用热质说和第一定律论证了他的卡诺定律, 可惜热质说被废, 卡诺 定律本身失去前提, 遂有开尔文直接确立开氏表述的挽救之举, 以他的威望 当时未有异议。 Obviously, 2 and 1 have the same meaning, and the difference is only the scope of application. Conclusion 1 It is derived from the law of individual cases, that is, the formula derived from the two isothermal and two adiabatic modes [Note 13]. To rise to the highest efficiency of all heat engines, it must be premised by Carnot's law. It is possible to push a special case to universal application, otherwise it will make a logical mistake in the point setting. It is for this reason that Carnot first demonstrated his Carnot law with the thermal theory and the first law, but the heat quality was said to be Abolished, Carnot's law itself lost its premise, and there was a Kelvin's direct decision to save the expression of Kelvin, and his prestige was not objectionable at the time.
把显而易见的规律确定为公理, 在科学史上并不少见。 但开尔文直接将 内容与卡诺热机的结论①相同, 仅是适用范围不同的②, 直接确定为 "开氏 表述", 就是跳过必要前提(卡诺定律)随便扩大了特殊案例的适用范围, 把 逻辑上原来 "推不出" 的结论作为 "公理"给确立了。 Determining the obvious laws as axioms is not uncommon in the history of science. However, Kelvin directly compares the content with the conclusion 1 of the Carnot engine. It is only the scope of application 2, which is directly determined as "Kai’s expression", which is to skip the necessary premise (Carnot Law) and expand the scope of application of special cases. The conclusion that the logic was "cannot be pushed out" was established as "axiom".
试想要是没有卡诺定律出来否定超过 n 1 一 T T^的热机存在, 即可 假设有一非卡诺热机 X 其效率是 1 一 T z/ T i n x 1, 那只要连上一只制 冷机即可在总体上成为单一热源的热机而违背开氏表述(图 1中只要非卡诺 热机 X (左) 去冷源的热量少掉点划线部份, 成为输出功 w , 减去给制冷 机所作的功 Wl, W2就是总体上由单一热源 Q2所作的功了) 所以说卡诺定律 实质上是开氏表述赖以生存的、 不可或缺的前提, 跳过它直接确立开氏表述 为公理是不符合逻辑要求的。 I want to think that there is no Carnot's law to deny the existence of a heat engine that exceeds n 1 - TT ^. It can be assumed that there is a non-Carnot heat engine X whose efficiency is 1 T z / T in x 1, then just connect a refrigerator. In general, it becomes a heat source of a single heat source and violates Kelvin's expression (in Figure 1, as long as the non-Carnot heat engine X (left) goes to the cold source, the heat is less than the dotted line part, and becomes the output work w, minus the refrigerator. The work Wl, W2 is the work done by a single heat source Q2 as a whole. So, Carnot's law is essentially an indispensable premise for Kelly's expression to survive. Skip it and directly establish that Kelvin's expression is axiom. Not logically required.
至于教科书称可以用开氏表述为前提, 用反证法论证的卡诺定律, 这完 全是用原结论为前提去论证原前提的循环论证【注 14】, 理由很简单, 因为 卡诺定律是开氏表述不可或缺的前提不能再回过来用 "开"证 "卡"。循环论 证在形式逻辑中被称无效论证。 至此, 开氏表述在 立过程中的二个逻辑缺 陷 S经很明确:①直接以公理的形式确立开氏表述,不符合逻辑要求。 ② 用 开氏表述作前提论证卡诺定律是无效的循环论证。 至于那个被称作为 "虽然 其前提热质说是错误的, 但结论却是正确的"【注 15】 卡诺定律随它的前提 而去, 应该是唯一的符合逻辑的必然归宿。 As for the textbook saying that Kelvin's expression can be used as a premise, the Carnot's law, which is demonstrated by the counter-evidence method, is completely based on the original conclusion as a premise to demonstrate the circular argument of the original premise [Note 14]. The reason is very simple, because Carnot's law is Kelvin. The indispensable premise can not be returned to use the "open" card "card". The circular argument is called invalid argumentation in formal logic. At this point, Kelly's two logical defects in the process of standing up are clear: 1 The Kelvin expression is established directly in the form of axioms, which does not meet the logic requirements. 2 Using Kelvin's expression as a premise to demonstrate that Carnot's law is an invalid circular argument. As for what is called "although its premise is that the thermal theory is wrong, but the conclusion is correct" [Note 15] Carnot's law with its premise should be the only logical inevitability.
我们之所以详细披露这一逻辑缺陷是因为它在本文的立论中具有基础意 义。 没有这个基础问题的破解, 文章就成无源之水、 无根之木, 也就没有必 要让人们倾听, 只有在上述缺陷被公认, 文章才有展开的价值。 We disclose this logical flaw in detail because it has a fundamental meaning in the arguments in this paper. Without the crack of this basic problem, the article becomes a passive water, a rootless wood, and there is no need to let people listen. Only when the above defects are recognized, the article has the value of expansion.
1、 热泵聚热的启示: 1. The enlightenment of heat pump heat collection:
我们之所以要假设理想气体和理想过程, 目的全在于让过程摆脱种种非 主要因素, 看一看在什么情况下可以得到最佳效果, 以便获得通向最高效果 的"路线图",如果理想化后的效果并非最佳,那就需要全面反思出错的原因, 很可能是一个不该摆脱的因素被摆脱了。 这因素就是力场的存在和变化。 The reason we want to assume the ideal gas and the ideal process is to get rid of the non-primary factors, and to see the best results under what circumstances, in order to get the "road map" to the highest effect, if idealized After the effect is not the best, then you need to fully reflect on the cause of the error, it is likely that a factor that should not be rid of is rid of. This factor is the existence and change of the force field.
卡诺假设的工质是分子之间没有作用力的理想气体, 热泵的制热效果恰 恰是依靠工质分子之间有引力存在——当工质被压缩到一定距离分子之间引 力起作用,凝结成液滴, 自由度改变而相变放热,才让我们获得了 "再生热", 其结果比 "理想" 的逆卡诺循环效果更好 (见图 1 中 a' dcba' 循环比逆卡
诺循环 adcba省了面积为 aba' —块功), 真实气体作冷媒的蒸发过程, 吸收 热量比卡诺循环的等温膨胀吸收的热量多(差一汽化热),真实气体的分子之 间因为有引力, 液化时相变放热, 又比理想气体单纯压缩得到的焦耳热多这 一现象让我们看到了真实气体的效果反而超过 "理想"气体的结果, 这一结 果有着重大理论意义, 这个被熟视无睹的现象与负温度现象、 徐业林的实验 【注 16】 系同一渊源, 详析见第一节。 Kano's hypothetical working fluid is an ideal gas with no force between the molecules. The heating effect of the heat pump is precisely due to the gravitational existence between the working medium molecules. When the working medium is compressed to a certain distance, the gravitational force acts between the molecules. Condensed into droplets, the degree of freedom changes and the phase change is exothermic, which gives us a "regeneration heat". The result is better than the "ideal" inverse Carnot cycle (see a'dcba' cycle ratio inverse in Figure 1). Card Connaught cycle adcba saves the area of aba'-block work, the real gas is used as the evaporation process of the refrigerant, the heat absorbed by the isothermal expansion of the Carnot cycle is much higher (poor heat of vaporization), because there are Gravity, the phase change heat release during liquefaction, and the more Joule heat obtained by the simple compression of the ideal gas, let us see that the effect of the real gas exceeds the result of the "ideal" gas. This result has great theoretical significance. The phenomenon of ignoring innocence and the negative temperature phenomenon, Xu Yelin's experiment [Note 16] are the same source, as detailed in the first section.
2、 经典理论的梳理: 2. Sorting out the classic theory:
受到实验事实、 最新理论、 形式逻辑挑战的经典理论的确有缺陷。 大家 知道热传导、功转热二项都是熵增过程,而热功转换却是无序向有序的转化, 因此, 把开氏表述与克氏表述等同、 与不可逆规律等同很不妥当, 可以说是 造成 "热寂"理论的真正原因, 大自然应该、 可以、 也的确存在 "非开"过 程, 只有非开过程才是驱除 "热寂" 的最精准的理由。 Classical theories that are challenged by experimental facts, the latest theories, and formal logic are indeed flawed. Everyone knows that both heat conduction and work heat transfer are entropy increase processes, while heat work conversion is disorderly to orderly transformation. Therefore, it is not appropriate to equate Kelvin’s expression with Kline’s expression and with irreversible law. It is the real reason for the theory of "hot silence". Nature should, can, and does have a "non-open" process. Only the non-opening process is the most accurate reason to drive out "hot silence."
诞生于热质说的卡诺理论有四方面的缺陷, 重新定位已不可避免。 The Kano theory born in the thermal theory has four defects, and repositioning is inevitable.
3、 负熵诞生的机制: 3. Mechanism of birth of negative entropy:
众所周知, 不可逆有动力和通量两个概念, 熵增律是以分布为 "动力", 以 "最大紊乱"为劫底【注 17】 的状态规律。 其广泛适用大家并无异议。 但 同时存在的状态规律不止一条一一势能最小原理、 速率分布以钟型曲线为劫 底、 能量分布以自由度均分为劫底等规律, 所有物质的原子结构都以 2n2规 律为劫底 ……这些都是状态规律。 运动在走向各自劫底时, 出现有向运动, 都有带来有序的可能, 负熵在走向运动有序和走向结构有序中诞生。 前者因 热变功而表现为吸热降温、 后者因自由度变小而表现为放热升温, 负熵与熵 增是一个问题的两个方面, 构成大千世界的循环, 本文会阐明正熵与负熵都 在一定条件下诞生, 所谓 "自发"只是以常态为条件而已。 完全不应该由人 为主观划分而得到的 "开放系统"和 "孤立系统"来划分适用范围 As we all know, there are two concepts of irreversible power and flux. The entropy increase law is based on the distribution of "power" and "maximum disorder" as the state law of the robbery. There is no objection to its wide application. However, the state laws that exist at the same time are not limited to the principle of minimum potential energy, the velocity distribution is dominated by the bell-shaped curve, and the energy distribution is divided into the bottom of the law. The atomic structure of all matter is 2n 2 rule. ... These are the laws of the state. When the movements go to their respective robberies, there is a directed movement, which brings about the possibility of order. The negative entropy is born in the orderly movement and orderly structure. The former shows heat absorption and cooling due to thermal work, and the latter shows exothermic heat because the degree of freedom becomes smaller. Negative entropy and entropy increase are two aspects of the problem, which constitute the cycle of the world, and this article will clarify the positive entropy. Both negative entropy and birth are born under certain conditions. The so-called "spontaneousness" is only conditional on the normal state. The "open system" and "isolated system" that should be obtained from the subjective division of human beings should not be divided into applicable scopes.
4、 可以有更好的循环: 4, there can be a better cycle:
第一次论证是前提错误, 第二次论证是逻辑错误的卡诺定律的确有错: 理想热机不仅要求运行理想 (可逆、 无摩擦的假设保证了运行理想) 还需要 模式理想, 卡诺循环在处理因膨胀而带来的工质熵增问题上, 用等温和绝热 压缩让工质仅在表面上回到了原点, "无限大"冷源的假设掩盖了熵增的后 果, "外界"并没有与 "系统"同时回到始点, 因此说卡诺循环不是完善的循 环, 不再具有结论来自孤立系统的理论价值, 这在还没有熵概念的卡诺时代 是无法感知的。 The first argument is a premise error, and the second argument is that the logic error of Carnot's law is indeed wrong: the ideal heat engine not only requires the ideal to operate (reversible, frictionless assumptions guarantee the ideal of operation) but also the pattern ideal, the Carnot cycle To deal with the problem of entropy increase due to expansion, isothermal compression is used to make the working fluid return to the origin only on the surface. The assumption of "infinite" cold source masks the consequences of entropy increase. "The outside world" does not. Returning to the starting point at the same time as the "system", it is said that the Carnot cycle is not a perfect cycle, and no longer has the conclusion from the theoretical value of the isolated system, which is not perceptible in the Kano era without the concept of entropy.
更重要的是, 卡诺热机本质上不是效率最高的理想热机, 只有在循环中 去除 "等温压缩"这一功变热的熵增过程而换成熵减过程, 才能得到真正的 理想热机, 模式为三维循环的理想热机, 会有更高的效率, 达到卡诺所说的
"再高就无中生有了 "【注 18】 的高度。 正如 '反证, 中所说, 如果有超过 卡诺效率公式的热机与制冷机联袂, 就会产生违背 '开氏表述' 的现象 -- 单一热源做功。 也就是说, 可以从 "联袂" 的结果得到从被称为抚的空气等 废热中获得 "再生功"。 More importantly, the Carnot engine is not the most efficient and ideal heat engine. Only by removing the entropy increase process of "isothermal compression" in the cycle and replacing it with the entropy reduction process, can the real ideal heat engine be obtained. The ideal heat engine for three-dimensional circulation will have higher efficiency, which is what Kano said. "The height is high, there is no middle school." [Note 18] The height. As stated in the 'reverse proof, if there is a heat engine that exceeds the Carnot efficiency formula and the refrigerator, there will be a phenomenon that violates the 'Kai’s expression' - a single heat source. In other words, it is possible to obtain "regeneration work" from the waste heat such as the air called Fu from the result of "joining".
5、 热功转换的本质: 5. The essence of thermal power conversion:
热功转换的本质是粒子的运动方向因 '势差'获得一致的有序后被截获, 才成为功。而温差只是势差的一种。据此,主导工业革命的温差热机只是"热 功转换" 中的一种。 热质说虽然被作废, 但作功是因为 "热质降落"必须有 温差才能作功的思想 【注 19】, 仍被保存在 "温差热力学" 中, 其卖工质靠 加热获得膨胀, 受气缸的限制, 膨胀朝一个方向进行而得到有序, 由活塞截 获而获得了功。 作为传统的温差热机也同样可用上述 "截获有序"来解释。 作为热功转换中的一种形式, 温差作功的模式只是一个"点", 其效率公式不 能向整个热功转换这个 "面"推广。 在 "面" 的范围里存在着靠其他势差获 得有序并截获为功的可能 (如场变做功) 因此, 结论应该是: 由无序走向有 序的热功转换, 有温差固然可以做功, 无温差而有其他势差也可"截获有序" 而做功。 至于效率问题, 当然就不应该受其中一个"点"的规律(卡诺公式) 的限制了。 The essence of thermal power conversion is that the direction of motion of the particles is intercepted by the 'potential difference', and it becomes the work. The temperature difference is only one kind of potential difference. According to this, the thermoelectric engine that dominates the industrial revolution is only one of the "heat power conversion". Although the heat quality theory is abolished, it is because the idea of "heat mass falling" must have a temperature difference to work hard [Note 19], and it is still stored in "temperature difference thermodynamics", and its selling quality is heated by heating to obtain expansion. The limitation of the cylinder, the expansion proceeds in one direction and is ordered, and the work is obtained by intercepting the piston. As a traditional thermoelectric heat engine, it can also be explained by the above-mentioned "interception". As a form of thermal power conversion, the mode of temperature difference work is only a "point", and its efficiency formula cannot be promoted to the whole "heat surface" conversion. In the scope of "face", there is the possibility of obtaining order by other potential differences and intercepting it as work (such as field work). Therefore, the conclusion should be: from disorder to ordered heat work conversion, although temperature difference can be done There is no temperature difference and other potential differences can also be "intercepted orderly" and work. As for the efficiency issue, of course, it should not be limited by one of the "point" rules (Carnot formula).
6、 真理简单而美丽 6, the truth is simple and beautiful
可以在沦落为怃的热能中获得热和功, (佣和怃的概念仍适用温差热力 学的范畴)其根本原因是因为改变粒子的运动方向只需要条件,而并不耗功, 这可以在洛伦兹力中电子的表现得到证实。 经典理论未考虑粒子在力场中的 表现成为出错的原因。 要得到热能, 除了可以给系统做功、 加热 (热传导) ——加强紊乱粒子的动能之外, 还可以由结构变化得到。 要得到功, 也可以 由力场来纠正粒子的方向, 把它们方向一致后的能量截获 (不用活塞) 就可 以。 真理是简单而美丽的, 人类可以在能量的形式转换中按需索取, 真正的 可再生能源让人类无需担心能源的枯竭。 发明的公开 Heat and work can be obtained in the heat of the fallen, (the concept of commission and 仍 is still applicable to the thermodynamics of temperature difference). The root cause is that changing the direction of movement of the particles requires only conditions, and does not consume work. The performance of electrons in Lenzeli was confirmed. The classical theory does not consider the performance of particles in the force field as the cause of error. In order to obtain thermal energy, in addition to the work and heating (heat conduction) of the system, which can enhance the kinetic energy of the disordered particles, it can also be obtained by structural changes. To get the work, the force field can also be used to correct the direction of the particles, and the energy after they are aligned (without the piston) can be intercepted. Truth is simple and beautiful. Humans can get it on demand in the form of energy conversion. Real renewable energy does not require humans to worry about the exhaustion of energy. Disclosure of invention
目录 table of Contents
1、 热泵集热的启示 1. Enlightenment from heat pump heat collection
2、 经典理论的梳理 2, combing the classic theory
2.1、 开氏表述与其他表述并非同一, 可以切割、 分离。 2.1. Kelvin's expression is not the same as other expressions and can be cut and separated.
2.2 、 开氏表述遭实验否定理论上并无羁绊。 2.2, Kelvin's expression is negative in theory.
2.3 -、 卡诺理论缺陷有四。 2.3 - There are four defects in Carnot's theory.
3、 负熵的诞生机制。
3.1、 由力场引起的 "最小能原理"可与熵增共辘 3. The birth mechanism of negative entropy. 3.1. The "minimum energy principle" caused by the force field can be increased with entropy.
3.2、 气态方程应该是 nQ= Mg / 4 ii r 2 K T 3.2, the gas equation should be n Q = Mg / 4 ii r 2 KT
3.3、 强力场改变自由度, 诞生结构热 3.3, the strong field changes the degree of freedom, the birth of the structure is hot
3.4、 力场带来位能的概念, 应恢复克劳休斯对第一定律的首次表述, 即 dQ =dH+dJ+dw, 3.4. The concept of potential energy brought by force field should restore the first expression of Clausius to the first law, ie dQ =dH+dJ+dw,
3.5、 力场带来了 "负温度"现象, 开论从此终结 3.5, the force field brings the phenomenon of "negative temperature", the beginning of this theory
3.6、 状态规律的多元化, 使正熵负熵皆有可能 3.6. Diversification of state laws, making positive entropy and negative entropy possible
4、 更好的三维循环 4, a better three-dimensional cycle
4.1、 可以在严格的孤立系统中演绎违背开氏表述的三维循环。 4.1. A three-dimensional loop that violates Kelvin's expression can be interpreted in a strictly isolated system.
4.2、 热功转换的本质与规律 4.2. The nature and law of thermal power conversion
5、 能量集中的方案 5. Energy concentration scheme
1、 热泵集热的启示 、 1. The enlightenment of heat pump heat collection,
一度电的投入, 却获得了几度电的热量,这现象在上一世纪中叶就让人称 奇。 此事发生在莫斯科卫生设备制备厂, 当时大家称奇的实际上是半导体的 帕耳第现象, 这是塞贝克效应的逆效应。 当一块 N型半导体与一块 P型半 导体联结成电偶对, 并在电路上加直流电时, 会出现一端吸热, 另一端发热 的现象, 发热的量超过了直流电应发的焦耳热, 超量的热来自冷端, 从空气 中吸收的热量。 好奇的人们惊呼得到了恩克斯所说的 "能量集中"但 "电制 冷"与 "热泵制冷"一样, 人们深究的兴趣都被 "逆卡诺循环"的解释浇灭。 The input of electricity once gained a few degrees of heat, which was amazing in the middle of the last century. This happened in the Moscow sanitary equipment preparation factory. At that time, everyone was surprised by the fact that the semiconductor was the Parr phenomenon, which was the inverse effect of the Seebeck effect. When an N-type semiconductor is connected to a P-type semiconductor as a galvanic pair and a DC current is applied to the circuit, there is a phenomenon that one end absorbs heat and the other end generates heat. The amount of heat exceeds the Joule heat of the DC power. The heat comes from the cold end, the heat absorbed from the air. Curious people exclaimed what Enx called "energy concentration" but "electric cooling" is the same as "heat pump cooling", and people's interest in deep learning has been ruined by the explanation of "anti-Kano cycle".
今天当可再生能源成为全球话语时, 我们觉得剖析一下热泵以及 "电制 冷"对获取 中热很有必要。 先说热泵: 图 2 中那条虚线来自图 3 中描述 真实气体的等温线族, b 向 a 的等温过程是汽液共存的状态,它温度不变, 压强不变, 但体积变小了, 我们知道在等温膨胀过程中因为 V2 >V , , 所以 △S = J dQ / T0= 1 / To 一/ dQ = v Rln V V )是正熵, 今 Vs V,应该 是一个负熵过程, 尽管这一过程是在外界作功压缩的帮助下得到, 但作功压 缩所费能量在热端以不少分文的焦耳热放出。 并不因为做了带来负熵的 "负 熵流"有任何能量损失,真实气体是靠气体分子之间到达某个距离引力为主。 Today, when renewable energy becomes a global discourse, we feel that it is necessary to analyze the heat pump and "electric cooling" to obtain medium heat. Let me talk about the heat pump: The dotted line in Figure 2 is from the isotherm family of the real gas in Figure 3. The isothermal process of b to a is the state of vapor-liquid coexistence. The temperature is constant, the pressure is constant, but the volume is smaller. We know that during isothermal expansion, because V 2 >V , so ΔS = J dQ / T 0 = 1 / To / dQ = v Rln VV ) is positive entropy, and today Vs V should be a negative entropy process, although This process is obtained with the help of external work compression, but the energy required for work compression is released at the hot end with a lot of Joule heat. It is not because of the energy loss caused by the "negative entropy flow" that brings negative entropy. The real gas is mainly caused by the attraction of gas molecules to a certain distance.
(图 4 中上方虚线为斥力, 下方虚线为引力, 实线为合力) r2处出现引力, η处引力最大,1¾为斥力、 引力的平衡点, '分子间凝结为液滴, 自由度改变, 遂在热端放出冷端吸收来的那份热量。 帕耳第效应基于同一原理, 只是由电 子"操作", 电子在冷端固有电场的吸引下加速, 从而吸收空气中热量, 在热 端放出而己, 共同点都是在力场的参与下成功, 关于自由度变化伴随熵变在 本文 3、 2中详述。 (The upper dotted line in Figure 4 is the repulsive force, the lower dotted line is the gravitational force, the solid line is the resultant force.) The gravitational force occurs at r 2 , the gravitational force at η is the largest, and the 13⁄4 is the equilibrium point of repulsive force and gravitation. 'Intermolecular condensation is droplets, and the degree of freedom changes. The cockroach releases the heat absorbed by the cold end at the hot end. The Peltier effect is based on the same principle. It is only operated by electrons. The electrons are accelerated by the intrinsic electric field of the cold end, so that the heat in the air is absorbed and released at the hot end. The common point is the success of the force field. The change in degrees of freedom associated with entropy changes is detailed in Sections 3 and 2.
大家知道功是 "过程量", 即功不是状态的函数, 只知道初末状态并不能 确定功的大小, 因此图 2 中我们完成同样循环却比卡诺循环少付出 ba'a—
块功有重要意义, 后面的分析会知道它与负温度、 徐氏实验出于同一渊源。Everyone knows that work is a "process quantity", that is, work is not a function of state. Only knowing the state of the beginning and the end does not determine the size of the work. Therefore, in Figure 2, we complete the same cycle but pay less than the Carnot cycle. Block work is important, and later analysis will know that it is the same source of negative temperature and Xu's experiment.
2、 经典理论的梳理 2, combing the classic theory
2.1、 开氏表述与其他表述并非同一, 可以切割、 分离 2.1, Kelvin's expression is not the same as other expressions, can be cut, separated
首先形式逻辑告诉我们, 概念有相容与否, 相容概念又有同一、交叉和从 属之分(首都和北京是同一、 男人和学生是交叉、 中国和上海是从属), 所以 将不可逆规律与克氏表述、 熵增律、 开氏表述称为同一并统称为热力学第二 定律是一个错误。 开氏表述与其他表述也的确不是同一关系。 First, the formal logic tells us that the concept is compatible or not. The concept of compatibility has the same, cross and subordinate (the capital and Beijing are the same, the man and the student are the cross, and the Chinese and Shanghai are the subordinates), so the irreversible law will be The expressions of Krebs, entropy, and Kelvin are called the same and collectively called the second law of thermodynamics is a mistake. The expression of Kelvin is not the same as other expressions.
热力学第二定律是作为热功转换规律的研究而展开的, 人们在研究该规 律时领悟了事物发展的不可逆属性, 应该说克氏表述是对热传导的不可逆性 的表述, 仅是不可逆过程中的一种, 但它又很快被证与开氏表述相通。 本节 会说明相通的含义但绝不是同一的意思,正如严济慈所说: "象这样的热力学 来泛指研究一切变化的科学, 热力学这个名字己失之太狭 "【注 22】 The second law of thermodynamics is developed as a study of the law of heat transfer. When people study this law, they understand the irreversible property of the development of things. It should be said that Krebs expression is an irreversible expression of heat conduction, only in the process of irreversibility. One, but it was quickly proved to be in communication with Kelvin. This section will explain the meaning of the same but it is not the same meaning, as Yan Jici said: "The thermodynamics like this refers to the science of studying all changes, the name of thermodynamics has been too narrow" [Note 22]
我们认为 1 、单一过程的不可逆规律是宇宙级规律, 它与相对性、 守恒 律、 因果律等一样, 是几乎渗透到每一角落都在起作用的普适规律, 可以说, 所有事物、 所有过程都在不可逆转的走向平衡的终点。 We believe that the irreversible law of a single process is a cosmic law. Like the relativity, the conservation law, the causal law, etc., it is a universal law that almost penetrates into every corner. It can be said that all things, all processes They are all irreversibly going to the end of the balance.
2、 克氏表述则狭小的多, 是描述热传导 "向"的规律, 它应该与描写热 传导 "量" 的规律- --—傅立叶定律并为一统。 2. The expression of Kjelda is much narrower. It is a law describing the heat conduction "direction". It should be consistent with the law describing the heat quantity "quantity" - Fourier's law.
3、大家知道, 不可逆有动力和通量 2 个属性, "熵增 "是以分布为动力 的不可逆过程, 大家对它的正确性并无异议, 但因为尚有其他动力的状态规 律存在, "系统熵极大"就不再是无条件的、唯一的状态结果。负熵过程不仅 如耗散结构理论所说存在, 而且可按本文所说求得。 3. As we all know, irreversible has two attributes: power and flux. "Entropy increase" is an irreversible process based on distribution. Everyone has no objection to its correctness, but because there are other dynamic state laws, " The system entropy is "no longer an unconditional, unique state result." The negative entropy process is not only described as the theory of dissipative structure, but can also be obtained as described in this paper.
4、 表达热功转换规律的开氏表述才是真正意义上的热力学范畴内的规 律: 它包含着 "单一热源无法作功"、 "第二种永动机不可能"和效率公式这 几个其实是同一互通的表述, 由于受实验事实的挑战, 它的正确性需要再研 究, 这个历史上争论最多的话题, 今天应该到定格的时候了, 它与单一过程 的不可逆性, 包括单一热传导过程的不可逆性, 可以切割分离。 互不影响各 自新的定位。 4. The expression of Kelvin expressing the law of thermal power conversion is the law within the true sense of thermodynamics: it contains the "single heat source can not work", "the second type of perpetual motion impossible" and the efficiency formula It is the expression of the same intercommunication. Due to the challenge of experimental facts, its correctness needs to be studied again. The most controversial topic in history, it should be time to freeze, it is irreversible with a single process, including the single heat conduction process. Irreversible, can be cut and separated. They do not affect each other's new positioning.
2.1.1 其次要定义,不可逆是指一个过程。该过程在某个条件下, 自发地、 不可逆转地朝某个方向发展。 "自发 "的动力来自梯度,过程因梯度的作用而 始、 因梯度的消失而终。 克氏表述的热传导梯度缘于温差, 熵增过程的梯度 缘于 "分布"要走向最可几状态。 我们把走向平衡所需要的时间称为驰豫时 间, 长则亿年短则几秒。 我们把这一过程都称为一劫, 把最后最为稳定的平 衡点称劫底。 有动力, 走向劫底成为必然, 没有动力, 则过程无法启动。 "可 逆"的假设是违背 "一切过程都是不可逆的"这一已知真理的。 "可逆"的思 维方式, 还停留在 "时间反演对称"的牛顿时代, 还没有引入 "对称性破缺"
的 "时间箭头"……这个经典热力学研究中最重要的收获。 2.1.1 Second, define, irreversible refers to a process. The process develops spontaneously and irreversibly in a certain direction under certain conditions. The "spontaneous" power comes from the gradient, and the process begins with the action of the gradient and ends with the disappearance of the gradient. The heat transfer gradient expressed by Kline is due to the temperature difference, and the gradient of the entropy increase process is due to the "distribution" going to the most probable state. We call the time required to go to balance as the relaxation time, which is as long as a few hundred years and a few seconds. We call this process a catastrophe, and we call the last most stable balance. With motivation, it is inevitable to go to the bottom of the robbery. Without motivation, the process cannot be started. The "reversible" assumption is against the known truth that "everything is irreversible." The "reversible" way of thinking still stays in the Newton era of "time inversion symmetry", and has not yet introduced "symmetry breaking" The "Time Arrow"... the most important gain in this classic thermodynamic study.
循环决不可能由 "可逆"来完成, 只可能由另一动力的不可逆过程互为 首尾构成循环。简言之图 5 中 abc 过程不可能由可逆的 cba 去完成, 而是 由另一动力的 cda来完成。 The cycle can never be done by "reversibility", and it is only possible that the irreversible process of another power constitutes a loop with each other. In short, the abc process in Figure 5 cannot be done by a reversible cba, but by another powered cda.
2.1.2 把熵增看作所有不可逆过程的共同原因是一个错误,不可逆过程各 有各的动力, 各有各的劫底。 说他们相通, 仅仅是指在不可逆这一点上存在 共性。 2.1.2 It is a mistake to regard entropy increase as the common cause of all irreversible processes. The irreversible process has its own motives, each with its own. To say that they are connected, it simply means that there is commonality on the irreversible point.
图 6 左图是教科书观点的逻辑图示, A为不可逆规律、 B 为熵增律、 C 为克氏表述、 D 为开氏表述, 图 6 左图表明 A与 B 、 C、 D 为同一 关系。 图 6 右图表明我们的观点: B 从属于 A , B 中 E、 C 二个不可逆 过程分别为功变热的 E 和热传导的 C , 都是不可逆过程中熵增的一种, 与 "不可逆"规律这个宇宙级规律是从属关系。将不可逆与熵增律、克氏表述、 开氏表述混为一谈之所以是一个错误,是因为这样会排斥掉同样是不可逆的, 但属另一动力的负熵过程 X , 梳理这个逻辑关系的目的就是借以说明在图 6 右图中可以有一个 X 的负熵过程,包括走向运动有序的 D 和走向结构有 序的 F , (热向功的转换说明系统内有一部无序转变成有序, 应该是负熵过 程) 它们都是 B 的对立面, 却也是不可逆过程, 它可与 E 或 C 构成循环 (后详述),而这在图 7 左图中,因为熵增律 B 错误的扩大为不可逆规律 A 的同一关系, X 是不允许存在的。这使图 6 左图"热死"不可避免.【注 21】, 图乙则不可能发生 "热死"。 Figure 6 The left picture is a logical diagram of the textbook view. A is irreversible, B is entropy law, C is Kelvin, D is Kelvin, and Figure 6 shows A is the same relationship with B, C, and D. . Figure 6 The right picture shows our point of view: B belongs to A, B. The two irreversible processes of E and C are the heat of heat and the heat of heat C, both of which are entropy increases in the irreversible process, and "irreversible" The law of the universe is a subordinate relationship. It is a mistake to confuse the irreversible and entropy law, the Kline expression, and the Kelvin expression because it rejects the same irreversible, but it is another negative entropy process X. The purpose of combing this logical relationship is It can be seen that there can be a negative entropy process of X in the right picture of Fig. 6, including the orderly moving D and the orderly structure F. (The conversion of the thermal work indicates that there is a disorder in the system into order, It should be a negative entropy process.) They are all opposites of B, but they are also irreversible processes. They can form a loop with E or C (described in detail later), and this is shown in the left graph of Figure 7, because the entropy increase law B error is expanded to The same relationship of irreversible law A, X is not allowed to exist. This makes the "hot death" in the left picture of Figure 6 unavoidable. [Note 21], Figure B is unlikely to occur "hot death."
2.1.3 在热和功这二个能量形态之间不存在势差, 因此不可能诞生 "自 发"的不可逆现象。热不可能无条件的转化为哪怕一丁点功是大家所熟知的, 转化是在热机的条件下成功的, 同样, 在没有摩擦和电阻的这一类条件下, 太空中的陨石、 超导中的电流并没有自发变慢而发热, 也就是说功转换为热 也是有一定条件的。 处于惯性状态的机械运动与处于最可几状态的分子热运 动一样, 都处在最稳定的平衡态, 连时间概念都已消失 (平衡态已无驰豫时 间概念), 无外界千预将一直维持这一状态, 不具有自发转化成其他状态的 动力。 后面我们将知道熵为零和熵极大是两个极端, 熵增、 熵减是在既不为 零也不极大的情况下描写走向 "更乱", 或 "更有序" 的 2 个动态的描写。 熵增熵减各有条件而成、 各由动力而生, 都是不可遏制的不可逆过程。 2.1.3 There is no potential difference between the two energy forms of heat and work, so it is impossible to create an irreversible phenomenon of "spontaneousness". It is impossible for the heat to be unconditionally transformed into even a little bit of work. The conversion is successful under the conditions of a heat engine. Similarly, in the absence of friction and electrical resistance, in the meteorites and superconductors in space. The current does not spontaneously slow down and heat up, which means that there is a certain condition for the work to be converted into heat. The mechanical motion in the inertial state is in the most stable equilibrium state as the molecular thermal motion in the most probable state. Even the concept of time has disappeared (the equilibrium state has no concept of relaxation time). Maintaining this state does not have the power to spontaneously transform into other states. We will know later that entropy is zero and entropy maximization is the two extremes. Entropy increase and entropy reduction are two ways to describe "more chaotic" or "more orderly" in the case of neither zero nor maximal. Dynamic description. Entropy, entropy, and entropy are all conditional and each is born by power. It is an irresistible irreversible process.
2.1.4 教科书在证 "克" "开"互通时称, 如果 "开"不管用, 则会导致 热量从冷端跑向热端的最终结果,我们认为这一点不奇怪,而且是应有之议, 因为此时的最终结果已不是 "单一过程"的结果, 而是循环的结果。这里"单 一过程" 的概念很重要。 熵增和热传导的单向不可逆都是指与梯度相始终的 单一过程。 不可逆并不排斥状态可以由循环重建。 简言之, 不可逆专指单一
过程, 不涉状态, 状态可以是多个过程的结果。 如果因 "非开" 的假设得到 了 "非克" 的推论——热传导反向原路返回了, 那克、 开的确相通。 现在的 情况是 "非开"提供了另一途径, 让热量回到高温端, 仅仅提供了热传导可 以重复出现、继续进行的可能, 非开过程是循环中的另一半(图 6中 cda ) , 二者称同一并不妥当, 正如 《 热力学分析 》 一书中所说 "近些年来, 对二 种表述的条件与等效性问题提出了新的疑问, 尤其是 1951 年核自旋系统实 验提示了负绝对温度的存在, 并证明负绝对温度比正绝对温度更高的事实, 对热力学第二定律提出了新的质疑"。 "克"、 "开"二论是不相容的并列概念, 描述热传导的克氏表述的 C 属于熵增过程, 而热变为功的过程则是负熵过 程, 说清这层关系是为了他们能分道扬镳。 2.1.4 Textbooks in the certificate "g""open" intercommunication, if "open" does not work, it will lead to the final result of heat running from the cold end to the hot end, we think this is not surprising, and it is due Because the end result at this time is not the result of a "single process", but the result of the cycle. The concept of "single process" is very important here. The one-way irreversibility of entropy increase and heat conduction refers to a single process that is consistent with the gradient phase. Irreversible and non-rejective states can be reconstructed by loops. In short, irreversible refers to a single Process, without state, state can be the result of multiple processes. If the "non-gram" hypothesis is obtained because of the "non-open" hypothesis - the heat conduction reverses the original path, and the gram and the open are indeed the same. The current situation is that "non-open" provides another way to return heat to the high temperature end, providing only the possibility that heat conduction can be repeated and proceeding. The non-opening process is the other half of the cycle (cda in Figure 6). It is not appropriate to call the same two, as stated in the book Thermodynamic Analysis. In recent years, new questions have been raised about the conditions and equivalence of the two expressions, especially the 1951 nuclear spin system experiment. The fact that negative absolute temperature exists and proves that the negative absolute temperature is higher than the absolute absolute temperature raises new questions about the second law of thermodynamics. The "ke" and "open" two arguments are incompatible parallel concepts. The C describing the heat conduction is a process of entropy increase, and the process of heat becoming work is a negative entropy process. They can part ways.
2.2开氏表述遭实验否定, 理论上并无羁绊 2.2 The expression of Kelvin was negatively rejected by the experiment. There is no theory in theory.
2.2.1生命的背后是负熵 2.2.1 Behind life is negative entropy
开尔文是提出 "开氏表述" 的始作俑者, 他在 "热的动力理论" 中仍很 小心地把表述放在 "生命"之外。 他说 "利用无生命物质的作用, 把物质的 任何部门冷到比它周围最冷的客体的温度以下, 以产生机械效应这是不可能 的" 即后来称之谓单一热源作功不可能的开氏表述。 我们认为开尔文把表述 的适用范围定为 "无生命"物质尽管学风审慎, 但不应以生命为界。 生命现 象是有序的奇迹, 它把吸收到的热能、 光能存储在结构中, 以至薛定谔极为 深刻地说"生命就是负熵 "。今天赖以为用的石化资源还是当年的太阳能存储, 在生命现象的背后必有规律——负熵的诞生机制支撑着, 一旦揭开, 开翁的 预留空白将证明先贤的前瞻性担忧十分英明。 与恩克斯的待解论一样, 表达 了大思想家严谨、 精确的风范。 Kelvin is the initiator of the "Kai's expression". He still carefully puts the expression outside of "life" in the "thermal dynamic theory". He said, "It is impossible to use the role of inanimate matter to cool any part of the material below the temperature of the coldest object around it to produce a mechanical effect," which is later called a single heat source. Kale’s statement. We believe that Kelvin defines the scope of expression as "inanimate" material. Although the style of study is prudent, it should not be bounded by life. Life is an orderly miracle. It stores the absorbed heat and light energy in the structure, and even Schrödinger profoundly says that "life is negative entropy." The petrochemical resources that we used today are still the solar energy storage of the year. There must be a law behind the phenomenon of life. The birth mechanism of negative entropy is supported. Once it is opened, the blank of the opening of the sage will prove that the prospects of the sages are very wise. . Like Enx's solution, it expresses the rigorous and precise style of the great thinker.
2 . 2 . 2 非开过程可以、 应该也的确存在着。 2 . 2 . 2 The non-opening process can, should, and does exist.
首先, 开氏表述并不是被实验直接验证的结果, 而是思辩结果, 不符合 科学定律要由实验支撑的规矩, 可以有错。 上个世纪美国负温度的实验得出 了直指开氏表述的结果, 中国报道的无偏二级管实验, 热泵的超理想工作都 与开论有悖。 如果说科学是实验为依据的规律探索, 那么面对排闼而来的实 验事实, 难道还坚持思辩结论? First of all, the expression of Kelvin is not the result of direct verification by experiments, but the result of speculation. The rules that are not in conformity with the laws of science to be supported by experiments can be wrong. In the last century, the experiment of negative temperature in the United States gave the result of direct expression of Kelvin. The unbiased diode experiment reported by China and the super ideal work of heat pump are all related to the theory. If science is an experimentally based law exploration, do you still insist on the conclusion of the facts in the face of the experimental facts?
其次,开氏表述有错误才附合对立统一之规律,才不与达尔文学说相悖; 既与几 η = 1 的能量守恒定律相合, 又不影响单一过程中的不可逆规律的广 泛运用, 其中包括克氏表述。 相反, 它的正确会带来热寂说, 会带来循环的 另一半的缺失, 会带来与第一定律"质"的矛盾(恩克斯语),所以应该有错。 Secondly, Kelly’s expression is wrong to conform to the law of unity of opposites, and it does not contradict Darwin’s theory; it is consistent with the law of conservation of energy of η = 1 without affecting the extensive application of irreversible laws in a single process, including Expression. On the contrary, its correctness will bring about the heat of silence, which will bring about the lack of the other half of the cycle, which will bring the contradiction of the first law "quality" (Enics), so there should be a mistake.
最后, 即使因为它的失效带来了单一热源作功的 "第二种永动机", 那也 与第一种永动机无中生有不一样, 正如严济慈所说 "永动机"这个名字很不 恰当,我们认为永动 2 字不该有贬义,因为这种循环永动的存在是永不停息、
循环运转的大自然的缩影, 有此 "缩影"才真实地描绘了大自然Finally, even if it fails to bring a single heat source to work as a "second perpetual motion machine", it is different from the first type of perpetual motion machine. Just as Yan Jici said that the name "perpetual motion machine" is not appropriate, we I think that the permanent word 2 should not be derogatory, because the existence of this kind of cyclical perpetuity is never stopped, The epitome of nature that circulates, with this "microcosm" to truly depict nature
2 . 2 . 3 由不完全归纳法确立的 "公理"有错并不奇怪。 2 . 2 . 3 It is not surprising that the "axioms" established by the incomplete induction method are wrong.
所谓不完全归纳法与完全归纳法的区别在于后者对所论都一一验证, 这 很可靠。 比如说"金属都导电"的这一判定就用所有金属的一一导电来证明, 而前者则不一样。 靠观察众多事例来确定规律往往是 N 个例证是正确的, 但无法证明 N + 1 的正确性所以需要科学解释来支撑,开氏表述是以"公理" 引入的, 它的支撑就是当时被看作绝对、 无条件的熵增论。 今天, 耗散结构 理论已论证大量负熵现象的存在, 并己获奖、 公认。 我们要阐述的仅仅是负 熵的诞生机制, 是另一些与熵增律同时存在的状态规律, 主导着负熵过程。 熵增熵减同时存在于宇宙之中, 不过各有不同的诞生条件罢了, 它们同样都 不可阻挡地走向各自平衡的劫底, 以至相应地诞生了有序、 无序。 一旦匡正 了 "科学解释"就可以解释二者在不同条件下如何诞生。 The difference between the so-called incomplete induction and the complete induction is that the latter verifies the arguments one by one, which is very reliable. For example, the determination that "metal is conductive" is proved by the conduction of all metals, and the former is different. Observing many cases to determine the law is often N examples are correct, but can not prove the correctness of N + 1 so it needs scientific explanation to support, Kelvin's expression is introduced by "axiom", its support is to be seen at that time Make an absolute, unconditional increase in entropy. Today, the theory of dissipative structure has demonstrated the existence of a large number of negative entropy phenomena, and has been awarded and recognized. What we want to elaborate is only the birth mechanism of negative entropy, and other state laws that exist simultaneously with the law of entropy increase, which dominates the process of negative entropy. Entropy and entropy reduction exist in the universe at the same time, but each has different birth conditions. They are also unstoppable to the balance of their own, so that the order and disorder are born accordingly. Once you have corrected the "scientific explanation", you can explain how the two are born under different conditions.
历史上不完全归纳法出错的例子并不少见 1、 亚里士多德的 "自由落体 定律"为典型, 亚里士多德认为自由落体总是以重的物体先落地, 这很容易 在石子和叶子落地速度的实践中观察到而成为 "公理", 所以 "正确"了二千 多年, 但在伽里略时代, 一个叫贝尼德蒂的意大利人用睿智的逻辑反诘提出 了问题,结果被伽里略一锤定音,亚里士多德错了。 2、在惯性定律发现之前, 人们 "观察"到一个规律: 所有运动都会慢慢停下来, 所以中国的庄子才对 日月的运行发问: "其运转而不能自止耶"很明显, 他认为 "不能自止"是反 常的, 哪知 "不能自止" 的惯性运动与静止一样, 才是不需要解释的正常状 . 态。可以说,现象与本质往往不完全统一, 同样说"熵增熵减都是有条件的", 会违背人们己经接受, 并定格了的 "真理"再认识必然有很大阻力, 需在后 面详析。 The example of the incomplete induction of errors in history is not uncommon. Aristotle’s "free fall law" is typical. Aristotle believes that free fall always landed with heavy objects, which is easy to be in the stone. And the practice of leaf landing speed has been observed as "axiom", so "correct" for more than 2,000 years, but in the Galileo era, an Italian named Benedetti raised questions with wise logic. The result was fixed by Galileo and Aristotle was wrong. 2. Before the discovery of the law of inertia, people "observe" a law: All movements will slowly stop, so China's Zhuangzi asks about the operation of the sun and the moon: "It can't stop ya", he thinks "Cannot stop" is abnormal, and the inertial motion that knows "cannot stop" is the same as static, which is a normal state that does not require interpretation. It can be said that the phenomenon and the essence are often not completely unified. Similarly, "entropy entropy reduction is conditional", it will violate the people's acceptance, and the "truth" that has been fixed will inevitably have great resistance. Detailed analysis.
2 . 3 卡诺理论缺陷有 4 2 . 3 Carnot theory defects have 4
既然开尔文论证无效, "挽救 "即归失败。而原来二个逻辑关系却依然存 在:①上面阐述的卡诺定律是开氏表述不可或缺的前提。 ②热质说又是卡诺 定律不可或缺的前提。 这样, 三者构成了热质说——卡诺定律——开氏表述 的逻辑链, 最终前提是热质说。 Since the Kelvin argument is invalid, "rescue" is a failure. However, the original two logical relationships still exist: 1 The Carnot's law described above is an indispensable premise for Kelvin's expression. 2 The thermal theory is an indispensable prerequisite for Carnot's law. In this way, the three constitute the thermal quality theory - Carnot's law - the logical chain of Kelvin's expression, the ultimate premise is the thermal theory.
热质说的组成有二部份, 当年热质说被废的只是 "热质不生不灭"这一 条, 另一个重要组成 "温差才能作功" 的思想一直保存至今, 仅仅把 "热质 的量决定于温差" 中的 "质"字改成了 "量"而已, "没有冷, 热将无用"、 瀑布和水轮机的比喻都反映温差作功的思想, 这与我们 "功是有序的截获" 的本质认识完全不同。 "温差可以作功"没有错误,但把它看作唯一才是一个 错误, 卡诺模式可以是热功转换中的一个模式, 但把它看作最佳才是一个错 误, 二个错误源于对本质认识有误, 以及逻辑思辩有误。 让我们打开尘封的
历史, 看一看卡诺理论的缺陷。 The composition of the heat quality theory has two parts. In the past, the heat quality was said to be abolished only by the fact that "the heat quality is not indestructible". Another important idea is that the "temperature difference can only work" has been preserved until now. The amount is determined by the "quality" in the temperature difference. The word "quantity" is changed to "quantity". "No cold, heat will be useless", the metaphor of waterfalls and turbines all reflect the idea of temperature difference, which is "we are orderly." The understanding of the nature of the interception is completely different. "The temperature difference can be done" is no mistake, but it is a mistake to regard it as the only one. The Carnot mode can be a mode in the conversion of thermal power, but it is a mistake to regard it as the best. The two errors stem from the error. The understanding of the essence is wrong, and the logic is wrong. Let's open the dusty History, take a look at the shortcomings of Kano's theory.
热力学经典理论诞生在蒸汽机发明之后。当 1768年蒸汽机基本完善,社 会急需回答热 的理论最高效率是多少, 年轻的法国工程师卡诺, 用思想实 验回答了这个问题。 他的基本思想 [注 22 ] 有: The classical theory of thermodynamics was born after the invention of the steam engine. When the steam engine was basically perfect in 1768, the society was in urgent need of answering the hottest theory. The young French engineer Kano, answered this question with thought experiments. His basic thoughts [Note 22] are:
a 、 当时占统治地位的热质说—— "热是无重量的在任何过程中不会产 生、 也不会消灭的粒子流"、 "物体的冷热程度决定它含热质的多少"。 a, the dominant thermal theory at the time - "Heat is a particle flow that does not produce weight in any process and does not disappear". "The degree of heat and cold of an object determines how much it contains heat."
b 、 他父亲拉扎尔研究并断言的 "永动机是不可能实现的"信念。 b. His father Lazar studied and asserted that "permanent motivation is impossible to achieve" belief.
c 、 温差作功的思想。 "单独提供热不足以给出推动力, 必须还要有冷, 没有冷, 热将是无用的"。 c, the idea of temperature difference work. "The heat provided alone is not enough to give a driving force. It must be cold, no cold, and heat will be useless."
d 、 最大值思想。 他把热机比作水轮机, 认为与水轮机依赖于水位差和 水量一样,热机的动力依赖于温度差和转移的热质,他说: "每种情况都有一 个最大值, 一方面不管水作用的是什么机器, 另一方面也不管热所作用的物 质, 我们总不能超过这个最大值"。 d, the maximum idea. He compared the heat engine to a water turbine. He believes that the turbine relies on the difference in water level and water volume. The power of the heat engine depends on the temperature difference and the heat quality of the transfer. He said: "Every situation has a maximum value, regardless of the action of water. What kind of machine, on the other hand, regardless of the substance of heat, we can't exceed this maximum."
e 、 不可逆思想。 从高温向低温所发生 "热质降落" "再完成相反过程, 这是不可能的了"。 e, irreversible thinking. "Hot quality drop" occurs from high temperature to low temperature. "It is impossible to complete the reverse process."
这些基本思想 ( b )、 ( e )、 ( d ) 竟是热力学第一定律、 第二定律、 以及卡诺定律的刍型。不能不承认这位天才的年轻人是经典热力学的奠基人, 但可悲的是在当时的社会里, 他在世唯一公开发表的著作, 在十一年内一本 也未卖出,那个被恩克斯称之为 "美丽的平行四边形 "的卡诺循环示意图(图 7 ) 还是这位 36 岁就英年早逝的天才死后二年由克拉珀龙所绘, 用绝对温 度来表达的式子 η ^ 1 -T Τ,是开尔文最后完成的。任何历史人物都会有受 时代限止的认识错误,—卡诺他们也不例外: ① 卡诺理论发端于热质说, 在 对热功转换的本质认识上至今还有热质说的影响, ② 由于当时尚未有熵理 论作指导, 以至卡诺的"理想热机"模式并不理想, ③ 研究方式有误 ④ 结 论的适用有误。 These basic ideas (b), (e), (d) are actually the first law of thermodynamics, the second law, and the type of Carnot's law. Can't help but admit that this genius young man is the founder of classical thermodynamics, but sadly in his society at the time, his only published work in the world was not sold in eleven years, that was the Enx The Carnot cycle diagram (Fig. 7), which is called the "beautiful parallelogram", is also the expression of the absolute temperature when the 36-year-old genius who died young is painted by Craperon two years after his death. ^ 1 -T Τ, was the final completion of Kelvin. Any historical figure will have a cognitive error that is limited by the times. - Kano is no exception: 1 Carnot theory originated from the heat theory, and there is still the influence of heat quality on the understanding of the nature of heat work conversion. 2 Because At that time, there was no entropy theory to guide, and even Kano’s “ideal heat engine” model was not ideal. 3 The research method was wrong. 4 The conclusion was incorrectly applied.
2 .3.1 卡诺之错在于当时流行的热质说, 使他对热功转换的本质认识有- 误因为热质说把热功转换称"热质降落", 这使它可以与瀑布一比, 把温度差 比作高度差, 诞生了温差作功的理念。 但实际上热和功的本质之别, 仅仅是 粒子的运动有无共同方向。 有, 则可以得到机械功或电能。 无, 则是热能。 因此从分子运动论的视角看, 热功转换本质仅仅是纠正粒子的运动方向, 使 其一致而已, 卡诺热机是用汽缸限制了其他方向的膨胀, 只留下活塞方向可 以膨胀的办法, 收获一致的, 这在当时很了不起, 可以说这在人类历史上有 划时代的意义, 火、 功、 电三者的获得都让人类历史有重大转折, 开创了新 时代。 也正因为 "膨胀作功"带来的欣喜。 以至卡诺说 "产生最大动力的必 要条件是, 在实现热的动力的物体中, 不应该存在任何不是由于体积变化而
引起的温度变化" 【注 23】这个 "温度变化"就是指热辐射、 传导、 摩擦 等浪费掉的热量。 可以看到卡诺当时还不知因工质膨胀而产生的熵增。 当时 的认识水平, 人们还不懂得熵增是什么。 后面的阐述让我们知道, 如果没有 温差存在, 也可以由力场变化来更有效的纠正方向, 而力场变化所作的功被 保存在方向一致后的功的增量中, 以至力场仅仅是这一转变的条件而并无消 耗, 这一新的理念让我们跃出了温差作功的桎桔。 2.3.1 Kano's fault lies in the popular heat quality theory at that time, which made him understand the nature of heat work conversion. - Because the heat quality said that the heat work is called "thermal mass drop", which makes it comparable to the waterfall. The temperature difference is compared to the height difference, and the idea of temperature difference work is born. But in fact, the essence of heat and work is only the common direction of the movement of particles. Yes, you can get mechanical work or electrical energy. No, it is heat. Therefore, from the perspective of molecular motion theory, the essence of thermal power conversion is only to correct the direction of particle motion, so that it is consistent. The Carnot heat engine uses cylinders to limit the expansion in other directions, leaving only the way the piston can expand. Consistent, this was great at the time. It can be said that this has epoch-making significance in human history. The acquisition of fire, power and electricity has made a major turning point in human history and created a new era. It is also because of the joy of "expansion work". So Kano said, "The necessary condition for generating maximum power is that in an object that achieves thermal power, there should be no such thing as not due to volume change. The temperature change caused by "Note 23] This "temperature change" refers to the heat that is wasted by heat radiation, conduction, friction, etc. It can be seen that Kano was still unaware of the increase in entropy due to the expansion of the working fluid. People still don't know what entropy is. Later, let us know that if there is no temperature difference, the force field can be changed to correct the direction more effectively, and the work done by the force field is saved in the same direction. In the increment, even the force field is only the condition of this transition without consumption. This new concept makes us jump out of the temperature difference.
从熵理论看热机作功就是某系统熵减的过程, 即系统中有一部分无序变 成了有序, 其本质完全不同于瀑布, 瀑布的比喻在热质说被废后则完全不能 再用, 它是势能向动能的转化, 在没有摩擦的理想境界, 势、 动能的转换效 率应该是 r = l, 与热功转换的规律没有共性, 当年卡诺却认识不到, 他运用 瀑布比喻称超过这个结论就是无中生有了。 被比喻的热机有瀑布一样的 100 From the entropy theory, the work of the heat engine is the process of entropy reduction of a system, that is, a part of the system becomes disordered, and its essence is completely different from the waterfall. The metaphor of the waterfall can no longer be used after the thermal theory is abolished. It is the transformation of potential energy into kinetic energy. In the ideal state without friction, the conversion efficiency of potential and kinetic energy should be r = l, and there is no commonality with the law of thermal power conversion. When Carnot did not know it, he used the waterfall metaphor. More than this conclusion is that there is nothing. The metaphorical heat engine has the same waterfall 100
%的效率, 才让大家承认它是理想热机, 正如大家知道的那样, 卡诺定律就 是用热质说和第一定律雏形来证明。 % efficiency, let everyone admit that it is the ideal heat engine, as you know, Carnot's law is proved by the thermal theory and the prototype of the first law.
热和功的转化有它自己的规律。 (1 ) 无序不会自发转变成有序。 (2 ) — 旦某个条件成就,无序可以转化为有序,也就不在乎无序处于常温还是高温。 热向功转换只有二个条件, (1) 必须诞生有序 (2 ) 必须截获或导出有序。 至 于效率可以在零到一之间, 不应该受温差作功规律的制约。 温差诞生有序, 只是 "某个条件"下的一种, 其规律不能以偏盖全。 The conversion of heat and work has its own laws. (1) Disorder does not spontaneously change into order. (2) — Once a condition is achieved, disorder can be transformed into order, and it does not matter whether the disorder is at normal temperature or high temperature. There are only two conditions for the conversion of heat to work, (1) must be born in order (2) must be intercepted or derived orderly. As for efficiency, it can be between zero and one, and should not be restricted by the law of temperature difference. The temperature difference is born in an orderly manner, just a kind of "a certain condition", and its law cannot be completely partial.
上面所说的 "其规律" 当然就是指卡诺得到的理想热机的效率公式。 不 能以偏盖全是指, 二个等温二个绝热的卡诺模式在热质说被废后, 就再无理 由称热功转换中的最佳模式。 The "rule" mentioned above is of course the efficiency formula of the ideal heat engine that Carnot obtained. It is impossible to use the partial cover. The two isothermal two adiabatic Carnot modes are no longer called the best mode in the conversion of thermal power after the thermal mass is discarded.
2 . 3 . 2 卡诺热机是改变容积作功,都在工质受热膨胀的情况下得到"功" 的, 都有一个工质膨胀的问题。 卡诺循环的 cd过程 (图 7 ) 目的要解决工 质的膨胀问题。 用外界作功、 等温压缩的过程来解决问题, 的确收到了体积 从 c到 d的结果, 但外界作功、 冷源收热是一个功变热, 有序变无序的熵增 过程, 与热机的尽可能多获取负熵的宗旨有悖。 所谓理想热机不是过程没有 摩擦就行, 还要从过程的模式考量是否理想说卡诺热机不可能是最理想的热 机,是从其设计的方案中看到 cd过程,这一胎记毛病,后面介绍的没有 cd 正 熵过程的三维循环就比它有更高的效率。 2 . 3 . 2 Carnot heat engine is to change the volume of work, both in the case of the thermal expansion of the working medium to get "work", there is a problem of working fluid expansion. The cd process of the Carnot cycle (Fig. 7) aims to solve the problem of expansion of the process. Using the process of external work and isothermal compression to solve the problem, it has indeed received the result of volume from c to d, but external work, cold source heat is a work heat, orderly change disorder entropy increase process, and The purpose of getting the negative entropy as much as possible for the heat engine is flawed. The so-called ideal heat engine is not a process without friction. It is also necessary to consider whether the Carnot heat engine is the most ideal heat engine from the model of the process. It is the cd process seen from its design scheme. This birthmark is described later. A three-dimensional loop without a cd positive entropy process is more efficient than it.
2 . 3 . 3 卡诺的 "二个无限"的假设, 使它的结论失去了理论上的指导意 义。 2 . 3 . 3 Kano's "two infinite" hypothesis makes its conclusion lose its theoretical guiding significance.
第一个 "无限缓慢"的假设已经有人作了抨击。他们是柯曾(F . L .curzon) 和阿尔博恩 (B . Ahlborn) 在 1975年最先注意到这个 "无限缓慢的循环"功 率会接近于零 [注 24], 没有功率输出的热机有什么意义呢? 失去了研究的必 要! 他们推得最大输出功率时的效率为 η 1一 0 / ΤΗ),/2 与卡诺的结论相差
很大, 假设高温是 1600K, 低温是 4Ό0Κ, 则卡的结论是 75 %而柯与阿的结 论只有 50 %差 25 % , 而 75 %的结论是 "功率接近于零的热机的结论 "没有 现实意义, 似乎不必去关注。 The first "infinitely slow" hypothesis has been attacked. They were Ke Zeng (F. L. curzon) and Alborn (B. Ahlborn). In 1975, they first noticed that this "infinitely slow cycle" power would be close to zero [Note 24 ]. There is no heat output for the heat engine. What is the point? Lost the need for research! The efficiency at which they push the maximum output power is η 1 - 0 / Τ Η ) , and /2 differs from Carnot’s conclusion. Very large, assuming a high temperature of 1600K, a low temperature of 4Ό0Κ, then the card's conclusion is 75% and the conclusion of Ke and A is only 50% 25%, and the conclusion of 75% is "the conclusion that the power is close to zero." Meaning, it seems that there is no need to pay attention.
第二个 "无限大冷源" 的假设遮盖了循环越出孤立系统的事实, 循环实 际上是在闭口系统中进行的。 我们发现: ①如果没有冷源, 压縮的结果只能 是沿着 cb 绝热线返回, 成不了循环。 ②冷源小了, 由第一定律可知冷源必 然升温, 这使外界"有变化"。 ③只有 "无限大冷源", 才使升温变得无限小, 外界的升温被掩盖, 达到了 "无变化" 的结果。 但由于有边界的孤立系统装 不下 "无限大的冷源", 也就是说无法回到孤立系统中讨论, 因此可以说 cd 过程不断向外界扔废热的过程, 实际上是在有热量转换的闭口系统内进行。 不再具备原来希望具有的意义——结论诞生于 "孤立系统" ! The hypothesis of the second "infinite cold source" obscures the fact that the loop is out of the isolated system, and the loop is actually carried out in a closed system. We found that: 1 If there is no cold source, the result of the compression can only be returned along the cb adiabatic line, which cannot be recycled. 2 The cold source is small. It is known from the first law that the cold source must heat up, which makes the outside world "changed." 3 Only the "infinite cold source" makes the temperature rise infinitely small, and the external temperature rises up, and the result of "no change" is achieved. However, because the isolated system with borders can't fit the "infinite cold source", that is to say, it can't be discussed in the isolated system. Therefore, it can be said that the cd process continuously throws waste heat into the outside world, actually in the closed state with heat conversion. In the system. No longer have the meaning that the original hope has - the conclusion was born in the "isolated system"!
如果我们放弃使用 "无限大"冷源的假设, 加进一个不断清除废热的过 程而从闭口系统回到孤立系统, 那结论就完全不可能达到 n i—T T,这个 理论上限, 而是更小, 这一式子的原意是理想热机使用等号, 而真实热机使 用小于号, 既然孤立系统里得不到理想热机这个上限, 即要放弃式子中的等 号, 这使卡诺理论在基础处出现崩塌。 崩塌从两个方面说: 首先按他方案设 计的热机, 即使在 "理想" 的层面上也根本到不了预定上限。 它让等于号失 效了。 第二, 其它模式一有负熵流参与的过程 (后面专谈) 又能够不受他上 限的限止, 又让小于号失效。 这就使卡诺的研究失去了意义。 究其原因, 不 仅因为卡诺模式有一个并不高明的 cd 过程, 而根本原因又根植于那个时代 对热功转换的本质了解不够。 If we abandon the assumption of using "infinite" cold source, add a process of continuously removing waste heat and return to the isolated system from the closed system, then the conclusion is completely impossible to reach ni-TT, the theoretical upper limit, but smaller, The original meaning of this formula is that the ideal heat engine uses the equal sign, and the real heat engine uses the less than the number. Since the upper limit of the ideal heat engine is not obtained in the isolated system, the equal sign in the equation is discarded, which causes the Carnot theory to appear at the foundation. collapse. The collapse said from two aspects: First, the heat engine designed according to his plan, even at the "ideal" level, could not reach the predetermined upper limit. It makes the equal sign invalid. Second, the other modes, the process of participating in the negative entropy flow (later), can be free from the upper limit and invalidate the less than. This made Kano's research lose its meaning. The reason is not only because the Carnot model has an unclear cd process, but the root cause is rooted in that era.
[ 0 091 ] 2 . 3 . 4 上面分析让我们得知, 因原设计的胎疾 η 1一 T,/ T,的效率 公式并不能称热功转换的最高效率, 只能是 2 个等温 2 个绝热的卡诺热机 - ^严格的说只能是功率接近于 0 的卡诺热机在闭口系统里运行的结论― 一一个没有理论指导意义的一般结论。 [ 0 091 ] 2 . 3 . 4 The above analysis let us know that the efficiency formula of the original design of fetal disease η 1 -T, / T, can not be called the highest efficiency of thermal power conversion, only 2 isothermal 2 The adiabatic Carnot heat engine - ^ strictly speaking only the conclusion that the Carnot heat engine with power close to zero runs in the closed system - a general conclusion without theoretical guidance.
如果我们摆脱热质说和 "卡"、 "开"的错误, 不仅仅局限于 "温差作功" 的思维定势, 将负熵过程嵌入热机, 结果会完全不一样, 今天耗散结构理论 列举的负熵案例己被公认, 我们只要再进一步说明其诞生机制, 就能得到真 正的理想热机和新的热功转换规律。 而这需要用更为宽泛的视角来看问题。 If we get rid of the thermal theory and the "card" and "open" mistakes, not only limited to the "temperature difference work" mentality, the negative entropy process is embedded in the heat engine, the result will be completely different, today's dissipative structure theory enumeration The case of negative entropy has been recognized. As long as we further explain its birth mechanism, we can get the true ideal heat engine and the new heat work conversion law. And this requires a broader perspective to look at the problem.
3 、 负熵诞生的机制 3. Mechanism of birth of negative entropy
3 . 1 、 由力场引起的 "最小能原理"可与熵增共辘 3. The "minimum energy principle" caused by the force field can be increased with entropy.
耗散结构理论列举了大量负熵实例, 并称称只要负熵流的绝对值大于熵 产生, 就能得到负熵。 我们认为这一说法与负熵诞生的最终机制破译仍有距 离, 而 "问题依然存在" 的原因是耗论并未涉及熵增律的适用范围。 The theory of dissipative structure lists a large number of examples of negative entropy, and it is said that as long as the absolute value of the negative entropy flow is greater than the entropy, negative entropy can be obtained. We believe that there is still a distance between this statement and the final mechanism for the birth of negative entropy, and the reason that the problem still exists is that the theory of consumption does not involve the application of the law of entropy.
人们把熵增律看作状态的唯一规律,将其完全等同不可逆规律是一个不小
的错误。世界是多维的, "不可逆"包含多种有势差的过程, 熵增律无疑是一 个走向自身 "劫底"——熵极大的规律, 但不是状态的唯一规律, 粒子走向 最小势能的规律完全可以与之共轭,有着同样广泛的适用范围。 "最小能"原 理可以从原子核的构建谈起。 People regard the law of entropy increase as the only law of state, and it is not a small matter to completely equate it with irreversible law. mistake. The world is multidimensional, "irreversible" contains a variety of processes with potential differences. The law of entropy is undoubtedly a law of "robbing the bottom" - the law of entropy is great, but it is not the only law of state, the law of particles going to minimum potential energy It can be fully conjugated and has the same wide range of applications. The principle of "minimum energy" can be discussed from the construction of the nucleus.
我们知道自由质子与中子结合成原子核时要放出能量。反之要使原子核分 裂为自由质子和中子时需要外加同样多的能量, 能量 ΔΕ 就称为结合能, ΔΕ与质量数 (核子数) 与之比就是平均结合能, 平均结合能愈大原子核就 愈稳定, 人们发现质量数为中等的数值 (铁、 镁、 铜) 其平均结合能最大, 平均为 8 . 6MeV 这就很好地解释了为什么重核的裂变和轻核的聚变都能放 出巨大能量, 原来它们都在朝中间走——趋向最为稳定核的状态劫底! We know that free protons and neutrons emit energy when they are combined into nucleus. On the contrary, when the atomic nucleus is split into free protons and neutrons, the same amount of energy needs to be added. The energy ΔΕ is called binding energy, and the ratio of ΔΕ to mass number (nuclear number) is the average binding energy. The larger the average binding energy is, the larger the atomic nucleus is. The more stable, the higher the mass (iron, magnesium, copper) is found to have the highest average binding energy, with an average of 8.6 MeV. This explains why the fission of heavy nuclei and the fusion of light nuclei can be released. Energy, it turns out that they are all moving towards the middle - the state of the most stable nuclear state!
再看原子的构成,由泡利不相容原理计算得到的各壳层可能的最多电子数 为 2n2, 对于 K、 L、 M、 N ······各层最多分别可容纳 2、 8、 18、 32 ··· ···个 电子。 当原子形成分子时, 又以外层为 8个电子的惰性元素的构型为劫底。 电子处于较高能级时, 总是伺机返回它的稳定态, 2n2、 八隅律…… 这些宇 宙大爆炸后就起作用的 "状态规律"让我们吃惊的发现, 宇宙在组建万物的 基石 ——元素时, 就不是简单的走向无序、 走向熵极大, 而是十分的有序! 能量最小原理、 能量按自由度平均分配的规律、 速率按麦克斯韦曲线分 布的规律。 这些大家熟知的涉及粒子和它所携能量的分布规律都应是状态规 律, 包括熵增律在内的这些 "状态规律"都在各自自发地走向各自的劫底, 从而带来能量的转换、 带来有序。 孔子曾感慨江河在走向势能最低的大海时 是那样的 "不舍昼夜"。 大自然这种互为始、 终的 "多维循环"比西方一唯追 求 "第一椎动力" 的哲学思维深邃得多。 我们在文章的最后会悟得 "各种形 式的能量因循环而互为能源"! "能无源、 唯循环"六个字是本文主题, 不管 什么形式能量的获得, 都不过是人类在某个循环中成功的截获, 原来意义上 的能源二字, 不过是地球村蒙昧时期的方言。 Looking at the composition of the atom, the maximum number of electrons possible for each shell calculated by the Pauli exclusion principle is 2n 2 , and for each layer of K, L, M, N ······ 8, 18, 32 ······E-electronics. When an atom forms a molecule, the configuration of an inert element having an outer layer of 8 electrons is a ruin. When the electron is at a higher energy level, it always waits for an opportunity to return to its steady state, 2n 2 , and the Eight Laws... These "state laws" that worked after the Big Bang surprised us to discover that the universe is the cornerstone of everything. - When you are an element, you are not simply going to disorder, going to entropy, but being very orderly! The principle of minimum energy, the law of equal distribution of energy according to degrees of freedom, and the rate of distribution according to the Maxwell curve. These well-known laws concerning the distribution of particles and the energy they carry should be state laws. These "state laws", including the entropy increase law, spontaneously move toward their own ruins, thus bringing about energy conversion. Bring orderly. Confucius once felt that the river was such a "not staying up late" when it came to the sea with the lowest potential energy. The "multidimensional cycle" of nature, which is the beginning and the end of each other, is much deeper than the philosophical thinking of the West, which pursues the "first wave of power". At the end of the article, we will realize that "all kinds of energy are mutually energized by circulation"! The six words "passive, only cycle" are the subject of this article. No matter what form of energy is obtained, it is just a successful interception of human beings in a certain cycle. The original word of energy is just a dialect of the global village. .
3 . 2 、 状态方程应该是 n。= Mg / 4 π r 2KT 经典热力学中最基本的是状态方程、 内能和熵, 其它热力学函数都可以 从这三个基本函数导出。 可惜状态方程中没有考虑力场的作用。 与上述核、 电相比, 万有引力是四种力中的最弱的力, 但它仍能左右熵变。 波尔兹曼的 式子 n = nQe- mgh / KT 中没有说到 n。由哪些因素决定, 而状态方程 P = n。KT 中的 η。也没有考虑到地球引力场的存在。 大气压是大气总重量 Mg 除以地 球表面积 4 π r 2而得到,所以有 Ρ = ]ν¾ / 4 π r 2这个 P 应与状态方程中的
P相等就有 n。KT = Mg / 4 Ji r 2 ,即 η。二 Mg / 4 π r 2ΚΤ ,这方程比 nQ= 3. 2, the equation of state should be n. = Mg / 4 π r 2 KT The most basic of classical thermodynamics is the equation of state, internal energy and entropy. Other thermodynamic functions can be derived from these three basic functions. Unfortunately, the role of the force field is not considered in the equation of state. Compared with the above nuclear and electric, universal gravitation is the weakest force among the four forces, but it can still influence the entropy change. Boltzmann's formula n = n Q e- m g h / KT does not say n. Which factors determine, and the state equation P = n. η in KT. Nor did it take into account the existence of the Earth's gravitational field. Atmospheric pressure is obtained by dividing the total weight of the atmosphere by Mg by the surface area of the earth by 4 π r 2 , so there is Ρ = ]ν3⁄4 / 4 π r 2 This P should be in the equation of state P is equal to n. KT = Mg / 4 Ji r 2 , ie η . Two Mg / 4 π r 2 ΚΤ , this equation is better than n Q =
P / KT状态方程就更全面了, 也就是说 η。由四个因素决定, 其中 M、 g、 r 三因素不变, 所以 ίΐ。仅与 T成反比。 T大 nQ变小, 是膨胀, T小 n。变大, 是收缩, 这是大家知道的。 但我们假设 M和 g也能变, 那么 g或 M变大时 n。也变大, 相反 nQ变小。 也就是说促使 n。变小的膨胀还可以由 T之外的其 他二个因素决定, 这让我们多了一份遐想。 图 8 中等温线族与大气压 P = l 的交点 0、 0、、 0、、 对应的横坐标 V。、 V V 2就是该温度在地球这个力场 中的当有体积。 The P / KT equation of state is more comprehensive, that is, η. It is determined by four factors, among which M, g, and r are the same, so ίΐ. It is only inversely proportional to T. T large n Q becomes smaller, is expansion, T is small n. It is big, it is shrinking, this is everyone knows. But let's assume that M and g can also change, then n when g or M becomes larger. It also becomes larger, and instead n Q becomes smaller. That is to say n. Smaller expansion can also be determined by two other factors beside T, which gives us a more delusion. Figure 8 The horizontal axis V of the intersection of the intermediate temperature line family and the atmospheric pressure P = l at 0, 0, 0, and . VV 2 is the volume of this temperature in the Earth's force field.
凡 P = l 直线以上的任一点都有膨胀的趋势。 要沿等温线膨胀到与 P = 1 的交点上, 与当有体积对应。 这一过程是熵增过程 ( V 变大)。 Any point above the P = l line has a tendency to swell. It is necessary to expand along the isotherm to the intersection with P = 1, corresponding to when there is volume. This process is the entropy increase process (V becomes larger).
我们过去并不注意 P = 1 直线以下任一点都有延等温线回归到与 P = 1 这直线交点的趋势。 因为它不自然存在, P = l 的以下诸点都有表现为被迫 收縮的行为, 即温度不变, 只是体积缩小了, 熵减了。 这二个现象是整个大 气与地球引力场有一非平衡定态所至, 用普利高津描写 "最小熵产生" 的话 来说, 凡是离开非平衡定态的 "小小扰动"最终都会自发地回到非平衡定态 上来。 能够证明这一规律的现象就是每摩尔气体在标准情况下都有 22.4 升 这个事实,不管离开这个体积的原因是什么,也不管是大于还是小于原体积, 它都要返回, 而不管返回时熵增还是熵减。 大家知道熵增的动力来自走向紊 乱——走向最可几状态的不可逆性, 而这里的负熵的动力来自走向势能最低 处, 同样具有不可逆性, 而且因为有力场背景, 显得十分强劲, 它们各自独 立作用, 走向各自的平衡点, 决不自行停歇。 非平衡定态是双方势均力敌的 结果。 We have not noticed in the past that P = 1 has any tendency to extend the isotherm back to the intersection with the line P = 1. Because it does not exist naturally, the following points of P = l have the behavior of being forced to contract, that is, the temperature is constant, but the volume is reduced, and the entropy is reduced. These two phenomena are caused by a non-equilibrium steady state of the whole atmosphere and the gravitational field of the earth. In the words of "the minimum entropy production" described by Prigogine, any "small disturbance" that leaves the unbalanced state will eventually spontaneously return. Go to the non-equilibrium steady state. The fact that this law can be proved is that the fact that every mole of gas has 22.4 liters in standard conditions, regardless of the reason for leaving this volume, whether it is larger or smaller than the original volume, it must return, regardless of the entropy at the time of return. Increase or entropy reduction. Everyone knows that the power of entropy increases from the chaos to the most irreversible state, and the negative entropy here comes from the lowest potential energy, which is also irreversible, and because of the strong field background, it is very strong, they are each Independently, go to their respective balance points and never stop for themselves. Non-equilibrium steady state is the result of equal integration between the two sides.
下面假设 g为可变,那么 n。= Mg / 4 π r 2ΚΤ中膨胀现象就不仅仅在 Τ 变化 (增高) 时出现了, 在力场变化 (变小) 时也能出现, 这不是启迪我们 可以利用力场变小引起的膨胀作功, 它可以在不加热升温的情况下靠内能降 低作功, 是的, 控制力场的变化与控制温度的变化一样也能带来有序, 而让 活塞截获膨胀带来的有序,就能得到机械功!这是该式子带来的第一个启示。 Let's assume that g is mutable, then n. = Mg / 4 π r 2 The expansion phenomenon in ΚΤ occurs not only in the Τ change (increased), but also in the force field change (smaller). This is not the enlightenment that we can use the force field to become smaller. Work, it can reduce the work without heating up, and the change of the control force field can bring order just like the change of the control temperature, and let the piston intercept the expansion. , you can get mechanical work! This is the first revelation brought by this formula.
第二个启示是原来作为熵增现象而广为举例的自由膨胀, 不过是 g为零 的时候的一个特例, (g→0 , n()→0 ) , 也就是说在有地球引力场的情况下,
最小能原理与熵增共同作用, 才导致气态方程这个规律的建立, 熵增不在是 没有条件的行为, 熵增、 熵减、 熵极大的出现都有一定条件。 The second revelation is the free expansion that was originally exemplified as the entropy increase phenomenon, but a special case when g is zero, (g→0, n() →0), that is, in the presence of the Earth's gravitational field. In case, The combination of the minimum energy principle and the entropy increase leads to the establishment of the law of the gas equation. Entropy increase is not an unconditional behavior. Entropy increase, entropy decrease, and entropy maximization have certain conditions.
产生上述现象的原因是最小能原理这个状态规律, 它要求粒子尽可能地 到势能最小处活动, 从原子的组成到大气的状态都服从这一规律, 原子系统 在正常状态下, 各电子趋向尽可能占有最低能级。 电子壳层的填充就是以最 低能级壳层开始, 然后依次向能级较高的能级发展。 如因某个原因跃迁到了 高能级, 它会发出相应电磁波而回到低能级。 大气则既要遵循膨胀、 扩散、 最大程度紊乱的熵增律, 又要遵循收縮、 集合、 最大限度的回到势能最小处 的最小能原理, 大气的状态是两者共同作用的结果。 P =l以上的任一点都有 膨胀到平衡点的趋向, 是正熵区, P = 1以下的任一点大气都有回平衡点的 趋向, 是负熵区。 我们看到熵增熵减都在一定条件下实现, 而力场这个条件 却是无处不在、 无时不在的, 没有力场倒是个特例, 是一个更苛克的条件, 因此可以说, 原来只有熵增存在的片面看法是经典理论遗漏了以力场为动力 的能量最小原理这个重要因素。 找回这个因素将在 "更好的三位循环"得到 体验。 The reason for the above phenomenon is the state law of the minimum energy principle, which requires the particles to move as far as possible to the minimum potential energy. The law from the composition of the atom to the state of the atmosphere obeys this law. Under normal conditions, the electrons tend to be exhausted. May have the lowest energy level. The filling of the electron shell begins with the lowest energy level of the shell and then proceeds to the higher energy level. If for some reason it transitions to a high energy level, it will emit a corresponding electromagnetic wave and return to the low energy level. The atmosphere must follow the entropy increase law of expansion, diffusion, and maximum disorder, and follow the principle of minimum energy that shrinks, gathers, and returns to the minimum potential. The state of the atmosphere is the result of the combination of the two. Any point above P = l has a tendency to expand to the equilibrium point, which is a positive entropy region. At any point below P = 1, the atmosphere has a tendency to return to equilibrium, which is a negative entropy region. We see that the entropy entropy reduction is achieved under certain conditions, and the force field is ubiquitous and omnipresent. The lack of force field is a special case and a more harsh condition. Therefore, it can be said that Only the one-sided view of the entropy increase is that the classical theory misses the important principle of the energy minimum principle powered by the force field. Retrieving this factor will be experienced in the "better three-digit loop."
如果没有力场存在, 原子核无法组成, 元素更无法诞生, 一切也无从谈 起。 如果说这个时候熵增律主宰, 那我们并不反对。 If there is no force field, the atomic nucleus cannot be formed, the element can not be born, and nothing can be said. If we say that the entropy law is dominant at this time, then we are not against it.
3 . 3 、 强力场改变自由度诞生结构热 3 . 3 , the strong field changes the degree of freedom birth structure heat
由 "内能"的定义告诉我们, 内能是分子总数与每个分子平均动能的乘 积, E =Ν ε k即 E= iv RT 12 而熵值决定于 S =Q / T ,把 Q = ST代入前一 式子得 ST = v RT i/2 g卩 S = i v R / 2 因为 v R / 2 为常数,也就是说熵The definition of "internal energy" tells us that internal energy is the product of the total number of molecules and the average kinetic energy of each molecule, E = Ν ε k ie E = iv RT 12 and the entropy value is determined by S = Q / T, Q = ST Substituting the previous expression ST = v RT i/2 g卩S = iv R / 2 because v R / 2 is a constant, that is, entropy
S 直接随自由度 i 的增减而增减。这很容易理解, 正如教课书解释自由膨胀 的熵增一样, 自由度的增加直接提供了紊乱的更大可能, 所以 i 变大发生熵 增。 而 i 变小能发生熵减——这就提供了负熵诞生的可能。 这使我们能得到 在 Q不变的孤系中, 因 i 变小(S变小)而 T升的结果, 这温升既不来自作 功、 又不来自热传导, 而是仅仅因为自由度变小而升温, 是结构热。 这在自 然界中是可以观察到的, 大雾变雨的时候能清晰观察到相变放热这一自发升 温的现象。 这现象在热泵的冷凝器放热中被成功复制, 以至热泵在热端放出 的热量高于压縮机作功放出的焦耳热的几倍。 这在前面启示中已经阐明, 他 应该是获取热能的最佳方法。 只是热泵的机理是外力促成, 由外界提供变化 的条件, 而大自然的成雨过程是靠自然界的自行耦合, 但机理却是一样的。 -从根本上说结构变化引起的熵变都是各层次的力场所引起, 是力场增强或减 弱到一定程度, 才出现自由度的突变。 S increases or decreases directly with the increase or decrease of the degree of freedom i. This is easy to understand. Just as the textbook explains the entropy increase of free expansion, the increase in freedom directly provides a greater possibility of disorder, so i becomes larger and entropy increases. And when i becomes smaller, entropy reduction can occur - this provides the possibility of the birth of negative entropy. This allows us to get the result of T liters in the unchanging lone system, because i becomes smaller (S becomes smaller), and this temperature rise is neither from work and heat conduction, but only because of the degree of freedom. Small and warm, it is structural heat. This can be observed in the natural world. The phenomenon of spontaneous warming of phase change exotherm can be clearly observed when the fog is raining. This phenomenon is successfully replicated in the heat release of the heat pump condenser, so that the heat pump discharges heat at the hot end several times higher than the Joule heat released by the compressor work. This has been stated in the previous revelation that he should be the best way to get thermal energy. Only the mechanism of the heat pump is the external force, and the changing conditions are provided by the outside world. The natural rain process is self-coupling by nature, but the mechanism is the same. - Fundamentally speaking, the entropy change caused by structural changes is caused by the force of each level. It is the sudden increase or decrease of the force field to a certain extent.
温熵图(图 9 )中 abed 与 a b ' e ' d '是二块面积相等的 A态和 B态,
也就是说八、 B两态所含热量相等., 温度分别为 TV和 Τ2。 由 Β态变成 Α态 是正熵过程 (8,至 S2) 由 A态变成 B 态则是负熵过程, 熵 变成 S2 、 温度就可以从 η上升到 T2, S,变成 S2是熵减过程, 是热二律所不能允许的, 但却在自由度变化的这个条件下出现了。 这也不难理解, 热能的量不变, 平 均分配的单位却少了, 每个单位就能多分, 动能多了, 温度也就高了。 这是 既不靠热传导从温度高处传来, 也不靠作功, 是靠自由度变化来而获得热能 的好办法。 在雷电的形成过程中, 也有类似这温升的现象——产生电势上升 的现象。 To^E/i式子与电学公式 U q/C有可以类比的逻辑结构。 雷电在形 成的时候各带电云块并作一统时云层表面积反而相对缩小而电容变小。 一旦 大雨离云而降, 电容量 c再降, 云层的电势 U就会因此而激增, 引成几十万 伏的高压电, 诞生电势差异的过程, 与气体液化时升温是同一个机理一一由 结构变化产生的负熵过程, 电容和自由度的变化起的作用相同。 这就是说自 然界中产生势差、 梯度不需要第一推动力。 结构热, 包括各层次粒子回到最 为稳定的结构时放出热量是各层次供热的重要来源。 In the temperature entropy graph (Fig. 9), abed and ab ' e ' d ' are two A-states and B-states with equal areas. That is to say, the two states of B and B contain the same amount of heat. The temperatures are TV and Τ 2 respectively. From the Β state to the Α state is the positive entropy process (8, to S 2 ). The change from the A state to the B state is a negative entropy process, the entropy becomes S 2 , and the temperature can rise from η to T 2 , S. S 2 is an entropy reduction process that is not allowed by the thermal law, but it occurs under the condition that the degree of freedom changes. It is not difficult to understand that the amount of heat energy is constant, the unit of average distribution is less, each unit can be multi-pointed, the kinetic energy is increased, and the temperature is high. This is a good way to obtain heat from the high temperature without relying on heat conduction, and not relying on work. In the formation of lightning, there is also a phenomenon similar to this temperature rise - the phenomenon of rising potential. The To^E/i expression has an analogous logical structure with the electrical formula U q/ C. When the lightning is formed, each of the charged clouds is unified and the surface area of the cloud layer is relatively reduced and the capacitance is reduced. Once the heavy rain falls from the cloud, the capacitance c drops again, and the potential U of the cloud layer will increase sharply, leading to hundreds of thousands of volts of high-voltage electricity. The process of generating the potential difference is the same mechanism as the temperature rise during gas liquefaction. A negative entropy process resulting from structural changes, the same effect of capacitance and degree of freedom. This means that the potential difference is generated in nature, and the gradient does not require the first driving force. Structural heat, including the release of heat from all levels of particles back to the most stable structure, is an important source of heat for all levels.
3 . 4 力场带来位能的概念, 应恢复克劳休斯对第一定律的首次表述, 即 dQ = dH + dJ + dw 3.4 The concept of potential energy in the force field should restore Claus Hughes’ first expression of the first law, ie dQ = dH + dJ + dw
1850年, 28岁的克劳休斯在获得哲学博士后的第三年, 发表了 "论热的 动力和能由此推出的热学理论的普遍规律"一文,论文认为传给物体的热量, 增量 dQ 等于物体中热量的变化 dH 、 内功的变化 dJ 和外功的变化 dW g卩 dQ = dH + dJ + dW In 1850, the 28-year-old Crow Hughes published the article "On the dynamics of heat and the general law of thermal theory that can be derived from this" in the third year after receiving a Ph.D. in philosophy. The paper believes that the heat transferred to objects is increased. dQ is equal to the change in heat dH in the object, the change in internal work dJ and the change in external work dW g卩dQ = dH + dJ + dW
他把 H 理解为物体中粒子的动能, 由温度决定, 内功 J 是由分子的 结构所决定的状态函数, 但由于不知道内功 J 的确切表示, 所以又引入一个 新的物理量 U 来表示 H 和 J 的和, 从而把能量守恒定律写成热力学第一 定律的形式 dQ=dU+dW—年后开尔文称 U 为内能。 He understands H as the kinetic energy of particles in an object, which is determined by temperature. The internal work J is a state function determined by the structure of the molecule. However, since the exact representation of the internal work J is not known, a new physical quantity U is introduced to represent H and The sum of J, thus writing the law of conservation of energy as the first law of thermodynamics dQ = dU + dW - after years Kelvin called U as internal energy.
克劳休斯关于第一定律的最初表述,反而是正确的。到现在我们才知道, 能量的形式从现象上分可以是电能、 光能、化学能、机械能、 原子能和热能。 而从本质上分, 能量的转化分 2 个方面。爱因斯坦的质能公式 E = mc2反映 了质量和能量的关系。 而克劳休斯最初的表述 dQ = dH + dJ + dW 则反映了 不涉及 "质量亏损" 时功、 热和结构 (位能) 三者之间的关系, 也就是说在 等式左边 dQ 不变的孤系中, 能量转换的本质是等式右边的无序, 以及结构 有序、 运动有序之间的变化进行, 可以有一个 "广义的热力学"。 Clausius’s initial statement about the first law is correct. Until now we have learned that the form of energy can be divided into phenomena such as electrical energy, light energy, chemical energy, mechanical energy, atomic energy and thermal energy. In essence, the transformation of energy is divided into two aspects. Einstein's mass equation E = mc 2 reflects the relationship between mass and energy. The initial expression of Clausius dQ = dH + dJ + dW reflects the relationship between work, heat and structure (bit energy) without involving "quality loss", that is, dQ on the left side of the equation In the changed orphans, the essence of energy conversion is the disorder on the right side of the equation, and the change between structural order and motion order. There can be a "generalized thermodynamics".
a 由于短程核力非常强大, 是万有引力的 1039 倍。 所以不管裂变还是
聚变都能由结构变化释放非常大的能量。 a Because the short-range nuclear force is very powerful, it is 10 39 times of gravitation. So regardless of fission or Fusion can release very large amounts of energy from structural changes.
b 电子在原子中能级的跃迁, 吸收或放出相应的电磁波, 其可见部分被 称为光能。 b The transition of an electron's energy level in an atom, absorbing or releasing a corresponding electromagnetic wave, the visible part of which is called light energy.
C 原子组成新的分子结构, 吸收或放出的热量就是人们所说的化学能, 燃烧只是其中一种形式而已。 The C atom constitutes a new molecular structure. The heat absorbed or released is what people call chemical energy. Combustion is only one form.
d分子层面的结晶、 融解、 液化、 气化, 人们称为相变, 也因为结构变 化而放出或吸收热量。 上述四项揭示了结构与能量的关系。 经典理论仅仅只 研究 C 中结构放热 (燃烧) 转化为功这一有限部分。 而原来用 "逆卡诺循 环"解释的热泵不过是由相变吸收或放出热量的低数量级的能量转换。 Crystallization, melting, liquefaction, and gasification at the molecular level are called phase transitions, and they also release or absorb heat because of structural changes. The above four items reveal the relationship between structure and energy. The classical theory only studies the limited part of the structural exothermic (combustion) conversion into work in C. The heat pump originally explained by the "reverse Kano cycle" is simply a low-order energy conversion that absorbs or releases heat from the phase change.
有序可以是粒子有着同方向的运动,也可以是稳定的结构,二者都是熵为 零。而无序则是失去了同一方向的紊乱热运动。 当 dQ = 0 即在孤立系统中, dH 、 dJ 、 dW三者之间的转换概括了所有能量转换的本质。 由于稳定的 结构熵是零, 走向稳定的结构也就成了负熵的过程, 这一过程往往给我们带 来大量热能 (放出), 就是我们常说的 "能源 ", 强度依次为核、 原子、 分子 的结构变化。如果出现负熵的同时,表现为吸收热量,并把它藏于结构的 "更 高能级 "中,那只有负温度现象和植物的光合作用等生命现象中存在, (植物 可以把能量存入结构,再由动物把植物中的结构能变为动能)。这样让我们找 回了一个被克氏简化掉的负熵诞生的可能。 不管是熵增还是熵减都应该真实 的描写。 因此我们认为应该恢复克氏对第一定律的最初描述。 Ordering can be that the particles have the same direction of motion or a stable structure, both of which have an entropy of zero. Disorder is the loss of thermal motion in the same direction. When dQ = 0, in an isolated system, the transition between dH, dJ, and dW summarizes the nature of all energy conversions. Since the stable structural entropy is zero, the stable structure becomes a process of negative entropy. This process often brings us a lot of heat (release), which is what we often call "energy". The intensity is nuclear and atom. , structural changes in the molecule. If negative entropy occurs, it is expressed as absorbing heat and hiding it in the "higher energy level" of the structure. Only negative temperature phenomena and photosynthesis of plants exist in life phenomena. (Plant can store energy into the structure. Then, the animal can turn the structure in the plant into kinetic energy). This allows us to retrieve the possibility of a negative entropy that was simplified by Krebs. Whether it is entropy increase or entropy reduction should be described in real terms. Therefore, we believe that the original description of the first law should be restored.
3 . 5 力场带来了 "负温度"现象, 开论从此终孥 3.5. The force field brings about the phenomenon of "negative temperature".
负温度现象的出现, 按某些学者的说法是 "由于开尔文温度有不完善的 地方 25]我们认为尚不尽然。 "负温度"的命名的确有悖常理, 因为谁都知道 温度是分子紊乱热运动的平均动能的量度, 成为负值很难理解, 再说 "负温 度" 比正温度更高, 就有颠倒之感, 但名称毕竟只是一个符号, 是记忆库里 提存的编号。 命名的权利常常授予发现者。 我们无意一定要改变这个称呼, 只是探索一下它的由来, 是否有更贴切的表达。 The appearance of negative temperature phenomenon, according to some scholars, is "because of the imperfections in Kelvin's temperature. 25" We think that it is not yet true. The name "negative temperature" does have a common sense, because everyone knows that temperature is a molecular disorder thermal movement. The measure of the average kinetic energy is difficult to understand. To say that the "negative temperature" is higher than the positive temperature, there is a sense of reversal, but the name is only a symbol after all, and is the number of the memory. The naming rights are often granted. The discoverer. We do not intend to change this title, just to explore its origin, whether there is a more appropriate expression.
负温度是这样推得的: 根据热力学基本方程, 系统的温度 T 与参量 y 保持不变时熵随内能的变化率(3S /3U ) y之间存在以下关系: 1 / T = (as /9U ) y在一般系统中内能越高时,系统可能的微观状态数也愈多, 即熵随内能单调 增加, 因此温度恒正。 但也有一些系统, 当系统内能增加时熵反而减少, 这 就使温度推出负号来, 系统被称为处于 "负温度"状态, 究其原因我们觉得 这与 3.4中所说的第一定律中能量形式不含 dJ有关, 即基本方程中不反映力
反映力场和势能这个事实有关。 负温度现象中内能的增加是通过力场的增加 而获得的, 增强的是粒子在力场中的势能。如果基本方程中加进了 dJ就能客 观真实的反映事物的变化, 承认增加的不是 dH而是 dJ, dJ增加时熵减少了。 这样当力场反转时,反映势能的 dJ应有符号来表达, 以至 T就不必要再带负 了。 让真理不再别扭, 不是更好? The negative temperature is derived as follows: According to the basic equation of thermodynamics, the relationship between the entropy and the internal energy change rate (3S /3U ) y when the temperature T and the parameter y of the system remain unchanged: 1 / T = (as / 9U) y In the general system, the higher the internal energy, the more the number of possible microscopic states of the system, that is, the entropy increases monotonously with the internal energy, so the temperature is constant. However, there are also some systems. When the system can increase, the entropy decreases, which causes the temperature to push out the negative sign. The system is called in the "negative temperature" state. The reason we think this is the first law mentioned in 3.4. The medium energy form does not contain dJ, that is, the basic equation does not reflect the force. Reflecting the fact that the force field and potential energy are related. The increase in internal energy in the negative temperature phenomenon is obtained by the increase of the force field, and the enhanced potential energy of the particles in the force field. If dJ is added to the basic equation, it can objectively and truthfully reflect the change of things. It is not dH but dJ that is recognized to increase, and entropy decreases when dJ increases. Thus, when the force field is reversed, the dJ reflecting the potential energy should be expressed by a symbol, so that T is not necessarily negative. Let the truth not be awkward, is it better?
负熵现象在负温度中被确认,此现象佐证了我们前面所阐述的力场变化能 带来负熵的观点, 在负温度诞生的瞬间, 出现"热比功贵"的现象很好解释。 图 10 中负温度从 c 开始, 这时晶体进入反向磁场中。 由于力场反转, 原来 平行的成了反平行, 原来反平行的倒成了平行, 因而有了 N 2 > N , (根据玻 尔兹曼分布 N2 / = e-2 ΜΎ 当 Ν 2 > Ν ,即是系统处在负温度之下),我们 看到, 置入反向磁场的晶体面对磁场反向不断增强的过程。 每一粒子的运动 只有一个方向可行, 不管粒子原来向什么方向的运动, 在这个时刻都要统一 方向, (时间虽短但也是一 "劫 ") 也就是说这一刻紊乱的运动反而成为不可 能, 同一方向的运动成为唯一可能。 这就是热比功更珍贵的微观解释, 力场 让所有粒子方向一致, 使原来的 dH加入了有序的行列, 这就是当年恩格斯 预言的能量集中的形式。所有方向异动的热能被集中成为同一个方向的运动。 这实在是个好办法, 比用汽缸获得一致好许多, 因为它做到了所有粒子同时 一致的结果, 负温度出现颠覆开氏表述的理由就在这里。 这是十分宝贵的一 亥 |J, 因为如不把它 "有效截获", 一埃力场变化结束, 就复归紊乱了。 一个可 以获得功的机会就要失之交臂了,原本可以得到功的一瞬间只能得到高温了, 目前我们仅在激光中利用了这个粒子反转的现象, 实践走到了理论的前面, 我们既有重塑理论的紧迫性, 更有列项研究这 "能量集中" 的紧迫性, 因为 他与成功只差一步之遥。 The phenomenon of negative entropy is confirmed in the negative temperature. This phenomenon proves that the force field change described above can bring about negative entropy. At the moment when the negative temperature is born, the phenomenon of "heat is more expensive" is well explained. In Figure 10, the negative temperature starts at c, at which point the crystal enters the reverse magnetic field. Since the force field is reversed, the original parallel becomes anti-parallel, and the original anti-parallel becomes parallel, thus having N 2 > N , (according to the Boltzmann distribution N 2 / = e- 2 ΜΎ当Ν 2 > Ν , that is, the system is under negative temperature.) We see that the crystal placed in the reverse magnetic field faces the process of increasing magnetic field reversal. The movement of each particle is only feasible in one direction. No matter what direction the particle is moving in, it must be unified at this moment. (The time is short but it is also a "robbery".) That is to say, this disordered movement becomes impossible. The movement in the same direction becomes the only possibility. This is the more precious microscopic interpretation of the heat work. The force field makes all the particles in the same direction, and the original dH is added to the orderly ranks. This is the form of energy concentration that Engels predicted in the past. The heat energy of all directions is concentrated into the same direction of motion. This is really a good idea, much better than using a cylinder, because it achieves the same result for all particles at the same time, the reason for the negative temperature to appear subverted Kelvin is here. This is a very valuable Yihai|J, because if it is not "effectively intercepted", the end of the change of the Eli field will be reversed. An opportunity to gain merits will be lost. The moment that you can get the work can only get high temperature. At present, we only use this phenomenon of particle reversal in the laser. The practice has come to the front of the theory. We have both The urgency of the plastic theory is more collinear in the study of the urgency of this "energy concentration" because he is only one step away from success.
负温度在力场反转后被认为温度是无穷大, 我们认为其原因是力场反转 的时间很短, 因为功率是与时间成反比, 时间越短, 功率就越大, 任何加热 方法, 都因为有一个驰豫时间的牵制都不如力场反转那样快, 力场让每个粒 子接到命令, 各自走到不可再高的结构高位(即所谓能级有限), 然后瞬即反 转, 各粒子又要第二次 "迁徙", 行动又是高度一致的, 由于没有有效截获, 所以只能以热的形式把力场赶它上高位后的 dj 、 反转后让它加速的 dw 以 及它原来拥有的 dH 全部在瞬间变热了 (在某种意义上可以称爆炸), 这就 得到一个非常高的温度了。 The negative temperature is considered to be infinite after the force field is reversed. We believe that the reason is that the force field reversal time is very short, because the power is inversely proportional to time, the shorter the time, the higher the power, any heating method, Because there is a relaxation time that is not as fast as the force field reversal, the force field allows each particle to receive commands, each going to a higher structural high (ie, the so-called energy level is limited), and then immediately reversed, Each particle has to be "migrated" for the second time. The action is highly consistent. Because there is no effective interception, the force field can only be driven in the form of heat to the dj after it is high, and the dw after it is reversed and accelerated. The dH it originally had all heat up in an instant (in a sense, it can be called an explosion), which gives a very high temperature.
这样一个囊括粒子所有能量瞬时变热的过程, 可以说是一个无与伦比的 制热过程, 热泵技术根本无法望其项背。 原因有二, 第一、 在热功转换中的
时间因为与功率有关, 所以显得非常重要, 驰豫时间要尽量縮短, 而力场的 倒置是可以达到这个要求。 第二、 拥有二次有序的负温度模式应该是逆卡诺 循环所无法比拟的废热制热的最佳模式。 这就是我们认为怃中取热尚有比热 泵更好的办法获得更高的温度的理由。 Such a process of including all the energy of the particles instantaneously heating up can be said to be an unparalleled heating process, and heat pump technology cannot be expected. There are two reasons, first, in the conversion of thermal power Time is very important because it is related to power. The relaxation time should be shortened as much as possible, and the inversion of the force field can achieve this requirement. Second, the secondary temperature mode with secondary order should be the best mode for waste heat heating that is unmatched by the inverse Carnot cycle. This is why we believe that heat is better than heat pumps to get higher temperatures.
3 . 6 状态规律的多元化, 使正熵、 负熵皆有可能 3. 6 The diversification of the state law makes both positive entropy and negative entropy possible.
综上所说, 既然熵增律不是大自然的唯一状态规律, 那么其他状态规律 中走向各自劫底的时候, 如果粒子的运动出现了短暂的有序状态, 用熵的标 准来衡量就是负熵的诞生了,只要有效截获, 由此可能带来"功",这是其一。 走向结构有序, 熵为零, 放出大量热, 这是其二。 这二项的共同点- …都少 不了负流流, 即要有操控者, 从控制论知道, 操控指令有 2 个来源, 一个是 系统外, 当人们了解到信息的传递必须由能量做载体时, 出现了布里渊驱赶 了 "麦克斯韦妖" 的结论, 其实指令还可以来自系统内, 即运动本身给下一 个运动发指令——正反馈。在孤立系统中,只要有负熵流这根"最后的火柴", 就能点燃起有有序的希望, 如果孤立系统中除了熵极大之外一无所有, 那作 为已热寂的孤系也不是必须批判的。因为客观存在不是以人的意志为转移的, 热寂就热寂吧, 这一 "孤系"也许要过很漫长的 "劫" , 象一千零一夜中被 封入邮瓶的魔鬼那样, 等待外界的开启- --…负熵流的介入。 In summary, since the law of entropy increase is not the only state law of nature, when other state laws are going to the bottom of each other, if the movement of particles appears in a short-ordered state, it is measured by the standard of entropy as negative entropy. The birth of this, as long as the effective interception, which may bring "gong", this is one of them. The structure is orderly, the entropy is zero, and a lot of heat is released. This is the second. The commonality of these two items - ... are indispensable for negative flow, that is, there must be a controller. From the cybernetic theory, there are two sources of manipulation commands, one is outside the system, when people understand that the transmission of information must be carried out by energy. Brillouin has driven the conclusion of "Maxwell Demon". In fact, the instructions can also come from within the system, that is, the movement itself gives instructions to the next movement - positive feedback. In an isolated system, as long as there is a "next match" in the negative entropy flow, it can ignite an orderly hope. If the isolated system has nothing but entropy, it is not a lonely orphan. Must be critical. Because the objective existence is not transferred by the will of the human being, the heat is silent, this "lonely" may have to go through a long "robbery", like the devil who was sealed in the mail bottle in the thousand and one nights, waiting The opening of the outside world ---... the intervention of negative entropy flow.
人不过是宇宙中一种十分脆弱的存在。 但尽管人的存在十分脆弱, 人脑 的进化却是大自然进化的一部分, 是宇宙发展的最新成果, 是代表着宇宙的 方向-…-他能感悟规律并予以模仿。 我们不妨再感悟一下大自然。 Man is just a very fragile existence in the universe. But despite the fragility of human existence, the evolution of the human brain is part of the evolution of nature, the latest achievement in the development of the universe, and the direction of the universe...--he can understand the law and imitate it. We may wish to realize nature again.
由分布作 "动力" 的不可逆过程, 一个是大家熟悉的熵增, 另一个就是 速率分布以麦克斯韦曲线为终点的不可逆过程,由曲线作为一个过程的劫底, 在走向这个劫底的时候诞生差异。 如果说熵增是大自然走向平衡、 走向差别 消失的过程, 那麦克斯韦曲线就是用分子的速度永远保持有规律的不相等, 来表达大自然永不平衡的意志。 The irreversible process of "power" by distribution, one is the familiar entropy increase, and the other is the irreversible process in which the velocity distribution ends at the Maxwell curve. The curve is used as a process of robbing the bottom, and the difference is born when it comes to this ruin. . If the entropy increase is the process of nature's transition to equilibrium and the disappearance of the difference, then Maxwell's curve is to use the speed of the molecule to always maintain a regular unequalness to express the will of nature's never-balance.
分布和状态不是同一概念, 但一个分布相对应的微观状态都近似的等于 定域系统的微观状态数除以 N !。 麦克斯韦速率分布曲线 (图 11 )表达了 分子速率分布永远呈钟形曲线, 即中间处于最可几状态的比例最大, 曲线的 左右二脚分别表示速率低和高的比例。 如果因为蒸发而让右脚处的高速分子 大量减少, 那整个曲线会因降温而向左移, 但可贵的是麦氏钟形曲线仍是新 的分布所追求的目标, 即使降至 · Τ2 , 右脚仍伸到竖线影形处, 也就是说又 有高速分子诞生了, 如果把这种高速分子的速度看作另一温度的最可几速率 那这自发选出高速分子的过程不就是走向 '高温' 的过程? 高速分子既不是 加热而得, 也不是作功而得, 仅因为状态要走向某个平衡态而得到, 与熵增 一样, 是以分布为动力的不可逆过程, 这样, 江河湖海的蒸发就犹如一只永
不停歇的自发加热的汽化锅炉! 由处于 "死态" 的废热支撑着! 又因为江河 湖海所含废热多得很, 书称如果可能, 降低 1 度就能开动全世界机器 1700 多年, 所以曲线左移很少很少, 又因为大气不断地有废热补充, 所以这样的 自发选拔高速分子的模式永无穷尽, 在这里我们看到了 "热量不可能从温度 低处自发走向高温处", 只是指单一过程, 是循环中的一段, 循环是由不可逆 过程连接而成, 它们首尾相接, 都在各自走向各自标准的平衡劫底, 从而构 成循环,也不断创造差异。以至当我们最后清算水力发电的能量来自何处时, 将有一个清晰的数据反映有多少是来自江河湖海的内能所得。 又有多少水分 子进入大气后, 继续靠大气内能抬升, 以每升高 100 米降低 1 度的代价进 入高空, 直至温度降至临界点, 水分子互相吸引超过了互相排斥, 结成水珠 从高空降下来。 我们看到诞生差异的负熵要成为连续过程, 必须进入循环, 如果没有地球引力无法从另一个途径返回 (下雨) 过程又不能持续。 Distribution and state are not the same concept, but the microscopic state corresponding to a distribution is approximately equal to the number of microstates of the localized system divided by N! . The Maxwell rate distribution curve (Fig. 11) expresses that the molecular velocity distribution is always a bell curve, that is, the ratio of the middle in the most probable state is the largest, and the left and right legs of the curve respectively indicate the ratio of the low rate and the high rate. If the high-speed molecules at the right foot are greatly reduced due to evaporation, the entire curve will shift to the left due to cooling, but it is valuable that the McGregor curve is still the target of the new distribution, even if it falls to · 2 The right foot still extends to the vertical line shadow, that is to say, there are high-speed molecules. If the speed of this high-speed molecule is regarded as the most probable rate of another temperature, the process of spontaneously selecting high-speed molecules is not Is the process of going to 'high temperature'? High-speed molecules are neither heated nor derived from work. They are obtained only because the state is going to a certain equilibrium state. Like the entropy increase, the distribution is the irreversible process of power. Thus, the evaporation of rivers and lakes is like One yong A spontaneously heated vaporization boiler that does not stop! Supported by waste heat in a "dead state"! Because the rivers, lakes and seas contain a lot of waste heat, the book says that if possible, a 1 degree reduction can drive the world's machines for more than 1,700 years, so the left shift of the curve is very rare, and because the atmosphere is constantly replenished with waste heat, so this The mode of spontaneously selecting high-speed molecules is endless. Here we see that "heat can't spontaneously go from high temperature to high temperature", just a single process, which is a segment of the cycle, which is connected by irreversible processes. The end-to-end encounters are all in the balance of their respective standards, thus forming a cycle, and constantly creating differences. Even when we finally liquidate the energy of hydropower, there will be a clear data reflecting how much energy is derived from the rivers and lakes. After how many water molecules enter the atmosphere, they continue to rise in the atmosphere and enter the sky at a cost of 1 degree per 100 meters. Until the temperature drops to a critical point, the water molecules attract each other more than each other and become water droplets. Down from high altitude. We see that the negative entropy of the birth difference has to be a continuous process, and it must enter the cycle. If there is no gravity of the earth, it cannot return from another route (rain).
大自然自发走向永不平衡的麦氏曲线与走向平衡的熵增律作为矛盾的双 方, 再一次佐证了二者既相互对立, 又相互依存的普遍规律, 走向 "麦氏曲 线" 的普遍适用性一点也不亚于最小能规律和熵增律, 在白蚁世界、 人类社 会都有它主导的案例 [注 26 ]。 Nature's spontaneous and unbalanced Max's curve and the entropy increase law of the balance as a contradiction, once again prove the universal law of the two opposite and interdependent, and the general applicability of the "Mc's curve" It is no less than the law of minimum energy and entropy increase. It has its dominant case in the termite world and human society [Note 26].
由 "差异制造者"……大海的蒸发, 让洋面充满水气, 混沌理论告诉我 们只要一个小小的诱因——蝴蝶效应就可能制造出旋转涡流, 加强这涡流的 可以是科里奥利力, 这从台风的旋向得到证明。另一个力就是从"涡流致冷" 这致冷机制中得到 【 注 27 】 , 爱因斯坦的等价原理告诉我们: 所有物理 定律在自由空间作匀速直线运动的惯性系中的形式, 与在引力场中作自由降 落的局域惯性系中的形式完全相同, 在旋转的台风中, 水分子相当于在一个 引力场中, 向其他各个方向的运动都受阻, 唯有旋转向的运动受到鼓励, 使 水分子一面在旋转中交出自己动能, 加强了台风, 另一方面又作为"负熵流" 胁迫新参加进这潮流的水分子与其统一方向——交出动能。 正是这个正反馈 使台风不断壮大直到摧枯拉朽——拥有十几个氢弹能量的来源, 直到把万亿 吨淡水扔到大陆, 最后因没有了后续水蒸气而终止。 我们看到了大自然是如 何"自组织", 通过自己当负熵流的正反馈, 获得负熵、 获得功的。 我们完全 可以仿效大自然的 "自行祸合", 设计一个 "三维循环"。 From the "differentiation of the makers" ... the evaporation of the sea, the ocean surface is filled with water vapor, chaos theory tells us that as long as a small incentive - the butterfly effect can create a rotating vortex, the reinforcement of this vortex can be Coriolis Force, this is proved by the direction of the typhoon. Another force is obtained from the cooling mechanism of "eddy current cooling" [Note 27]. Einstein's equivalent principle tells us: the form of all physical laws in the inertial system of uniform linear motion in free space, and The form of the local inertial system for free fall in the gravitational field is exactly the same. In a rotating typhoon, the water molecules are equivalent to being in a gravitational field, and the movement to other directions is blocked. Only the rotational motion is encouraged. To make the water molecules surrender their own kinetic energy in the rotation, strengthen the typhoon, and on the other hand, as a "negative entropy flow", coerce the new water molecules that participate in this trend and their unified direction - surrender kinetic energy. It is this positive feedback that keeps the typhoon growing until it is destroyed – it has a source of more than a dozen hydrogen bomb energies until it throws trillions of tons of fresh water to the mainland and ends up with no subsequent water vapor. We have seen how nature is “self-organizing”, and through its positive feedback of negative entropy flow, it gains negative entropy and gains merit. We can completely imitate nature's "self-discipline" and design a "three-dimensional cycle."
4、 更好的三维循环 4, a better three-dimensional cycle
4.1 可以在严格的孤立系统中演绎违背开氏表述的三维循环 4.1 Three-dimensional loops that violate Kay's expression can be interpreted in a rigorous isolated system
前面探讨了负熵诞生的可能, 取得如下共识: 负熵需在负熵流的情况下 诞生。这又有二个观点: a 当负熵流的绝对值大于熵产生才获得负熵——这 是耗论观点。这是靠负熵流来对消熵产生而得到。 b 依靠负熵流带来的负熵 超过熵产生就有纯负熵的结果。 这是整个第三部分 "熵可正负" 的主题。 根
据 b 的观念设计了三维循环(图 12 ) , ab 、 be 与卡诺同, 卡诺的 cd 过 程被取消换上因力场的增加而出现负熵的曲线 cd , 截获负熵可以得功, 让 这份外界的投入在 de 的升温中归还, 可获得热能。 In the previous discussion, the possibility of the birth of negative entropy was discussed. The following consensus was reached: Negative entropy needs to be born in the case of negative entropy flow. This has two more points: a When the absolute value of the negative entropy flow is greater than the entropy generation, the negative entropy is obtained - this is the theory of cost. This is obtained by the negative entropy flow to generate the de-entropy. b The negative entropy brought by the negative entropy flow exceeds the entropy to produce pure negative entropy. This is the theme of the third part of the "entropy can be positive and negative". Root According to the concept of b, a three-dimensional cycle is designed (Fig. 12). Ab and be are the same as Carnot. Kano's cd process is cancelled and replaced with a negative entropy curve cd due to the increase of the force field. The interception of negative entropy can be achieved. Let this outside investment be returned in the heat of de, and the heat can be obtained.
4.1.1 有负熵流参与的热机 4.1.1 Heat engine with negative entropy flow participation
' 下面让我们看一看有负熵流进入热机的运行会有什么结果。 Let's take a look at what happens when a negative entropy flow enters the heat engine.
图 13 中, ① 循环从等温线上某一点 a 开始, 工质吸收热源热量沿 ab 线作等温膨胀, 到达与外界大气压平衡的 b 点, 热机对外作净功为 abf) ' 一块。 In Fig. 13, the 1 cycle starts from a point a on the isotherm, and the heat absorbed by the working medium heats up along the ab line to reach the point b which is in equilibrium with the external atmospheric pressure, and the external work of the heat engine is abf) '.
② 由外界作功,拉着活塞继续向右,外界克服大气压作功,体积从 b 点 到 o点, 工质作绝热膨胀到达 c 点, 外界作功 boc —块。 2 Working from the outside world, pulling the piston to the right, the outside world overcomes the atmospheric pressure, the volume is from point b to point o, the working medium is adiabatically expanded to reach point c, and the outside works boc.
③ 放开活塞, 因为 c 是等温线 cd 上的一点, 根据 2 . 1 节分析, ab 过程是对大气的非平衡定态作了小小的扰动。 它会在大气压压力下回到非平 衡定点 d 点,气缸内外压差作功 ocd —块,减去 ② 中外界作功 boc —块, 得净功 bed —块。 3 Release the piston, because c is a point on the isotherm cd. According to Section 2.1, the ab process is a small disturbance to the non-equilibrium steady state of the atmosphere. It will return to the non-balanced fixed point d point under atmospheric pressure, and the pressure difference inside and outside the cylinder will be ocd-block, minus the external work boc-block in 2, and the net work bed-block.
④ 由 d 点绝热压缩, 外界作功 dao ' —块, 此外界作功可在 ① 热机 作功的 abo' —块中消去, 使 ① 净得 abd —块, abd + bcd 正好是一块完 整的 "平行四边行"但却没有 cd 的外界作功过程, 也没有把热量抛向 "无 限大冷源" 的过程, 是诞生在孤立系统里的结论。 夹在二等温线之间的热量 全部转变成了功 ( Q = cmAT ) 不过, 这与卡诺热机的模式完全不一样, 只是完成了卡诺的愿望, 我们是依靠负熵过程 cd来消除工质因膨胀而带来 的熵增, 才得到此结果的。 4 Adiabatic compression by d point, the external work is done dao ' - block, in addition, the work can be eliminated in the abo' block of 1 heat machine work, so that 1 net abd - block, abd + bcd is just a complete piece" Parallel four sides "but the process of external work without cd, nor the process of throwing heat to the "infinite cold source" is the conclusion that was born in an isolated system. The heat sandwiched between the two isotherms is all converted into work (Q = cmAT). However, this is completely different from the model of the Carnot engine. It just completes Kano's wish. We rely on the negative entropy process cd to eliminate the work. This result is obtained by the entropy increase caused by the expansion of mass.
4.1.2 单一热源的热机 4.1.2 Single heat source heat engine
经典理论称如果有超过卡诺热机的效率, 必然可以引出单一热源作功的 过程, 的确如此, 请看图 14 的过程。 The classical theory states that if there is more than the efficiency of the Carnot engine, it is inevitable that a single heat source can be used to perform the work. This is true. Please refer to the process in Figure 14.
为了更清晰地说明问题, 我们把上述循环简化: To illustrate the problem more clearly, we simplify the above cycle:
① 过程从常温等温线 , 与大气压 P = l 的交点 b 开始,外界作功 boc 一块工质从 b 绝热膨胀到 C 1 The process starts from the normal temperature isotherm and the intersection point b of the atmospheric pressure P = l, and the external work boc a working fluid expands from b adiabatic to C
② 工质沿 T2等温线回到 d ,气缸与大气压之间的压差作功 ocd —块, 减去 boc——外界在 ① 中作功的一块剩 bed —块 2 The working fluid returns to d along the T 2 isotherm, and the pressure difference between the cylinder and the atmospheric pressure is ocd — block, minus boc – the remaining bed in the outside world
③工质吸收大气废热由 d 升温至 b,循环再由 b 开始。整个过程出现 了 "单一热源"作功的结果, bed面积虽小但意义重大, 它将让我们重新认 识热功转换规律 3 The working fluid absorbs the waste heat of the atmosphere from d to b, and the cycle starts from b. The whole process has the result of "single heat source" work. The bed area is small but significant, it will let us reconsider the law of heat work conversion.
4 . 2 热功转换的本质和规律 4.2 The nature and law of thermal power conversion
卡诺时代产生错误源于对热功转换的本质理解有误。 ① 卡诺把热功转 换看作 "热质降落"与热功转换是无序向有序转换的观点有着本质区别, 至
于不生不灭的热质说甚至与第一定律都是对立的, 由这样的认识作基础怎么 能得到真正的热功转换规律呢?他的结论是与当时尚没有确立分子运动论, 没有熵概念的认识水平相对应的。 ② 卡诺热机着眼点是容积改变的膨胀作 功, 而膨胀少不了让工质熵增, 用外界作功压縮工质的办法, 虽然得到了体 积缩小的结果。 但功变成了热, 反而增加了熵值, 热量转化为功的比例就小 了, 与获得有序并转化为机械能的热机目的是南辕北辙之事, 怎么能得到最 高效率呢? The error in the Kano era stems from the misunderstanding of the nature of thermal power conversion. 1 Kano regards the conversion of thermal power as "thermal mass fall" and the conversion of thermal power is an essential difference from the viewpoint of disordered to ordered conversion. The heat quality that is not indestructible is even opposite to the first law. How can we get the true heat work conversion law based on this understanding? His conclusion is that when fashion does not establish molecular movement theory, there is no level of understanding of the concept of entropy. 2 Carnot thermal machine focuses on the expansion of volume change work, and the expansion is indispensable to increase the entropy of working fluid, and the method of compressing the working fluid by the outside world has obtained the result of volume reduction. However, the work has become hot, but the entropy value has been increased. The proportion of heat converted into work is small. The purpose of getting a heat engine that is ordered and converted into mechanical energy is to do things in the south. How can we get the highest efficiency?
热功转换的本质是分子运动出现一致时, 及时截获这有序成为机械功。 是一个紊乱走向有序, 有序被截获的过程。 有序是首要条件, 截获是必要过 程。 风是一种空气的有序运动, 如果没有风车去截获很快回归无序; 江河流 向大海无疑是有序但没有水轮机组, 就谈不上发电。 就是变压器中的涡流, 也是因为没有截获而成浪费。 用这个观点来看卡诺热机, 首先该热机是依靠 温差来诞生有序的 The essence of thermal power conversion is that when molecular motion appears to be consistent, timely interception of this order becomes mechanical work. It is a process in which disorder is directed to order and intercepted in an orderly manner. Order is the primary condition, and interception is a necessary process. The wind is an orderly movement of the air. If there is no windmill to intercept, it will return to disorder quickly. If the river is undoubtedly orderly to the sea but there is no turbine, it will not be able to generate electricity. It is the eddy current in the transformer, and it is also because there is no interception and waste. Using this point of view to look at the Carnot heat engine, first of all, the heat engine is based on the temperature difference to give birth orderly.
- ""一用气缸限制了其他方向的膨胀, 仅留下活塞方向可以膨胀而得到有序, 由活塞接受工质分子的撞击来截获有序, 这就出现了 2 个问题: 1, 有序是 否必须从膨胀得到, 膨胀除了加热是否还存在其他办法, 回答是通向有序不 仅仅是膨胀; 膨胀尚可以由力场的变化得到。 2 由紊乱转向有序, 紊乱的热 能是否必须来自高温, 回答也是否定的, 紊乱转为有序, 并不要求紊乱的热 能必须来自高温, 因为有序源于势差, 而势差不一定仅仅是温差, 这样开氏 表述对单一热源作功的否定就站不住了。 如果把紊乱的烈度称温度, 那么紊 乱的程度就是熵值。 热功转换的本质就变乱为治, 改变的只是粒子运动的方 向, 只有这一致被传递出去——被截获, 成机械功, 才会降温, 因为由紊乱 转为有序, 熵值必定降低, 但热量来自何处却无要求, 这就使废热为源作功 成为可能。 - ""The cylinder is used to limit the expansion in other directions. Only the direction of the piston can be expanded and ordered. The piston receives the impact of the working medium molecules to intercept the order. Two problems arise: 1. Order Whether it must be obtained from expansion, expansion, in addition to heating, there are other ways, the answer is that the order is not just expansion; expansion can still be obtained by the change of the force field. 2 From disorder to order, whether the turbulent heat must come from high temperature, the answer is also negative, the disorder turns into order, and the thermal energy that does not require disorder must come from high temperature, because the order is derived from the potential difference, and the potential difference is not necessarily only It is the temperature difference, so that the negative expression of Kelly's work on a single heat source can't stand. If the intensity of the disorder is called temperature, then the degree of turbulence is the entropy. The essence of thermal power conversion is chaotic. The only change is the direction of particle motion. Only when this is consistently transmitted is intercepted and turned into mechanical work, it will cool down. Because the disorder is changed to order, the entropy value must be reduced. But where the heat comes from, there is no requirement, which makes it possible to use waste heat as a source.
· 我们借用耗散理论中的 "负熵流"这一名词, 把能带来负熵过程的能流 · We borrow the term "negative entropy flow" in the dissipative theory to apply the energy flow that can bring about a negative entropy process.
(有序运动) 称为负熵流, 按照这个定义, 那个拉着活塞向右的过程就是负 熵流, 图 13 图 14 中的 bo 就是负熵流, 在热泵中就是压缩机拉着蒸发的 过程, 活塞在被迫向右移动时, 凡向右运动的分子, 在撞击活塞时都把这一 方向的动能交给了它, 这与洋面上的水气分子把动能交给旋转的台风一样, 只是台风的 "负熵流"就是不断扩大的气旋。 活塞在抵抗大气压的过程中, 工质因贡献了内能而降低温度达到 c 点,整个大气被 bo 过程扩大了一点点 体积, 受到 "小小的扰动" 正如前面分析所说, 整体看大气要回到它原来的 "非平衡定态", 由于温度已从 b 降到 c ,所以局部看就是工质被大气压压 着从 c 沿等温线回到 d 。在到 d 点的过程中,我们可以得到因为活塞内外 压差所带来的功 bed 。最后, 在取之不尽的大气废热中吸热, 而回到 b 点。
面积 bed 很小,但意义重大, 如果我们认定卡诺理论对热功转换的本质认识 有误, 那么接受这个新结论应该不具心理障碍。 (Ordered motion) is called negative entropy flow. According to this definition, the process of pulling the piston to the right is the negative entropy flow. The Bo in Figure 13 is the negative entropy flow. In the heat pump, the compressor is pulling the evaporation. In the process, when the piston is forced to move to the right, the molecules moving to the right give the kinetic energy in this direction to the piston when it hits the piston. This is the typhoon that is given to the rotating typhoon by the water and gas molecules on the ocean surface. The same, just the "negative entropy flow" of the typhoon is the expanding cyclone. In the process of resisting atmospheric pressure, the working fluid reduces the temperature to the point c due to the contribution of internal energy. The whole atmosphere is enlarged by the bo process by a little volume, and is subject to "small disturbance". As the previous analysis said, the overall atmosphere is Going back to its original "non-equilibrium steady state", since the temperature has dropped from b to c, it is locally seen that the working medium is pressed by atmospheric pressure from c along the isotherm back to d. In the process of reaching point d, we can get the work bed due to the pressure difference between the inside and outside of the piston. Finally, absorb heat in the inexhaustible atmospheric waste heat and return to point b. The area bed is small, but significant. If we believe that Carnot's theory has a wrong understanding of the nature of heat transfer, then accepting this new conclusion should be without psychological barriers.
教科书的开氏表述是这样表达的: "不可能从单一热源吸热使之完全变 成有用功, 而不引起其他变化"在接着解释 "不可能" 时是这样说的 "不可 能不仅是指, 在不引起其他变化的条件下直接从单一热源吸热而将之完全变 成有用的功, 而且是指, 不论用任何曲折复杂的方法, 在全部过程终了时, 其最终的唯一效果是从单一热源吸热而将之完全变成有用的功" [注 28] The Kelvin's expression of the textbook is expressed as follows: "It is impossible to absorb heat from a single heat source and turn it into useful work without causing other changes." When it is explained "impossible", it is impossible to mean not only , directly absorbs heat from a single heat source without causing other changes, and completely turns it into useful work, and means that, regardless of any complicated method, at the end of the whole process, the ultimate effect is A single heat source absorbs heat and turns it into a useful work completely [Note 28]
该解释的第一个不可能, 可以理解为紊乱不会自发有序。 后一个 "而且 是指"就属于真理多走了一步, 既违背了相生相克这一矛盾法则, 也是带来 热寂说的直接原因, 是不正确的。 正如许多先贤哲人所说的那样, 矛盾的一 方失去了与之矛盾的另一方, 其本身也就无法存在, 因为循环无法构成, 他 自己的行动也就无以为继了。 The first one of the explanations is impossible, and it can be understood that the disorder is not spontaneous. The latter "and refers to" is a step closer to the truth. It violates the contradiction of mutual sympathy, and it is also the direct cause of the hot silence. It is not correct. As many sages have said, the contradictory side loses the other party that contradicts it, and it cannot exist by itself. Because the cycle cannot be constituted, his own actions are unsustainable.
有了上述论证,热功转换的效率问题不再是问题, η ι 是孤系的结论, 其中等于号是指 "全部过程终了时"——即有负熵流存在的非单一过程。 其 他单一过程为小于号, 从此它与第一定律的潜在矛盾并不再存在。 负熵流仅 起 "催化剂" 的作用, 过程结束时它无一损耗, 起到条件的作用, 唯一的作 用是促使热向功转换,这也是大自然中有序可以成为负熵流, "自行耦合"而 不断诞生新的有序的原因。 负熵流除带来负熵之外, 其他什么都没有发生, 我们与耗散结构理论不同之处在于不指望 ds =diS + des 式中靠 ldes| >diS 才 得到 ds 变负, 也就是说, 不是靠外界提供的负熵流大于熵产生——靠对消 而获得负熵, 而是把 des 看作条件, 在这个条件下发生 diS 的熵产生为负值 的过程。 负熵是宇宙中客观存在的一种过程, 与正熵一样需要在一定的条件 下出现, 而 "一定条件"在印度哲学中称因和缘, 因是主要条件, 缘是次要 条件, "因缘"可以是自然界的祸合, 也可以是人工设计。 With the above argument, the efficiency problem of heat work conversion is no longer a problem, η ι is the conclusion of the orphan system, where the equal sign refers to "the end of the whole process" - that is, the non-single process with the existence of negative entropy flow. The other single process is the less than sign, and since then its potential contradiction with the first law no longer exists. The negative entropy flow only acts as a "catalyst". At the end of the process, it has no loss and plays a role. The only role is to promote the conversion of heat to work. This is also the order in nature that can become a negative entropy flow. Coupling" and constantly creating new and orderly reasons. The negative entropy flow divides negative entropy, nothing else happens. We differ from the dissipative structure theory in that we do not expect ds =d iS + d e s to get ds by ld e s| >d iS Negative, that is to say, the negative entropy flow that is not provided by the outside is greater than the entropy generation—the negative entropy is obtained by the cancellation, but the d e s is regarded as the condition. Under this condition, the entropy of d iS is negative. The process of values. Negative entropy is a kind of objective existence process in the universe. Like positive entropy, it needs to appear under certain conditions. The "certain condition" is called the cause and the origin in Indian philosophy. Because it is the main condition, it is the secondary condition. The cause of karma can be a natural disaster, or it can be artificial.
从麦克斯韦妖的假设开始, 小妖一直让热二律难堪。 信息论确立后因为 信息的传递必须由能量支撑, 大家又似乎驱逐了小妖。 错误发生在布里渊, 他把香农之熵与热力学之熵混同在一起。 香农在为 "不定性"起名时, 曾与 约翰 · 冯 · 诺伊曼讨论过, 诺伊曼说 "你应当称它为熵, 这有二个理由: 第 一你的不定性函数, 在统计力学中己经用在熵的下面, 因此他本来就有这个 名称, 第二、 而且是更重要的一点, 谁也不懂熵是什么, 因此在争论时对你 有利"。 [注 2 9]所以可以说 "香农的信息熵完全不同于热力学熵, 它同样是概 率函数, 这与能量、 温度都无关, 香农的熵是一个无量纲的量, 布里渊将香 农熵与热力学熵进行换算是一个明显的错误"。 [注 301让小妖点灯照亮分子并 去抓捕 "快速分子"其实是对大思想家麦克斯韦的假设理解有误, "小妖"之 说是他对热二律总体持怀疑的思想。 从控制论知导 "抓捕" 只是控制的一种
形式, 完全可以设计好程序让其自行分离, 我们说有序诞生于单向阀和自循 环, 其中单向阀是指广义的改变方向的程序设置, 自循环则是这一过程的终 点, 搭上了另一个过程的始点, 互为始末的循环过程。 而正反馈是让这一程 序连续的机制之一。 运动继续的指令来自上一运动本身的, 就是正反馈, 正 反馈发展到顶点而结束。 Starting with the assumptions of Maxwell's demon, the demon has always embarrassed the heat. After the establishment of information theory, because the transmission of information must be supported by energy, everyone seems to have expelled the demon. The error occurred in Brillouin, who mixed the entropy of Shannon with the entropy of thermodynamics. Shannon discussed with John von Neumann when he named "unqualified", Neumann said, "You should call it entropy. There are two reasons for this: First, your uncertainty function, in statistics Mechanics has been used under entropy, so he originally had this name, second, and more importantly, no one knows what entropy is, so it is good for you in the debate." [Note 2 9] So it can be said that "Shannon's information entropy is completely different from thermodynamic entropy, it is also a probability function, which is independent of energy and temperature. Shannon's entropy is a dimensionless quantity, Brillouin will Shannon entropy and The conversion of thermodynamic entropy is an obvious mistake." [Note 3 01 Let the little demon light illuminate the molecule and arrest the "fast molecule" is actually a misunderstanding of the hypothesis of the great thinker Maxwell. The "little demon" is his thought of the general suspicion of the hot law. Knowing "catch" from cybernetics is just a kind of control Form, it is entirely possible to design the program to separate itself. We say that orderly is born in the check valve and self-circulation. The check valve refers to the generalized program setting for changing direction, and the self-circulation is the end point of this process. At the beginning of another process, they are the beginning and end of the cycle. Positive feedback is one of the mechanisms for making this program continuous. The instruction to continue the movement comes from the previous movement itself, which is positive feedback, and the positive feedback develops to the apex and ends.
不管是在空中运送淡水的台风, 还是被称为负温度现象的激光过程, 都 有一个共同点——正反馈。 即某一方向的运动不断的得到加强, 其他方向的 运动, 则受到抑制。 台风形成的过程中, 水分子唯一可行动的方向是顺着旋 转方向运动, 其他方向一律受阻。 同样, 激光的形成过程告诉我们, 光学谐 振腔中某一方向的受激辐射能够不断得到加强,而其他方向的受到抑制,这 2 个例子让我们悟得一个道理, 有序的获得需要条件, 但不需要能耗。 Whether it is a typhoon that transports fresh water in the air or a laser process called a negative temperature phenomenon, there is one thing in common – positive feedback. That is, the movement in one direction is continuously strengthened, and the movement in other directions is suppressed. During the formation of the typhoon, the only actionable direction of the water molecules is to move in the direction of rotation, and the other directions are blocked. Similarly, the formation process of the laser tells us that the stimulated radiation in one direction of the optical cavity can be continuously strengthened, while the other directions are suppressed. These two examples make us realize a reason and orderly conditions. But no energy is needed.
我们知道, 在机械运动中改变某物的运动方向需要外力, 但不消耗外力 的"量",改变者与被改变者运动的量,在矢量和中保存着(保守力英文有"保 存" 的意思)。 被绳子系住的小石子, 绕着绳子的另一端为圆心的圆周运动, 小石子每时每刻都在改变运动方向, 但绳子却并不作功。 就这个意义上说改 变运动方向不需要能耗。另一个例子是洛仑兹力,它是涉及粒子的状态规律, 洛仑兹力既和磁场方向垂直, 又和带电粒子的速度方向垂直, 所以对粒子作 功为零, 带电粒子的速率和动能均无变化, 只是方向有变化。 所以改变运动 的方向, 负熵流是必要的前提。但它不消耗能量, 这等于找到了麦克斯韦妖, 也找到了恩克斯的 "能量集中" 的方法。 We know that changing the direction of movement of something in mechanical motion requires external force, but does not consume the "quantity" of external force. The amount of movement of the changer and the changed person is preserved in the vector sum (conservative English has "save" meaning). The pebbles tied by the rope move around the other end of the rope in a circular center. The pebbles change direction of movement all the time, but the rope does not work. In this sense, it is not necessary to consume energy to change the direction of motion. Another example is the Lorentz force, which is a state law involving particles. The Lorentz force is perpendicular to the direction of the magnetic field and perpendicular to the velocity direction of the charged particles, so the work on the particles is zero, the rate and kinetic energy of the charged particles. There is no change, only the direction changes. So changing the direction of motion, negative entropy flow is a necessary premise. But it does not consume energy, which is equivalent to finding Maxwell's demon, and also found Enke's "energy concentration" method.
正如一个哲人所说"真理其实是简单而美丽的",清扫理论障碍后接着的 问题就是设计方案了。 As a philosopher said, "The truth is actually simple and beautiful." The problem after cleaning up the theoretical obstacles is the design.
1 、 严济慈 《 热力学第一和第二定律 》 1. Yan Jici, The First and Second Laws of Thermodynamics
2 、 恩格斯 《 自然辩证法 》 2, Engels, Dialectics of Nature
3 、 郑宏飞 《 佣一种新的方法论 》 P2 北京理工大学出版社 2004 3, Zheng Hongfei, "A new method of commission" P2 Beijing Institute of Technology Press 2004
4 、 朱明善等 《 热力学分析 》 P115 高等教育出版社 1992 版 4, Zhu Mingshan, etc. Thermodynamic Analysis P115 Higher Education Press, 1992 Edition
5 、何美芸"绿色能源 2050 前 100%可再生能源是能达到的"摘自 《 世 界环境 》 2009 第 6 期 5, He Meizhen "Green Energy 2050 before 100% renewable energy can be achieved" from "World Environment" 2009 No. 6
6 、许志治"废热制热将成为新的产业"摘自 《 高科技与产业化 》 2007 . 2 6. Xu Zhizhi "Waste heat and heat will become a new industry" from "High-tech and industrialization" 2007. 2
7、 朱明善等 《 热力学分析 》 P76 高等教育出版社 1992 版 7. Zhu Mingshan et al. Thermodynamic Analysis P76 Higher Education Press, 1992 Edition
8、 《 普利高津与耗散结构理论 》 一书序言 8. Preface to the book "Puli Gaojin and Dissipative Structure Theory"
9、 《 普利高津与耗散结构理论 》 一书序言 9. Preface to the book "Puli Gaojin and Dissipative Structure Theory"
10 、 朱明善等 《 热力学分析 》 P82 高等教育出版社 1992 版 10, Zhu Mingshan, etc. Thermodynamic Analysis P82 Higher Education Press, 1992 Edition
11、 熊吟涛 《 热力学 》 P67 高等教育出版社 1961 版
12、 熊吟涛 《 热力学 》 P63 高等教育出版社 1961 版 11, Xiong Yitao, "Thermodynamics" P67 Higher Education Press, 1961 Edition 12, Xiong Yitao, "Thermodynamics" P63 Higher Education Press, 1961 Edition
13、 张三惠、 沈慧君编, 分子物理学也热力学 P114 13. Zhang Sanhui, Shen Huijun, Molecular Physics and Thermodynamics P114
14、 人民大学哲学系 《 形式逻辑 》 P194 14. Department of Philosophy, Renmin University “Formal Logic” P194
15、 见各类热力学教科书 15. See various thermodynamic textbooks
16、 中国光明日报 2004 . 12 . 30 无偏二极管的实验报道 16. China Guangming Daily 2004 . 12 . 30 Experimental report of unbiased diode
17、 "劫"是印度佛学的时间概念, 每一劫都有生成、 稳定、 毁坏、 消亡 四个阶段组成。 他比均分地球自转的时间概念更为科学 1 与驰豫时间一样, 各过程长短不一 2 、都有四个阶段的完整性,概括了所有走向劫底运动的共 性 3 启动后不可逆转的必然性。 17. "Robbery" is the concept of time in Indian Buddhism. Each robbery consists of four stages: generation, stability, destruction, and extinction. He is more scientific than the concept of equalizing the Earth's rotation. 1 It is the same as the time of relaxation. The length of each process is different. There are four stages of completeness, summarizing all the commonalities that move toward the bottom of the robbery. 3 It is irreversible after the start. Inevitability.
18、 胡家聪 "熵概念渊源初探" P177 摘自王福山主编 《 近代物理学 史研究 》 18, Hu Jiacong "Preliminary Study on the Origin of Entropy Concept" P177 Selected by Wang Fushan, Editor-in-Chief of Modern Physics History
19、 胡家聪 "熵概念渊源初探" P177 摘自王福山主编 《 近代物理学 史研究 》 19, Hu Jiacong "Preliminary Study on the Origin of Entropy Concept" P177 Selected by Wang Fushan, Editor-in-Chief of Modern Physics History
20、 严济慈 《 热力学第一和第二定律 》 P2 20, Yan Jici, The First and Second Laws of Thermodynamics, P2
21、 对 "热寂"的批判有著名的 "宇宙无限说" "起伏说"等多种, 但皆 牵强附会, 因熵是广延量既然可以证明孤立系统有热寂的可能, 那一个一个 孤立系统相连不仍是熵相加吗?所以没有负熵的制约, 热死不可避免, 最彻 底的批判就应该是有负熵参与的 "非开"过程。 即耗散结构理论向前跨一步。 21. The critique of "hot silence" is famous for "the infinite theory of the universe" and "the ups and downs", but it is all far-fetched. Because entropy is extensive, it can prove that there is a possibility of isolation in the isolated system, one by one. Is the isolated system connected still not entropy added? Therefore, without the restriction of negative entropy, hot death is inevitable, and the most thorough criticism should be the "non-open" process with negative entropy participation. That is, the theory of dissipative structure moves forward one step.
22、 胡家聪 "熵概念渊源初探" P177 摘自王福山主编 《 近代物理学 史研究 》 22, Hu Jiacong "Preliminary Study on the Origin of Entropy Concept" P177 Selected by Wang Fushan, Editor-in-Chief of Modern Physics History
23 、 胡家聪 "熵概念渊源初探" P177 摘自王福山主编 《 近代物理 学史研究 》 23, Hu Jiacong "Preliminary Study on the Origin of Entropy Concept" P177 Selected by Wang Fushan, Editor-in-Chief of Modern Physics History
24 、 朱明善等 《 热力学分析 》 P86 高等教育出版社 1992 版 24, Zhu Mingshan, etc. Thermodynamic Analysis P86 Higher Education Press, 1992 Edition
25、 朱明善等 《 热力学分析 》 P379 25, Zhu Mingshan, etc. Thermodynamic Analysis P379
26、 白蚁中的 "瀚隋者"有一定比例, 必须原瀚隋者死亡, 方能按照钟 形曲线补充。 人类社会的贫富也按此曲线配比。 26. There is a certain proportion of the "squatters" in termites, and the original ones must die before they can be supplemented according to the bell curve. The rich and the poor in human society are also matched according to this curve.
27、 陈光明、 陈国邦编, 制冷与低温原理 P32 27, Chen Guangming, Chen Guobang, The principle of refrigeration and low temperature P32
28 、 汪志诚 《 热力学 · 统计物理 》 P40 28, Wang Zhicheng, Thermodynamics, Statistical Physics, P40
29 、 美 · 迈伦 · 特赖布斯等 《 能量和信息 》 摘译 74 . 2 期 P8 30、 《 21 世纪科学, 探索 · 实验文库 》 "熵的故事" P92 29, US · Myron Trebs and other "Energy and Information" excerpt 74 . 2 P8 30, "21st Century Science, Exploration · Experimental Library" "The Story of Entropy" P92
5 、 能量集中的方案 5, energy concentration scheme
本发明提供一种方法, 它能让空气、 地表水(江河湖海)、 地源热等已沦 为玩的废热成为可再生能源, 其特征是: 1 、 由空气等废热为热源, 工质吸 收该废热, 在真空中膨胀; 2 、工质染上电荷服从电场变化的指令将无序转 为有序; 3 、 由电磁感应, 在次级获得感应电流。
附图的筒要说明 The invention provides a method, which can make waste heat which has been played as air, surface water (river, river and sea), ground source heat, etc. into renewable energy, and is characterized by: 1. Waste heat from air and the like as a heat source, working medium Absorbing the waste heat and expanding in a vacuum; 2. The instruction to change the charge on the working medium to obey the electric field will turn the disorder into order; 3. Inductive current is obtained in the secondary by electromagnetic induction. The barrel of the drawing is to be explained
图 1 中热机只要去冷源 Q2 的部分少点划线这一块,就能多输出功 w2 一块 In Figure 1, the heat engine only needs to go to the part of the cold source Q2 with less dotted lines, and it can output more work w2
图 2、 3 、 4 图 2 中真实气体压缩成液过程比理想气体反而少作功 ba ' a , 原因是真实气体在图 3 中有一 ba过程, 即靠分子间引力凝结成液滴, 而分子间产生引力的距离在图 4 中可以看到 Y。- ¥ 2 ( ^时最大) 这就是理 想过程失去效率之最的原因。 Figure 2, 3, and 4 The real gas compression process in Figure 2 is less than the ideal gas. The reason is that the real gas has a ba process in Figure 3, that is, it condenses into droplets by intermolecular attraction, and the molecule The distance between which gravitation is generated can be seen in Figure 4. - ¥ 2 (maximum when ^) This is the most important reason for the loss of efficiency in the ideal process.
图 5 大自然中循环是由不可逆过程首尾相接而构成, abc 过程不可能 由 cba 回去, 而必须是另一动力的不可逆过程 cda 回去。 Figure 5: The loops in nature are formed by the irreversible process. The abc process cannot be returned by cba, but must be the irreversible process of another power.
图 6 表示自从"耗散结构"理论确立后,可以有一个负熵过程 X存在, 其中 A为不可逆规律 B 为熵增率, C 为克氏表述 D 为运动有序 F 为结 构有序。 Figure 6 shows that since the theory of "dissipative structure" is established, there can be a negative entropy process X, where A is the irreversible law B is the entropy increase rate, C is the Kelvin expression D is the motion order F is the structure order.
图 7 为卡诺循环的示意图 , Figure 7 is a schematic diagram of the Carnot cycle.
图 8 为等温线族 Τοΐγΐ^与大气压交点 00 ' 0"和对应体积。 Figure 8 shows the isotherm family Τοΐγΐ^ and the atmospheric pressure intersection 00 ' 0" and the corresponding volume.
图 9 为负熵图, Α与 Β 所含热量相等, 但温度不同, A 向 B 变是 负熵过程, B 向 A正熵过程 Figure 9 is a negative entropy diagram. The heat contained in Α and Β is equal, but the temperature is different. A to B is a negative entropy process, and B is a positive entropy process.
图 10 为诞生负温度的重要原因是力场反转 Figure 10 shows that the important reason for the birth of negative temperature is force field reversal.
图 11 为麦克斯韦钟型曲线,温度虽由 降到 T2但在高速分子诞生的 阴影处, τ2 的 "脚"仍然伸到, 也就是说高速分子仍诞生。 Figure 11 shows Maxwell's bell curve. Although the temperature is lowered to T 2 but in the shadow of high-speed molecules, the "foot" of τ 2 still extends, which means that high-speed molecules are still born.
图 12 三位循环示意图 Figure 12 Schematic diagram of three-digit cycle
图 13 由负熵流加入的循环 Figure 13 Loop added by negative entropy flow
图 14 由负熵流加入的循环简化图 Figure 14 Simplified diagram of the cycle added by the negative entropy flow
图 15是本发明的附图说明 ab 、 be 两过程是等温膨胀和绝热膨胀, cd 过程是负熵过程, 该过程在力场的变化下诞生, de 过程回到原点。 Figure 15 is a diagram of the present invention. The ab and be processes are isothermal expansion and adiabatic expansion. The cd process is a negative entropy process, which is born under the change of the force field, and the de process returns to the origin.
图 16 由三维循环带来有序能的原理图甲实验图乙 Figure 16 Schematic diagram of the orderly energy brought by the three-dimensional cycle
图 17 由三维循环带来有热能的原理图甲实验图乙 实现本发明的最佳方式 Figure 17 Schematic diagram of thermal energy brought by three-dimensional cycle. Experimental diagram B. The best way to achieve the present invention.
图 16 乙 1 是附有翅片的铜管, 铜管中间走冷媒, 铜管靠翅片吸热, 2 是冷媒加电室在这里由 2 . 1 供给电荷, 经 3 膨胀, 到 4 冷凝成液体, 图 中 6 是电源使冷凝加速也让膨胀气体经 3 的时候应带电而成为初级电流, 电磁感应使 AB 处输出电流。 Figure 16 B 1 is a copper tube with fins. The copper tube is in the middle of the refrigerant, the copper tube is heated by the fins, and 2 is the refrigerant charging chamber where the charge is supplied by 2.1, expanded by 3, and condensed into 4 Liquid, Figure 6 is the power supply to accelerate the condensation and let the inflation gas be charged to become the primary current when passing through 3, and the electromagnetic induction causes the output current at AB.
图 17 乙稍有不同, 4 . 1 内有接受热量的液体流动, 接受由冷媒送来
的热量。 工业应用性 Figure 17 B is slightly different, 4.1 has a liquid that accepts heat, and is accepted by the refrigerant. The heat. Industrial applicability
把空气中热能转变为电能。
Convert heat from the air into electricity.
Claims
1、本发明提供一种从空气等废热中获取可再生能源的理论和方法, 它能 让空气、 地表水(江河湖海)、 地源热等已沦为 的废热成为可再生能源, 其特征是: 1、 由空气等废热为热源, 工质吸收该废热, 在真空中膨胀; 2 、 工质染上电荷服从电场变化的指令将无序转为有序; 3、 由电磁感应, 在次 级获得感应电流。 1. The present invention provides a theory and method for obtaining renewable energy from waste heat such as air, which can make waste heat of air, surface water (river and lake), ground source heat and the like become renewable energy, and its characteristics. It is: 1. The waste heat such as air is used as the heat source, the working medium absorbs the waste heat and expands in the vacuum; 2, the instruction that the working medium is dyed with electric charge changes according to the electric field will be disorderly turned into order; 3. By electromagnetic induction, at times The stage obtains the induced current.
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CN1058090A (en) * | 1990-07-08 | 1992-01-22 | 朱伟民 | Freon recovery device |
CN1979052A (en) * | 2005-11-30 | 2007-06-13 | 任文华 | Skin effect electric water heater |
WO2008044008A2 (en) * | 2006-10-12 | 2008-04-17 | Energetix Genlec Limited | A closed cycle heat transfer device and method |
CN201280956Y (en) * | 2008-10-31 | 2009-07-29 | 郭清温 | Flue gas waste heat recovering and generating set |
CN101902177A (en) * | 2009-02-21 | 2010-12-01 | 许志治 | Theory and method for acquiring renewable energy sources from air and other waste heat |
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CN1058090A (en) * | 1990-07-08 | 1992-01-22 | 朱伟民 | Freon recovery device |
CN1979052A (en) * | 2005-11-30 | 2007-06-13 | 任文华 | Skin effect electric water heater |
WO2008044008A2 (en) * | 2006-10-12 | 2008-04-17 | Energetix Genlec Limited | A closed cycle heat transfer device and method |
CN201280956Y (en) * | 2008-10-31 | 2009-07-29 | 郭清温 | Flue gas waste heat recovering and generating set |
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