WO2011078316A1 - Étoffe tissée ou tricotée - Google Patents

Étoffe tissée ou tricotée Download PDF

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Publication number
WO2011078316A1
WO2011078316A1 PCT/JP2010/073310 JP2010073310W WO2011078316A1 WO 2011078316 A1 WO2011078316 A1 WO 2011078316A1 JP 2010073310 W JP2010073310 W JP 2010073310W WO 2011078316 A1 WO2011078316 A1 WO 2011078316A1
Authority
WO
WIPO (PCT)
Prior art keywords
heat
elastic fiber
knitted fabric
woven
polyurethane elastic
Prior art date
Application number
PCT/JP2010/073310
Other languages
English (en)
Japanese (ja)
Inventor
美由紀 森下
Original Assignee
日清紡テキスタイル株式会社
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by 日清紡テキスタイル株式会社 filed Critical 日清紡テキスタイル株式会社
Priority to CN201080058993.8A priority Critical patent/CN102666959B/zh
Priority to EP10839546.8A priority patent/EP2518201A4/fr
Priority to US13/518,599 priority patent/US20120270455A1/en
Publication of WO2011078316A1 publication Critical patent/WO2011078316A1/fr

Links

Classifications

    • D—TEXTILES; PAPER
    • D04—BRAIDING; LACE-MAKING; KNITTING; TRIMMINGS; NON-WOVEN FABRICS
    • D04B—KNITTING
    • D04B1/00—Weft knitting processes for the production of fabrics or articles not dependent on the use of particular machines; Fabrics or articles defined by such processes
    • D04B1/14—Other fabrics or articles characterised primarily by the use of particular thread materials
    • D04B1/18—Other fabrics or articles characterised primarily by the use of particular thread materials elastic threads
    • D—TEXTILES; PAPER
    • D03—WEAVING
    • D03D—WOVEN FABRICS; METHODS OF WEAVING; LOOMS
    • D03D15/00—Woven fabrics characterised by the material, structure or properties of the fibres, filaments, yarns, threads or other warp or weft elements used
    • D03D15/50—Woven fabrics characterised by the material, structure or properties of the fibres, filaments, yarns, threads or other warp or weft elements used characterised by the properties of the yarns or threads
    • D03D15/56—Woven fabrics characterised by the material, structure or properties of the fibres, filaments, yarns, threads or other warp or weft elements used characterised by the properties of the yarns or threads elastic
    • D—TEXTILES; PAPER
    • D04—BRAIDING; LACE-MAKING; KNITTING; TRIMMINGS; NON-WOVEN FABRICS
    • D04B—KNITTING
    • D04B21/00—Warp knitting processes for the production of fabrics or articles not dependent on the use of particular machines; Fabrics or articles defined by such processes
    • D04B21/14—Fabrics characterised by the incorporation by knitting, in one or more thread, fleece, or fabric layers, of reinforcing, binding, or decorative threads; Fabrics incorporating small auxiliary elements, e.g. for decorative purposes
    • D04B21/18—Fabrics characterised by the incorporation by knitting, in one or more thread, fleece, or fabric layers, of reinforcing, binding, or decorative threads; Fabrics incorporating small auxiliary elements, e.g. for decorative purposes incorporating elastic threads
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
    • Y10T442/00—Fabric [woven, knitted, or nonwoven textile or cloth, etc.]
    • Y10T442/30—Woven fabric [i.e., woven strand or strip material]
    • Y10T442/3008—Woven fabric has an elastic quality

Definitions

  • the present invention relates to a molded knitted fabric.
  • the present invention relates to a woven or knitted fabric that is provided with good moldability by using heat-bonded polyurethane elastic fibers.
  • Patent Document 1 discloses a technique of performing molding using polyurethane elastic fibers having a high heat setting rate.
  • Patent Laid-Open No. 2006-225817 discloses a technique for performing molding using polyurethane elastic fibers and nylon fibers.
  • the molding process is performed by applying excessive heat, so that the thermoplastic fiber of the surface yarn is cured, and as a result, the texture of the resulting woven fabric or knitted fabric is poor and tinged. There is a case.
  • Patent Document 3 discloses a technique for performing mold processing using a thread excellent in low-temperature setting property.
  • this yarn has excellent formability from a low temperature range, the appropriate range of processing temperature is narrow, so there are many restrictions in the dyeing process when creating a base fabric for molding, and there are fibers that can be shared. Limited.
  • the heat treatment temperature, mold processing temperature, or the like at the time of creating the base fabric is shifted to a high temperature side, there is a problem that the polyurethane elastic fiber is broken. Due to the yarn breakage of the polyurethane elastic fiber, the molded fabric is easily deformed, has no stretchability, and is inferior in appearance.
  • the present applicant has proposed a technique for achieving heat setting property, prevention of misalignment, and the like by using heat-bonded polyurethane elastic fibers in a woven or knitted fabric including polyurethane elastic fibers (Patent Documents 4 and 5).
  • Patent Documents 4 and 5 the technique for achieving heat setting property, prevention of misalignment, and the like by using heat-bonded polyurethane elastic fibers in a woven or knitted fabric including polyurethane elastic fibers.
  • this technology is limited to prevention of misalignment and fraying.
  • the present invention has been made to solve the above-described problems of the prior art, and the object of the present invention is to obtain mold processability even in a woven or knitted fabric containing natural fibers and recycled fibers without thermoplasticity.
  • the object of the present invention is to obtain mold processability even in a woven or knitted fabric containing natural fibers and recycled fibers without thermoplasticity.
  • thermoplastic fibers such as nylon and polypropylene with low heat resistance
  • the present inventor can obtain mold processability even when used in combination with natural fibers and recycled fibers having no thermoplasticity by using a predetermined heat-fusion polyurethane.
  • the present invention has been completed.
  • the molded woven or knitted fabric of the present invention is composed of a yarn including elastic fibers and at least one non-elastic fiber; the elastic fibers include a heat-bonded polyurethane elastic fiber of 17 dtex or more; At least a portion of the heat-sealable polyurethane elastic fiber is heat-sealed; molded at 120-190 ° C.
  • the elastic fiber is a polyurethane elastic fiber, the mixing ratio of the polyurethane elastic fiber in the fabric is 5% or more, and the mixing ratio of the heat-sealing polyurethane elastic fiber in the polyurethane elastic fiber is 50% or more.
  • the woven or knitted fabric has a color fading grade (conforming to JIS L0804) of grade 3 or higher after being dyed and molded. In a preferred embodiment, the woven or knitted fabric has a molding rate after molding of 20% or more.
  • mold processability can be obtained even with a woven or knitted fabric containing non-thermoplastic natural fibers or recycled fibers, and even with a woven or knitted fabric containing thermoplastic fibers such as nylon and polypropylene having low heat resistance, it can be processed. It is possible to mold the light-colored fabric without yellowing and curing the subsequent fabric.
  • the molded knitted or knitted fabric of the present invention has the following operations and effects.
  • (1) Formability can be ensured without losing the texture of the surface yarn and without curing.
  • (2) Natural fibers and recycled fibers can be used for the surface yarn, and polypropylene fibers that can only be used in low-temperature processing or yarns with special functions such as contact cooling and heat generation can be used in combination. .
  • the woven or knitted fabric of the present invention is composed of a yarn containing elastic fibers and at least one type of inelastic fiber, and is molded.
  • the elastic fiber includes a heat-bonded polyurethane elastic fiber of 17 dtex or more, and at least a part of the heat-bonded polyurethane elastic fiber is heat-sealed in the woven or knitted fabric. Mold processing is performed at 120 to 190 ° C.
  • an elastic fiber well known in the art can be used.
  • it is a polyurethane elastic fiber.
  • a polyurethane elastic fiber well known in the art can be used.
  • the heat-sealable polyurethane elastic fiber used in the present invention is a heat-sealable polyurethane elastic fiber capable of heat-sealing the intersections between the polyurethane elastic fibers, its composition, production method and the like are not particularly limited. Absent.
  • a polyol and an excess molar amount of diisocyanate are reacted to produce a polyurethane intermediate polymer having isocyanate groups at both ends, and easily react with the isocyanate groups of the intermediate polymer.
  • polyol A method of solidifying a polymer obtained by reacting a diisocyanate with a low molecular weight diamine or a low molecular weight diol, dissolving the polymer in a solvent, and then removing the solvent to form a yarn; (3) dissolving the solidified polymer in the solvent (4)
  • the above polyol, diisocyanate and low molecular weight diol To obtain a polymer and form the polymer without solidifying the polymer; or (5) after mixing the
  • the heat-sealable polyurethane elastic fiber is a both-end isocyanate group prepolymer (A) obtained by reacting a polyol and a diisocyanate, and a both-end hydroxyl group prepolymer obtained by reacting a polyol, a diisocyanate and a low molecular weight diol. It can be obtained by a method of melt spinning a polymer obtained by reacting the polymer (B). This method is preferable in terms of economy or environment because it does not involve recovery of the solvent.
  • the composition contains 50% by mass or more of the polyether polyol among the polyol components in the raw material. If it is such a composition, since the polymer excellent in alkali resistance can be obtained, the condition restrictions at the time of dyeing a common fiber can be reduced.
  • the heat-sealing performance of the heat-sealing polyurethane elastic fiber used in the present invention is preferably 0.15 cN / dtex or more, more preferably 0.30 cN / dtex or more. If the heat fusion force is less than 0.15 cN / dtex, satisfactory mold processability may not be obtained.
  • the heat fusion force is measured as follows.
  • the knitted fabric is cut in the course direction, and the deknitting tension of the heat-bonded polyurethane elastic fiber or the yarn containing the heat-bonded polyurethane elastic fiber knitted in the cut portion is measured.
  • the knitting speed is 100 mm / min, and the average knitting tension for 1 minute is measured.
  • the average knitting tension before and after heat treatment is measured, and then the average knitting tension (cN) after heat treatment is divided by the initial fineness (dtex) of the heat-bonded polyurethane elastic fiber.
  • the heat fusion force (cN / dtex) is used.
  • the thermal fusing force in this case is 0.15 cN / dtex or more, and it is judged as “complete fusing”.
  • the thickness of the heat-sealable polyurethane elastic fiber used in the present invention is preferably 17 dtex or more, more preferably 22 to 311 dtex, still more preferably 28 to 156 dtex, in terms of the texture of the resulting woven or knitted fabric. . If the polyurethane elastic fiber is thinner than 17 dtex, the area of the portion where the polyurethane elastic fibers are in contact with each other and heat-sealed, that is, the heat-sealing area becomes small, and as a result, the fabric setting property becomes low, and the desired It may be difficult to obtain moldability.
  • the upper limit of the fineness is not particularly limited, but since the fabric becomes rubber-like at a thick fineness, generally a finer fineness tends to be preferred.
  • the heat-sealable polyurethane elastic fiber used in the present invention may be a yarn (bare yarn) composed only of a heat-sealable polyurethane elastic fiber, a covering yarn (single covering yarn, double covering yarn), a twisted yarn, air It may be a composite yarn such as an entangled yarn.
  • a covering yarn that can arrange a heat-sealable polyurethane elastic fiber at the center of the composite yarn and that can easily control the coverage of the heat-sealable polyurethane elastic fiber and that can be uniformly coated is preferable.
  • the non-elastic fiber coated around the heat-sealable polyurethane elastic fiber is not particularly limited.
  • inelastic fibers include natural fibers such as cotton, hemp, wool, and silk, regenerated fibers such as rayon, cupra, and polynosic, semi-regenerated fibers such as acetate, and chemicals such as nylon, polyester, acrylic, and polypropylene. Synthetic fibers and the like can be used.
  • the elastic fiber in the fabric is preferably a polyurethane elastic fiber
  • the mixing ratio of the polyurethane elastic fiber in the fabric is preferably 5% or more, more preferably 8% or more. More preferably, it is 10% or more.
  • the upper limit of the mixing ratio of the polyurethane elastic fibers is preferably 35%, more preferably 25%.
  • the mixing ratio of the heat-sealing polyurethane elastic fiber in the polyurethane elastic fiber is preferably 50% or more, more preferably 80% or more, and further preferably 100%.
  • inelastic fibers well known in the art can be used.
  • specific examples of the non-elastic fiber include those described above with respect to the case where the composite yarn is used as the heat-sealable polyurethane elastic fiber.
  • the molded knitted or knitted fabric of the present invention is generally manufactured as follows. First, at least one type of the non-elastic fiber and the elastic fiber including a bare yarn of the heat-fusion polyurethane elastic fiber or a composite yarn containing the heat-fusion polyurethane elastic fiber are prepared. Using these elastic fibers and non-elastic fibers, a fabric is obtained as a woven or knitted fabric by weaving or knitting, etc., and then heat fusion of at least some of the heat-bonded polyurethane elastic fibers by heat treatment of heat setting or molding. Put on.
  • the woven or knitted fabric of the present invention can be composed of a woven fabric or a knitted fabric depending on its application.
  • the woven or knitted fabric of the present invention is made of, for example, a woven fabric, any of plain weave, twill weave, satin weave and the like may be used.
  • well-known knitting methods such as warp knitting and weft knitting, can be used appropriately.
  • the woven or knitted fabric of the present invention is composed of, for example, a knitted fabric, a knitted fabric obtained by plating knitting a heat-sealable polyurethane elastic fiber and at least one inelastic fiber is preferable.
  • the knitted fabric obtained by the plating knitting can stably heat-bond the heat-sealable polyurethane elastic fibers to each other at the intersection of the stitches during heat treatment, and can fix the stitches.
  • a flat knitted fabric, a rubber knitted fabric, a double-sided knitted fabric or the like can be used as appropriate.
  • the flat knitting is preferable because the dough is finished thinly and there is no significant change in the shape of the needle loop and the sinker loop even if it is partially stretched by molding.
  • the draft ratio of the heat-sealable polyurethane elastic fiber when weaving or knitting the fabric is preferably 1.0 to 3.6 times, more preferably 2.0 to 3.0 times.
  • the dough is processed in a normal process. For example, a series of processes of scouring-bleaching-preset-dying-final set is performed.
  • the processed fabric is molded.
  • the molding process is preferably performed at a temperature of 120 to 190 ° C.
  • the knitted or knitted fabric of the present invention can have a grade of color change or fading of the fabric subjected to the mold processing after the dyeing process. If it is less than 120 degreeC, a moldability may become inadequate.
  • the temperature is 190 ° C. or higher, yellowing and hardening of the surface yarn may occur, and the discoloration grade may not be cleared.
  • the color fading grade can be obtained in accordance with JIS L0804.
  • the mold processing is typically performed as follows. Further, the molding rate is calculated as follows.
  • An iron spherical jig (diameter 105 mm, weight 1.5 kg) as a mold processing jig is heated to a predetermined processing temperature with a dryer. When the temperature of the jig has stabilized, the jig is pressed against the fabric that has been left unstretched for 1 minute to be molded. At this time, the jig is submerged 70 mm. After standing at room temperature for 30 minutes, the indentation depth of the dough is measured, and the ratio with respect to the depth of 70 mm at the time of molding is calculated as the molding rate.
  • the molding rate is preferably 20% or more, more preferably 25% or more, and further preferably 30% or more. It is one of the achievements of the present invention that such a molding rate (mold processability) and an excellent color fading grade are compatible.
  • Example 1 Using 60/1 cotton as the front yarn and Mobilon R (22 dtex: bare yarn) as the heat-sealable polyurethane elastic fiber, the plate was knitted with a circular knitting machine (28 gauge) to prepare a plain knitted fabric. After this plain knitted fabric was dyed by a normal process, it was molded. Table 1 shows the details of the fibers used and the evaluation results of the mold processing.
  • Mobilon R is a registered trademark of Nisshinbo Textile Co., Ltd.
  • Roika is a registered trademark of Asahi Kasei Fibers Co., Ltd.
  • ESPAR is a registered trademark of Toyobo Co., Ltd.
  • bare represents polyurethane elastic fiber bare yarn
  • SCY represents single covering yarn
  • PP represents polypropylene
  • PU represents polyurethane elastic fiber.
  • Example 2 Using the fibers shown in Table 1, processing was performed in the same manner as in Example 1.
  • the structure of the heat-fusion polyurethane elastic fiber (SCY) used in Example 2 is as follows. Core: heat fusion polyurethane elastic fiber (Mobilon R), sheath: nylon (13 dtex) Draft magnification: 2.3 times, number of twists: 600 T / m
  • Table 1 shows the details of the fibers used for knitting and the evaluation results of the mold processing at the same magnification during the creation of the fabric. Examples 2 to 6 were carried out by changing the fineness of the heat-sealable polyurethane elastic fiber and / or the type of inelastic fiber used in combination.
  • Comparative Examples 1 to 5 Using the fibers shown in Table 2, processing was performed in the same manner as in Example 1. Table 2 shows the details of the fibers used and the evaluation results of the mold processing. Comparative Examples 1 to 5 were performed using elastic fibers other than the heat-sealing polyurethane elastic fibers. Both leuca and ESPAR used in the comparative examples are polyurethane fibers that do not have heat-fusibility.
  • Table 3 shows the results of tests conducted to confirm the formability of the used yarn.
  • the test was conducted according to the following procedure. Polyester 33T10 filament is used for the front yarn, polyurethane elastic fiber of Table 3 is used for the back yarn, and draft ratio is 2. using a pantyhose knitting machine (L416 / R made by Lonati, hook diameter: 4 inches, number of needles: 400). A plating knitting was performed at 0 times to create a plain knitted fabric. This was stretched 1.2 times with both vertical and horizontal, and heat set at 150 ° C. for 60 seconds to obtain a base fabric. This fabric was evaluated for mold processability at 120 ° C. treatment and heat-sealing power of polyurethane elastic fibers.
  • each example of the present invention is excellent in both the forming ratio and the color fading grade.
  • Comparative Examples 1 and 2 were inferior in moldability, and Comparative Examples 4 and 5 were inferior in color fading.
  • the moldability was good, but the polyurethane elastic fiber was broken.
  • mold processability can be obtained even with natural fibers and recycled fibers having no thermoplasticity, and the heat resistance is low. Even with a woven or knitted fabric containing thermoplastic fibers such as nylon and polypropylene, the processed fabric is not yellowed, and a light-colored fabric can be molded.
  • the woven or knitted fabric of the present invention can be suitably used in the clothing field.
  • it can be suitably used as underwear such as brassiere cups, shorts, girdle hips, knitted fabrics for inner sports such as swimwear, and outer fabrics such as bottoms.
  • the woven or knitted fabric of the present invention can be suitably used in other industrial fields, for example, as a laminate having elasticity.

Abstract

L'invention concerne une technique par laquelle même une étoffe tissée ou tricotée contenant une fibre non thermoplastique naturelle ou régénérée peut être moulée et par laquelle même une étoffe tissée ou tricotée de couleur claire contenant une fibre thermoplastique faiblement résistante à la chaleur comme du nylon ou du polypropylène peut être moulée sans subir un jaunissement ou un raidissement après moulage. L'invention concerne également une étoffe tissée ou tricotée qui est essentiellement composée d'un fil qui contient à la fois une fibre élastique et au moins une fibre non élastique et qui a fait l'objet d'un moulage. La fibre élastique contient une fibre élastique en polyuréthane thermofusible présentant une finesse d'au moins 17dtex et, au sein de l'étoffe tissée ou tricotée, la fibre élastique en polyuréthane thermofusible est au moins partiellement fondue thermiquement. L'étoffe tissée ou tricotée est produite par moulage entre 120 et 190°C.
PCT/JP2010/073310 2009-12-25 2010-12-24 Étoffe tissée ou tricotée WO2011078316A1 (fr)

Priority Applications (3)

Application Number Priority Date Filing Date Title
CN201080058993.8A CN102666959B (zh) 2009-12-25 2010-12-24 编织品
EP10839546.8A EP2518201A4 (fr) 2009-12-25 2010-12-24 Étoffe tissée ou tricotée
US13/518,599 US20120270455A1 (en) 2009-12-25 2010-12-24 Woven or knitted fabric

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
JP2009-295421 2009-12-25
JP2009295421A JP5485687B2 (ja) 2009-12-25 2009-12-25 織編物

Publications (1)

Publication Number Publication Date
WO2011078316A1 true WO2011078316A1 (fr) 2011-06-30

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Family Applications (1)

Application Number Title Priority Date Filing Date
PCT/JP2010/073310 WO2011078316A1 (fr) 2009-12-25 2010-12-24 Étoffe tissée ou tricotée

Country Status (5)

Country Link
US (1) US20120270455A1 (fr)
EP (1) EP2518201A4 (fr)
JP (1) JP5485687B2 (fr)
CN (1) CN102666959B (fr)
WO (1) WO2011078316A1 (fr)

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KR20130111874A (ko) 2012-04-02 2013-10-11 삼성디스플레이 주식회사 박막 트랜지스터, 이를 포함하는 박막 트랜지스터 표시판 및 표시 장치, 그리고 박막 트랜지스터의 제조 방법
CN104552934A (zh) * 2013-10-22 2015-04-29 谢贤晓 织物成形方法
CN103952849A (zh) * 2014-05-21 2014-07-30 香港中大实业有限公司 针织物的生产方法、针织物和针织鞋
WO2019105402A1 (fr) * 2017-11-30 2019-06-06 东丽纤维研究所（中国）有限公司 Tissu tricoté moulé
KR20190127877A (ko) * 2018-02-23 2019-11-13 나카노 산교 가부시키가이샤 주머니 모양 필터
US10758007B2 (en) 2018-07-03 2020-09-01 Under Armour, Inc. Article with thermally bonded ribbon structure and method of making
US10786043B2 (en) * 2018-07-03 2020-09-29 Under Armour, Inc. Article with thermally bonded ribbon structure and method of making
US20220042217A1 (en) * 2019-03-01 2022-02-10 Kaihara Co., Ltd. Stretchable fabric, and manufacturing method and manufacturing device for same

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WO2003033797A1 (fr) * 2001-10-15 2003-04-24 Asahi Kasei Fibers Corporation Tricot circulaire destine a etre utilise pour la confection de vetements de mode
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WO2003033797A1 (fr) * 2001-10-15 2003-04-24 Asahi Kasei Fibers Corporation Tricot circulaire destine a etre utilise pour la confection de vetements de mode
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WO2004053218A1 (fr) 2002-12-12 2004-06-24 Nisshinbo Industries, Inc. Textiles melanges tisses ou tricotes, contenant des fibres elastiques de polyurethanne, et leur procede de production
JP2006225817A (ja) 2005-02-21 2006-08-31 Social:Kk ヒップ下部に持ち上げ力を付与した補整機能を有するガードル及びその製造方法
JP2007182649A (ja) 2006-01-10 2007-07-19 Nisshinbo Ind Inc 熱融着ポリウレタン弾性繊維混用緯編地及び該緯編地を使用した衣類、並びに該緯編地の製造方法
JP2008138298A (ja) 2006-11-30 2008-06-19 Toyobo Co Ltd モールド加工品

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Title
See also references of EP2518201A4

Also Published As

Publication number Publication date
EP2518201A4 (fr) 2015-05-13
JP2011132644A (ja) 2011-07-07
US20120270455A1 (en) 2012-10-25
JP5485687B2 (ja) 2014-05-07
CN102666959B (zh) 2014-08-13
EP2518201A1 (fr) 2012-10-31
CN102666959A (zh) 2012-09-12

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