WO2011050554A1 - Method for directly burning and dispersedly supplying heat in biomass pyrolysis furnace - Google Patents

Method for directly burning and dispersedly supplying heat in biomass pyrolysis furnace Download PDF

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Publication number
WO2011050554A1
WO2011050554A1 PCT/CN2010/000022 CN2010000022W WO2011050554A1 WO 2011050554 A1 WO2011050554 A1 WO 2011050554A1 CN 2010000022 W CN2010000022 W CN 2010000022W WO 2011050554 A1 WO2011050554 A1 WO 2011050554A1
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pyrolysis furnace
biomass
pyrolysis
furnace
combustion
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PCT/CN2010/000022
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French (fr)
Chinese (zh)
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韩剑锋
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中节环(北京)能源技术有限公司
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Publication of WO2011050554A1 publication Critical patent/WO2011050554A1/en

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    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10BDESTRUCTIVE DISTILLATION OF CARBONACEOUS MATERIALS FOR PRODUCTION OF GAS, COKE, TAR, OR SIMILAR MATERIALS
    • C10B53/00Destructive distillation, specially adapted for particular solid raw materials or solid raw materials in special form
    • C10B53/02Destructive distillation, specially adapted for particular solid raw materials or solid raw materials in special form of cellulose-containing material
    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10BDESTRUCTIVE DISTILLATION OF CARBONACEOUS MATERIALS FOR PRODUCTION OF GAS, COKE, TAR, OR SIMILAR MATERIALS
    • C10B49/00Destructive distillation of solid carbonaceous materials by direct heating with heat-carrying agents including the partial combustion of the solid material to be treated
    • C10B49/02Destructive distillation of solid carbonaceous materials by direct heating with heat-carrying agents including the partial combustion of the solid material to be treated with hot gases or vapours, e.g. hot gases obtained by partial combustion of the charge
    • C10B49/04Destructive distillation of solid carbonaceous materials by direct heating with heat-carrying agents including the partial combustion of the solid material to be treated with hot gases or vapours, e.g. hot gases obtained by partial combustion of the charge while moving the solid material to be treated
    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F23COMBUSTION APPARATUS; COMBUSTION PROCESSES
    • F23GCREMATION FURNACES; CONSUMING WASTE PRODUCTS BY COMBUSTION
    • F23G5/00Incineration of waste; Incinerator constructions; Details, accessories or control therefor
    • F23G5/02Incineration of waste; Incinerator constructions; Details, accessories or control therefor with pretreatment
    • F23G5/027Incineration of waste; Incinerator constructions; Details, accessories or control therefor with pretreatment pyrolising or gasifying stage
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02EREDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
    • Y02E50/00Technologies for the production of fuel of non-fossil origin
    • Y02E50/10Biofuels, e.g. bio-diesel

Definitions

  • the direct combustion and dispersion heating method of the biomass pyrolysis furnace of the invention relates to the technical field of energy chemical industry; in particular to the field of thermochemical technology of biomass; in particular, the medium temperature is rapid for biomass gasification of the entrained flow of biomass
  • the technical field of pyrolysis treatment specifically relates to the technical field of direct combustion dispersion heating method of biomass pyrolysis furnace. Background technique
  • Biomass is an organic substance produced by the absorption of carbon dioxide in the air through photosynthesis. It is widely distributed, widely available, and is the only renewable natural raw material that contains hydrocarbon components and heat. It can be used as energy source. Utilization and chemical production, with the characteristics of C0 2 zero emissions. With the decreasing of traditional fossil energy reserves and the environmental pollution caused by the use of fossil energy, it has become the consensus of governments of all countries to attach importance to and develop renewable and environmentally friendly energy. Through thermochemical, biochemical and other methods, it can transform biomass into clean gas or liquid fuel, produce synthetic diesel/gasoline, chemical products and meet power demand, etc. It has the potential to completely replace fossil energy and become a priority for countries around the world. New energy.
  • biomass high-temperature entrained gas gasification technology can adapt to all kinds of biomass compared with other technologies.
  • the gasification temperature is higher, and the furnace temperature is compared.
  • Uniform, the tar is completely cracked in the entrained flow bed, the CH 4 content is less, and the gasification is refined to obtain refined syngas;
  • the bed has excellent magnification characteristics and is especially suitable for large industrial applications.
  • 5% ⁇ Refined synthesis gas refers to: in the synthesis gas directly obtained by gasification, CO and the main component, no tar, CH 4 content ⁇ 0. 5%.
  • Refined syngas is mainly used in the production of synthetic diesel/gasoline, olefins, alkanes, naphtha, lubricating oil, and as a fuel cell raw material, etc. It is suitable for the production of various chemical products and new energy utilization of various ultra-clean oil products. Especially in the field of renewable bio-energy utilization, it is the key technology of bio-shield chemical industry and biomass-based synthetic oil new energy industry.
  • the entrained flow gasification has strict limits on the particle size of the raw materials, and the raw materials entering the entrained flow bed need to be ground into ultrafine micron-sized particles.
  • the existing crushing or milling technology it is impossible to contain more fibers.
  • the biomass feedstock is ground to meet the particle size required for the operation of the entrained flow bed, which results in the inability to directly use the biomass feedstock for gasification of the entrained flow bed; preferably, the biomass is pyrolyzed into pyrolysis gas and solid state.
  • the charcoal is then sent to the gas stream bed for gasification together with the solid carbon powder and the pyrolysis gas.
  • the best method is to carry out the medium temperature rapid pyrolysis treatment and decompose the biomass at a medium pyrolysis temperature of 400 °C ⁇ 60 TC (referred to as medium temperature pyrolysis).
  • the hot degassing and solid carbon grinding the solid carbon into carbon powder) are then sent to an entrained gas bed for gasification.
  • the key to realizing the rapid pyrolysis technology of biomass is the heating method of pyrolysis furnace, which is the heat utilization efficiency, pyrolysis rate, pyrolysis product quality, and pyrolysis equipment cost and pyrolysis of biomass pyrolysis.
  • the heating methods for pyrolysis of biomass are mainly divided into two types, one is indirect heat transfer pyrolysis, and the other is direct heat transfer pyrolysis.
  • Indirect heat transfer pyrolysis is the transfer of heat to the heating element of the pyrolysis furnace, which then transfers the heat to the biomass to be pyrolyzed, as in the application number.
  • direct heat transfer pyrolysis generally uses direct combustion of heat in a pyrolysis furnace with oxidant and/or external fuel.
  • the pyrolysis furnace in the Carbon-V process of Colin Company of Germany burns and supplies heat.
  • direct heat transfer pyrolysis is a better method, and the best method that can be implemented by engineering is direct combustion and heat pyrolysis.
  • all known direct combustion and heat pyrolysis methods have various deficiencies and safety hazards, and cannot simultaneously satisfy high heat transfer efficiency, high heat utilization efficiency, combustion heat supply safety, and operation.
  • Industrialized implementation requirements such as safety and stability, low investment in pyrolysis furnace equipment.
  • the direct combustion dispersion heating method of the biomass pyrolysis furnace of the present invention is a key technology that must be preferentially solved in the medium temperature rapid pyrolysis technology of biomass renewable solid fuel.
  • the biomass pyrolysis furnace of the invention adopts the key technology of "direct combustion and dispersion heating", and the heating and burning device of the pyrolysis furnace is composed of a plurality of burner groups, all of which are arranged in the upper part of the pyrolysis furnace, and Disposed in the axial direction in the upper part of the pyrolysis furnace, and each burner group is composed of a plurality of small burner nozzles, and the maximum temperature of the combustion zone in the pyrolysis furnace is controlled below 1600 ° C; heating for the pyrolysis furnace
  • the fuel and oxidant are separated before entering the pyrolysis furnace, and are non-premixed combustion in the pyrolysis furnace; the pyrolysis furnace is horizontally arranged, and the outer casing is fixed, and the stirring furnace is stirred in the pyrolysis furnace.
  • the shaft rotates to agitate the biomass; according to the pyrolysis temperature requirement of the biomass feedstock entering the pyrolysis furnace, the average temperature in the pyrolysis furnace can be controlled by adjusting the amount of the oxidant; the pyrolysis furnace can be adjusted during operation The amount of fuel supplied externally and the content of the inert component in the oxidant to adjust the maximum temperature of the combustion zone, and the combustion zone can also be adjusted by adjusting the rotational speed of the agitator shaft with the stirring rod The highest temperature.
  • the objects achieved by the present invention are as follows: 1. To create the preconditions for the gasification of biomass by applying an entrained flow bed; 2. To make full use of the new biomass of natural biomass, large quantity, wide distribution and renewable "biomass” Waste is a treasure and effectively protect the environment; 3.
  • the application adopts the horizontal pyrolysis furnace. Under the premise of meeting the technical requirements of "medium temperature rapid pyrolysis", the key technology of "direct combustion and dispersion heating” is provided, and the direct combustion dispersion of the biomass pyrolysis furnace is provided.
  • the thermal method has realized the technical requirements of high efficiency of biomass pyrolysis furnace, safety of combustion and heat supply, safe and stable operation, and low investment in equipment;
  • the present invention achieves the intended purpose.
  • the technical solution provided by the present invention is:
  • a direct combustion dispersion heating method for a biomass pyrolysis furnace the heating combustion device of the pyrolysis furnace is composed of a plurality of burner groups, all of which are arranged in the upper part of the pyrolysis furnace, and in the pyrolysis furnace The upper part is arranged in the axial direction, and each burner group is composed of a plurality of small burner nozzles, and the maximum temperature of the combustion zone in the pyrolysis furnace is controlled at
  • the direct combustion dispersion heating method of the biomass pyrolysis furnace wherein the fuel and the oxidant for heating the pyrolysis furnace are separated before entering the pyrolysis furnace, and the pyrolysis furnace is Non-premixed combustion.
  • the direct combustion dispersion heating method of the biomass pyrolysis furnace is arranged horizontally, and the furnace body shell of the pyrolysis furnace is fixed, and the pyrolysis furnace adopts a stirring rod
  • the agitator shaft rotates to agitate the biomass. .
  • the direct combustion and dispersion heating method of the biomass pyrolysis furnace is a plant root/stem/leaf/flower/fruit, animal carcass, feces, waste rubber, coal and carbohydrate waste.
  • the direct combustion dispersion heating method of the biomass pyrolysis furnace the fuel is divided into an externally supplied fuel, and a part of the pyrolysis gas generated by pyrolysis of the biomass inside the pyrolysis furnace, and the externally supplied fuel It is one of a combustible gas and a fuel; the oxidant is one of oxygen, air, a mixture of oxygen and carbon dioxide, and a mixture of oxygen and nitrogen.
  • the direct combustion dispersion heating method of the biomass pyrolysis furnace can adjust the maximum temperature of the combustion zone by adjusting the amount of externally supplied fuel and the inert component content of the oxidant during operation.
  • the direct combustion dispersion heating method of the bio-shield pyrolysis furnace can also adjust the maximum temperature of the combustion zone by adjusting the rotation speed of the stirring shaft with the stirring rod during the operation.
  • the direct combustion dispersion heating method of the biomass pyrolysis furnace can control the average temperature in the pyrolysis furnace by adjusting the amount of the oxidant according to the pyrolysis temperature requirement of the biomass raw material entering the pyrolysis furnace.
  • the technical solution provided by the present invention is adopted. Since the pyrolysis furnace of the present invention satisfies the technical requirements of "medium temperature rapid pyrolysis of biomass", the key technology of "direct combustion and dispersion heating" is adopted.
  • the heating and burning device of the pyrolysis furnace of the present invention is composed of a plurality of burner groups, all of the burner groups are arranged in the upper part of the pyrolysis furnace, and are arranged in the axial direction in the upper part of the pyrolysis furnace, and each burner is arranged.
  • the groups are composed of a plurality of small burner nozzles, and the maximum temperature of the combustion zone in the pyrolysis furnace is controlled below 1600 ° C; the fuel and oxidant for heating the pyrolysis furnace are separated before entering the pyrolysis furnace.
  • Non-premixed combustion in the pyrolysis furnace the pyrolysis furnace is horizontally arranged and the outer casing is solid
  • the stirring shaft with the stirring rod is rotated to stir the biomass; according to the pyrolysis temperature requirement of the biomass raw material entering the pyrolysis furnace, the average amount in the pyrolysis furnace can be controlled by adjusting the amount of the oxidizing agent.
  • Temperature; during the operation of the pyrolysis furnace, the maximum temperature of the combustion zone can be adjusted by adjusting the amount of fuel supplied from the outside and the content of inert components in the oxidant, and also by adjusting the rotation speed of the stirring shaft with the stirring rod To adjust the maximum temperature of the combustion zone.
  • the biomass of the present invention is plant roots/stems/leaves/flowers/fruits, animal carcasses, feces, coal and carbohydrate waste, and according to the pyrolysis temperature requirements of the biomass feedstock entering the pyrolysis furnace, By adjusting the amount of oxidant to control the average temperature in the pyrolysis furnace, the beneficial effects of large amount of natural raw materials, wide distribution, reproducible, convenient material selection, large choice of choice, and pyrolysis average temperature can be adjusted according to changes in raw material requirements. .
  • the heating fuel of the present invention can be either an external fuel such as a combustible gas and a fuel oil, or a pyrolysis gas generated by pyrolysis of biomass inside the pyrolysis furnace, the oxidant is a mixture of air, oxygen, oxygen and carbon dioxide gas.
  • the mixed gas of oxygen and nitrogen thereby obtaining the advantages of large selection of fuel and oxidant, stable and reliable combustion, and easy implementation.
  • the pyrolysis furnace used in the present invention is horizontally arranged and the outer casing is fixed, the pyrolysis furnace is rotated by the stirring shaft with the stirring rod to stir the biomass, thereby obtaining the direct combustion of the pyrolysis furnace.
  • the method of decentralized heating "based on the layout design, engineering implementation and installation operation of the pyrolysis furnace, and achieving uniform temperature in the pyrolysis furnace, Biomass heat transfer efficiency and other effects
  • the pyrolysis furnace heating and burning device of the present invention is composed of a plurality of burner groups, all of the burner groups are arranged in an upper portion of the pyrolysis furnace, and are arranged in the axial direction in the upper portion of the pyrolysis furnace, and each The burner group is composed of a plurality of small burner nozzles, and the maximum temperature of the combustion zone in the pyrolysis furnace is controlled below 1600 ° C, thereby satisfying the high efficiency of the medium-temperature rapid pyrolysis of biomass, the safety of combustion heating, and the safe and stable operation.
  • the low investment requirement of the equipment has obtained the beneficial effect of implementing the carrier of the "biomass pyrolysis furnace direct combustion dispersion heating method".
  • the pyrolysis furnace according to the present invention can adjust the maximum temperature of the combustion zone by adjusting the amount of fuel supplied from the outside and the content of the inert component in the oxidant during operation; and also adjusting the stirring rod by adjusting The rotation speed of the stirring shaft is used to adjust the maximum temperature of the combustion zone, thereby obtaining the adjustment of the "highest temperature of the combustion zone".
  • the specific implementation is flexible, simple, convenient, fast and effective, and is convenient for engineering implementation and application, and reducing the investment of equipment. effect.
  • the key technology of "direct combustion and dissipative heating” has obtained the technical requirements to meet the "medium temperature rapid pyrolysis of biomass", providing "direct combustion and dispersive heating method for pyrolysis furnace with rapid pyrolysis of biomass”.
  • a direct combustion dispersion heating method for a biomass pyrolysis furnace the heating combustion device of the pyrolysis furnace is composed of a plurality of burner groups, all of which are arranged in the upper part of the pyrolysis furnace, and in the pyrolysis furnace The upper portion is axially dispersed, and each burner group is composed of a plurality of small burner nozzles, and the maximum temperature of the combustion zone in the pyrolysis furnace is controlled below 1600 °C.
  • the direct combustion dispersion heating method of the biomass pyrolysis furnace wherein the fuel and the oxidant for heating the pyrolysis furnace are separated before entering the pyrolysis furnace,
  • the pyrolysis furnace is non-premixed combustion.
  • the direct combustion dispersion heating method of the biomass pyrolysis furnace is arranged horizontally, and the furnace body of the pyrolysis furnace is fixed, and the pyrolysis furnace is equipped with a stirring rod
  • the agitator shaft rotates to agitate the biomass.
  • the direct combustion and dispersion heating method of the biomass pyrolysis furnace the biomass is plant root/stem/leaf/flower/fruit, animal carcass, feces, waste rubber, coal and carbohydrate compound waste.
  • the direct combustion dispersion heating method of the biomass pyrolysis furnace the fuel is divided into an externally supplied fuel, and a part of the pyrolysis gas generated by pyrolysis of the biomass inside the pyrolysis furnace, and the externally supplied fuel It is one of a combustible gas and a fuel; the oxidant is one of oxygen, air, a mixture of oxygen and carbon dioxide, and a mixture of oxygen and nitrogen.
  • the direct combustion dispersion heating method of the bio-shield pyrolysis furnace can adjust the maximum temperature of the combustion zone by adjusting the amount of externally supplied fuel and the inert component content of the oxidant during operation.
  • the direct combustion dispersion heating method of the biomass pyrolysis furnace in the operation of the pyrolysis furnace, can also adjust the maximum temperature of the combustion zone by adjusting the rotation speed of the stirring shaft with the stirring rod.
  • the direct combustion dispersion heating method of the biomass pyrolysis furnace can control the average temperature in the pyrolysis furnace by adjusting the amount of the oxidant according to the pyrolysis temperature requirement of the biomass raw material entering the pyrolysis furnace.
  • a horizontally arranged pyrolysis furnace and heat
  • the furnace shell is fixed, and the stirring of the stirring shaft with the stirring rod is used in the pyrolysis furnace to carry out the stirring of the biomass; according to the biomass pyrolysis yield, the burner is arranged on the pyrolysis furnace
  • the groups are arranged in a distributed manner and are implemented in two or more different quantities respectively; likewise, according to the size of the output, the small burner nozzles of each of the burner groups are also respectively carried out in more than four different quantities.
  • Determining the average pyrolysis temperature of the furnace taking the maximum temperature of the combustion flame zone in the pyrolysis furnace to be 1600 ° C or less, respectively, by changing the fuel
  • the supply amount is used to adjust the maximum temperature of the combustion zone and to make it stable, to change the maximum temperature of the combustion zone by changing the content of the inert component in the oxidant and to make it stable, by adjusting the stirring of the pyrolysis furnace
  • the rotation speed of the stirring shaft of the rod is adjusted to adjust the maximum temperature of the combustion zone and to make it stable.
  • the pyrolysis furnace adopts the horizontal arrangement, and the outer casing is fixed, and the structural cylinder in which the stirring shaft rotating with the stirring rod is used to stir the biomass in the pyrolysis furnace provides the implementation of the invention.
  • Carrier 2, application of pyrolysis furnace
  • the direct combustion and dispersive heating method is scientific and reasonable, and satisfies the technical requirements of "medium temperature rapid pyrolysis of biomass”;
  • the burner group of the present invention is dispersedly arranged, and each burner group is composed of a plurality of small burner nozzles.
  • the fuel and the oxidant are non-premixed combustion in the pyrolysis furnace, fully embodying the safety, reliability, operability, and material requirements and cost of the pyrolysis furnace equipment of the present invention; 4.
  • the present invention The pyrolysis furnace can adjust the maximum temperature of the combustion zone by adjusting the amount of fuel supplied from the outside during operation, and can adjust the maximum temperature of the combustion zone by adjusting the content of inert components in the oxidant, and can also adjust the The speed of the stirring shaft with the stirring rod is adjusted to adjust the maximum temperature of the combustion zone, thereby realizing the adjustment of the core "highest temperature of the combustion zone" in the pyrolysis furnace technology, and the operation is flexible and convenient in the specific implementation.

Abstract

A method for directly burning and dispersedly supplying heat in a biomass pyrolysis furnace is provided, wherein a heat supply combustion device of the pyrolysis furnace is composed of several burner groups (2), all of which are dispersedly arranged at the upper part of the pyrolysis furnace along the axial direction. Each burner group (2) is composed of several small burner nozzles (3). The highest temperature in the combustion area of the furnace is controlled at less than 1600 0C. The fuel supplying heat for the furnace and the oxidizer are separated before entering into the furnace and burnt in a non-premixed combustion mode in the furnace. The pyrolysis furnace is horizontally arranged and has a fixed casing (1). The biomass in the furnace is stirred by a mixing shaft (4) with bars (5). The highest temperature in the combustion area is regulated by adjusting the heat supplied from the external fuel and/or the content of the inert component in the oxidizer and/or rotating speed of the mixing shaft (4) with bars (5) in the process.

Description

生物质热解炉的直接燃烧分散供热方法 技术领域  Direct combustion and dispersion heating method for biomass pyrolysis furnace
本发明的生物质热解炉的直接燃烧分散供热方法,涉及能源 化工技术领域; 特别涉及生物质的热化学技术领域; 尤其涉及为 了实现生物质的气流床气化而对生物质进行中温快速热解处理 的技术领域;具体涉及生物质热解炉的直接燃烧分散供热方法的 技术领域。 背景技术  The direct combustion and dispersion heating method of the biomass pyrolysis furnace of the invention relates to the technical field of energy chemical industry; in particular to the field of thermochemical technology of biomass; in particular, the medium temperature is rapid for biomass gasification of the entrained flow of biomass The technical field of pyrolysis treatment; specifically relates to the technical field of direct combustion dispersion heating method of biomass pyrolysis furnace. Background technique
生物质是通过光合作用吸收空气中二氧化碳生成的有机物 质, 其分布广泛、 可利用量大、 并且是唯一可再生的含有碳氢组 分和热能的、可储存的自然原料; 利用生物质进行能源利用和化 工生产, 具有 C02零排放的特征。 随着传统化石能源储量的日益 减少, 以及由于使用化石能源带来的环境污染问题, 重视和发展 可再生、 环保能源已成为各国政府的共识。 通过热化学、 生物化 学等方法, 能够将生物质转变为清洁的气体或液体燃料, 生产合 成柴油 /汽油、 化工产品以及满足电力需求等等, 具有全面替代 化石能源的潜力, 成为世界各国优先发展的新能源。 Biomass is an organic substance produced by the absorption of carbon dioxide in the air through photosynthesis. It is widely distributed, widely available, and is the only renewable natural raw material that contains hydrocarbon components and heat. It can be used as energy source. Utilization and chemical production, with the characteristics of C0 2 zero emissions. With the decreasing of traditional fossil energy reserves and the environmental pollution caused by the use of fossil energy, it has become the consensus of governments of all countries to attach importance to and develop renewable and environmentally friendly energy. Through thermochemical, biochemical and other methods, it can transform biomass into clean gas or liquid fuel, produce synthetic diesel/gasoline, chemical products and meet power demand, etc. It has the potential to completely replace fossil energy and become a priority for countries around the world. New energy.
将生物质转变为清洁气体或液体燃料的方法很多, 在这其 中,生物质高温气流床气化技术与其它技术相比能够适应所有的 生物质种类, 其气化温度较高, 炉内温度比较均匀, 焦油在气流 床中全部裂解, CH4含量较少, 气化得到精制合成气; 同时气流 床具有很好的放大特性, 特别适用于大型工业化的应用。 而精制 合成气指的是: 气化直接得到的合成气中, CO和 为主要组分, 无焦油, CH4含量 <0. 5%。 精制合成气主要用于生产合成柴油 /汽 油、 烯烃、烷烃、石脑油、 润滑油, 以及作为燃料电池原料等等, 适用于生产各种化工产品、 以及各种超清洁油品的新能源利用; 特别在可再生的生物廣能源利用领域, 它是生物盾化工产业、 生 物质合成油新能源产业的关键技术。但是, 气流床气化对原料的 粒径有着严格的限制,进入气流床的原料需要磨成超细的微米级 的颗粒, 然而按照现有的破碎或制粉技术, 无法将含纤维较多的 生物质原料磨制成满足气流床运行所需的粒径,这就导致了无法 将生物质原料直接用于气流床气化;最好就是先将生物质进行热 解分解成热解气和固态炭,然后将固态炭制粉和热解气一起送入 气流床中气化。 There are many ways to convert biomass into clean gas or liquid fuel. Among them, biomass high-temperature entrained gas gasification technology can adapt to all kinds of biomass compared with other technologies. The gasification temperature is higher, and the furnace temperature is compared. Uniform, the tar is completely cracked in the entrained flow bed, the CH 4 content is less, and the gasification is refined to obtain refined syngas; The bed has excellent magnification characteristics and is especially suitable for large industrial applications. 5%。 Refined synthesis gas refers to: in the synthesis gas directly obtained by gasification, CO and the main component, no tar, CH 4 content <0. 5%. Refined syngas is mainly used in the production of synthetic diesel/gasoline, olefins, alkanes, naphtha, lubricating oil, and as a fuel cell raw material, etc. It is suitable for the production of various chemical products and new energy utilization of various ultra-clean oil products. Especially in the field of renewable bio-energy utilization, it is the key technology of bio-shield chemical industry and biomass-based synthetic oil new energy industry. However, the entrained flow gasification has strict limits on the particle size of the raw materials, and the raw materials entering the entrained flow bed need to be ground into ultrafine micron-sized particles. However, according to the existing crushing or milling technology, it is impossible to contain more fibers. The biomass feedstock is ground to meet the particle size required for the operation of the entrained flow bed, which results in the inability to directly use the biomass feedstock for gasification of the entrained flow bed; preferably, the biomass is pyrolyzed into pyrolysis gas and solid state. The charcoal is then sent to the gas stream bed for gasification together with the solid carbon powder and the pyrolysis gas.
为了降低热解炉设备的材料要求, 最好的方法就是在 400 °C ~ 60 TC的中等热解温度下(简称中温热解), 对生物质进行中 温快速热解处理、将生物质分解成热解气和固态炭(将固态炭研 磨成炭粉 )后再送入气流床中进行气化。 而实现生物质中温快速 热解技术的关键就是热解炉的供热方法,它是决定生物质热解的 热量利用效率、 热解速率、 热解产物品质、 以及热解炉设备造价 和热解炉供热安全运行的核心。  In order to reduce the material requirements of the pyrolysis furnace equipment, the best method is to carry out the medium temperature rapid pyrolysis treatment and decompose the biomass at a medium pyrolysis temperature of 400 °C ~ 60 TC (referred to as medium temperature pyrolysis). The hot degassing and solid carbon (grinding the solid carbon into carbon powder) are then sent to an entrained gas bed for gasification. The key to realizing the rapid pyrolysis technology of biomass is the heating method of pyrolysis furnace, which is the heat utilization efficiency, pyrolysis rate, pyrolysis product quality, and pyrolysis equipment cost and pyrolysis of biomass pyrolysis. The core of safe operation of furnace heating.
目前对生物质进行热解的供热方法主要分为两类, 一是间接 换热热解, 另一是直接换热热解。 间接换热热解是先将热量传递到热解炉的加热部件, 然后再 由加热部件将热量传递给需热解的生物质, 如申请号为At present, the heating methods for pyrolysis of biomass are mainly divided into two types, one is indirect heat transfer pyrolysis, and the other is direct heat transfer pyrolysis. Indirect heat transfer pyrolysis is the transfer of heat to the heating element of the pyrolysis furnace, which then transfers the heat to the biomass to be pyrolyzed, as in the application number.
2000480005170. 3 中国专利、 申请号为 200610124521. 3 中国专 利等, 都是典型的间接换热热解的供热装置, 可以较好地满足慢 速热解的需求, 但其缺点就是热解升温速率慢、 传热效率低、 夕卜 供热量大、 热量利用率低, 特别针对大型工业化的生物盾中温快 速热解需求, 导致外供热量极大、 传热效率及热量利用率低、 加 热部件温度很高或加热部件设备庞大、加热部件材质要求极高且 容易损坏, 基本不能满足工业化生物质快速热解的需求。 2000480005170. 3 Chinese patent, application number 200610124521. 3 Chinese patents, etc., are typical indirect heat transfer pyrolysis heating devices, which can better meet the needs of slow pyrolysis, but the disadvantage is the pyrolysis heating rate. Slow, low heat transfer efficiency, large heat supply, low heat utilization, especially for the large industrialized bio-shield medium temperature rapid pyrolysis demand, resulting in large external heat supply, heat transfer efficiency and low heat utilization, heating The temperature of the parts is very high or the heating parts are huge, the heating parts are extremely high in material quality and easily damaged, which basically cannot meet the requirements of rapid pyrolysis of industrial biomass.
直接换热热解目前有两种方式, 一是将热介质(如外部高温 烟气等)直接输入到热解炉中; 另一是在热解炉中通入氧化剂和 /或外部燃料直接燃烧供热, 与需热解的生物质直接混合。 其共 同特点是传热效率高、 热量利用率可达到 100%, 但在工业化的 应用中如果供热方法不当将存在极大的运行安全隐患。  There are two ways to directly transfer heat to the heat. One is to directly input the heat medium (such as external high-temperature flue gas) into the pyrolysis furnace; the other is to directly burn the oxidant and/or external fuel in the pyrolysis furnace. Heating, mixing directly with the biomass to be pyrolyzed. The common feature is that the heat transfer efficiency is high and the heat utilization rate can reach 100%. However, in industrial applications, if the heating method is improper, there will be great operational safety hazards.
将外部高温烟气直接输入到热解炉中的方法会导致外部进 入的烟气温度 ί艮高、 烟气量极大、 烟道材料要求极高, 热解炉气 量大, 并导致后面的气流床气化效率低下, 这种直接换热热解方 法显然并不适合在工业化中应用。 目前, 直接换热热解一般都采 用在热解炉中通入氧化剂和 /或外部燃料直接燃烧供热。 如德国 科林公司的 Carbon - V工艺中的热解炉燃烧供热,在其对外公开 宣传的材料中, 其氧化剂为氧气或空气, 布置在热解炉下部, 用 烧结板将氧化剂进口与木炭分隔开,氧化剂与热解炉中自产的木 炭和热解气进行燃烧反应供热; 其烧结板温度极高, 并且在热解 炉的搅拌状态下燃烧存在较大的安全隐患。 又如申请号为The method of directly inputting the external high-temperature flue gas into the pyrolysis furnace will result in high temperature of the externally entering flue gas, a large amount of flue gas, extremely high requirements of the flue material, a large amount of pyrolysis furnace gas, and a subsequent gas flow. The bed gasification efficiency is low, and this direct heat transfer pyrolysis method is obviously not suitable for industrial application. At present, direct heat transfer pyrolysis generally uses direct combustion of heat in a pyrolysis furnace with oxidant and/or external fuel. For example, the pyrolysis furnace in the Carbon-V process of Colin Company of Germany burns and supplies heat. In its publicly publicized materials, its oxidant is oxygen or air, which is arranged in the lower part of the pyrolysis furnace, and the oxidant is imported into the charcoal with a sintered plate. Separated, oxidant and wood produced in the pyrolysis furnace The charcoal and the pyrolysis gas are subjected to combustion reaction for heating; the temperature of the sintered plate is extremely high, and there is a large safety hazard in the combustion state of the pyrolysis furnace. Another example is the application number
200810236614. 4 中国专利中提出了利用外供的可燃气体和氧气 在热解炉内发生直接燃烧反应,反应放出的热量直接用于提供生 物质热解所需的热量,但并没有说明如何进行燃烧组织, 只是提 到通过控制氧化剂量来控制热解炉的平均温度,但没有说明如何 在热解炉中进行燃烧组织供热。而热解炉直接燃烧供热的技术关 键是如何进行燃烧组织、如何控制燃烧区域的最高温度, 这是热 解炉安全稳定运行的关键, 也是决定热解炉设备材料要求的核 心。 200810236614. 4 Chinese patents propose that the direct combustion reaction takes place in the pyrolysis furnace by using the externally supplied combustible gas and oxygen. The heat released by the reaction is directly used to provide the heat required for pyrolysis of the biomass, but does not explain how to carry out the combustion. The organization only mentions controlling the average temperature of the pyrolysis furnace by controlling the amount of oxidant, but does not explain how to burn the tissue heating in the pyrolysis furnace. The key to the direct combustion of the pyrolysis furnace is how to burn the structure and how to control the maximum temperature of the combustion zone. This is the key to the safe and stable operation of the pyrolysis furnace and the core of the material requirements for the pyrolysis furnace equipment.
为了满足生物质中温快速热解的各方面需求, 采用直接换热 热解为较好的方式,而可以工程化实施的最佳方法就是采用直接 燃烧供热热解。但从上面的介绍可看出, 目前所有已知的直接燃 烧供热热解方法都存在各种不足和安全隐患,都不能同时满足高 传热效率、 高热量利用效率、 燃烧供热安全、 运行安全稳定、 热 解炉设备低投资等工业化实施要求。  In order to meet the various needs of biomass medium-temperature rapid pyrolysis, direct heat transfer pyrolysis is a better method, and the best method that can be implemented by engineering is direct combustion and heat pyrolysis. However, as can be seen from the above description, all known direct combustion and heat pyrolysis methods have various deficiencies and safety hazards, and cannot simultaneously satisfy high heat transfer efficiency, high heat utilization efficiency, combustion heat supply safety, and operation. Industrialized implementation requirements such as safety and stability, low investment in pyrolysis furnace equipment.
本发明的生物质热解炉的直接燃烧分散供热方法,是生物质 可再生固体燃料的中温快速热解技术中必须优先解决的关键技 术。  The direct combustion dispersion heating method of the biomass pyrolysis furnace of the present invention is a key technology that must be preferentially solved in the medium temperature rapid pyrolysis technology of biomass renewable solid fuel.
基于发明人的专业知识底蕴与多年丰富的实践经验及对事 业精益求精的不懈追求, 在认真而充分的调查、 了解、 分析、 总 结上述已有公知技术和现状基础上,根据生物质气流床气化的要 求, 在生物质的热解处理过程中满足 "生物质的中温快速热解及 热解气多次裂解" 的技术要求前提下, 对卧式热解炉采取 "直接 燃烧分散供热" 关键技术, 研制成功了 "生物质热解炉的直接燃 烧分散供热方法", 可高效、 燃烧供热安全、 运行安全稳定、 热 解炉设备低投资地满足生物质的精制合成气的原料预处理要求, 具有非常重要的现实意义与深远的战略意义。 发明内容 Based on the inventor's professional knowledge and years of rich practical experience and the relentless pursuit of excellence in the business, based on the careful and thorough investigation, understanding, analysis and summarization of the above-mentioned well-known technologies and status quo, based on biomass gasification bed gasification Want Under the premise of satisfying the technical requirements of "medium temperature rapid pyrolysis and pyrolysis gas multiple cracking" in the pyrolysis process of biomass, the key technology of "direct combustion and decentralized heating" is adopted for the horizontal pyrolysis furnace. , successfully developed the "direct combustion and dispersing heating method for biomass pyrolysis furnace", which can efficiently meet the requirements of raw material pretreatment for refined synthesis gas with high efficiency, safe combustion, safe and stable operation, and low investment in pyrolysis furnace equipment. , with very important practical significance and far-reaching strategic significance. Summary of the invention
本发明的生物质热解炉采取"直接燃烧分散供热"关键技术, 热解炉的供热燃烧装置由多个燃烧器组而组成,所有燃烧器组均 布置在热解炉的上部, 并在热解炉上部沿轴向分散布置, 而每个 燃烧器组均由多个小燃烧器喷嘴构成,热解炉内燃烧区域的最高 温度控制在 1600 °C以下; 为热解炉供热的燃料与氧化剂在进入 热解炉内以前是分隔开的, 在热解炉内为非预混燃烧; 热解炉为 卧式布置, 并且外壳固定, 热解炉内采用带有搅拌杆的搅拌轴旋 转来对生物质进行搅拌;根据进入热解炉的生物质原料的热解温 度要求, 可以通过调整氧化剂量来控制热解炉内的平均温度; 热 解炉在运行过程中,可以通过调整外部提供的燃料量和氧化剂中 的惰性组分含量来调节燃烧区域的最高温度,同时也可以通过调 整所述带有搅拌杆的搅拌轴的转速来调节燃烧区域的最高温度。  The biomass pyrolysis furnace of the invention adopts the key technology of "direct combustion and dispersion heating", and the heating and burning device of the pyrolysis furnace is composed of a plurality of burner groups, all of which are arranged in the upper part of the pyrolysis furnace, and Disposed in the axial direction in the upper part of the pyrolysis furnace, and each burner group is composed of a plurality of small burner nozzles, and the maximum temperature of the combustion zone in the pyrolysis furnace is controlled below 1600 ° C; heating for the pyrolysis furnace The fuel and oxidant are separated before entering the pyrolysis furnace, and are non-premixed combustion in the pyrolysis furnace; the pyrolysis furnace is horizontally arranged, and the outer casing is fixed, and the stirring furnace is stirred in the pyrolysis furnace. The shaft rotates to agitate the biomass; according to the pyrolysis temperature requirement of the biomass feedstock entering the pyrolysis furnace, the average temperature in the pyrolysis furnace can be controlled by adjusting the amount of the oxidant; the pyrolysis furnace can be adjusted during operation The amount of fuel supplied externally and the content of the inert component in the oxidant to adjust the maximum temperature of the combustion zone, and the combustion zone can also be adjusted by adjusting the rotational speed of the agitator shaft with the stirring rod The highest temperature.
通过本发明达到的目的是: ①、 为应用气流床对生物质气化 创造前提技术条件; ②、 使自然生成、 数量大、 分布广、 可再生 的 "生物质"新原料得到充分利用,变废为宝并有效地保护环境; ③、 应用采用卧式热解炉, 在满足 "生物质的中温快速热解" 的 技术要求前提下, 以 "直接燃烧分散供热" 关键技术、 提供 "生 物质热解炉的直接燃烧分散供热方法", 实现了生物质热解炉的 高效、 燃烧供热安全、 运行安全稳定、 设备低投资的技术要求;The objects achieved by the present invention are as follows: 1. To create the preconditions for the gasification of biomass by applying an entrained flow bed; 2. To make full use of the new biomass of natural biomass, large quantity, wide distribution and renewable "biomass" Waste is a treasure and effectively protect the environment; 3. The application adopts the horizontal pyrolysis furnace. Under the premise of meeting the technical requirements of "medium temperature rapid pyrolysis", the key technology of "direct combustion and dispersion heating" is provided, and the direct combustion dispersion of the biomass pyrolysis furnace is provided. The thermal method has realized the technical requirements of high efficiency of biomass pyrolysis furnace, safety of combustion and heat supply, safe and stable operation, and low investment in equipment;
④、为生物质化工产业及合成油新能源产业的开拓奠定坚实的技 术依托; ⑤、 有效保护环境、 提高综合经济效益。 4. Lay a solid technical support for the development of biomass chemical industry and synthetic oil new energy industry; 5. Effectively protect the environment and improve comprehensive economic benefits.
本发明可达到预期目的。 为实现上述目的 , 本发明提供的技术方案为:  The present invention achieves the intended purpose. To achieve the above object, the technical solution provided by the present invention is:
一种生物质热解炉的直接燃烧分散供热方法,热解炉的供热 燃烧装置由多个燃烧器组而组成,所有燃烧器组均布置在热解炉 的上部, 并在热解炉上部沿轴向分散布置, 而每个燃烧器组均由 多个小燃烧器喷嘴构成, 热解炉内燃烧区域的最高温度控制在 A direct combustion dispersion heating method for a biomass pyrolysis furnace, the heating combustion device of the pyrolysis furnace is composed of a plurality of burner groups, all of which are arranged in the upper part of the pyrolysis furnace, and in the pyrolysis furnace The upper part is arranged in the axial direction, and each burner group is composed of a plurality of small burner nozzles, and the maximum temperature of the combustion zone in the pyrolysis furnace is controlled at
1600 °C以下。 Below 1600 °C.
所述的生物质热解炉的直接燃烧分散供热方法,为所述热解 炉燃烧供热的燃料与氧化剂在进入热解炉内以前是分隔开的,在 所述热解炉内为非预混燃烧。  The direct combustion dispersion heating method of the biomass pyrolysis furnace, wherein the fuel and the oxidant for heating the pyrolysis furnace are separated before entering the pyrolysis furnace, and the pyrolysis furnace is Non-premixed combustion.
所述的生物质热解炉的直接燃烧分散供热方法 ,所述热解炉 为卧式布置, 并且所述热解炉的炉体外壳固定, 所述热解炉内采 用带有搅拌杆的搅拌轴旋转来对生物质进行搅拌。 .  The direct combustion dispersion heating method of the biomass pyrolysis furnace, the pyrolysis furnace is arranged horizontally, and the furnace body shell of the pyrolysis furnace is fixed, and the pyrolysis furnace adopts a stirring rod The agitator shaft rotates to agitate the biomass. .
所述的生物质热解炉的直接燃烧分散供热方法 ,所述生物质 为植物的根 /茎 /叶 /花 /果、 动物尸体、 粪便、 废旧橡胶、 煤和碳 水化合物的垃圾。 所述的生物质热解炉的直接燃烧分散供热方法,所述燃料分 为外部提供的燃料,以及所述热解炉内部生物质热解产生的热解 气中一部分, 而外部提供的燃料为可燃气体、 燃油中的一种; 所 述氧化剂为氧气、 空气、 氧气与二氧化碳气的混合气、 氧气与氮 气的混合气中的一种。 The direct combustion and dispersion heating method of the biomass pyrolysis furnace is a plant root/stem/leaf/flower/fruit, animal carcass, feces, waste rubber, coal and carbohydrate waste. The direct combustion dispersion heating method of the biomass pyrolysis furnace, the fuel is divided into an externally supplied fuel, and a part of the pyrolysis gas generated by pyrolysis of the biomass inside the pyrolysis furnace, and the externally supplied fuel It is one of a combustible gas and a fuel; the oxidant is one of oxygen, air, a mixture of oxygen and carbon dioxide, and a mixture of oxygen and nitrogen.
所述的生物质热解炉的直接燃烧分散供热方法,所述热解炉 在运行过程中,可以通过调整外部提供的燃料量和氧化剂中的惰 性组分含量来调节燃烧区域的最高温度。  The direct combustion dispersion heating method of the biomass pyrolysis furnace can adjust the maximum temperature of the combustion zone by adjusting the amount of externally supplied fuel and the inert component content of the oxidant during operation.
所述的生物盾热解炉的直接燃烧分散供热方法,所述热解炉 在运行过程中,同时也可以通过调整所述带有搅拌杆的搅拌轴的 转速来调节燃烧区域的最高温度。  The direct combustion dispersion heating method of the bio-shield pyrolysis furnace can also adjust the maximum temperature of the combustion zone by adjusting the rotation speed of the stirring shaft with the stirring rod during the operation.
所述的生物质热解炉的直接燃烧分散供热方法,根据进入所 述热解炉的生物质原料的热解温度要求,可以通过调整氧化剂量 来控制热解炉内的平均温度。 由于采用了本发明所提供的技术方案。由于本发明的热解炉 在满足 "生物质的中温快速热解"的技术要求前提下,采用了 "直 接燃烧分散供热"关键技术。 由于本发明热解炉的供热燃烧装置 由多个燃烧器组而组成, 所有燃烧器組均布置在热解炉的上部, 并在热解炉上部沿轴向分散布置,而每个燃烧器组均由多个小燃 烧器喷嘴构成, 热解炉内燃烧区域的最高温度控制在 1600°C以 下;为热解炉供热的燃料与氧化剂在进入热解炉内以前是分隔开 的, 在热解炉内为非预混燃烧; 热解炉为卧式布置, 并且外壳固 定, 热解炉内采用带有搅拌杆的搅拌轴旋转来对生物质进行搅 拌; 根据进入热解炉的生物质原料的热解温度要求, 可以通过调 整氧化剂量来控制热解炉内的平均温度; 热解炉在运行过程中, 可以通过调整外部提供的燃料量和氧化剂中的惰性组分含量来 调节燃烧区域的最高温度,同时也可以通过调整所述带有搅拌杆 的搅拌轴的转速来调节燃烧区域的最高温度。与已有公知技术相 比, 获得了如下有益效果: The direct combustion dispersion heating method of the biomass pyrolysis furnace can control the average temperature in the pyrolysis furnace by adjusting the amount of the oxidant according to the pyrolysis temperature requirement of the biomass raw material entering the pyrolysis furnace. The technical solution provided by the present invention is adopted. Since the pyrolysis furnace of the present invention satisfies the technical requirements of "medium temperature rapid pyrolysis of biomass", the key technology of "direct combustion and dispersion heating" is adopted. Since the heating and burning device of the pyrolysis furnace of the present invention is composed of a plurality of burner groups, all of the burner groups are arranged in the upper part of the pyrolysis furnace, and are arranged in the axial direction in the upper part of the pyrolysis furnace, and each burner is arranged. The groups are composed of a plurality of small burner nozzles, and the maximum temperature of the combustion zone in the pyrolysis furnace is controlled below 1600 ° C; the fuel and oxidant for heating the pyrolysis furnace are separated before entering the pyrolysis furnace. Non-premixed combustion in the pyrolysis furnace; the pyrolysis furnace is horizontally arranged and the outer casing is solid In the pyrolysis furnace, the stirring shaft with the stirring rod is rotated to stir the biomass; according to the pyrolysis temperature requirement of the biomass raw material entering the pyrolysis furnace, the average amount in the pyrolysis furnace can be controlled by adjusting the amount of the oxidizing agent. Temperature; during the operation of the pyrolysis furnace, the maximum temperature of the combustion zone can be adjusted by adjusting the amount of fuel supplied from the outside and the content of inert components in the oxidant, and also by adjusting the rotation speed of the stirring shaft with the stirring rod To adjust the maximum temperature of the combustion zone. Compared with the prior art, the following beneficial effects are obtained:
1、 由于本发明的生物质为植物的根 /茎 /叶 /花 /果、 动物尸 体、 粪便、 煤和碳水化合物的垃圾, 并可根据进入热解炉的生物 质原料的热解温度要求,通过调整氧化剂量来控制热解炉内的平 均温度, 从而获得了自然生成原料数量大、 分布广、 可再生、 取 材方便、选择余地大、 热解平均温度可随原料要求变化进行调整 等有益效果。  1. Since the biomass of the present invention is plant roots/stems/leaves/flowers/fruits, animal carcasses, feces, coal and carbohydrate waste, and according to the pyrolysis temperature requirements of the biomass feedstock entering the pyrolysis furnace, By adjusting the amount of oxidant to control the average temperature in the pyrolysis furnace, the beneficial effects of large amount of natural raw materials, wide distribution, reproducible, convenient material selection, large choice of choice, and pyrolysis average temperature can be adjusted according to changes in raw material requirements. .
2、 由于本发明的供热燃料既可以是外加燃料如可燃气体和 燃油、也可以是热解炉内部生物质热解产生的热解气, 氧化剂为 空气、 氧气、 氧气与二氧化碳气的混合气、 氧气与氮气的混合气 中的一种, 从而获得了对燃料及氧化剂的选择余地均大、 并且燃 烧稳定安全可靠、 便于实施的有益效果。  2. Since the heating fuel of the present invention can be either an external fuel such as a combustible gas and a fuel oil, or a pyrolysis gas generated by pyrolysis of biomass inside the pyrolysis furnace, the oxidant is a mixture of air, oxygen, oxygen and carbon dioxide gas. One of the mixed gas of oxygen and nitrogen, thereby obtaining the advantages of large selection of fuel and oxidant, stable and reliable combustion, and easy implementation.
3、 由于本发明采用的热解炉为卧式布置, 并且外壳固定, 热解炉内釆用带有搅拌杆的搅拌轴旋转来对生物质进行搅拌,从 而获得了 "热解炉的直接燃烧分散供热方法"在热解炉的布置设 计、 工程实施和安装运行的基础, 并实现了热解炉内温度均匀, 生物质换热效率高等效果 3. Since the pyrolysis furnace used in the present invention is horizontally arranged and the outer casing is fixed, the pyrolysis furnace is rotated by the stirring shaft with the stirring rod to stir the biomass, thereby obtaining the direct combustion of the pyrolysis furnace. The method of decentralized heating "based on the layout design, engineering implementation and installation operation of the pyrolysis furnace, and achieving uniform temperature in the pyrolysis furnace, Biomass heat transfer efficiency and other effects
4、 由于本发明的热解炉供热燃烧装置由多个燃烧器组而组 成, 所有燃烧器组均布置在热解炉的上部, 并在热解炉上部沿轴 向分散布置, 而每个燃烧器组均由多个小燃烧器喷嘴构成, 热解 炉内燃烧区域的最高温度控制在 1600°C以下, 从而满足了生物 质中温快速热解的高效、 燃烧供热安全, 运行安全稳定、 设备低 投资的要求, 获得了使 "生物质热解炉直接燃烧分散供热方法" 之实施载体的有益效果。  4. Since the pyrolysis furnace heating and burning device of the present invention is composed of a plurality of burner groups, all of the burner groups are arranged in an upper portion of the pyrolysis furnace, and are arranged in the axial direction in the upper portion of the pyrolysis furnace, and each The burner group is composed of a plurality of small burner nozzles, and the maximum temperature of the combustion zone in the pyrolysis furnace is controlled below 1600 ° C, thereby satisfying the high efficiency of the medium-temperature rapid pyrolysis of biomass, the safety of combustion heating, and the safe and stable operation. The low investment requirement of the equipment has obtained the beneficial effect of implementing the carrier of the "biomass pyrolysis furnace direct combustion dispersion heating method".
5、 由于本发明为热解炉提供燃烧供热的燃料与氧化剂在进 入热解炉内以前是分隔开的, 在热解炉内为非预混燃烧; 从而获 得了热解炉燃烧供热方式的运行过程安全可靠,杜绝了回火等安 · 全隐患, 且保障了设备安全稳定运行的有益效果。  5. Since the fuel and oxidant for providing combustion heat for the pyrolysis furnace are separated before entering the pyrolysis furnace, non-premixed combustion is performed in the pyrolysis furnace; thereby obtaining combustion heat of the pyrolysis furnace The operation process of the mode is safe and reliable, and the urgency and other hidden dangers are eliminated, and the beneficial effects of safe and stable operation of the equipment are guaranteed.
6、 由于本发明所述的热解炉在运行过程中可以通过调整外 部提供的燃料量和氧化剂中的惰性组分含量来调节燃烧区域的 最高温度; 同时也可以通过调整所述带有搅拌杆的搅拌轴的转速 来调节燃烧区域的最高温度, 从而获得了对 "燃烧区域的最高温 度" 的调节, 具体实施的操作灵活并简单方便且快捷有效、 便于 工程实施推广应用、 降低设备投资的有益效果。 了 "直接燃烧分散供热" 关键技术, 从而获得了满足 "生物质的 中温快速热解" 的技术要求, 提供 "生物质中温快速热解的热解 炉直接燃烧分散供热方法", 为生物质的气流床气化技术应用解 决了困难、创造了前提技术条件,使自然生成、数量大、分布广、 可再生的 "生物质"新原料变废为宝而得到充分利用、 并有效地 保护环境,为生物质化工产业及合成油新能源产业的开拓奠定技 术依托、 提供技术储备及技术实施方案, 效果稳定可靠、 综合经 济效益佳, 摆脱对传统化石能源依赖等有益效果。 附图说明 6. The pyrolysis furnace according to the present invention can adjust the maximum temperature of the combustion zone by adjusting the amount of fuel supplied from the outside and the content of the inert component in the oxidant during operation; and also adjusting the stirring rod by adjusting The rotation speed of the stirring shaft is used to adjust the maximum temperature of the combustion zone, thereby obtaining the adjustment of the "highest temperature of the combustion zone". The specific implementation is flexible, simple, convenient, fast and effective, and is convenient for engineering implementation and application, and reducing the investment of equipment. effect. The key technology of "direct combustion and dissipative heating" has obtained the technical requirements to meet the "medium temperature rapid pyrolysis of biomass", providing "direct combustion and dispersive heating method for pyrolysis furnace with rapid pyrolysis of biomass". Application of material entrained flow gasification technology Difficulties have been made, and the premise technical conditions have been created, so that the natural biomass, large quantity, wide distribution, and renewable "biomass" new raw materials are turned into waste and fully utilized, and the environment is effectively protected. The development of new energy industry of synthetic oil lays the foundation for technology support, provides technical reserves and technical implementation plan, and the effect is stable and reliable, comprehensive economic benefits are good, and the beneficial effects of dependence on traditional fossil energy are eliminated. DRAWINGS
说明书附图为本发明具体实施方式中 "卧式热解炉"的示意 图。 图中的实线箭头表示经粉碎的生物质原料入口、虚线箭头表 示热解气出口、 双实线箭头表示炭出口。  BRIEF DESCRIPTION OF THE DRAWINGS The accompanying drawings are schematic illustrations of a "horizontal pyrolysis furnace" in accordance with an embodiment of the present invention. The solid arrows in the figure indicate the pulverized biomass feedstock inlet, the dashed arrow indicates the pyrolysis gas outlet, and the double solid arrows indicate the char outlet.
图中的标号: 1、 热解炉的炉体外壳, 2、 燃烧器组, 3、 小 燃烧器喷嘴 (非预混燃烧的小燃烧器喷嘴), 4、 搅拌轴, 5、 搅 拌杆。 具体实施方式  Reference numerals in the figure: 1. Furnace shell of pyrolysis furnace, 2. Burner group, 3. Small burner nozzle (small burner nozzle without premixed combustion), 4. Stirring shaft, 5. Stirring rod. detailed description
下面结合说明书附图,对本发明作详细描述。正如说明书附 图所示:  The present invention will be described in detail below with reference to the accompanying drawings. As shown in the attached picture:
一种生物质热解炉的直接燃烧分散供热方法,热解炉的供热 燃烧装置由多个燃烧器组而組成,所有燃烧器組均布置在热解炉 的上部, 并在热解炉上部沿轴向分散布置, 而每个燃烧器组均由 多个小燃烧器喷嘴构成, 热解炉内燃烧区域的最高温度控制在 1600°C以下。  A direct combustion dispersion heating method for a biomass pyrolysis furnace, the heating combustion device of the pyrolysis furnace is composed of a plurality of burner groups, all of which are arranged in the upper part of the pyrolysis furnace, and in the pyrolysis furnace The upper portion is axially dispersed, and each burner group is composed of a plurality of small burner nozzles, and the maximum temperature of the combustion zone in the pyrolysis furnace is controlled below 1600 °C.
所述的生物质热解炉的直接燃烧分散供热方法,为所述热解 炉燃烧供热的燃料与氧化剂在进入热解炉内以前是分隔开的,在 所述热解炉内为非预混燃烧。 The direct combustion dispersion heating method of the biomass pyrolysis furnace, wherein the fuel and the oxidant for heating the pyrolysis furnace are separated before entering the pyrolysis furnace, The pyrolysis furnace is non-premixed combustion.
所述的生物质热解炉的直接燃烧分散供热方法 ,所述热解炉 为卧式布置, 并且所述热解炉的炉体外壳固定, 所述热解炉内釆 用带有搅拌杆的搅拌轴旋转来对生物质进行搅拌。  The direct combustion dispersion heating method of the biomass pyrolysis furnace, the pyrolysis furnace is arranged horizontally, and the furnace body of the pyrolysis furnace is fixed, and the pyrolysis furnace is equipped with a stirring rod The agitator shaft rotates to agitate the biomass.
所述的生物质热解炉的直接燃烧分散供热方法 ,所述生物质 为植物的根 /茎 /叶 /花 /果、 动物尸体、 粪便、 废旧橡胶、 煤和碳 水化合物的垃圾。  The direct combustion and dispersion heating method of the biomass pyrolysis furnace, the biomass is plant root/stem/leaf/flower/fruit, animal carcass, feces, waste rubber, coal and carbohydrate compound waste.
所述的生物质热解炉的直接燃烧分散供热方法,所述燃料分 为外部提供的燃料,以及所述热解炉内部生物质热解产生的热解 气中一部分, 而外部提供的燃料为可燃气体、 燃油中的一种; 所 述氧化剂为氧气、 空气、 氧气与二氧化碳气的混合气、 氧气与氮 气的混合气中的一种。  The direct combustion dispersion heating method of the biomass pyrolysis furnace, the fuel is divided into an externally supplied fuel, and a part of the pyrolysis gas generated by pyrolysis of the biomass inside the pyrolysis furnace, and the externally supplied fuel It is one of a combustible gas and a fuel; the oxidant is one of oxygen, air, a mixture of oxygen and carbon dioxide, and a mixture of oxygen and nitrogen.
所述的生物盾热解炉的直接燃烧分散供热方法,所述热解炉 在运行过程中,可以通过调整外部提供的燃料量和氧化剂中的惰 性组分含量来调节燃烧区域的最高温度。  The direct combustion dispersion heating method of the bio-shield pyrolysis furnace can adjust the maximum temperature of the combustion zone by adjusting the amount of externally supplied fuel and the inert component content of the oxidant during operation.
所述的生物质热解炉的直接燃烧分散供热方法,所述热解炉 在运行过程中, 同时也可以通过调整所述带有搅拌杆的搅拌轴的 转速来调节燃烧区域的最高温度。  The direct combustion dispersion heating method of the biomass pyrolysis furnace, in the operation of the pyrolysis furnace, can also adjust the maximum temperature of the combustion zone by adjusting the rotation speed of the stirring shaft with the stirring rod.
所述的生物质热解炉的直接燃烧分散供热方法,根据进入所 述热解炉的生物质原料的热解温度要求,可以通过调整氧化剂量 来控制热解炉内的平均温度。 在上述的具体实施过程中: 采用卧式布置的热解炉, 并且热 解炉外壳固定,热解炉内采用带有搅拌杆的搅拌轴旋转来对生物 质进行搅拌进行了实施; 根据生物质热解产量的大小, 在所述热 解炉上对所述的燃烧器组分散布置,分别以两个以上的各种不同 数量进行了实施; 同样根据产量的大小, 对所述每个燃烧器组的 小燃烧器喷嘴也分别以四个以上的各种不同数量进行了实施;对 所述的燃料分别以外加燃料的天然气、 液化石油气、其他可燃气 体、燃油中的一种, 和采用了热解炉自身产生的热解气进行了实 施; 对所述的氧化剂分别以空气、 氧气、 氧气与二氧化碳气的混 合气、氧气与氮气的混合气进行了实施;根据生物质原料的不同, 以满足原料热解温度要求为前提, 通过调整氧化剂的供量, 满足 了热解炉平均热解温度的要求;以热解炉内燃烧火焰区域的最高 温度为 1600°C以下为前提, 分别以通过改变燃料的供给量来调 节燃烧区域的最高温度并使其处于稳定状态、通过改变氧化剂中 的惰性组分含量来调节燃烧区域的最高温度并使其处于稳定状 态、通过调整所述热解炉的带有搅拌杆的搅拌轴的转速来调节燃 烧区域的最高温度并使其处于稳定状态进行了实施。上述各种方 式、 各种规模的实施, 先后完成了多次原理性试验、 小型试验、 中型试验、 大型试 H 生产性试验, 均收到了预期的良好效果, 充分印证了本发明的可靠性与可操作性。 The direct combustion dispersion heating method of the biomass pyrolysis furnace can control the average temperature in the pyrolysis furnace by adjusting the amount of the oxidant according to the pyrolysis temperature requirement of the biomass raw material entering the pyrolysis furnace. In the above specific implementation process: a horizontally arranged pyrolysis furnace, and heat The furnace shell is fixed, and the stirring of the stirring shaft with the stirring rod is used in the pyrolysis furnace to carry out the stirring of the biomass; according to the biomass pyrolysis yield, the burner is arranged on the pyrolysis furnace The groups are arranged in a distributed manner and are implemented in two or more different quantities respectively; likewise, according to the size of the output, the small burner nozzles of each of the burner groups are also respectively carried out in more than four different quantities. Implementing; performing one of natural gas, liquefied petroleum gas, other combustible gas, and fuel oil separately fueled, and using pyrolysis gas generated by the pyrolysis furnace itself; respectively It is carried out with a mixture of air, oxygen, oxygen and carbon dioxide gas, and a mixture of oxygen and nitrogen. According to the difference in biomass raw materials, it meets the requirements of the pyrolysis temperature of the raw materials, and the heat is satisfied by adjusting the supply of the oxidant. Determining the average pyrolysis temperature of the furnace; taking the maximum temperature of the combustion flame zone in the pyrolysis furnace to be 1600 ° C or less, respectively, by changing the fuel The supply amount is used to adjust the maximum temperature of the combustion zone and to make it stable, to change the maximum temperature of the combustion zone by changing the content of the inert component in the oxidant and to make it stable, by adjusting the stirring of the pyrolysis furnace The rotation speed of the stirring shaft of the rod is adjusted to adjust the maximum temperature of the combustion zone and to make it stable. The above-mentioned various methods and implementations of various scales have successively completed a number of principle tests, small tests, medium-sized tests, and large-scale test H productivity tests, all of which have received the expected good results, fully confirming the reliability and reliability of the present invention. Operability.
通过以上的具体实施说明: ①、 热解炉采用卧式布置, 并且 外壳固定,热解炉内采用带有搅拌杆的搅拌轴旋转来对生物质进 行搅拌的结构筒单, 提供了实施本发明的载体; ②、 应用热解炉 的直接燃烧分散供热的方法科学合理, 满足了 "生物质的中温快 速热解" 的技术要求; ③、 本发明的燃烧器组分散布置, 每个燃 烧器组又由多个小燃烧器喷嘴构成,燃料与氧化剂在热解炉内为 非预混燃烧, 充分体现了本发明的安全性、 可靠性、 可操作性、 降低了热解炉设备的材料要求和造价; ④、本发明所述的热解炉 在运行过程中既可以通过调整外部提供的燃料量来调节燃烧区 域的最高温度、又可以通过调整氧化剂中的惰性组分含量来调节 燃烧区域的最高温度、同时也可以通过调整所迷带有搅拌杆的搅 拌轴的转速来调节燃烧区域的最高温度,从而实现了热解炉技术 中核心的 "燃烧区域的最高温度" 的调节, 并且在具体实施的操 作灵活、 筒单方便、 快捷有效、 便于工程实施推广应用、 降低设 备投资的有益效果显著; ⑤、 适应生物质原料的共有特点, 为下 一步实施生物质的高效气流床气化解决了技术困难、完成了原料 的技术处理。 以上所述仅为本发明的较佳实施例,并非对本发明作任何形 式上的限制; 凡本行业的普通技术人员, 均可按以上所述和说明 书附图所示而顺畅地实施本发明;但凡在不脱离本发明技术方案 而作出的更动、修饰与演变的等同变化, 均为本发明的等效实施 例, 均仍属于本发明技术方案的保护范围。 Through the above specific implementation description: 1. The pyrolysis furnace adopts the horizontal arrangement, and the outer casing is fixed, and the structural cylinder in which the stirring shaft rotating with the stirring rod is used to stir the biomass in the pyrolysis furnace provides the implementation of the invention. Carrier; 2, application of pyrolysis furnace The direct combustion and dispersive heating method is scientific and reasonable, and satisfies the technical requirements of "medium temperature rapid pyrolysis of biomass"; 3. The burner group of the present invention is dispersedly arranged, and each burner group is composed of a plurality of small burner nozzles. The fuel and the oxidant are non-premixed combustion in the pyrolysis furnace, fully embodying the safety, reliability, operability, and material requirements and cost of the pyrolysis furnace equipment of the present invention; 4. The present invention The pyrolysis furnace can adjust the maximum temperature of the combustion zone by adjusting the amount of fuel supplied from the outside during operation, and can adjust the maximum temperature of the combustion zone by adjusting the content of inert components in the oxidant, and can also adjust the The speed of the stirring shaft with the stirring rod is adjusted to adjust the maximum temperature of the combustion zone, thereby realizing the adjustment of the core "highest temperature of the combustion zone" in the pyrolysis furnace technology, and the operation is flexible and convenient in the specific implementation. Fast and effective, easy to implement and promote the application of the project, reduce the investment of equipment, the beneficial effect is significant; 5, adapt to the biomass raw materials Characteristics for the next implementation of efficient entrained flow gasification of biomass to solve the technical difficulties, the completion of the technical process feedstock. The above is only the preferred embodiment of the present invention, and is not intended to limit the scope of the present invention; those skilled in the art can smoothly implement the present invention as shown in the above description and the accompanying drawings; The equivalent changes of the modification, modification and evolution which are made without departing from the technical solution of the present invention are all equivalent embodiments of the present invention, and still belong to the protection scope of the technical solution of the present invention.

Claims

权 利 要 求 书 Claim
1、 一种生物质热解炉的直接燃烧分散供热方法, 其特征在 于: 热解炉的供热燃烧装置由多个燃烧器组而组成, 所有燃烧器 组均布置在热解炉的上部, 并在热解炉上部沿轴向分散布置, 而 每个燃烧器组均由多个小燃烧器喷嘴构成,热解炉内燃烧区域的 最高温度控制在 1600°C以下。  A direct combustion dispersion heating method for a biomass pyrolysis furnace, characterized in that: the heating combustion device of the pyrolysis furnace is composed of a plurality of burner groups, all of which are arranged in the upper part of the pyrolysis furnace And arranged in the axial direction in the upper part of the pyrolysis furnace, and each burner group is composed of a plurality of small burner nozzles, and the maximum temperature of the combustion zone in the pyrolysis furnace is controlled below 1600 °C.
2、 根据权利要求 1所述的生物质热解炉的直接燃烧分散供 热方法, 其特征在于: 为所述热解炉燃烧供热的燃料与氧化剂在 进入热解炉内以前是分隔开的, 在所述热解炉内为非预混燃烧。  2. The direct combustion dispersion heating method of a biomass pyrolysis furnace according to claim 1, wherein: the fuel and the oxidant for heating the pyrolysis furnace are separated before entering the pyrolysis furnace. In the pyrolysis furnace, it is non-premixed combustion.
3、 根据权利要求 1所述的生物质热解炉的直接燃烧分散供 热方法, 其特征在于: 所述热解炉为卧式布置, 并且所述热解炉 的炉体外壳固定,所述热解炉内采用带有搅拌杆的搅拌轴旋转来 对生物质进行搅拌。  3. The direct combustion dispersion heating method of a biomass pyrolysis furnace according to claim 1, wherein: the pyrolysis furnace is horizontally arranged, and a furnace body casing of the pyrolysis furnace is fixed, The pyrolysis furnace is rotated by a stirring shaft with a stirring rod to stir the biomass.
4、 根据权利要求 1所述的生物质热解炉的直接燃烧分散供 热方法, 其特征在于: 所述生物质为植物的根 /茎 /叶 /花 /果、 动 物尸体、 粪便、 废旧橡胶、 煤和碳水化合物的垃圾。  4. The direct combustion dispersion heating method of a biomass pyrolysis furnace according to claim 1, wherein: the biomass is a plant root/stem/leaf/flower/fruit, animal carcass, feces, waste rubber , coal and carbohydrate waste.
5、 根据权利要求 2所述的生物质热解炉的直接燃烧分散供 热方法, 其特征在于: 所述燃料分为外部提供的燃料, 以及所述 热解炉内部生物质热解产生的热解气中一部分,而外部提供的燃 料为可燃气体、 燃油中的一种; 所述氧化剂为氧气、 空气、 氧气 与二氧化碳气的混合气、 氧气与氮气的混合气中的一种。  5. The direct combustion dispersion heating method of a biomass pyrolysis furnace according to claim 2, wherein: said fuel is divided into externally supplied fuel, and heat generated by biomass pyrolysis inside said pyrolysis furnace One part of the degassing, and the externally supplied fuel is one of a combustible gas and a fuel; the oxidizing agent is one of oxygen, air, a mixture of oxygen and carbon dioxide gas, and a mixture of oxygen and nitrogen.
6、 根据权利要求 1或 2所述的生物质热解炉的直接燃烧分 散供热方法, 其特征在于: 所述热解炉在运行过程中, 可以 . 通过调整外部提供的燃料量和氧化剂中的惰性组分含量来调节 燃烧区域的最高温度。 6. Direct combustion of a biomass pyrolysis furnace according to claim 1 or 2. The method of heat dissipation is characterized in that: during the operation of the pyrolysis furnace, the maximum temperature of the combustion zone can be adjusted by adjusting the amount of fuel supplied from the outside and the content of the inert component in the oxidant.
7、 根据权利要求 1或 3所述的生物质热解炉的直接燃烧分 散供热方法, 其特征在于: 所述热解炉在运行过程中, 同时也可 以通过调整所述带有搅拌杆的搅拌轴的转速来调节燃烧区域的 最高温度。  The direct combustion and dispersion heating method of the biomass pyrolysis furnace according to claim 1 or 3, wherein: the pyrolysis furnace is in operation, and at the same time, adjusting the stirring rod The speed of the agitator shaft is adjusted to adjust the maximum temperature in the combustion zone.
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