WO2011047890A1 - Verfahren zur schichtdickenmessung mittels lasertriangulation und vorrichtung - Google Patents

Verfahren zur schichtdickenmessung mittels lasertriangulation und vorrichtung Download PDF

Info

Publication number
WO2011047890A1
WO2011047890A1 PCT/EP2010/058722 EP2010058722W WO2011047890A1 WO 2011047890 A1 WO2011047890 A1 WO 2011047890A1 EP 2010058722 W EP2010058722 W EP 2010058722W WO 2011047890 A1 WO2011047890 A1 WO 2011047890A1
Authority
WO
WIPO (PCT)
Prior art keywords
component
coating
layer thickness
blade
laser triangulation
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Ceased
Application number
PCT/EP2010/058722
Other languages
German (de)
English (en)
French (fr)
Inventor
Torsten Melzer-Jokisch
Andreas Oppert
Dimitrios Thomaidis
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Siemens AG
Siemens Corp
Original Assignee
Siemens AG
Siemens Corp
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Siemens AG, Siemens Corp filed Critical Siemens AG
Priority to JP2012534593A priority Critical patent/JP2013508696A/ja
Priority to CN2010800472248A priority patent/CN102575927A/zh
Priority to US13/502,381 priority patent/US20120263866A1/en
Priority to EP10728168A priority patent/EP2491338A1/de
Priority to RU2012120660/28A priority patent/RU2541440C2/ru
Publication of WO2011047890A1 publication Critical patent/WO2011047890A1/de
Anticipated expiration legal-status Critical
Ceased legal-status Critical Current

Links

Classifications

    • GPHYSICS
    • G01MEASURING; TESTING
    • G01BMEASURING LENGTH, THICKNESS OR SIMILAR LINEAR DIMENSIONS; MEASURING ANGLES; MEASURING AREAS; MEASURING IRREGULARITIES OF SURFACES OR CONTOURS
    • G01B11/00Measuring arrangements characterised by the use of optical techniques
    • G01B11/02Measuring arrangements characterised by the use of optical techniques for measuring length, width or thickness
    • G01B11/06Measuring arrangements characterised by the use of optical techniques for measuring length, width or thickness for measuring thickness ; e.g. of sheet material
    • GPHYSICS
    • G01MEASURING; TESTING
    • G01BMEASURING LENGTH, THICKNESS OR SIMILAR LINEAR DIMENSIONS; MEASURING ANGLES; MEASURING AREAS; MEASURING IRREGULARITIES OF SURFACES OR CONTOURS
    • G01B11/00Measuring arrangements characterised by the use of optical techniques
    • G01B11/02Measuring arrangements characterised by the use of optical techniques for measuring length, width or thickness
    • G01B11/06Measuring arrangements characterised by the use of optical techniques for measuring length, width or thickness for measuring thickness ; e.g. of sheet material
    • G01B11/0616Measuring arrangements characterised by the use of optical techniques for measuring length, width or thickness for measuring thickness ; e.g. of sheet material of coating
    • GPHYSICS
    • G01MEASURING; TESTING
    • G01BMEASURING LENGTH, THICKNESS OR SIMILAR LINEAR DIMENSIONS; MEASURING ANGLES; MEASURING AREAS; MEASURING IRREGULARITIES OF SURFACES OR CONTOURS
    • G01B11/00Measuring arrangements characterised by the use of optical techniques
    • G01B11/02Measuring arrangements characterised by the use of optical techniques for measuring length, width or thickness
    • G01B11/06Measuring arrangements characterised by the use of optical techniques for measuring length, width or thickness for measuring thickness ; e.g. of sheet material
    • G01B11/0616Measuring arrangements characterised by the use of optical techniques for measuring length, width or thickness for measuring thickness ; e.g. of sheet material of coating
    • G01B11/0683Measuring arrangements characterised by the use of optical techniques for measuring length, width or thickness for measuring thickness ; e.g. of sheet material of coating measurement during deposition or removal of the layer

Definitions

  • the invention relates to a method and a device for measuring layer thickness by means of laser triangulation.
  • a destructive test precludes the subsequent use of the component and can only be used for parameter optimization.
  • the object is achieved by a method according to claim 1 and a device according to claim 1 or 9.
  • FIG. 3 shows a schematic representation of the sequence of the method
  • FIG. 4 positions of the layer thickness measurement
  • FIG. 5 shows a gas turbine
  • FIG. 6 shows a turbine blade
  • Figure 7 is a combustion chamber
  • Figure 8 is a list of superalloys.
  • FIG. 1 shows a turbine blade 120, 130 as a component 1 used as an example.
  • the turbine blade or vane 120, 130 may be a new part or a ent harshetes component 120, 130 (from the refurbishment), which was already in use, and for example, has a wall thickness ⁇ dilution by the stripping process.
  • the blade 120, 130 is measured at each position 13 ', 13' '(FIG. 4) at which a review of the layer thickness seems sensible (I in FIG. 3). , This can be done locally at one or more points or globally over the entire area to be coated.
  • the measurement by means of laser triangulation can preferably also take place during the coating (II).
  • the data obtained therefrom before and after or during the coating can be compared with one another by means of a computer (IV in FIG. 3) and thus the layer thickness can be determined at each desired position (FIG. 4) and preferably compared with desired values.
  • Layer thickness determined at each desired position 13 ', 13''( Figure 4) (V in Figure 3).
  • the layer thickness can be produced for metallic and ceramic Schich ⁇ th and by means of APS, VPS, PVP, CVD ⁇ be true.
  • the measurements are carried out before and after in the same holder, preferably without installation and removal of the component 120, 130.
  • the measurement is carried out only before and after the coating, because the technical structure is somewhat simpler.
  • the component is a large surface area, in the case of a turbine blade 120, 130 the turbine blade and the blade platform ⁇ scanned over a large area as set, different layer thicknesses particularly in ge ⁇ curved surfaces.
  • a reference point on the component 1, 120, 139, 155 in particular in the case of a blade 120, 130, this is preferably a point at the point which does not distort itself, such as, for example, FIG . B. on the blade root - because it is very solid - or on the holder, the delay of the component 1, 120, 130, 155, in particular of the much thinner part of the
  • Coating material application means in general: local, like a blade of a turbine blade coating local loading on the blade or complete Beschich ⁇ th, but also welding application method.
  • FIG. 5 shows by way of example a gas turbine 100 in a longitudinal partial section.
  • the gas turbine 100 has a rotatably mounted about a rotational axis 102 ⁇ rotor 103 with a shaft, which is also referred to as the turbine rotor.
  • a compressor 105 for example, a torus-like
  • Combustion chamber 110 in particular annular combustion chamber, with a plurality of coaxially arranged burners 107, a turbine 108 and the exhaust housing 109th
  • the annular combustion chamber 110 communicates with an annular annular hot gas channel 111, for example.
  • annular annular hot gas channel 111 for example.
  • turbine stages 112 connected in series form the turbine 108.
  • Each turbine stage 112 is formed, for example, from two blade rings . As seen in the direction of flow of a working medium 113, in the hot gas channel 111 of a row of guide vanes 115, a series 125 formed of rotor blades 120 follows.
  • the guide vanes 130 are fastened to an inner housing 138 of a stator 143, whereas the moving blades 120 of a row 125 are attached to the rotor 103 by means of a turbine disk 133, for example.
  • Coupled to the rotor 103 is a generator or work machine (not shown).
  • air 135 is sucked by the compressor 105 through the intake housing and ver ⁇ seals.
  • the 105 ⁇ be compressed air provided at the turbine end of the compressor is ge ⁇ leads to the burners 107, where it is mixed with a fuel.
  • the mixture is then burned to form the working fluid 113 in the combustion chamber 110.
  • the working medium 113 flows along the hot gas channel 111 past the guide vanes 130 and the rotor blades 120.
  • the working medium 113 expands in a pulse-transmitting manner so that the rotor blades 120 drive the rotor 103 and drive the machine coupled to it.
  • the components exposed to the hot working medium 113 are subject to thermal loads during operation of the gas turbine 100.
  • the guide vanes 130 and rotor blades 120 of the first turbine stage 112, viewed in the flow direction of the working medium 113, are subjected to the greatest thermal stress in addition to the heat shield elements lining the annular combustion chamber 110.
  • substrates of the components may have a directional structure, i. they are monocrystalline (SX structure) or have only longitudinal grains (DS structure).
  • the components in particular for the turbine blade ⁇ 120, 130 and components of the combustion chamber 110, for example, iron-, nickel- or cobalt-based superalloys are used.
  • Such superalloys are known, for example, from EP 1 204 776 B1, EP 1 306 454, EP 1 319 729 A1, WO 99/67435 or WO 00/44949.
  • the guide vane 130 has an inner housing 138 of the turbine 108 facing guide vane root (not Darge here provides ⁇ ) and a side opposite the guide-blade root vane root.
  • the vane head faces the rotor 103 and fixed to a mounting ring 140 of the stator 143.
  • FIG. 6 shows a perspective view of a rotor 120 or guide vane 130 of a turbomachine that extends along a longitudinal axis 121.
  • the turbomachine may be a gas turbine of an aircraft or a power plant for electricity generation, a steam turbine or a compressor.
  • the blade 120, 130 has along the longitudinal axis 121 to each other, a securing region 400, an thereto adjacent blade platform 403 and an airfoil 406 and a blade tip 415.
  • the blade 130 may have at its blade tip ⁇ 415 another platform (not shown).
  • a blade root 183 is formed, which serves for attachment of the blades 120, 130 to a shaft or a disc (not shown).
  • the blade root 183 is, for example, as a hammerhead out staltet ⁇ .
  • Other designs as Christmas tree or Schwalbenschwanzfuß are possible.
  • the blade 120, 130 has for a medium which flows past the scene ⁇ felblatt 406, a leading edge 409 and a trailing edge 412.
  • Such superalloys are known, for example, from EP 1 204 776 B1, EP 1 306 454, EP 1 319 729 A1, WO 99/67435 or WO 00/44949.
  • the blade 120, 130 can be made by a casting process, also by directional solidification, by a forging process, by a milling process or combinations thereof.
  • Workpieces with a monocrystalline structure or structures are used as components for machines which are exposed to high mechanical, thermal and / or chemical stresses during operation.
  • Stem-crystal structures which probably have longitudinally extending grain boundaries, but no transverse grain boundaries. These second-mentioned crystalline structures are also known as directionally solidified structures.
  • M is at least one element of the group iron (Fe), cobalt (Co),
  • Nickel (Ni) is an active element and stands for yttrium (Y) and / or silicon and / or at least one element of the rare earths, or hafnium (Hf)).
  • Such alloys are known from EP 0 486 489 B1, EP 0 786 017 B1, EP 0 412 397 B1 or EP 1 306 454 A1.
  • the density is preferably 95% of the theoretical
  • the layer composition comprises Co-30Ni-28Cr-8A1-0, 6Y-0, 7Si or Co-28Ni-24Cr-10Al-0, 6Y.
  • nickel-based protective layers such as Ni-10Cr-12Al-0.6Y-3Re or Ni-12Co-21Cr-IIAl-O, 4Y-2Re or Ni-25Co-17Cr-10A1-0, 4Y-1 are also preferably used , 5Re.
  • thermal barrier coating which is preferably the outermost layer, and consists for example of Zr0 2 , Y2Ü3-Zr02, ie it is not, partially ⁇ or fully stabilized by yttria
  • the thermal barrier coating covers the entire MCrAlX layer.
  • Electron beam evaporation produces stalk-shaped grains in the thermal barrier coating.
  • the heat insulating layer can ⁇ ner to have better thermal shock resistance porous, micro- or macro-cracked pERSonal.
  • the thermal barrier coating is therefore preferably more porous than the
  • the blade 120, 130 may be hollow or solid. If the blade 120, 130 is to be cooled, it is hollow and also has, if necessary, film cooling holes 418 (indicated by dashed lines) on.
  • FIG. 7 shows a combustion chamber 110 of the gas turbine 100.
  • the combustion chamber 110 is configured, for example, as so-called an annular combustion chamber, in which a plurality of in the circumferential direction about an axis of rotation 102 arranged burners 107 open into a common combustion chamber space 154 and generate flames 156th
  • the combustion chamber 110 is configured in its entirety as an annular structure, which is positioned around the axis of rotation 102 around.
  • the combustion chamber 110 is designed for a comparatively high temperature of the working medium M of about 1000 ° C to 1600 ° C.
  • the combustion chamber wall 153 is provided on its side facing the working medium M facing side with a formed from heat shield elements 155. liner. Due to the high temperatures inside the combustion chamber
  • the 110 may also be provided for the heat shield elements 155 and for their holding elements, a cooling system.
  • the heat shield elements 155 are then, for example, hollow and possibly still have cooling holes (not shown) which open into the combustion chamber space 154.
  • Each heat shield element 155 made of an alloy is equipped on the working fluid side with a particularly heat-resistant protective layer (MCrAlX layer and / or ceramic coating) or is made of high-temperature-resistant material (solid ceramic blocks).
  • M is at least one element of the group iron (Fe), cobalt (Co), nickel (Ni), X is an active element and stands for yttrium (Y) and / or
  • a ceramic Wär ⁇ medämm Anlagen be present and consists for example of ZrÜ2, Y203 ⁇ Zr02, ie it is not, partially or fully ⁇ dig stabilized by yttrium and / or calcium oxide and / or magnesium oxide.
  • Suitable coating processes such as electron beam evaporation (EB-PVD), produce stalk-shaped grains in the thermal barrier coating.
  • Other coating methods are conceivable, for example atmospheric plasma spraying (APS), LPPS, VPS or CVD.
  • APS atmospheric plasma spraying
  • LPPS LPPS
  • VPS VPS
  • CVD chemical vapor deposition
  • the heat insulation layer may have ⁇ porous, micro- or macro-cracked compatible grains for better thermal shock resistance.
  • Reprocessing means that turbines ⁇ blades 120, 130, heat shield elements have to be removed from 155, after ⁇ A set of protective layers (for example by sandblasting). This is followed by removal of the corrosion and / or oxidation layers or products.
  • cracks in the turbine blade 120, 130 or the heat shield element 155 are also repaired. This is followed by a re-coating of the turbine blades 120, 130, heat shield elements 155 and a renewed use of the turbine blades 120, 130 or the heat shield elements 155.

Landscapes

  • Physics & Mathematics (AREA)
  • General Physics & Mathematics (AREA)
  • Turbine Rotor Nozzle Sealing (AREA)
  • Length Measuring Devices By Optical Means (AREA)
PCT/EP2010/058722 2009-10-19 2010-06-21 Verfahren zur schichtdickenmessung mittels lasertriangulation und vorrichtung Ceased WO2011047890A1 (de)

Priority Applications (5)

Application Number Priority Date Filing Date Title
JP2012534593A JP2013508696A (ja) 2009-10-19 2010-06-21 レーザー三角測量によって膜厚を測定するための方法および装置
CN2010800472248A CN102575927A (zh) 2009-10-19 2010-06-21 用于借助于激光三角法进行层厚度测量的方法和装置
US13/502,381 US20120263866A1 (en) 2009-10-19 2010-06-21 Method for measuring layer thickness by means of laser triangulation, and device
EP10728168A EP2491338A1 (de) 2009-10-19 2010-06-21 Verfahren zur schichtdickenmessung mittels lasertriangulation und vorrichtung
RU2012120660/28A RU2541440C2 (ru) 2009-10-19 2010-06-21 Способ измерения толщины слоя посредством лазерной триангуляции

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
EP09013170.7 2009-10-19
EP09013170A EP2312267A1 (de) 2009-10-19 2009-10-19 Verfahren zur Schichtdickenmessung mittels Lasertriangulation und Vorrichtung

Publications (1)

Publication Number Publication Date
WO2011047890A1 true WO2011047890A1 (de) 2011-04-28

Family

ID=41557637

Family Applications (1)

Application Number Title Priority Date Filing Date
PCT/EP2010/058722 Ceased WO2011047890A1 (de) 2009-10-19 2010-06-21 Verfahren zur schichtdickenmessung mittels lasertriangulation und vorrichtung

Country Status (7)

Country Link
US (1) US20120263866A1 (enExample)
EP (2) EP2312267A1 (enExample)
JP (1) JP2013508696A (enExample)
KR (1) KR20120098632A (enExample)
CN (1) CN102575927A (enExample)
RU (1) RU2541440C2 (enExample)
WO (1) WO2011047890A1 (enExample)

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE102015217166A1 (de) * 2015-09-09 2017-03-09 Mtu Aero Engines Gmbh Verfahren zur Bestimmung von mindestens einer Oberflächeneigenschaft

Families Citing this family (7)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US9303983B2 (en) 2012-04-02 2016-04-05 The Boeing Company Sealant analysis system
DE102012217176A1 (de) 2012-09-24 2014-03-27 Evonik Litarion Gmbh Verfahren zur Ausrichtung eines Lasersensors zu einem Messobjekt
DE102012217175A1 (de) 2012-09-24 2014-03-27 Evonik Litarion Gmbh Verfahren zur Ausrichtung zweier Lasersensoren zueinander
CN103245291B (zh) * 2013-04-24 2015-12-09 中国船舶重工集团公司第十二研究所 叶片类零件装配精度检测方法
US9721044B2 (en) 2013-05-10 2017-08-01 General Electric Company Systems and methods for non-destructive evaluation of molds and crucibles used in investment casting
NL2016652B1 (en) 2016-04-21 2017-11-16 Innovative Mechanical Engineering Tech B V Electrospinning device and method.
GB201808325D0 (en) * 2018-05-21 2018-07-11 3D Automated Metrology Inspection Ltd Apparatus For Monitoring A Coating

Citations (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE10313888A1 (de) * 2003-03-27 2004-10-28 Fraunhofer-Gesellschaft zur Förderung der angewandten Forschung e.V. Verfahren und Vorrichtung zur online Materialschichtdickenbestimmung
US20050137829A1 (en) * 2003-12-17 2005-06-23 Siemens Westinghouse Power Corporation System and method for measuring coating thickness
US20060246213A1 (en) * 2005-04-29 2006-11-02 National Research Council Of Canada Method of on-line thickness measurement of applied coatings
US20070279645A1 (en) * 2004-09-30 2007-12-06 Marian Dratwinski Method for measuring a thickness of a coating
US20100110451A1 (en) * 2008-10-31 2010-05-06 Siemens Energy, Inc. Coating Evaluation Process

Family Cites Families (7)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US7027A (en) * 1850-01-15 Circulak
US6024A (en) * 1849-01-09 Cast-iron gar-wheel
US10011A (en) * 1853-09-13 Improvement in the shape of scythes
US5013A (en) * 1847-03-13 Improvement in apparatus for the manufacture of malleable iron
EP1844892A1 (de) * 2006-04-13 2007-10-17 ALSTOM Technology Ltd Verfahren zur Laserentfernung von Beschichtenmaterialen in Kühlenlöchern eines Turbinenbauteiles
JP2008202969A (ja) * 2007-02-16 2008-09-04 Toppan Printing Co Ltd 膜厚測定装置及び膜厚測定方法
RU82035U1 (ru) * 2008-08-28 2009-04-10 Юрий Андреевич Сазонов Устройство для измерения толщины движущейся пленки (варианты)

Patent Citations (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE10313888A1 (de) * 2003-03-27 2004-10-28 Fraunhofer-Gesellschaft zur Förderung der angewandten Forschung e.V. Verfahren und Vorrichtung zur online Materialschichtdickenbestimmung
US20050137829A1 (en) * 2003-12-17 2005-06-23 Siemens Westinghouse Power Corporation System and method for measuring coating thickness
US20070279645A1 (en) * 2004-09-30 2007-12-06 Marian Dratwinski Method for measuring a thickness of a coating
US20060246213A1 (en) * 2005-04-29 2006-11-02 National Research Council Of Canada Method of on-line thickness measurement of applied coatings
US20100110451A1 (en) * 2008-10-31 2010-05-06 Siemens Energy, Inc. Coating Evaluation Process

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE102015217166A1 (de) * 2015-09-09 2017-03-09 Mtu Aero Engines Gmbh Verfahren zur Bestimmung von mindestens einer Oberflächeneigenschaft

Also Published As

Publication number Publication date
RU2012120660A (ru) 2013-11-27
KR20120098632A (ko) 2012-09-05
CN102575927A (zh) 2012-07-11
JP2013508696A (ja) 2013-03-07
EP2312267A1 (de) 2011-04-20
EP2491338A1 (de) 2012-08-29
US20120263866A1 (en) 2012-10-18
RU2541440C2 (ru) 2015-02-10

Similar Documents

Publication Publication Date Title
EP2491339A1 (de) Oberflächenanalyse zur detektierung verschlossener löcher und vorrichtung
EP2436798B1 (de) Maskierungsmaterial, Maskierungsschicht und Verfahren zum Maskieren eines Substrats
EP2593582B1 (de) Poröses keramisches schichtsystem
EP2569594B1 (de) Oberflächenanalyse zur detektierung verschlossener löcher und verfahren zur wiederöffnung
WO2011047890A1 (de) Verfahren zur schichtdickenmessung mittels lasertriangulation und vorrichtung
EP2614174A1 (de) Poröses schichtsystem mit poröserer innenschicht
EP2907888A1 (de) Verdichterschaufel mit erosionsbeständiger Hartstoffbeschichtung
EP2227346A2 (de) Belotung von löchern, verfahren zum beschichten und lötgutstäbchen
WO2011045343A1 (de) Referenzbestimmung zur ermittlung der lage von verschlossenen löchern, vorrichtung und bearbeitungsvorrichtung
EP2224039A1 (de) Beschichtung mit thermischen und nicht-thermischen Beschichtungsverfahren
EP2365106A1 (de) Keramische Wärmedämmschichtsystem mit modifizierter Anbindungsschicht
WO2011141430A1 (de) Oberflächenanalyse zur detektierung verschlossener löcher und verfahren zur wiederöffnung
EP2431736A1 (de) Verfahren zum Testen einer für das Durchführen eines Thermografieverfahrens ausgebildeten Thermografieanlage auf ihre ordnungsgemäße Funktion, Testbauteil hierfür sowie Verfahren dessen Herstellung
EP2733236A1 (de) Zweilagiges keramisches Schichtsystem mit äußerer poröser Schicht und Vertiefungen darin
EP2597259A1 (de) Modifizierte Oberfläche um ein Loch
WO2011128239A1 (de) Germaniumhaltiges lot, ein bauteil mit einem lot und ein verfahren zum löten
WO2011138415A2 (de) Verfahren zur ermittlung der lage von verschlossenen löchern, vorrichtung und bearbeitungsvorrichtung
EP2194163A1 (de) Keramische Wärmedämmschichten mit Aluminiumoxidteilchen und Verfahren zur Charakterisierung einer solchen Wärmedämmschicht
EP2177643A1 (de) Verfahren zum Reparieren einer Superlegierung mit dem gleichen Superlegierungspulver und Keramik
WO2008049456A1 (de) Beschichtungsoptimierungsverfahren mit einem coupon und bauteil mit einem coupon
EP2589681A1 (de) Kombination von kolumnaren und globularen Strukturen
WO2012059306A1 (de) Rissdetektierung mittels kryotechnischer vorbehandlung
WO2009089840A1 (de) Verfahren und vorrichtung zur geregelten edm-bearbeitung
WO2011057661A1 (de) Bauteil mit bereichen unterschiedlicher duktilität und verfahren zur herstellung eines bauteils
EP2614219A2 (de) Verfahren zur bauteilüberprüfung und zum betreiben einer maschine.

Legal Events

Date Code Title Description
WWE Wipo information: entry into national phase

Ref document number: 201080047224.8

Country of ref document: CN

121 Ep: the epo has been informed by wipo that ep was designated in this application

Ref document number: 10728168

Country of ref document: EP

Kind code of ref document: A1

REEP Request for entry into the european phase

Ref document number: 2010728168

Country of ref document: EP

WWE Wipo information: entry into national phase

Ref document number: 2010728168

Country of ref document: EP

ENP Entry into the national phase

Ref document number: 20127009905

Country of ref document: KR

Kind code of ref document: A

WWE Wipo information: entry into national phase

Ref document number: 2012534593

Country of ref document: JP

NENP Non-entry into the national phase

Ref country code: DE

WWE Wipo information: entry into national phase

Ref document number: 2012120660

Country of ref document: RU

WWE Wipo information: entry into national phase

Ref document number: 13502381

Country of ref document: US