Classifications

• • B—PERFORMING OPERATIONS; TRANSPORTING
  • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
  • B01D—SEPARATION
  • B01D53/00—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols
  • B01D53/14—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols by absorption
  • B01D53/1425—Regeneration of liquid absorbents
• • B—PERFORMING OPERATIONS; TRANSPORTING
  • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
  • B01D—SEPARATION
  • B01D53/00—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols
  • B01D53/14—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols by absorption
  • B01D53/1456—Removing acid components
  • B01D53/1475—Removing carbon dioxide
• • B—PERFORMING OPERATIONS; TRANSPORTING
  • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
  • B01D—SEPARATION
  • B01D53/00—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols
  • B01D53/34—Chemical or biological purification of waste gases
  • B01D53/46—Removing components of defined structure
  • B01D53/62—Carbon oxides
• • C—CHEMISTRY; METALLURGY
  • C21—METALLURGY OF IRON
  • C21B—MANUFACTURE OF IRON OR STEEL
  • C21B13/00—Making spongy iron or liquid steel, by direct processes
  • C21B13/14—Multi-stage processes processes carried out in different vessels or furnaces
• • C—CHEMISTRY; METALLURGY
  • C21—METALLURGY OF IRON
  • C21B—MANUFACTURE OF IRON OR STEEL
  • C21B5/00—Making pig-iron in the blast furnace
  • C21B5/06—Making pig-iron in the blast furnace using top gas in the blast furnace process
• • B—PERFORMING OPERATIONS; TRANSPORTING
  • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
  • B01D—SEPARATION
  • B01D2256/00—Main component in the product gas stream after treatment
  • B01D2256/22—Carbon dioxide
• • B—PERFORMING OPERATIONS; TRANSPORTING
  • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
  • B01D—SEPARATION
  • B01D2257/00—Components to be removed
  • B01D2257/50—Carbon oxides
  • B01D2257/504—Carbon dioxide
• • B—PERFORMING OPERATIONS; TRANSPORTING
  • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
  • B01D—SEPARATION
  • B01D2258/00—Sources of waste gases
  • B01D2258/02—Other waste gases
  • B01D2258/025—Other waste gases from metallurgy plants
• • C—CHEMISTRY; METALLURGY
  • C21—METALLURGY OF IRON
  • C21B—MANUFACTURE OF IRON OR STEEL
  • C21B2100/00—Handling of exhaust gases produced during the manufacture of iron or steel
  • C21B2100/20—Increasing the gas reduction potential of recycled exhaust gases
  • C21B2100/28—Increasing the gas reduction potential of recycled exhaust gases by separation
  • C21B2100/282—Increasing the gas reduction potential of recycled exhaust gases by separation of carbon dioxide
• • C—CHEMISTRY; METALLURGY
  • C21—METALLURGY OF IRON
  • C21B—MANUFACTURE OF IRON OR STEEL
  • C21B2100/00—Handling of exhaust gases produced during the manufacture of iron or steel
  • C21B2100/60—Process control or energy utilisation in the manufacture of iron or steel
  • C21B2100/62—Energy conversion other than by heat exchange, e.g. by use of exhaust gas in energy production
• • C—CHEMISTRY; METALLURGY
  • C21—METALLURGY OF IRON
  • C21C—PROCESSING OF PIG-IRON, e.g. REFINING, MANUFACTURE OF WROUGHT-IRON OR STEEL; TREATMENT IN MOLTEN STATE OF FERROUS ALLOYS
  • C21C2100/00—Exhaust gas
  • C21C2100/02—Treatment of the exhaust gas
• • C—CHEMISTRY; METALLURGY
  • C21—METALLURGY OF IRON
  • C21C—PROCESSING OF PIG-IRON, e.g. REFINING, MANUFACTURE OF WROUGHT-IRON OR STEEL; TREATMENT IN MOLTEN STATE OF FERROUS ALLOYS
  • C21C2100/00—Exhaust gas
  • C21C2100/04—Recirculation of the exhaust gas
• • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
  • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
  • Y02C—CAPTURE, STORAGE, SEQUESTRATION OR DISPOSAL OF GREENHOUSE GASES [GHG]
  • Y02C20/00—Capture or disposal of greenhouse gases
  • Y02C20/40—Capture or disposal of greenhouse gases of CO2
• • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
  • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
  • Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
  • Y02P10/00—Technologies related to metal processing
  • Y02P10/10—Reduction of greenhouse gas [GHG] emissions
  • Y02P10/122—Reduction of greenhouse gas [GHG] emissions by capturing or storing CO2
• • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
  • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
  • Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
  • Y02P10/00—Technologies related to metal processing
  • Y02P10/10—Reduction of greenhouse gas [GHG] emissions
  • Y02P10/134—Reduction of greenhouse gas [GHG] emissions by avoiding CO2, e.g. using hydrogen
• • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
  • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
  • Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
  • Y02P10/00—Technologies related to metal processing
  • Y02P10/25—Process efficiency

Definitions

• Pig iron production plants For the production of pig iron, which also includes the production of pig iron-like products, there are essentially two known common processes: the
• the blast furnace process first produces pig iron from iron ore using coke. In addition, scrap can also be used. Thereafter, steel is produced by further processes from pig iron.
• the iron ore is used as lump, pellets or sinter together with the reducing agents (usually coke, or coal, for example in the form of a
• Fine coal indisposition plant Fine coal indisposition plant
• other constituents limestone, slag formers, etc.
• the blast furnace is a metallurgical reactor in which the Möllerklax reacts in countercurrent with hot air, the so-called hot blast.
• hot blast By burning the carbon from the coke, the necessary heat for the reaction and carbon monoxide or hydrogen, which is a significant part of the reducing gas and flows through the Möllerklale and reduces the iron ore.
• the result is pig iron and slag, which are tapped periodically.
• oxygen blast furnace which is also referred to as blast furnace with top or top gas recirculation, in the gasification of coke or coal oxygen-containing gas with more than 90% oxygen content (0 2 ) in the blast furnace
• a gas cleaning For the emerging from the blast furnace gas, the so-called top or top gas, a gas cleaning must be provided (for example, dust and / or cyclones in combination with
• the oxygen blast furnace usually a compressor, preferably with aftercooler, for in the blast furnace
• Blast furnace methods are a heater for the reducing gas and / or a combustion chamber for partial combustion with oxygen.
• the disadvantages of the blast furnace are the demands on the feedstock and the high emission of carbon dioxide.
• the iron carrier used and the coke must be lumpy and hard, so that sufficient cavities remain in the Möllerklale, which ensure the flow through the blown wind.
• the C0 2 output represents a strong
• Natural gas sponge iron production (MIDREX, HYL, FINMET) and smelting reduction processes (Corex and Finex processes).
• a melter gasifier in which hot liquid metal is produced, and at least one reduction reactor in which the carrier of the iron ore (lump, fine ore, pellets, sinter) with
• Reduction gas is reduced, the reducing gas in the melter gasifier by gasification of coal (and
• the Corex process is a two-step process
• the smelting reduction combines the process of direct reduction (prereduction of iron to sponge iron) with one
• CO 2 Capture and Sequestration CCS
• PSA Pressure swing adsorption
• Adsorption in particular also the vacuum pressure swing adsorption (English: VPSA - Vacuum Pressure Swing Adsorption) used.
• Pressure swing adsorption is a physical process for the selective decomposition of gas mixtures under pressure.
• Special porous materials eg zeolites,
• Activated carbon activated silica (Si0 2 ), activated alumina (Al 2 O 3 ) or the combined use of these materials) are used as a molecular sieve to molecules according to their adsorption and / or their
• Recyclable material here CO, H 2 , CH 4
• Recyclable material flows freely through the column. Once the adsorbent is fully loaded, the pressure is released and the column rinsed.
• electrical power is required for the prior compression of the C0 2 rich recycle gas.
• the product gas stream after the pressure swing adsorption which contains the recyclables, contains in exhaust gases from the
• Pig iron production still about 2-6 vol% CO 2 .
• the residual gas stream from the (V) PSA plant still contains relatively high reducing gas constituents (such as CO, H 2 ), which are lost for pig iron production.
• the residual gas stream after pressure swing adsorption which contains the undesirable components, is typically composed of exhaust gases from pig iron production as follows:
• the residual gas can not simply be thermally recycled because it - due to the low and / or fluctuating
• CCPP combined cycle power plant
• Boiler would increase the flame temperature during the
• Combustion can be reduced.
• the residual gas must be compressed so that the CO2 is in liquid form, and then the liquid CO2 must be placed in a reservoir, to which the pressure must usually be increased so far that the CO2 in the liquid-solid or supercritical state, where CO2 has a density of about 1000 kg / m 3 .
• the supercritical state is a state above the critical point in the phase diagram (see FIG. 1) which is characterized by the equalization of the densities of the liquid and gas phases. The differences between the two
• High-power compressor can be used to bring the typical densities at line level, which is in the range of greater than 0 ° C and greater than 70 bar (7,000,000 Pa), preferably 80-150 bar at ambient temperatures.
• the residual gas from a (V) PSA is not suitable for being bound because, in addition to CO2, it has a relatively high proportion of CO, H 2 , N 2 , CH 4 , etc.
• the CO content poses a safety risk, as this can lead to a risk of injury to persons (CO poisoning) and, under certain circumstances, to inflammation or explosion.
• the "impurities" CO, H 2 , ... of CO2 for the
• the impurities must also reduce the distances between the stations, where the transported gas mixture or the transported liquid must be recompressed, so that the investment and
• Inlet pressure in the line can be increased to reduce the number or power of the additional pumps and compressors along the line.
• the object is achieved by a method according to claim 1, by the CO 2 is removed by means of chemical absorption, wherein the heat for the regeneration of the absorbent at least partially
• low-pressure steam which is used from a steam turbine of a steam power plant and / or a steam turbine to use the heat from the pig iron production (reducing gases, top gases, etc.),
• low pressure steam is meant steam which is saturated and has a pressure between 2 and 10 bar g
• this also includes a combined cycle power plant, more precisely a combined cycle power plant (CCPP), in which the principles of a CCPP
• Gas turbine power plant and a steam power plant are Gas turbine power plant and a steam power plant.
• a gas turbine serves as a heat source for a downstream waste heat boiler, which in turn as
• the CO, H 2 , CH 4 fraction recovered from the pig iron production can be increased over (V) PSA and the C0 2 fraction in the product gas can be substantially reduced (up to a few ppmv).
• the residual gas stream consists mainly of CO2 and can therefore be used for
• Vacuum compressors are needed, which also consume a lot of energy and cause high maintenance costs.
• the low energy consumption is an advantage especially for those countries where energy is scarce and / or expensive.
• Absorption processes are comparable to those for a VPSA plant. But the absorption process needs large amounts of low-pressure steam with a pressure of more than 2 bar g or higher, eg 10 bar g . This steam would be expensive if it had to be specially made and could not be taken from an existing steam source.
• a first absorption method is characterized by the use of potassium carbonate as the absorbent. It is used hot potassium carbonate (English Hot Potassium
• HPC hydrogen carbonate
• a second absorption process is known as amine scrubbing with several sub-processes.
• slightly alkaline aqueous solutions of amines are used
• Chemically absorb gases such as CO 2 , reversibly.
• the acidic gas is thermally separated (by heating) from the amine and the recovered amine is used again for washing.
• Amines such as diethanolamine (DEA) are also used as activators for absorption processes using potassium carbonate, such as the Benfield process.
• DEA diethanolamine
• amine scrubbing primary amines can be used, such as methylamine, monoethanolamine (MEA) and / or diglycolamine
• secondary amines may be used in addition to or as an alternative to primary amines, such as
• DEA Diethanolamine
• DIPA diisopropanolamine
• tertiary amines for example triethanolamine (TEA) and / or methyldiethanolamine (MDEA).
• TAA triethanolamine
• MDEA methyldiethanolamine
• An existing process for this purpose is the aMDEA process from BASF (offered by Linde and Lurgi), which uses activated methyldiethanolamine (MDEA).
• top gas from a blast furnace in particular from an oxygen blast furnace with top gas recirculation, which is operated predominantly with oxygen instead of hot blast, can be purified of CO 2 .
• the inventive method is exhaust gases from
• Exhaust gas (so-called top gas) from at least one Fixed bed reactor for preheating and / or reduction of
• Iron oxides and / or iron briquettes Iron oxides and / or iron briquettes.
• a device according to the invention corresponding device is provided for the removal of CO 2 by means of chemical absorption, wherein the plant part for the regeneration of the absorbent
• Pig iron production is connected that low-pressure steam from the steam turbine can be at least partially directed into the plant part for the regeneration of the absorbent,
• waste heat boiler of a steam power plant is connected to the waste heat boiler of a steam power plant and / or the waste heat boiler for using the waste heat from the pig iron production that the waste heat can be used at least partially for the generation of low pressure steam for the regeneration of the absorbent.
• a line may be provided for the blast furnace process, with which top gas from a blast furnace, in particular from an oxygen blast furnace with
• Top gas recirculation can be directed into the plant for the removal of CO 2 by means of chemical absorption.
• a smelting reduction plant can be conducted into the plant for the removal of CO 2 by means of chemical absorption.
• At least one of these lines may be connected to at least one of the following devices:
• a further embodiment consists in that a line is provided, with which at least a part of the purified exhaust gas can be redirected back to the pig iron production as reducing gas.
• Removal of CO 2 can be provided that it is connected to the low pressure part of the steam turbine and / or the waste heat boiler.
• Fig. 1 shows a phase diagram of CO 2 .
• Fig. 2 shows the relationship between impurities of gases and the compaction stations necessary for the transport of liquefied gases.
• Fig. 3 shows the connection according to the invention between a blast furnace and two power plants.
• Fig. 4 shows the connection according to the invention between a plant for smelting reduction and two power plants.
• FIG. 1 shows a phase diagram of CO 2 .
• the individual states of matter solid or solid, Liquid or liquid and gas or gaseous are separated by lines.
• the triple point is the point where solid, liquid and gaseous phases meet.
• the supercritical state (supercritical fluid) is a state above the critical point in the phase diagram, which is due to the matching of the densities of liquid and liquid
• the impurities are plotted in% of the gas volume, on the vertical axis of the
• FIG. 3 an oxygen blast furnace is shown with top gas recirculation 1, in which iron ore from a sinter plant 2 and coke (not shown) is supplied.
• Oxygenated gas 3 with an oxygen content> 80% is introduced into the ring line 4, as is in
• Reduction gas furnace 6 heated reducing gas 5 together with cold or preheated oxygen O 2 introduced into the blast furnace 1. Slag 7 and pig iron 8 will be down
• the top ⁇ or top gas 9 is removed and pre-cleaned in a dust separator or cyclone 10 and a wet scrubber 11 (or a bag filter or hot gas filter system) cleaned again.
• the purified top or top gas can on the one hand taken directly as export gas 12 from the blast furnace system and a Exporting gas container 13 are supplied, on the other hand, it can be fed to a system 14 for the chemical absorption of CO2, wherein the purified top or top gas previously compressed in a compressor 15 to about 2-6 bar g and in an aftercooler 16 to about 30-60 ° C is cooled.
• the system 14 for the chemical absorption of CO2 consists essentially of an absorber 17 and a stripper 18. Such systems are known from the prior art and will therefore be described here only in outline.
• top or top gas 9 is introduced from below, while from the top one the acidic
• Components of the gas absorbing solution about one
• the loaded absorbent (the absorbent liquid) is passed from the top into the stripper 18, where it is with warm
• Low-pressure steam 19 which has a temperature of about 120-260 ° C, in particular 150 ° C, is heated to> 100 ° C, in particular 110-120 ° C, whereby the acid gases, in particular the CO2, again as residual gas 20th be released.
• Residual gas 20 can either be released into the atmosphere again after H 2 S purification 21 and / or fed to a further compressor 22 for the liquefaction of CO 2, in order to be forwarded and stored underground, or as a substitute for nitrogen in the atmosphere To use iron production.
• the resulting in the stripper condensate 23 is withdrawn and can be fed to the steam cycle of a steam power plant 32.
• the export gas from an optional export gas container 13 can be fed to a combined cycle power plant 24 as fuel, optionally via a buffer memory 25 and a filter 26.
• the export gas is supplied in a gas compressor 27 and the gas turbine 28.
• the waste heat from the gas turbine is in the waste heat boiler 29 for a steam cycle with a
• the export gas 12 - optionally via another
• Steam power plant 32 are supplied as fuel. From the last stage or stages of the steam turbine 34 of the
• Steam power plant 32 is withdrawn low-pressure steam 19 and fed to the stripper 18.
• the pressure energy content of the export gas 12 can also be measured in an expansion turbine 35 (top gas pressure recovery
• Fig. 4 shows the connection according to the invention between a plant for smelting reduction and two power plants, namely a combined cycle power plant 24, which is constructed exactly the same as that in Fig. 3, and a steam power plant 32, also with the same structure as that in Fig. 3. Also in Fig. 4, either only the combined cycle power plant 24 or only the
• Steam power plant 32 may be provided or both the
• the two power plants 24, 32 are supplied by a Finex plant with export gas 12, which can be cached in an export gas tank 13 and 31 respectively.
• An optional Expansion turbine 35 is again the exploitation of the
• Export gas 12 contained energy. Not required for the power plants 24, 32 export gas 12 can again a
• Raw material drying 36 are supplied.
• the Finex system has four in this example
• Fine ore and additives 41 are the
• Reactor 37 they then enter the third 38, the second 39 and finally the first reduction reactor 40.
• the third 38 the second 39 and finally the first reduction reactor 40.
• the first reduction reactor 40 instead of four fluidized bed reactors 37-40 but only three may be present.
• the reducing gas 43 is guided. It is introduced at the bottom of the first reduction reactor 40 and exits at its top. Before it enters from below into the second reduction reactor 39, it can still with
• Oxygen O 2 are heated, as well between the second 39 and third 38 reduction reactor.
• the heat of the exhaust gas 44 from the reduction reactors 37-40 is used in a waste heat boiler 45 for generating steam, the resulting
• Low-pressure steam 46 is supplied to the stripper 18 of the CO 2 chemical absorption plant.
• the exiting from the waste heat boiler 45 exhaust 44 is cleaned in a wet scrubber 47 and used as export gas 12 as described above in downstream power plants on.
• a partial flow of the exhaust gas 44 is - according to the invention - the absorber 17 to C0 2 ⁇ distance supplied.
• the reducing gas 43 is prepared in a melter gasifier 48, in the one hand coal in the form of lumpy coal 49 and coal in powder form 50 - this is supplied together with oxygen O 2 - in the other hand, the pre-reduced in the reduction reactors 37-40 and in of the
• Iron briquetting 51 in hot condition to briquettes.
• HCl Hot Compacted Iron shaped iron ore is added.
• the iron briquettes arrive via a conveyor 52 in a storage tank 53, which serves as a fixed bed reactor
• Iron briquettes 63 are added. Subsequently, the iron briquettes or oxides are charged from above into the melter gasifier 48. Low reduced iron (LRI) may also be withdrawn from iron briquetting 51.
• LRI Low reduced iron
• the coal in the melter gasifier 48 is gasified, it produces a gas mixture consisting mainly of CO and H2, and withdrawn as a reducing gas (generator gas) 54 and a
• the top gas 54 withdrawn from the melter gasifier 48 is first passed into a separator 57 to deposit with discharged dust and to return the dust to the melter gasifier 48 via dust burners.
• a portion of the top dust purified by the coarse dust is further purified by wet scrubber 58 and removed as excess gas 59 from the Finex plant and - according to the invention - the
• Another portion of the purified generator gas 54 is also further purified in a wet scrubber 60, fed to a gas compressor 61 for cooling and then after mixing with the removed from the absorber 17, freed from CO 2 product gas 62 back to the generator gas 54 after the melter gasifier 48 for cooling fed.
• Iron oxides with dedusted and cooled generator gas 54 are heated and reduced from the melter gasifier 48, emerging top gas 55 is purified in a wet scrubber 64 and then also supplied to the absorber 17 for removing CO 2 .
• the stripper 18 can on the one hand low-pressure steam 46 from the waste heat boiler 45 and / or low-pressure steam 19 from the
• Low-pressure steam from the steam turbine 34 of the steam power plant 32 are supplied.
• the waste heat from the iron production process should be used because of the short distances between waste heat boiler and Appendix 14 to
• the condensate 23 of the stripper 18 is supplied to the steam cycle of the steam power plant 32 in this example. But it can also be supplied to the waste heat boiler or the combined cycle power plant.
• the residual gas 20 after the stripper 18 can be released into the atmosphere again wholly or in part after H 2 S cleaning 21 or completely or partially - after compression by means of compressor 22 - a C0 2 ⁇ storage are supplied.

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• Chemical & Material Sciences (AREA)
• Engineering & Computer Science (AREA)
• Analytical Chemistry (AREA)
• Chemical Kinetics & Catalysis (AREA)
• Oil, Petroleum & Natural Gas (AREA)
• General Chemical & Material Sciences (AREA)
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• Materials Engineering (AREA)
• Manufacturing & Machinery (AREA)
• Health & Medical Sciences (AREA)
• Biomedical Technology (AREA)
• Environmental & Geological Engineering (AREA)
• Waste-Gas Treatment And Other Accessory Devices For Furnaces (AREA)
• Gas Separation By Absorption (AREA)
• Separation Of Gases By Adsorption (AREA)
• Treating Waste Gases (AREA)

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Citations (8)

• 2009
  • 2009-09-11 AT AT0144009A patent/AT508770B1/de not_active IP Right Cessation
• 2010
  • 2010-06-09 UA UAU201202739U patent/UA75033U/ru unknown
  • 2010-09-06 BR BR212012005399U patent/BR212012005399U2/pt not_active IP Right Cessation
  • 2010-09-06 UA UAU201205160U patent/UA76874U/ru unknown
  • 2010-09-06 RU RU2012114143/05U patent/RU125879U1/ru not_active IP Right Cessation
  • 2010-09-06 CN CN2010900011302U patent/CN203002174U/zh not_active Expired - Fee Related
  • 2010-09-06 WO PCT/EP2010/063023 patent/WO2011029792A1/de active Application Filing

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