WO2011024794A1 - 膜濾過装置 - Google Patents
膜濾過装置 Download PDFInfo
- Publication number
- WO2011024794A1 WO2011024794A1 PCT/JP2010/064259 JP2010064259W WO2011024794A1 WO 2011024794 A1 WO2011024794 A1 WO 2011024794A1 JP 2010064259 W JP2010064259 W JP 2010064259W WO 2011024794 A1 WO2011024794 A1 WO 2011024794A1
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- Prior art keywords
- wall
- pressure vessel
- membrane
- internal member
- pressure
- Prior art date
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D61/00—Processes of separation using semi-permeable membranes, e.g. dialysis, osmosis or ultrafiltration; Apparatus, accessories or auxiliary operations specially adapted therefor
- B01D61/02—Reverse osmosis; Hyperfiltration ; Nanofiltration
- B01D61/12—Controlling or regulating
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D61/00—Processes of separation using semi-permeable membranes, e.g. dialysis, osmosis or ultrafiltration; Apparatus, accessories or auxiliary operations specially adapted therefor
- B01D61/14—Ultrafiltration; Microfiltration
- B01D61/22—Controlling or regulating
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D63/00—Apparatus in general for separation processes using semi-permeable membranes
- B01D63/10—Spiral-wound membrane modules
- B01D63/12—Spiral-wound membrane modules comprising multiple spiral-wound assemblies
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D2311/00—Details relating to membrane separation process operations and control
- B01D2311/14—Pressure control
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D2311/00—Details relating to membrane separation process operations and control
- B01D2311/16—Flow or flux control
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D2311/00—Details relating to membrane separation process operations and control
- B01D2311/24—Quality control
- B01D2311/243—Electrical conductivity control
Definitions
- the present invention relates to a membrane filtration device for producing a permeate by filtering a stock solution with a filtration membrane.
- a membrane filtration device configured by arranging a plurality of membrane elements in a straight line in a pressure vessel is known (for example, see Patent Document 1 below).
- This type of membrane filtration apparatus is generally used for obtaining purified permeated water (permeated liquid) by filtering raw water (raw liquid) such as waste water or seawater.
- raw water raw liquid
- a large number of membrane filtration devices are held in a rack called a train, so that processing characteristics (pressure, quality of permeated water, amount of water, etc.) are managed for each train.
- the property of the liquid in the membrane filtration device is detected by a sensor, and the signal from the sensor is transmitted from the inside of the pressure vessel to the outside, so that the property of the liquid in the membrane filtration device is externally transmitted. It is possible to observe.
- a signal from the sensor is transmitted to the outside by wire, a special structure or device is required in a pressure vessel filled with raw water at a high pressure of 10 MPa at maximum, so it is wireless. A configuration that transmits is preferable.
- raw water such as seawater with high salt concentration has high electrical conductivity
- a wireless antenna is provided in an environment where raw water with such high electrical conductivity is interposed, radio waves are attenuated by the raw water, There is a problem that wireless communication cannot be performed satisfactorily.
- the inventor of the present application has considered suppressing the influence of raw water by holding the wireless antenna by an internal member provided in the pressure vessel and devising the arrangement position of the internal member.
- the thickness of the raw water existing between the outer wall of the internal member and the inner wall of the pressure vessel is small, a certain amount of space is provided between the radio antenna provided on the inner member and the inner wall of the pressure vessel. It has been found that even if there is a distance, wireless communication can be performed satisfactorily.
- the present invention has been made in view of the above circumstances, and an object of the present invention is to provide a membrane filtration apparatus that can perform radio communication satisfactorily by arranging radio antennas more suitably.
- the membrane filtration device is a membrane filtration device that generates a permeate by filtering a stock solution with a filtration membrane, and contains a pressure-resistant container that contains the filtration membrane and is filled with the stock solution, Provided at a position different from between the filtration membrane and the inner wall of the pressure vessel in the pressure vessel, and at least a part of the outer wall is provided on the inner member near the inner wall of the pressure vessel.
- the structure provided with the radio antenna is mentioned.
- an internal member in which at least a part of the outer wall is close to the inner wall of the pressure vessel is provided at a position different from between the filtration membrane and the inner wall of the pressure vessel in the pressure vessel.
- a wireless antenna is provided on the member. Since at least a part of the outer wall of the internal member is close to the inner wall of the pressure vessel, the thickness of the stock solution existing between the outer wall and the inner wall of the pressure vessel is small, and attenuation of radio waves due to the stock solution can be suppressed. Therefore, wireless communication can be performed satisfactorily.
- the distance between the outer wall of the inner member adjacent to the inner wall of the pressure vessel and the inner wall of the pressure vessel is within 10 cm.
- the thickness of the stock solution existing between the outer wall of the inner member and the inner wall of the pressure vessel is within 10 cm, and the radio wave attenuation due to the stock solution can be effectively suppressed. It can be done better.
- This numerical value of “10 cm” is a numerical value derived from experiments based on the general electric conductivity range of the stock solution and the general frequency band used for wireless communication.
- the outer wall of the inner member adjacent to the inner wall of the pressure vessel is separated from the inner wall of the pressure vessel.
- the wireless antenna is embedded in the internal member.
- a sensor for detecting the property of the liquid in the pressure vessel may be provided, and a signal from the sensor may be transmitted via the wireless antenna.
- the signal from the sensor is transmitted via the wireless antenna and the signal is received outside the pressure vessel, the property of the liquid in the pressure vessel can be observed from the outside.
- the maintenance can be performed satisfactorily based on the observation result.
- the senor may be provided on the internal member.
- the wireless antenna and the sensor are integrally provided in the internal member, the electrical connection between the wireless antenna and the sensor can be reliably performed with a shorter wiring.
- the wireless antenna and the sensor can be handled integrally, assembly work of the membrane filtration device and the like are facilitated.
- the internal member may be provided at an end of a membrane element having the filtration membrane.
- the wireless antenna can be easily provided by providing the wireless antenna on the internal member provided at the end of the membrane element as compared with the configuration in which the wireless antenna is provided on the filtration membrane side. Can do.
- the internal member may be provided separately from the membrane element having the filtration membrane.
- the wireless antenna is more easily provided by providing the wireless antenna on the internal member provided separately from the membrane element, compared to the configuration in which the wireless antenna is provided on the membrane element. be able to.
- FIG. 1 is a schematic cross-sectional view showing an example of a membrane filtration device 50 according to an embodiment of the present invention.
- the membrane filtration device 50 is a device that generates permeated water (permeate) by filtering raw water (raw solution) with a filtration membrane, such as a spiral RO membrane element, a hollow fiber membrane module, and an immersion flat membrane module.
- a filtration membrane such as a spiral RO membrane element, a hollow fiber membrane module, and an immersion flat membrane module.
- the present invention can be applied to a membrane filtration device 50 including various water treatment membrane modules.
- the membrane filtration device 50 includes a pressure vessel 40, an internal member 100 provided in the pressure vessel 40, and an internal communication device 103 held by the internal member 100.
- the inside of the pressure vessel 40 is made of a resin container filled with raw water such as waste water or seawater.
- the pressure vessel 40 is formed in a cylindrical shape having an outer diameter of 11 cm (for 4 inch, low pressure vessel) to 45 cm (for 16 inch, high pressure vessel) and a wall thickness of 0.5 cm to 2.5 cm. Yes.
- the pressure vessel 40 is not limited to a cylindrical shape.
- the internal communication device 103 includes a wireless antenna 103A, and wireless communication can be performed with the external communication device 202 provided outside the pressure vessel 40 via the wireless antenna 103A.
- the frequency band for wireless communication by the internal communication device 103 is, for example, 2.4 GHz, UHF band such as 430 MHz, 13.56 MHz, or the like.
- the internal communication device 103 includes, for example, a crystal resonator, a resistor, a capacitor, an inductor, an arithmetic element (CPU, MPU, etc.), a control microcomputer, a rectifier element, an antenna, a memory, an operational amplifier, a signal A conversion element (analog-digital converter, digital-analog converter, etc.) and an imaging element (CCD, CMOS, etc.) are provided, and these electric components are connected on a circuit board.
- the wireless antenna 103A may be mounted on the circuit board, may be provided separately from the circuit board, and may be wired to the circuit board.
- the inner member 100 is made of, for example, resin, and at least a part of the outer wall thereof is close to the inner wall of the pressure vessel 40.
- the internal member 100 is formed in a circular shape having a smaller diameter than the inner periphery of the pressure resistant container 40, and the entire outer peripheral surface thereof is close to the inner wall of the pressure resistant container 40, but is not limited to this shape. If at least a part of the outer wall is close to the inner wall of the pressure vessel 40, various shapes such as a shape in which a concave portion is formed on a part of the outer peripheral surface can be adopted.
- various electrical components such as the internal communication device 103 including the wireless antenna 103A are embedded in the resin internal member 100.
- “embedding” means covering the object closely, and is highly waterproof, and there is no space between the object and there is a space between the object. Compared to the case, the pressure resistance against external pressure is high.
- the waterproof property can be improved, the wireless antenna 103A can be prevented from being rusted, and the pressure resistance can be improved. Wireless communication can be performed well even underneath.
- Examples of the molding method of the resin-made internal member 100 include injection molding, extrusion molding, insert molding, casting molding, vacuum casting molding, and the like, but are not limited to these molding methods.
- Examples of the resin 8 used in insert molding include polystyrene (PS), acrylonitrile-butadiene-styrene copolymer synthetic resin (ABS), polymethyl methacrylate (PMMA), polycarbonate (PC), vinyl chloride resin (PVC), and nylon.
- PA polyacetal
- PET polyethylene terephthalate
- PBT polybutylene terephthalate
- PPO polyphenylene oxide
- PSU polysulfone
- PPS polyphenylene sulfide
- PAS polyallylsulfone
- PAR polyarylate
- PPE polyphenylene ether
- PES polyethersulfone
- PEEK polyetheretherketone
- PI polyimide
- the resin forming the internal member 100 is preferably a highly rigid resin from the viewpoint of pressure resistance, and its Young's modulus is 0.3 GPa or more, more preferably 2 GPa or more, and even more preferably 3 GPa.
- the resin forming the internal member 100 is not limited to a single layer, and may have a configuration in which two or more layers are stacked.
- Raw water exists between the outer wall of the internal member 100 and the inner wall of the pressure vessel 40.
- Raw water such as seawater with high salinity has high electrical conductivity.
- wireless communication is performed via the wireless antenna 103A in an environment where raw water with such high electrical conductivity is present, radio waves are attenuated by the raw water. End up. Therefore, the thickness of the raw water existing between the outer wall of the internal member 100 and the inner wall of the pressure vessel 40, that is, the distance D1 between the outer wall of the internal member 100 close to the inner wall of the pressure vessel 40 and the inner wall of the pressure vessel 40 is as much as possible. The smaller one is better, and according to the results of experiments conducted by the inventors, it has been found that the distance D1 is preferably within 10 cm. The experimental results will be described below using Table 1.
- Example 1 The pressure resistant container 40 is filled with a saline solution having a salt concentration of 3.15%, and the thickness (distance D1) of the saline solution existing between the outer wall of the internal member 100 and the inner wall of the pressure resistant container 40 is 10 cm.
- Wireless communication was performed in the frequency band of 2.4 GHz via 103A, and the reception intensity was measured.
- the electrical conductivity of the saline solution as described above was 50500 ⁇ S / cm. As a result of this experiment, it was confirmed that the radio wave attenuation allowable range of a normal wireless system is 80 to 90 dB or less, and the reception strength is low, but wireless communication can be performed.
- radio wave attenuation allowable range for example, in a 2.4 GHz band IEEE 802.15.4-compliant wireless transmission system capable of operating with low power consumption in a container, data transmission with few errors and reliable communication is possible.
- Example 2 The pressure vessel 40 is filled with a saline solution having a salt concentration of 1.07%, and the thickness (distance D1) of the saline solution existing between the outer wall of the internal member 100 and the inner wall of the pressure vessel 40 is set to 9 cm.
- Wireless communication was performed in the frequency band of 2.4 GHz via 103A, and the reception intensity was measured.
- the electrical conductivity of the saline solution as described above was 18990 ⁇ S / cm. As a result of this experiment, it was confirmed that radio wave attenuation was small, sufficient reception intensity was obtained, and wireless communication could be performed.
- Example 3 The pressure resistant container 40 is filled with a saline solution having a salt concentration of 3.15%, and the thickness (distance D1) of the saline solution existing between the outer wall of the internal member 100 and the inner wall of the pressure resistant container 40 is 10 cm.
- Wireless communication was performed in the frequency band of 430 MHz via 103A, and the reception intensity was measured.
- the electrical conductivity of the saline solution as described above was 50500 ⁇ S / cm. As a result of this experiment, it was confirmed that radio wave attenuation was small, sufficient reception intensity was obtained, and wireless communication could be performed.
- Example 4 The pressure resistant container 40 is filled with a saline solution having a salt concentration of 2.81%, and the thickness (distance D1) of the saline existing between the outer wall of the internal member 100 and the inner wall of the pressure resistant container 40 is 10 cm.
- Wireless communication was performed in the frequency band of 13.56 MHz via 103A, and the received intensity was measured.
- the electrical conductivity of the saline solution as described above was 45600 ⁇ S / cm. As a result of this experiment, it was confirmed that radio wave attenuation was small, sufficient reception intensity was obtained, and wireless communication could be performed.
- the pressure resistant container 40 is filled with a saline solution having a salt concentration of 2.81%, and the thickness (distance D1) of the saline existing between the outer wall of the internal member 100 and the inner wall of the pressure resistant container 40 is 12 cm.
- Wireless communication was performed in the frequency band of 2.4 GHz via 103A, and the reception intensity was measured.
- the electrical conductivity of the saline solution as described above was 45600 ⁇ S / cm. As a result of this experiment, it was confirmed that the attenuation of radio waves greatly exceeded the allowable range of a normal wireless system, a signal could not be received, and wireless communication could not be performed.
- the pressure-resistant container 40 is filled with permeated water having a salt concentration of 0%, and the thickness of the permeated water (distance D1) existing between the outer wall of the internal member 100 and the inner wall of the pressure-resistant container 40 is 14 cm.
- Wireless communication was performed in the 2.4 GHz frequency band, and the received intensity was measured.
- the electric conductivity of the permeated water as described above was 10 ⁇ S / cm. As a result of this experiment, it was confirmed that the attenuation level of radio waves greatly exceeded the allowable range of a normal wireless system, the signal could not be continuously received, and it was an unsuitable condition for wireless communication. .
- the pressure vessel 40 is filled with a saline solution having a salt concentration of 3.15%, and the thickness (distance D1) of the salt solution existing between the outer wall of the internal member 100 and the inner wall of the pressure vessel 40 is set to 15 cm.
- Wireless communication was performed in the frequency band of 430 MHz via 103A, and the reception intensity was measured.
- the electrical conductivity of the saline solution as described above was 50500 ⁇ S / cm. As a result of this experiment, it was confirmed that the attenuation of radio waves greatly exceeded the allowable range of a normal wireless system, and sufficient reception intensity could not be obtained, which is an unsuitable condition for wireless communication.
- the pressure vessel 40 is filled with a salt solution having a salt concentration of 2.81%, and the thickness (distance D1) of the salt solution existing between the outer wall of the internal member 100 and the inner wall of the pressure vessel 40 is 20 cm.
- Wireless communication was performed in the frequency band of 13.56 MHz via 103A, and the received intensity was measured.
- the electrical conductivity of the saline solution as described above was 45600 ⁇ S / cm.
- the radio wave attenuation due to the raw water can be effectively suppressed. Communication can be performed better.
- This numerical value of “10 cm” indicates that the general electric conductivity of raw water is 500 to 130000 ⁇ S / cm and the general frequency band used for wireless communication is 13.56 MHz to 2.4 GHz. It can be derived based on such experimental results.
- the outer wall of the inner member 100 adjacent to the inner wall of the pressure vessel 40 is separated from the inner wall of the pressure vessel 40. That is, the distance D1 is preferably not “0”. With such a configuration, the outer wall of the internal member 100 and the inner wall of the pressure vessel 40 are not in contact with each other. Therefore, when the member such as the internal member 100 is loaded in the pressure vessel 40, the internal member 100 is not attached to the pressure vessel 40. It is possible to prevent damage due to friction with the inner wall or increase in labor during loading.
- the thickness (distance D1) of the raw water existing between the outer wall of the internal member 100 and the inner wall of the pressure vessel 40 is small, the distance D2 between the radio antenna 103A provided on the internal member 100 and the inner wall of the pressure vessel 40 Even if there is a certain amount, wireless communication can be performed satisfactorily.
- FIG. 2 is a schematic cross-sectional view showing a configuration example of the membrane filtration device 50.
- FIG. 3 is a perspective view showing a part of the internal configuration of the membrane element 10 of FIG.
- the membrane filtration device 50 is configured by arranging a plurality of membrane elements 10 in a straight line in the pressure vessel 40.
- the pressure vessel 40 is a resin cylinder called a vessel, and is formed of, for example, FRP (Fiberglass Reinforced Plastics).
- FRP Fiberberglass Reinforced Plastics
- the pressure vessel 40 is formed in a cylindrical shape.
- a raw water inlet 48 into which raw water (raw solution) such as drainage and seawater flows is formed at one end of the pressure vessel 40, and the raw water flowing in from the raw water inlet 48 is filtered by the plurality of membrane elements 10. As a result, purified permeated water (permeated liquid) and concentrated water (concentrated liquid) that is raw water after filtration are obtained.
- a permeate outlet 46 through which permeate flows out and a concentrated water outlet 44 through which concentrated water flows out are formed.
- the membrane element 10 is spirally wound around the central tube 20 in a state where the filtration membrane 12, the supply-side channel material 18, and the permeation-side channel material 14 are laminated.
- RO Reverse Osmosis
- Filtration membranes 12 having the same rectangular shape are superposed on both sides of a rectangular permeation-side flow path material 14 made of a resin-made net-like member, and the three sides are bonded to each other so that an opening is formed on one side.
- a bag-like film member 16 having the above is formed. And the opening part of this membrane member 16 is attached to the outer peripheral surface of the center pipe
- the filtration membrane 12 is formed, for example, by sequentially laminating a porous support and a skin layer (dense layer) on a nonwoven fabric layer.
- the raw water passes through the membrane element 10 through the raw water flow path formed by the supply-side flow path material 18 that functions as a raw water spacer. To do. At that time, the raw water is filtered by the filtration membrane 12, and the permeated water filtered from the raw water penetrates into the permeated water flow path formed by the permeate side flow path material 14 functioning as a permeated water spacer.
- the permeated water that has permeated into the permeated water flow path flows to the central tube 20 side through the permeated water flow path, and the central tube is formed from a plurality of water passage holes (not shown) formed on the outer peripheral surface of the central tube 20. 20 is led.
- the permeated water flows out from the other end side of the membrane element 10 through the central tube 20, and the concentrated water flows out through the raw water flow path formed by the supply side flow path material 18.
- the central tubes 20 of the adjacent membrane elements 10 are connected by a tubular interconnector (connecting portion) 42. Therefore, the raw water flowing in from the raw water inlet 48 flows into the raw water flow path in order from the membrane element 10 on the raw water inlet 48 side, and the permeated water filtered from the raw water in each membrane element 10 is connected by the interconnector 42.
- the permeated water outlet 46 flows out through the single central pipe 20.
- the concentrated water that is filtered and concentrated by passing through the raw water flow path of each membrane element 10 flows out from the concentrated water outlet 44.
- each internal member 100 functions as a telescope prevention member for preventing the wound membrane member 16 from becoming a telescope shape by being displaced in the axial direction.
- the inner member 100 has a shape in which the outer peripheral surface thereof corresponds to the outer peripheral surface of the membrane element 10, and the outer peripheral surface of the inner member 100 is opposed to the inner peripheral surface of the pressure vessel 40.
- the internal member 100 is detachably provided at both ends of each membrane element 10.
- An external unit 200 is provided at a position facing the internal member 100 outside the pressure vessel 40.
- the external unit 200 is for performing data communication wirelessly with the internal communication device 103 provided in the internal member 100.
- the external unit 200 is formed integrally with the pressure vessel 40.
- FIG. 4A and 4B are diagrams showing a configuration example of the internal member 100, where FIG. 4A is a cross-sectional view and FIG. 4B is a front view. However, in FIG.4 (b), the internal structure of the internal member 100 is shown with the continuous line instead of the broken line.
- the internal member 100 includes a main body 101, a first conductive wire 102 held by the main body 101, an internal communication device 103, a plurality of sensors 104, 105, 106, and an IC chip 107.
- the main body 101 has a configuration in which a first annular portion 111 and a second annular portion 112 having a smaller diameter than the first annular portion 111 are connected through a rib 113 so as to be integrally formed. Yes.
- the main body 101 is formed of resin, but may be formed of other materials.
- the first annular portion 111 has an outer diameter that is substantially the same as the outer diameter of the membrane element 10, and is disposed so that its outer peripheral surface is close to and faces the inner peripheral surface of the pressure vessel 40.
- the internal peripheral surface comprises the flow path of permeated water.
- the rib 113 is a member that connects the inner peripheral surface of the first annular portion 111 and the outer peripheral surface of the second annular portion 112, and a plurality of ribs 113 are preferably provided.
- the main body 101 is not limited to the shape as described above, and may be another shape such as a disk shape.
- the first conductive wire 102 is a coiled conductive wire formed by winding a conductive wire, and is attached to the first annular portion 111 of the main body 101.
- the first conductive wire 102 is provided in a shape (state) along the outer peripheral surface of the first annular portion 111 inside the first annular portion 111.
- the first conductive wire 102 is provided so as to face the inner peripheral surface of the pressure resistant container 40 in the vicinity thereof.
- the first conductive wire 102 may be provided outside the internal member 100 or may be provided inside.
- the distance between the first conductive wire 102 and the inner peripheral surface of the pressure vessel 40 is preferably as short as possible from the viewpoint of satisfactorily transmitting and receiving radio waves to and from the outside of the pressure vessel 40. Specifically, the distance is preferably within 15 cm, more preferably within 5 cm, and even more preferably within 3 cm.
- the internal communication device 103 is attached to the first annular portion 111 of the main body 101. As described above, the internal communication device 103 includes the wireless antenna 103A, and can transmit and receive data via the wireless antenna 103A.
- the internal communication device 103 may be configured to include RFID (Radio Frequency Identification).
- the internal communication device 103 can wirelessly transmit output signals of sensors 104, 105, and 106 described later from the wireless antenna 103A.
- the wireless antenna 103 ⁇ / b> A is provided so as to face the inner peripheral surface of the pressure vessel 40 in the vicinity.
- the distance between the radio antenna 103A of the internal communication device 103 and the inner peripheral surface of the pressure vessel 40 is preferably as short as possible from the viewpoint of satisfactorily transmitting and receiving radio waves to and from the outside of the pressure vessel 40. Specifically, the distance is preferably within 15 cm, more preferably within 5 cm, and even more preferably within 3 cm.
- the inner member 100 is provided at the end of the membrane element 10 having the filtration membrane 12, so that the inner member 100 is provided at a position different from that between the filtration membrane 12 and the inner wall of the pressure vessel 40. It has been. With such a configuration, it is possible to relax restrictions on the arrangement position of the radio antenna 103A compared to the case where the radio antenna 103A is provided between the filtration membrane 12 and the inner wall of the pressure vessel 40 in the pressure vessel 40. Thus, the radio antenna 103A can be more suitably arranged.
- the wireless antenna 103A can be easily provided as compared with the configuration in which the wireless antenna 103A is provided on the filtration membrane 12 side. Can do.
- the conductivity sensor 104 and the flow rate sensor 105 are sensors that are attached to the second annular portion 112 of the main body 101 and detect the properties of the permeated water flowing inside the second annular portion 112.
- the conductivity sensor 104 is a sensor that detects the conductivity of the permeated water
- the flow rate sensor 105 is a sensor that detects the flow rate of the permeated water.
- the pressure sensor 106 is a sensor that is attached to the rib 113 of the main body 101 and detects the property of raw water.
- the pressure sensor 106 is a sensor that detects the pressure of raw water, and can be configured by, for example, a piezoelectric element or a strain gauge.
- the configuration of the liquid flowing in the pressure resistant container 40 is not limited to such a configuration. If it is a sensor which detects this, various sensors, such as a well-known physical sensor, a chemical sensor, and a smart sensor (sensor with an information processing function), can be provided in the internal member 100 according to the characteristic. However, it is preferable that at least one of the conductivity sensor 104, the flow sensor 105, and the pressure sensor 106 is provided in the internal member 100. In addition, as a property of the liquid detected by the sensor provided in the internal member 100, a flow rate, a pressure, electrical conductivity, temperature, a contamination condition (ion concentration etc.) can be mentioned, for example.
- the pressure vessel 40 Since the property of the liquid in 40 can be observed from the outside, the maintenance can be favorably performed based on the observation result.
- the wireless antenna 103A and the sensor 104, 105, 106 are integrally provided on the internal member 100.
- the electrical connection between the wireless antenna 103A and the sensors 104, 105, 106 can be reliably performed with a shorter wiring.
- the wireless antenna 103A and the sensors 104, 105, and 106 can be handled integrally, assembly work and the like of the membrane filtration device 50 are facilitated.
- the IC chip 107 is a microcomputer that performs power control, sensor control, communication control, and the like for each of the electrical components provided in the internal member 100.
- the IC chip 107 may be configured by a plurality of chips, or may be configured as a single chip.
- the electrical components held by the main body 101 of the internal member 100 as described above, that is, the first conductive wire 102, the internal communication device 103, the plurality of sensors 104, 105, 106, and the IC chip 107 are embedded in the main body 101, respectively.
- the periphery is covered with resin.
- the wiring for electrically connecting the components as described above is also embedded in the main body 101 so that the periphery is covered with resin.
- corrosion and damage of each component can be suppressed by seawater, wastewater, acid, alkali used at the time of washing, or the like.
- the other part excluding the detection part is embedded in the main body 101.
- the membrane element 10 is replaced.
- the internal member 100 used for the old membrane element 10 for the new membrane element 10 these electrical components can be reused.
- FIG. 5 is a schematic cross-sectional view showing an example of a membrane filtration device 50 using the internal member 100 of FIG.
- the internal configuration of the internal member 100 is indicated by a solid line instead of a broken line.
- the external unit 200 provided outside the pressure vessel 40 includes a second conductive wire 201, an external communication device 202, and an IC chip 203.
- the second conductive wire 201 is a coiled conductive wire formed by winding the conductive wire, and has a shape (state) along the outer peripheral surface of the pressure-resistant container 40 at a position facing the first conductive wire 102. ).
- the second conductive wire 201 may be in contact with the outer peripheral surface of the pressure-resistant container 40 or may be separated from the outer peripheral surface of the pressure-resistant container 40 when adopting a separated configuration. It is preferable that they face each other in close proximity.
- the second conductive line 201 may be embedded in a material (for example, a resin material) constituting the pressure resistant container 40.
- the distance between the second conductive wire 201 and the outer peripheral surface of the pressure vessel 40 is preferably as short as possible from the viewpoint of satisfactorily transmitting and receiving radio waves between the inside of the pressure vessel 40. Specifically, the distance is preferably within 15 cm, more preferably within 5 cm, and even more preferably within 3 cm.
- the external communication device 202 is provided at a position facing the internal communication device 103 outside the pressure vessel 40.
- the external communication device 202 functions as a relay device that receives data from the internal communication device 103 and transmits the received data to a management device or the like wirelessly.
- Data communication between the internal communication device 103 and the external communication device 202 is performed by transmitting and receiving radio waves in a frequency band of 2.4 GHz, for example.
- the IC chip 203 constitutes a power feeding device that wirelessly supplies power from the second conductive line 201 to the first conductive line 102.
- the IC chip 203 includes an oscillation circuit and an amplification circuit, and performs power supply by transmitting radio waves from the second conductive line 201 to the first conductive line 102 in a frequency band of 13.56 MHz, for example.
- the IC chip 203 may be formed integrally with the external communication device 202.
- the configuration in which power is supplied via the first conductive line 102 and the second conductive line 201 has been described.
- the first conductive line 102 and the second conductive line 201 are omitted, and the pressure vessel 40
- the configuration may be such that power is generated internally.
- a rotating body such as an impeller in the pressure vessel 40 and rotating the rotating body with the flow pressure of the liquid (raw water, permeated water, etc.) flowing in the pressure vessel 40, power generation can be performed. It may be a configuration or the like.
- FIGS. 6A and 6B are diagrams showing another configuration example of the internal member 100, where FIG. 6A is a cross-sectional view and FIG. 6B is a front view. However, in FIG.6 (b), the internal structure of the internal member 100 is shown with the continuous line instead of the broken line. Only the configuration different from the configuration example of FIGS. 4 and 5 will be described below.
- the internal member 100 includes a main body 101, a first conductive wire 102, a plurality of sensors 104, 105, 106, and an IC chip 107 held by the main body 101, respectively. Unlike the configuration example, the internal communication device 103 is not provided.
- the IC chip 107 is provided with a modulation / demodulation circuit 108.
- the modulation / demodulation circuit 108 is a modulation / demodulation device for modulating a radio signal transmitted through the first conductive line 102 and demodulating a radio signal received through the first conductive line 102.
- the modulation / demodulation circuit 108 is not limited to the configuration formed integrally with the IC chip 107, and may be a configuration provided separately from the IC chip 107.
- FIG. 7 is a schematic cross-sectional view showing an example of a membrane filtration device 50 using the internal member 100 of FIG.
- the internal configuration of the internal member 100 is indicated by a solid line instead of a broken line.
- the external unit 200 provided outside the pressure vessel 40 includes a second conductive wire 201, an external communication device 202, and an IC chip 203.
- the IC chip 203 is provided with a modulation / demodulation circuit 204.
- the modulation / demodulation circuit 204 is a modulation / demodulation device for modulating a radio signal transmitted through the second conductive line 201 and demodulating a radio signal received through the second conductive line 201.
- the modulation / demodulation circuit 204 is not limited to the configuration formed integrally with the IC chip 203, and may be a configuration provided separately from the IC chip 203.
- the output signals of the sensors 104, 105, 106 are modulated by the modulation / demodulation circuit 108 and transmitted wirelessly from the first conductive line 102, and the radio signal received via the second conductive line 201 is demodulated by the modulation / demodulation circuit 204. It has come to be.
- the signal demodulated by the modulation / demodulation circuit 204 is received by the external communication device 202 functioning as a repeater and transmitted wirelessly to a management device or the like.
- the first conductive line 102 functions as a wireless antenna in the present invention. To do.
- the configuration in which power is supplied through the first conductive wire 102 and the second conductive wire 201 has been described.
- a configuration in which power generation is performed inside the pressure vessel 40 may be employed.
- a rotating body such as an impeller in the pressure vessel 40 and rotating the rotating body with the flow pressure of the liquid (raw water, permeated water, etc.) flowing in the pressure vessel 40, power generation can be performed. It may be a configuration or the like.
- FIG. 8 is a schematic sectional view showing another example of the membrane filtration device 50. Similar to the membrane filtration device 50 shown in FIG. 2, the membrane filtration device 50 is configured by arranging a plurality of membrane elements 10 in a straight line in the pressure vessel 40. The specific configuration of the membrane element 10 is the same as the configuration described with reference to FIG.
- an internal member 100 is provided as a separate body from the membrane element 10.
- the inner member 100 has a shape in which the outer peripheral surface thereof corresponds to the outer peripheral surface of the membrane element 10, and the outer peripheral surface of the inner member 100 is opposed to the inner peripheral surface of the pressure vessel 40.
- the internal member 100 is attached to the interconnector 42, and the internal member 100 is provided with the above-described wireless antenna 103A and the like.
- the interconnector 42 can be attached to and detached from the central tube 20 of each membrane element 10, whereby the internal member 100 can be attached and detached.
- the configuration described with reference to FIG. 4 or FIG. 6 can be adopted.
- the membrane filtration device 50 having such a configuration is compared with a configuration in which the radio antenna 103A is provided on the membrane element 10 by providing the radio antenna 103A on the internal member 100 provided separately from the membrane element 10.
- the wireless antenna 103A can be provided more easily.
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- Water Supply & Treatment (AREA)
- Chemical & Material Sciences (AREA)
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- Separation Using Semi-Permeable Membranes (AREA)
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Abstract
Description
耐圧容器40内に、塩分濃度3.15%の食塩水を充填し、内部部材100の外壁と耐圧容器40の内壁との間に存在する食塩水の厚み(距離D1)を10cmとして、無線アンテナ103Aを介して2.4GHzの周波数帯で無線通信を行い、その受信強度を測定した。上記のような食塩水の電気伝導度は50500μS/cmであった。この実験の結果、通常の無線システムの電波減衰許容範囲である80~90dB以下の程度で、受信強度は低いものの、無線通信を行うことができる程度であることが確認された。なお、上記電波減衰許容範囲については、例えば容器内での少ない消費電力で動作可能な2.4GHz帯のIEEE802.15.4準拠の無線伝送方式では、誤りが少なく通信確実性のあるデータ伝送が可能な無線装置での受信電力は、-90dBm(1mW=0dBm)程度であり、容器内無線装置送信電力が0mWでは、電波減衰度の許容範囲は80~90dB以下程度が目安となる。
耐圧容器40内に、塩分濃度1.07%の食塩水を充填し、内部部材100の外壁と耐圧容器40の内壁との間に存在する食塩水の厚み(距離D1)を9cmとして、無線アンテナ103Aを介して2.4GHzの周波数帯で無線通信を行い、その受信強度を測定した。上記のような食塩水の電気伝導度は18990μS/cmであった。この実験の結果、電波の減衰度は小さく、十分な受信強度が得られ、無線通信を行うことができることが確認された。
耐圧容器40内に、塩分濃度3.15%の食塩水を充填し、内部部材100の外壁と耐圧容器40の内壁との間に存在する食塩水の厚み(距離D1)を10cmとして、無線アンテナ103Aを介して430MHzの周波数帯で無線通信を行い、その受信強度を測定した。上記のような食塩水の電気伝導度は50500μS/cmであった。この実験の結果、電波の減衰度は小さく、十分な受信強度が得られ、無線通信を行うことができることが確認された。
耐圧容器40内に、塩分濃度2.81%の食塩水を充填し、内部部材100の外壁と耐圧容器40の内壁との間に存在する食塩水の厚み(距離D1)を10cmとして、無線アンテナ103Aを介して13.56MHzの周波数帯で無線通信を行い、その受信強度を測定した。上記のような食塩水の電気伝導度は45600μS/cmであった。この実験の結果、電波の減衰度は小さく、十分な受信強度が得られ、無線通信を行うことができることが確認された。
耐圧容器40内に、塩分濃度2.81%の食塩水を充填し、内部部材100の外壁と耐圧容器40の内壁との間に存在する食塩水の厚み(距離D1)を12cmとして、無線アンテナ103Aを介して2.4GHzの周波数帯で無線通信を行い、その受信強度を測定した。上記のような食塩水の電気伝導度は45600μS/cmであった。この実験の結果、電波の減衰度は通常の無線システムの許容範囲を大幅に超え、信号を受信することができず、無線通信を行うことができないことが確認された。
耐圧容器40内に、塩分濃度0%の透過水を充填し、内部部材100の外壁と耐圧容器40の内壁との間に存在する透過水の厚み(距離D1)を14cmとして、無線アンテナ103Aを介して2.4GHzの周波数帯で無線通信を行い、その受信強度を測定した。上記のような透過水の電気伝導度は10μS/cmであった。この実験の結果、電波の減衰度は通常の無線システムの許容範囲を大幅に超え、信号を継続的に受信することができず、無線通信を行うには不適な条件であることが確認された。
耐圧容器40内に、塩分濃度3.15%の食塩水を充填し、内部部材100の外壁と耐圧容器40の内壁との間に存在する食塩水の厚み(距離D1)を15cmとして、無線アンテナ103Aを介して430MHzの周波数帯で無線通信を行い、その受信強度を測定した。上記のような食塩水の電気伝導度は50500μS/cmであった。この実験の結果、電波の減衰度は通常の無線システムの許容範囲を大幅に超え、十分な受信強度が得られず、無線通信を行うには不適な条件であることが確認された。
耐圧容器40内に、塩分濃度2.81%の食塩水を充填し、内部部材100の外壁と耐圧容器40の内壁との間に存在する食塩水の厚み(距離D1)を20cmとして、無線アンテナ103Aを介して13.56MHzの周波数帯で無線通信を行い、その受信強度を測定した。上記のような食塩水の電気伝導度は45600μS/cmであった。この実験の結果、電波の減衰度は通常の無線システムの許容範囲を大幅に超え、十分な受信強度が得られず、無線通信を行うには不適な条件であることが確認された。
12 濾過膜
40 耐圧容器
50 膜濾過装置
100 内部部材
101 本体
102 第1導電線
103 内部通信装置
103A 無線アンテナ
104 電導度センサ
105 流量センサ
106 圧力センサ
200 外部ユニット
201 第2導電線
202 外部通信装置
Claims (8)
- 濾過膜で原液を濾過することにより透過液を生成する膜濾過装置であって、
前記濾過膜を収容し、内部に原液が充填される耐圧容器と、
前記耐圧容器内における前記濾過膜と前記耐圧容器の内壁との間とは異なる位置に設けられ、その外壁の少なくとも一部が前記耐圧容器の内壁に近接する内部部材と、
前記内部部材に設けられた無線アンテナとを備えたことを特徴とする膜濾過装置。 - 前記内部部材における前記耐圧容器の内壁に近接する外壁と前記耐圧容器の内壁との距離が、10cm以内であることを特徴とする請求項1に記載の膜濾過装置。
- 前記内部部材における前記耐圧容器の内壁に近接する外壁は、前記耐圧容器の内壁から離間していることを特徴とする請求項1に記載の膜濾過装置。
- 前記無線アンテナが、前記内部部材に包埋されていることを特徴とする請求項1に記載の膜濾過装置。
- 前記耐圧容器内の液体の性状を検知するセンサを備え、
前記センサからの信号が、前記無線アンテナを介して送信されることを特徴とする請求項1に記載の膜濾過装置。 - 前記センサが、前記内部部材に設けられていることを特徴とする請求項5に記載の膜濾過装置。
- 前記内部部材は、前記濾過膜を有する膜エレメントの端部に設けられていることを特徴とする請求項1に記載の膜濾過装置。
- 前記内部部材は、前記濾過膜を有する膜エレメントとは別体として設けられていることを特徴とする請求項1に記載の膜濾過装置。
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EP10811844.9A EP2471591A4 (en) | 2009-08-27 | 2010-08-24 | membrane filtration |
AU2010287648A AU2010287648B2 (en) | 2009-08-27 | 2010-08-24 | Membrane filtration device |
CN201080037849.6A CN102481523B (zh) | 2009-08-27 | 2010-08-24 | 膜过滤装置 |
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JP2009-197156 | 2009-08-27 | ||
JP2009197156A JP5473482B2 (ja) | 2009-08-27 | 2009-08-27 | 膜濾過装置 |
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JP (1) | JP5473482B2 (ja) |
CN (1) | CN102481523B (ja) |
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Cited By (4)
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JP2012213729A (ja) * | 2011-03-31 | 2012-11-08 | Mitsubishi Heavy Ind Ltd | 逆浸透膜淡水化装置及びこの検査方法 |
CN103459000A (zh) * | 2011-04-06 | 2013-12-18 | 日东电工株式会社 | 分离膜模块及连接部件 |
JP2016165669A (ja) * | 2015-03-09 | 2016-09-15 | 株式会社日本トリム | 電解水生成装置、及びその管理システム |
US9685381B2 (en) | 2013-06-28 | 2017-06-20 | Intel Corporation | Integrating VLSI-compatible fin structures with selective epitaxial growth and fabricating devices thereon |
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JP2012176370A (ja) * | 2011-02-28 | 2012-09-13 | Nitto Denko Corp | 連結部材および分離膜モジュール |
JP5628709B2 (ja) * | 2011-02-28 | 2014-11-19 | 日東電工株式会社 | 分離膜モジュール |
JP2012176372A (ja) * | 2011-02-28 | 2012-09-13 | Nitto Denko Corp | 連結部材および分離膜モジュール |
KR102411322B1 (ko) * | 2016-08-31 | 2022-06-22 | 다우 글로벌 테크놀로지스 엘엘씨 | 통합된 투과액 모니터링을 포함하는 나권형 모듈 조립체 |
JP7121036B2 (ja) * | 2017-04-05 | 2022-08-17 | ダウ グローバル テクノロジーズ エルエルシー | 統合圧力モニタリングを含むスパイラル巻きモジュールアセンブリ |
US20200197869A1 (en) * | 2017-05-11 | 2020-06-25 | Cms Interests Pty Ltd | Monitoring of membrane modules |
ES2890815T3 (es) * | 2017-07-27 | 2022-01-24 | Ddp Specialty Electronic Mat Us Llc | Módulo de membrana enrollada en espiral que incluye supervisión de presión diferencial integrada |
KR20200109321A (ko) | 2018-01-15 | 2020-09-22 | 디디피 스페셜티 일렉트로닉 머티리얼즈 유에스, 인크. | 일체형 유동 제한기 및 센서를 갖는 와권형 조립체 |
SI26349A (sl) | 2022-04-11 | 2023-10-30 | Instrumentation Technologies, D.O.O. | Postopek za merjenje različnih parametrov fluida in naprava za izvedbo postopka |
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- 2010-08-24 EP EP10811844.9A patent/EP2471591A4/en not_active Withdrawn
- 2010-08-24 CN CN201080037849.6A patent/CN102481523B/zh not_active Expired - Fee Related
- 2010-08-24 WO PCT/JP2010/064259 patent/WO2011024794A1/ja active Application Filing
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CN102481523B (zh) | 2014-11-12 |
EP2471591A4 (en) | 2014-01-15 |
EP2471591A1 (en) | 2012-07-04 |
CN102481523A (zh) | 2012-05-30 |
AU2010287648B2 (en) | 2014-01-30 |
JP5473482B2 (ja) | 2014-04-16 |
AU2010287648A1 (en) | 2012-04-12 |
JP2011045841A (ja) | 2011-03-10 |
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