WO2011010049A2 - Procédé et appareil de séparation d'air par distillation cryogénique - Google Patents
Procédé et appareil de séparation d'air par distillation cryogénique Download PDFInfo
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- WO2011010049A2 WO2011010049A2 PCT/FR2010/051492 FR2010051492W WO2011010049A2 WO 2011010049 A2 WO2011010049 A2 WO 2011010049A2 FR 2010051492 W FR2010051492 W FR 2010051492W WO 2011010049 A2 WO2011010049 A2 WO 2011010049A2
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- air
- booster
- exchange line
- hot
- cold
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- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F25—REFRIGERATION OR COOLING; COMBINED HEATING AND REFRIGERATION SYSTEMS; HEAT PUMP SYSTEMS; MANUFACTURE OR STORAGE OF ICE; LIQUEFACTION SOLIDIFICATION OF GASES
- F25J—LIQUEFACTION, SOLIDIFICATION OR SEPARATION OF GASES OR GASEOUS OR LIQUEFIED GASEOUS MIXTURES BY PRESSURE AND COLD TREATMENT OR BY BRINGING THEM INTO THE SUPERCRITICAL STATE
- F25J3/00—Processes or apparatus for separating the constituents of gaseous or liquefied gaseous mixtures involving the use of liquefaction or solidification
- F25J3/02—Processes or apparatus for separating the constituents of gaseous or liquefied gaseous mixtures involving the use of liquefaction or solidification by rectification, i.e. by continuous interchange of heat and material between a vapour stream and a liquid stream
- F25J3/04—Processes or apparatus for separating the constituents of gaseous or liquefied gaseous mixtures involving the use of liquefaction or solidification by rectification, i.e. by continuous interchange of heat and material between a vapour stream and a liquid stream for air
- F25J3/04763—Start-up or control of the process; Details of the apparatus used
- F25J3/04769—Operation, control and regulation of the process; Instrumentation within the process
- F25J3/04781—Pressure changing devices, e.g. for compression, expansion, liquid pumping
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- F25J—LIQUEFACTION, SOLIDIFICATION OR SEPARATION OF GASES OR GASEOUS OR LIQUEFIED GASEOUS MIXTURES BY PRESSURE AND COLD TREATMENT OR BY BRINGING THEM INTO THE SUPERCRITICAL STATE
- F25J3/00—Processes or apparatus for separating the constituents of gaseous or liquefied gaseous mixtures involving the use of liquefaction or solidification
- F25J3/02—Processes or apparatus for separating the constituents of gaseous or liquefied gaseous mixtures involving the use of liquefaction or solidification by rectification, i.e. by continuous interchange of heat and material between a vapour stream and a liquid stream
- F25J3/04—Processes or apparatus for separating the constituents of gaseous or liquefied gaseous mixtures involving the use of liquefaction or solidification by rectification, i.e. by continuous interchange of heat and material between a vapour stream and a liquid stream for air
- F25J3/04006—Providing pressurised feed air or process streams within or from the air fractionation unit
- F25J3/04012—Providing pressurised feed air or process streams within or from the air fractionation unit by compression of warm gaseous streams; details of intake or interstage cooling
- F25J3/04018—Providing pressurised feed air or process streams within or from the air fractionation unit by compression of warm gaseous streams; details of intake or interstage cooling of main feed air
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- F25J3/04006—Providing pressurised feed air or process streams within or from the air fractionation unit
- F25J3/04012—Providing pressurised feed air or process streams within or from the air fractionation unit by compression of warm gaseous streams; details of intake or interstage cooling
- F25J3/04024—Providing pressurised feed air or process streams within or from the air fractionation unit by compression of warm gaseous streams; details of intake or interstage cooling of purified feed air, so-called boosted air
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- F25J3/0429—Generation of cold for compensating heat leaks or liquid production, e.g. by Joule-Thompson expansion using internal refrigeration by open-loop gas work expansion, e.g. of intermediate or oxygen enriched (waste-)streams of feed air, e.g. used as waste or product air or expanded into an auxiliary column
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- F25J3/04763—Start-up or control of the process; Details of the apparatus used
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Definitions
- the present invention relates to a method and apparatus for air separation by cryogenic distillation.
- the invention is particularly applicable to air separation methods using a hot air booster, a cold air booster and two air turbines.
- a cold air booster is a booster powered by air at a temperature colder than the temperature of the hot end of the main exchange line of the apparatus, typically powered by air unless -20 0 C.
- the purified air from the main compressor is divided into two. A portion is sent to a hot booster, cooled in the exchange line to an intermediate temperature and then relaxed in two Claude turbines connected in parallel. Part of the air from the hot booster may possibly be liquefied in the exchange line instead of being sent to the turbines.
- the remainder of the air from the main compressor cools in the exchange line without being overpressurized upstream of it and is supercharged in a cold booster at an intermediate temperature of the exchange line, returned to the line d exchange at an intermediate temperature of the exchange line, liquefied and sent to at least one column of the double column.
- At least one waste gas is heated in the exchange line where a pressurized liquid from the double column, in particular oxygen, is also vaporized.
- the optimum configuration in this case is to supply the cold booster to a pressure close to the outlet pressure of the main compressor.
- the rest of the air (70% of the flow rate) feeds the Claude turbines after passing through the hot booster.
- the output pressure of the main compressor is very insufficient to allow the vaporization of oxygen.
- the present invention seeks to find a solution to this problem.
- a process for separating air by cryogenic distillation in an installation comprising a double or triple air separation column, whose column operating at the highest pressure operates at a pressure said medium pressure and an exchange line where all the air for distillation is cooled in which in normal operation:
- the first cooled fraction is divided into two portions, each portion is expanded in a respective turbine,
- the inlet pressure of the first and second turbines is, or the pressures of the two turbines are greater than or greater than 5 bars at medium pressure
- a second fraction of the purified air at high pressure is cooled in a first series of passages of the exchange line and then supercharged with an inlet temperature equal to an intermediate temperature of the exchange line in a cold booster mechanically connected to the second turbine, the hot booster being mechanically connected to the first turbine,
- the cold booster delivers the second fraction of air at a temperature higher than the inlet temperature, and the second air fraction thus overpressed is reintroduced into a second series of passages of the exchange line, possibly at a intermediate point thereof, wherein at least a portion of the second fraction is condensed or pseudo-condensed
- at least one pressurized liquid from one of the columns of the double or triple column is vaporized or pseudo vaporized in the exchange line at a vaporization temperature and characterized in that if the cold booster does not operate, a first part of the purified air at high pressure is sent to the hot booster liquefies and is sent to at least one column of the double or triple column and / or air from the hot booster and / or bypassed the
- the hot booster cools in the exchange line and is expanded in the turbine coupled to the hot booster, before being sent at least in part to the column operating at medium pressure.
- the cold booster does not operate a second part of the purified air cools to high pressure at an intermediate temperature of the exchange line, is expanded in a valve and is sent to the atmosphere without being overpressed by the hot booster, preferably after reheating in the exchange line;
- air from the hot booster cools in the exchange line and is expanded in the turbine coupled to the hot booster, before being sent at least in part at the column operating at medium pressure;
- air having short-circuited the hot booster cools in the exchange line and is expanded in the turbine coupled to the hot booster, before being sent to less in part to the column operating at medium pressure;
- an air separation installation by cryogenic distillation comprising:
- a valve means for sending purified air at high pressure and not supercharged to the exchange line to cool and then to the valve and means for sending the expanded air in the valve to distillation and / or the atmosphere and / or
- k means for connecting the discharge of the hot booster to the first series of passages of the exchange line.
- Eventually the installation may include:
- Means for short-circuiting the cold booster these means being connected to the exchange line and the discharge of the cold booster, so that the air passes from the first series of passages to the second series without going through the booster cold;
- means for short-circuiting the first and second turbines these means being connected to the discharge of the hot booster and the cold end of the exchange line (91) and / or to the column system;
- the means for short-circuiting the first and second turbines are connected to the inlet of the cold booster;
- valve means for sending purified air at high pressure and not supercharged to the exchange line to cool and then to the valve and means for sending the expanded air into the valve at the distillation and / or atmosphere;
- valve is connected to the inlet and the discharge of at least one of the turbines
- a process for separating air by cryogenic distillation in an installation comprising a double or triple air separation column, whose column operating at the highest pressure operates at a pressure said medium pressure and an exchange line where all the air for distillation is cooled in which, in normal operation:
- the first cooled fraction is divided into two portions, each portion is expanded in a turbine
- the inlet pressure of the first and second turbines is (the pressures of the two turbines are) at least 5 bars greater than the average pressure, f) the discharge pressure of at least one of the two turbines is substantially equal to the average pressure,
- a second fraction of the purified air at high pressure is cooled in a first series of passages of the exchange line and then supercharged with an inlet temperature equal to an intermediate temperature of the exchange line in a cold booster mechanically connected to the second turbine, the hot booster being mechanically connected to the first turbine,
- the cold booster delivers the second fraction of air at a temperature higher than the inlet temperature, and the second air fraction thus overpressed is reintroduced into a second series of passages of the exchange line, possibly at a intermediate point thereof, wherein at least a portion of the second fraction is (pseudo) condensed
- at least one pressurized liquid from one of the columns of the double or triple column is (pseudo) vaporized in the line exchange at a vaporization temperature and characterized in that if one of the boosters does not operate, a first portion of the purified air at high pressure is sent to the booster still operating, a second part of the air purified is cooled to high pressure at an intermediate temperature of the exchange line, is relaxed and is sent to the atmosphere without being overpressed by the booster still in operation ionization, preferably after reheating in the exchange line and a third portion of the purified air is cooled to high pressure at an intermediate temperature of the exchange line, is expanded in the turbine coupled to the booster still
- the second part of the purified air is sent to the atmosphere only when one of the boosters does not work;
- the part of the air supercharged in the hot booster cools in the first series of passages of the exchange line, leaves the exchange line without passing by the cold booster and enters the exchange line in the second series of passages, the air having passed in these two series of passages then being sent to the system of columns;
- the third part of the purified air is sent to the high pressure at the turbine coupled to the cold booster, without being overpressed in the cold booster .
- an air separation installation by cryogenic distillation comprising:
- a valve means for sending purified air at high pressure and not supercharged to the exchange line to cool and then to the valve and means for sending the expanded air in the valve to distillation and / or the atmosphere.
- the installation comprises means for short-circuiting the cold booster, these means being connected to the exchange line, preferably only to the exchange line;
- the installation comprises means for short-circuiting the first and second turbines, these means being connected to the hot booster and to the cold end of the exchange line and / or to the column system;
- the means for short-circuiting the first and second turbines are connected to the cold booster.
- the air sent to the turbines is at the outlet pressure of the hot booster
- At least one final product is produced in liquid form
- the air 11 from the main compressor (not shown) and a purification unit (not shown) is divided into two parts only.
- Part 13 is sent to a hot booster C1, cooled in the line exchange 91 to an intermediate temperature and then sent by the open valve 4 and the lines 23, 27 to be expanded in two turbines T1, T2 connected in parallel by the pipes 31, 35.
- the expanded air 35 from the turbines T1, T2 is sent to the middle pressure column of the double column.
- Part of the air from the hot booster C1 may possibly be liquefied in the exchange line instead of being sent to the turbines.
- the remainder of the air from the main compressor cools in a first series of passages of the exchange line 91 through the open valve 9 and is supercharged in a cold booster C2 at an intermediate temperature of the line. exchange, returned to the exchange line at an intermediate temperature thereof in a second series of passages, liquefied and sent to at least one column of the double column, for example the medium pressure column.
- a first series of passages of the exchange line 91 through the open valve 9 and is supercharged in a cold booster C2 at an intermediate temperature of the line. exchange, returned to the exchange line at an intermediate temperature thereof in a second series of passages, liquefied and sent to at least one column of the double column, for example the medium pressure column.
- At least one waste gas WN arrives from the low pressure column through line 39 and heats up in the exchange line where a pressurized liquid 41 from the double column, in particular pressurized oxygen, is also vaporized.
- valves 1, 2, 5 and 6 are closed, so that the lines 21, 25, 29, 39 do not receive air.
- Pipes 19 and 17 are not necessarily present and their operation will not be described. It is assumed that the valves 3 and 7 are closed for the explanation of the method according to the invention.
- air 11 from the main compressor (not shown) is split in two. Part 13 is sent to the hot booster C1.
- the air supercharged in the hot booster C1 is sent in part to the pipe 21 and partly to the pipe 23, 27.
- the air passing through the pipe 23, 27 and the valve 4 is cooled in the exchange line 91 to an intermediate temperature to be expanded in a single Claude T1 turbine.
- the turbine T2 does not work since it is usually coupled to the C2 cold booster.
- the expanded air is sent to the medium pressure column of the double column.
- the air sent via the pipe 21 and the valve 2 cools in the heat exchange line 91 to an intermediate temperature thereof in the passages in which the air intended for the cold compressor C2 normally cools.
- the air is sent to the valve 5 through line 39 at an intermediate temperature of the exchange line through the passages normally traversed by the air from the cold compressor C2.
- the air from the valve 5 liquefies before being sent to at least one column of the double column.
- Part of the air coming from the pipe 27 can also possibly be liquefied in the exchange line instead of being sent to the turbines.
- the remainder of the air from the main compressor is sent through the valve 1 and the lines 25, 27 cool with the air from the valve 4 in the exchange line 91 to an intermediate temperature.
- At least one waste gas WN arrives via line 39 and heats up in the exchange line where a pressurized liquid 41 from the double column, in particular oxygen, is also vaporized.
- valves 2 and 4 are closed, valves 1, 6 and 9 open and air 1 1 from the main compressor
- Part of the air coming from the pipe 25 can also possibly be liquefied in the exchange line instead of being sent to the turbine T2.
- At least one waste gas WN arrives via line 39 and heats up in the exchange line where a pressurized liquid 41 from the double column, in particular oxygen, is also vaporized.
- valves 2 and 4 are closed, so that the pipes 13, 21, 31, 39 do not receive air.
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- Engineering & Computer Science (AREA)
- Physics & Mathematics (AREA)
- Mechanical Engineering (AREA)
- Thermal Sciences (AREA)
- General Engineering & Computer Science (AREA)
- Health & Medical Sciences (AREA)
- Emergency Medicine (AREA)
- Separation By Low-Temperature Treatments (AREA)
Abstract
Description
Claims
Priority Applications (4)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
JP2012521081A JP2012533725A (ja) | 2009-07-20 | 2010-07-16 | 低温蒸留による空気分離の方法および装置 |
US13/384,432 US9091478B2 (en) | 2009-07-20 | 2010-07-16 | Method and apparatus for separating air by cryogenic distillation |
CN201080031705.XA CN102741635B (zh) | 2009-07-20 | 2010-07-16 | 通过低温蒸馏分离空气的方法和设备 |
EP10754355.5A EP2457047B1 (fr) | 2009-07-20 | 2010-07-16 | Procédé et appareil de séparation d'air par distillation cryogénique |
Applications Claiming Priority (2)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
FR0955007A FR2948184B1 (fr) | 2009-07-20 | 2009-07-20 | Procede et appareil de separation d'air par distillation cryogenique |
FR0955007 | 2009-07-20 |
Publications (2)
Publication Number | Publication Date |
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WO2011010049A2 true WO2011010049A2 (fr) | 2011-01-27 |
WO2011010049A3 WO2011010049A3 (fr) | 2012-11-15 |
Family
ID=42136076
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
PCT/FR2010/051492 WO2011010049A2 (fr) | 2009-07-20 | 2010-07-16 | Procédé et appareil de séparation d'air par distillation cryogénique |
Country Status (6)
Country | Link |
---|---|
US (1) | US9091478B2 (fr) |
EP (1) | EP2457047B1 (fr) |
JP (1) | JP2012533725A (fr) |
CN (1) | CN102741635B (fr) |
FR (1) | FR2948184B1 (fr) |
WO (1) | WO2011010049A2 (fr) |
Cited By (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
FR2985305A1 (fr) * | 2012-01-03 | 2013-07-05 | Air Liquide | Procede et appareil de production de gaz de l'air sous pression utilisant un surpresseur cryogenique |
US20140318179A1 (en) * | 2011-11-24 | 2014-10-30 | L'air Liquide, Societe Anonyme Pour I'etude Et I'exploitation Des Procedes Georges Claude | Process And Apparatus For The Separation Of Air By Cryogenic Distillation |
Families Citing this family (3)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
EP3438585A3 (fr) * | 2017-08-03 | 2019-04-17 | L'air Liquide, Societe Anonyme Pour L'etude Et L'exploitation Des Procedes Georges Claude | Procédé de dégivrage d'un appareil de séparation d'air par distillation cryogénique et appareil adapté pour être dégivré par ce procédé |
FR3069916B1 (fr) * | 2017-08-03 | 2021-12-31 | Air Liquide | Procede de degivrage d'un appareil de separation d'air par distillation cryogenique et appareil adapte pour etre degivre par ce procede |
WO2020124427A1 (fr) * | 2018-12-19 | 2020-06-25 | L'air Liquide, Societe Anonyme Pour L'etude Et L'exploitation Des Procedes Georges Claude | Procédé de démarrage d'une unité de séparation d'air cryogénique et unité de séparation d'air associée |
Citations (2)
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WO2004099690A1 (fr) | 2003-05-05 | 2004-11-18 | L'air Liquide Societe Anonyme A Directoire Et Conseil De Surveillance Pour L'etude Et L'exploitation Des Procedes Georges Claude | Procede et installation de separation d'air par distillation cryogenique |
FR2895068A1 (fr) | 2005-12-15 | 2007-06-22 | Air Liquide | Procede de separation d'air par distillation cryogenique |
Family Cites Families (8)
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IT1019710B (it) * | 1974-07-12 | 1977-11-30 | Nuovo Pignone Spa | Processo ed apparato per la produ zione di elevate percentuali di os sigeno e/o azoto allo stato liquido |
FR2692664A1 (fr) * | 1992-06-23 | 1993-12-24 | Lair Liquide | Procédé et installation de production d'oxygène gazeux sous pression. |
US5881570A (en) * | 1998-04-06 | 1999-03-16 | Praxair Technology, Inc. | Cryogenic rectification apparatus for producing high purity oxygen or low purity oxygen |
US6962062B2 (en) * | 2003-12-10 | 2005-11-08 | L'Air Liquide, Société Anonyme à Directoire et Conseil de Surveillance pour l'Etude et l'Exploitation des Proédés Georges Claude | Process and apparatus for the separation of air by cryogenic distillation |
US7272954B2 (en) * | 2004-07-14 | 2007-09-25 | L'air Liquide, Societe Anonyme A Directoire Et Conseil De Surveillance Pour L'etude Et L'exploitation Des Proceded Georges Claude | Low temperature air separation process for producing pressurized gaseous product |
FR2913759B1 (fr) * | 2007-03-13 | 2013-08-16 | Air Liquide | Procede et appareil de production de gaz de l'air sous forme gazeuse et liquide a haute flexibilite par distillation cryogenique. |
DE102007014643A1 (de) * | 2007-03-27 | 2007-09-20 | Linde Ag | Verfahren und Vorrichtung zur Erzeugung von gasförmigem Druckprodukt durch Tieftemperaturzerlegung von Luft |
JP4908634B2 (ja) * | 2007-08-10 | 2012-04-04 | レール・リキード−ソシエテ・アノニム・プール・レテュード・エ・レクスプロワタシオン・デ・プロセデ・ジョルジュ・クロード | 極低温蒸留によって空気を分離する方法及び装置 |
-
2009
- 2009-07-20 FR FR0955007A patent/FR2948184B1/fr not_active Expired - Fee Related
-
2010
- 2010-07-16 US US13/384,432 patent/US9091478B2/en active Active
- 2010-07-16 JP JP2012521081A patent/JP2012533725A/ja not_active Withdrawn
- 2010-07-16 EP EP10754355.5A patent/EP2457047B1/fr active Active
- 2010-07-16 CN CN201080031705.XA patent/CN102741635B/zh active Active
- 2010-07-16 WO PCT/FR2010/051492 patent/WO2011010049A2/fr active Application Filing
Patent Citations (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
WO2004099690A1 (fr) | 2003-05-05 | 2004-11-18 | L'air Liquide Societe Anonyme A Directoire Et Conseil De Surveillance Pour L'etude Et L'exploitation Des Procedes Georges Claude | Procede et installation de separation d'air par distillation cryogenique |
FR2895068A1 (fr) | 2005-12-15 | 2007-06-22 | Air Liquide | Procede de separation d'air par distillation cryogenique |
Cited By (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US20140318179A1 (en) * | 2011-11-24 | 2014-10-30 | L'air Liquide, Societe Anonyme Pour I'etude Et I'exploitation Des Procedes Georges Claude | Process And Apparatus For The Separation Of Air By Cryogenic Distillation |
FR2985305A1 (fr) * | 2012-01-03 | 2013-07-05 | Air Liquide | Procede et appareil de production de gaz de l'air sous pression utilisant un surpresseur cryogenique |
Also Published As
Publication number | Publication date |
---|---|
EP2457047B1 (fr) | 2018-12-26 |
CN102741635A (zh) | 2012-10-17 |
FR2948184A1 (fr) | 2011-01-21 |
JP2012533725A (ja) | 2012-12-27 |
CN102741635B (zh) | 2014-12-10 |
US20120118006A1 (en) | 2012-05-17 |
FR2948184B1 (fr) | 2016-04-15 |
WO2011010049A3 (fr) | 2012-11-15 |
EP2457047A2 (fr) | 2012-05-30 |
US9091478B2 (en) | 2015-07-28 |
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