WO2011009936A3 - Process for the preparation of 1,2-propanediol from glycerol - Google Patents

Process for the preparation of 1,2-propanediol from glycerol Download PDF

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Publication number
WO2011009936A3
WO2011009936A3 PCT/EP2010/060692 EP2010060692W WO2011009936A3 WO 2011009936 A3 WO2011009936 A3 WO 2011009936A3 EP 2010060692 W EP2010060692 W EP 2010060692W WO 2011009936 A3 WO2011009936 A3 WO 2011009936A3
Authority
WO
WIPO (PCT)
Prior art keywords
glycerol
preparation
propanediol
containing stream
propandiol
Prior art date
Application number
PCT/EP2010/060692
Other languages
French (fr)
Other versions
WO2011009936A2 (en
Inventor
Jens Heimann
Rolf Pinkos
Jochem Henkelmann
Original Assignee
Basf Se
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Basf Se filed Critical Basf Se
Publication of WO2011009936A2 publication Critical patent/WO2011009936A2/en
Publication of WO2011009936A3 publication Critical patent/WO2011009936A3/en

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C29/00—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring
    • C07C29/60—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring by elimination of -OH groups, e.g. by dehydration
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/70—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper
    • B01J23/76—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36
    • B01J23/83—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36 with rare earths or actinides
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/70—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper
    • B01J23/76—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36
    • B01J23/84—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36 with arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium
    • B01J23/889—Manganese, technetium or rhenium
    • B01J23/8892—Manganese
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J25/00—Catalysts of the Raney type

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)

Abstract

The present invention relates to a process for the preparation of 1,2-propandiol, at least comprising the following steps a) providing a glycerol-containing stream comprising at least 40% by weight of at least one organic solvent and b) subjecting the glycerol-containing stream of step a) to a hydrogenation in the presence of a copper-containing, heterogeneous catalyst at a pressure of at least 50 bar.
PCT/EP2010/060692 2009-07-24 2010-07-23 Process for the preparation of 1,2-propanediol from glycerol WO2011009936A2 (en)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
EP09166308 2009-07-24
EP09166308.8 2009-07-24

Publications (2)

Publication Number Publication Date
WO2011009936A2 WO2011009936A2 (en) 2011-01-27
WO2011009936A3 true WO2011009936A3 (en) 2011-07-28

Family

ID=43244911

Family Applications (1)

Application Number Title Priority Date Filing Date
PCT/EP2010/060692 WO2011009936A2 (en) 2009-07-24 2010-07-23 Process for the preparation of 1,2-propanediol from glycerol

Country Status (1)

Country Link
WO (1) WO2011009936A2 (en)

Families Citing this family (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
ITMI20130209A1 (en) * 2013-02-14 2014-08-15 Eni Spa INTEGRATED PROCESS FOR THE PREPARATION OF USEFUL COMPOUNDS AS FUEL COMPONENTS
CN105771999B (en) * 2016-03-25 2019-02-26 北京石油化工学院 A kind of glycerine hydrogenation catalyst and the preparation method and application thereof

Citations (9)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP0523015A2 (en) * 1991-07-10 1993-01-13 NOVAMONT S.p.A. A method of hydrogenating glycerol
WO2007053705A2 (en) * 2005-10-31 2007-05-10 University Of Missouri Board Of Curators Method of producing lower alcohols from glycerol
WO2007099161A1 (en) * 2006-03-03 2007-09-07 Basf Se Process for the preparation of 1,2-propanediol
CN101195557A (en) * 2006-12-07 2008-06-11 中国科学院兰州化学物理研究所 Method for producing 1-propylene glycol with glycerol hydrogenation
WO2008089899A1 (en) * 2007-01-22 2008-07-31 Clariant Finance (Bvi) Limited Method for preparing 1,2-propanediol by hydrogenolysis of glycerol
WO2009027500A2 (en) * 2007-08-31 2009-03-05 Basf Se Method for producing 1,2-propandiol by hydrogenating glycerine in a two-step reactor cascade
WO2009027502A2 (en) * 2007-08-31 2009-03-05 Basf Se Method for producing 1,2-propandiol by low-pressure hydrogenation of glycerine
EP2070902A1 (en) * 2007-12-13 2009-06-17 Lanzhou Institute of Chemical Physics A method for producing 1, 2-propylene glycol using bio-based glycerol
WO2009111352A1 (en) * 2008-03-02 2009-09-11 Dow Global Technologies, Inc. Improved hydrogenation process

Family Cites Families (20)

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DE524101C (en) 1926-01-13 1931-05-11 I G Farbenindustrie Akt Ges Process for converting higher quality alcohols into lower quality ones
DE541362C (en) 1927-10-25 1932-01-11 I G Farbenindustrie Akt Ges Process for the hydrogenation of polyoxy compounds
DE2628987C3 (en) 1976-06-28 1981-10-22 Basf Ag, 6700 Ludwigshafen Process for the preparation of C? 3? -C? 5? Alkanols
DE2909671A1 (en) 1979-03-12 1980-10-02 Basf Ag METHOD FOR PRODUCING SHELL CATALYSTS
JPH03128334A (en) 1989-07-04 1991-05-31 Ube Ind Ltd Production of alcohol
US5008235A (en) 1989-12-21 1991-04-16 Union Carbide Chemicals And Plastics Technology Corporation Catalysts of Cu-Al-third metal for hydrogenation
DE4028295A1 (en) 1990-09-06 1992-03-12 Henkel Kgaa CUPFER-MANGANE CATALYSTS
DE4141199A1 (en) 1991-12-13 1993-06-17 Sued Chemie Ag CHROME-FREE CATALYST FOR HYDRATING ORGANIC COMPOUNDS CONTAINING THE CARBONYL FUNCTIONS
DE4302464A1 (en) 1993-01-29 1994-08-04 Henkel Kgaa Prepn. of propylene glycol from re-generable fossil fuel sources
DE4345265A1 (en) 1993-10-16 1995-09-21 Degussa Prodn. of shaped Raney metal catalysts for use in a fixed bed
DE4442124A1 (en) 1994-11-26 1996-05-30 Basf Ag Process for the preparation of 1,2-propanediol
DE4442346A1 (en) 1994-11-29 1996-05-30 Basf Ag Process for producing a catalyst consisting of a support body and a catalytically active oxide mass applied to the surface of the support body
DE4446907A1 (en) 1994-12-27 1996-07-04 Basf Ag Process for the preparation of a hydrogenation catalyst
DE19643126A1 (en) 1996-10-18 1998-04-23 Basf Ag Raney metal fixed bed catalyst, process for its preparation and a process for the hydrogenation of polymers using this catalyst
DE10218849A1 (en) 2002-04-26 2003-11-06 Basf Ag Catalyst for hydrogenation of aldehyde to alcohol contains chromium, calcium and copper on a silica support material
DE10243700A1 (en) 2002-09-20 2004-04-01 Oelmühle Leer Connemann Gmbh & Co. Method and device for producing biodiesel
ES2501391T3 (en) 2004-03-25 2014-10-01 Galen J. Suppes Procedure for producing an antifreeze composition containing lower alcohols and glycerol through glyceride alcohololysis
DE102004033556A1 (en) 2004-07-09 2006-02-16 Basf Ag Catalyst molding and process for the hydrogenation of carbonyl compounds
GB0514593D0 (en) 2005-07-15 2005-08-24 Davy Process Techn Ltd Process
US20080274019A1 (en) 2007-04-24 2008-11-06 Joseph Robert Beggin Preparation of Derivative of Polyhydric Alcohols

Patent Citations (9)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP0523015A2 (en) * 1991-07-10 1993-01-13 NOVAMONT S.p.A. A method of hydrogenating glycerol
WO2007053705A2 (en) * 2005-10-31 2007-05-10 University Of Missouri Board Of Curators Method of producing lower alcohols from glycerol
WO2007099161A1 (en) * 2006-03-03 2007-09-07 Basf Se Process for the preparation of 1,2-propanediol
CN101195557A (en) * 2006-12-07 2008-06-11 中国科学院兰州化学物理研究所 Method for producing 1-propylene glycol with glycerol hydrogenation
WO2008089899A1 (en) * 2007-01-22 2008-07-31 Clariant Finance (Bvi) Limited Method for preparing 1,2-propanediol by hydrogenolysis of glycerol
WO2009027500A2 (en) * 2007-08-31 2009-03-05 Basf Se Method for producing 1,2-propandiol by hydrogenating glycerine in a two-step reactor cascade
WO2009027502A2 (en) * 2007-08-31 2009-03-05 Basf Se Method for producing 1,2-propandiol by low-pressure hydrogenation of glycerine
EP2070902A1 (en) * 2007-12-13 2009-06-17 Lanzhou Institute of Chemical Physics A method for producing 1, 2-propylene glycol using bio-based glycerol
WO2009111352A1 (en) * 2008-03-02 2009-09-11 Dow Global Technologies, Inc. Improved hydrogenation process

Non-Patent Citations (1)

* Cited by examiner, † Cited by third party
Title
DATABASE WPI Week 200873, Derwent World Patents Index; AN 2008-M34795, XP002638572 *

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