WO2010136174A2 - Elektrodenwickel - Google Patents
Elektrodenwickel Download PDFInfo
- Publication number
- WO2010136174A2 WO2010136174A2 PCT/EP2010/003173 EP2010003173W WO2010136174A2 WO 2010136174 A2 WO2010136174 A2 WO 2010136174A2 EP 2010003173 W EP2010003173 W EP 2010003173W WO 2010136174 A2 WO2010136174 A2 WO 2010136174A2
- Authority
- WO
- WIPO (PCT)
- Prior art keywords
- electrode
- separator
- housing
- temperature
- winding
- Prior art date
Links
- 239000000463 material Substances 0.000 claims abstract description 19
- 229910010293 ceramic material Inorganic materials 0.000 claims abstract description 9
- 238000004804 winding Methods 0.000 claims description 99
- 238000012546 transfer Methods 0.000 claims description 22
- 239000000919 ceramic Substances 0.000 claims description 21
- 239000002131 composite material Substances 0.000 claims description 12
- 239000002608 ionic liquid Substances 0.000 claims description 12
- 239000004020 conductor Substances 0.000 claims description 9
- 229910052744 lithium Inorganic materials 0.000 claims description 8
- -1 polyethylene terephthalate Polymers 0.000 claims description 8
- WHXSMMKQMYFTQS-UHFFFAOYSA-N Lithium Chemical compound [Li] WHXSMMKQMYFTQS-UHFFFAOYSA-N 0.000 claims description 6
- 150000001875 compounds Chemical class 0.000 claims description 6
- PXHVJJICTQNCMI-UHFFFAOYSA-N nickel Substances [Ni] PXHVJJICTQNCMI-UHFFFAOYSA-N 0.000 claims description 6
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- 229910052759 nickel Inorganic materials 0.000 claims description 4
- 229910052609 olivine Inorganic materials 0.000 claims description 4
- 239000010450 olivine Substances 0.000 claims description 4
- 229910052723 transition metal Inorganic materials 0.000 claims description 4
- 229910012851 LiCoO 2 Inorganic materials 0.000 claims description 2
- 229910013275 LiMPO Inorganic materials 0.000 claims description 2
- 229910015643 LiMn 2 O 4 Inorganic materials 0.000 claims description 2
- 229910013290 LiNiO 2 Inorganic materials 0.000 claims description 2
- 229910019142 PO4 Inorganic materials 0.000 claims description 2
- 229910052782 aluminium Inorganic materials 0.000 claims description 2
- 229910017052 cobalt Inorganic materials 0.000 claims description 2
- 239000010941 cobalt Substances 0.000 claims description 2
- GUTLYIVDDKVIGB-UHFFFAOYSA-N cobalt atom Chemical compound [Co] GUTLYIVDDKVIGB-UHFFFAOYSA-N 0.000 claims description 2
- QHGJSLXSVXVKHZ-UHFFFAOYSA-N dilithium;dioxido(dioxo)manganese Chemical compound [Li+].[Li+].[O-][Mn]([O-])(=O)=O QHGJSLXSVXVKHZ-UHFFFAOYSA-N 0.000 claims description 2
- 238000005470 impregnation Methods 0.000 claims description 2
- 229910010272 inorganic material Inorganic materials 0.000 claims description 2
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- XEEYBQQBJWHFJM-UHFFFAOYSA-N iron Substances [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 claims description 2
- 229910052748 manganese Inorganic materials 0.000 claims description 2
- 239000011572 manganese Substances 0.000 claims description 2
- WPBNNNQJVZRUHP-UHFFFAOYSA-L manganese(2+);methyl n-[[2-(methoxycarbonylcarbamothioylamino)phenyl]carbamothioyl]carbamate;n-[2-(sulfidocarbothioylamino)ethyl]carbamodithioate Chemical compound [Mn+2].[S-]C(=S)NCCNC([S-])=S.COC(=O)NC(=S)NC1=CC=CC=C1NC(=S)NC(=O)OC WPBNNNQJVZRUHP-UHFFFAOYSA-L 0.000 claims description 2
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- RVTZCBVAJQQJTK-UHFFFAOYSA-N oxygen(2-);zirconium(4+) Chemical compound [O-2].[O-2].[Zr+4] RVTZCBVAJQQJTK-UHFFFAOYSA-N 0.000 claims description 2
- 239000002245 particle Substances 0.000 claims description 2
- 230000000737 periodic effect Effects 0.000 claims description 2
- 235000021317 phosphate Nutrition 0.000 claims description 2
- 150000003013 phosphoric acid derivatives Chemical class 0.000 claims description 2
- 229920000642 polymer Polymers 0.000 claims description 2
- 150000004760 silicates Chemical class 0.000 claims description 2
- 229910052596 spinel Inorganic materials 0.000 claims description 2
- 239000011029 spinel Substances 0.000 claims description 2
- 150000003467 sulfuric acid derivatives Chemical class 0.000 claims description 2
- 229910052719 titanium Inorganic materials 0.000 claims description 2
- 239000010936 titanium Substances 0.000 claims description 2
- 229910052726 zirconium Inorganic materials 0.000 claims description 2
- 229910001928 zirconium oxide Inorganic materials 0.000 claims description 2
- 238000000465 moulding Methods 0.000 description 13
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- HBBGRARXTFLTSG-UHFFFAOYSA-N Lithium ion Chemical compound [Li+] HBBGRARXTFLTSG-UHFFFAOYSA-N 0.000 description 3
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- 229910018072 Al 2 O 3 Inorganic materials 0.000 description 1
- 241000282320 Panthera leo Species 0.000 description 1
- 229910004298 SiO 2 Inorganic materials 0.000 description 1
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 description 1
- 239000000853 adhesive Substances 0.000 description 1
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- TWNQGVIAIRXVLR-UHFFFAOYSA-N oxo(oxoalumanyloxy)alumane Chemical compound O=[Al]O[Al]=O TWNQGVIAIRXVLR-UHFFFAOYSA-N 0.000 description 1
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Classifications
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- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02E—REDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
- Y02E60/00—Enabling technologies; Technologies with a potential or indirect contribution to GHG emissions mitigation
- Y02E60/10—Energy storage using batteries
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- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
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- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
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- Y10T29/00—Metal working
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- Y10T29/49002—Electrical device making
- Y10T29/49108—Electric battery cell making
- Y10T29/49115—Electric battery cell making including coating or impregnating
Definitions
- the invention relates to an electrode winding according to the preamble of claim 1.
- the invention will be described in connection with a lithium-ion battery for supplying a motor vehicle. It should be noted that the invention can also be used independently of the chemistry, the type of electrode winding or the type of powered drive.
- Electrode coils or galvanic cells are known from the prior art, which possibly release uncontrolled energy in the event of mechanical damage or overheating. This can endanger the environment.
- the object of the invention is to make an electrode winding or a galvanic cell with an electrode winding safer.
- an electrode coil of substantially cylindrical shape has at least one anodic electrode, a cathodic electrode, and a separator.
- the separator is at least partially disposed between these electrodes.
- the separator is made of a material which has at least one component made of a ceramic material.
- an electrode winding means a device which also serves to store chemical energy and to deliver electrical energy, in particular as an assembly of a galvanic cell. Before the release of electrical energy stored chemical energy is converted into electrical energy. During charging, the electrical energy supplied to the electrode winding or the galvanic cell is converted into chemical energy and stored.
- the electrode winding has a plurality of layers, at least one anode layer, a cathode layer and a separator layer. The layers are stacked, with the separator layer at least partially disposed between an anode layer and a cathode layer.
- the layers of the electrode coil are wound up, in particular around a core. Starting from its base or end face, the electrode winding extends perpendicularly along its longitudinal axis.
- the base surface of the electrode coil is substantially circular or polygonal, in particular hexagonal.
- the corners of the base rounded.
- a galvanic cell is to be understood as a device which also serves to store chemical energy and to deliver electrical energy.
- the galvanic cell according to the invention has at least two electrodes and one electrolyte.
- the galvanic cell can be designed to receive electrical energy during charging, to convert it into chemical energy and to store it. This is also referred to as a secondary cell or an accumulator.
- an anode layer or an anode means a device which charges electrons and / or positively charged during charging lions, in particular stored on interstitial sites.
- the anode is thin-walled, more preferably, the thickness of the anode is less than 5% of its outer circumference.
- the anode has a metal foil or a metallic mesh structure.
- the anode is substantially rectangular.
- a cathode layer or a cathode means a device which also receives electrons and / or positively charged ions during discharging or during the discharge of electrical energy.
- the cathode is formed thin-walled, more preferably, the thickness of the cathode is less than 5% of its outer circumference.
- the cathode has a metal foil or a metallic mesh structure.
- the shape of a cathode substantially corresponds to the shape of an anode of the electrode coil.
- a cathode is also provided for electrochemical interaction with an anode or with the electrolyte.
- At least one electrode of the electrode coil comprises a compound having the formula LiMPO 4 , where M is at least one transition metal cation of the first row of the Periodic Table of the Elements.
- the transition metal cation is preferably selected from the group consisting of Mn, Fe, Ni and Ti or a
- the compound preferably has an olivine structure, preferably parent olivine.
- At least one electrode of the electrode coil comprises a lithium manganate, preferably LiMn 2 O 4 VOm spinel type, a lithium cobaltate, preferably LiCoO 2 , or a lithium nickelate, preferably LiNiO 2 , or a mixture two or three of these oxides, or a lithium mixed oxide containing manganese, cobalt and nickel, auf.lm meaning of the invention is a separator and an electrically insulating device to understand, which is a Anode separated from a cathode and spaced.
- a separator layer is applied to an anode and / or a cathode.
- the separator layer or separator also at least partially accommodates an electrolyte, wherein the electrolyte preferably contains lithium ions.
- the electrolyte is also electrochemically operatively connected to adjacent layers of the electrode stack.
- the shape of a separator substantially corresponds to the shape of an anode of the electrode coil.
- the separator (hereinafter “ceramic separator”) is made of a material which comprises at least one constituent of a ceramic material .
- This ceramic material has a porosity which is sufficient for the function of the electrode coil, but is in comparison with polyolefin Separators are considerably more temperature-resistant and shrink less at higher temperatures.
- a ceramic separator also advantageously has a high mechanical strength.
- preference is also given to using Al 2 O 3 (aluminum oxide) and / or SiO 2 (silicon oxide) required battery power can be provided ceramic separators with different thickness and / or porosity.
- a separator formed of a polyolefinic material can greatly shrink upon excessive heating, eg due to a short circuit or overcharging, thereby rendering the electrode coil at least unusable.
- a strong shrinkage effect there is also direct contact between the anodic electrode and the cathodic electrode and thus an even greater overheating of the electrode winding, which can also trigger a fire.
- the separator made of a ceramic material in particular its temperature resistance is increased or the temperature-induced shrinkage of the separator is reduced.
- the electrical separation of electrodes by a ceramic separator tor largely preserved especially at higher temperatures. The risk of uncontrolled discharge of the electrode coil is advantageously reduced and solved the underlying task.
- the ceramic separator is formed of a flexible ceramic composite material.
- a composite material is made of different, firmly bonded materials. Such a material may also be referred to as a composite material.
- this composite material is formed from ceramic materials and from polymeric materials. It is known to provide a fleece made of PET with a ceramic impregnation or support. Such composite materials can withstand temperatures of over 200 ° Celsius (sometimes up to 700 ° Celsius).
- the ceramic separator is wetted on one side with an ionic liquid.
- the ionic liquid in particular increases the flexibility of the ceramic separator.
- the ceramic separator is wetted on two sides with an ionic liquid. For this purpose, especially ionic liquids are suitable. These are adjusted so that they adhere to the ceramic separator and thus can wet well, especially with regard to the production.
- a separator layer or a separator at least partially extends over a boundary edge of at least one in particular adjacent electrode.
- a separator layer or a separator extends beyond all boundary edges, in particular of adjacent electrodes. This also reduces electrical currents between the edges of electrodes of the electrode coil.
- the electrode winding comprises at least two pairs of electrodes, ie at least two anodes (a) and at least two cathodes (k).
- electrodes of different polarity are separated by means of at least one separator (s).
- the layers of the electrode coil in the sequence ai - s - ki - s - a 2 - s - k 2 . These layers are wound up into an electrode winding.
- a plurality of electrode layers are preferably connected to one another, in particular in an electrically conductive manner. With an electrically conductive connection of electrodes of the same polarity, the electrode pairs are connected in parallel. With electrically conductive connection of electrodes, in particular different polarity, the pairs of electrodes are preferably connected in series. In particular, the electrical voltage of the electrode winding is advantageously increased.
- At least one contact element which is connected to an electrode, is advantageously arranged on at least one boundary surface of the electrode winding.
- a boundary surface of an electrode winding is to be understood as one of its lateral surfaces.
- an end face falls within the meaning of the invention under the concept of "boundary surface”.
- a contact element is to be understood as meaning a conductive device which in particular electrically contacts an electrode of the electrode winding and in particular protrudes from the electrode winding or protrudes therefrom.
- at least two contact elements are arranged on at least one respective boundary surface.
- at least one contact element at different boundary surfaces of the electric denwickels are arranged.
- At least two contact elements are arranged on the same boundary surface of the electrode coil, in particular on an end face.
- a plurality of contact elements are associated with an electrode layer of the electrode winding, in particular with a regular spacing.
- the current density per contact element is lowered.
- a contact element is formed as an electrically conductive, planar element on a boundary surface of the electrode coil.
- a contact element is designed as Ableitfähnchen.
- at least two contact elements of different electrode layers are electrically conductively connected to one another, in particular for series connection of the electrode layers.
- a separator is preferably used, which consists of a material-permeable carrier, preferably partially permeable to material, ie substantially permeable with respect to at least one material and substantially impermeable with respect to at least one other material.
- the carrier is coated on at least one side with an inorganic material.
- an organic material is preferably used, which is preferably configured as a non-woven fabric.
- the organic material preferably a polymer and more preferably polyethylene terephthalate (PET), is coated with an inorganic ion-conducting material, which is preferably ion-conducting in a temperature range of -40 ° C to 200 ° C.
- the inorganic, ion-conducting material preferably comprises at least one compound from the group of oxides, phosphates, sulfates, titanates, silicates, aluminosolizates with at least one of the elements Zr, Al, Li, particularly preferably zirconium oxide.
- the inorganic, ion-conducting material preferably has particles with a largest diameter below 100 nm. Such a separator is sold, for example, under the trade name "Separation" by Evonik AG in Germany.
- a galvanic cell has at least one electrode winding and an enclosure.
- a housing is to be understood as a device which in particular separates the at least one electrode winding from the surroundings.
- the housing surrounds the at least one electrode winding essentially completely with a wall.
- the housing is at least partially adapted to the shape of an electrode coil.
- the housing is particularly preferably adapted to the shape of an electrode winding.
- the housing is designed as a composite film.
- the housing has a metal foil.
- the housing lies predominantly on the electrode winding.
- the housing encloses the electrode winding at least partially positively, supporting the Electrode winding and keeps its layers together.
- the enclosure is biased and exerts a force on the electrode coil. In this way, the enclosure forces the layers of the electrode coil together and advantageously reduces any displacements of a layer of the electrode coil with respect to its remaining layers.
- the housing is designed as a thin-walled metal sheet.
- a galvanic cell has at least two electrode windings and an enclosure.
- the at least two electrode windings are preferably connected to one another, in particular electrically, in particular in series.
- the at least two electrode windings are arranged relative to each other such that their longitudinal axes are substantially parallel and, more preferably, coincide.
- two electrode coils touch each other on one end face.
- at least two electrode coils are at least partially surrounded by a common housing.
- the common housing is formed as described above.
- the inner side of the housing is assigned at least one current-conducting device.
- the Stromleiterie also serves the electrical operative connection of two electrode winding, in particular for series connection.
- the at least one current conducting device is provided for contacting at least one contact element of an electrode winding, particularly preferably for contacting at least one contact element of at least two electrode windings.
- the inside of the enclosure at the same time on several separate Stromleit bootsen.
- the at least one Stromleit boots is designed as a conductor track or Stromleit Structure, which is applied in particular to the inside of the housing.
- the Stromleit driving is vapor-deposited on the inside of the housing.
- the at least one Stromleit Vietnamese is formed as a conductive plate, which is inserted in the manufacture of the housing.
- the at least one conductor is Device designed so that it fails at predetermined conditions, in particular above a predetermined temperature.
- the at least one current conducting device has a thin spot.
- the at least one current conducting device is in particular electrically conductively connected to a pole contact of the housing.
- at least one Stromleiterie extends through the enclosure.
- At least one contact element of an electrode winding is advantageously connected to a region of the housing, in particular in an electrically conductive manner.
- at least one contact element of an electrode coil is connected to the wall of the enclosure in certain regions, in particular in an electrically conductive manner.
- this electrically conductive region of the wall extends at least in the direction of a pole contact, of a further electrode coil and / or to the outside of the wall.
- This electrically conductive region of the wall of the housing serves, in particular, for the electrical contacting of at least one electrode winding.
- This electrically conductive region of the wall in particular two electrode windings are electrically conductively connected to one another.
- This electrically conductive region of the wall preferably serves to house the electrical connection of an electrode winding with a pole contact and / or the surroundings.
- At least one contact element of an electrode winding is guided through the housing.
- This led out contact element is used in particular for electrical contacting of the electrode coil.
- the at least one contact element is gas-tight through the housing, in particular its wall, out.
- at least two contact elements are guided through the housing.
- the housing has at least one first connection area.
- This first connection area is used in particular for connecting the Housing with at least one other body, in particular with another housing, a region of the battery case and / or with a heat exchange device.
- the enclosure preferably has a plurality of first connection regions.
- the connection is formed with at least one other body cohesively and / or non-positively.
- the housing has at least one heat transfer area.
- the heat transfer region of the wall of the enclosure is assigned. This heat transfer area serves in particular for heat transfer into or out of an electrode winding.
- the electrode stack is connected at least partially thermally conductively connected to the housing.
- the heat transfer area preferably extends over a majority of the wall of the enclosure.
- the heat transfer region is flown by a first temperature control and / or is thermally conductive connected to a heat exchange device.
- a first connection region and a heat transfer region coincide at least partially.
- the housing has at least two molded parts. These are intended to be interconnected.
- the connection of at least two moldings with each other is preferably carried out positively and / or materially. Depending on the materials of the various moldings, these are connected to each other in particular by gluing or a welding process. In particular, ultrasonic welding is used to connect a metallic molding to a thermoplastic molding. In this case, a pretreatment or activation of at least one of the outer surfaces of a molded part involved is particularly useful.
- a particularly non-positive or material-locking connection connects the at least two molded parts such that preferably a circumferential strip-shaped connection seals the space between the molded parts relative to the environment.
- At least two molded parts in a second connection region in particular cohesively connected to each other.
- This second connection region preferably extends along an edge region of a molded part involved.
- the second connection region is strip-shaped. It is not necessary for the second connection area to completely run along the bounding edges of the molding.
- at least one contact element of electrode winding is arranged so that it extends partially from the housing.
- the casing is also designed to be gas-tight with respect to the environment in the regions of a contact element that has been made.
- At least one molded part of the housing has a heat transfer area.
- the heat transfer region is simultaneously formed as a first connection region.
- the heat transfer region can simultaneously serve for fastening the galvanic cell to a heat exchange device, in particular by screwing, riveting, gluing or welding.
- at least one molded part of the housing is rigid. This molded part in particular holds the electrode winding, protects the electrode winding from mechanical damage and / or serves for the mechanical connection of the galvanic cell to a receiving device.
- a rigid molded part is formed as a metal plate or sheet metal. The molding is preferably stiffened by beads, raised areas and / or ribs.
- At least one molded part of the housing is made thin-walled.
- the wall thickness of a thin-walled molded part is adapted to a mechanical, electrical or thermal stress.
- the wall thickness is preferably not uniform.
- a region of a thin-walled molded part with increased wall thickness acts in particular as a heat sink or heat reservoir and contributes in particular to the fact that heat energy is removed from the electrode winding or transported in this.
- at least one molded part is formed as a film, particularly preferably as a composite film. Suitable materials for the composite film are in particular metals and / or plastics in question.
- At least one molded part of the housing has a coating at least in some areas.
- This coating also serves to adapt to stresses to which the molded part is exposed.
- the coating is used for electrical insulation, for protection of the molded part against the chemicals of the galvanic cell, for improving the adhesion of an adhesive bond, for improving the thermal conductivity and / or for protection against particular damaging effects from the environment.
- a coating causes in particular a chemical activation of the surface of the molding.
- a coating preferably has at least one material that deviates from the materials of the molded part.
- the at least one molded part preferably also has a plurality of different coatings, which are arranged in particular on different regions of the molded part. If a molded part is in electrical contact with the electrode winding, then a current conductor is preferably electrically insulated from this molded part.
- At least one molded part of the housing has a recess, in particular a shell.
- the molded part gains in particular an increased area moment of inertia or bending stiffness.
- this recess at least partially receives the electrode coil. This serves in particular for the protection of the electrode winding.
- the wall thickness of a molded part with a recess is preferably adapted to the stress.
- Several moldings of the housing each have at least one recess, which together form a space for receiving the electrode coil.
- a molded part is formed as a deep-drawn or kaltf beaugepresstes sheet metal.
- a molded part is formed as a deep-drawn plastic plate or plastic film.
- At least one molding is cup-shaped.
- the curvature of the bowl-shaped gene shaped part adapted to the radius of the electrode coil.
- at least one shaped part extends over a plurality of surfaces along the longitudinal axis of the electrode winding.
- at least one molded part is designed as a lid.
- At least one molded part advantageously has a first connection region.
- the first connection region serves in particular for fastening the galvanic cell, in particular in a housing, in a frame or on a base plate.
- a first connection region is formed such that the connection of the respective molded part with another body can take place only in a predetermined manner.
- a first connection region has a geometric shape which corresponds to a region of another body.
- a connection between the molding and the other body is possible only in a predetermined manner, by means of an arrangement of mold elements, in particular holes and pins.
- the arrangement of through-holes or threads allows a connection only in a predetermined manner.
- a first connection area is spatially separated from a second connection area.
- At least one molded part of the housing preferably has a plurality of separate first connecting regions.
- the connection of the molded part with another body takes place in particular by means of riveting, screwing, welding or gluing.
- a first connection region of a molded part and a heat transfer region of the same molded article coincide. In these areas, the molding is in particular connected to a heat exchange device, a frame or with a base plate of the battery case.
- a battery has at least two galvanic cells, which are preferably electrically interconnected, in particular in a series circuit.
- the battery is preferably associated with at least one heat exchange device, which is in particular thermally conductively connected to at least one of the at least two galvanic cells.
- the heat exchanger tion is provided to exchange thermal energy with at least one of the at least two galvanic cells under given conditions. These predetermined conditions are fulfilled in particular when the temperature of an electrode winding or a galvanic cell exceeds or falls below a limit temperature. In particular, when the temperature of an electrode winding or a galvanic cell approaches or falls below a minimum temperature, the heat exchange device supplies thermal energy to this electrode winding or galvanic cell.
- the heat exchange device dissipates thermal energy from this electrode winding or from this galvanic cell.
- a limit temperature is selected as a function of the permissible operating temperatures of an electrode winding, in particular taking into account the heat capacity of the housing and / or the location of the temperature measurement.
- the battery has at least one measuring device, which is provided to detect in particular the temperature of at least one electrode stack or at least one galvanic cell.
- the measuring device has a plurality of measuring sensors, which are provided to detect, in particular, the temperature of a plurality of electrode stacks or a plurality of galvanic cells.
- the temperature of the heat exchange device is preferably selected as a function of the temperature of the electrode winding of a galvanic cell.
- a predetermined temperature gradient causes a heat flow in this electrode winding into or out of this electrode winding.
- the heat exchange device exchanges thermal energy with an electrode winding over at least one region of the housing or its heat transfer region, which is in contact with the heat exchange device.
- the existing galvanic cells are in particular non-positively or materially connected via a first connection region of the housing with the at least one heat exchange device.
- the heat exchange device has at least one first channel, in particular for setting a predetermined temperature. Preferably, this channel is filled with a second temperature control. Especially preferred A second temperature control medium flows through this at least one channel.
- the flowing second temperature control of the heat exchange means heat energy or dissipates heat energy.
- the at least one heat exchange device is preferably operatively connected to a heat exchanger.
- the heat exchanger dissipates heat energy from this heat exchange device or supplies thermal energy to this heat exchange device, in particular by means of a second temperature control medium.
- the heat exchanger or the temperature control interact in particular with the air conditioning system of a motor vehicle.
- the heat exchanger preferably has an electrical heating device.
- the heat exchange device is designed as a receiving device, in particular as a base plate or frame, for the at least two galvanic cells of the battery.
- the longitudinal axes of the at least two galvanic cells have a predetermined distance from one another.
- the longitudinal axes are parallel to each other.
- the distance of the longitudinal axes to one another is such that the housings of the at least two galvanic cells touch one another.
- the distance of the longitudinal axes of two adjacent galvanic cells is dimensioned such that they exert a force on an intermediate heat exchange device. This force serves in particular to improve the thermal contact of at least one galvanic cell with a heat exchange device.
- their longitudinal axes are preferably arranged parallel to one another. The distances of these longitudinal axes are determined by three predetermined distance vectors.
- these distance vectors lie in a common plane.
- the amounts of the three distance vectors are the same.
- a heat exchange device is preferably inserted into the space between the three galvanic cells.
- the distances between the longitudinal axes of the galvanic cells are such that the galvanic cells exert a force on the heat Exercise exchange device.
- the arrangement of the galvanic cells is based on a square.
- the longitudinal axes of four galvanic cells form the corners of this square. While the space utilization decreases compared to a triangular unit cell, the heat exchange device is preferably larger and / or more powerful.
- the galvanic cells are formed prismatic, wherein the base, in particular of the enclosure, designed as a regular hexagon.
- the heat exchange device is preferably designed as a sheet metal known at least once. At least one heat exchange device formed in this way is preferably inserted in an arrangement of prismatic galvanic cells.
- a heat exchange device has at least one channel, in particular for a second temperature control.
- this second temperature control passes through a phase passage during operation of the battery.
- the second temperature control is conveyed by a conveyor through the at least one channel of the heat exchange device.
- At least one channel is closed in a heat exchange device and filled with a second temperature control medium, which undergoes a phase transition within the operating temperatures of the galvanic cells.
- the heat exchange device further comprises at least one heat sink with an enlarged surface.
- the heat exchange device is designed as a heat pipe.
- the heat exchange device is flown by a first temperature control.
- a lithium-ion battery according to the invention is used for a motor vehicle with an electric drive or a hybrid drive.
- the method according to the invention for producing an electrode winding comprises the following steps: a) wetting or soaking both sides of this (ceramic) separator with an ionic liquid; b) placing said (ceramic) separator between an anodic electrode and a cathodic electrode; c) winding this arrangement to an electrode winding.
- the separator is to be provided before step a).
- the separator and the electrodes are cut before step b).
- the arrangement of ceramic separator and electrodes is preferably taken after winding to the electrode coil in an enclosure to prevent in particular the outflow or outgassing of the ionic liquid. It is preferably provided to apply or laminate the wetted or impregnated ceramic separator to an electrode, wherein the separator is preferably designed to project beyond the edge of the electrode.
- the mechanical connection between the separator and an electrode is based on adhesion. Lamination is understood in the sense of the invention as joining under pressure application. During the application of the ceramic separator, chemical additives are preferably added and / or heat is introduced.
- ionic liquids are used with additives which wet the ceramic separator and allow processing under normal climatic conditions.
- the coordinated combination of a ceramic separator and an ionic liquid allows new processing paths. For example, an inert gas environment or an anhydrous environment (air humidity ⁇ 2%), as well as clean room conditions (atmosphere quality ⁇ 30 ppm), as they must be provided in protective gas boxes according to the prior art, no longer required.
- an inventive electrode winding can be produced in an energy-saving and cost-effective manner.
- the ceramic separator becomes flexible only by applying a wetting solution with any additives, in particular an ionic liquid becomes processable. The wetting solution including any additives is then not removed, but installed with the electrode winding.
- the method according to the invention can thus be carried out easily and is thus particularly suitable for automated mass production.
- a battery with at least two galvanic cells and a heat exchange device is operated such that the temperature of the at least one heat exchange device is set as a function of the temperature of at least one of the two galvanic cells.
- the temperature of the at least one heat exchange device is preferably set as a function of the permissible operating temperatures of the at least two galvanic cells.
- the temperature of the at least one heat exchange device is set above the temperature of the galvanic cell.
- the temperature of the heat exchange device is preferably selected to be lower than the temperature of the at least one galvanic cell.
- the galvanic cell or the electrode winding heat energy is withdrawn.
- the at least one heat exchange device is thereby flowed against and / or flowed through by a first temperature control medium.
- the coolant of the motor vehicle air conditioning system serves as a temperature control for the heat exchange device.
- the temperature of the first temperature control agent is preferably set as a function of the permissible operating temperatures of the at least two galvanic cells. When the temperature falls below a minimum temperature or when the temperature of at least one galvanic cell approaches this minimum temperature, the temperature of the first temperature control medium is set above the temperature of the galvanic cell. This will be beneficial a heat flow is driven into the galvanic cell.
- the temperature of the first temperature control means is preferably chosen to be lower than the temperature of the at least one galvanic cell. Thus, the galvanic cell or the electrode winding heat energy is removed.
- the at least one heat transfer region of a galvanic cell is at least temporarily supplied and / or flowed through by a first temperature control medium.
- a first temperature control medium Preferably, the ambient air and / or the first temperature control means of the air conditioning system of the motor vehicle is used for the flow or
- the temperature is set at least one heat transfer area as a function of the permissible operating temperatures of the at least two galvanic cells.
- the temperature of the at least one heat transfer region is set above the temperature of the galvanic cell.
- a heat flow is advantageously driven into the galvanic cell.
- the temperature of a galvanic cell or of an electrode angle approaches a permissible maximum temperature
- the temperature of the at least one heat transfer region is preferably selected to be lower than the temperature of the at least one galvanic cell.
- the galvanic cell or the electrode winding heat energy is removed.
- 1 shows an electrode winding according to the invention in a perspective view
- 2 shows a galvanic cell according to the invention with a plurality of electrode windings according to the invention in a common housing, in a schematic partial section
- FIG. 3 is a schematic representation of a partially cut housing for a galvanic cell according to the invention.
- FIG. 5 shows a further arrangement of a plurality of inventive galvanic cells with a heat exchange device in a schematic representation
- FIG. 6 shows a further arrangement of a plurality of inventive galvanic cells with a heat exchange device in a schematic representation.
- FIG. 1 shows an electrode winding 3 according to the invention in a perspective view. Shown is the electrode coil 3 before the winding is completely completed.
- the electrode winding 3 includes a ceramic separator 4, an anodic electrode 5 and a cathodic electrode 6.
- the separator 4 is formed so as to protrude beyond the outer edge and the outer contour of the electrodes 5 and 6, respectively, whereby the chemical and electric Stability of the electrode coil 3 is improved.
- the electrodes 5 and 6 have contact elements or Ableiterfähnchen 71 and 81, which are electrically connected to a non-illustrated terminal leadthrough.
- a plurality of contact elements 71 and 81 are provided, which protrude from the end face of the electrode winding.
- the electrode winding 3 is accommodated in a housing, not shown, or a housing.
- the contact to the outside takes place in particular by means of at least one pole feedthrough.
- the battery cell 3 may also be arranged in a separate enclosure (not shown).
- a sheath By means of such a sheath, it is also possible, in particular, to prevent the electrodes 5 and 6 arranged on the opposite sides of the separator 4 from coming into electrical contact with one another in the slot arrangement.
- an insulating layer 9 are wrapped in the winding assembly, which is shown in dashed lines in the figure.
- Such an insulating layer is preferably also formed of a ceramic material, but may also be formed of another, thermally stable and electrically non-conductive material.
- FIG. 2 schematically shows a galvanic cell 2 with a plurality of electrode wicks 3, which are arranged in a common housing 11. Not shown are the contacts on the boundary surfaces of the electrode winding, several Stromleit respondeden 15 on the inside within the housing 11 and the pole contacts of the galvanic cell 2. Also not dar- are placed second mold parts 11b for closing the housing or the first molded part 11a.
- the electrode coils 3 are connected in series.
- the first molded part 11 a is formed as a metal sheet adapted to the shape of the electrode coil 3.
- the inside of the molded part 11a is partially thermally conductive and at the same time electrically insulating coated.
- the housing 11 or the first molded part 11a have a heat transfer area 12 which simultaneously serves as a connecting area 13. Depending on the operating mode, the heat transfer region 12 flows around a first temperature control means or is connected to a heat exchange device.
- FIG 3 shows a portion of a housing 11 for a galvanic cell.
- the housing 11 is formed as a composite film. This composite film surrounds the electrode winding, not shown, under pretension, so that the housing 11 exerts a force on the electrode winding. This force forces the electrode wraps together and together.
- On the inside of the housing 11 more Stromleit drivingen 15, 15 a are applied.
- the Stromleit driving 15 is formed as Stromleitband and passed through the walls of the housing 11.
- the current conducting device 15 also serves for contacting the galvanic cell from outside and for contacting an electrode winding.
- the current conducting device 15a is designed as a metallic plate, which is connected to the inside of the housing 11.
- the Stormleit beautiful 15a is electrically contacted both from the inside of the housing 11 and from the outside.
- the current-conducting device 15a is embedded gas-tight in the composite foil of the housing 11.
- the housing 11 has a heat transfer area 12.
- FIG. 4 shows a battery 1 in section.
- the illustrated battery 1 has seven galvanic cells 2. Their enclosures 11 are formed substantially prismatic and have a hexagonal base.
- the housing 11 or the first molded part 11a is formed from a metal sheet, which on the inside partially electrically insulating and heat-conductive coated.
- the housing 11 encloses the electrode winding 3 such that the housing 11 exerts a force on the electrode winding 3. It is not shown that a galvanic cell 2 contains four electrode windings which are connected in series.
- the battery 1 is further equipped with two heat exchange devices 14, 14a. The distances of the longitudinal axes of the individual galvanic cells are dimensioned such that the galvanic cells exert forces on the heat exchange devices 14, 14a.
- the heat exchange devices 14, 14a are flown by a temperature control medium. It is not shown that the first mold parts 11a are closed by adapted and designed as a lid second moldings. The heat exchange devices 14, 14a are folded over several times, in particular to enable a space-saving arrangement of the galvanic cells 2 and to touch the galvanic cells 2 over a large area in a heat-conducting manner.
- Figure 5 shows an arrangement of three galvanic cells with predetermined
- the free space between the galvanic cells 2 is filled with a heat exchange device 14.
- the heat exchange device 14 has a channel 17 for a temperature control. It is not shown that the heat exchange device 14 is adapted to the shape of the surrounding galvanic cells 2. Thus, the heat exchange device 14 nestles with the largest possible surfaces of the galvanic cells 2.
- the heat exchange device 14 has a channel 17 for a second temperature control.
- the second temperature control medium is conveyed through the channels 17 by a conveyor device associated with the battery 1.
- the second temperature control medium is selected so that it undergoes a phase transition at a temperature of three Kelvin below the maximum permissible operating temperature of the galvanic cell.
- FIG. 6 likewise shows an arrangement of a plurality of galvanic cells 2, around a common heat exchange device 14.
- This heat exchange device 14 hugs the galvanic cells 2 surrounding it with as large an area as possible.
- the heat exchange device 14 has a plurality of channels 17, which are provided to be filled with a second temperature control. Not shown is that the channels 17 are closed and have at their ends a heat sink with increased surface area.
- the heat exchange device 14 acts together with the surface-enlarged heat sink and the second temperature control with ability to phase change as a heat pipe. For this it is necessary that the temperature of a phase passage of the second temperature control is adapted to the operating temperatures of the galvanic cells.
- the second temperature control medium is chosen such that a phase change temperature is five Kelvin below the maximum permissible operating temperature of the galvanic cells 2 or of the electrode windings.
- the square elementary cell of the arrangement is the dashed line
- the heat exchange device 14 is designed with larger surfaces and additional channels 17.
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- Electrochemistry (AREA)
- General Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Manufacturing & Machinery (AREA)
- Inorganic Chemistry (AREA)
- Ceramic Engineering (AREA)
- Materials Engineering (AREA)
- Secondary Cells (AREA)
- Cell Separators (AREA)
- Battery Electrode And Active Subsutance (AREA)
- Connection Of Batteries Or Terminals (AREA)
Abstract
Description
Claims
Priority Applications (5)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
CN2010800231415A CN102449810A (zh) | 2009-05-26 | 2010-05-25 | 卷绕电极 |
JP2012512248A JP2012528424A (ja) | 2009-05-26 | 2010-05-25 | 電極コイル |
US13/322,119 US20120164494A1 (en) | 2009-05-26 | 2010-05-25 | Electrode coil |
EP10722004A EP2436062A2 (de) | 2009-05-26 | 2010-05-25 | Elektrodenwickel |
BRPI1014396A BRPI1014396A2 (pt) | 2009-05-26 | 2010-05-25 | bobina de eletrodo, célula galvânica , bateria,método para produzir uma bobina de eletrodo, método para operar uma bateria e método para operar uma célula galvânica |
Applications Claiming Priority (4)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
DE200910022678 DE102009022678A1 (de) | 2009-05-26 | 2009-05-26 | Elektrodenwickel |
DE102009022678.8 | 2009-05-26 | ||
EP09012982.6 | 2009-10-14 | ||
EP20090012982 EP2267820A3 (de) | 2009-05-26 | 2009-10-14 | Elektrodenwickel |
Publications (2)
Publication Number | Publication Date |
---|---|
WO2010136174A2 true WO2010136174A2 (de) | 2010-12-02 |
WO2010136174A3 WO2010136174A3 (de) | 2011-03-03 |
Family
ID=42668143
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
PCT/EP2010/003173 WO2010136174A2 (de) | 2009-05-26 | 2010-05-25 | Elektrodenwickel |
Country Status (8)
Country | Link |
---|---|
US (1) | US20120164494A1 (de) |
EP (2) | EP2267820A3 (de) |
JP (1) | JP2012528424A (de) |
KR (1) | KR20120081027A (de) |
CN (1) | CN102449810A (de) |
BR (1) | BRPI1014396A2 (de) |
DE (1) | DE102009022678A1 (de) |
WO (1) | WO2010136174A2 (de) |
Cited By (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
WO2013065500A1 (ja) * | 2011-11-04 | 2013-05-10 | 株式会社 日立製作所 | 円筒捲回型電池 |
JP2020513649A (ja) * | 2016-11-18 | 2020-05-14 | ロメオ・システムズ,インコーポレーテッド | 蒸気チャンバを利用したバッテリ熱管理のためのシステムおよび方法 |
Families Citing this family (20)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
FR2987940A1 (fr) * | 2012-03-06 | 2013-09-13 | Peugeot Citroen Automobiles Sa | Dispositif de regulation thermique d'un systeme de stockage d'energie |
EP2816629A1 (de) | 2013-03-28 | 2014-12-24 | Technische Universität München | Energiespeicherzelle |
DE102015214526A1 (de) * | 2015-07-30 | 2017-02-02 | Robert Bosch Gmbh | Kompaktes Batteriemodul |
DE102015221524B4 (de) * | 2015-11-03 | 2017-09-07 | Robert Bosch Gmbh | Wärmeleitender Halterahmen für Vorrichtungen |
EP3236513A1 (de) * | 2016-04-22 | 2017-10-25 | HILTI Aktiengesellschaft | Elektrodenanordnung für eine batteriezelle |
EP3327822A1 (de) | 2016-11-29 | 2018-05-30 | Lithium Energy and Power GmbH & Co. KG | Batteriezelle |
GB201704294D0 (en) | 2017-03-17 | 2017-05-03 | Dyson Technology Ltd | Energy storage device |
GB201704295D0 (en) * | 2017-03-17 | 2017-05-03 | Dyson Technology Ltd | Energy storage device |
GB201704292D0 (en) | 2017-03-17 | 2017-05-03 | Dyson Technology Ltd | Energy storage device |
GB201704293D0 (en) | 2017-03-17 | 2017-05-03 | Dyson Technology Ltd | Energy storage device |
EP3401978B1 (de) | 2017-05-09 | 2022-06-08 | Robert Bosch GmbH | Verfahren zur herstellung einer elektrodenanordnung für eine batteriezelle |
EP3416210B1 (de) | 2017-06-12 | 2020-12-02 | Robert Bosch GmbH | Verfahren zum schneiden einer separatorfolie und batteriezelle |
WO2019063082A1 (de) * | 2017-09-28 | 2019-04-04 | Hilti Aktiengesellschaft | Elektrodenanordnung für eine batteriezelle |
CN109179016B (zh) * | 2018-08-09 | 2020-04-21 | 业成科技(成都)有限公司 | 卷材及其制备方法 |
KR102503269B1 (ko) | 2018-09-05 | 2023-02-22 | 주식회사 엘지에너지솔루션 | 육각기둥 형상의 배터리 셀 및 그 제조방법, 그리고 이를 포함하는 배터리 모듈 |
NL1043392B1 (en) * | 2019-09-26 | 2021-05-27 | Hinten Beheer B V | Battery heat exchanger |
DE102020117689A1 (de) | 2020-07-06 | 2022-01-13 | Bayerische Motoren Werke Aktiengesellschaft | Elektrischer Energiespeicher mit Wabenstruktur sowie Fahrzeug mit einem solchen |
DE102021107000A1 (de) | 2021-03-22 | 2022-09-22 | Bayerische Motoren Werke Aktiengesellschaft | Zellpack für eine Fahrzeugbatterie sowie Fahrzeugbatterie |
DE102021109634A1 (de) | 2021-04-16 | 2022-10-20 | Bayerische Motoren Werke Aktiengesellschaft | Batteriezellenanordnung |
CN114793522B (zh) * | 2022-03-31 | 2023-09-22 | 江苏大学 | 一种电吸附结合冷凝法的土壤洗盐水循环利用系统及方法 |
Family Cites Families (12)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JP4642179B2 (ja) * | 1999-10-08 | 2011-03-02 | パナソニック株式会社 | 集合型二次電池 |
DE10238944A1 (de) * | 2002-08-24 | 2004-03-04 | Creavis Gesellschaft Für Technologie Und Innovation Mbh | Separator zur Verwendung in Hochenergiebatterien sowie Verfahren zu dessen Herstellung |
DE10255121B4 (de) * | 2002-11-26 | 2017-09-14 | Evonik Degussa Gmbh | Separator mit asymmetrischem Porengefüge für eine elektrochemische Zelle |
DE102004018930A1 (de) * | 2004-04-20 | 2005-11-17 | Degussa Ag | Verwendung eines keramischen Separators in Lithium-Ionenbatterien, die einen Elektrolyten aufweisen, der ionische Flüssigkeiten enthält |
DE102004018929A1 (de) * | 2004-04-20 | 2005-11-17 | Degussa Ag | Elektrolytzusammensetzung sowie deren Verwendung als Elektrolytmaterial für elektrochemische Energiespeichersysteme |
US20050255379A1 (en) * | 2004-05-12 | 2005-11-17 | Michael Marchio | Battery assembly with heat sink |
BRPI0511309B1 (pt) * | 2004-07-07 | 2018-12-18 | Lg Chemical Ltd | separador poroso composto orgânico/inorgânico e dispositivo eletroquímico |
CN1858932A (zh) * | 2005-05-07 | 2006-11-08 | 深圳市美拜电子有限公司 | 一种锂离子电池 |
JP4819399B2 (ja) * | 2005-05-26 | 2011-11-24 | 日本電気株式会社 | 薄型電池 |
CN1992415B (zh) * | 2005-12-30 | 2010-05-05 | 比亚迪股份有限公司 | 卷绕电极组结构及采用该结构的二次电池以及该结构的卷绕方法 |
CN101375436B (zh) * | 2006-05-22 | 2010-10-06 | 松下电器产业株式会社 | 隔膜及非水电解质二次电池 |
DE102007010739B4 (de) * | 2007-02-27 | 2009-01-29 | Daimler Ag | Batterie mit einer Wärmeleitplatte |
-
2009
- 2009-05-26 DE DE200910022678 patent/DE102009022678A1/de not_active Withdrawn
- 2009-10-14 EP EP20090012982 patent/EP2267820A3/de not_active Withdrawn
-
2010
- 2010-05-25 WO PCT/EP2010/003173 patent/WO2010136174A2/de active Application Filing
- 2010-05-25 BR BRPI1014396A patent/BRPI1014396A2/pt not_active IP Right Cessation
- 2010-05-25 KR KR20117030969A patent/KR20120081027A/ko not_active Application Discontinuation
- 2010-05-25 JP JP2012512248A patent/JP2012528424A/ja active Pending
- 2010-05-25 CN CN2010800231415A patent/CN102449810A/zh active Pending
- 2010-05-25 EP EP10722004A patent/EP2436062A2/de not_active Withdrawn
- 2010-05-25 US US13/322,119 patent/US20120164494A1/en not_active Abandoned
Non-Patent Citations (1)
Title |
---|
None |
Cited By (3)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
WO2013065500A1 (ja) * | 2011-11-04 | 2013-05-10 | 株式会社 日立製作所 | 円筒捲回型電池 |
JP2020513649A (ja) * | 2016-11-18 | 2020-05-14 | ロメオ・システムズ,インコーポレーテッド | 蒸気チャンバを利用したバッテリ熱管理のためのシステムおよび方法 |
JP7149269B2 (ja) | 2016-11-18 | 2022-10-06 | ロメオ・システムズ,インコーポレーテッド | 蒸気チャンバを利用したバッテリ熱管理のためのシステムおよび方法 |
Also Published As
Publication number | Publication date |
---|---|
CN102449810A (zh) | 2012-05-09 |
EP2436062A2 (de) | 2012-04-04 |
DE102009022678A1 (de) | 2010-12-02 |
US20120164494A1 (en) | 2012-06-28 |
BRPI1014396A2 (pt) | 2016-04-12 |
JP2012528424A (ja) | 2012-11-12 |
EP2267820A3 (de) | 2011-02-16 |
KR20120081027A (ko) | 2012-07-18 |
EP2267820A2 (de) | 2010-12-29 |
WO2010136174A3 (de) | 2011-03-03 |
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